JPH1060482A - Perfume carrier - Google Patents
Perfume carrierInfo
- Publication number
- JPH1060482A JPH1060482A JP9166182A JP16618297A JPH1060482A JP H1060482 A JPH1060482 A JP H1060482A JP 9166182 A JP9166182 A JP 9166182A JP 16618297 A JP16618297 A JP 16618297A JP H1060482 A JPH1060482 A JP H1060482A
- Authority
- JP
- Japan
- Prior art keywords
- perfume
- carrier
- fragrance
- carrier according
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002304 perfume Substances 0.000 title claims abstract description 73
- 239000000203 mixture Substances 0.000 claims abstract description 60
- 239000003599 detergent Substances 0.000 claims abstract description 46
- 239000007787 solid Substances 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002562 thickening agent Substances 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 8
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 7
- 239000004927 clay Substances 0.000 claims abstract description 4
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000010452 phosphate Substances 0.000 claims abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract 2
- 239000003205 fragrance Substances 0.000 claims description 28
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 13
- 239000000440 bentonite Substances 0.000 claims description 11
- 229910000278 bentonite Inorganic materials 0.000 claims description 11
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical group O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 11
- 239000010457 zeolite Substances 0.000 claims description 11
- 229910021536 Zeolite Inorganic materials 0.000 claims description 10
- 239000000344 soap Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 6
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 4
- 238000011156 evaluation Methods 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 239000004480 active ingredient Substances 0.000 claims 1
- 230000001953 sensory effect Effects 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000003860 storage Methods 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 11
- 238000009472 formulation Methods 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 229920005862 polyol Polymers 0.000 description 4
- 150000003077 polyols Chemical class 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229940057838 polyethylene glycol 4000 Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0069—Laundry bars
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は洗剤組成物、特に非
石鹸洗剤組成物、に使用のための香料担体、芳香づけ洗
剤のための前記香料担体の使用及び前記香料担体を含む
洗剤組成物に関する。The present invention relates to a perfume carrier for use in detergent compositions, especially non-soap detergent compositions, the use of said perfume carrier for perfuming detergents and a detergent composition comprising said perfume carrier. .
【０００２】[0002]
【発明が解決しようとする課題】ローンドリーバー（ｌ
ａｕｎｄｒｙ ｂａｒ）、好ましくは非石鹸ローンドリ
ーバー、は通例として無機質、界面活性剤（洗剤）及び
香料を含む組成物を高い温度（約９０℃）で混合するこ
とにより製造される。そのような混合物は次に、好都合
には高い温度、例えば約８０℃、で押し出される。SUMMARY OF THE INVENTION A lawn leaver (l)
Aundry bar, preferably a non-soap lawn drinker, is usually prepared by mixing a composition comprising minerals, surfactants (detergents) and fragrance at an elevated temperature (about 90 ° C). Such a mixture is then extruded, conveniently at an elevated temperature, for example at about 80 ° C.
【０００３】香料は消費者の最初の選択を強く決定づけ
るので、それは前記組成物の重要な成分である。ローン
ドリーバーの高い製造温度のために、香料の一部は工場
内で蒸発により失われる。香料の損失を制限する一つの
方法は低い蒸気圧を有する香料の調合材料を使用して香
料を設計することである。この方法は完全に満足できる
ものではない、何故ならばそれは香料の損失を完全に回
避せず、またそれは香料の創造において調香者により使
用される芳香物質の範囲を大幅に制限するからである。[0003] Perfume is an important component of the composition, since it strongly determines the initial choice of the consumer. Due to the high production temperature of the Lone Dreaver, some of the perfume is lost in the factory by evaporation. One way to limit perfume loss is to design the perfume using a perfume formulation that has a low vapor pressure. This method is not entirely satisfactory, because it does not completely avoid the loss of perfume, because it greatly limits the range of fragrances used by perfumers in perfume creation .
