JPH1126221A - Rare earth bonded magnet - Google Patents

Rare earth bonded magnet

Info

Publication number
JPH1126221A
JPH1126221A JP9187386A JP18738697A JPH1126221A JP H1126221 A JPH1126221 A JP H1126221A JP 9187386 A JP9187386 A JP 9187386A JP 18738697 A JP18738697 A JP 18738697A JP H1126221 A JPH1126221 A JP H1126221A
Authority
JP
Japan
Prior art keywords
magnet
rare earth
plating layer
earth bonded
metal plating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9187386A
Other languages
Japanese (ja)
Inventor
Yoshiyasu Koike
吉康 小池
Yasumitsu Hayashi
保光 林
Takeshi Anpo
武志 安保
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DAIDOO DENSHI KK
Original Assignee
DAIDOO DENSHI KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DAIDOO DENSHI KK filed Critical DAIDOO DENSHI KK
Priority to JP9187386A priority Critical patent/JPH1126221A/en
Publication of JPH1126221A publication Critical patent/JPH1126221A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F41/00Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
    • H01F41/02Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
    • H01F41/0253Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets for manufacturing permanent magnets
    • H01F41/026Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets for manufacturing permanent magnets protecting methods against environmental influences, e.g. oxygen, by surface treatment

Abstract

PROBLEM TO BE SOLVED: To obtain a rare earth bonded magnet which is high in corrosion resistance and mechanical strength, by a method wherein a magnet main body is formed of a mixture composed of a rare earth magnet powder and resin binder mixed at the required ratio, and all the surface of the magnet main body is coated directly with a metal plating layer. SOLUTION: A magnet main body 12 of a rare earth bonded magnet 10 is formed through such a manner that resin binder is added to magnetic material powder which contains one or more elements selected out of rare earth elements such as Sm, Nd, Pr and the like, the magnetic material powder mixed with resin binder is kneaded and injection-molded or compression-molded into a required shape. The magnet main body 12 is so set as to be 100 μm or less in surface roughness and 5.0 to 6.5 g/cm<3> in density. All the surface of the magnet main body 12 is coated with a metal plating layer 14 of thickness 5 to 50 μm. The metal plating layer 14 is formed of nickel or chrome. By this setup, a metal plating layer is imposed in film-forming efficiency, corrosion resistance and mechanical strength.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】この発明は、希土類ボンド磁
石に関し、更に詳細には、磁石本体の表面全体に金属メ
ッキ層が直に被覆されている希土類ボンド磁石に関する
ものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a rare earth bonded magnet, and more particularly, to a rare earth bonded magnet in which a metal plating layer is directly coated on the entire surface of a magnet main body.

【0002】[0002]

【従来の技術】Sm、Nd、Pr等の希土類元素の1種
または2種以上を含む磁性材料の粉末と樹脂バインダー
とを所要の割合で混合した混合物を射出成形または圧縮
成形して得られる希土類ボンド磁石が、例えばモータの
ロータ等に好適に使用されている。しかるに、希土類ボ
ンド磁石は、酸化し易い原料成分を含んでいるため、そ
の表面が素地のままでは経時的に錆が発生し易く、モー
タ部品等にそのまま使用すると、耐久性の低下や故障の
原因を招くことになる。そこで、錆止めのために希土類
ボンド磁石の表面を、スプレー塗装、電着塗装または浸
漬塗装等によって樹脂被膜で被覆する対策が一般に採ら
れている。
2. Description of the Related Art Rare earth obtained by injection molding or compression molding of a mixture obtained by mixing a powder of a magnetic material containing one or more kinds of rare earth elements such as Sm, Nd, Pr and a resin binder in a required ratio. Bond magnets are suitably used, for example, for motor rotors and the like. However, since rare-earth bonded magnets contain raw materials that are easily oxidized, rust easily occurs over time if the surface is unmodified, and if used as such for motor parts, the durability and failure may be reduced. Will be invited. Therefore, a measure is generally taken to coat the surface of the rare-earth bonded magnet with a resin film by spray coating, electrodeposition coating, dip coating or the like to prevent rust.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、樹脂被
膜で表面を被覆した希土類ボンド磁石を用いた製品にお
いては、その機械的強度が低く、組立工程中に樹脂被膜
が損傷したり、運搬時に誤って落したときに簡単に破損
してしまう等の難点が指摘される。そこで、希土類ボン
ド磁石の表面に下地処理を施した後、更に金属メッキ層
で被覆することで、機械的強度を向上させる提案がなさ
れている。しかるにこの場合は、下地の厚みのばらつき
が金属メッキ層の不安定要素となり、該メッキ層の成膜
効率が低下し、これによって耐食性も低下してしまう難
点が指摘される。また下地処理を施すために工程数が多
くなり、生産性の向上を図り得なかった。
However, in a product using a rare-earth bonded magnet whose surface is covered with a resin film, the mechanical strength is low, and the resin film is damaged during the assembling process or erroneously occurs during transportation. Difficulties such as being easily damaged when dropped are pointed out. Therefore, a proposal has been made to improve the mechanical strength by performing a base treatment on the surface of the rare-earth bonded magnet, and further covering the surface with a metal plating layer. However, in this case, it is pointed out that the unevenness of the thickness of the underlayer becomes an unstable factor of the metal plating layer, and the film formation efficiency of the plating layer is reduced, and thereby the corrosion resistance is also reduced. In addition, the number of steps is increased due to the base treatment, and the productivity cannot be improved.

