JPH11266835A - Processed raw meat - Google Patents

Processed raw meat

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Publication number
JPH11266835A
JPH11266835A JP10075170A JP7517098A JPH11266835A JP H11266835 A JPH11266835 A JP H11266835A JP 10075170 A JP10075170 A JP 10075170A JP 7517098 A JP7517098 A JP 7517098A JP H11266835 A JPH11266835 A JP H11266835A
Authority
JP
Japan
Prior art keywords
starch
meat
fats
oil
oils
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP10075170A
Other languages
Japanese (ja)
Other versions
JP3958858B2 (en
Inventor
Sukeaki Satsuba
祐昭 札場
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Matsutani Chemical Industries Co Ltd
Original Assignee
Matsutani Chemical Industries Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsutani Chemical Industries Co Ltd filed Critical Matsutani Chemical Industries Co Ltd
Priority to JP07517098A priority Critical patent/JP3958858B2/en
Publication of JPH11266835A publication Critical patent/JPH11266835A/en
Application granted granted Critical
Publication of JP3958858B2 publication Critical patent/JP3958858B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To produce a processed raw meat good in yield in heat cooking and excellent in palatability of the meat and taste derived from oils and fats by adding a liquid mixture containing starch having average particle size equal to or smaller than a predetermined value and a gelation-initiating temperature in a predetermined range and pseudo-emulsified oils and fats. SOLUTION: This raw meat is obtained by adding a liquid mixture containing preferably 0.2-10 wt.% (based on the solid component to the raw meat) of starch such as nonglutinous rice starch, processed starch, etc., having a >=20 μm average particle size and a 40-70 deg.C gelation-initiating temperature, and preferably 0.5-25 wt.% of pseudo-emulsified oils and fats such as solid fat, etc.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、加熱調理後の食感と風
味が良好で加熱調理での歩留に優れる生肉に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to raw meat having good texture and flavor after cooking and excellent yield in cooking.

【0002】[0002]

【従来の技術】食品の内でも肉類,特に生肉は細菌や微
生物の増殖があるため、チルド(冷蔵)や冷凍で流通さ
れており、生肉をそのまま食する場合もあるが大部分は
加熱調理して食するのが一般的である。しかし肉類を加
熱調理すると、肉にパサツキがみられたり、肉が硬くな
って食感が悪くなる、或は加熱によって肉の歩留が低下
するなどの問題がしばしば見られた。肉類の中でも、黒
毛和牛のような肉用種をグレインフエッドで肥育した牛
より得られた肉のように、肉質そのものが非常に軟らか
くて加熱調理しても加熱調理後の肉の食感及び風味が極
めて良好なものもあるが、それだけ価格も非常に高くな
るという問題があった。一方、より安価な肉として、老
廃家畜、経産家畜、ホルスタイン種などの乳肉種より得
られる牛肉などでは肉質そのものが非常に硬くて加熱調
理によってさらに食感が悪くなるなどの問題があった。
また、脂身の少ない肉では加熱調理後の風味に乏しいも
のであった。
2. Description of the Related Art Among foods, meat, especially raw meat, is distributed by chilling (refrigeration) or freezing because of proliferation of bacteria and microorganisms. In some cases, raw meat is eaten as it is, but most of it is cooked by heating. It is common to eat. However, when the meat was cooked with heat, there were often problems such as pastsuki on the meat, hardening of the meat to deteriorate the texture, and reduction in the yield of the meat due to heating. Among meats, meat quality itself is very soft, such as meat obtained from cows fattened with grain hues such as Japanese black beef, and the texture and flavor of the meat after cooking even after cooking. Some were very good, but the price was very high. On the other hand, inexpensive meat, such as aged livestock, multiparous livestock, and beef obtained from dairy meat species such as Holstein breed, has a problem that the meat itself is very hard and the cooking texture is further deteriorated by cooking.
In addition, meat having less fat was poor in flavor after cooking.

【0003】食肉の食感などを改善する試みとして、有
機酸モノグリセライド(例:アセチル化モノグリセライ
ド)を使用する方法、レシチンなどの界面活性剤を使用
する方法(特開昭54−62353号)、酵素を使用す
る方法(特開平4−278063号、特開平5−747
6号、特開平5−252911号)、塩類等を使用する
方法(特開昭58−23767号、特開平4−3616
7号)などが知られており、肉を柔らかくするなどの食
感改善はある程度はみられるけれども風味の点では物足
りないものであった。
[0003] As attempts to improve the texture of meat, for example, a method using an organic acid monoglyceride (eg, acetylated monoglyceride), a method using a surfactant such as lecithin (JP-A-54-62353), an enzyme (JP-A-4-278063, JP-A-5-747)
No. 6, JP-A-5-252911), a method using salts and the like (JP-A-58-23767, JP-A-4-3616).
No. 7), etc., and although the texture was improved to some extent by softening the meat, the flavor was unsatisfactory.

【0004】従来ソーセージなどの肉練り製品の保水性
や食感の改善に関して、澱粉や大豆蛋白などの蛋白が使
用されているが、肉はブロック状でなく、ミンチ状にな
って存在するために肉片としての食感をそれほど問題と
しなくてよかった。ハムなどのブロック状の肉に対して
は、一般に蛋白質はピックル液の一部として使用され、
加熱調理後の肉の歩留り向上などに寄与するが、加熱調
理後の肉の食感が硬くなるなどの問題がみられる。一
方、澱粉はピックル液の一部として使用すると沈澱しや
すいなどの問題があってあまり使用されていなかった。
これに対して、特開平9−140352号では澱粉をエ
ステル化、エーテル化、酸化、架橋などを単独または組
み合わせた加工澱粉(膨潤度2.0以上5.0以下で糊化開
始温度60℃以上、77℃以下)と糊料(例:グアーガ
ムなどの天然多糖類やアルギン酸ソーダなどの合成高分
子)を含有するピックル液を用いてハムなどの食肉加工
品に使用している。ピックル液を使用すると、糊料によ
ってピックル液中の加工澱粉の分散性が改善され、ハム
などの食肉製品の容積が大きくなり、肉に近い自然な食
感になるとされているが、糊料の溶解や分散時にダマが
発生したり、食感を硬めにするものであり、風味も良好
としているが油脂のもたらすような風味とは異なる。
Conventionally, proteins such as starch and soybean protein have been used to improve the water retention and texture of meat paste products such as sausage. However, meat is not a block but a minced meat. I didn't care about the texture as much. For blocky meat such as ham, protein is generally used as part of the pickle solution,
Although this contributes to improving the yield of meat after cooking, there are problems such as the texture of the meat becoming hard after cooking. On the other hand, starch has not been used much due to problems such as easy precipitation when used as part of a pickle solution.
On the other hand, Japanese Patent Application Laid-Open No. Hei 9-140352 discloses a modified starch obtained by subjecting starch to esterification, etherification, oxidation, cross-linking or the like alone or in combination (with a swelling degree of 2.0 or more and 5.0 or less and a gelatinization start temperature of 60 ° C or more). , 77 ° C or lower) and a paste (eg, a natural polysaccharide such as guar gum or a synthetic polymer such as sodium alginate) are used in processed meat products such as ham using a pickle liquid. The use of pickle liquid is said to improve the dispersibility of the processed starch in the pickle liquid by the paste, increase the volume of meat products such as ham, and provide a natural texture close to meat. Lum is generated during dissolution or dispersion, and the texture is hardened. The flavor is also good, but is different from the flavor brought by fats and oils.

【0005】黒毛和牛の肉のような高級品とされている
肉では、脂身が多く肉質のみならず、共存する油脂が風
味をひき立たさせていることから、脂身の少ない食肉を
柔らかくしたり、食感、風味を改良する方法として、食
肉中に油脂を添加しようとする試みがなされている。イ
ンジェクション法などによって油脂のみを肉に添加する
場合、常温で液状の液状油ではそのまま添加できるが肉
中に油脂を残存させることが難しく、常温で固体状の固
形脂では加熱溶融して液状にして初めて添加が可能にな
るが、固形脂では添加温度を高く保持しておかないと肉
への添加ができず、添加温度を高くすると食肉温度が上
昇して細菌が増殖しやすく、肉の鮮度が下がるという問
題がみられた。
[0005] Meats such as Japanese black beef meat, which is considered to be of high quality, has a large amount of fat and not only meat quality, but also coexisting oils and fats enhance the flavor. As a method for improving texture and flavor, attempts have been made to add fats and oils to meat. When adding only fats and oils to meat by injection method etc., it can be added as it is in liquid oil which is liquid at normal temperature, but it is difficult to leave fats and oils in meat, and solid fat at room temperature is heated and melted to liquid state Addition is possible for the first time, but solid fat cannot be added to meat unless the addition temperature is kept high.If the addition temperature is increased, the meat temperature rises, bacteria grow easily, and the freshness of the meat increases. The problem of falling was seen.

【0006】また、油脂を単なる油脂としてでなく、乳
化してから肉に添加する試みもなされている。しかし、
ポリグリセリン縮合リシノレイン酸エステルを用いて食
用油脂を油中水滴型乳化液にして肉に添加する方法(特
開平4−197157号)では、油脂が油中水滴型であ
るため、水溶性の呈味物質、調味料、香料などは内相部
に添加され、それらの物質が油相で覆われる結果、水溶
性物質による風味の強化が期待できないなどの問題があ
る。このため、通常は油中水滴型乳化液ではなく、水中
油滴型の乳化液として使用されている。
Attempts have also been made to add fats and oils to meat after emulsification, not just fats and oils. But,
According to the method in which an edible oil / fat is converted into a water-in-oil type emulsion by using polyglycerin condensed ricinoleate and added to meat (Japanese Patent Laid-Open No. 4-197157), the water-soluble taste is obtained because the oil / fat is water-in-oil type. Substances, seasonings, fragrances, and the like are added to the internal phase, and these substances are covered with the oil phase. As a result, there is a problem in that flavor enhancement by water-soluble substances cannot be expected. For this reason, it is usually used not as a water-in-oil type emulsion but as an oil-in-water type emulsion.

【0007】水中油滴型の乳化液でも、常温で固体の脂
肪(好ましくは牛脂)を溶融後乳化剤を添加して乳化し
た乳化液を食肉に注入する方法(特開昭58−8916
1号)や蛋白質(例:卵白)を用い脂肪の固化温度より
高く、蛋白質の熱変性温度より低い温度で乳化した液を
食肉に注入する方法(特開昭59−162853号)な
どでは、低温での乳化液の安定性が悪く、注入時の乳化
液の温度を高くする必要があり、生肉に不必要な熱を与
え、肉の品質上、及び微生物衛生上好ましくないもので
あり、調理加熱時の油脂などの流出が多いものであっ
た。
[0007] Even in the case of an oil-in-water type emulsion, a method in which a solid fat (preferably beef tallow) is melted at room temperature, and an emulsifier is added to the emulsion to inject the emulsion into meat (Japanese Patent Laid-Open No. 58-8916).
No. 1) or a method of injecting a liquid emulsified with protein (eg, egg white) at a temperature higher than the solidification temperature of fat and lower than the heat denaturation temperature of protein (Japanese Patent Laid-Open No. 59-162853). Stability of the emulsion at the time of injection, it is necessary to raise the temperature of the emulsion at the time of injection, giving unnecessary heat to raw meat, undesirable in terms of meat quality and microbial hygiene, There was much outflow of oils and fats at the time.

【0008】水中油滴型の乳化液の安定性を改善し、低
温で食肉に注入することを可能にしたものとして、水と
油脂にキトサン(乳化力を有す)を添加して乳化したエ
マルジョンを使用する方法(特開平2−227053
号)、蛋白質(例:ホエー蛋白質や卵白)の熱変性温度
より高い温度で加熱し、脂肪を乳化したエマルジョンを
食肉に注入する方法(特開平3−7544号)、血漿蛋
白質を用いて乳化した食用油脂を使用する方法(特開平
4−320662号)、食用油脂、好ましくは豚脂、牛
脂からなる油脂組成物にアルギン酸ソーダ、塩類、天然
多糖類(例:アラビアガム、グアーガムやローカストビ
ーンガム等)からなる水相部を添加して得られるO/W
型乳化組成物を使用する方法(特開平6−62376
号)などが例示され、調理加熱時でも乳化油脂に乳化破
壊をおこさない、或はおこしにくくすることで油脂など
が食肉からドリップするのを防止し、肉にソフト感やジ
ューシー感を与えるとされているが、油脂由来の風味の
発現についてはものたりないものであった。
An emulsion obtained by adding chitosan (having an emulsifying power) to water and fats and oils to improve the stability of an oil-in-water type emulsion and make it possible to inject meat into meat at a low temperature. (Japanese Unexamined Patent Publication No. 2-227053)
No. 3), a method of heating the protein (eg, whey protein or egg white) at a temperature higher than the thermal denaturation temperature and injecting an emulsion in which fat is emulsified into meat (JP-A-3-7544), emulsification using plasma protein A method using edible oils and fats (Japanese Patent Application Laid-Open No. 4-320662), edible oils and fats, preferably sodium alginate, salts, natural polysaccharides (eg, gum arabic, guar gum, locust bean gum, etc.) O / W obtained by adding an aqueous phase portion comprising
Using a liquid emulsion composition (JP-A-6-62376)
No.) and the like. It is said that emulsified oils and fats do not cause emulsification destruction even during cooking and heating, or prevent oils and fats from dripping from meat to give a soft and juicy feeling to meat. However, the expression of the flavor derived from fats and oils was unsatisfactory.

【0009】また、水中油滴型の乳化液と蛋白分解酵素
の併用が、ジューシー感や食感(柔らかさ)の改善効果
が大きいとして、食用油脂とキウイフルーツの抽出部か
らなる乳化物を食肉に添加する方法(特開平5−103
633号、特開平8−173096号)なども開示さ
れ、特に特開平8−173096号では乳化剤にポリグ
リセリン脂肪酸エステルを使用して乳化を極めて安定に
し、より低温でも乳化液を肉に添加することを可能にす
るなどの改良がなされている。しかし、調理加熱時の油
脂由来の風味の発現は必ずしも良好なものとはいえな
い。
On the other hand, it is considered that the combined use of an oil-in-water type emulsion and a proteolytic enzyme has a large effect of improving juicy feeling and texture (softness). (Japanese Patent Laid-Open No. 5-103)
No. 633, JP-A-8-173096) and the like. In particular, JP-A-8-173096 discloses that a polyglycerin fatty acid ester is used as an emulsifier to make the emulsification extremely stable, and that the emulsion is added to the meat even at a lower temperature. Improvements have been made, such as enabling However, the expression of flavor derived from fats and oils during cooking and heating is not always satisfactory.

【0010】加熱調理後の肉の食感を改善することに関
して、本発明者はDE4以下のデキストリンのようなゲ
ル形成性澱粉加水分解物とDE7〜45の澱粉分解物の
ようにゲル非形成性糖質を含む水溶液を生肉に添加した
加工生肉(特開平9−348401号)、糊化開始温度
が70℃以下の澱粉とDE4以下のデキストリンを含む
混合液を生肉に添加した加工生肉(特願平8−2604
96号)を提案し、加熱調理後の肉の食感を改善し、加
熱調理における肉の歩留を改善したが、加熱調理後の肉
における油脂がもたらす風味についてさらに検討の余地
があった。
With respect to improving the texture of meat after cooking, the present inventors have found that gel-forming starch hydrolysates such as dextrins of DE4 or less and non-gel-forming starches such as starch hydrolysates of DE 7-45. Processed raw meat obtained by adding an aqueous solution containing a saccharide to raw meat (Japanese Patent Application Laid-Open No. 9-348401), and processed raw meat obtained by adding a mixture containing starch having a gelatinization start temperature of 70 ° C. or less and dextrin of DE4 or less to raw meat (Japanese Patent Application Hei 8-2604
No. 96) was proposed to improve the texture of meat after cooking and to improve the yield of meat in cooking, but there was room for further study on the flavor brought by fats and oils in the meat after cooking.

【0011】[0011]

【発明が解決しようとする課題】本発明の目的は、加熱
調理での歩留がよく、加熱調理後の肉の食感と油脂由来
の風味に優れた生肉を提供することである。
SUMMARY OF THE INVENTION It is an object of the present invention to provide raw meat which has a good yield in cooking by heating, and has an excellent meat texture and a flavor derived from fats and oils after cooking.

【0012】[0012]

【課題を解決するための手段】本発明者等は上記の課題
を解決すべく鋭意努力の結果、平均粒径20μm以下
で、且つ糊化開始温度が70℃以下の澱粉と疑似乳化状
の油脂を含む混合液を用いて生肉を処理することにより
上記課題が解決されることを見出し本発明を完成させ
た。本発明は、平均粒径20μm以下で、且つ糊化開始
温度が40〜70℃の澱粉と疑似乳化状の油脂を含む混
合液を生肉に添加してなる加工生肉である。混合液に
は、平均粒径20μm以下で、且つ糊化開始温度が40
〜70℃の澱粉を0.1〜50重量%、疑似乳化状の油脂
を10〜60重量%含有させるのが好ましく、生肉に対
する混合液の添加量を5〜100重量%程度とするのが
好ましい。生肉に対する添加量(固形分)として、平均
粒径20μm以下で、且つ糊化温度が40〜70℃の澱
粉0.2〜10重量%、疑似乳化状の油脂0.5〜25重量
%が好ましい本発明に使用する澱粉は平均粒径20μm
以下で且つ糊化開始温度40〜70℃の未糊化の澱粉
で、好ましくは糯米澱粉及び/又はその加工澱粉であ
る。疑似乳化状の油脂としては、可食性の液状油や固形
脂を用いるが、より好ましくは固形脂である。また、混
合液の生肉への添加法としてはインジェクション法が挙
げられる。
Means for Solving the Problems The present inventors have made intensive efforts to solve the above-mentioned problems, and as a result, starch and pseudo-emulsified oils and fats having an average particle size of 20 μm or less and a gelatinization start temperature of 70 ° C. or less. It has been found that the above problems can be solved by treating raw meat using a mixed solution containing the present invention, and thus the present invention has been completed. The present invention is a processed raw meat obtained by adding a mixed liquid containing starch having a mean particle size of 20 μm or less and a gelatinization start temperature of 40 to 70 ° C. and a pseudo-emulsified fat to the raw meat. The mixture has an average particle size of 20 μm or less and a gelatinization start temperature of 40 μm.
It is preferable to contain 0.1 to 50% by weight of starch at ~ 70 ° C and 10 to 60% by weight of pseudo emulsified fats and oils, and it is preferable to add about 5 to 100% by weight of the mixed solution to raw meat. . As an addition amount (solid content) to raw meat, starch having an average particle size of 20 μm or less and a gelatinization temperature of 40 to 70 ° C. is preferably 0.2 to 10% by weight, and a pseudo emulsified oil or fat is preferably 0.5 to 25% by weight. The starch used in the present invention has an average particle size of 20 μm.
An ungelatinized starch having a gelatinization start temperature of 40 to 70 ° C., preferably a waxy rice starch and / or a modified starch thereof. As the pseudo-emulsified oil or fat, edible liquid oil or solid fat is used, and more preferably solid fat. In addition, as a method for adding the mixture to the raw meat, an injection method is exemplified.

【0013】[0013]

【発明の実施の形態】本発明の対象とする生肉は、牛、
豚、羊などの家畜、鶏、七面鳥、鴨、ガチョウなどの家
きん類から得られ、肉の表面積として少なくとも1cm2
以上の大きさを有するブロック状で、焼く、煮るなどの
加熱処理が施されていない肉類を総称し、硬質タイプの
肉、生鮮肉、チルドの肉、冷凍の肉などを包含する。但
し、冷凍の肉は予め解凍することによって本発明が実施
できる。この明細書において、「加熱調理後の肉」と
は、焼肉、焼鳥、ステーキ、カツ、鶏野菜煮、肉野菜
煮、肉じゃが、カレー、シチュー、茶碗蒸しなどのよう
に焼く、炒める、揚げる、煮込む、蒸すなどの加熱処理
を施した肉、及び肉料理中に含まれる肉を指称し、加熱
調理の方法は特に限定されない。
BEST MODE FOR CARRYING OUT THE INVENTION
Obtained from domestic animals such as pigs and sheep, and poultry such as chickens, turkeys, duck and geese, and have a surface area of meat of at least 1 cm 2.
A block-shaped meat having the above size and not subjected to heat treatment such as baking or boiling is a general term and includes hard-type meat, fresh meat, chilled meat, frozen meat and the like. However, the present invention can be implemented by thawing frozen meat in advance. In this specification, "meat after cooking" means grilled meat, yakitori, steak, cutlet, chicken and vegetable stew, meat and vegetable stew, meat and potatoes, curry, stew, boiled like steamed bowl, fried, fried, stewed, It refers to meat that has been subjected to heat treatment such as steaming and meat included in meat dishes, and the method of heating and cooking is not particularly limited.

【0014】本発明で言うインジェクションするとは、
ハムなどで利用されているピックル注射機を用いる方法
で、肉塊の中心部や関節の周囲に注射針を突きさし、圧
力をかけた状態で澱粉と疑似乳化している油脂を含有す
る混合液を押し出すことで混合液を肉塊の内部まで注入
することを意味し、容易に短時間で実施できる。これに
対して、混合液を肉塊に噴霧したり、混合液に肉塊を浸
漬するなどの方法を用いて混合液を肉塊に添加しようと
すると、これらの方法では混合液が肉塊の表面のみの添
加であったり、時間をかけても混合液が肉塊の内部まで
浸透しないなどの問題があるので、本発明では混合液を
肉塊に添加する方法としてインジェクションする方法が
最も好ましい。
In the present invention, the injection means
A method using a pickle syringe used in hams, etc., in which a syringe needle is pierced around the center of a meat mass or around a joint, and a mixture containing fat or oil emulsified with starch under pressure is applied. Extruding the liquid means injecting the mixed liquid to the inside of the meat mass, which can be easily performed in a short time. On the other hand, if it is attempted to add the mixture to the meat mass by using a method such as spraying the mixture onto the meat mass or dipping the meat mass into the mixture, the mixed solution is not used in these methods. In the present invention, the most preferable method for adding the mixture to the meat mass is a method of adding the mixture to the meat mass, since there are problems such as addition of the mixture only to the surface, and a problem that the mixture does not penetrate into the meat mass even if it takes a long time.

【0015】本発明に使用する澱粉とは、平均粒径が2
0μm以下で、且つその糊化開始温度が40〜70℃以
下の未糊化澱粉である。未糊化澱粉の平均粒径が20μ
mを越えると食感の改善効果や油脂由来の風味の発現を
期待できないなどの理由から本発明では平均粒径を20
μm以下に限定する。一方、未糊化澱粉とは、常温水で
溶解ないし、膨潤しない澱粉を意味し、その糊化開始温
度で表現すれば約40℃以上と言える。常温水で溶解な
いし膨潤する澱粉では、混合液にした時の粘度が高くな
ってインジェクションし難くなるだけなく、食感改善効
果も乏しい。また、糊化開始温度が70℃を越える澱粉
では、生肉の加熱処理後の食感を悪くしたり、油脂由来
の風味の発現も弱くする。
The starch used in the present invention has an average particle size of 2
It is an ungelatinized starch having a gelatinization start temperature of 0 μm or less and a gelatinization start temperature of 40 to 70 ° C. or less. Average particle size of ungelatinized starch is 20μ
If the average particle size is more than 20 m, the effect of improving the texture and the expression of the flavor derived from fats and oils cannot be expected.
Limited to μm or less. On the other hand, ungelatinized starch means starch that does not dissolve or swell in water at normal temperature, and can be said to be about 40 ° C. or higher in terms of the gelatinization start temperature. A starch that dissolves or swells in normal-temperature water has a high viscosity when formed into a mixed solution, making injection difficult, and also has a poor texture-improving effect. In the case of starch having a gelatinization start temperature exceeding 70 ° C., the texture of raw meat after the heat treatment is deteriorated, and the expression of flavor derived from fats and oils is also weakened.

【0016】この条件を満たす澱粉であれば、未加工の
澱粉、各種加工澱粉の区別を問わず、何れも使用でき、
具体的には、小麦澱粉、ワキシーコーンスターチ、タピ
オカ澱粉、糯米澱粉及びこれらの加工澱粉、更に糊化開
始温度が70℃を越える澱粉、例えばコーンスターチ、
粳米澱粉、甘藷澱粉、大麦澱粉などであっても、それら
を加工することによって糊化開始温度が上記範囲内にな
るようにした加工澱粉は使用できる。これらの中でも、
糯米澱粉及びそれらの加工澱粉がより好ましく、本発明
の目的をより効果的に発現する。尚、加工澱粉は天然澱
粉(未加工の澱粉)を何らかの方法で加工処理した澱粉
を表現し、具体的には常法により加工して、一般的に熱
処理澱粉、漂白澱粉、酸化澱粉、可溶性澱粉、架橋澱
粉、エーテル化澱粉、エステル化澱粉、架橋澱粉、架橋
エステル化澱粉、架橋エーテル化澱粉と呼ばれている加
工澱粉を包含する。これらの中でも、酸化澱粉、エーテ
ル化澱粉、エステル化澱粉は、その加工の程度に従って
糊化開始温度が低下するので、本発明の糊化開始温度の
条件を満たさない天然澱粉の加工方法として有効であ
る。
Any starch which satisfies this condition can be used regardless of whether it is unprocessed starch or various kinds of modified starch.
Specifically, wheat starch, waxy corn starch, tapioca starch, glutinous rice starch and their modified starches, and starch having a gelatinization initiation temperature exceeding 70 ° C., such as corn starch,
Even for non-glutinous rice starch, sweet potato starch, barley starch, etc., a processed starch having a gelatinization start temperature within the above range by processing them can be used. Among these,
Glutinous rice starch and their modified starches are more preferred and more effectively express the object of the present invention. The processed starch is a starch obtained by processing natural starch (unprocessed starch) by any method, and specifically, is processed by an ordinary method, and is generally heat-treated starch, bleached starch, oxidized starch, soluble starch. , Modified starches, which are called crosslinked starch, etherified starch, esterified starch, crosslinked starch, crosslinked esterified starch, crosslinked etherified starch. Among these, oxidized starch, etherified starch, and esterified starch are effective as a method for processing natural starch that does not satisfy the conditions of gelatinization start temperature of the present invention, because the gelatinization start temperature decreases according to the degree of processing. is there.

【0017】また、本発明で述べる糊化開始温度は、ブ
ラベンダーアミログラフを用いて澱粉濃度20重量%の
澱粉懸濁液(懸濁液500g中に澱粉を絶乾物として1
00gと溶解した食塩7.5gを含有)を攪拌しながら3
0℃より1分間1.5℃の昇温速度で加熱し、澱粉が糊化
する前にはチャート上のベースラインを動いていたペン
先(マーカー)が澱粉の糊化による粘性の為にベースラ
インからズレを生じるようになるが、そのズレの生じた
温度を読み取った値で表示する。本発明において、「疑
似乳化状の油脂」とは、水に油脂の85%以上、好まし
くは90%以上が10〜200μmの大きさで油滴又は
油塊として分散した状態にある油脂を称する。この分散
状態は穏やかな攪拌で保持されるが、攪拌を停止して静
置状態にすると油脂の分離や凝集などが起こりやすい。
一方、通常の乳化油脂とは、牛乳中に存在する乳脂肪の
ような油脂を意味し、静置状態でも油脂の分離や凝集が
起こりにくい。油脂の粒子径には明確な規定はないが、
例えば、牛乳では、油脂の粒子径が0.1〜20μm程
度にあるとされている。このような油脂は、常温で液状
の液状油や常温で固体状の固形脂を用いて、例えば下記
のような方法によって得られるが、それら以外の何れの
方法を用いてもよく、要は混合液中の油脂が疑似乳化状
であればよい。
The gelatinization start temperature described in the present invention is determined by using a Brabender amilograph with a starch suspension having a starch concentration of 20% by weight.
(With 7.5 g of dissolved sodium chloride) while stirring.
Heat from 0 ° C for 1 minute at a rate of 1.5 ° C. Before the starch was gelatinized, the nib (marker) that moved the baseline on the chart was changed to the base due to the viscosity due to starch gelatinization. A shift occurs from the line, and the temperature at which the shift occurs is indicated by a read value. In the present invention, the term "pseudo emulsified fat" refers to a fat in which 85% or more, preferably 90% or more of the fat is dispersed in water as oil droplets or oil lumps with a size of 10 to 200 µm. This dispersed state is maintained by gentle stirring, but if the stirring is stopped and the apparatus is allowed to stand still, separation and agglomeration of fats and oils are likely to occur.
On the other hand, ordinary emulsified fats and oils means fats and oils such as milk fats present in milk, and separation or aggregation of the fats and oils does not easily occur even in a static state. There is no clear rule for the particle size of fats and oils,
For example, in milk, the particle diameter of fats and oils is said to be about 0.1 to 20 μm. Such fats and oils can be obtained using a liquid oil that is liquid at room temperature or a solid fat that is solid at room temperature, for example, by the following method, but any other method may be used. It is sufficient that the fats and oils in the liquid are in a pseudo-emulsified state.

【0018】液状油の場合には、液状油を混合液に加え
て継続的に攪拌をすることで疑似乳化状の油脂が容易に
得られる。この場合、乳化剤を使用すると、攪拌を続け
るに従って乳化状態(10μm以下の油滴)の油脂が増
えてきて、本発明の目的にそぐわなくなるので、乳化剤
を使用せずに油脂を物理的に疑似乳化状にするのが好ま
しい。固形脂の場合には、固形脂を溶融し、適当な乳化
剤、例えばモノグリセリドを重合させて親水性をあげた
ポリグリセリドをベースとし、脂肪酸としてオレイン酸
等を含有し、HLBが10以上の乳化剤を添加して混合
後冷却し、これを混合液に添加して穏やかな攪拌をする
ことで疑似乳化状の油脂が得られる。穏やかな攪拌と
は、油脂を疑似乳化状に保持する程度の攪拌をすること
で、攪拌速度が通常1000rpm以下、好ましくは5
00rpm以下でなされる。攪拌速度が1000rpm
越えると疑似乳化状の油脂でなくなり、本発明の目的に
そぐわなくなる。
In the case of a liquid oil, a pseudo-emulsified oil can be easily obtained by adding the liquid oil to the mixture and continuously stirring the mixture. In this case, if an emulsifier is used, the amount of oil and fat in an emulsified state (oil droplets of 10 μm or less) increases as stirring is continued, which is not suitable for the purpose of the present invention. It is preferred that In the case of a solid fat, the solid fat is melted, and an appropriate emulsifier, for example, a polyglyceride which has been made hydrophilic by polymerizing monoglyceride, contains oleic acid or the like as a fatty acid, and has an emulsifier having an HLB of 10 or more. After addition, mixing and cooling, the mixture is added to the mixed solution and gently stirred to obtain a pseudo-emulsified oil and fat. Gentle agitation refers to agitation such that the fats and oils are maintained in a pseudo-emulsified state, and the agitation speed is generally 1000 rpm or less, preferably 5 rpm or less.
It is performed at 00 rpm or less. Stirring speed is 1000rpm
If it exceeds, it will not be a pseudo-emulsified oil and fat, and will not be suitable for the purpose of the present invention.

【0019】このように疑似乳化状の油脂は、液状油、
固形脂の何れからでも得られるが、より好ましくは固形
脂である。乳化剤を使用しないで液状油を油滴にして疑
似乳化状にすると攪拌を止めるとすぐ元の液状油にもど
る、或は乳化剤を使用して液状油を疑似乳化状にしても
疑似乳化状が保持される時間が短く攪拌中に乳化状態の
油脂が増えやすいなど疑似乳化状を保持することに問題
がみられる。しかし、固形脂の場合には疑似乳化状の油
脂が油塊であるため、攪拌を止めても油脂が油塊である
ことに変わりがなくて疑似乳化状に復元することが極め
て容易である、或は固形脂の方が生肉に注入後の油脂と
しての風味の発現が強くなる。用いる油脂は可食性の油
脂なら何れも使用でき、液状油としては大豆油、菜種
油、綿実油、サフラワー油、ヒマワリ油、トウモロコシ
油、コメ油、アマニ油など、固形脂としてはパーム油、
ヤシ油、パーム核油、カカオ脂、牛脂、豚脂のなどが例
示される。また、これらの油脂に水素添加、分別、エス
テル交換などの処理をして改質された油脂も利用でき
る。
Thus, the pseudo emulsified fats and oils are liquid oils,
Although it can be obtained from any of solid fats, it is more preferably a solid fat. If the liquid oil is converted to oil droplets without using an emulsifier to make it into a pseudo-emulsified state, the liquid oil returns to the original liquid oil as soon as stirring is stopped. There is a problem in maintaining the pseudo-emulsified state, for example, the oil and fats in the emulsified state tend to increase during stirring for a short time. However, in the case of solid fats, since the fats and oils in the pseudo-emulsified form are oil lumps, it is extremely easy to restore the pseudo-emulsified state without stopping stirring even if the stirring is stopped. Alternatively, solid fat has a stronger flavor as an oil or fat after being injected into raw meat. Any fats and oils that can be used can be used as long as they are edible fats and oils such as soybean oil, rapeseed oil, cottonseed oil, safflower oil, sunflower oil, corn oil, rice oil, linseed oil, etc.
Examples include coconut oil, palm kernel oil, cocoa butter, beef tallow, lard and the like. Also, fats and oils modified by subjecting these fats and oils to treatments such as hydrogenation, fractionation, and transesterification can be used.