【０００４】本発明はその一つの態様において、洗剤組
成物、特に非石鹸洗剤組成物、殊にローンドリーバー、
即ち洗剤組成物の棒、の製造の間の香料の損失を制限す
る、及び／又は洗剤組成物、特に非石鹸洗剤組成物、殊
に洗剤粉末及び前記のローンドリーバーの香料貯蔵安定
度を増加させる香料を含有する担体に関する。この効果
は新しく製造された洗剤製品の、そして又高温と高湿の
下に貯蔵されたローンドリーバーと粉末のより良い芳香
賦与を可能にする。[0004] In one embodiment, the present invention relates to a detergent composition, especially a non-soap detergent composition, especially a lawn leaver,
That is, to limit perfume loss during the manufacture of the bars of the detergent composition, and / or to increase the perfume storage stability of the detergent compositions, especially non-soap detergent compositions, especially detergent powders and the aforementioned lawn leavers. The present invention relates to a carrier containing a flavor. This effect allows better aroma imparting of freshly manufactured detergent products, and also of lawn drier and powder stored under high temperatures and humidity.
【０００５】多くの技術がこれまで織物への芳香賦与を
改良するために用いられた。[0005] A number of techniques have heretofore been used to improve fragrance delivery to textiles.
【０００６】マイクロカプセル化が記載されたことがあ
る（米国特許第４１４５１８４号，米国特許第４２３４
６２７号，米国特許第４０９６０７２号，米国特許第４
４０２８５６号，国際特許出願第９２／１８６０１
号）。これらの技術は納得のゆくものであるが、しかし
コストが高くつく。[0006] Microencapsulation has been described (US Pat. No. 4,145,184, US Pat. No. 4,234,234).
627, U.S. Pat. No. 4,096,072, U.S. Pat.
No. 402856, International Patent Application No. 92/18601
issue). These techniques are acceptable, but costly.
【０００７】香料はまた非水溶性のマトリックスの中に
包含されることもできる（米国特許第４１５２２７２
号）。Fragrances can also be included in a water-insoluble matrix (US Pat. No. 4,152,272).
issue).
【０００８】その他の方法は、シリカ、ゼオライト、粘
土又はポリマーのようないろいろな多孔質支持体に香料
を吸着させることから成る。そのように、米国特許第
４，５３９，１３５号明細書は微粒子の洗剤組成物又は
その洗剤組成物とは別個の洗浄液への添加物と混合して
使用するための香料を含有する担体を開示している。そ
の担体は少なくとも９０重量％の粘土、特にベントナイ
ト、及び／又はゼオライト、及び約５重量％未満の界面
活性洗剤化合物と香料を含む分離している粒子から本質
的に成り、前記の香料は周囲温度で液体であって前記の
粒子に吸着及び／又は吸収されている。さらに、国際特
許出願第９４／２８１０７号明細書は、少なくとも６オ
ングストロームの公称細孔径を有する天然又は合成のゼ
オライト、前記ゼオライト担体の細孔の中に開放され得
るように組み込まれて（閉じ込められて）芳香づけされ
たゼオライトを与える香料及びその中に香料が実質的に
不溶である水溶性組成物から成る前記の芳香づけされた
ゼオライトの上に被覆されたマトリックスから成る固体
の、非水溶性の、多孔質担体から成る粒子の形をした芳
香賦与組成物を開示している。このマトリックスは香料
をゼオライトの細孔内に閉じ込めかつ維持する保護障壁
を形成する。そのマトリックスは重量で０％〜８０％
の、三つより多くのヒドロキシル部分を含む少なくとも
一種の固体ポリオール及び重量で２０％〜１００％の、
その中に香料が実質上不溶でありかつ前記固体ポリオー
ルか実質上可溶である液状ジオール又はポリオールから
成る。それらのポリオール又はジオールはグリセロー
ル、エチレングリコール、及びジクリセロールから成る
群より選択される。Another method consists in adsorbing perfume on various porous supports such as silica, zeolites, clays or polymers. As such, U.S. Pat. No. 4,539,135 discloses a fragrance-containing carrier for use in admixture with a particulate detergent composition or an additive to a cleaning liquid separate from the detergent composition. doing. The carrier consists essentially of at least 90% by weight of clay, especially bentonite, and / or zeolite, and less than about 5% by weight of discrete particles comprising a surfactant detergent compound and a fragrance, wherein the fragrance is at ambient temperature. And is a liquid which is adsorbed and / or absorbed by the particles. Further, WO 94/28107 discloses natural or synthetic zeolites having a nominal pore size of at least 6 Å, incorporated (confined) so that they can be opened into the pores of the zeolite support. A) a solid, water-insoluble substance comprising a matrix coated on said perfumed zeolite, comprising a perfume providing the perfumed zeolite and a water-soluble composition in which the perfume is substantially insoluble; Discloses fragrance-providing compositions in the form of particles comprising a porous carrier. This matrix forms a protective barrier that confines and maintains the perfume within the pores of the zeolite. The matrix is 0% to 80% by weight
At least one solid polyol comprising more than three hydroxyl moieties and from 20% to 100% by weight of
The fragrance is substantially insoluble therein and comprises the solid polyol or a substantially soluble liquid diol or polyol. The polyol or diol is selected from the group consisting of glycerol, ethylene glycol, and dichrycerol.
