JPH1088148A - System for conversion of waste plastic into oil and system for conversion into oil and power generation - Google Patents

System for conversion of waste plastic into oil and system for conversion into oil and power generation

Info

Publication number
JPH1088148A
JPH1088148A JP24013396A JP24013396A JPH1088148A JP H1088148 A JPH1088148 A JP H1088148A JP 24013396 A JP24013396 A JP 24013396A JP 24013396 A JP24013396 A JP 24013396A JP H1088148 A JPH1088148 A JP H1088148A
Authority
JP
Japan
Prior art keywords
gas
oil
tank
pyrolysis
waste plastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP24013396A
Other languages
Japanese (ja)
Other versions
JP3317155B2 (en
Inventor
Ryokichi Yamada
良吉 山田
Tomoko Kaneko
朋子 金子
Tsuyoshi Shibata
強 柴田
Norio Arashi
紀夫 嵐
Hisao Yamashita
寿生 山下
Shigeru Azuhata
茂 小豆畑
Tomoyuki Saito
知行 斉藤
Masayoshi Kokubo
匡由 小久保
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP24013396A priority Critical patent/JP3317155B2/en
Publication of JPH1088148A publication Critical patent/JPH1088148A/en
Application granted granted Critical
Publication of JP3317155B2 publication Critical patent/JP3317155B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Landscapes

  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Processing Of Solid Wastes (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a light oil useful as a fuel for diesel power generation, etc., by converting a waste plastic into an oil. SOLUTION: This system for conversion of a plastic into an oil comprises a pyrolytic vessel 1 for the waste plastic, gas-solid and liquid separators 2 and 12 for separating dust and a condensed heavy component in a pyrolyzed gas, a cooler 3 for condensing and liquefying the pyrolyzed gas, a reflux vessel 4 for separating a condensed heavy component and an uncondensed light component therefrom, a chlorine fixing vessel 5 for removing a chlorine component, a condenser 6 for condensing and liquefying the pyrolyzed light gas and converting the pyrolyzed light gas into the oil, a gas-liquid separator 7 for separating the uncondensed gas from the condensed and liquefied oil, a light oil storage tank 9, etc. The pyrolyzed oil of the waste plastic can be used as a fuel for a diesel engine to enable clean power generation.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、廃プラスチックか
らディーゼル発電燃料として有用な油を回収する廃プラ
スチック油化システムに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a waste plastic liquefaction system for recovering useful oil as a diesel power generation fuel from waste plastic.

【0002】[0002]

【従来の技術】経済の発展に伴い再生品の市況悪化に起
因されるごみの再資源化の低迷、事務所のオフィス・オ
ートメーション化によるコピー用紙の多量排出,生活様
式の変化等に伴う家具電品等粗大廃棄物が年々増加して
いる。また、プラスチック生産量の増加に伴いその廃棄
物は年々増加しており社会問題となっている。現在、廃
棄プラスチックの大半が埋立てと焼却によって処分され
ている。しかし、埋立て用地の不足の問題や、また焼却
処分の場合には焼却炉の短命化や排ガスによる環境汚染
の問題がある。これらの問題を解決するために、廃棄プ
ラスチックの再資源化やエネルギ回収の方法が研究され
ている。
2. Description of the Related Art Recycling of garbage due to deterioration of the market of recycled products due to economic development, a large amount of copy paper discharge due to office automation in offices, and changes in lifestyle due to changes in lifestyle. Coarse waste such as goods is increasing year by year. In addition, with the increase in plastic production, the amount of waste is increasing year by year, and has become a social problem. Currently, most waste plastics are disposed of by landfill and incineration. However, there is a problem of shortage of landfill sites, and in the case of incineration, there is a problem of shortening the life of the incinerator and environmental pollution by exhaust gas. In order to solve these problems, methods of recycling waste plastics and recovering energy have been studied.

【0003】可燃物、特にプラスチック類のリサイクル
法の一つとして、廃プラスチックを熱分解して油化する
方法がある。熱可塑性プラスチックを対象として溶融・
熱分解によって油化・回収し、燃料化して利用する方法
が特開昭49−17477 号,同59−174689号などに開示され
ている。しかし、廃プラスチックを単に熱分解しただけ
では、生成油中に高分子量の留分やワックス状物等の重
質成分が多量に含有し、かつ、ガソリン等の軽質分から
重質分の広範囲の沸点油成分が存在するため、市販の燃
料油に比べディーゼル発電等の燃料油として流動性や着
火性に難点がある燃料油が回収される。熱分解生成油中
の高分子量の留分やワックス状物等の重質成分を触媒を
用いて接触分解により生成油の軽質化を行う方法が特開
平2− 29492 号,同3−200892号,同3−287694号等に
開示されている。
[0003] As one of the recycling methods for combustibles, especially plastics, there is a method in which waste plastics are thermally decomposed into oil. Melting and processing of thermoplastics
JP-A-49-17477 and JP-A-59-174689 disclose methods of converting oil into a fuel by thermal decomposition and recovering it. However, simply thermal decomposition of waste plastics results in a large amount of heavy components such as high molecular weight fractions and wax-like substances in the product oil, and a wide range of boiling points from light to heavy components such as gasoline. Due to the presence of the oil component, a fuel oil having difficulty in fluidity and ignitability is recovered as a fuel oil for diesel power generation or the like as compared with a commercially available fuel oil. JP-A-2-29492, JP-A-3-200892, and JP-A-2-29492 disclose a method of catalytically cracking heavy components such as high molecular weight fractions and wax-like substances in the thermally cracked oil to catalytically crack the resulting oil. No. 3-287694, and the like.

【0004】[0004]

