CN1169467A - Perfume delivery system - Google Patents
Perfume delivery system Download PDFInfo
- Publication number
- CN1169467A CN1169467A CN 97105588 CN97105588A CN1169467A CN 1169467 A CN1169467 A CN 1169467A CN 97105588 CN97105588 CN 97105588 CN 97105588 A CN97105588 A CN 97105588A CN 1169467 A CN1169467 A CN 1169467A
- Authority
- CN
- China
- Prior art keywords
- carrier
- perfume
- spices
- mixture
- fragrance carrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002304 perfume Substances 0.000 title claims abstract description 27
- 239000000203 mixture Substances 0.000 claims abstract description 63
- 239000007787 solid Substances 0.000 claims abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003599 detergent Substances 0.000 claims abstract description 13
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 7
- 239000004927 clay Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 3
- 235000013599 spices Nutrition 0.000 claims description 50
- 239000003205 fragrance Substances 0.000 claims description 23
- 239000000344 soap Substances 0.000 claims description 21
- 238000005406 washing Methods 0.000 claims description 19
- 229910021536 Zeolite Inorganic materials 0.000 claims description 17
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 17
- 239000010457 zeolite Substances 0.000 claims description 17
- 238000004140 cleaning Methods 0.000 claims description 15
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 11
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 7
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 6
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 229960001866 silicon dioxide Drugs 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 6
- 239000000796 flavoring agent Substances 0.000 claims description 5
- 235000019634 flavors Nutrition 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 150000003016 phosphoric acids Chemical class 0.000 claims description 2
- -1 polyoxyethylene Polymers 0.000 claims description 2
- 239000012876 carrier material Substances 0.000 claims 2
- 230000008961 swelling Effects 0.000 claims 1
- 239000002562 thickening agent Substances 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 9
- 239000002245 particle Substances 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- TZBAVQKIEKDGFH-UHFFFAOYSA-N n-[2-(diethylamino)ethyl]-1-benzothiophene-2-carboxamide;hydrochloride Chemical compound [Cl-].C1=CC=C2SC(C(=O)NCC[NH+](CC)CC)=CC2=C1 TZBAVQKIEKDGFH-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The perfume carrier comprises a solid water-insoluble inorganic carrier, a perfume composition and a perfume thickener soluble in water and a perfume, and is suitable for use in a detergent composition, especially a nonsoap composition. The material of the solid inorganic carrier is silica, a silicate, especially a clay, a phosphate or a mixture of any thereof. The perfume thickener is preferably a polyethylene glycol having 400-20,000 molecular weight.
Description
The present invention relates to be used for detergent composition, particularly relate to fragrance carrier in the detergent composition of non-soap, fragrance carrier at the purposes of perfuming detergent and the detergent composition that contains fragrance carrier.
Washing soap, preferred non-soap washing soap normally prepare by mixing the component that contains mineral, tensio-active agent (washing composition) and spices down at high temperature (about 90 ℃).Then this class mixture is extruded under high temperature (80 ℃ according to appointment) easily.
Spices is the main component of composition, because it has determined human consumer's first to select consumingly.Because high temperature prepares washing soap, part spices is owing to the evaporation in factory is lost.A kind of method that limits perfume loss is the spices that the perfume base with low-steam pressure is used in design.This method is not satisfied fully, because it does not avoid perfume loss fully, and it has limited the scale that perfumer is produced aromatic raw material used in the spices to a great extent.
One aspect of the present invention relates to is making detergent composition, particularly in the manufacturing of nonsoap detergent composition, especially the soap bar of doing washing, in the detergent composition soap bar, the carrier that contains spices of restriction perfume loss, and/or the spices package stability of raising detergent composition, particularly nonsoap detergent composition, especially washing powder and laundry soap bar noted earlier.This effect makes freshly prepd cleaning product and the laundry soap bar of storing in high temperature and high humidity and powder can carry out spices better and carries.
Adopted many technology to improve the conveying of spices already to fabric:
Described already microcosmic sealing (micro encapsulation) (USP4145184, USP4234627, USP4096072, USP4402856, WO92/18601).This technology is gratifying, but cost is higher.
In water-insoluble matrix, also can add spices (USP4152272).