【０００９】これらの開示はいずれも初めに略述したよ
うな高温における洗剤の製造の間における蒸発による香
料の損失の問題を克服しない。従って、本発明の目的
は、特に高温において、例えば、ローンドリーバー又は
洗剤粉末が製造される及び／又は貯蔵されるときに、香
料の損失が低い、洗剤組成物のための、特に非石鹸洗剤
のための香料担体を提供することである。None of these disclosures overcome the problem of perfume loss due to evaporation during the manufacture of detergents at elevated temperatures as outlined at the outset. It is therefore an object of the present invention to provide a detergent composition, especially a non-soap detergent, which has a low perfume loss, especially at elevated temperatures, for example when a lawn drier or detergent powder is produced and / or stored. To provide a perfume carrier for
【００１０】[0010]
【課題を解決するための手段】本発明は今や従来の技術
の欠点を克服するため廉価にして、特に、簡単な手段を
提供する。The present invention now provides an inexpensive and, in particular, simple means to overcome the disadvantages of the prior art.
【００１１】次の諸態様は本発明を形成する。一態様に
おいて、本発明は、洗剤、特に非石鹸洗剤、例えばロー
ンドリーバー又は洗剤粉末、に導入されるときより良い
芳香賦与を可能にする組成物、特に顆粒状組成物に関す
る。The following aspects form the invention. In one aspect, the present invention relates to compositions, especially granular compositions, that allow for better fragrance imparting when introduced into detergents, especially non-soap detergents, such as lawn leaves or detergent powders.
【００１２】この態様は、固体の非水溶性無機質、即ち
無機担体、香料（組成物）及び水と香料に可溶な香料増
粘剤を含む洗剤組成物、特に非石鹸組成物を包含する。This embodiment encompasses detergent compositions, especially non-soap compositions, comprising a solid, water-insoluble mineral, ie, an inorganic carrier, a perfume (composition) and a perfume thickener soluble in water and perfume.
【００１３】[0013]
【発明の実施の形態】固体担体（「無機質」）の役割は
主として香料／増粘剤混合物を吸着することにより固体
の顆粒を製造することにある。２０〜９０％、好ましく
は５０〜９０％の、洗剤製品に普通使用されている原料
の中より選択されるいずれかの固体担体が通例として存
在する。固体担体の材料はシリカ、ケイ酸塩、特に粘
土、リン酸塩又はそれらの混合物であってよい。好まし
い固体担体はベントナイト、ベントナイト／トリポリリ
ン酸ナトリウム（ＳＴＰＰ）、ゼオライト、ベントナイ
ト／ゼオライト、ベントナイト／シリカから成る。DETAILED DESCRIPTION OF THE INVENTION The role of a solid carrier ("inorganic") is primarily to produce solid granules by adsorbing a perfume / thickener mixture. 20-90%, preferably 50-90%, of any solid carrier selected from the ingredients commonly used in detergent products is typically present. The material of the solid carrier may be silica, silicates, especially clays, phosphates or mixtures thereof. Preferred solid supports consist of bentonite, bentonite / sodium tripolyphosphate (STPP), zeolite, bentonite / zeolite, bentonite / silica.
【００１４】用語「ゼオライト」はゼオライト構造を有
する、例えば、一般式The term "zeolite" has a zeolite structure, for example, of the general formula
【化１】 （Ｎａ2 Ｏ）ｘ．Ａｌ2 Ｏ3.（ＳｉＯ2 ）ｙ．ｚＨ2 Ｏ を有する、天然または合成起源のいずれかの結晶性アル
ミノケイ酸塩のことを言う。好ましいゼオライトはＤｅ
ｇｕｓｓａにより商品名ＨＡＢ Ａ４０で製造されてい
るようなＺｅｏｌｉｔｅ Ａである。Embedded image (Na 2 O) x. Al 2 O 3. (SiO 2 ) y. zH having 2 O, it refers to any crystalline aluminosilicate of natural or synthetic origin. The preferred zeolite is De
Zeolite A as manufactured by G. gussa under the trade name HAB A40.