【0020】従来、生肉そのものを加熱すると、加熱に
よって肉の縮みが大きくなって肉が硬くなったりして食
感が悪くなるという問題があり、加熱による肉の歩留り
低下の他、赤身の肉などでは油脂含量が少なく加熱して
も油脂由来の風味が期待できるものではなかった。しか
し、平均粒径20μm以下で、且つ糊化開始温度が40
〜70℃の澱粉と疑似乳化状の油脂を含有する混合液を
生肉に添加することで初めて、加熱調理での肉の歩留が
よく、加熱調理後の肉の食感や油脂由来の風味に優れた
生肉の製造が可能になった。本発明では混合液に平均粒
径20μm以下で、且つ糊化開始温度が40〜70℃の
澱粉と疑似乳化状の油脂を含有していることをが必須の
条件となる。その際、澱粉や油脂の種類、混合液として
の添加量などによっても変わるが、通常、混合液中に糊
化開始温度が40〜70℃の澱粉を0.1〜50重量%、
疑似乳化状の油脂を10〜60重量%含有していること
が望ましい。混合液中において、澱粉濃度が0.1重量未
満であったり、疑似乳化状の油脂が10重量%未満では
混合液の添加量が多くなりすぎるし、澱粉濃度が50重
量%を越えると澱粉の分散が悪くなるし、疑似乳化状の
油脂を60重量%を含有させようとすると油滴や油塊の
大きさにバラツキがみられて本発明が意図している疑似
乳化状の油脂の殆どを10〜200μmの大きさに保持
させられなくなる。
Conventionally, when raw meat itself is heated, there is a problem that the meat shrinks due to the heating and the meat becomes hard and the texture deteriorates. Thus, even when heated, the flavor derived from fats and oils could not be expected even if heated. However, when the average particle size is 20 μm or less and the gelatinization start temperature is 40
Only by adding a mixture containing starch and pseudo-emulsified oils and fats at temperatures of up to 70 ° C to raw meat can the meat be cooked with a good yield and the meat texture and the flavor derived from oils and fats after cooking can be improved. Excellent raw meat production has become possible. In the present invention, it is an essential condition that the mixed solution contains starch having an average particle size of 20 μm or less and a gelatinization start temperature of 40 to 70 ° C. and a pseudo emulsified fat or oil. At this time, although it varies depending on the types of starch and fats and the amount added as a mixed solution, usually, the gelatinization start temperature is 0.1 to 50% by weight in the mixed solution.
It is desirable to contain 10 to 60% by weight of pseudo emulsified fats and oils. If the starch concentration in the mixture is less than 0.1% by weight or the pseudo emulsified fat or oil is less than 10% by weight, the added amount of the mixture is too large, and if the starch concentration exceeds 50% by weight, the starch Dispersion becomes worse, and if the emulsified fat or oil is contained in an amount of 60% by weight, the size of oil droplets or oil lumps varies, and most of the pseudo emulsified fat or oil intended by the present invention is removed. It is no longer possible to keep the size of 10 to 200 μm.

【0021】生肉への混合液の添加は、混合液を生肉に
インジェクションすることにより行う。インジェクショ
ンする際の混合液の温度は生肉の温度と同程度に冷却
し、インジェクションする量として、生肉100重量部
に対して混合液を5〜100重量部程度を目安として行
う。混合液の温度があまりに高いと肉の変質をきたすこ
とになるし、混合液の添加量があまりに少ないと肉中で
均一に分散することが困難になったり、あまりに多いと
肉に保持されにくくなる。混合液がインジェクションさ
れた生肉は、好ましくはタンブラー又はバキュームタン
ブラーを用いてタンブリングする。
The addition of the mixture to the raw meat is carried out by injecting the mixture into the raw meat. The temperature of the mixture at the time of injection is cooled to about the same as the temperature of the raw meat, and the amount of the injection is about 5 to 100 parts by weight of the mixed liquid per 100 parts by weight of raw meat. If the temperature of the mixture is too high, the meat will deteriorate, and if the amount of the mixture is too small, it will be difficult to uniformly disperse in the meat, or if it is too large, it will be difficult for the meat to be retained by the meat. . Raw meat into which the mixture has been injected is preferably tumbled using a tumbler or a vacuum tumbler.

【0022】このようにして平均粒径20μm以下で、
且つ糊化開始温度が40〜70℃の澱粉と疑似乳化状の
油脂を生肉に添加して本発明の加工生肉は得られる。そ
の際、生肉に対して平均粒径20μm以下で、且つ糊化
開始温度70℃以下の澱粉と疑似乳化状の油脂の固形分
としての添加量はそれぞれ、0.2〜10重量%、及び0.
5〜25重量%、更に好ましくは0.5〜5重量%、及び
1.0〜20重量%にする。生肉に対する平均粒径20μ
m以下で、且つ糊化開始温度が40〜70℃の澱粉の固
形分としての添加量が0.2重量%未満では本発明の効果
がみられず、10重量%を越えると加熱調理後の食感に
異和感を生じる。一方、生肉に対する疑似乳化した油脂
の固形分としての添加量が0.5重量%未満では加熱調理
後の肉の油脂由来の風味に乏しく、25重量%を越える
と加熱調理後の肉に油っぽさが感じられるようになった
り、加熱調理での歩留りも低下する傾向がある。
As described above, when the average particle size is 20 μm or less,
In addition, the processed raw meat of the present invention can be obtained by adding starch having a gelatinization start temperature of 40 to 70 ° C. and pseudo-emulsified fats and oils to the raw meat. At this time, the amounts of starch and pseudo emulsified fat and oil having an average particle size of 20 μm or less and the gelatinization start temperature of 70 ° C. or less with respect to the raw meat are respectively 0.2 to 10% by weight and 0 to 10% by weight. .
5 to 25% by weight, more preferably 0.5 to 5% by weight, and
1.0 to 20% by weight. Average particle size 20μ for raw meat
m or less and the gelatinization start temperature is 40 to 70 ° C., the effect of the present invention is not obtained when the amount of the solid added is less than 0.2% by weight. Produces discomfort in the texture. On the other hand, if the amount of the pseudo-emulsified fat or oil added to the raw meat as a solid content is less than 0.5% by weight, the flavor derived from the fat or oil of the cooked meat is poor, and if it exceeds 25% by weight, the cooked meat becomes greasy. The length tends to be felt, and the yield by heating tends to decrease.

【0023】本発明では平均粒径20μm以下で、且つ
糊化開始温度が40〜70℃の澱粉と疑似乳化した油脂
を含む混合液を生肉にインジェクションすれば良く、こ
れら以外の添加物は特に必要としないが、必要に応じて
添加することもできる。例えば、グルコース、砂糖、乳
糖、フラクトース、異性化糖、直鎖や環状或は分岐オリ
ゴ糖、デキストリン、マルトデキストリンや水飴などの
糖質やそれらの還元物、食塩、グルタミン酸ナトリウ
ム、イノシン酸ナトリウムなどの調味料や味付け剤、植
物性蛋白、卵蛋白、乳蛋白などの蛋白質類、亜硝酸ナト
リウム、硝酸カリウム、ニコチン酸アミドなどの発色剤
又は発色助剤、L−アスコルビン酸ナトリウム、エリソ
ルビン酸、エリソルビン酸ナトリウム、αートコフェロ
ールなどの酸化防止剤、キサンタンガム、グアーガム、
アルファー澱粉等の増粘剤などの他、香辛料、重合リン
酸塩などを必要に応じて混合液に添加することもでき
る。これらの中でも食塩は、何れの料理においても基本
的な調味料なので生肉に対して0.5重量%程度添加させ
おくことが食味の点から好ましい。
In the present invention, a mixture containing starch and a pseudo emulsified fat or oil having an average particle size of 20 μm or less and a gelatinization start temperature of 40 to 70 ° C. may be injected into raw meat, and additives other than these are particularly necessary. However, they can be added as needed. For example, glucose, sugar, lactose, fructose, isomerized sugar, linear or cyclic or branched oligosaccharides, saccharides such as dextrin, maltodextrin and starch syrup, and their reduced products, salt, sodium glutamate, sodium inosinate, etc. Seasonings and flavoring agents, proteins such as vegetable protein, egg protein and milk protein, coloring agents or coloring aids such as sodium nitrite, potassium nitrate, nicotinamide, sodium L-ascorbate, erythorbic acid, sodium erythorbate , Antioxidants such as α-tocopherol, xanthan gum, guar gum,
In addition to thickeners such as alpha starch, spices, polymerized phosphates, and the like can be added to the mixture as needed. Among them, salt is a basic seasoning in any dish, so it is preferable to add about 0.5% by weight to raw meat from the viewpoint of taste.

【0024】かくして得られた本発明の加工生肉は、加
熱による肉汁の流逸が顕著に抑制され、各種の肉料理に
供して油脂由来の風味に優れ、味もよく、ジューシーで
ソフトな優れた食感が得られると共に、加熱調理による
歩留も顕著に改善される。さらにこの歩留の改善は、加
熱調理の際の肉汁の流逸抑制効果を示すものであり、混
合液の添加を加味すると元の生肉に対しては大幅な歩留
向上効果となり、経済効果も大である。また、料理の種
類に応じて好みの形状、例えば好みのサイズのブロック
状、スライス状、ミンチ状にしてもよい。さらに、本発
明の加工生肉はそのまま加熱調理することは勿論、冷
蔵、或は冷凍してからでも加熱調理に供することができ
る。
[0024] The processed raw meat of the present invention thus obtained has a remarkably suppressed escape of the gravy due to heating, and is excellent in flavors derived from fats and oils when used in various kinds of meat dishes, and has excellent taste, and is juicy and soft. The texture can be obtained, and the yield by heating and cooking can be significantly improved. Furthermore, the improvement of the yield indicates the effect of suppressing the escape of the gravy during cooking, and when the addition of the mixed solution is added, the yield of the original raw meat is greatly improved, and the economic effect is also improved. Is big. In addition, the shape may be a desired shape, for example, a block shape, a slice shape, or a mince shape of a desired size according to the type of dish. Further, the processed raw meat of the present invention can be cooked as it is, or can be subjected to cooking even after being refrigerated or frozen.

【0025】[0025]

【参考例1】攪拌下の水120部(重量部、以下特に明
記しない限り「部」は重量部である)にタピオカ澱粉1
00部を投入して分散し、3%水酸化ナトリウム水溶液
を投入しpHを9.5に維持しながら、無水酢酸4部を投
入して反応し、10%塩酸で中和、水洗、乾燥して糊化
開始温度59℃のエステル化タピオカ澱粉を得た。
REFERENCE EXAMPLE 1 Tapioca starch 1 was added to 120 parts of water (parts by weight; hereinafter, "parts" are parts by weight unless otherwise specified) under stirring.
Then, while maintaining the pH at 9.5 by adding a 3% aqueous solution of sodium hydroxide, 4 parts of acetic anhydride was added and reacted, neutralized with 10% hydrochloric acid, washed with water and dried. As a result, esterified tapioca starch having a gelatinization start temperature of 59 ° C. was obtained.

【参考例2】攪拌下の水130部に硫酸ナトリウム20
部を溶解し、コーンスターチ100部を投入して分散さ
せ、3%水酸化ナトリウム溶液35部を滴下し、プロピ
レンオキサイド6部を添加し、40℃で20時間反応
後、10%硫酸で中和、水洗、乾燥して糊化開始温度6
0℃のエーテル化コーンスターチを得た。
Reference Example 2 20 parts of sodium sulfate were added to 130 parts of water under stirring.
Was dissolved, 100 parts of corn starch was added and dispersed, 35 parts of a 3% sodium hydroxide solution was added dropwise, 6 parts of propylene oxide was added, the mixture was reacted at 40 ° C. for 20 hours, and neutralized with 10% sulfuric acid. Washing, drying and gelatinization start temperature 6
An etherified corn starch at 0 ° C. was obtained.

【0026】[0026]

【参考例3】攪拌下の水130部に硫酸ナトリウム10
部を溶解し、糯米澱粉100部を投入して分散させ、ト
リメタリン酸ソーダ0.01部を投入し、40℃で10時
間反応後、10%硫酸で中和、水洗、乾燥して糊化開始
温度65℃の架橋糯米澱粉を得た。
Reference Example 3 10 parts of sodium sulfate were added to 130 parts of water under stirring.
Dissolve 100 parts of glutinous rice starch and disperse it. Add 0.01 parts of sodium trimetaphosphate, react at 40 ° C for 10 hours, neutralize with 10% sulfuric acid, wash with water, and dry to start gelatinization. A crosslinked glutinous rice starch having a temperature of 65 ° C. was obtained.

【参考例4】精製ラード98部を加熱して溶融後、デカ
グリセリンモノオレート2部を添加して混合し、30℃
まで冷却して元の精製ラードより幾分柔らかい固体状を
呈する油脂を得た。得られた油脂を前処理ラードとす
る。攪拌速度300rpmにして、前処理ラードを水の
みで分散した分散液、前処理ラードを澱粉25重量%を
含有する水に分散後ヨード溶液で澱粉を染色した分散液
を調製し、2つの分散液を顕微鏡で観察したところ、何
れの分散液においても油脂の粒径の殆どが10〜200
μmの範囲にあり、粒径に格別変化が起こっていないこ
とから、澱粉の有無に関わらず油脂が水に同じように分
散することを確認した。次いで、前処理ラードを水に分
散した分散液をSALT1000(島津製作所製のレー
ザ回折式粒度測定装置)を用いて実測したところ、10
〜200μmの範囲にある油脂の量が95.2%と観測
された。このように添加した前処理ラードの殆どが疑似
乳化状の油脂となることから、本発明では添加した油脂
の量を混合液中に含有する疑似乳化油脂の量とみなし
た。
[Reference Example 4] 98 parts of purified lard was heated and melted, and then 2 parts of decaglycerin monooleate was added and mixed at 30 ° C.
Cooling to obtain an oil / fat which was slightly softer than the original refined lard. The resulting fat is referred to as pre-treated lard. At a stirring speed of 300 rpm, a dispersion prepared by dispersing the pretreated lard in water only, and a dispersion prepared by dispersing the pretreated lard in water containing 25% by weight of starch and then dyeing the starch with an iodine solution were prepared. When observed with a microscope, in any of the dispersions, most of the particle size of the fat or oil was 10 to 200.
Since the particle diameter was in the range of μm and no particular change in particle size occurred, it was confirmed that the fats and oils were similarly dispersed in water regardless of the presence or absence of starch. Next, when a dispersion obtained by dispersing the pretreated lard in water was actually measured using a SALT1000 (a laser diffraction particle size analyzer manufactured by Shimadzu Corporation),
The amount of fats and oils in the range of 200200 μm was observed to be 95.2%. Since most of the pretreated lard added in this way becomes a pseudo-emulsified fat, in the present invention, the amount of the added fat and oil was regarded as the amount of the pseudo-emulsified fat contained in the mixture.

【参考例5】参考例4の油脂を精製ヘッドとした以外、
同じように処理して得られた固体状を呈する油脂を前処
理ヘッドとする。参考例4と同じ方法で油脂の粒径を測
定したところ、10〜200μmの範囲にある油脂の量
が95.2%と観測された。
[Reference Example 5] Except that the fat and oil of Reference Example 4 was used as a refining head,
The solid-state fats and oils obtained by the same treatment are used as a pretreatment head. When the particle size of the fat or oil was measured in the same manner as in Reference Example 4, the amount of the fat or oil in the range of 10 to 200 μm was observed to be 95.2%.

【0027】[0027]

【実施例1】コーンスターチ、馬鈴薯澱粉、タピオカ澱
粉、糯米澱粉、参考例1〜3で得られた加工澱粉の物性
を表1に記載した。尚、澱粉の平均粒径は、SALD1
000(島津製作所製のレーザ回折式粒度測定装置)を
用いて求めた値である。300rpmの速度で攪拌中の
水に表1の澱粉、参考例4の前処理ラード、食塩を投入
して分散し、混合液100重量部中に固形分として澱粉
8部、疑似乳化豚脂20部、食塩2部を含有する混合液
を調整し、9℃に冷却した。添加した前処理ラードの殆
ど(95.2%)が10〜200μmの油塊として分散
しているので、前処理ラードの添加量を混合液中に含有
している疑似乳化状の油脂の量と見なして計算した。表
面積約100cm2 の生鮮豚もも肉ブロック(品温約9
℃)100部に上記の混合液30部(澱粉2.4部、疑似
乳化状の油脂6部、食塩0.6部)をインジェクション
し、20分間タンブリングして表2の加工生肉を製造し
た。タンブリング後の生肉と未処理の生肉を3×3×2
cmに裁断し、未処理の生肉を対照例として、90℃で1
0分間蒸煮した。蒸煮した肉を下記の基準で評価した結
果を表2に示す。
Example 1 Table 1 shows the physical properties of corn starch, potato starch, tapioca starch, glutinous rice starch, and the processed starches obtained in Reference Examples 1 to 3. The average particle size of the starch was SALD1
000 (a laser diffraction particle size analyzer manufactured by Shimadzu Corporation). The starch of Table 1, the pretreated lard of Reference Example 4, and sodium chloride were added and dispersed in water while stirring at a speed of 300 rpm, and 8 parts of starch and 20 parts of pseudo emulsified lard in 100 parts by weight of the mixed solution were added. , A mixture containing 2 parts of common salt was prepared and cooled to 9 ° C. Since most (95.2%) of the added pre-treated lard is dispersed as an oil mass of 10 to 200 μm, the amount of the pre-treated lard added to the amount of the pseudo emulsified oil and fat contained in the mixed solution Assumed and calculated. Fresh pork thigh meat block with surface area of about 100 cm 2 (product temperature about 9
(C), 30 parts of the above mixture (2.4 parts of starch, 6 parts of pseudo emulsified oil and fat, and 0.6 parts of salt) were injected and tumbled for 20 minutes to produce processed raw meat shown in Table 2. 3 × 3 × 2 raw meat after tumbling and untreated raw meat
cm and cut untreated raw meat at 90 ° C. as a control.
Steamed for 0 minutes. Table 2 shows the results of evaluating the steamed meat based on the following criteria.