【0004】[0004]

【発明の目的】本発明は、前述した従来の技術に内在し
ている前記欠点に鑑み、これを好適に解決するべく提案
されたものであって、高い耐食性が得られ、かつ機械的
強度を向上し得る希土類ボンド磁石を提供することを目
的とする。
SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned drawbacks inherent in the prior art, and has been proposed in order to suitably solve the drawback. The present invention provides high corrosion resistance and high mechanical strength. It is an object of the present invention to provide a rare earth bonded magnet that can be improved.

【0005】[0005]

【課題を解決するための手段】前記課題を克服し、所期
の目的を達成するため、本発明に係る希土類ボンド磁石
は、希土類磁石粉末と樹脂バインダーとを所要の割合で
混合した混合物から磁石本体が構成され、この磁石本体
の表面全体に金属メッキ層が直に被覆してあることを特
徴とする。
In order to overcome the above-mentioned problems and achieve the intended object, a rare-earth bonded magnet according to the present invention is a magnet made of a mixture obtained by mixing a rare-earth magnet powder and a resin binder in a required ratio. A main body is formed, and the entire surface of the magnet main body is directly covered with a metal plating layer.

【0006】[0006]

【発明の実施の形態】次に、本発明に係る希土類ボンド
磁石につき、添付図面を参照しながら以下説明する。図
1および図2は、実施例に係る希土類ボンド磁石を示す
ものであって、該希土類ボンド磁石10の磁石本体12
は、Sm、Nd、Pr等の希土類元素の1種または2種
以上を含む磁性材料の粉末に樹脂バインダーを添加して
混練したものを、所要形状に射出または圧縮成形するこ
とにより得られる。この磁石本体12は、その表面粗度
が100μm以下で、密度が5.0〜6.5g/cm3
間で好適には6.0g/cm3に設定されている。そし
て、この磁石本体12の表面全体は、5〜50μmの厚
みの金属メッキ層14で被覆されている。なお、金属メ
ッキ層14に用いられる金属材料としては、ニッケルや
クロム等が好適に使用される。
Next, a rare earth bonded magnet according to the present invention will be described with reference to the accompanying drawings. FIG. 1 and FIG. 2 show a rare earth bonded magnet according to an embodiment, and a magnet main body 12 of the rare earth bonded magnet 10.
Can be obtained by adding or kneading a resin binder to a magnetic material powder containing one or two or more rare earth elements such as Sm, Nd, and Pr into a required shape or by injection molding or compression molding. The magnet body 12 has a surface roughness at 100μm or less, the density is preferably between 5.0~6.5g / cm 3 is set to 6.0 g / cm 3. The entire surface of the magnet main body 12 is covered with a metal plating layer 14 having a thickness of 5 to 50 μm. In addition, as the metal material used for the metal plating layer 14, nickel, chromium, or the like is preferably used.