【発明が解決しようとする課題】接触分解による廃プラ
スチック熱分解ガスの軽質化は、軽質油を回収する手段
としては有効であるが、ガス化分解が促進され易くガス
の生成量が多くなり、油の回収率が低下する課題があ
る。この場合は、生成ガスを廃プラスチック熱分解時の
加熱源に有効利用すればエネルギー面において得策にな
ろう。燃料としての貯蔵性は、液体のほうが貯蔵し易く
運搬する際も容易である。したがって、ガスの生成率を
出来るだけ低く抑制し、燃料油などに適した油の回収率
を向上することが望ましい。また、接触触媒では、経時
変化に伴い触媒上にカーボン等が析出し、軽質化特性が
低下することや触媒の再生及び交換等を行う必要があ
り、メンテナンスが容易でないという課題がある。さら
に、接触分解により軽質化した回収油は芳香族系及びオ
レフィン系の炭化水素を多量に含有しており、燃料とし
ての着火性が低くなり、排煙中の炭化水素濃度が高くな
るという課題がある。
Lightening waste plastic pyrolysis gas by catalytic cracking is effective as a means for recovering light oil, but gasification cracking is easily promoted and the amount of gas generated increases. There is a problem that the oil recovery rate is reduced. In this case, it would be advantageous in terms of energy if the generated gas is effectively used as a heating source during pyrolysis of waste plastic. As for the storability as a fuel, liquids are easier to store and transport. Therefore, it is desirable to suppress the gas generation rate as low as possible and to improve the recovery rate of oil suitable for fuel oil and the like. Further, in the case of the contact catalyst, there is a problem that carbon or the like precipitates on the catalyst with the lapse of time, the lightening characteristics are deteriorated, and it is necessary to regenerate and replace the catalyst, and maintenance is not easy. Furthermore, the recovered oil lightened by catalytic cracking contains a large amount of aromatic and olefinic hydrocarbons, which reduces the ignitability as a fuel and increases the concentration of hydrocarbons in flue gas. is there.

【0005】一方、熱分解ガス中に残渣(炭化物)等の
ダストが飛散同伴し、このダストが回収油に混入してデ
ィーゼル発電等の燃焼性の低下あるいは燃焼ノズルを閉
塞するという課題がある。また、廃プラスチック中に塩
化ビニールが混入すると回収油中に塩素成分が溶融含有
され、ディーゼル発電等のエンジンの腐食,燃焼排ガス
からの有害成分が排出され、人的弊害をもたらすことに
なる。
On the other hand, there is a problem that dust such as residue (carbide) is scattered and entrained in the pyrolysis gas, and this dust mixes with the recovered oil to lower the combustibility of diesel power generation or block the combustion nozzle. Further, if vinyl chloride is mixed in the waste plastic, the chlorine component is melted and contained in the recovered oil, and the harmful components from the exhaust gas such as the corrosion of engines such as diesel power generation and the combustion exhaust gas are discharged, resulting in human harm.

【0006】本発明の目的は、触媒を用いることなくガ
ス生成率を低減して効率よく重質油分を還流軽質化しデ
ィーゼル発電等の燃料に有用な軽質油を製造すると共に
油の回収率の向上を図る。また、熱分解ガス中に混入し
てくるダストを高効率で除去しディーゼル発電等の燃焼
性の向上あるいは燃焼噴霧ノズルの閉塞を防止する。さ
らに、重質成分及びダストの塩素固定化剤への付着を防
止し塩素固定化剤の利用率を向上し熱分解ガス中の塩素
成分を効率よく除去し、油中の塩素含有量を低下した良
質の燃料油を回収することにある。
SUMMARY OF THE INVENTION An object of the present invention is to reduce the gas generation rate without using a catalyst to efficiently reflux and lighten heavy oil components to produce light oil useful for fuels such as diesel power generation and to improve the oil recovery rate. Plan. In addition, dust mixed into the pyrolysis gas is removed with high efficiency to improve the combustibility of diesel power generation or the like or prevent the combustion spray nozzle from being clogged. In addition, it prevented heavy components and dust from adhering to the chlorine fixing agent, improved the utilization of the chlorine fixing agent, efficiently removed the chlorine component in the pyrolysis gas, and reduced the chlorine content in the oil. The purpose is to recover high quality fuel oil.

【0007】[0007]

【課題を解決するための手段】本発明では、熱分解ガス
に飛散同伴するダスト及び凝縮重質成分を第1の気・固
液分離器,還流槽及び第2の気・固液分離器により順次
分離し、第1,第2及び第3の固液滞留槽によりダスト
及び凝縮液化する重質成分を滞留しながら前記熱分解槽
に還流する。また、前記第1の気・固液分離器からの熱
分解ガスを所定の温度に冷却し重質成分を凝縮液化した
のち、還流槽により液化重質成分と未凝縮ガスとを分離
し、還流槽から液化重質成分を前記熱分解槽に還流して
繰り返し熱分解を促進する。この操作により重質油分の
軽質化を促進し燃料に有用な軽質油を回収するように
し、かつ、燃料油に適した油の回収率を向上する。ま
た、熱分解ガス中のダストを順次還流槽に還流し回収油
中のダストの混入率を低減し、塩素固定化剤への重質成
分及びダストの付着を防止することにより塩素固定化剤
の利用率を向上して還流槽からの未凝縮軽質ガス成分を
塩素固定化槽に通して塩素成分を効率よく除去し、腐食
性を抑制すると共に有害成分の排出を軽減する。また、
塩素固定化槽に通して塩素成分を除去した軽質ガス成分
を凝縮液化して軽質油分を回収すると共に沸点の異なる
油を分縮する凝縮器により燃料として有用な油を回収す
る。
According to the present invention, dust and condensed heavy components scattered in a pyrolysis gas are separated by a first gas-solid separator, a reflux tank and a second gas-solid separator. The dust and the heavy component to be condensed and liquefied are retained in the first, second and third solid-liquid retaining tanks, and are returned to the thermal decomposition tank while being retained. Further, after the pyrolysis gas from the first gas-solid liquid separator is cooled to a predetermined temperature to condense and liquefy the heavy component, the liquefied heavy component and the uncondensed gas are separated by a reflux tank and refluxed. The liquefied heavy component is refluxed from the tank to the thermal decomposition tank to repeatedly promote thermal decomposition. By this operation, lightening of heavy oil is promoted, light oil useful for fuel is recovered, and the recovery rate of oil suitable for fuel oil is improved. In addition, the dust in the pyrolysis gas is returned to the reflux tank in order to reduce the mixing ratio of dust in the recovered oil and prevent the heavy components and dust from adhering to the chlorine fixing agent. The utilization rate is improved, and the uncondensed light gas components from the reflux tank are passed through a chlorine fixing tank to efficiently remove the chlorine components, thereby suppressing corrosiveness and reducing the emission of harmful components. Also,
The light gas component from which the chlorine component has been removed is condensed and liquefied by passing it through a chlorine immobilization tank to collect the light oil component, and to collect useful oil as a fuel by means of a condenser that condenses oil having a different boiling point.