【0028】 〈柔らかさ〉 ◎:対照に較べ、かなり柔らかい。 ○:対照に較べ、柔らかい。 △:対照とほぼ同じ程度。 ×:対照より硬い、又は異和感がある。 〈ジューシー感〉◎:対照に較べ、かなりジューシーである。 ○:対照に較べ、ジューシーである。 △:対照とほぼ同じ程度。 ×:対照よりジューシー感に欠ける。 〈風味〉 ◎:対照に較べ、油脂由来の風味がより強く感じられ、旨さ も極めて良好。 ○:対照に較べ、油脂由来の風味が強く、旨さも良好。 △:対照とほぼ同じ程度。 ×:対照に較べ、油脂由来の風味が多少とも弱く感じられる 、又は油っつぽい感じが強くなる。 〈歩留〉 蒸煮前の肉の重量に対する蒸煮後の肉の重量%で表示する。<Softness> A: considerably softer than control. :: Softer than control. Δ: Almost the same as the control. X: Harder than control or uncomfortable. <Juicy feeling> :: Very juicy compared to the control. :: Juicy as compared to the control. Δ: Almost the same as the control. ×: Less juicy than control. <Flavor> A: The flavor derived from fats and oils is felt stronger than the control, and the taste is extremely good. :: Compared with the control, the flavor derived from fats and oils is strong and the taste is good Δ: Almost the same as the control. X: Compared with the control, the flavor derived from fats and oils is felt somewhat weak or greasy. <Yield> Expressed as the weight% of the meat after steaming with respect to the weight of the meat before steaming.

【0029】[0029]

【表1】 澱粉No. 未加工又は加工澱粉 糊化開始温度 平均粒径 1 コーンスターチ 75℃ 13.3μm 2 馬鈴薯澱粉 61℃ 39.0μm 3 タピオカ澱粉 64℃ 14.2μm 4 糯米澱粉 64℃ 5.2μm 5 エステル化タピオカ澱粉 59℃ 14.3μm 6 エーテル化コーンスターチ 60℃ 13.5μm 7 架橋糯米澱粉 65℃ 5.3μm [Table 1] starch No. Raw or processed starch gelatinization start temperature average particle size 1 Corn starch 75 ° C 13.3 µm 2 Potato starch 61 ° C 39.0 µm 3 Tapioca starch 64 ° C 14.2 µm 4 Waxy rice starch 64 ° C 5.2 µm 5 Esterified tapioca starch 59 ° C 14.3 μm 6 Etherified corn starch 60 ° C. 13.5 μm 7 Crosslinked waxy rice starch 65 ° C. 5.3 μm

【0030】[0030]

【表2】 使用澱粉 柔らかさ ジューシ−感 風味 歩留り(%) 対照例 - △ △ △ 78.0 比較例 澱粉No.1 × × × 80.4 本発明 澱粉No.2 △ ○ △ 88.5 本発明 澱粉No.3 ○ ○ ○ 89.1 本発明 澱粉No.4 ◎ ◎ ◎ 91.3 本発明 澱粉No.5 ○ ○ ○ 87.9 本発明 澱粉No.6 ○ ○ ○ 89.5 本発明 澱粉No.7 ◎ ◎ ◎ 92.2 [Table 2] Starch softness used Juicy-feeling flavor yield (%) Control example- △ △ △ 78.0 Comparative example Starch No. 1 ××× 80.4 The present starch No. 1 2 △ ○ △ 88.5 Starch No. of the present invention 3 ○ ○ ○ 89.1 The present invention starch No. 3 4 ◎ ◎ ◎ 91.3 Starch No. of the present invention 5 ○ ○ ○ 87.9 The present starch No. 5 6 ○ ○ ○ 89.5 Invention Starch No. 6 7 ◎ ◎ ◎ 92.2

【0031】[0031]

【実施例2】混合液中に食塩を1%、澱粉No.7の架
橋糯米澱粉、疑似乳化状の油脂(参考例4の前処理ラー
ドを使用)を表3の割合で含有する混合液を調製し、生
肉100部に対する混合液の添加量を50部(生肉に対
する添加量として食塩0.5%と糯米澱粉と疑似乳化状の
油脂は表3に示す)とした以外は実施例1に準じて加工
生肉を製造し、実施例1の評価方法を用いて評価した。
結果を表4に示す。
Example 2 In a mixture, 1% of sodium chloride was added to a starch no. A mixed solution containing the crosslinked glutinous rice starch of No. 7 and the pseudo emulsified fat (using the pretreated lard of Reference Example 4) in the ratio of Table 3 was prepared, and the addition amount of the mixed solution to 50 parts of raw meat (100 parts of raw meat) The processed raw meat was produced in the same manner as in Example 1 except that the amount of salt added was 0.5% of salt, glutinous rice starch and pseudo emulsified fats and oils are shown in Table 3), and evaluated using the evaluation method of Example 1. did.
Table 4 shows the results.

【0032】[0032]

【表3】 混合液 混合液中固形分(%) 生肉に対する固形分添加量(%) No. 架橋糯米澱粉 疑似乳化状油脂 架橋糯米澱粉 疑似乳化状油脂 1 0.2 20.0 0.1 10.0 2 0.6 20.0 0.3 10.0 3 1.4 20.0 0.7 10.0 4 8.0 20.0 4.0 10.0 5 8.0 − 4.0 − 6 8.0 0.6 4.0 0.3 7 8.0 1.4 4.0 0.7 8 8.0 2.6 4.0 1.3 9 8.0 40.0 4.0 18.0 10 8.0 46.0 4.0 23.0 11 8.0 60.0 4.0 30.0 12 16.0 20.0 8.0 10.0 13 24.0 20.0 12.0 10.0 TABLE 3 mixture mixed solution solids (%) solids amount for meat (%) No. Crosslinked glutinous rice starch pseudo emulsified fat and oil Crosslinked glutinous rice starch pseudo emulsified fat and oil 1 0.2 20.0 0.1 10.0 2 0.6 20.0 0.3 10.0 3 1.4 20.0 0.7 10.0 4 8.0 20.0 4.0 10.0 5.0 8.0-4.0-6 8.0 0.6 4.0 0.37 8.0 1.4 1.4 4.0. 7 8 8.0 2.6 4.0 1.3 9 8.0 40.0 4.0 18.0 10 8.0 46.0 4.0 23.0 11 8.0 60.0 4.0 30.0 12 16.0 20.0 8.0 10.0 13 24.0 20.0 12.0 10.0

【0033】[0033]

