JPH11142603A - Antireflection film - Google Patents

Antireflection film

Info

Publication number
JPH11142603A
JPH11142603A JP9301931A JP30193197A JPH11142603A JP H11142603 A JPH11142603 A JP H11142603A JP 9301931 A JP9301931 A JP 9301931A JP 30193197 A JP30193197 A JP 30193197A JP H11142603 A JPH11142603 A JP H11142603A
Authority
JP
Japan
Prior art keywords
film
index transparent
refractive
antireflection
transparent film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9301931A
Other languages
Japanese (ja)
Inventor
Shingo Ono
信吾 大野
Masahito Yoshikawa
雅人 吉川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Corp
Original Assignee
Bridgestone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridgestone Corp filed Critical Bridgestone Corp
Priority to JP9301931A priority Critical patent/JPH11142603A/en
Publication of JPH11142603A publication Critical patent/JPH11142603A/en
Pending legal-status Critical Current

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  • Liquid Crystal (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Laminated Bodies (AREA)
  • Physical Vapour Deposition (AREA)
  • Gas-Filled Discharge Tubes (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide an antireflection film having good light transparency, high transparency and good color tones. SOLUTION: The antireflection films 5 consisting of laminated films of a high-refractive index transparent film 4 and a low-refractive index transparent film 3 are formed on the front surface of an org. film 2. In such a case, zinc oxide is used as the material of the high-refractive index transparent film and the antireflection film is formed by a reactive sputtering method preferably using metal zinc as a target, more particularly preferably a reactive sputtering method in a gaseous oxygen atmosphere or a gaseous oxygen - argon atmosphere contg. >=40% oxygen.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は反射防止フィルムに
係り、特に、光透過性に優れ、高透明性で色調の良い反
射防止フィルムに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an antireflection film, and more particularly to an antireflection film having excellent light transmittance, high transparency and good color tone.

【0002】[0002]

【従来の技術】OA機器のPDP(プラズマディスプレ
イパネル)や液晶板、車輌ないし特殊建築物の窓材には
光の反射を防止して高い光透過性を確保するために反射
防止フィルムが適用されている。
2. Description of the Related Art An anti-reflection film is applied to PDPs (plasma display panels) of OA equipment, liquid crystal panels, and windows of vehicles or special buildings to prevent reflection of light and ensure high light transmittance. ing.

【0003】従来、この種の用途に用いられる反射防止
フィルムは、TiO2,SiO2,ITO,SnO2,M
gF2等の透明膜を有機フィルム上に積層した構成とさ
れている。
Conventionally, antireflection films used for this kind of application are made of TiO 2 , SiO 2 , ITO, SnO 2 , M
It has a configuration in which a transparent film such as gF 2 is laminated on an organic film.

【0004】この反射防止フィルムでは、一般には紫外
線カット性をも兼備することが要求されている。
[0004] In general, this antireflection film is required to also have an ultraviolet cut property.

【0005】[0005]

【発明が解決しようとする課題】有機フィルム上に透明
膜を積層する方式の従来の反射防止フィルムでは、材料
に十分な透明性がなく、特に400nm付近から短い波
長での光の透過率が急激に下がってしまう。そのため、
反射防止フィルムが黄色味がかって見えるという欠点が
ある。透明性の高い材料も提案されてはいるが、成膜速
度が著しく遅い、或いは、350nm付近よりも波長の
短い紫外線に対してかなりの光透過があるため、紫外線
カット性が得られないという欠点があった。
In a conventional antireflection film of a system in which a transparent film is laminated on an organic film, the material does not have sufficient transparency, and in particular, the light transmittance at a short wavelength from about 400 nm is sharp. Will fall. for that reason,
There is a disadvantage that the antireflection film looks yellowish. Although a material having high transparency has been proposed, a drawback that the ultraviolet ray cut property cannot be obtained because the film formation rate is extremely slow or there is considerable light transmission for ultraviolet rays having a wavelength shorter than about 350 nm. was there.

【0006】本発明は上記従来の問題点を解決し、光透
過性に優れ、高透明性で色調の良い反射防止フィルムを
提供することを目的とする。
An object of the present invention is to solve the above-mentioned conventional problems and to provide an antireflection film having excellent light transmittance, high transparency and good color tone.

【0007】本発明はまた、高速成膜が可能で生産性に
優れ、また、紫外線カット性も備える反射防止フィルム
を提供することを目的とする。
Another object of the present invention is to provide an antireflection film capable of forming a film at a high speed, having excellent productivity, and also having an ultraviolet cut property.