【0008】本発明によれば、熱分解ガスに飛散同伴す
るダスト及び凝縮液化する重質成分を第1及び第2の気
・固液分離器、または還流槽により順次分離し、該第1
及び第2の気・固液分離器、還流槽で分離したダスト及
び液化重質成分を前記第1,第2及び第3の固液滞留槽
で滞留しながら順次熱分解槽に還流するため、高効率で
ダストが除去でき回収油中へのダスト混入が防止でき
る。前記第1の気・固液分離器からの熱分解ガスを冷却
する冷却器により所定の温度で重質成分を凝縮液化し、
かつ、液化重質成分と未凝縮軽質ガス成分とを還流槽に
より分離して該還流槽からの液化重質成分を前記熱分解
槽に繰り返し還流するため、触媒を用いることなく重質
成分の軽質化促進を図ることができると共に油の回収率
を向上することができる。また、重質成分及びダストを
塩素固定化槽前段で熱分解槽に還流するため、塩素固定
化剤への重質成分及びダストの付着を防止でき、塩素固
定化剤の利用率向上が図れる。これにより、前記第2の
気・固液分離器からの未凝縮ガス中の塩素成分を塩素固
定化槽により効率よく除去できるため、腐食性の抑制及
び有害な塩素成分の排ガスの排出を軽減できる。塩素除
去後の前記未凝縮軽質ガス成分を冷却して軽質油化し、
該軽質化油から沸点の異なる油を分縮回収するため、燃
料等に有用な油を回収できる。
According to the present invention, the dust scattered along with the pyrolysis gas and the heavy component condensed and liquefied are sequentially separated by the first and second gas-solid-liquid separators or the reflux tank.
And the second gas-solid-liquid separator, the dust and the liquefied heavy component separated in the reflux tank are sequentially returned to the thermal decomposition tank while being retained in the first, second, and third solid-liquid retention tanks. Dust can be removed with high efficiency and dust can be prevented from being mixed into the recovered oil. A heavy component is condensed and liquefied at a predetermined temperature by a cooler that cools the pyrolysis gas from the first gas-solid liquid separator,
Further, since the liquefied heavy component and the uncondensed light gas component are separated by the reflux tank and the liquefied heavy component from the reflux tank is repeatedly returned to the pyrolysis tank, the light component of the heavy component can be used without using a catalyst. And the recovery rate of oil can be improved. Further, since the heavy components and the dust are returned to the pyrolysis tank in the preceding stage of the chlorine fixing tank, the adhesion of the heavy components and the dust to the chlorine fixing agent can be prevented, and the utilization rate of the chlorine fixing agent can be improved. Thereby, since the chlorine component in the uncondensed gas from the second gas-solid liquid separator can be efficiently removed by the chlorine fixing tank, the corrosiveness can be suppressed and the emission of harmful chlorine component exhaust gas can be reduced. . Cooling the uncondensed light gas component after chlorine removal to light oil,
Since the oils having different boiling points are fractionally recovered from the lightened oil, useful oils such as fuel can be recovered.

【0009】一方、回収した軽質油を発電機を接続した
ディーゼルエンジンの燃料として用いるため、腐食の抑
制及び燃焼排ガス中の有害な塩素成分の排出を軽減で
き、クリーンな発電ができる。
On the other hand, since the recovered light oil is used as a fuel for a diesel engine connected to a generator, it is possible to suppress corrosion and reduce the emission of harmful chlorine components in the combustion exhaust gas, thereby achieving clean power generation.

【0010】[0010]

【発明の実施の形態】以下、本発明の一実施例を図1を
用いて説明する。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS One embodiment of the present invention will be described below with reference to FIG.

【0011】図1には本発明の廃プラスチック油化発電
システムの基本構成模式図を示す。図1による実施例に
ついて述べる。本システムは熱分解槽1,第1及び第2
の気・固液分離器2,12,冷却器3,還流槽4,塩素
固定化5,凝縮器6,気液分離器7,燃焼器8,油貯留
槽9,第1,第2及び第3の固液滞留槽10,11,1
3,洗浄塔14,圧縮機15,未凝縮ガス貯留槽16,
送油ポンプ17,18,ガス吸引ポンプ19,吸引ブロ
アー22,ディーゼル発電機20,排ガス処理装置2
1,制御機23,弁500から508,514,調整弁
509から513,515などから構成される。
FIG. 1 is a schematic diagram showing the basic configuration of a waste plastic oil-based power generation system according to the present invention. An embodiment according to FIG. 1 will be described. This system is composed of pyrolysis tank 1, first and second
Gas-solid-liquid separators 2, 12, cooler 3, reflux tank 4, chlorine immobilization 5, condenser 6, gas-liquid separator 7, combustor 8, oil storage tank 9, first, second and first 3 solid-liquid retention tanks 10, 11, 1
3, washing tower 14, compressor 15, uncondensed gas storage tank 16,
Oil pumps 17, 18, gas suction pump 19, suction blower 22, diesel generator 20, exhaust gas treatment device 2
1, a controller 23, valves 500 to 508, 514, regulating valves 509 to 513, 515 and the like.