【００１５】ベントナイトは、例えば、シュドヘミー
（Ｓｕｅｄ Ｈｅｍｉｅ）により商標Ｌａｕｎｄｒｏｓ
−ｉｌ ＤＧＡで、又はＢｅｎｔｏｎ Ｃｌａｙ Ｃｏ
ｍｐａｎｙにより商標 Ｍｉｎｅｒａｌ Ｃｏｌｌｏ
ｉｄで販売されているような粘土である。Bentonite can be obtained, for example, from Sued Hemie under the trademark Laundros.
-Il DGA or Benton Clay Co
mpany Trademark Mineral Collo
It is a clay as sold by id.
【００１６】シリカは、例えば、Ｄｅｇｕｓｓａにより
商標Ｓｕｐｅｒｎａｔ ２２Ｓで製造されている。Silica is manufactured, for example, by Degussa under the trademark Supernat 22S.
【００１７】トリポリリン酸ナトリウムは洗剤製品にお
いて普通の原料であり、その目的は主としてカルシウム
イオンを錯体にすることである。適当な材料はＡｌｂｒ
ｉ−ｇｈｔ ＆ Ｗｉｌｓｏｎにより商標Ｅｍｐｉｐｈ
ｏｓ ＳＴＰＰで製造されている。[0017] Sodium tripolyphosphate is a common raw material in detergent products and its purpose is mainly to complex calcium ions. A suitable material is Albr
The trademark Empiph by i-ght & Wilson
os manufactured by STPP.
【００１８】用語「香料」は合成及び／又は天然起源の
すべての香料材料の必要とされた混合物を表し、それは
石鹸棒又は洗剤に芳香をつけるために適するものであ
る。それはこの目的に向けられた（少量の）普通の溶媒
及び希釈剤を含むことができる。プロピレングリコール
は、そのような溶媒の一例である。The term "perfume" refers to the required mixture of all perfume materials of synthetic and / or natural origin, which are suitable for perfuming soap bars or detergents. It can contain (small) common solvents and diluents intended for this purpose. Propylene glycol is an example of such a solvent.
【００１９】用語「香料組成物」は、本発明に関連して
用いられるとき、香料材料のそのような溶液を意味す
る。The term "perfume composition" as used in connection with the present invention means such a solution of a perfume material.
【００２０】本発明の文脈において、「香料」と「香料
組成物」は互換性あるものとして用いられるであろう。In the context of the present invention, "perfume" and "perfume composition" will be used interchangeably.
【００２１】香料増粘剤の役割は、その蒸発を減少させ
てより良い安定性を与える程度に香料の粘度を増すこと
である。１〜６０％のポリエチレングリコール、特に４
００より２００００までの、より好ましくは２０００と
１００００の間の、分子量を有するもの、がこの目的に
使用されることができる。The role of the perfume thickener is to increase the viscosity of the perfume to a degree that reduces its evaporation and provides better stability. 1-60% polyethylene glycol, especially 4
Those having a molecular weight between 00 and 20000, more preferably between 2000 and 10000, can be used for this purpose.
【００２２】香料担体は香料増粘剤及び香料の混合物を
固体担体上に、造粒機の中で、吹きつけること、又は香
料増粘剤／香料混合物を固体担体と単に混合することに
より顆粒の形に調製されることが好ましい。The fragrance carrier is formed by spraying the mixture of fragrance thickener and fragrance onto the solid carrier in a granulator, or simply mixing the fragrance thickener / perfume mixture with the solid carrier. It is preferably prepared in a form.
【００２３】香料担体内の諸成分の適当な濃度（％ ｗ
／ｗ）は次の通りである。Suitable concentrations (% w) of the components in the perfume carrier
/ W) is as follows.