【0007】図3は、実施例に係る希土類ボンド磁石の
製造工程を示すフローチャートである。なお、実施例で
使用される磁石本体12は、例えば公知の急冷法で作製
したNd27wt%、Fe67wt%、B1wt%、C
o5wt%の組成からなる平均粒径150μmの合金粉
末に、カップリング剤0.1wt%、エポキシ樹脂1.5
〜3.0wt%および潤滑剤を加えて混練し、所要圧力
で圧縮成形した後に170℃で30〜60分間の熱処理
により硬化させることで製造される。なお、得られた磁
石本体12の表面粗度が100μm以下で、かつ密度が
5.0〜6.5g/cm3となるように、各製造条件が設
定される。また合金粉末の組成としては、Nd30wt
%、Fe69wt%、B1wt%のものでもよい。
FIG. 3 is a flowchart showing the steps of manufacturing the rare earth bonded magnet according to the embodiment. In addition, the magnet main body 12 used in the examples includes, for example, Nd 27 wt%, Fe 67 wt%, B 1 wt%, C
o An alloy powder having an average particle size of 150 μm having a composition of 5 wt%, a coupling agent of 0.1 wt%, and an epoxy resin of 1.5
33.0 wt% and a lubricant are added, kneaded, compression molded at a required pressure, and then cured by heat treatment at 170 ° C. for 30 to 60 minutes. Each manufacturing condition is set so that the surface roughness of the obtained magnet main body 12 is 100 μm or less and the density is 5.0 to 6.5 g / cm 3 . The composition of the alloy powder is Nd 30 wt.
%, 69 wt% of Fe, and 1 wt% of B.

【0008】次いで、前記磁石本体12を、純水により
洗浄して表面に付着している不純物を除去する。そし
て、この磁石本体12を、メッキ用金属としてニッケル
を用いて電気金属メッキした後、洗浄工程を経て乾燥さ
れる。これにより、磁石本体12の表面全体が直にニッ
ケルメッキ層で被覆された高い耐食性を有し、かつ機械
的強度が向上した希土類ボンド磁石10が得られる。な
お電気金属メッキとしては、メッキ液が貯留されたバレ
ルタンク内に磁石本体12を装入し、このタンクを回転
させると共に該タンク内に配設した電極に電流を流すこ
とによりメッキを行なうバレル法が好適に用いられる。
Next, the magnet body 12 is washed with pure water to remove impurities adhering to the surface. Then, the magnet main body 12 is subjected to electrometal plating using nickel as a plating metal, and then dried through a washing step. Thereby, the rare earth bonded magnet 10 having high corrosion resistance and improved mechanical strength in which the entire surface of the magnet main body 12 is directly covered with the nickel plating layer is obtained. In addition, as the electrometal plating, a barrel method in which the magnet main body 12 is loaded into a barrel tank storing a plating solution, and the tank is rotated and plating is performed by applying a current to an electrode provided in the tank. Is preferably used.

【0009】[0009]

【実施例の試験例について】前述した実施例に係る直に
金属メッキ層が被覆された希土類ボンド磁石および従来
の下地処理が施された後に金属メッキ層が被覆された希
土類ボンド磁石の各20個について、80℃×95%の
雰囲気中に置いて、錆の発生の有無を検査した結果を以
下の表1に示した。なお試験結果は、夫々20個の希土
類ボンド磁石に対する錆の発生個数の割合(錆の発生個
数/20)で示す。
Test Examples of Examples: Rare earth bonded magnets directly covered with a metal plating layer and rare earth bonded magnets coated with a metal plating layer after being subjected to a conventional undercoating treatment according to the above-described embodiment. Was placed in an atmosphere of 80 ° C. × 95% and inspected for the occurrence of rust. The results are shown in Table 1 below. The test results are shown as the ratio of the number of rusts generated to 20 rare-earth bonded magnets (the number of rusts generated / 20).

【0010】 [0010]

【0011】また、実施例の希土類ボンド磁石および従
来例の希土類ボンド磁石の各20個について、ロードセ
ルによって応力荷重を加え、破壊強度を測定した結果を
表2に示す。
Table 2 shows the results obtained by applying a stress load to each of the 20 rare earth bonded magnets of the embodiment and the conventional rare earth bonded magnet using a load cell and measuring the breaking strength.

【0012】 [0012]

【0013】すなわち、この試験結果から、磁石本体1
2の表面全体に金属メッキ層14を直に被覆した実施例
の希土類ボンド磁石10は、下地処理を施した後に金属
メッキ層を被覆した従来例の希土類ボンド磁石に比較し
て、耐食性(防錆効果)および破壊強度が共に向上するこ
とが明らかとなった。これは、金属メッキ層14の不安
定要素となる下地がないので、該メッキ層14の成膜効
率が良好になり、これにより耐食性が向上したものと考
えられる。
That is, from the test results, the magnet body 1
The rare-earth bonded magnet 10 of the embodiment in which the metal plating layer 14 is directly coated on the entire surface of the second example 2 has a higher corrosion resistance (corrosion prevention) than the conventional rare-earth bonded magnet in which the metal plating layer is coated after the base treatment. Effect) and the breaking strength were both improved. This is thought to be because the metal plating layer 14 does not have an underlayer that becomes an unstable element, so that the efficiency of forming the plating layer 14 is improved, and thereby the corrosion resistance is improved.