【0008】[0008]

【課題を解決するための手段】本発明の反射防止フィル
ムは、有機フィルムの表面に、高屈折率透明膜と低屈折
率透明膜との積層膜よりなる反射防止膜が形成されてい
ることを特徴とする。
According to the antireflection film of the present invention, an organic film is provided with an antireflection film comprising a laminated film of a high refractive index transparent film and a low refractive index transparent film formed on the surface thereof. Features.

【0009】高屈折率透明膜と低屈折率透明膜との積層
膜であれば、その積層構造による光の干渉作用で光の反
射を効果的に防止し、光透過性に優れ、高透明性で色調
の良い反射防止フィルムを実現できる。
In the case of a laminated film of a high-refractive-index transparent film and a low-refractive-index transparent film, light reflection is effectively prevented by the light interference effect of the laminated structure, and excellent light transmittance and high transparency are achieved. Thus, an antireflection film having a good color tone can be realized.

【0010】この積層膜の高屈折率透明膜の材料として
400nm付近の光の透過性が高く、350nm付近及
びそれ以下の光の吸収が多い材料を用いることにより、
より一層優れた可視光透過性と紫外線カット性とを兼備
する反射防止フィルムを実現できる。また、成膜速度の
速い材料を用いることで、生産性を高めることができ
る。
By using a material having a high light transmittance near 400 nm and a large light absorption near 350 nm and below as a material of the high refractive index transparent film of the laminated film,
It is possible to realize an antireflection film having both more excellent visible light transmittance and ultraviolet cut properties. Further, by using a material with a high film formation rate, productivity can be increased.

【0011】酸化亜鉛(ZnO)は、400nm付近の
光の透過性が高く、350nm付近及びそれ以下の光の
吸収が多い材料であり、かつ、成膜速度の速い材料であ
るため、高屈折率透明膜の材料として酸化亜鉛を用いる
ことにより、優れた可視光透過性と紫外線カット性とを
兼備し、しかも生産性も良好な反射防止フィルムを提供
することができる。
Zinc oxide (ZnO) is a material having a high light transmittance near 400 nm, a large amount of light absorption near 350 nm and below, and a material having a high film formation rate, and therefore has a high refractive index. By using zinc oxide as the material of the transparent film, it is possible to provide an antireflection film having both excellent visible light transmittance and ultraviolet cut properties, and also having good productivity.

【0012】この酸化亜鉛膜は、好ましくは金属亜鉛を
ターゲットとする反応性スパッタ法、特に好ましくは、
酸素ガス雰囲気又は酸素を40%以上含む酸素−アルゴ
ンガス雰囲気中における反応性スパッタ法で形成され
る。
This zinc oxide film is preferably formed by a reactive sputtering method using zinc metal as a target.
It is formed by a reactive sputtering method in an oxygen gas atmosphere or an oxygen-argon gas atmosphere containing 40% or more of oxygen.

【0013】本発明において、反射防止膜は高屈折率透
明膜と低屈折率透明膜とを交互に積層した多層膜である
ことが好ましい。
In the present invention, the antireflection film is preferably a multilayer film in which high-refractive-index transparent films and low-refractive-index transparent films are alternately laminated.

【0014】[0014]

【発明の実施の形態】以下に図面を参照して本発明の反
射防止フィルムの実施の形態を詳細に説明する。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the antireflection film of the present invention will be described below in detail with reference to the drawings.

【0015】図1は本発明の反射防止フィルムの実施の
形態を示す模式的な断面図である。
FIG. 1 is a schematic sectional view showing an embodiment of the antireflection film of the present invention.

【0016】図示の如く、本発明の反射防止フィルム1
は、有機フィルム2上に、高屈折率透明膜4と低屈折率
透明膜3との積層膜よりなる反射防止膜5を形成したも
のである。
As shown, the antireflection film 1 of the present invention
Is an organic film 2 on which an antireflection film 5 composed of a laminated film of a high refractive index transparent film 4 and a low refractive index transparent film 3 is formed.