【0012】まず、動作について説明する。図1におい
て、廃プラスチックは熱分解槽1に供給される。廃プラ
スチックは未凝縮ガス貯留槽16あるいは油貯留槽9か
らの燃料を用いたガスバーナ燃焼(図示していない)に
より熱分解槽1が加熱され、ガス化分解される。該分解
ガスは配管700を経て気・固液分離器2に導入され、
ガス成分と分解ガス中に飛散同伴されるダスト及び分解
ガスの一部が凝縮液化される重質成分とが分離される。
ここで、分離されたダストと一部の液化重質成分は配管
702を経て第1の滞留槽10に滞留され、この後弁5
00を介して熱分解槽1に還流される。第1の滞留槽1
0においては、全てを第1の滞留槽10から熱分解槽1
に還流しないで一部のダスト及び液化重質成分が一定レ
ベルで滞留されながら熱分解槽1に還流されるようにな
っている。気・固液分離器2からの未凝縮分解ガスは配
管701を通して冷却器3に導入され、冷却水200に
より任意の所定温度に冷却され重質成分が凝縮液化され
たのち、還流槽4に導入される。還流槽4において凝縮
された重質成分は前段で除去し得なかったダストと共に
未凝縮軽質ガス成分のガスと分離され、ダストと液化重
質成分は配管705を経て第2の滞留槽11に滞留さ
れ、この後弁501を介して熱分解槽1に還流される。
第2の滞留槽11においても第1の滞留槽10と同様
に、全てを第2の滞留槽11から熱分解槽に還流しない
で一部のダスト及び液化重質成分が一定レベルで滞留さ
れながら熱分解槽1に還流されるようになっている。軽
質ガス成分は還流槽4において一定の温度に保持され、
かつ、軽質ガス成分中のミストが除去されながら還流槽
4から配管704を介して第2の気・固液分離器12に
導入され、前段で除去されないダスト及び凝縮液化する
重質成分とが未凝縮軽質ガス成分とに分離される。還流
槽4には、適宜アルミナボール等が充填される。分離さ
れたダスト及び液化重質成分は第3の滞留槽13に滞留
され、この後弁506を介して熱分解槽1に還流され
る。第3の滞留槽13においても全てを第3の滞留槽1
3から熱分解槽に還流しないで一部のダスト及び液化重
質成分が一定レベルで滞留されながら熱分解槽1に還流
されるようになっている。第2の気・固液分離器12か
らの未凝縮軽質ガス成分は、弁503を通して塩素固定
化槽5に導入される。弁504は閉の状態にある。該塩
素固定化槽5には塩素固定化剤として水酸化カルシュム
(Ca(OH)2)が充填されており、還流槽4と同等の温
度、あるいは前記塩素固定化剤のミスト油分付着による
利用率低下を防止するため、5ないし10℃高い温度に
加熱されている。還流槽4からの軽質ガス成分中に含有
される塩素成分は塩素固定化槽5において固定化除去さ
れたのち、弁505,配管706を通して凝縮器6に導
入される。軽質ガス成分は凝縮器6において冷却手段2
01により冷却され凝縮されて液化油化される。液化油
は配管707を経て気液分離器7に導入され、液化油と
未凝縮ガスとに分離される。分離された液化油は配管7
08を経て弁502を介して油貯留槽9に回収される。
未凝縮ガスは弁508,調整弁510を介して吸引ブロ
アー22により燃焼器8に導入され、燃焼後の排気ガス
300は処理されて系外に放出される。弁507は閉の
状態にある。あるいは、弁508,調節弁510が閉の
状態で弁507が開の状態から圧縮機15により未凝縮
ガス貯留槽16に回収される。未凝縮ガス貯留槽16に
は凝縮成分がガスの状態で貯留されるように温水管が設
けられてある。また、前記凝縮器6においては凝縮器6
を通過する間に温水,空気,冷却水などの冷却手段20
1により冷却・凝縮され、沸点の異なる液化油が回収さ
れるようになっている。この場合は、別の油受け槽(図
示していない)により回収される。前記分解槽1の加熱
は、未凝縮ガス貯留槽16からガス吸引ポンプ19によ
り調整弁512を通してガスバーナ(図示していない)燃
焼により行われる。あるいは、油貯留槽9から油送ポン
プ17により回収油の一部を供給し油燃焼バーナで加熱
される。熱分解槽1において分解ガス化されない成分は
残渣(炭化物)100として系外に取り出され処分され
る。熱分解槽1に還流される液化重質成分は還流軽質化
が促進されて油として殆ど回収されるが、それでも還流
槽1に残留する液化重質成分は沸点が高く、容易に軽質
化し得ない重質成分であるため、弁503,505を閉
じ弁504を開にして塩素固定化槽5を経由しないで凝
縮器6により冷却して回収される。この操作は、塩素固
定化槽5に充填された固定化剤への重質油分付着による
利用率低下を防止するために行われる。一方、ディーゼ
ル発電は上記動作により回収された燃料油が油貯留槽9
から弁514を介して送油ポンプ18により燃料タンク
に導入され、発電されて電力800が得られる。この電
力700は所内のモータ、各ポンプなどの動力として使
用される。また、ディーゼル発電機20からの排ガスは
熱分解槽1の加熱源として利用してもよい。
First, the operation will be described. In FIG. 1, waste plastic is supplied to a pyrolysis tank 1. The waste plastic is gasified and decomposed by heating the pyrolysis tank 1 by gas burner combustion (not shown) using fuel from the uncondensed gas storage tank 16 or the oil storage tank 9. The cracked gas is introduced into the gas-solid separator 2 through the pipe 700,
The gas component is separated from the dust that is entrained in the cracked gas and the heavy component that condenses and liquefies part of the cracked gas.
Here, the separated dust and a part of the liquefied heavy component are retained in the first retention tank 10 via the pipe 702, and thereafter the valve 5
The mixture is refluxed to the pyrolysis tank 1 through the fuel cell 00. First detention tank 1
In the case of 0, everything is transferred from the first retention tank 10 to the pyrolysis tank 1
Some of the dust and liquefied heavy components are refluxed to the thermal decomposition tank 1 while staying at a certain level without being refluxed. The uncondensed decomposition gas from the gas-solid liquid separator 2 is introduced into the cooler 3 through the pipe 701, cooled to an arbitrary predetermined temperature by the cooling water 200, and the heavy components are condensed and liquefied, and then introduced into the reflux tank 4. Is done. The heavy component condensed in the reflux tank 4 is separated from the gas of the uncondensed light gas component together with the dust that cannot be removed in the previous stage, and the dust and the liquefied heavy component are retained in the second retention tank 11 via the pipe 705. Then, it is returned to the pyrolysis tank 1 via the valve 501.
In the second retention tank 11 as well as in the first retention tank 10, all of the dust and liquefied heavy components are retained at a certain level without being entirely refluxed from the second retention tank 11 to the pyrolysis tank. The heat is returned to the thermal decomposition tank 1. The light gas component is maintained at a constant temperature in the reflux tank 4,
In addition, while the mist in the light gas component is being removed, the dust that is introduced from the reflux tank 4 through the pipe 704 to the second gas-solid-liquid separator 12 and is not removed in the preceding stage and the heavy component that is condensed and liquefied are not yet removed. It is separated into condensed light gas components. The reflux tank 4 is appropriately filled with alumina balls and the like. The separated dust and liquefied heavy component are retained in the third retention tank 13 and then returned to the thermal decomposition tank 1 via the valve 506. In the third retention tank 13 as well, all the components are stored in the third retention tank 1.
From 3, some dust and liquefied heavy components are refluxed to the thermal decomposition tank 1 while staying at a certain level without returning to the thermal decomposition tank. The uncondensed light gas component from the second gas-solid liquid separator 12 is introduced into the chlorine fixing tank 5 through the valve 503. Valve 504 is in a closed state. The chlorine immobilization tank 5 is filled with calcium hydroxide (Ca (OH) 2 ) as a chlorine immobilizing agent, and has the same temperature as that of the reflux tank 4 or the utilization rate of the chlorine immobilizing agent due to mist oil adhesion. It is heated to a temperature higher by 5 to 10 ° C. to prevent the drop. The chlorine component contained in the light gas component from the reflux tank 4 is fixed and removed in the chlorine fixing tank 5 and then introduced into the condenser 6 through the valve 505 and the pipe 706. The light gas component is cooled in the condenser 6 by the cooling means 2.
01, condensed and liquefied oil. The liquefied oil is introduced into the gas-liquid separator 7 via the pipe 707, and is separated into liquefied oil and uncondensed gas. The separated liquefied oil is supplied to pipe 7
08 and is collected in the oil storage tank 9 via the valve 502.
The uncondensed gas is introduced into the combustor 8 by the suction blower 22 via the valve 508 and the regulating valve 510, and the exhaust gas 300 after combustion is processed and discharged out of the system. The valve 507 is in a closed state. Alternatively, the compressed gas is collected by the compressor 15 into the non-condensed gas storage tank 16 while the valve 508 and the control valve 510 are closed and the valve 507 is opened. The uncondensed gas storage tank 16 is provided with a hot water pipe so that the condensed components are stored in a gaseous state. In the condenser 6, the condenser 6
Cooling means 20 such as hot water, air and cooling water while passing through
The liquid 1 is cooled and condensed, and liquefied oils having different boiling points are collected. In this case, the oil is collected by another oil receiving tank (not shown). Heating of the decomposition tank 1 is performed by burning a gas burner (not shown) from the uncondensed gas storage tank 16 through a regulating valve 512 by a gas suction pump 19. Alternatively, a part of the recovered oil is supplied from the oil storage tank 9 by the oil feed pump 17 and heated by the oil combustion burner. Components that are not decomposed and gasified in the pyrolysis tank 1 are taken out of the system as residues (carbides) 100 and disposed of. The liquefied heavy components refluxed to the pyrolysis tank 1 are almost recovered as oil by promoting lightening, but the liquefied heavy components remaining in the reflux tank 1 still have a high boiling point and cannot be easily lightened. Since it is a heavy component, it is cooled and collected by the condenser 6 without passing through the chlorine immobilization tank 5 by closing the valves 503 and 505 and opening the valve 504. This operation is performed in order to prevent a reduction in the utilization factor due to the attachment of heavy oil to the fixing agent filled in the chlorine fixing tank 5. On the other hand, in diesel power generation, the fuel oil
Is introduced into the fuel tank by the oil feed pump 18 via the valve 514, and is generated to generate electric power 800. The electric power 700 is used as power for a motor, pumps, and the like in the station. Further, the exhaust gas from the diesel generator 20 may be used as a heating source for the pyrolysis tank 1.