【表１】 固体担体 ２０−９０ ５０−９０ ４０−６０ 増粘剤 ０．１−２０ ０．２−５ ０．５−３ 香料 １−６０ ５−５０ １０−４０Table 1 Solid carrier 20-90 50-90 40-60 Thickener 0.1-20 0.2-5 0.5-3 Fragrance 1-60 5-50 10-40
【００２４】新規な香料担体の有効量、特に約０．５−
２０％、は最終製品に存在すべきであり、その際最終製
品内の香料の濃度は好都合には０．１〜約４％、好まし
くは０．１〜約２％、であるべきである。An effective amount of the novel perfume carrier, especially about 0.5-
20% should be present in the final product, wherein the concentration of perfume in the final product should be conveniently between 0.1 and about 4%, preferably between 0.1 and about 2%.
【００２５】[0025]
【実施例】例 １ 次の組成の香料担体が調製された。EXAMPLES Example 1 A perfume carrier of the following composition was prepared.
【表２】 [Table 2]
【００２６】Ｂ２は最終組成物において０．１５％の香
料の水準に達するようにローンドリーバー及び洗剤粉末
に添加され、そしてローンドリーバーと洗剤粉末がそれ
ぞれ製造された。B2 was added to the lawn leaver and detergent powder to reach a perfume level of 0.15% in the final composition, and a lawn drawer and detergent powder were produced, respectively.
【００２７】製品の貯蔵安定性が、同じ配合の製品であ
るが香料は０．２％の水準（Ｂ１）で洗剤製品中に導入
され、そして室温に貯蔵されたものに対して評価され
た。Ｂ２の製品は４３℃（粉末につき）及び５５℃（ロ
ーンドリーバーにつき）で２週間貯蔵された。これらの
製品はそれから匂いを嗅ぐことにより評価された。次の
結果が得られた。The storage stability of the product was evaluated against a product of the same formulation, but the perfume was introduced into the detergent product at the 0.2% level (B1) and stored at room temperature. The B2 product was stored at 43 ° C. (per powder) and 55 ° C. (per lawn drinker) for 2 weeks. These products were then evaluated by smelling. The following results were obtained.
【００２８】[0028]
【表３】配合 安定性 安定性 ローンドリーバー 洗剤粉末 ０．２％の保護されぬ Ｂ１ 良好 良好 香料 ０．１５％の保護された Ｂ２ Ｂ１と同等 Ｂ１と同等 香料Table 3 Formulation stability Stability Lawn Reaver detergent powder 0.2% unprotected B1 good good fragrance 0.15% protected B2 equivalent to B1 equivalent to B1 fragrance
【００２９】これらの結果から、本発明の香料担体の使
用は、その材料製品が比較的高い温度に貯蔵されるとき
香料の安定性を増加させる、即ち、香料の損失が比較的
高い温度において全くないか又は殆どないことが結論さ
れることができる。例 ２ 次の組成の香料担体顆粒が調製された。From these results, the use of the perfume carrier of the present invention increases the perfume stability when the material product is stored at a relatively high temperature, ie, the perfume loss is quite high at relatively high temperatures. It can be concluded that there is none or little. Example 2 A perfume carrier granule of the following composition was prepared.
【表４】成分 Ｒ１ ベントナイト １０ ＳＴＰＰ ７０ ポリエチレングリコール ４０００ １ 香料 １９Table 4 Component R1 Bentonite 10 STPP 70 Polyethylene glycol 4000 1 Fragrance 19
【００３０】これらの顆粒は最終製品、即ち、保護され
た香料を含む製品、において０．１５％の香料濃度に達
するように洗剤粉末に導入された。下記に示されるよう
ないろいろな条件の下に香料の性能がベンチマーク、即
ち、０．２％の保護されない香料を含む標準、に対して
匂いを嗅ぐことにより評価された。These granules were introduced into the detergent powder to reach a perfume concentration of 0.15% in the final product, ie the product containing the protected perfume. The perfume performance under various conditions as shown below was evaluated by smelling against a benchmark, a standard containing 0.2% unprotected perfume.
【００３１】評価は１０人の熟練した委員により行われ
た。それらの製品は０より４までの尺度で評価された
が、０は最悪のそして４は最良の得点であった。The evaluation was performed by 10 skilled members. The products were rated on a scale from 0 to 4, with 0 being the worst and 4 being the best score.
【００３２】次の結果が得られた。The following results were obtained.
【表５】配合 リンス後 洗濯中 純品 ０．２％の ベンチマーク ３ ３ ３ 保護されぬ香料 ０．１５％の Ｒ１ ３．２５ ３．２５ ３．４０ 保護された香料TABLE 5 benchmarks 3 of pure 0.2% in after washing formulation rinsing 3 3 protected unexpected flavor 0.15% R1 3.25 3.25 3.40 Protected perfume
【００３３】これらの結果は、保護された香料がより良
好な性能を有していたことを示す。These results show that the protected perfume had better performance.
