JPH11505026A - ガス連続分光分析用マイクロ波空洞共振器 - Google Patents
ガス連続分光分析用マイクロ波空洞共振器Info
- Publication number
- JPH11505026A JPH11505026A JP9527266A JP52726697A JPH11505026A JP H11505026 A JPH11505026 A JP H11505026A JP 9527266 A JP9527266 A JP 9527266A JP 52726697 A JP52726697 A JP 52726697A JP H11505026 A JPH11505026 A JP H11505026A
- Authority
- JP
- Japan
- Prior art keywords
- resonator
- microwave
- cavity
- waveguide
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004611 spectroscopical analysis Methods 0.000 title claims description 7
- 238000005259 measurement Methods 0.000 claims abstract description 27
- 230000008878 coupling Effects 0.000 claims description 21
- 238000010168 coupling process Methods 0.000 claims description 21
- 238000005859 coupling reaction Methods 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 18
- 230000008569 process Effects 0.000 claims description 17
- 239000004020 conductor Substances 0.000 claims description 10
- 238000010521 absorption reaction Methods 0.000 claims description 9
- 230000000694 effects Effects 0.000 claims description 7
- 238000004458 analytical method Methods 0.000 claims description 2
- 230000005284 excitation Effects 0.000 claims description 2
- 230000007704 transition Effects 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 16
- 229910021529 ammonia Inorganic materials 0.000 abstract description 8
- 238000001514 detection method Methods 0.000 abstract description 5
- 230000035945 sensitivity Effects 0.000 abstract description 5
- 230000004044 response Effects 0.000 abstract description 3
- 239000007789 gas Substances 0.000 description 40
- 238000005516 engineering process Methods 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 239000004809 Teflon Substances 0.000 description 3
- 229920006362 Teflon® Polymers 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000003546 flue gas Substances 0.000 description 3
- 238000005192 partition Methods 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- 230000005699 Stark effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 229920003223 poly(pyromellitimide-1,4-diphenyl ether) Polymers 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005672 electromagnetic field Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002094 microwave spectroscopy Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N22/00—Investigating or analysing materials by the use of microwaves or radio waves, i.e. electromagnetic waves with a wavelength of one millimetre or more
- G01N22/005—Investigating or analysing materials by the use of microwaves or radio waves, i.e. electromagnetic waves with a wavelength of one millimetre or more and using Stark effect modulation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01P—WAVEGUIDES; RESONATORS, LINES, OR OTHER DEVICES OF THE WAVEGUIDE TYPE
- H01P7/00—Resonators of the waveguide type
- H01P7/04—Coaxial resonators
Landscapes
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
- Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. プロセス媒体流の中のある特定成分の濃度検出用のガス連続分光分析用マイ クロ波空洞共振器において、 共振器(1)が、マイクロ波リフレクタ(4,5)により制限されている空 洞円筒体であり、前記空洞円筒体は円形空洞導波管部分(2)と同軸導波管部分 (3)とから成り、前記円筒形空洞導波管部分(2)と前記同軸導波管部分(3 )とを互いにガス密かつ圧力密の誘電ウィンドウ(7)を介して分離し、前記同 軸導波管部分(3)の軸線方向にスライド可能な内部導体(6)をStark変 調を適用するための電極として用い、マイクロ波リフレクタ(5)の中で貫通案 内して保持し、 2つの空洞導波管(11)すなわち共振器(1)の中へのマイクロ波入力結 合のための一方の空洞導波管(11)と前記共振器(1)からのマイクロ波出力 結合のための前記空洞導波管(11)とを、前記共振器(1)の軸線に対称に前 記共振器に前記円形空洞導波管部分(2)の領域内でフランジ接続し、 前記マイクロ波リフレクタ(4,5)のうちの一方を固定配置し、他方を、 予定の最大吸収周波 数とマイクロ波の最適な入力結合及び出力結合への調整への同調のために軸線方 向にスライド可能にし、 前記プロセス媒体流から連続的に、分岐されている部分がガス状で貫流する バイパス導管(21)が、直接的に前記同軸導波管部分(3)の側を前記誘電ウ ィンドウ(7)の領域内で通過し、その場所で共振器壁の中の絞りすなわち制限 装置(9)を介して前記同軸導波管部分(3)への短い長さの分岐を有し、これ により連続的で小さい体積での試料導入が可能となり、前記導入試料を連続的に 、所与の圧力勾配を維持してその場所の前記マイクロ波リフレクタ(5)の中の 少なくとも1つの開口を介してポンピングして吸込むことが可能であり、 前記共振器(1)のQが1000〜2000の間の値をとることを特徴とす るガス連続分光分析用マイクロ波空洞共振器。 2. 共振器(1)が、機械的安定性のために及び大きな熱容量を形成するために 肉厚な構造を有していることを特徴とする請求項1に記載のマイクロ波空洞共振 器。 3. 