【0017】本発明において、有機フィルム2として
は、ポリエステル、ポリエチレンテレフタレート(PE
T)、ポリブチレンテレフタレート、ポリメチルメタア
クリレート(PMMA)、アクリル、ポリカーボネート
(PC)、ポリスチレン、トリアセテート、ポリビニル
アルコール、ポリ塩化ビニル、ポリ塩化ビニリデン、ポ
リエチレン、エチレン−酢酸ビニル共重合体、ポリウレ
タン、セロファン等、好ましくはPET、PC、PMM
Aの透明フィルムが挙げられる。
In the present invention, as the organic film 2, polyester, polyethylene terephthalate (PE)
T), polybutylene terephthalate, polymethyl methacrylate (PMMA), acrylic, polycarbonate (PC), polystyrene, triacetate, polyvinyl alcohol, polyvinyl chloride, polyvinylidene chloride, polyethylene, ethylene-vinyl acetate copolymer, polyurethane, cellophane Etc., preferably PET, PC, PMM
A transparent film.

【0018】有機フィルム2の厚さは得られる反射防止
フィルムの用途による要求特性(例えば、強度、薄膜
性)等によって適宜決定されるが、通常の場合、1μm
〜10mmの範囲とされる。
The thickness of the organic film 2 is appropriately determined according to the required characteristics (for example, strength and thin film properties) depending on the use of the obtained antireflection film.
It is in the range of 10 to 10 mm.

【0019】高屈折率透明膜4としては、ITO(スズ
インジウム酸化物)又はZnO、AlをドープしたZn
O、TiO2、SnO2、ZrO等の屈折率1.8以上の
薄膜を採用することができるが、前述の如く、高屈折率
透明膜4の材料としては、400nm付近の光の透過性
が高く、350nm付近及びそれ以下の光の吸収が多い
材料であって、成膜速度の速い材料を用いるのが好まし
い。このような材料として、特に、ZnOが好適であ
る。
The high refractive index transparent film 4 is made of ITO (tin indium oxide), ZnO or Al-doped Zn.
Although a thin film having a refractive index of 1.8 or more, such as O, TiO 2 , SnO 2 , or ZrO, can be employed, as described above, as a material for the high refractive index transparent film 4, light transmittance near 400 nm is required. It is preferable to use a material which is high and absorbs a lot of light near 350 nm or less and has a high film formation rate. As such a material, ZnO is particularly preferable.

【0020】一方、低屈折率透明膜3としてはSi
2、MgF2、Al23等の屈折率が1.6以下の低屈
折率材料よりなる薄膜を採用することができる。これら
高屈折率透明膜3及び低屈折率透明膜4の膜厚は光の干
渉で可視光領域での反射率を下げるため、膜構成、膜
種、中心波長により異なってくるが、図1に示すような
4層構造の場合、有機フィルム2側の第1層(高屈折率
透明膜4)が5〜50nm、第2層(低屈折率透明膜
3)が5〜50nm、第3層(高屈折率透明膜4)が5
0〜150nm、第4層(低屈折率透明膜3)が50〜
150nm程度の膜厚で形成するのが好ましい。
On the other hand, the low refractive index transparent film 3 is made of Si
A thin film made of a low-refractive-index material having a refractive index of 1.6 or less, such as O 2 , MgF 2 , or Al 2 O 3, can be used. The thicknesses of the high-refractive-index transparent film 3 and the low-refractive-index transparent film 4 are different depending on the film configuration, the film type, and the center wavelength in order to reduce the reflectance in the visible light region due to light interference. In the case of a four-layer structure as shown, the first layer (high-refractive-index transparent film 4) on the organic film 2 side is 5 to 50 nm, the second layer (low-refractive-index transparent film 3) is 5 to 50 nm, and the third layer ( High refractive index transparent film 4) is 5
0 to 150 nm, fourth layer (low refractive index transparent film 3) 50 to 50 nm
It is preferable to form the film with a thickness of about 150 nm.

【0021】このような高屈折率透明膜4及び低屈折率
透明膜3は、蒸着、スパッタリング、イオンプレーティ
ング、CVD法等により形成することができるが、特
に、高屈折率透明膜としての酸化亜鉛膜は、金属亜鉛を
ターゲットとする反応性スパッタ法で形成するのが好ま
しい。この場合、スパッタ条件は、O2100%又はO2
−ArでO240%以上の雰囲気条件とするのが好まし
い。
The high-refractive-index transparent film 4 and the low-refractive-index transparent film 3 can be formed by vapor deposition, sputtering, ion plating, CVD, or the like. The zinc film is preferably formed by a reactive sputtering method using metal zinc as a target. In this case, the sputtering conditions are O 2 100% or O 2
Preferably with O 2 40% or more ambient conditions in -ar.