Claims (14)
及び水と香料に可溶な香料増粘剤を含む、洗剤組成物、
特に非石鹸洗剤組成物、に使用のため適当な香料担体。1. A detergent composition comprising a solid water-insoluble inorganic carrier, a perfume composition and a perfume thickener soluble in water and perfume.
A perfume carrier suitable especially for use in non-soap detergent compositions.
に粘土、リン酸塩又はいずれかのそれらの混合物である
請求項１に記載の香料担体。2. A perfume carrier according to claim 1, wherein the material of the solid carrier is silica, silicate, especially clay, phosphate or any mixture thereof.
ナイトとゼオライトの混合物、又はベントナイトとトリ
ポリリン酸ナトリウムの混合物、又はベントナイトとシ
リカの混合物である請求項１又は２に記載の香料担体。3. The fragrance carrier according to claim 1, wherein the material of the solid carrier is bentonite, a mixture of bentonite and zeolite, a mixture of bentonite and sodium tripolyphosphate, or a mixture of bentonite and silica.
価において活性な成分を含む請求項１より３までのいず
れか１項に記載の香料担体。4. The fragrance carrier according to claim 1, wherein the fragrance contains an active ingredient in sensory evaluation of natural and / or synthetic origin.
量を有するポリエチレングリコールである請求項１より
４までのいずれか１項に記載の香料担体。5. The perfume carrier according to claim 1, wherein the perfume thickener is polyethylene glycol having a molecular weight of 400 to 20,000.
０〜９０％、の量に存在する請求項１より５までのいず
れか１項に記載の香料担体。6. The solid carrier comprises 20-90%, preferably 5%.
A fragrance carrier according to any one of the preceding claims, which is present in an amount of 0-90%.
は０．２〜５％の量に存在する請求項１より６までのい
ずれか１項に記載の香料担体。7. A perfume carrier according to any one of claims 1 to 6, wherein the perfume thickener is present in an amount of 0.1 to 20%, preferably 0.2 to 5%.
〜５０％、最も好ましくは１０〜４０％、の量に存在す
る請求項１より７までのいずれか１項に記載の香料担
体。8. The perfume composition comprises 1 to 60%, preferably 5%.
A fragrance carrier according to any one of the preceding claims, wherein the fragrance carrier is present in an amount of ５０50%, most preferably 10-40%.
ドリーバーの形をしている請求項１より８までのいずれ
か１項に記載の香料担体。9. A perfume carrier according to any one of claims 1 to 8, wherein the detergent composition is in the form of a stick or a powder, in particular a lawn leaver.
体上に、好ましくは造粒機の中で、吹きつけること、ま
たは香料増粘剤及び香料の混合物を固体担体と混合する
ことから成る方法により得られる請求項１より９までの
いずれか１項に記載の香料担体。10. Spraying the mixture of perfume thickener and perfume onto a solid carrier, preferably in a granulator, or mixing the mixture of perfume thickener and perfume with the solid carrier. The fragrance carrier according to any one of claims 1 to 9, which is obtained by a method.
％〜約２０％の請求項１より１０までのいずれか１項に
記載の香料担体を含む洗剤組成物。11. About 4% to about 80% detergent and about 0.5%.
A detergent composition comprising from about 10% to about 20% of a fragrance carrier according to any one of claims 1 to 10.
１〜約２％の、香料濃度を有する請求項１１に記載の洗
剤組成物。12. About 0.1 to 4%, preferably about 0.1%.
The detergent composition according to claim 11, having a perfume concentration of 1 to about 2%.
いずれか１項に記載の香料担体の混合、及び ｂ）そのような混合物の押し出し、から成る方法により
得られる請求項１１または１２に記載の組成を有するロ
ーンドリーバーの形の洗剤組成物。13. The following steps: a) mixing the usual components of the detergent composition with the fragrance carrier according to any one of claims 1 to 10, and b) extruding such a mixture. 13. Detergent composition in the form of a lawn drawer having the composition according to claim 11 or 12, obtained by the method.