【0013】次に制御系統について動作を述べる。熱分
解槽1に投入された廃プラスチックの加熱温度は排ガス
ライン301に設けた温度検知器600により排ガスの
温度が検知される。検知された温度の情報は、制御機2
3に入力され、ここからの出力信号により未凝縮ガス貯
留槽16あるいは油貯留槽9の燃料供給ラインに設けた
調節弁512あるいは513が調整されて熱分解槽1の
加熱温度が一定になるように燃料供給量が制御される。
未凝縮ガス貯留槽16へのガスの貯留は圧力検知器60
3により所定の圧力以上にならないように監視され、所
定の圧力に達したら圧縮機15は停止され、未凝縮ガス
の供給が停止される。また、系内は常時吸引ブロアー2
2によって若干負圧で運転されるが、熱分解槽1内の圧
力は圧力検知器602により検知され、制御機23によ
って調節弁510が調整されて熱分解槽1内の圧力の変
動幅を最小になるように制御される。冷却器3の分解ガ
スの冷却調整は配管703に設けた温度検知器601及
び調節弁509により行われる。任意の温度に設定され
た冷却器3出口の分解ガス温度は温度検知器601によ
り検知され、この信号を受けて制御機23により調節弁
509が調整されて冷却機3の冷却水量が制御される。
なお、配管700から706,第1及び第2気・固液分
離機2,12,還流槽4,塩素固定化槽5,第1,第2
及び第3固液滞留槽10,11,13には加熱ヒータが
付設されており、加熱調整される(図示していない)よ
うになっている。
Next, the operation of the control system will be described. As for the heating temperature of the waste plastic put into the pyrolysis tank 1, the temperature of the exhaust gas is detected by a temperature detector 600 provided in the exhaust gas line 301. The detected temperature information is transmitted to the controller 2
The control valve 512 or 513 provided in the fuel supply line of the uncondensed gas storage tank 16 or the oil storage tank 9 is adjusted by the output signal from the control unit 3 so that the heating temperature of the pyrolysis tank 1 becomes constant. The fuel supply amount is controlled.
The gas is stored in the uncondensed gas storage tank 16 by a pressure detector 60.
It is monitored by 3 that the pressure does not exceed a predetermined pressure. When the pressure reaches the predetermined pressure, the compressor 15 is stopped and the supply of the uncondensed gas is stopped. The inside of the system is always a suction blower 2
2, the pressure in the pyrolysis tank 1 is detected by the pressure detector 602, and the control valve 510 is adjusted by the controller 23 to minimize the fluctuation range of the pressure in the pyrolysis tank 1. Is controlled so that The cooling of the decomposed gas in the cooler 3 is adjusted by a temperature detector 601 and a control valve 509 provided in the pipe 703. The temperature of the decomposed gas at the outlet of the cooler 3 set to an arbitrary temperature is detected by the temperature detector 601, and upon receiving this signal, the control valve 509 is adjusted by the controller 23 to control the amount of cooling water of the cooler 3. .
The pipes 700 to 706, the first and second gas / solid-liquid separators 2, 12, the reflux tank 4, the chlorine fixing tank 5, the first and second
The third solid-liquid stagnation tanks 10, 11, 13 are provided with heaters for heating and adjusting (not shown).

【0014】一方、前記廃プラスチック油化プロセスに
より回収した油を燃料とするディーゼル発電は上記動作
により回収された燃料油が油貯留槽9から弁514を介
して送油ポンプ18により燃料タンクに導入され、発電
されて電力800が得られる。この間、燃料タンク内へ
の送油は燃料タンク内に設けたレベル検知器615によ
り燃料の消費量が検知され、燃料油が所定のレベルに維
持されるように制御機23により調節弁514が調整さ
れて供給される。
On the other hand, in the diesel power generation using the oil recovered by the waste plastic oiling process as fuel, the fuel oil recovered by the above operation is introduced into the fuel tank from the oil storage tank 9 via the valve 514 by the oil pump 18. Then, power is generated and electric power 800 is obtained. During this time, when the oil is fed into the fuel tank, the fuel consumption is detected by the level detector 615 provided in the fuel tank, and the control valve 514 is adjusted by the controller 23 so that the fuel oil is maintained at a predetermined level. Supplied and supplied.