【表4】 使用混合液 柔らかさ ジューシ−感 風味 歩留(%) 比較例 混合液1 △ △ △ 78.2 本発明 混合液2 ○ ○ ○ 86.7 本発明 混合液3 ◎ ◎ ◎ 90.3 本発明 混合液4 ◎ ◎ ◎ 82.9 比較例 混合液5 ◎ ◎ △ 85.4 比較例 混合液6 ◎ ◎ △ 86.9 本発明 混合液7 ◎ ◎ ○ 91.7 本発明 混合液8 ◎ ◎ ◎ 91.0 本発明 混合液9 ◎ ◎ ◎ 90.1 本発明 混合液10 ◎ ◎ ○ 90.2 本発明 混合液11 ◎ ◎ × 87.3 本発明 混合液12 ◎ ◎ ◎ 90.3 比較例 混合液13 △ △ ○ 89.1 [Table 4] Comparative example of the used mixture softness juicy- flavor yield (%) Mixed liquid 1 △ △ △ 78.2 Present mixed liquid 2 ○ ○ ○ 86.7 Present mixed liquid 3 ◎ ◎ ◎ 90. 3 Present invention Mixed liquid 4 ◎ ◎ ◎ 82.9 Comparative example Mixed liquid 5 ◎ ◎ △ 85.4 Comparative example Mixed liquid 6 ◎ ◎ △ 86.9 Present invention mixed liquid 7 ◎ ◎ ○ 91.7 Present mixed liquid 8 ◎ ◎ ◎ 91.0 Invention mixture 9 ◎ ◎ ◎ 90.1 Invention mixture 10 ◎ ◎ ○ 90.2 Invention mixture 11 ◎ ◎ × 87.3 Invention mixture 12 ◎ ◎ ◎ 90.3 Comparative Example Mixed Liquid 13 △ △ ○ 89.1

【0034】[0034]

【実施例3】実施例2において、生鮮豚肉ブロックと前
処理ラードを、ホルスタイン種の牛のもも肉と参考例5
の前処理ヘッドに変えた以外は同じようにして加工生肉
を製造し、対照とする未処理の生肉と比較したところ、
ほぼ同じような結果が得られた。
Example 3 In Example 2, fresh pork block and pre-treated lard were replaced with Holstein cow thigh and Reference Example 5.
Processed raw meat was produced in the same manner except that the pre-treatment head was changed to a pre-treated head, and compared with untreated raw meat as a control,
Almost the same result was obtained.

【0035】[0035]

【実施例4】全量100部中各種成分を表5の割合で含
む混合液30部を豚肩ロース肉一本物100部にインジ
ェックションし、30分間タンブリング後、未処理の豚
肩ロース肉と共に75℃で120分間蒸煮した。加熱前
後の重量差よりみたボイリング歩留は加工生肉で87.
3%、未処理の豚肩ロース肉では74.7%であった。蒸
煮後の肉を表6の処方からなるタレにつけ、オーブンを
使用し、250℃で20分間焼成して焼き豚にした。タ
レをつけるだけで焼成した焼き豚では、硬さもがあっ
て、ジューシー感の不足もみられたが、本発明による焼
き豚は柔らかく、ジューシー感もあり、油脂由来の風味
に優れて美味しいものであった。
Example 4 Injection of 30 parts of a mixed solution containing various components in the total amount of 100 parts shown in Table 5 into 100 parts of pork shoulder loin meat, tumbling for 30 minutes, together with untreated pork shoulder loin meat Steamed at 75 ° C for 120 minutes. The boiling yield based on the weight difference before and after heating is 87.
3%, and 74.7% for untreated pork loin. The steamed meat was immersed in a sauce having the formulation shown in Table 6 and baked in an oven at 250 ° C. for 20 minutes to obtain a baked pork. The baked pork baked just by adding sauce has a high hardness and lacks a juicy feeling, but the baked pork according to the present invention is soft, has a juicy feeling, and is excellent in flavor derived from fats and oils and delicious.

【0036】[0036]

【表5】 架橋糯米澱粉 4.30 疑似乳化状油脂(前処理ラード使用) 8.00 粉末水飴(DE18) 3.90 砂糖 0.95 カゼインナトリウム 2.52 食塩 4.00 亜硝酸ナトリウム 0.00 L−アスコルビン酸ナトリウム 0.256 トリポリリン酸ナトリウム 0.43 ピロリン酸ナトリウム 0.43 ジンジャー粉末 0.5 みりん 2.0 醤油(濃口) 1.0 グルタミン酸ナトリウム 0.5 ごま油 2.0 大豆白絞油 3.0[Table 5] Cross-linked glutinous rice starch 4.30 Pseudo emulsified oil (use of pre-treated lard) 8.00 Powdered starch syrup (DE18) 3.90 Sugar 0.95 Sodium caseinate 2.52 Salt 4.00 Sodium nitrite 0.00 Sodium L-ascorbate 0.256 Sodium tripolyphosphate 0.43 Sodium pyrophosphate 0.43 Ginger powder 0.5 Mirin 2.0 Soy sauce (dark mouth) 1.0 Sodium glutamate 0.5 Sesame oil 2.0 Soybean white squeezed oil 3 .0

【0037】[0037]

【表6】 醤油(濃口) 40 みりん 15 砂糖 5 白みそ 1 おろししょうが 1 カラメル 12 水 12[Table 6] Soy sauce (dark mouth) 40 mirin 15 sugar 5 white miso 1 grated ginger 1 caramel 12 water 12

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 平均粒径20μm以下で、且つ糊化開始
温度が40〜70℃の澱粉と疑似乳化状の油脂を含有す
る混合液を生肉に添加してなることを特徴とする加工生
肉。
1. Processed raw meat characterized by adding a mixed liquid containing starch having a mean particle size of 20 μm or less and a gelatinization start temperature of 40 to 70 ° C. and a pseudo-emulsified fat or oil to raw meat.
【請求項2】 生肉に対する固形分としての添加量が、
平均粒径20μm以下で、且つ糊化開始温度40〜70
℃の澱粉0.2〜10重量%、疑似乳化状の油脂0.5〜2
5重量%である請求項1に記載の加工生肉。
2. The amount of solids added to raw meat,
An average particle size of 20 μm or less and a gelatinization start temperature of 40 to 70
0.2% to 10% by weight of starch at 0.5 DEG C.
The processed raw meat according to claim 1, which is 5% by weight.
【請求項3】 疑似乳化状の油脂が固形脂であることを
特徴とする請求項1又は2に記載の加工生肉。
3. The processed raw meat according to claim 1, wherein the pseudo emulsified fat is a solid fat.
【請求項4】 澱粉が糯米澱粉及び/又はその加工澱粉
であることを特徴とする請求項1、2、又は3に記載の
加工生肉。
4. The processed raw meat according to claim 1, wherein the starch is glutinous rice starch and / or a processed starch thereof.
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004173572A (en) * 2002-11-27 2004-06-24 Honen Corp Fish meat quality improving agent and cooking processing method using the same
WO2004086884A1 (en) * 2003-03-28 2004-10-14 Uno Shoyu Co., Ltd. Modifier for meat, process for producing meat product, and meat product
JP2007274999A (en) * 2006-04-10 2007-10-25 Ajinomoto Co Inc Method for producing meat processed food
JP2008043288A (en) * 2006-08-21 2008-02-28 Matsutani Chem Ind Ltd Emulsified composition for meat processed product, and meat processed product using the same
JP2017099308A (en) * 2015-11-30 2017-06-08 キユーピー株式会社 Acidic liquid seasoning
JP2020000095A (en) * 2018-06-27 2020-01-09 味の素株式会社 Method for suppressing coagulation of oil/fat in processed meat product, method for producing oil/fat coagulation suppressed processed meat product, and processed meat product oil/fat coagulation suppressing agent

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JP2004173572A (en) * 2002-11-27 2004-06-24 Honen Corp Fish meat quality improving agent and cooking processing method using the same
JP4603235B2 (en) * 2002-11-27 2010-12-22 株式会社J−オイルミルズ Meat quality improver and cooking process using the same
WO2004086884A1 (en) * 2003-03-28 2004-10-14 Uno Shoyu Co., Ltd. Modifier for meat, process for producing meat product, and meat product
AU2004226523B2 (en) * 2003-03-28 2007-05-10 Uno Shoyu Co., Ltd Meat modifying agent, method of producing meat product and meat product
US7498052B2 (en) 2003-03-28 2009-03-03 Uno Shoyu Co., Ltd. Meat modifying agent, method of producing meat product and meat product
JP2007274999A (en) * 2006-04-10 2007-10-25 Ajinomoto Co Inc Method for producing meat processed food
JP4692361B2 (en) * 2006-04-10 2011-06-01 味の素株式会社 Process for producing processed meat products
JP2008043288A (en) * 2006-08-21 2008-02-28 Matsutani Chem Ind Ltd Emulsified composition for meat processed product, and meat processed product using the same
JP4702555B2 (en) * 2006-08-21 2011-06-15 松谷化学工業株式会社 Emulsified composition for processed meat products and processed meat products using the same
JP2017099308A (en) * 2015-11-30 2017-06-08 キユーピー株式会社 Acidic liquid seasoning
JP2020000095A (en) * 2018-06-27 2020-01-09 味の素株式会社 Method for suppressing coagulation of oil/fat in processed meat product, method for producing oil/fat coagulation suppressed processed meat product, and processed meat product oil/fat coagulation suppressing agent

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