Other method comprises spices is adsorbed on the various porous matrixes (as silicon-dioxide, zeolite, clay or polymkeric substance).Therefore, USP4,539,135 disclose carrier that contains spices or the additive a kind of and the isolating washing lotion of cleaning composition that is used for the admixture of particulate state cleaning composition.This carrier is made up of discrete particles that contains 90% (weight) clay, especially wilkinite and/or zeolite and the surfactant compounds and the spices that are less than 5% (weight) substantially at least.This spices at room temperature is in a liquid state, and is adsorbed and/or is absorbed on the said particle.In addition, WO94/28107 discloses a kind of granular spices delivering composition that is, that this particle comprises is solid-state, water-fast porous support, spices and matrix, wherein porous support comprises having the natural or synthetic zeolite of 6A nominal pore size at least, spices is coated on the described zeolite that spices arranged with the zeolite that provides spices and matrix in the hole of described Zeolite support in conjunction with (holding back) releasedly, this zeolite comprises a kind of water miscible composition, and spices is largely insoluble in said composition.This matrix has formed the protective barrier of spices being held back and remaining in the zeolite pore.This matrix comprises the liquid dihydric alcohols of at least a solid polyalcohol (containing the hydroxyl more than 3) of 0%～80% (weight) and 20%～100% (weight) or polyvalent alcohol (in liquid binary or polyvalent alcohol spices be insoluble basically and solid polyalcohol is dissolved basically).Polyvalent alcohol or dibasic alcohol are selected from glycerine, ethylene glycol and Glycerol dimer.
These two kinds of open source literatures all do not overcome as the described problem that causes perfume loss in the production of cleaning composition under the high temperature because of evaporation of beginning in the literary composition.Therefore, the purpose of this invention is to provide that cleaning composition is used, especially be that non-soaping washed the fragrance carrier that composition is used, this carrier has low perfume loss (especially under the high temperature), as when producing and/or store laundry soap bar or washing powder.
The present invention now provide a kind of cheapness and, particularly, simply overcome the method for shortcoming of the prior art.
Constitute the present invention by following aspect.
On the one hand, the present invention relates to composition, granular composition particularly, said composition is when adding washing composition, particularly nonsoap detergent, as in laundry soap bar or the washing powder time, can provide good spices to carry.
This respect comprises the fragrance carrier that is applicable in the cleaning composition (being that non-soaping washed composition especially), and this carrier comprises the insoluble mineral of solid water (being inorganic carrier), a kind of spices (composition) and water and dissolves in the perfume tackifier of spices.
The effect of solid carrier (" mineral ") mainly is so that solid particles to be provided by absorption spices/tackifier mixture.Usually have 20～90%, preferred about 50～90% any solid carrier that is selected from the raw material that is usually used in the cleaning product.Solid carrier can be silicon-dioxide, silicate (especially clay), phosphoric acid salt or its any mixture.Preferred solid carrier comprises wilkinite, wilkinite/tripoly phosphate sodium STPP (STPP), zeolite, wilkinite/zeolite, wilkinite/silicon-dioxide.
Term " zeolite " refers to have the manosil AS material of the natural or any lenticular of synthetic of zeolite structured (as having following general formula), and this general formula is as follows:
(Na
2O)
x·Al
2O
3·(SiO
2)
y·zH
2O
Preferred zeolite is by the zeolite A (Zeolite A) of Degussa with name of an article HAB A40 preparation.
Wilkinite is a kind of clay, as those by Sud Chemie with trade name Laundrosil DGA or by Beaton Clay Company with trade name Mineral Colloid product sold.
Silicon-dioxide is produced with trade mark Supemat 22S by Degussa.
Tripoly phosphate sodium STPP is the raw material that is usually used in the cleaning product, and its purpose mainly is complexing Ca
2+Suitable material is by Albright ﹠amp; Wilson produces with trade mark Empiphos STPP.
The required mixture of any synthetic and/or natural perfume of term " spices " representative, it is applicable to perfuming soap bar and washing composition.It can contain solvent and the thinner that (on a small quantity) is used for this purpose.Propylene glycol is an example of this kind solvent.
The term that the present invention uses " flavor compositions " means the solution of this class spices.
Among the present invention, " spices " and " flavor compositions " can exchange use.
The effect of perfume tackifier is that the viscosity of spices is brought up to the degree that can reduce the evaporation and better stability is provided.1%～60% polyoxyethylene glycol, particularly molecular weight are 400～20000, are more preferably 2000～10000, can be used for this purpose.
Fragrance carrier preferably be sprayed on the solid carrier in the granulator by mixture with perfume tackifier and spices or by with perfume tackifier/spice mixt with simple mixing of solid-state carrier with granular preparation.
The suitable concn of the component in the fragrance carrier (% w/w) is as follows:
Solid carrier 20～90 50～90 40～60
Tackifier 0.1～20 0.2～5 0.5～3
Spices 1～60 5～50 10～40
The significant quantity of this new fragrance carrier (particularly about 0.5～20%) should be present in the finished product, and the concentration of perfume in the finished product advantageously should be 0.1%～4%, and preferred 0.1～2%.
Embodiment 1
The fragrance carrier of preparation following ingredients
Composition B2
Wilkinite 10
Zeolite 70
Macrogol 4000 1
Spices 19
B2 is joined in washing soap bar composition and the washing powder composition so that the flavour content in the final composition is 0.15%, and preparation laundry soap bar and washing powder respectively.