ための、特に最終製品において約０．１〜約４％の、好
ましくは約０．１〜約２％の、香料濃度に達するよう
な、請求項１より１０までのいずれか１項に記載の香料
担体の使用。14. A perfume concentration of about 0.1% to about 4%, preferably about 0.1% to about 2%, for fragrance detergents, especially in the form of bars or powders, in the final product. Use of a fragrance carrier according to any one of claims 1 to 10, as such.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96110135 | 1996-06-24 | ||
| AT961101359 | 1996-06-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH1060482A true JPH1060482A (en) | 1998-03-03 |
Family
ID=8222925
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9166182A Pending JPH1060482A (en) | 1996-06-24 | 1997-06-23 | Perfume carrier |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0816484B1 (en) |
| JP (1) | JPH1060482A (en) |
| AR (1) | AR007449A1 (en) |
| AU (1) | AU728170B2 (en) |
| BR (1) | BR9703689A (en) |
| DE (1) | DE69734043T2 (en) |
| ES (1) | ES2245788T3 (en) |
| ID (1) | ID17072A (en) |
| MX (1) | MX9704712A (en) |
| SG (1) | SG55330A1 (en) |
| ZA (1) | ZA975339B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005179396A (en) * | 2003-12-16 | 2005-07-07 | Lion Corp | Perfume composition enhanced in preservation stability, detergent composition and stabilizing method of perfume |
| JP2005330362A (en) * | 2004-05-19 | 2005-12-02 | Kao Corp | Perfume particle |
| WO2011073139A1 (en) | 2009-12-16 | 2011-06-23 | Unilever Plc | Method of enhancing perfume retention during storage or of enhancing perfume bloom using low total fatty matter extruded bars having starch polyol structuring system |
| US7981852B2 (en) | 2009-12-16 | 2011-07-19 | Conopco, Inc. | Method of enhancing perfume retention during storage using low total fatty matter extruded bars having starch polyol structuring system |
| US7989410B2 (en) | 2009-12-16 | 2011-08-02 | Conopco, Inc. | Method of enhancing perfume bloom in extruded diluted bars having low total fatty matter and using starch polyol structuring system |
| JP2012504158A (en) * | 2008-09-30 | 2012-02-16 | イントリンシツク・マテリアルズ・グローバル・リミテツド | Porous material |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999051715A1 (en) * | 1998-04-06 | 1999-10-14 | The Procter & Gamble Company | Electrostatically coated non-particulate detergent product |
| US6498135B1 (en) * | 1998-04-06 | 2002-12-24 | Procter & Gamble Company | Process for producing electrostatically coated non-particulate detergent product |
| US6689740B1 (en) | 1999-06-15 | 2004-02-10 | Givaudan Sa | Method for preparing fragrance products |
| EP1061124A1 (en) * | 1999-06-15 | 2000-12-20 | Givaudan SA | Method for preparing fragrance products |
| EP1111034A1 (en) * | 1999-12-22 | 2001-06-27 | The Procter & Gamble Company | Laundry and cleaning and/or fabric care compositions |
| EP1190725A3 (en) * | 2000-09-25 | 2003-01-29 | Givaudan SA | Process for maintaining fragrance perception in the presence of an absorbent material |
| EP1383858A1 (en) | 2001-05-04 | 2004-01-28 | The Procter & Gamble Company | Dryer-added fabric softening articles and methods |
| WO2002090481A1 (en) * | 2001-05-04 | 2002-11-14 | The Procter & Gamble Company | Compositions and articles for effective deposition of perfume |
| EP1463792B1 (en) | 2001-09-06 | 2008-12-03 | The Procter & Gamble Company | Scented candles |
| DE102005042053A1 (en) * | 2005-09-02 | 2007-03-08 | Henkel Kgaa | Zeolite and perfume containing particles with improved fragrance properties |
| DE102005060006B4 (en) * | 2005-12-13 | 2016-12-29 | Henkel Ag & Co. Kgaa | Safe solid-state spray perfuming |
| CN103249826B (en) | 2010-12-23 | 2015-07-15 | 西姆莱斯有限公司 | Fragrance granules for detergents |
| CN111133088A (en) | 2017-09-22 | 2020-05-08 | 西姆莱斯有限公司 | Active substance sheet |
| WO2021156213A1 (en) | 2020-02-04 | 2021-08-12 | Clariant International Ltd | Lipid nanoparticles for delayed delivery of fragrance with enhanced water solubility, their preparation and use |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3016170A1 (en) * | 1980-04-26 | 1981-10-29 | Bayer Ag, 5090 Leverkusen | MICROCAPSULES WITH A DEFINED OPENING TEMPERATURE, METHOD FOR THE PRODUCTION AND USE THEREOF |
| US4536315A (en) * | 1983-06-01 | 1985-08-20 | Colgate Palmolive Co. | Perfume-containing carrier having surface-modified particles for laundry composition |
| US4539135A (en) * | 1983-06-01 | 1985-09-03 | Colgate Palmolive Co. | Perfume-containing carrier for laundry compositions |
| JPH01101399A (en) * | 1987-10-14 | 1989-04-19 | Shiseido Co Ltd | Solid detergent |
| EP0523287A1 (en) * | 1991-07-18 | 1993-01-20 | The Procter & Gamble Company | Perfume additives for fabric-softening compositions |
| TR28670A (en) * | 1993-06-02 | 1996-12-17 | Procter & Gamble | Perfume release system containing zeolites. |
-
1997
- 1997-04-12 ID IDP972148A patent/ID17072A/en unknown
- 1997-06-17 SG SG1997002071A patent/SG55330A1/en unknown
- 1997-06-17 ZA ZA975339A patent/ZA975339B/en unknown
- 1997-06-18 ES ES97109905T patent/ES2245788T3/en not_active Expired - Lifetime
- 1997-06-18 DE DE69734043T patent/DE69734043T2/en not_active Expired - Fee Related
- 1997-06-18 EP EP97109905A patent/EP0816484B1/en not_active Expired - Lifetime
- 1997-06-20 AU AU26166/97A patent/AU728170B2/en not_active Ceased
- 1997-06-23 MX MX9704712A patent/MX9704712A/en not_active Application Discontinuation
- 1997-06-23 JP JP9166182A patent/JPH1060482A/en active Pending
- 1997-06-23 AR ARP970102747A patent/AR007449A1/en unknown
- 1997-06-24 BR BR9703689A patent/BR9703689A/en active Search and Examination
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005179396A (en) * | 2003-12-16 | 2005-07-07 | Lion Corp | Perfume composition enhanced in preservation stability, detergent composition and stabilizing method of perfume |
| JP4509547B2 (en) * | 2003-12-16 | 2010-07-21 | ライオン株式会社 | Fragrance composition having improved storage stability, detergent composition, and method for stabilizing fragrance |
| JP2005330362A (en) * | 2004-05-19 | 2005-12-02 | Kao Corp | Perfume particle |
| JP2012504158A (en) * | 2008-09-30 | 2012-02-16 | イントリンシツク・マテリアルズ・グローバル・リミテツド | Porous material |
| US9243144B2 (en) | 2008-09-30 | 2016-01-26 | Psimedica Limited | Composition containing loaded and capped porous silica particles |
| WO2011073139A1 (en) | 2009-12-16 | 2011-06-23 | Unilever Plc | Method of enhancing perfume retention during storage or of enhancing perfume bloom using low total fatty matter extruded bars having starch polyol structuring system |
| US7981852B2 (en) | 2009-12-16 | 2011-07-19 | Conopco, Inc. | Method of enhancing perfume retention during storage using low total fatty matter extruded bars having starch polyol structuring system |
| US7989410B2 (en) | 2009-12-16 | 2011-08-02 | Conopco, Inc. | Method of enhancing perfume bloom in extruded diluted bars having low total fatty matter and using starch polyol structuring system |
Also Published As
| Publication number | Publication date |
|---|---|
| BR9703689A (en) | 1998-10-27 |
| MX9704712A (en) | 1997-12-31 |
| DE69734043T2 (en) | 2006-06-08 |
| ZA975339B (en) | 1998-09-10 |
| AU2616697A (en) | 1998-01-15 |
| EP0816484B1 (en) | 2005-08-24 |
| ES2245788T3 (en) | 2006-01-16 |
| ID17072A (en) | 1997-06-23 |
| DE69734043D1 (en) | 2005-09-29 |
| EP0816484A2 (en) | 1998-01-07 |
| EP0816484A3 (en) | 1999-01-27 |
| SG55330A1 (en) | 1998-12-21 |
| AU728170B2 (en) | 2001-01-04 |
| AR007449A1 (en) | 1999-10-27 |
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