企図するモードの励起が空洞円筒形共振器体の内半径を定めるようにするか 又は内半径を過大寸法に定めることを特徴とする請求項2に記載のマ イクロ波空洞共振器。 4. 同軸導波管部分(3)の中のマイクロ波リフレクタ(5)を定置に配置し、 前記マイクロ波リフレクタ(5)がモードフィルタとして作用し、Stark電 極(6)を導入する導入部材として用いられ、導入した測定ガスを前記同軸導波 管部分(5)を貫通して広面積で吸込み可能に構成し、 円形空洞導波管部分(2)の中のマイクロ波リフレクタ(4)を、前記円形 空洞導波管部分(2)がλ/4変換器として作用し、マイクロ波サンプとして用 いられる薄肉誘電空洞円筒(22)を介して共振器壁から導電的に分離されてい るように構成することを特徴とする請求項3に記載のマイクロ波空洞共振器。 5. Stark電極(6)の自由端が尖端(23)を有し、これにより双方の導 波管領域(2,3)の間の移行がマイクロ波技術的に滑らかに生ずるようにする ことが可能であり、前記Stark電極(6)を、共振器(1)の中のガス流及 びマイクロ波に影響しないか最大でも無視できる程度にしか影響しない誘電星状 体(10)を介して同軸に保持することを特徴とする請求項4に記載のマイクロ 波空洞共振器。 6. 絞りすなわち制限装置(9)が交換可能であり、前記絞り(9)の通気突出 部分がバイパス導管 (21)の横断面領域内に突出していることを特徴とする請求項5に記載のマイ クロ波空洞共振器。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19603905.3 | 1996-02-03 | ||
DE19603905A DE19603905C1 (de) | 1996-02-03 | 1996-02-03 | Mikrowellenhohlraumresonator für die kontinuierliche, spektroskopische Gasanalyse |
PCT/EP1997/000175 WO1997028440A1 (de) | 1996-02-03 | 1997-01-16 | Mikrowellenhohlraumresonator für die kontinuierliche, spektroskopische gasanalyse |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH11505026A true JPH11505026A (ja) | 1999-05-11 |
JP3187061B2 JP3187061B2 (ja) | 2001-07-11 |
Family
ID=7784427
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP52726697A Expired - Lifetime JP3187061B2 (ja) | 1996-02-03 | 1997-01-16 | ガス連続分光分析用マイクロ波空洞共振器 |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0877929B1 (ja) |
JP (1) | JP3187061B2 (ja) |
AT (1) | ATE217082T1 (ja) |
DE (2) | DE19603905C1 (ja) |
WO (1) | WO1997028440A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005172779A (ja) * | 2003-12-10 | 2005-06-30 | Semiconductor Res Found | 電磁波を照射してバクテリア、ウィルスおよび毒性物質を測定する方法および装置 |
JP2009075134A (ja) * | 2009-01-05 | 2009-04-09 | Junichi Nishizawa | 細菌又は毒性物質の同定装置 |
WO2023095524A1 (ja) * | 2021-11-23 | 2023-06-01 | Emラボ株式会社 | 開放形共振器およびそれを用いた誘電特性の測定方法 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19723462A1 (de) * | 1997-06-05 | 1998-12-10 | Thomas Dr Bluemchen | Mikrowellengassensor und Verfahren der Mikrowellenspektroskopie |
WO2014029663A1 (en) * | 2012-08-20 | 2014-02-27 | Sony Corporation | Gas analysis apparatus and method |
RU2762058C1 (ru) * | 2021-02-17 | 2021-12-15 | Федеральное государственное бюджетное учреждение науки Институт проблем управления им. В.А. Трапезникова Российской академии наук | Устройство для измерения физических свойств диэлектрической жидкости |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5544904B2 (ja) * | 1973-09-05 | 1980-11-14 | ||
DE3645240C2 (en) * | 1986-07-09 | 1993-08-12 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe, De | Analysis of gaseous media using microwaves |
DE3723606A1 (de) * | 1987-07-17 | 1989-01-26 | Kernforschungsz Karlsruhe | Verfahren und vorrichtung zur analyse mittels mikrowellen |
-
1996
- 1996-02-03 DE DE19603905A patent/DE19603905C1/de not_active Expired - Lifetime
-
1997
- 1997-01-16 DE DE59707157T patent/DE59707157D1/de not_active Expired - Fee Related
- 1997-01-16 EP EP97901535A patent/EP0877929B1/de not_active Expired - Lifetime
- 1997-01-16 JP JP52726697A patent/JP3187061B2/ja not_active Expired - Lifetime
- 1997-01-16 WO PCT/EP1997/000175 patent/WO1997028440A1/de active IP Right Grant
- 1997-01-16 AT AT97901535T patent/ATE217082T1/de active
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005172779A (ja) * | 2003-12-10 | 2005-06-30 | Semiconductor Res Found | 電磁波を照射してバクテリア、ウィルスおよび毒性物質を測定する方法および装置 |
JP2009075134A (ja) * | 2009-01-05 | 2009-04-09 | Junichi Nishizawa | 細菌又は毒性物質の同定装置 |
WO2023095524A1 (ja) * | 2021-11-23 | 2023-06-01 | Emラボ株式会社 | 開放形共振器およびそれを用いた誘電特性の測定方法 |
Also Published As
Publication number | Publication date |
---|---|
ATE217082T1 (de) | 2002-05-15 |
EP0877929B1 (de) | 2002-05-02 |
WO1997028440A1 (de) | 1997-08-07 |
JP3187061B2 (ja) | 2001-07-11 |
EP0877929A1 (de) | 1998-11-18 |
DE19603905C1 (de) | 1997-03-20 |
DE59707157D1 (de) | 2002-06-06 |
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