The stability of product is to assess by comparing with the product of same composition, but latter's spices is to add and store at room temperature with the content of 0.2% (B1).The product that contains B2 was stored for two weeks down at 43 ℃ (for powder) and 55 ℃ (for laundry soap bars).Then by assessing with nasil.Find following result:
Formulation stability stability
Laundry soap bar washing powder
Contain 0.2% unshielded spices B1 carefully
It is quite suitable with B1 to contain 0.15% shielded spices B2 and B1
Can reach a conclusion from these results, use spices of the present invention when at high temperature storing product, to improve the stability of spices, the loss of spices does not promptly at high temperature take place hardly.
Embodiment 2
The fragrance carrier particle that preparation has following component:
Composition R1
Wilkinite 10
STPP 70
Macrogol 4000 1
Spices 19
Particle added washing powder so that the finished product, the concentration of perfume that promptly contains in the product that is protected spices is 0.15%.Fragrance performance under the different condition below by with leveling base be that 0.2% the spices that is not protected of containing of standard is relatively assessed with nasil.
This assessment is that the group that is trained by 10 people carries out.Product is with 0～4 grade of assessment, and the 0th, the poorest rank, the 4th, best.
The result who obtains is as follows:
Purified in the prescription rinsing after scouring
0.2% the non-spices standard substance 333 that is protected
0.15% quilt protects spices R1 3.25 3.25 3.40
These results show that the spices that is protected has better properties.
Claims (14)
1. one kind is applicable to cleaning composition, is the fragrance carrier in the cleaning composition of non-soap especially, contains solid-state water-insoluble mineral carrier, flavor compositions, water and dissolves in the perfume tackifier of spices.
2. the fragrance carrier of claim 1, wherein the solid carrier material is silicon-dioxide, silicate (especially clay), phosphoric acid salt or its mixture.
3. claim 1 or 2 fragrance carrier, wherein the solid carrier material is mixture or the mixture of wilkinite and tripoly phosphate sodium STPP or the mixture of swelling and silicon-dioxide of wilkinite, wilkinite and zeolite.
4. each fragrance carrier among the claim 1-3, wherein spices contains natural and/or the organoleptic activeconstituents of synthetic.
5. each fragrance carrier among the claim 1-4, wherein perfume tackifier is that molecular weight is 400～20,000 polyoxyethylene glycol.
6. each fragrance carrier among the claim 1-5, wherein solid carrier is with 20～90%, and preferred 50～90% amount exists.
7. each fragrance carrier among the claim 1-6, wherein perfume tackifier exists with about amount of 0.1～20%, preferred 0.2～5%.
8. each fragrance carrier among the claim 1-7, wherein flavor compositions is with 1～60%, and is preferred 5～50%, and most preferably 10～40% amount exists.
9. each fragrance carrier among the claim 1-8, wherein cleaning composition is soap bar or Powdered, particularly is the washing soap strip.
10. each fragrance carrier among the claim 1-9 comprises that from a kind of mixture with perfume tackifier and spices is sprayed on the solid carrier, preferably the method in granulator or with the mixture of perfume tackifier and spices and solid carrier blended method mutually.
11. a cleaning composition contains among the claim 1-10 of have an appointment 4～80% washing composition and about 0.5～20% each fragrance carrier.
12. the cleaning composition of a claim 11 has about 0.1～4% concentration of perfume, and especially about 0.1～2%.
13. a cleaning composition that is the washing soap strip that contains the composition of claim 11 or 12, by following method preparation, this method comprises the following steps:
A) each fragrance carrier among the component of cleaning composition commonly used and the claim 1-10 is mixed mutually, and
B) extrude this mixture.
14. each the application of material carrier in perfuming detergent among the claim 1-10, this perfuming detergent is soap bar or Powdered, and especially making the concentration of perfume in the finished product is 0.1～4%, especially about 0.1～2%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97105588 CN1169467A (en) | 1996-06-24 | 1997-06-19 | Perfume delivery system |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96110135.9 | 1996-06-24 | ||
| CN 97105588 CN1169467A (en) | 1996-06-24 | 1997-06-19 | Perfume delivery system |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1169467A true CN1169467A (en) | 1998-01-07 |
Family
ID=5167918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 97105588 Pending CN1169467A (en) | 1996-06-24 | 1997-06-19 | Perfume delivery system |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1169467A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753898A (en) * | 2017-01-06 | 2017-05-31 | 南京福科帝生物科技有限公司 | A kind of odor prolongation clothes washing compositions of additives containing porous-starch and preparation method thereof |
-
1997
- 1997-06-19 CN CN 97105588 patent/CN1169467A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753898A (en) * | 2017-01-06 | 2017-05-31 | 南京福科帝生物科技有限公司 | A kind of odor prolongation clothes washing compositions of additives containing porous-starch and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |