JPH1192980A - Corrosion protection method of seawater cooling water series equipment by constant potential external power source system and electric corosion protection device - Google Patents
Corrosion protection method of seawater cooling water series equipment by constant potential external power source system and electric corosion protection deviceInfo
- Publication number
- JPH1192980A JPH1192980A JP9248665A JP24866597A JPH1192980A JP H1192980 A JPH1192980 A JP H1192980A JP 9248665 A JP9248665 A JP 9248665A JP 24866597 A JP24866597 A JP 24866597A JP H1192980 A JPH1192980 A JP H1192980A
- Authority
- JP
- Japan
- Prior art keywords
- potential
- anticorrosion
- power supply
- constant
- cooling water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Prevention Of Electric Corrosion (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】この発明は、火力発電所や化
学工場などで使用される海水中で耐食性を示す金属を含
む複数の異種金属から構成される海水冷却水系統機器
(例えば、復水器、熱交換器、海水取水口スクリーン、
ボール捕集器等)に適用する定電位外部電源方式による
電気防食方法及び電気防食装置に関するものであり、特
に現に使用されている海水冷却水系統機器に備えられて
いる定電位外部電源方式電気防食装置の防食電流の通電
を制御することにより効率良く電気防食を行う方法及び
装置に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a seawater cooling water system device (for example, a condenser) comprising a plurality of dissimilar metals including metals having corrosion resistance in seawater used in thermal power plants and chemical factories. , Heat exchanger, seawater intake screen,
The present invention relates to a cathodic protection method and a cathodic protection device using a constant-potential external power supply method applied to a ball collector, etc., and particularly to a constant-potential external power supply cathodic protection provided in a seawater cooling water system device currently used. TECHNICAL FIELD The present invention relates to a method and an apparatus for efficiently performing electrolytic protection by controlling the passage of anticorrosion current of the apparatus.
【0002】[0002]
【従来の技術】例えば、従来の復水器は、図4の断面図
に見られるように、復水器10の冷却管11にはチタン
合金が使用されており、海水冷却水系統機器の主要部に
は海水中でほぼ完全な耐食性を示す金属が使用されるこ
とが多い。しかし一方で、復水器10の管板12にはネ
ーバル黄銅などの銅合金が、また、復水器の水室13に
は表面にゴムライニングや防食塗装16を施した鋼板1
7などの海水中であまり耐食性を示さない金属が使用さ
れている。図4において1は定電位直流電源装置、14
は鉛銀電極或はチタン白金電極からなる耐久性電極また
は鉄電極、15は塩化銀または亜鉛等からなる照合電極
である。この従来の復水器においてゴムライニング16
が健全である間は問題はないが、ゴムライニング16が
劣化して破損すると、鋼板17と冷却管のチタン合金ま
たは管板12の銅合金と冷却管のチタン合金という異種
金属の接触が起こり、それににより腐食が起こる。この
腐食を防止するために防食電流を流して腐食を阻止して
いるが、チタン合金が電気防食により過度に分極される
と水素脆化が起こるところから、復水器には常に防食管
理電位(防食に必要な範囲の電位)を保つように防食電
流を自動的に制御する定電位外部電源方式電気防食装置
が取り付けられている。2. Description of the Related Art For example, in a conventional condenser, a titanium alloy is used for a cooling pipe 11 of a condenser 10 as shown in a sectional view of FIG. Metals that exhibit almost perfect corrosion resistance in seawater are often used for parts. On the other hand, a copper alloy such as naval brass is used for the tube sheet 12 of the condenser 10, and a steel sheet 1 whose surface is coated with rubber lining or anticorrosion coating 16 is used for the water chamber 13 of the condenser.
For example, a metal having low corrosion resistance in seawater such as 7 is used. In FIG. 4, reference numeral 1 denotes a constant potential DC power supply,
Is a durable electrode made of a lead silver electrode or a titanium platinum electrode or an iron electrode, and 15 is a reference electrode made of silver chloride or zinc. In this conventional condenser, the rubber lining 16
There is no problem while the sound is healthy, but when the rubber lining 16 is deteriorated and damaged, dissimilar metals such as the steel alloy 17 and the titanium alloy of the cooling pipe or the copper alloy of the tube sheet 12 and the titanium alloy of the cooling pipe occur, It causes corrosion. In order to prevent this corrosion, corrosion prevention current is passed to prevent corrosion. However, hydrogen embrittlement occurs when titanium alloy is excessively polarized by cathodic protection. A constant-potential external power supply type anti-corrosion device that automatically controls the anti-corrosion current so as to maintain a potential in a range necessary for anti-corrosion is installed.
【0003】同様に、ボール捕集器(図示せず)の胴体
部分には表面にゴムライニングや防食塗装を施した鋼板
などの海水中であまり耐食性を示さない金属が使用され
るので、ボール捕集器のゴムライニング等が劣化した胴
体部分は高級ステンレス鋼で構成した捕集格子との接触
により鋼とステンレス鋼との異種金属接触腐食が起こ
る。この高級ステンレス鋼で構成した捕集格子は過度に
分極されると水素脆性割れを起こすおそれがあるので厳
密な防食電位の管理が必要であることから、かかるボー
ル捕集器には常に防食管理電位を保つように防食電流を
自動的に制御する定電位外部電源方式電気防食装置が取
り付けられている。[0003] Similarly, the body of a ball collector (not shown) is made of a metal that does not show much corrosion resistance in seawater, such as a steel lining or a steel plate coated with anticorrosive paint on the surface. The body portion of the collector where the rubber lining or the like has deteriorated is in contact with the collection grid made of high-grade stainless steel, so that corrosion of the different metals between the steel and stainless steel occurs. Excessive polarization of this collection grid made of high-grade stainless steel may cause hydrogen embrittlement cracking, so strict control of the anticorrosion potential is required. A constant-potential external power supply type anti-corrosion device that automatically controls the anti-corrosion current to maintain the current is installed.