【0022】なお、図1に示す反射防止フィルム1の反
射防止膜5は、有機フィルム2上に高屈折率透明膜4、
低屈折率透明膜3、高屈折率透明膜4、低屈折率透明膜
3の順で各膜が2層ずつ交互に合計4層積層された多層
膜とされたものであるが、この反射防止膜5の高屈折率
透明膜と低屈折率透明膜との積層構造は、図示のものの
他、次のようなものであっても良い。
The anti-reflection film 5 of the anti-reflection film 1 shown in FIG.
Each of the low-refractive-index transparent film 3, the high-refractive-index transparent film 4, and the low-refractive-index transparent film 3 is a multilayer film in which two layers are alternately laminated in total in a total of four layers. The laminated structure of the high-refractive-index transparent film and the low-refractive-index transparent film of the film 5 may be the following in addition to the illustrated one.

【0023】(a) 高屈折率透明膜と低屈折率透明膜
を1層ずつ合計2層に積層したもの (b) 中屈折率透明膜/高屈折率透明膜/低屈折率透
明膜の順で1層ずつ、合計3層に積層したもの (c) 高屈折率透明膜/低屈折率透明膜の順で各層を
交互に3層ずつ、合計6層に積層したもの なお、本発明の反射防止フィルムは、必要に応じて、表
面の耐汚染性を高めるために、更に反射防止膜上に汚染
防止膜を形成しても良い。この場合、汚染防止膜として
は、フッ素系薄膜、シリコン系薄膜等よりなる膜厚1〜
1000nm程度の薄膜が好ましい。
(A) A high-refractive-index transparent film and a low-refractive-index transparent film are laminated in a total of two layers each. (B) In order of medium-refractive-index transparent film / high-refractive-index transparent film / low-refractive-index transparent film. (C) A layer in which three layers are alternately laminated in order of a high refractive index transparent film / a low refractive index transparent film to form a total of six layers. The anti-reflection film may be further provided with an anti-reflection film, if necessary, on the anti-reflection film in order to increase the surface's resistance to contamination. In this case, as the contamination prevention film, a film thickness of 1 to 1 made of a fluorine-based thin film, a silicon-based thin film, or the like
A thin film of about 1000 nm is preferred.

【0024】このような本発明の反射防止フィルムは、
OA機器のPDPや液晶板の前面フィルタ、或いは、車
輌や特殊建築物の窓材に適用することで、良好な光透過
性を確保することができる。
Such an antireflection film of the present invention comprises:
By applying to a PDP of OA equipment, a front filter of a liquid crystal plate, or a window material of a vehicle or a special building, good light transmittance can be secured.

【0025】[0025]

【実施例】以下に実施例及び比較例を挙げて本発明をよ
り具体的に説明する。
The present invention will be described more specifically below with reference to examples and comparative examples.

【0026】実施例1、比較例1,2 有機フィルムとしてPETフィルム(膜厚100μm)
を用い、このフィルムの表面に表1に示す構成の反射防
止膜を反応性スパッタ法により形成し、その光透過率と
可視光反射率、色調及び成膜速度を下記方法で調べ、結
果を表1に示した。
Example 1, Comparative Examples 1 and 2 PET film (100 μm thick) as organic film
On the surface of this film, an antireflection film having the composition shown in Table 1 was formed by a reactive sputtering method, and its light transmittance, visible light reflectance, color tone, and film formation rate were examined by the following methods. 1 is shown.

【0027】[光透過率(%),可視光反射率(%)]
日立製可視紫外光分光測定装置(U−4000)を用
い、表1に示す波長付近の平均透過率と可視光反射率を
求めた。
[Light transmittance (%), visible light reflectance (%)]
The average transmittance and the visible light reflectance near the wavelengths shown in Table 1 were determined using a Hitachi Ultraviolet Spectrophotometer (U-4000).

【0028】[色調]目視により観察し、ほぼ無色透明
のものを○、黄色味がかったものを×とした。
[Color Tone] Observed visually, a colorless and transparent one was rated as ○, and a yellowish one was rated as x.

【0029】[成膜速度]全反射防止膜の膜厚を全成膜
時間で除して、単位厚さ当りの平均成膜時間を算出し
た。
[Film forming rate] The average film forming time per unit thickness was calculated by dividing the total antireflection film thickness by the total film forming time.

