JPH11506143A - 製品または書類の認証方法およびその認証用組成物 - Google Patents
製品または書類の認証方法およびその認証用組成物Info
- Publication number
- JPH11506143A JPH11506143A JP8536488A JP53648896A JPH11506143A JP H11506143 A JPH11506143 A JP H11506143A JP 8536488 A JP8536488 A JP 8536488A JP 53648896 A JP53648896 A JP 53648896A JP H11506143 A JPH11506143 A JP H11506143A
- Authority
- JP
- Japan
- Prior art keywords
- activator
- group
- branched
- alkyl group
- unbranched alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000012190 activator Substances 0.000 claims abstract description 81
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 19
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 claims abstract description 17
- 150000003931 anilides Chemical class 0.000 claims abstract description 11
- 150000001408 amides Chemical class 0.000 claims abstract description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000008859 change Effects 0.000 claims abstract description 7
- 230000004044 response Effects 0.000 claims abstract description 7
- 230000000694 effects Effects 0.000 claims abstract description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 48
- 125000003118 aryl group Chemical group 0.000 claims description 47
- 239000000975 dye Substances 0.000 claims description 43
- 238000007639 printing Methods 0.000 claims description 22
- 238000002844 melting Methods 0.000 claims description 9
- 230000008018 melting Effects 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 150000002989 phenols Chemical class 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- -1 amide phenols Chemical class 0.000 claims description 5
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 5
- 125000005027 hydroxyaryl group Chemical group 0.000 claims description 5
- 229940051881 anilide analgesics and antipyretics Drugs 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 3
- 230000008569 process Effects 0.000 abstract description 3
- 239000000758 substrate Substances 0.000 description 9
- 239000000976 ink Substances 0.000 description 7
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 5
- 238000002845 discoloration Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- YBPAYPRLUDCSEY-UHFFFAOYSA-N 2-(4-hydroxyphenyl)acetamide Chemical compound NC(=O)CC1=CC=C(O)C=C1 YBPAYPRLUDCSEY-UHFFFAOYSA-N 0.000 description 4
- QXSAKPUBHTZHKW-UHFFFAOYSA-N 4-hydroxybenzamide Chemical compound NC(=O)C1=CC=C(O)C=C1 QXSAKPUBHTZHKW-UHFFFAOYSA-N 0.000 description 4
- 239000013543 active substance Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 3
- WKEDVNSFRWHDNR-UHFFFAOYSA-N salicylanilide Chemical compound OC1=CC=CC=C1C(=O)NC1=CC=CC=C1 WKEDVNSFRWHDNR-UHFFFAOYSA-N 0.000 description 3
- JFGQHAHJWJBOPD-UHFFFAOYSA-N 3-hydroxy-n-phenylnaphthalene-2-carboxamide Chemical compound OC1=CC2=CC=CC=C2C=C1C(=O)NC1=CC=CC=C1 JFGQHAHJWJBOPD-UHFFFAOYSA-N 0.000 description 2
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229950000975 salicylanilide Drugs 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- SXSIHVNMXOMEDS-UHFFFAOYSA-N 1-(2-chlorophenyl)-n-methylpropan-2-amine Chemical compound CNC(C)CC1=CC=CC=C1Cl SXSIHVNMXOMEDS-UHFFFAOYSA-N 0.000 description 1
- ADVGKWPZRIDURE-UHFFFAOYSA-N 2'-Hydroxyacetanilide Chemical compound CC(=O)NC1=CC=CC=C1O ADVGKWPZRIDURE-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- MOZDKDIOPSPTBH-UHFFFAOYSA-N Benzyl parahydroxybenzoate Chemical compound C1=CC(O)=CC=C1C(=O)OCC1=CC=CC=C1 MOZDKDIOPSPTBH-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- NAXXKBKLAWQLAI-UHFFFAOYSA-N C(C)(=O)NC1=CC=C(C=C1)O.C(C)(=O)NC=1C=C(C=CC1)O.C(C)(=O)NC1=C(C=CC=C1)O Chemical compound C(C)(=O)NC1=CC=C(C=C1)O.C(C)(=O)NC=1C=C(C=CC1)O.C(C)(=O)NC1=C(C=CC=C1)O NAXXKBKLAWQLAI-UHFFFAOYSA-N 0.000 description 1
- IPAJDLMMTVZVPP-UHFFFAOYSA-N Crystal violet lactone Chemical compound C1=CC(N(C)C)=CC=C1C1(C=2C=CC(=CC=2)N(C)C)C2=CC=C(N(C)C)C=C2C(=O)O1 IPAJDLMMTVZVPP-UHFFFAOYSA-N 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- METKIMKYRPQLGS-UHFFFAOYSA-N atenolol Chemical compound CC(C)NCC(O)COC1=CC=C(CC(N)=O)C=C1 METKIMKYRPQLGS-UHFFFAOYSA-N 0.000 description 1
- 229940034794 benzylparaben Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 210000003813 thumb Anatomy 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- PZXFWBWBWODQCS-UHFFFAOYSA-L zinc;2-carboxyphenolate Chemical class [Zn+2].OC1=CC=CC=C1C([O-])=O.OC1=CC=CC=C1C([O-])=O PZXFWBWBWODQCS-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G21/00—Arrangements not provided for by groups G03G13/00 - G03G19/00, e.g. cleaning, elimination of residual charge
- G03G21/04—Preventing copies being made of an original
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
- B41M3/142—Security printing using chemical colour-formers or chemical reactions, e.g. leuco-dye/acid, photochromes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G21/00—Arrangements not provided for by groups G03G13/00 - G03G19/00, e.g. cleaning, elimination of residual charge
- G03G21/04—Preventing copies being made of an original
- G03G21/043—Preventing copies being made of an original by using an original which is not reproducible or only reproducible with a different appearence, e.g. originals with a photochromic layer or a colour background
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Color Printing (AREA)
- Credit Cards Or The Like (AREA)
- Inspection Of Paper Currency And Valuable Securities (AREA)
- Paper (AREA)
- Printing Methods (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/455,949 US5595590A (en) | 1995-05-31 | 1995-05-31 | Method and compositions for authenticating a product or document |
| US08/455,949 | 1995-05-31 | ||
| PCT/US1996/006405 WO1996038509A1 (en) | 1995-05-31 | 1996-05-07 | Method and compositions for authenticating a product or document |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11506143A true JPH11506143A (ja) | 1999-06-02 |
Family
ID=23810852
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8536488A Pending JPH11506143A (ja) | 1995-05-31 | 1996-05-07 | 製品または書類の認証方法およびその認証用組成物 |
Country Status (10)
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999014327A2 (en) * | 1997-09-17 | 1999-03-25 | Genentech, Inc. | Genes amplified in tumours, antibodies against the proteins coded thereby, and their use in diagnosis and treatment of cancer |
| US6232124B1 (en) | 1996-05-06 | 2001-05-15 | Verification Technologies, Inc. | Automated fingerprint methods and chemistry for product authentication and monitoring |
| US6240396B1 (en) | 1996-09-04 | 2001-05-29 | Priceline.Com Incorporated | Conditional purchase offer management system for event tickets |
| US5912205A (en) * | 1997-01-30 | 1999-06-15 | The Standard Register Company | Heat resistant security document |
| US6031021A (en) * | 1997-04-11 | 2000-02-29 | Ncr Corporation | Thermal transfer ribbon with thermal dye color palette |
| CN1050146C (zh) * | 1997-07-11 | 2000-03-08 | 南开大学戈德防伪技术公司 | 分子识别型固相防伪技术 |
| US6107932A (en) * | 1997-08-22 | 2000-08-22 | Walker Digital, Llc | System and method for controlling access to a venue using alterable tickets |
| GB2339784A (en) | 1998-07-21 | 2000-02-09 | Courtaulds Chemicals | Plastics film; identifying goods |
| US6490030B1 (en) | 1999-01-18 | 2002-12-03 | Verification Technologies, Inc. | Portable product authentication device |
| US7079230B1 (en) | 1999-07-16 | 2006-07-18 | Sun Chemical B.V. | Portable authentication device and method of authenticating products or product packaging |
| US6512580B1 (en) | 1999-10-27 | 2003-01-28 | Verification Technologies, Inc. | Method and apparatus for portable product authentication |
| US7486790B1 (en) | 2000-06-30 | 2009-02-03 | Verification Technologies, Inc. | Method and apparatus for controlling access to storage media |
| AU2001259033A1 (en) | 2000-06-30 | 2002-01-14 | Verification Technologies, Inc. | Copy-protected optical media and method of manufacture thereof |
| US6638593B2 (en) | 2000-06-30 | 2003-10-28 | Verification Technologies, Inc. | Copy-protected optical media and method of manufacture thereof |
| US7124944B2 (en) | 2000-06-30 | 2006-10-24 | Verification Technologies, Inc. | Product packaging including digital data |
| US7660415B2 (en) | 2000-08-03 | 2010-02-09 | Selinfreund Richard H | Method and apparatus for controlling access to storage media |
| US6783991B1 (en) | 2002-02-06 | 2004-08-31 | The Standard Register Company | Reversible and reusable authentication system for secure documents |
| CA2499742C (en) * | 2002-09-30 | 2011-08-02 | Polymeric Converting Llc | Color changing tape, label, card and game intermediates |
| US7147801B2 (en) * | 2003-03-13 | 2006-12-12 | Videojet Technologies Inc. | Ink jet ink composition and method for security marking |
| WO2004087430A1 (en) | 2003-04-02 | 2004-10-14 | Ucb, S.A. | Authentication means |
| US20050165131A1 (en) * | 2003-10-06 | 2005-07-28 | Terry Stovold | Invisible ink |
| US8053494B2 (en) * | 2003-10-06 | 2011-11-08 | Nocopi Technologies, Inc. | Invisible ink and scratch pad |
| US20050075420A1 (en) * | 2003-10-06 | 2005-04-07 | Terry Stovold | Invisible ink |
| US7163909B2 (en) * | 2004-04-23 | 2007-01-16 | Appleton Papers Inc. | Authenticity indicator |
| US7087265B1 (en) | 2005-02-10 | 2006-08-08 | Netsch Bryan A | Image developing device |
| US8330122B2 (en) | 2007-11-30 | 2012-12-11 | Honeywell International Inc | Authenticatable mark, systems for preparing and authenticating the mark |
| US8822374B2 (en) | 2012-01-06 | 2014-09-02 | Nocopi Technologies, Inc. | Color-changing marking implement and substrate |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE627436A (enrdf_load_stackoverflow) * | 1962-01-24 | |||
| US4012554A (en) * | 1972-12-15 | 1977-03-15 | Ncr Corporation | Single coating record system-solvent loss produces color |
| US4180405A (en) * | 1977-02-25 | 1979-12-25 | Graphic Controls Corporation | Heat-sensitive recording composition with mixed color precursors |
| JPS57116695A (en) * | 1981-01-14 | 1982-07-20 | Ricoh Co Ltd | Thermal recording material |
| JPS59140096A (ja) * | 1982-12-30 | 1984-08-11 | Ricoh Co Ltd | 感熱記録材料 |
| JPS59124885A (ja) * | 1982-12-30 | 1984-07-19 | Ricoh Co Ltd | 感熱記録材料 |
| JPH0673993B2 (ja) * | 1984-03-12 | 1994-09-21 | 株式会社リコー | 感熱記録材料 |
| US4939117A (en) * | 1988-01-08 | 1990-07-03 | Ricoh Company, Ltd. | Leuco dyes and recording material employing the same |
| KR0139923B1 (ko) * | 1989-04-07 | 1998-07-01 | 스즈끼 가즈오 | 가역성 감열 기록매체용 조성물 |
| CA2023112C (en) * | 1989-08-11 | 2000-09-26 | Jun Yamaguchi | Light- and heat-sensitive recording material |
| DE4110354A1 (de) * | 1990-03-30 | 1991-10-02 | Kanzaki Paper Mfg Co Ltd | Farbentwickler-zusammensetzung, verfahren zur herstellung einer waessrigen dispersion derselben und durckempfindliches durchschreibmaterial |
| JPH0688071A (ja) * | 1992-09-08 | 1994-03-29 | Sakura Color Prod Corp | 熱変色性組成物 |
| JP3453741B2 (ja) * | 1993-07-08 | 2003-10-06 | 日本製紙株式会社 | 感熱記録体 |
| US5485792A (en) * | 1995-07-07 | 1996-01-23 | Western Publishing Co., Inc. | Latent image development system |
-
1995
- 1995-05-31 US US08/455,949 patent/US5595590A/en not_active Expired - Lifetime
-
1996
- 1996-05-07 ES ES96913952T patent/ES2160244T3/es not_active Expired - Lifetime
- 1996-05-07 CA CA002218635A patent/CA2218635A1/en not_active Abandoned
- 1996-05-07 WO PCT/US1996/006405 patent/WO1996038509A1/en active IP Right Grant
- 1996-05-07 DE DE69614380T patent/DE69614380T2/de not_active Expired - Fee Related
- 1996-05-07 AU AU56767/96A patent/AU5676796A/en not_active Abandoned
- 1996-05-07 EP EP96913952A patent/EP0828799B1/en not_active Expired - Lifetime
- 1996-05-07 AT AT96913952T patent/ATE204010T1/de not_active IP Right Cessation
- 1996-05-07 JP JP8536488A patent/JPH11506143A/ja active Pending
- 1996-09-27 US US08/722,329 patent/US5786509A/en not_active Expired - Fee Related
-
1998
- 1998-01-27 US US09/013,998 patent/US6114281A/en not_active Expired - Fee Related
-
2001
- 2001-09-17 GR GR20010401486T patent/GR3036628T3/el not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US5595590A (en) | 1997-01-21 |
| EP0828799B1 (en) | 2001-08-08 |
| ATE204010T1 (de) | 2001-08-15 |
| ES2160244T3 (es) | 2001-11-01 |
| GR3036628T3 (en) | 2001-12-31 |
| EP0828799A1 (en) | 1998-03-18 |
| US6114281A (en) | 2000-09-05 |
| DE69614380T2 (de) | 2002-05-29 |
| US5786509A (en) | 1998-07-28 |
| DE69614380D1 (de) | 2001-09-13 |
| AU5676796A (en) | 1996-12-18 |
| EP0828799A4 (enrdf_load_stackoverflow) | 1998-04-29 |
| WO1996038509A1 (en) | 1996-12-05 |
| CA2218635A1 (en) | 1996-12-05 |
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