【0015】実験例1 図1の廃プラスチックの油化システムによる実験例を述
べる。廃プラスチックの原料として、ポリプロピレン1
3.5kg,ポリエチレン6.6kg,ポリスチレン2.1k
g,ポリ塩化ビニール0.3kg,エポキシ樹脂5.4kg ,
フェノール樹脂2.1kg 混合したものを用いた。これら
の原料は5mm程度に破砕したのち、熱分解槽1に投入し
上記作動により連続操作で150kg処理した。熱分解槽
1の廃プラスチックの加熱温度は420ないし430
℃,還流槽4の温度は280℃,塩素固定槽5は290
℃に維持した。
Experimental Example 1 An experimental example using the waste plastic oiling system of FIG. 1 will be described. As a raw material for waste plastic, polypropylene 1
3.5 kg, polyethylene 6.6 kg, polystyrene 2.1 k
g, polyvinyl chloride 0.3kg, epoxy resin 5.4kg,
A mixture of 2.1 kg of a phenol resin was used. After crushing these raw materials to about 5 mm, they were put into the pyrolysis tank 1 and 150 kg were continuously processed by the above operation. The heating temperature of the waste plastic in the pyrolysis tank 1 is 420 to 430
° C, the temperature of the reflux tank 4 is 280 ° C, and the temperature of the chlorine fixing tank 5 is 290.
C. was maintained.

【0016】この結果、油,未凝縮ガス,残渣の収率は
投入処理原料廃プラスチック重量に対してそれぞれ6
7.2wt%,17.7wt%,15.1wt% となっ
た。回収した油について、炭化水素の成分分析をガスク
ロマトグラフ質量分析計を用いて調べた。各成分をパラ
フィン,ナフテン,オレフィン,芳香族に分類し、その
割合は芳香族が45%,オレフィンが36%,パラフィ
ンが19%であった。
As a result, the yield of oil, uncondensed gas, and residue was 6% with respect to the weight of the input waste plastic.
It was 7.2 wt%, 17.7 wt%, and 15.1 wt%. The recovered oil was analyzed for hydrocarbon components using a gas chromatograph mass spectrometer. Each component was classified into paraffin, naphthene, olefin, and aromatic, and the proportion was 45% for aromatic, 36% for olefin, and 19% for paraffin.

【0017】比較例1 実験例1の回収油中の塩素含有量をイオンクロマトグラ
フ法で調べた結果、30ppm 以下となった。第1,第2
及び第3の固液滞留槽,還流槽による重質成分及びダス
トを熱分解槽に還流する機器構成によらず、熱分解ガス
を290℃に冷却したのち直接塩素固定化槽に供給した
場合、固定化剤の表面全域に重質成分とダストが付着し
ており、回収油中の塩素濃度は1600ppm であった。
これより、図1の機器構成により塩素固定化剤への重質
成分とダストの付着が防止でき、固定化剤の利用率向上
が図れることがわかる。
Comparative Example 1 The chlorine content in the recovered oil of Experimental Example 1 was determined by ion chromatography to be 30 ppm or less. 1st, 2nd
In the case where the pyrolysis gas is cooled to 290 ° C. and then supplied directly to the chlorine fixing tank, regardless of the equipment configuration for returning heavy components and dust to the pyrolysis tank by the third solid-liquid storage tank and the reflux tank, Heavy components and dust adhered to the entire surface of the immobilizing agent, and the concentration of chlorine in the recovered oil was 1600 ppm.
From this, it can be seen that the equipment configuration of FIG. 1 can prevent heavy components and dust from adhering to the chlorine fixing agent, and improve the utilization rate of the fixing agent.

【0018】比較例2 比較例として還流槽4を用いず、熱分解で生成した分解
ガスを直接触媒槽へ導入し、軽質化した。触媒槽からの
ガス成分を凝縮器6で冷却して凝縮液化油として回収し
た。廃プラスチック原料,熱分解法及び条件は本発明の
実験例1と同じである。触媒はゼオライト系のZSM−
5にSnを5wt%担持したものを用いた。回収した油
を上記と同様にガスクロマトグラフ質量分析計を用いて
調べた結果、89%が芳香族であった。また、油,未凝
縮ガス,残渣の収率は投入処理原料廃プラスチック重量
に対してそれぞれ59wt%,25.9wt%,15.1
wt%となった。
Comparative Example 2 As a comparative example, without using the reflux tank 4, the cracked gas generated by the thermal decomposition was directly introduced into the catalyst tank to reduce the weight. The gas component from the catalyst tank was cooled by the condenser 6 and recovered as condensed liquefied oil. The waste plastic raw material, the thermal decomposition method, and the conditions are the same as in Experimental Example 1 of the present invention. The catalyst is a zeolite-based ZSM-
5 was used which carried 5 wt% of Sn. The recovered oil was examined using a gas chromatograph mass spectrometer in the same manner as described above, and as a result, 89% was aromatic. The yields of oil, uncondensed gas, and residue were 59 wt%, 25.9 wt%, and 15.1 wt%, respectively, based on the weight of the input waste plastic.
wt%.

【0019】これより、触媒接触法による回収油の性状
に比べ本発明によれば芳香族系の炭化水素が少ないた
め、着火性が高く燃焼時の炭化水素の排煙濃度が低くな
る油が回収できる。特に、ディーゼルエンジンに用いる
際にノッキングが防止できる。また、ガスの生成が低下
し油の収率が向上できることがわかる。
According to the present invention, since the amount of aromatic hydrocarbons is small according to the present invention as compared with the properties of the oil recovered by the catalytic contact method, oil having high ignitability and low hydrocarbon exhaust gas concentration during combustion is recovered. it can. In particular, knocking can be prevented when used in a diesel engine. In addition, it can be seen that the generation of gas is reduced and the oil yield can be improved.

【0020】比較例3 実験例1で回収した油中のダストを濾過法により調べた
結果、回収油重量当り1.3wt% であった。比較する
ため、ここでは第1,第2及び第3の固液滞留槽10,
11,13,第1及び第2気・固液分離槽2,12を用
いないで廃プラスチックを熱分解油化した。廃プラスチ
ック原料,熱分解法及び条件は実験例と同じである。
Comparative Example 3 The dust in the oil recovered in Experimental Example 1 was examined by a filtration method and found to be 1.3% by weight based on the weight of the recovered oil. For comparison, here, the first, second, and third solid-liquid retention tanks 10,
The waste plastic was pyrolyzed to oil without using the eleventh, thirteenth, first and second gas / solid-liquid separation tanks 2,12. Waste plastic raw materials, pyrolysis method and conditions are the same as in the experimental example.