【0030】[0030]

【表1】 [Table 1]

【0031】表1より、実施例の反射防止フィルムは、
可視光透過率(可視光反射防止性)、紫外線カット性に
優れ、色調も良好で高速成膜が可能であることがわか
る。これに対して、比較例1の反射防止フィルムでは色
調が悪く、350nmの光を透過する。また、比較例2
の反射防止フィルムでは350nmの光を透過し、成膜
速度が遅い。
According to Table 1, the antireflection films of the examples are
It can be seen that the film has excellent visible light transmittance (visible light antireflection property), excellent ultraviolet light cut property, good color tone, and high-speed film formation. On the other hand, the antireflection film of Comparative Example 1 has poor color tone and transmits light of 350 nm. Comparative Example 2
In the anti-reflection film, the light of 350 nm is transmitted, and the film formation speed is low.

【0032】[0032]

【発明の効果】以上詳述した通り、本発明の反射防止フ
ィルムによれば、光透過性に優れ、高透明性で色調の良
い反射防止フィルムが提供される。
As described above in detail, according to the antireflection film of the present invention, an antireflection film having excellent light transmittance, high transparency and good color tone is provided.

【0033】特に、請求項2〜4の反射防止フィルムに
よれば、高速成膜が可能で生産性に優れ、また、紫外線
カット性も備える反射防止フィルムが提供される。
In particular, according to the antireflection film of the second to fourth aspects, an antireflection film which can be formed at a high speed, is excellent in productivity, and has an ultraviolet cut property is provided.

【0034】請求項5の反射防止フィルムによれば、よ
り一層優れた反射防止性能を有する反射防止フィルムが
提供される。
According to the antireflection film of claim 5, an antireflection film having more excellent antireflection performance is provided.

【図面の簡単な説明】[Brief description of the drawings]

【図1】図1は本発明の反射防止フィルムの実施の形態
を示す模式的な断面図である。
FIG. 1 is a schematic sectional view showing an embodiment of the antireflection film of the present invention.

【符号の説明】[Explanation of symbols]

1 反射防止フィルム 2 有機フィルム 3 低屈折率透明膜 4 高屈折率透明膜 5 反射防止膜 DESCRIPTION OF SYMBOLS 1 Antireflection film 2 Organic film 3 Low refractive index transparent film 4 High refractive index transparent film 5 Antireflection film

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 FI G02F 1/1335 G02F 1/1335 H01J 11/02 H01J 11/02 Z ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 6 Identification code FI G02F 1/1335 G02F 1/1335 H01J 11/02 H01J 11/02 Z

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 有機フィルムの表面に、高屈折率透明膜
と低屈折率透明膜との積層膜よりなる反射防止膜が形成
されていることを特徴とする反射防止フィルム。
1. An anti-reflection film, wherein an anti-reflection film comprising a laminated film of a high-refractive-index transparent film and a low-refractive-index transparent film is formed on the surface of the organic film.
【請求項2】 請求項1において、高屈折率透明膜が酸
化亜鉛膜であることを特徴とする反射防止フィルム。
2. The antireflection film according to claim 1, wherein the high refractive index transparent film is a zinc oxide film.
【請求項3】 請求項2において、酸化亜鉛膜は、金属
亜鉛をターゲットとする反応性スパッタ法により形成さ
れた被膜であることを特徴とする反射防止フィルム。
3. The anti-reflection film according to claim 2, wherein the zinc oxide film is a film formed by a reactive sputtering method using metal zinc as a target.
【請求項4】 請求項3において、反応性スパッタは、
酸素ガス雰囲気又は酸素を40%以上含む酸素−アルゴ
ンガス雰囲気中で行うことを特徴とする反射防止フィル
ム。
4. The reactive sputtering according to claim 3, wherein
An antireflection film, which is performed in an oxygen gas atmosphere or an oxygen-argon gas atmosphere containing 40% or more of oxygen.
【請求項5】 請求項1ないし4のいずれか1項におい
て、該反射防止膜は高屈折率透明膜と低屈折率透明膜と
を交互に積層した多層膜であることを特徴とする反射防
止フィルム。
5. The anti-reflection film according to claim 1, wherein the anti-reflection film is a multilayer film in which high-refractive-index transparent films and low-refractive-index transparent films are alternately laminated. the film.
JP9301931A 1997-11-04 1997-11-04 Antireflection film Pending JPH11142603A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9301931A JPH11142603A (en) 1997-11-04 1997-11-04 Antireflection film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9301931A JPH11142603A (en) 1997-11-04 1997-11-04 Antireflection film

Publications (1)

Publication Number Publication Date
JPH11142603A true JPH11142603A (en) 1999-05-28

Family

ID=17902838

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9301931A Pending JPH11142603A (en) 1997-11-04 1997-11-04 Antireflection film

Country Status (1)

Country Link
JP (1) JPH11142603A (en)

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