【0004】一般に、複数の異種金属から構成される構
造物を防食するために必要な防食電流は、金属の種類ご
との防食対象面積と金属単位面積当たりに必要な防食電
流密度との積によって求めた防食電流の和で求めること
ができる。チタン合金や高級ステンレス鋼などの耐食性
金属と黄銅や鋼などの耐食性に劣る金属を含む複数の異
種金属で構成される復水器やボール捕集器などの海水冷
却水系統機器にも、上記計算で求めた防食電流を供給す
るに十分な容量をもった定電位電気防食装置が設置され
るが、耐食性金属は海水中で不動態皮膜と呼ばれる電気
抵抗が非常に高い酸化皮膜を表面に形成するので防食電
流は僅かで済み、かかる耐食性金属を含まない海水冷却
水系統機器よりも電気防食装置の防食電流容量をかなり
小さく設計することができる。In general, a corrosion protection current required to protect a structure composed of a plurality of dissimilar metals is determined by a product of a corrosion protection target area for each type of metal and a corrosion protection current density required per metal unit area. It can be obtained by the sum of the anticorrosion currents. The above calculations are also applied to seawater cooling water system equipment such as condensers and ball collectors composed of multiple dissimilar metals including corrosion-resistant metals such as titanium alloys and high-grade stainless steel and metals with poor corrosion resistance such as brass and steel. A constant-potential cathodic protection device with sufficient capacity to supply the anticorrosion current determined in step 1 is installed, but the corrosion-resistant metal forms an oxide film with a very high electrical resistance called a passive film in the seawater on the surface. As a result, the anticorrosion current is small, and the anticorrosion current capacity of the anticorrosion device can be designed to be considerably smaller than that of a seawater cooling water system device that does not contain such a corrosion-resistant metal.
【0005】[0005]
【発明が解決しようとする課題】近年、特に大都市をひ
かえた東京湾や大阪湾或いは伊勢湾などの沿岸に建設さ
れた火力発電所や化学工場などの耐食性金属を含む複数
の異種金属で構成された海水冷却水系統機器では、海水
の水質悪化に伴い防食に必要な電流が激増して、従来の
設計に基づく電気防食装置の電流容量では防食電流が不
足して防食管理電位を維持できず、一部には腐食が発生
しているケースもみられる。本発明者等が分極試験を行
った結果では、かかる海水冷却水系統機器に必要な防食
電流は従来の設計値の数倍から十数倍にも達する場合が
あることが判明した。In recent years, it is composed of a plurality of dissimilar metals including corrosion-resistant metals, such as thermal power plants and chemical factories constructed along the coasts of Tokyo Bay, Osaka Bay, Ise Bay, etc., especially in large cities. In the seawater cooling water system equipment, the current required for anticorrosion increases drastically due to the deterioration of seawater quality, and the anticorrosion current is insufficient with the current capacity of the cathodic protection device based on the conventional design, and the anticorrosion control potential cannot be maintained. In some cases, corrosion has occurred. The present inventors have conducted a polarization test and found that the anticorrosion current required for such a seawater cooling water system device may reach several times to ten and several times the conventional design value.
【0006】現に使用されている海水冷却水系統機器に
備えられている既設の定電位外部電源方式電気防食装置
から供給される防食電流と防食電位との関係をグラフに
示すと図3のようになる。防食電流が増加して、防食電
流が定電位直流電源装置の最大出力電流値の170Aに
達すると、既設の電気防食装置の容量からしてこれ以上
防食電流を増加することはできなくなると同時に防食電
位が電位設定値の−600Vよりも貴に移行し、防食電
位が防食管理電位の下限の−450Vを外れると、「電
位不足」警報が出てしまう。すなわち、通電開始当初は
少ない防食電流でも防食管理電位の範囲内の電位設定値
が確保されているのであるが、防食電流が暫時増加して
定電位直流電源装置の最大出力電流値を越えてしまい、
防食電流不足となると電位設定値から外れて貴に移行
し、さらに貴に移行して防食管理電位を維持できない状
態になることが分かったのである。既設の電気防食装置
を数倍から十数倍もの容量の電気防食装置に交換すれ
ば、図3の二点鎖線Aに示されるように防食電流を増加
して防食管理電位を維持することができるが、既設の電
気防食装置を数倍から十数倍もの容量の電気防食装置に
交換するとなれば膨大な費用を要するばかりでなく、海
水冷却水系統機器本体に電極装置等を多数増設するなど
の大規模な改造を行わなければならないという困難な問
題がある。FIG. 3 is a graph showing the relationship between the anticorrosion current and the anticorrosion potential supplied from the existing constant-potential external power supply type cathodic protection device provided in the currently used seawater cooling water system equipment. Become. When the anticorrosion current increases and the anticorrosion current reaches the maximum output current value of 170 A of the constant potential DC power supply device, it is impossible to increase the anticorrosion current any more due to the capacity of the existing cathodic protection device, and at the same time anticorrosion When the potential shifts to a value higher than the potential set value of -600 V and the anticorrosion potential deviates from the lower limit of -450 V of the anticorrosion control potential, an "insufficient potential" alarm is issued. That is, at the beginning of energization, a potential set value within the range of the anticorrosion control potential is secured even with a small anticorrosion current, but the anticorrosion current temporarily increases and exceeds the maximum output current value of the constant-potential DC power supply. ,
It was found that when the anticorrosion current became insufficient, the potential deviated from the potential set value and shifted to noble, and further shifted to noble so that the anticorrosion control potential could not be maintained. If the existing cathodic protection device is replaced with a cathodic protection device having a capacity several times to several tens times, the anticorrosion current can be increased and the anticorrosion control potential can be maintained as shown by the two-dot chain line A in FIG. However, replacing existing cathodic protection devices with cathodic protection devices of several to several tens of times more would not only require enormous costs but also increase the number of electrode devices etc. in the seawater cooling water system equipment main body. There is a difficult problem that large-scale remodeling must be performed.