【0021】回収した油中のダストを濾過法により調べ
た結果、回収油重量当り8.9wt%であった。これよ
り、図1のシステムにより、回収油中へのダスト混入量
の低減が図れることがわかる。
As a result of examining the dust in the collected oil by a filtration method, it was found to be 8.9% by weight based on the weight of the recovered oil. From this, it can be seen that the amount of dust mixed into the recovered oil can be reduced by the system of FIG.

【0022】比較例4 実験例1の回収油中の塩素含有量をイオンクロマトグラ
フ法で調べた結果、30ppm 以下となった。比較するた
め、ここでは熱分解ガスを塩素固定化槽5を通さず、弁
503及び505を閉じ弁504を開にして分解ガスを
直接凝縮器6に導入し、冷却・凝縮して液化油を回収し
た。回収油中の塩素含有量をボンベ燃焼法による排ガス
をイオンクロマトグラフ法により調べた結果、850pp
m であった。図1のシステムにより、原料廃プラスチッ
ク中に混入する塩化ビニール等に含有される塩素成分が
除去されることがわかる。
Comparative Example 4 The chlorine content in the recovered oil of Experimental Example 1 was determined by ion chromatography to be 30 ppm or less. For comparison, here, the pyrolysis gas is not passed through the chlorine immobilization tank 5, the valves 503 and 505 are closed, the valve 504 is opened, and the decomposition gas is directly introduced into the condenser 6, where the liquefied oil is cooled and condensed. Collected. As a result of examining the chlorine content in the recovered oil by exhaust gas using a cylinder combustion method by ion chromatography, 850 pp
m. It can be seen that the system of FIG. 1 removes chlorine components contained in vinyl chloride and the like mixed in the raw material waste plastic.

【0023】実験例2 次に、実験例1で回収した油によるディーゼル発電を実
施した。ディーゼル発電機20は出力6kWの用量のも
のを用いた。電力700は負荷4kWのヒータを水中に
設置して回収した。発電は約2時間行った。
Experimental Example 2 Next, diesel power generation using the oil recovered in Experimental Example 1 was performed. The diesel generator 20 used had a power output of 6 kW. Electric power 700 was collected by installing a heater with a load of 4 kW in water. Power generation was performed for about 2 hours.

【0024】この結果、前記動作により油貯留槽9から
ディーゼル発電機20への油の供給は円滑にでき、油を
連続燃焼でき、電力を回収できた。また、ダストによる
エンジンの閉塞も見られなかった。さらに、排ガス中の
一部を0.04% 苛性ソーダ水溶液のガス洗浄ビンに入
れ、2リットル/min の流量で吸引して導入・採集し、
塩素成分濃度をイオンクロマトグラフ法により調べた。
その結果、排ガス中の塩素成分濃度は塩素成分を固定化
除去した場合は6.2ppm、除去しない場合は130ppm
になり、実験例1の油を用いることにより有害な塩素成
分の排ガスの排出を軽減でき、クリーンな燃焼発電がで
きることがわかる。
As a result, the above operation made it possible to smoothly supply the oil from the oil storage tank 9 to the diesel generator 20, to continuously burn the oil, and to recover the electric power. Also, no blockage of the engine due to dust was observed. Further, a part of the exhaust gas is put into a gas washing bottle of a 0.04% aqueous solution of caustic soda, introduced at a flow rate of 2 liters / min and introduced and collected.
The chlorine component concentration was examined by ion chromatography.
As a result, the chlorine component concentration in the exhaust gas was 6.2 ppm when the chlorine component was fixed and removed, and 130 ppm when the chlorine component was not removed.
It can be seen that the use of the oil of Experimental Example 1 can reduce the emission of harmful chlorine component exhaust gas, thus enabling clean combustion power generation.

【0025】[0025]

【発明の効果】本発明によれば、分解ガスを任意の所定
温度に冷却し重質成分を凝縮液化し還流槽から熱分解槽
に還流し軽質化が促進でき、軽質油が回収できると共に
油回収率の向上が図れる効果がある。これにより、触媒
の活性低下による触媒の交換等をするメンテナンスがな
くなり、かつ、軽質化時のガス化発生率の増大による油
回収率の低下を防止できる効果がある。また、廃プラス
チックの分解ガス中の重質成分及びダストを順次熱分解
槽に還流するため、塩素固定化剤への重質成分及びダス
トの付着が防止でき、塩素固定化剤の利用率向上が図れ
る効果がある。これより、回収油中へのダスト及び塩素
成分の混入を防止でき、ここで得られた軽質油をディー
ゼルエンジンの燃料として用いることにより、腐食の抑
制及び燃焼排ガス中の有害な塩素成分の排出を軽減で
き、クリーンな発電ができる効果がある。
According to the present invention, the cracked gas is cooled to an arbitrary predetermined temperature to condense and liquefy heavy components, and is refluxed from the reflux tank to the pyrolysis tank to promote lightening. This has the effect of improving the recovery rate. As a result, there is an effect that there is no need to perform maintenance such as replacement of the catalyst due to a decrease in the activity of the catalyst, and it is possible to prevent a decrease in the oil recovery rate due to an increase in the rate of gasification at the time of lightening. In addition, since heavy components and dust in the decomposition gas of waste plastic are sequentially returned to the pyrolysis tank, it is possible to prevent heavy components and dust from adhering to the chlorine fixing agent and improve the utilization rate of the chlorine fixing agent. There is an effect that can be achieved. As a result, dust and chlorine components can be prevented from being mixed into the recovered oil, and by using the obtained light oil as a fuel for a diesel engine, it is possible to suppress corrosion and discharge harmful chlorine components in the combustion exhaust gas. This has the effect of reducing power consumption and producing clean power.

【図面の簡単な説明】[Brief description of the drawings]

【図1】廃プラスチックの油化発電システムの模式図。FIG. 1 is a schematic diagram of a waste plastic oil-based power generation system.