【0014】[0014]

【発明の効果】以上説明した如く、本発明に係る希土類
ボンド磁石によれば、磁石本体の表面全体を金属メッキ
層で直に被覆したので、金属メッキ層の成膜効率が向上
して高い耐食性を確保することができる。また、金属メ
ッキ層により希土類ボンド磁石の機械的強度が向上する
ので、当該希土類ボンド磁石を用いた製品においては、
その組立工程中に損傷したり、運搬時に誤って破損する
のを抑制することができ、取扱が容易となる利点を有す
る。更に、下地処理を施す必要はないから、製造工程数
も減少し、生産性が向上する利点がある。
As described above, according to the rare earth bonded magnet of the present invention, the entire surface of the magnet body is directly covered with the metal plating layer, so that the efficiency of forming the metal plating layer is improved and the corrosion resistance is high. Can be secured. In addition, since the mechanical strength of the rare earth bonded magnet is improved by the metal plating layer, in a product using the rare earth bonded magnet,
Damage during the assembling process and erroneous damage during transportation can be suppressed, and there is an advantage that handling becomes easy. Further, since it is not necessary to perform a base treatment, there is an advantage that the number of manufacturing steps is reduced and productivity is improved.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の実施例に係る希土類ボンド磁石を示す
断面図である。
FIG. 1 is a cross-sectional view illustrating a rare-earth bonded magnet according to an embodiment of the present invention.

【図2】実施例に係る希土類ボンド磁石の要部を拡大し
て示す説明図である。
FIG. 2 is an explanatory view showing an enlarged main part of the rare earth bonded magnet according to the embodiment.

【図3】実施例に係る希土類ボンド磁石の製造工程を示
すフローチャート図である。
FIG. 3 is a flowchart illustrating a manufacturing process of the rare-earth bonded magnet according to the embodiment.

【符号の説明】[Explanation of symbols]

12 磁石本体 14 金属メッキ層 12 Magnet body 14 Metal plating layer

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 希土類磁石粉末と樹脂バインダーとを所
要の割合で混合した混合物から磁石本体が構成され、こ
の磁石本体の表面全体に金属メッキ層が直に被覆してあ
ることを特徴とする希土類ボンド磁石。
1. A rare earth element comprising a mixture of a rare earth magnet powder and a resin binder mixed at a required ratio to form a magnet body, and a metal plating layer directly covering the entire surface of the magnet body. Bond magnet.
【請求項2】 前記金属メッキ層はニッケルメッキ層で
ある請求項1記載の希土類ボンド磁石。
2. The rare earth bonded magnet according to claim 1, wherein the metal plating layer is a nickel plating layer.
【請求項3】 前記磁石本体の表面粗度は、100μm
以下である請求項1または2記載の希土類ボンド磁石。
3. The magnet body has a surface roughness of 100 μm.
The rare earth bonded magnet according to claim 1, wherein:
【請求項4】 前記磁石本体の密度は、5.0〜6.5g
/cm3である請求項1〜3の何れかに記載の希土類ボ
ンド磁石。
4. The density of the magnet main body is 5.0 to 6.5 g.
/ Cm 3 rare-earth bonded magnet according to any one of claims 1 to 3.
【請求項5】 前記金属メッキ層の厚みは、5〜50μ
mである請求項1〜4の何れかに記載の希土類ボンド磁
石。
5. The metal plating layer has a thickness of 5 to 50 μm.
The rare earth bonded magnet according to any one of claims 1 to 4, wherein m is m.
JP9187386A 1997-06-27 1997-06-27 Rare earth bonded magnet Pending JPH1126221A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9187386A JPH1126221A (en) 1997-06-27 1997-06-27 Rare earth bonded magnet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9187386A JPH1126221A (en) 1997-06-27 1997-06-27 Rare earth bonded magnet

Publications (1)

Publication Number Publication Date
JPH1126221A true JPH1126221A (en) 1999-01-29

Family

ID=16205119

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9187386A Pending JPH1126221A (en) 1997-06-27 1997-06-27 Rare earth bonded magnet

Country Status (1)

Country Link
JP (1) JPH1126221A (en)

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