【0007】[0007]
【課題を解決するための手段】そこで本発明者等は、現
に使用されている海水冷却水系統機器に備えられている
既設の定電位外部電源方式電気防食装置をそのまま使用
してこれら困難な問題を解決すべく試験研究を行った結
果、(イ)防食管理電位を維持するために、防食電流を
暫時増加していくが、防食電流がある程度増加した後に
一定時間通電を停止して再び通電を再開すると、防食電
位を維持するために必要な防食電流は通電停止前よりも
大幅に減少し、その後再び防食電流が暫時増加するこ
と、(ロ)これにより防食電流通電開始時から防食電流
が暫時増加して所定の電流値に達するまでの時間を予め
計測しておき、通電開始後この計測した時間経過時に通
電を停止し、通電停止から所定時間経過後に防食電流の
通電を再開する手順を繰り返すことにより、防食管理電
位を維持することができること、(ハ)防食電流が定電
位直流電源装置の最大出力電流値以下の所定の電流値に
達した時に、防食電流の通電を停止して所定時間放置し
た後に再び通電を開始する手順を繰り返すと防食管理電
位を維持することができること、(ニ)防食電流が定電
位直流電源装置の最大出力電流値に達した時に通電を停
止して所定期間経過後に再び通電を開始する手順を繰り
返した場合にも防食管理電位を維持することができるこ
と、(ホ)防食電流の増加に伴う防食電流の不足により
海水冷却水系統機器の防食電位が防食管理電位を外れる
前に通電を停止し、通電停止から所定時間経過後に防食
電流の通電を再開しても良いこと、(ト)前記通電を停
止する時間は30分〜3時間の範囲内で十分であるこ
と、などが判明したのである。SUMMARY OF THE INVENTION Accordingly, the present inventors have solved these difficult problems by using the existing constant-potential external power supply type cathodic protection system provided in the currently used seawater cooling water system equipment as it is. As a result of conducting test research to solve the problem, (a) the anticorrosion current is increased for a while to maintain the anticorrosion control potential. When restarted, the anticorrosion current required to maintain the anticorrosion potential is significantly reduced from before the current was stopped, and then temporarily increased again. A procedure in which the time until the current value increases and reaches a predetermined current value is measured in advance, the energization is stopped when the measured time elapses after the energization starts, and the energization of the anticorrosion current is restarted after the elapse of the predetermined time from the energization stop. (C) When the anticorrosion current reaches a predetermined current value that is equal to or less than the maximum output current value of the constant-potential DC power supply, the application of the anticorrosion current is stopped by repeating It is possible to maintain the anticorrosion control potential by repeating the procedure of starting energization again after standing for a period of time, and (d) stopping energization when the anticorrosion current reaches the maximum output current value of the constant-potential DC power supply, for a predetermined period. The anticorrosion control potential can be maintained even when the procedure of restarting the energization is repeated after the elapse, and (e) the anticorrosion potential of the seawater cooling water system equipment is reduced by the shortage of anticorrosion current accompanying the increase in anticorrosion current. The power supply may be stopped before the power supply deviates, and the power supply of the anticorrosion current may be restarted after a predetermined time has elapsed from the power supply stop. (G) The time for stopping the power supply is within a range of 30 minutes to 3 hours. It is enough, it's like it was found.
【0008】この発明は、かかる研究結果に基づいてな
されたものであって、(1)耐食性金属を含む複数の異
種金属で構成される海水冷却水系統機器を防食する定電
位外部電源方式による電気防食方法において、防食電流
通電開始から所定時間経過時に通電を停止し、通電停止
から所定時間経過後に防食電流の通電を再開する手順を
繰り返す定電位外部電源方式による海水冷却水系統機器
の電気防食方法、(2)耐食性金属を含む複数の異種金
属で構成される海水冷却水系統機器を防食する定電位外
部電源方式による電気防食方法において、防食電流が増
加して定電位直流電源装置の最大出力電流値以下の所定
の電流値に達したときに通電を停止し、通電停止から所
定時間経過後に防食電流の通電を再開する手順を繰り返
す定電位外部電源方式による海水冷却水系統機器の電気
防食方法、(3)耐食性金属を含む複数の異種金属で構
成される海水冷却水系統機器を防食する定電位外部電源
方式による電気防食方法において、防食電流が増加して
定電位直流電源装置の最大出力電流値に達したときに通
電を停止し、通電停止から所定時間経過後に防食電流の
通電を再開する手順を繰り返す定電位外部電源方式によ
る海水冷却水系統機器の電気防食方法、(4)耐食性金
属を含む複数の異種金属で構成される海水冷却水系統機
器を防食する定電位外部電源方式による電気防食方法に
おいて、防食電流の増加に伴う防食電流の不足により海
水冷却水系統機器の防食電位が防食管理電位を外れる前
に通電を停止し、通電停止から所定時間経過後に防食電
流の通電を再開する手順を繰り返す定電位外部電源方式
による海水冷却水系統機器の電気防食方法、に特徴を有
するものである。The present invention has been made based on the results of such research, and (1) a constant-potential external power supply system for protecting seawater cooling water system equipment composed of a plurality of dissimilar metals including corrosion-resistant metals. In the anticorrosion method, the method of stopping the energization when a predetermined time has elapsed since the start of the anticorrosion current energization, and repeating the procedure of resuming the energization of the anticorrosion current after the elapse of the predetermined time from the stop of the energization, a method of electrolytic anticorrosion of a seawater cooling water system device by a constant potential external power supply system. (2) In a cathodic protection method using a constant potential external power supply method for protecting seawater cooling water system equipment composed of a plurality of dissimilar metals including corrosion resistant metals, the maximum output current of the constant potential DC power supply increases due to an increase in the corrosion protection current. A constant-potential external power supply that repeats the procedure of stopping the energization when a predetermined current value equal to or less than the value is reached and restarting the application of the anticorrosion current after a lapse of a predetermined time from the stop of the energization Corrosion protection method for seawater cooling water system equipment by the formula, (3) an anticorrosion current is increased in a cathodic protection method using a constant-potential external power supply system for protecting seawater cooling water system equipment composed of a plurality of dissimilar metals including corrosion-resistant metals. Seawater cooling water system equipment using a constant-potential external power supply system that repeats the procedure of stopping the energization when the maximum output current value of the constant-potential DC power supply device is reached and restarting the application of the anticorrosion current after a lapse of a predetermined time from the stop of the energization (4) In a cathodic protection method using a constant-potential external power supply system for protecting seawater cooling water system equipment composed of a plurality of dissimilar metals including corrosion-resistant metals, there is a shortage of anticorrosion current accompanying an increase in anticorrosion current. The procedure of stopping the energization before the anticorrosion potential of the seawater cooling water system device deviates from the anticorrosion control potential, and resuming the energization of the anticorrosion current after a lapse of a predetermined time from the stop of energization is repeated. Cathodic protection method of seawater cooling water system equipment by potential external power supply system, and it has the characteristics to.