【符号の説明】[Explanation of symbols]

1…熱分解槽、2…第1気・固液分離器、3…冷却器、
4…還流槽、5…塩素固定化、6…凝縮器、7…気液分
離器、8…燃焼器、9…油貯留槽、10…第1固液滞留
槽、11…第2固液滞留槽、12…第2気・固液分離
器、13…第3固液滞留槽、14…洗浄塔、15…圧縮
機、16…未凝縮ガス貯留槽、17,18…送油ポン
プ、19…ガス吸引ポンプ、20…ゼィーゼル発電機、
21…排ガス処理装置、22…吸引ブロアー、23…制
御機、500〜508,514…弁、509〜513…
調整弁。
DESCRIPTION OF SYMBOLS 1 ... Pyrolysis tank, 2 ... 1st gas-solid-liquid separator, 3 ... Cooler,
4 ... reflux tank, 5 ... chlorine immobilization, 6 ... condenser, 7 ... gas-liquid separator, 8 ... combustor, 9 ... oil storage tank, 10 ... first solid-liquid retention tank, 11 ... second solid-liquid retention Tank, 12: second gas / solid-liquid separator, 13: third solid-liquid storage tank, 14: washing tower, 15: compressor, 16: uncondensed gas storage tank, 17, 18: oil feed pump, 19 ... Gas suction pump, 20 ... Seesel generator,
21: exhaust gas treatment device, 22: suction blower, 23: controller, 500 to 508, 514: valve, 509 to 513 ...
tuning valve.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 嵐 紀夫 茨城県日立市大みか町七丁目1番1号 株 式会社日立製作所日立研究所内 (72)発明者 山下 寿生 茨城県日立市大みか町七丁目1番1号 株 式会社日立製作所日立研究所内 (72)発明者 小豆畑 茂 茨城県日立市大みか町七丁目1番1号 株 式会社日立製作所日立研究所内 (72)発明者 斉藤 知行 東京都千代田区神田駿河台四丁目6番地 株式会社日立製作所内 (72)発明者 小久保 匡由 東京都千代田区三崎町二丁目9番18号 株 式会社日立システムテクノロジー内 ──────────────────────────────────────────────────続 き Continued on the front page (72) Norio Arashi 7-1-1, Omikacho, Hitachi City, Ibaraki Prefecture Inside Hitachi, Ltd. Hitachi Research Laboratory, Ltd. (72) Inventor Hisao Yamashita 7-1 Omikacho, Hitachi City, Ibaraki Prefecture No. 1 Inside Hitachi, Ltd.Hitachi Research Laboratory (72) Inventor Shigeru Azuhata 7-1-1, Omikacho, Hitachi City, Ibaraki Prefecture Inside Hitachi, Ltd.Hitachi Laboratory (72) Inventor Tomoyuki Saito Kanda, Chiyoda-ku, Tokyo 4-6, Surugadai Inside Hitachi, Ltd. (72) Inventor Masayoshi Kokubo 2-9-18 Misaki-cho, Chiyoda-ku, Tokyo Inside Hitachi System Technology Co., Ltd.

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】廃プラスチックを加熱下で熱分解ガス化す
る熱分解槽と、得られた熱分解ガスを重質成分と軽質成
分とに分離し、重質成分を前記熱分解槽に還流する還流
槽と、分離された軽質成分中の塩素成分を除去する塩素
固定化槽と、塩素除去後の前記軽質成分を段階的に冷却
・凝縮液化して沸点の異なる油を得る凝縮器と、該凝縮
器において液化しない未凝縮ガスを分離する気液分離器
と、該気液分離器からの軽質油を貯留する油貯留槽とを
具備したことを特徴とする廃プラスチックの油化システ
ム。
1. A pyrolysis tank for converting waste plastic into a pyrolysis gas under heating, separating the obtained pyrolysis gas into a heavy component and a light component, and returning the heavy component to the pyrolysis tank. A reflux tank, a chlorine fixing tank for removing chlorine components in the separated light components, a condenser for cooling and condensing and liquefying the light components after chlorine removal stepwise to obtain oils having different boiling points, An oil liquefaction system for waste plastic, comprising: a gas-liquid separator for separating uncondensed gas that is not liquefied in a condenser; and an oil storage tank for storing light oil from the gas-liquid separator.
【請求項2】請求項1において、前記熱分解槽にて得ら
れた熱分解ガスに同伴するダスト及び該熱分解ガスを前
記還流槽に送る途中で凝縮液化する重質成分を分離して
前記熱分解槽に還流する手段を備えたことを特徴とする
廃プラスチックの油化システム。
2. The method according to claim 1, wherein dust accompanying the pyrolysis gas obtained in the pyrolysis tank and heavy components condensed and liquefied while the pyrolysis gas is sent to the reflux tank are separated. An oil recycling system for waste plastics, comprising a means for refluxing a pyrolysis tank.
【請求項3】請求項1又は2において、前記還流槽に導
入する熱分解ガス温度を調整する手段を備えたことを特
徴とする廃プラスチックの油化システム。
3. The waste plastics liquefaction system according to claim 1, further comprising means for adjusting the temperature of the pyrolysis gas introduced into the reflux tank.
【請求項4】請求項1〜3のいずれかにおいて、前記還
流槽からの軽質ガス成分の一部を前記塩素固定化槽をバ
イパスして前記凝縮器に直接供給する手段と、前記気液
分離器からの未凝縮ガスを貯留する加熱機能付きのガス
貯留槽と、前記油貯留槽の油及び前記ガス貯留槽のガス
を前記熱分解槽の廃プラスチックのガス化分解熱源とし
て搬送する手段とを備えたことを特徴とする廃プラスチ
ックの油化システム。
4. The gas-liquid separation device according to claim 1, wherein a part of the light gas component from the reflux tank is directly supplied to the condenser by bypassing the chlorine fixing tank. A gas storage tank with a heating function for storing uncondensed gas from the vessel, and means for transporting the oil in the oil storage tank and the gas in the gas storage tank as a heat source for gasifying and cracking waste plastic in the pyrolysis tank. An oil recycling system for waste plastic, comprising:
【請求項5】請求項1〜4のいずれかに記載の廃プラス
チック油化システムにおける前記油貯留槽からの液化油
を燃料とした内燃機関と、該内燃機関に付随した発電装
置と、該発電装置の燃焼排ガスを処理する排ガス処理装
置とを具備したことを特徴とする廃プラスチック油化発
電システム。
5. An internal combustion engine using liquefied oil from the oil storage tank as a fuel in the waste plastic liquefaction system according to any one of claims 1 to 4, a power generation device associated with the internal combustion engine, and the power generation A waste plastic oil power generation system, comprising: an exhaust gas treatment device for treating combustion exhaust gas of the device.
JP24013396A 1996-09-11 1996-09-11 Waste plastic liquefaction system and liquefaction power generation system Expired - Fee Related JP3317155B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP24013396A JP3317155B2 (en) 1996-09-11 1996-09-11 Waste plastic liquefaction system and liquefaction power generation system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24013396A JP3317155B2 (en) 1996-09-11 1996-09-11 Waste plastic liquefaction system and liquefaction power generation system

Publications (2)

Publication Number Publication Date
JPH1088148A true JPH1088148A (en) 1998-04-07
JP3317155B2 JP3317155B2 (en) 2002-08-26

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Country Status (1)

Country Link
JP (1) JP3317155B2 (en)

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