【0009】上記したこの発明の防食方法は手動操作で
も達成できるが、定電位直流電源装置に、防食電流が暫
時増加して予め設定した電流値に達した場合や防食電流
不足により海水冷却水系統機器の電位が防食管理電位を
外れた時或いは通電開始時から所定の時間が経過した時
に出力電流の通電を停止し、通電停止から所定期間経過
後に通電を開始する装置を備えておけば、電気防食装置
の防食電流や電位を監視することなくこの発明にかかる
防食方法を達成することができる。The above-described anticorrosion method of the present invention can be achieved by manual operation. However, when the anticorrosion current temporarily increases and reaches a preset current value, or when the anticorrosion current is insufficient, the seawater cooling water system is supplied to the constant potential DC power supply. If a device is provided that stops the application of the output current when the potential of the device deviates from the anticorrosion management potential or when a predetermined time has elapsed from the start of energization, and starts the energization after a lapse of a predetermined period from the stop of energization, The anticorrosion method according to the present invention can be achieved without monitoring the anticorrosion current or potential of the anticorrosion device.
【0010】従って、この発明は、(5)商用交流電圧
を所定の電圧に降圧する変圧器と、交流を直流に変換す
る整流器と防食対象物の防食電位を一定に制御する電位
制御回路とから構成される定電位直流電源装置と海水冷
却水系統機器に防食電流を供給する電極装置と該海水冷
却水系統機器の電位を計測する照合電極装置とから基本
的に構成される定電位外部電源方式電気防食装置におい
て、該定電位直流電源装置に防食電流通電開始から所定
時間経過後に通電を停止する制御装置と通電停止から所
定期間経過時に通電を再開する制御装置とを備えた耐食
性金属を含む複数の異種金属で構成される海水冷却水系
統機器の定電位外部電源方式電気防食装置、(6)商用
交流電圧を所定の電圧に降圧する変圧器と、交流を直流
に変換する整流器と防食対象物の防食電位を一定に制御
する電位制御回路とから構成される定電位直流電源装置
と海水冷却水系統機器に防食電流を供給する電極装置と
該海水冷却水系統機器の電位を計測する照合電極装置と
から基本的に構成される定電位外部電源方式電気防食装
置において、該定電位直流電源装置に出力電流が増加し
て定電位直流電源装置の最大出力電流値以下の所定の電
流値に達した時に通電を停止する制御装置と、通電停止
から所定時間経過後に通電を再開する制御装置とを備え
た耐食性金属を含む複数の異種金属で構成される海水冷
却水系統機器の定電位外部電源方式電気防食装置、
(7)商用交流電圧を所定の電圧に降圧する変圧器と、
交流を直流に変換する整流器と防食対象物の防食電位を
一定に制御する電位制御回路とから構成される定電位直
流電源装置と海水冷却水系統機器に防食電流を供給する
電極装置と該海水冷却水系統機器の電位を計測する照合
電極装置とから基本的に構成される定電位外部電源方式
電気防食装置において、該定電位直流電源装置に出力電
流が増加して定電位直流電源装置の最大出力電流値に達
した時に通電を停止する制御装置と、通電停止から所定
時間経過後に通電を再開する制御装置とを備えた耐食性
金属を含む複数の異種金属で構成される海水冷却水系統
機器の定電位外部電源方式電気防食装置、(8)商用交
流電圧を所定の電圧に降圧する変圧器と、交流を直流に
変換する整流器と防食対象物の防食電位を一定に制御す
る電位制御回路とから構成される定電位直流電源装置と
海水冷却水系統機器に防食電流を供給する電極装置と該
海水冷却水系統機器の電位を計測する照合電極装置とか
ら基本的に構成される定電位外部電源方式電気防食装置
において、該定電位直流電源装置の最大出力電流値を越
えて防食電流が不足し、海水冷却水系統機器の電位が防
食管理電位を外れて貴に移行した前に通電を停止する制
御装置と、通電停止から所定時間経過後に通電を再開す
る制御装置とを備えた耐食性金属を含む複数の異種金属
で構成される海水冷却水系統機器の定電位外部電源方式
電気防食装置、に特徴を有するものである。Therefore, the present invention comprises (5) a transformer for stepping down a commercial AC voltage to a predetermined voltage, a rectifier for converting AC to DC, and a potential control circuit for controlling the anticorrosion potential of the anticorrosion target to be constant. A constant-potential external power supply system basically comprising a constant-potential DC power supply device, an electrode device for supplying an anticorrosion current to seawater cooling water system equipment, and a reference electrode device for measuring the potential of the seawater cooling water system equipment. In the cathodic protection device, a plurality of devices including a corrosion-resistant metal including a control device that stops energization after a lapse of a predetermined time from the start of anticorrosion current energization to the constant-potential DC power supply device and a control device that restarts energization after a lapse of a predetermined period from the stop of energization (6) A constant voltage external power supply type anticorrosion system for seawater cooling water system equipment composed of dissimilar metals, (6) a transformer that steps down a commercial AC voltage to a predetermined voltage, and a rectifier that converts AC to DC A constant-potential DC power supply comprising a potential control circuit for controlling the anticorrosion potential of the anticorrosion target to be constant, an electrode device for supplying anticorrosion current to the seawater cooling water system equipment, and measuring the potential of the seawater cooling water equipment. In a constant potential external power supply type anticorrosion device basically comprising a reference electrode device, a predetermined current value equal to or less than a maximum output current value of the constant potential DC power supply device when an output current increases to the constant potential DC power supply device. A control device that stops energization when the current reaches the control unit, and a control device that restarts energization after a predetermined time has elapsed from the stop of energization. Power supply type cathodic protection device,
(7) a transformer for stepping down a commercial AC voltage to a predetermined voltage;
A constant-potential direct-current power supply comprising a rectifier for converting alternating current to direct current and a potential control circuit for controlling the corrosion prevention potential of the anticorrosion target to be constant, an electrode device for supplying a corrosion protection current to seawater cooling water system equipment, and the seawater cooling. In a constant-potential external power supply type anticorrosion device basically consisting of a reference electrode device for measuring the potential of water system equipment, the output current increases to the constant-potential DC power supply and the maximum output of the constant-potential DC power supply is increased. A seawater cooling water system device comprising a plurality of dissimilar metals including a corrosion-resistant metal, comprising a control device that stops energization when the current value is reached, and a control device that restarts energization after a predetermined time has elapsed from the stoppage of energization. (8) a transformer for stepping down a commercial AC voltage to a predetermined voltage, a rectifier for converting AC to DC, and a potential control circuit for controlling the corrosion prevention potential of an object to be protected at a constant level. A constant-potential external power supply basically consisting of a constant-potential DC power supply device composed of an electrode device for supplying an anticorrosive current to seawater cooling water system equipment and a reference electrode device for measuring the potential of the seawater cooling water system equipment In the anticorrosion system, the anticorrosion current is insufficient beyond the maximum output current value of the constant-potential DC power supply device, and the energization is stopped before the potential of the seawater cooling water system device deviates from the anticorrosion management potential and shifts to noble. A constant-potential external power-supply type cathodic protection device for seawater cooling water system equipment comprising a plurality of different metals including a corrosion-resistant metal, comprising a control device and a control device that restarts power supply after a lapse of a predetermined time from the stop of power supply. It has.
【0011】[0011]
【発明の実施の形態】つぎに、この発明の海水冷却水系
統機器の定電位外部電源方式による防食方法および定電
位外部電源方式電気防食装置を図面に基づいて具体的に
説明する。図1は、この発明の防食方法に使用する定電
位外部電源方式電気防食装置の概略構成を示した図であ
る。図1において、1は定電位直流電源装置であり、そ
の主回路は商用交流電流を定電位直流電源装置1に導入
するための入力スイッチ2、商用交流電圧を所定の電圧
に降圧するための変圧器3、交流電流を防食用の直流電
流に変換するための整流体4などで構成されている。5
は最適な防食電位を設定し且つこれを維持するために直
流回路に電流制御用信号を発信するコントローラ、6は
直流電流値を検出するためのシャント抵抗、7は防食電
流が所定の設定値または最大出力電流値に達したとき、
或いは防食対象物の電位が防食管理電位を外れる前に電
磁スイッチ8に「電源OFF」信号を、タイマー9に
「タイマーON」信号を送る防食不足検出回路である。
また、10は復水器、11はチタン合金製の冷却管、1
2はネーバル黄銅製の管板、13は鋼製の水室で内面は
ゴムライニングで被覆されている。14は鉛銀電極或い
はチタン白金電極等の耐久性電極または鉄電極、15は
塩化銀または亜鉛等の照合電極である。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, a method for preventing corrosion of a seawater cooling water system apparatus by a constant potential external power supply system and a constant potential external power supply type anticorrosion apparatus of the present invention will be specifically described with reference to the drawings. FIG. 1 is a diagram showing a schematic configuration of a constant-potential external power supply type anticorrosion device used in the anticorrosion method of the present invention. In FIG. 1, reference numeral 1 denotes a constant potential DC power supply, the main circuit of which is an input switch 2 for introducing a commercial AC current to the constant potential DC power supply 1, and a transformer for stepping down the commercial AC voltage to a predetermined voltage. And a rectifier 4 for converting an AC current into a DC current for anticorrosion. 5
Is a controller for setting an optimum anticorrosion potential and transmitting a current control signal to a DC circuit in order to maintain the same, 6 is a shunt resistor for detecting the DC current value, 7 is a predetermined set value of the anticorrosion current or When the maximum output current value is reached,
Alternatively, the anti-corrosion detection circuit sends a “power OFF” signal to the electromagnetic switch 8 and a “timer ON” signal to the timer 9 before the potential of the anti-corrosion target deviates from the anti-corrosion control potential.
10 is a condenser, 11 is a cooling pipe made of titanium alloy, 1
2 is a tube sheet made of Naval brass, 13 is a water chamber made of steel and the inner surface is covered with a rubber lining. Reference numeral 14 denotes a durable electrode such as a lead silver electrode or a titanium platinum electrode or an iron electrode, and 15 denotes a reference electrode such as silver chloride or zinc.
【0012】このような定電位外部電源方式電気防食装
置によりこの発明の防食方法を実施するときは、入力ス
イッチ2をONにして定電位直流電源装置1に交流電流
を導入し、コントローラ5で防食管理電位を設定した後
に電磁スイッチ8をONにして直流出力回路の正極に接
続された耐久性電極14から海水を介して冷却管11、
管板12及び水室13に防食電流を供給する。冷却管1
1、管板12及び水室13の電位は照合電極15で検出
され、この電位信号がコントローラ5にフィードバック
されて冷却管11、管板12及び水室13の電位が常に
防食管理電位に保たれるように防食電流が制御される。When the anticorrosion method of the present invention is performed by such a constant potential external power supply type anticorrosion device, the input switch 2 is turned on to introduce an alternating current to the constant potential DC power supply device 1, and the controller 5 performs corrosion protection. After setting the control potential, the electromagnetic switch 8 is turned on, and the cooling pipe 11 is connected via the seawater from the durable electrode 14 connected to the positive electrode of the DC output circuit.
An anticorrosion current is supplied to the tube sheet 12 and the water chamber 13. Cooling pipe 1
1. The potentials of the tube sheet 12 and the water chamber 13 are detected by the reference electrode 15, and this potential signal is fed back to the controller 5 so that the potentials of the cooling pipe 11, the tube sheet 12 and the water chamber 13 are always kept at the anticorrosion control potential. The anticorrosion current is controlled so that
【0013】時間の経過とともに暫時防食電流が増加し
て防食不足検出回路7に設定された電流値に達するか、
または、防食電流が直流電源装置の最大出力電流値に達
して海水冷却水系統機器の電位が貴に移行し、防食管理
電位から外れることが防食不足検出回路7で検知される
とその前に電磁スイッチ8が開いて防食電流の供給が停
止されるとともにタイマー9が差動する。タイマー9の
設定時間が経過すると防食不足検出回路7からの信号に
より電磁スイッチ8が閉じて再び防食電流の供給が開始
される。なお、電磁スイッチ8は本図のように直流出力
回路に置いてもよいが、交流入力側に置いてもよく、ま
た、コントローラ5からの信号により整流体4から防食
電流が流れなくなるように構成すれば電磁スイッチ8を
省略することができる。As the time elapses, the anticorrosion current temporarily increases and reaches a current value set in the anticorrosion insufficient detection circuit 7,
Alternatively, if the anticorrosion shortage detection circuit 7 detects that the anticorrosion current reaches the maximum output current value of the DC power supply device, the potential of the seawater cooling water system equipment shifts to noble, and deviates from the anticorrosion control potential, the anticorrosion protection circuit 7 detects that The switch 8 is opened to stop the supply of the anticorrosion current, and the timer 9 differentially operates. When the set time of the timer 9 elapses, the electromagnetic switch 8 is closed by the signal from the anticorrosion insufficient detection circuit 7 and the supply of the anticorrosion current is started again. The electromagnetic switch 8 may be placed on the DC output circuit as shown in this figure, but may be placed on the AC input side. Also, the electromagnetic switch 8 is configured so that the anticorrosion current does not flow from the rectifier 4 by the signal from the controller 5. Then, the electromagnetic switch 8 can be omitted.
【0014】つぎに、この発明の実施例を図面に基づい
て一層具体的に説明する。チタン合金冷却管を使用して
いる2系列からなる発電所の復水器の片系列に対して図
1に示す定電位外部電源方式の電気防食装置を設置し、
30日間通電試験をおこない、他系列には従来例として
通常の定電位外部電源方式の電気防食装置を設置して通
電を行った。なお、実施例、従来例とも復水器1水室当
たりの直流電源装置の最大出力電流は170Aであり、
電極14には白金チタン電極を、照合電極15には塩化
銀照合電極を使用した。Next, embodiments of the present invention will be described more specifically with reference to the drawings. A constant potential external power supply type cathodic protection system shown in FIG. 1 is installed for one series of condensers of a power plant consisting of two series using titanium alloy cooling pipes,
An energization test was performed for 30 days, and a conventional constant potential external power supply type anticorrosion device was installed as a conventional example in the other series to energize. Note that the maximum output current of the DC power supply device per condenser water chamber is 170 A in both the embodiment and the conventional example.
A platinum titanium electrode was used as the electrode 14 and a silver chloride reference electrode was used as the reference electrode 15.
【0015】〔実施例〕海水入口水室及び出口水室の防
食管理電位を−600mVに設定し、最大出力電流が3
0分間維持された時に防食不足検出回路7からの信号に
より電磁スイッチ8が開いて防食電流の供給が停止さ
れ、1時間経過後に電磁スイッチ8が閉じて再び防食電
流の供給が開始されるようにタイマー9を設定して定電
位直流電源装置1の通電を開始した。防食電流と電位の
推移を図2のグラフに示す。通電開始直後の防食電流は
海水入口水室が40Aで、海水出口水室は14Aであっ
たが、その後両水室とも電流が次第に増加し、海水出口
水室が通電開始11日目に最大出力電流に達したために
防食電流の供給が一時間停止された。停止時の海水入口
水室の防食電流は142Aであった。通電再開直後の海
水出口水室は150Aに、海水入口水室は120Aにそ
れぞれ防食電流が減少した。また、2回目の電流供給停
止は23日目、3回目の電流供給停止は30日目であ
り、通電再開直後の防食電流は電流供給停止前よりも2
0Aから65A程度減少した。なお、試験期間中、海水
入口水室及び出口水室の電位は、ともに防食管理電位で
ある−600mVを維持していた。[Embodiment] The anticorrosion control potential of the seawater inlet and outlet water chambers was set to -600 mV, and the maximum output current was 3
When maintained for 0 minutes, the signal from the anticorrosion insufficient detection circuit 7 opens the electromagnetic switch 8 to stop the supply of the anticorrosion current, and after one hour, closes the electromagnetic switch 8 and restarts the supply of the anticorrosion current. The timer 9 was set and the energization of the constant potential DC power supply 1 was started. The change of the anticorrosion current and the potential is shown in the graph of FIG. The anticorrosion current immediately after the start of energization was 40 A for the seawater inlet water chamber and 14 A for the seawater outlet water chamber. Thereafter, the current gradually increased in both water chambers, and the maximum output of the seawater outlet water chamber was reached on the eleventh day after the start of energization. The supply of anticorrosion current was stopped for one hour because the current was reached. The anticorrosion current of the seawater inlet water chamber at the time of stoppage was 142A. The anticorrosion current in the seawater outlet water chamber was reduced to 150 A immediately after the resumption of power supply, and the corrosion protection current was reduced to 120 A in the seawater inlet water chamber. In addition, the second current supply stop is on the 23rd day, the third current supply is on the 30th day, and the anticorrosion current immediately after the current supply is resumed is 2 times smaller than before the current supply was stopped.
It decreased by about 65A from 0A. During the test period, the potential of the seawater inlet water chamber and the outlet water chamber both maintained the anticorrosion control potential of -600 mV.
【0016】〔従来例〕海水入口水室及び出口水室の防
食管理電位を−600mVに設定し、通常の定電位電気
防食を行った。防食電流と電位の推移を図3のグラフに
示す。通電開始直後の防食電流は海水入口水室が44A
で、海水出口水室は20Aであったが、その後両水室と
も電流が次第に増加し、海水入口水室が通電開始12日
目に最大出力電流に達し、その後両水室とも電位が次第
に貴に推移して15日目に海水入口水室の電位が防食管
理範囲の下限値である−450mVを外れて定電位直流
電源装置内蔵の「電位不足」警報が発令されたために通
電を停止した。[Conventional example] The anticorrosion control potential of the seawater inlet water chamber and outlet water chamber was set to -600 mV, and ordinary constant potential cathodic protection was performed. The change of the anticorrosion current and the potential is shown in the graph of FIG. The anticorrosion current immediately after the start of energization is 44 A for the seawater inlet water chamber.
Then, the seawater outlet water chamber was 20A, but then the current in both water chambers gradually increased, and the seawater inlet water chamber reached the maximum output current on the 12th day from the start of energization, and then the potential in both water chambers gradually became higher. On the 15th day, the potential of the seawater inlet water chamber deviated from -450 mV, which is the lower limit of the anticorrosion control range, and the "potential shortage" alarm built in the constant potential DC power supply was issued, and the power supply was stopped.
【0017】[0017]
【発明の効果】以上説明したように、この発明による定
電位外部電源方式による防食方法を使用すれば、電気防
食装置の容量を超えた防食電流が必要な状態となって
も、一時的に通電を停止し、その後通電を再開すること
により再び該電気防食装置の容量内で海水冷却水系統機
器の防食管理電位の維持が可能となるので、新たに大容
量の電気防食装置を設置する必要がなく、また、防食電
流が所定の設定値を超えた場合や防食電流が不足して防
食管理電位を外れた場合或いは防食電流通電開始から所
定時間経過ごとに通電を停止し、所定時間経過後に通電
を再開する回路を組み込んだ定電位直流電源装置を用い
れば、防食電流値や電位を監視することなくこの発明の
防食法を達成できるという優れた効果を奏する。As described above, if the anticorrosion method using the constant potential external power supply system according to the present invention is used, even if the anticorrosion current exceeds the capacity of the cathodic protection device, the current is temporarily supplied. And restarting the energization after that, it is possible to maintain the anticorrosion control potential of the seawater cooling water system equipment again within the capacity of the anticorrosion device, so it is necessary to newly install a large-capacity anticorrosion device. In addition, when the anticorrosion current exceeds a predetermined set value, when the anticorrosion current is insufficient and deviates from the anticorrosion control potential, or when the anticorrosion current is started, the energization is stopped every elapse of a predetermined time, and the energization is performed after the elapse of the predetermined time. The use of a constant-potential DC power supply device incorporating a circuit for resuming the process of the present invention has an excellent effect that the anticorrosion method of the present invention can be achieved without monitoring the anticorrosion current value and potential.
【図1】この発明の定電位外部電源方式電気防食装置の
概略構成図である。FIG. 1 is a schematic configuration diagram of a constant potential external power supply type anticorrosion device of the present invention.
【図2】この発明の定電位外部電源方式電気防食装置に
よりこの発明の防食方法を適用した場合の復水器の防食
電流と電位の推移を示したグラフである。FIG. 2 is a graph showing transition of the anticorrosion current and the potential of the condenser when the anticorrosion method of the present invention is applied by the constant potential external power supply type anticorrosion device of the present invention.
【図3】従来の定電位外部電源方式の電気防食装置によ
り復水器を防食した場合の防食電流と電位の推移を示し
たグラフである。FIG. 3 is a graph showing transition of anticorrosion current and potential when a condenser is anticorrosively protected by a conventional constant potential external power supply type anticorrosion device.
【図4】従来の復水器の構造を示す概略断面図である。FIG. 4 is a schematic sectional view showing the structure of a conventional condenser.
1 定電位直流電源装置 2 入力スイッチ 3 変圧器 4 整流体 5 コントローラ 6 シャント抵抗 7 防食不足検出回路 8 電磁スイッチ 9 タイマー 10 復水器 11 冷却管 12 管板 13 水室 14 電極 15 照合電極 16 ゴムライニング 17 鋼板 DESCRIPTION OF SYMBOLS 1 Constant potential DC power supply 2 Input switch 3 Transformer 4 Rectifier 5 Controller 6 Shunt resistor 7 Corrosion protection insufficient detection circuit 8 Electromagnetic switch 9 Timer 10 Condenser 11 Cooling pipe 12 Tube plate 13 Water chamber 14 Electrode 15 Reference electrode 16 Rubber Lining 17 Steel plate
Claims (8)
される海水冷却水系統機器を防食する定電位外部電源方
式による電気防食方法において、 防食電流通電開始から所定時間経過時に通電を停止し、
通電停止から所定時間経過後に防食電流の通電を再開す
る手順を繰り返すことを特徴とする定電位外部電源方式
による海水冷却水系統機器の電気防食方法。Claims: 1. An anticorrosion method using a constant-potential external power supply system for anticorrosion of a seawater cooling water system device composed of a plurality of dissimilar metals including a corrosion-resistant metal, comprising:
An electrolytic protection method for a seawater cooling water system device using a constant potential external power supply method, wherein a procedure for restarting the application of the anticorrosion current is repeated after a predetermined time has elapsed from the stop of energization.
される海水冷却水系統機器を防食する定電位外部電源方
式による電気防食方法において、 防食電流を通電し、防食電流が増加して定電位直流電源
装置の最大出力電流値以下の所定の電流値に達したとき
に通電を停止し、通電停止から所定時間経過後に防食電
流の通電を再開する手順を繰り返すことを特徴とする定
電位外部電源方式による海水冷却水系統機器の電気防食
方法。2. An anticorrosion method using a constant-potential external power supply method for anticorrosion of a seawater cooling water system device composed of a plurality of dissimilar metals including a corrosion-resistant metal. A constant-potential external power supply characterized by repeating the procedure of stopping energization when a predetermined current value equal to or less than the maximum output current value of the DC power supply device is reached and restarting energization of the anticorrosion current after a lapse of a predetermined time from the stoppage of energization. Corrosion protection method for seawater cooling water system equipment by the method.
される海水冷却水系統機器を防食する定電位外部電源方
式による電気防食方法において、 防食電流を通電し、防食電流が増加して定電位直流電源
装置の最大出力電流値に達したときに通電を停止し、通
電停止から所定時間経過後に防食電流の通電を再開する
手順を繰り返すことを特徴とする定電位外部電源方式に
よる海水冷却水系統機器の電気防食方法。3. An anticorrosion method using a constant-potential external power supply system for anticorrosion of a seawater cooling water system device composed of a plurality of dissimilar metals including a corrosion-resistant metal. A seawater cooling water system using a constant potential external power supply system, in which the power supply is stopped when the maximum output current value of the DC power supply device is reached, and the procedure for restarting the supply of the anticorrosive current is repeated after a lapse of a predetermined time from the stoppage of the power supply. The method of cathodic protection of equipment.
される海水冷却水系統機器を防食する定電位外部電源方
式による電気防食方法において、 防食電流を通電し、防食電流が増加して定電位直流電源
装置の最大出力電流値を越えることにより防食電流が不
足し、海水冷却水系統機器の電位が貴に移行して防食管
理電位を外れる前に通電を停止し、通電停止から所定時
間経過後に防食電流の通電を再開する手順を繰り返すこ
とを特徴とする定電位外部電源方式による海水冷却水系
統機器の電気防食方法。4. An anticorrosion method using a constant-potential external power supply system for anticorrosion of a seawater cooling water system device composed of a plurality of dissimilar metals including a corrosion-resistant metal. The anti-corrosion current is insufficient due to exceeding the maximum output current value of the DC power supply, the electric potential of the seawater cooling water system equipment is shifted to noble, and the energization is stopped before the anti-corrosion management potential is deviated, and after a predetermined time has elapsed from the stop of energization An electrolytic protection method for a seawater cooling water system device using a constant potential external power supply method, characterized by repeating a procedure for resuming the application of a corrosion prevention current.
圧器と、交流を直流に変換する整流器と防食対象物の防
食電位を一定に制御する電位制御回路とから構成される
定電位直流電源装置と海水冷却水系統機器に防食電流を
供給する電極装置と該海水冷却水系統機器の電位を計測
する照合電極装置とから基本的に構成される定電位外部
電源方式電気防食装置において、 該定電位直流電源装置に防食電流通電開始から所定時間
経過後に通電を停止する制御装置と通電停止から所定期
間経過時に通電を再開する制御装置とを備えたことを特
徴とする耐食性金属を含む複数の異種金属で構成される
海水冷却水系統機器の定電位外部電源方式電気防食装
置。5. A constant-potential DC power supply comprising a transformer for stepping down a commercial AC voltage to a predetermined voltage, a rectifier for converting AC to DC, and a potential control circuit for controlling the corrosion protection potential of an object to be protected to a constant value. A constant-potential external power supply type anticorrosion device basically comprising an electrode device for supplying an anticorrosion current to the device and the seawater cooling water system device, and a reference electrode device for measuring the potential of the seawater cooling water system device. A plurality of heterogeneous metals including a corrosion-resistant metal, comprising: a control device that stops energization after a lapse of a predetermined time from the start of the application of the anticorrosion current to the potential DC power supply device; A constant-potential external power type cathodic protection system for seawater cooling water system equipment made of metal.
圧器と、交流を直流に変換する整流器と防食対象物の防
食電位を一定に制御する電位制御回路とから構成される
定電位直流電源装置と海水冷却水系統機器に防食電流を
供給する電極装置と該海水冷却水系統機器の電位を計測
する照合電極装置とから基本的に構成される定電位外部
電源方式電気防食装置において、 該定電位直流電源装置に出力電流が増加して定電位直流
電源装置の最大出力電流値以下の所定の電流値に達した
時に通電を停止する制御装置と、通電停止から所定時間
経過後に通電を再開する制御装置とを備えたことを特徴
とする耐食性金属を含む複数の異種金属で構成される海
水冷却水系統機器の定電位外部電源方式電気防食装置。6. A constant-potential DC power supply comprising: a transformer for stepping down a commercial AC voltage to a predetermined voltage; a rectifier for converting AC to DC; and a potential control circuit for controlling the corrosion prevention potential of the anticorrosion target to be constant. A constant-potential external power supply type anticorrosion device basically comprising an electrode device for supplying an anticorrosion current to the device and the seawater cooling water system device, and a reference electrode device for measuring the potential of the seawater cooling water system device. A control device that stops energization when the output current of the potential DC power supply increases and reaches a predetermined current value equal to or less than the maximum output current value of the constant potential DC power supply, and restarts energization after a lapse of a predetermined time from the stop of energization A constant-potential external power supply type anticorrosion device for a seawater cooling water system device comprising a plurality of dissimilar metals including a corrosion-resistant metal, comprising a control device.
圧器と、交流を直流に変換する整流器と防食対象物の防
食電位を一定に制御する電位制御回路とから構成される
定電位直流電源装置と海水冷却水系統機器に防食電流を
供給する電極装置と該海水冷却水系統機器の電位を計測
する照合電極装置とから基本的に構成される定電位外部
電源方式電気防食装置において、 該定電位直流電源装置に出力電流が増加して定電位直流
電源装置の最大出力電流値に達した時に通電を停止する
制御装置と、通電停止から所定時間経過後に通電を再開
する制御装置とを備えたことを特徴とする耐食性金属を
含む複数の異種金属で構成される海水冷却水系統機器の
定電位外部電源方式電気防食装置。7. A constant potential DC power supply comprising a transformer for stepping down a commercial AC voltage to a predetermined voltage, a rectifier for converting AC to DC, and a potential control circuit for controlling the corrosion protection potential of the object to be protected to a constant value. A constant-potential external power supply type anticorrosion device basically comprising an electrode device for supplying an anticorrosion current to the device and the seawater cooling water system device, and a reference electrode device for measuring the potential of the seawater cooling water system device. A control device that stops energization when an output current of the potential DC power supply increases and reaches a maximum output current value of the constant potential DC power supply, and a control device that restarts energization after a predetermined time has elapsed from the stop of energization. A constant-potential external power type cathodic protection system for seawater cooling water system equipment comprising a plurality of dissimilar metals including corrosion-resistant metals.
圧器と、交流を直流に変換する整流器と防食対象物の防
食電位を一定に制御する電位制御回路とから構成される
定電位直流電源装置と海水冷却水系統機器に防食電流を
供給する電極装置と該海水冷却水系統機器の電位を計測
する照合電極装置とから基本的に構成される定電位外部
電源方式電気防食装置において、 該定電位直流電源装置の出力電流が増加して最大出力電
流値を越えて防食電流が不足し、海水冷却水系統機器の
電位が貴に移行して防食管理電位を外れる前に通電を停
止する制御装置と、通電停止から所定時間経過後に通電
を再開する制御装置とを備えたことを特徴とする耐食性
金属を含む複数の異種金属で構成される海水冷却水系統
機器の定電位外部電源方式電気防食装置。8. A constant potential DC power supply comprising a transformer for stepping down a commercial AC voltage to a predetermined voltage, a rectifier for converting AC to DC, and a potential control circuit for controlling the corrosion protection potential of an object to be protected to a constant value. A constant-potential external power supply type anticorrosion device basically comprising an electrode device for supplying an anticorrosion current to the device and the seawater cooling water system device, and a reference electrode device for measuring the potential of the seawater cooling water system device. A control device that stops the energization before the output current of the potential DC power supply increases and exceeds the maximum output current value and the anticorrosion current runs short, and the potential of the seawater cooling water system equipment shifts to noble and deviates from the anticorrosion management potential. And a control device that restarts energization after a lapse of a predetermined time from the stoppage of energization. A constant-potential external power-supply type cathodic protection device for seawater cooling water system equipment composed of a plurality of different metals including corrosion-resistant metals.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP24866597A JP3348633B2 (en) | 1997-09-12 | 1997-09-12 | Corrosion protection method and electrolytic protection device for seawater cooling water system equipment by constant potential external power supply system |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP24866597A JP3348633B2 (en) | 1997-09-12 | 1997-09-12 | Corrosion protection method and electrolytic protection device for seawater cooling water system equipment by constant potential external power supply system |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH1192980A true JPH1192980A (en) | 1999-04-06 |
JP3348633B2 JP3348633B2 (en) | 2002-11-20 |
Family
ID=17181527
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Application Number | Title | Priority Date | Filing Date |
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JP24866597A Expired - Fee Related JP3348633B2 (en) | 1997-09-12 | 1997-09-12 | Corrosion protection method and electrolytic protection device for seawater cooling water system equipment by constant potential external power supply system |
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Country | Link |
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JP (1) | JP3348633B2 (en) |
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1997
- 1997-09-12 JP JP24866597A patent/JP3348633B2/en not_active Expired - Fee Related
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JP3348633B2 (en) | 2002-11-20 |
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