JPH104919A - Food and drink and its production - Google Patents

Food and drink and its production

Info

Publication number
JPH104919A
JPH104919A JP8162020A JP16202096A JPH104919A JP H104919 A JPH104919 A JP H104919A JP 8162020 A JP8162020 A JP 8162020A JP 16202096 A JP16202096 A JP 16202096A JP H104919 A JPH104919 A JP H104919A
Authority
JP
Japan
Prior art keywords
cyclodextrin
caffeine
catechins
activated carbon
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP8162020A
Other languages
Japanese (ja)
Other versions
JP3259758B2 (en
Inventor
Takashi Yumoto
本 隆 湯
Sumihisa Iida
田 純 久 飯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyo Sugar Refining Co Ltd
Original Assignee
Toyo Sugar Refining Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Sugar Refining Co Ltd filed Critical Toyo Sugar Refining Co Ltd
Priority to JP16202096A priority Critical patent/JP3259758B2/en
Publication of JPH104919A publication Critical patent/JPH104919A/en
Application granted granted Critical
Publication of JP3259758B2 publication Critical patent/JP3259758B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Tea And Coffee (AREA)
  • Non-Alcoholic Beverages (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a food and drink hardly having a bitter and astringent taste, capable of ingesting a large amount thereof and excellent in efficacy of a medicine by including catechins, caffeine and a cyclodextrin in the specific ratio. SOLUTION: This food and drink include catechins containing a proanthocyanidin polymer, caffeine and a cyclodextrin such as β-cyclodextrin in a ratio of <=0.1 pt.wt. caffeine and 0.1-20.0 pts.wt. cyclodextrin based on 1 pt.wt. catechins. Moreover, the food and drink is obtained by acting an activated carbon such as the carbon activated by water vapor on an extract of a tea containing the catechins and the caffeine in the presence of the β- cyclodextrin, and removing the caffeine in the extract of the tea by an adsorption of the caffeine on the activated carbon.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の技術分野】本発明は、飲食物に関し、さらに詳
しくは、カテキン類を多量に含有しているにも拘らず苦
味・渋味がほとんどなく、しかもカフェイン含量が少な
く、多量に摂取しやすい飲食物およびその製造方法に関
する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to foods and drinks, and more particularly, it has little bitterness and astringency despite containing a large amount of catechins, and has a low caffeine content, so that it can be consumed in large amounts. The present invention relates to easy food and drink and a method for producing the same.

【0002】[0002]

【発明の技術的背景】茶には、カフェイン、カテキン類
などが含まれているが、カテキン類の生理作用が多数の
研究によって近年明らかにされてきている。
BACKGROUND OF THE INVENTION Tea contains caffeine, catechins and the like, and the physiological effects of catechins have been recently elucidated by numerous studies.

【0003】主なものを挙げると、抗酸化作用、抗菌作
用、コレステロールおよび脂質上昇抑制作用、血圧上昇
抑制作用、血糖値上昇抑制作用、抗腫瘍作用などがあ
る。こうしたカテキン類の生理作用は、日常的に飲まれ
る数杯の茶からでも少しは期待できるが、カテキン類の
摂取量を増やすことによって、より大きな効果が期待で
きる。
The main ones include antioxidant action, antibacterial action, cholesterol and lipid rise suppression action, blood pressure rise suppression action, blood sugar level rise suppression action, antitumor action and the like. Although the physiological effects of such catechins can be expected to some extent even from a few cups of tea that are consumed on a daily basis, a greater effect can be expected by increasing the intake of catechins.

【0004】上記のように茶抽出液中には、カテキン類
とともに相当量(カテキン類1重量部に対して0.1〜
0.4重量部程度)のカフェインが含まれており、茶抽
出液(お茶)を摂取するとカフェインも通常同時に摂取
され、消化管からほぼ全量が効率よく吸収される。この
茶抽出液中のカフェインは、利尿作用や中枢神経の刺激
による脳の働きの活性化など有益な生理作用をもってい
る。
As described above, the tea extract contains a considerable amount of catechins together with catechins (0.1 to 1 part by weight of catechins).
(Ca. 0.4 parts by weight) of caffeine. When a tea extract (tea) is ingested, caffeine is usually taken at the same time, and almost the entire amount is efficiently absorbed from the digestive tract. Caffeine in this tea extract has beneficial physiological actions such as diuretic action and activation of the brain by stimulation of the central nervous system.

【0005】成人がお茶を嗜好品として普通に飲む場合
には、カフェイン摂取量が過剰になることはほとんどな
い。しかしカテキン類の生理作用を期待してお茶を多量
に飲むと、茶に多量に含まれるカフェインの過剰摂取と
なり、食欲喪失、頭痛、神経過敏症の発生を引き起こす
虞がある。また、カテキン類は強い苦味・渋味をもって
いるため、このようにカテキン類を摂取する上での障害
となっている。
[0005] When an adult normally drinks tea as a luxury item, caffeine intake is rarely excessive. However, if a large amount of tea is consumed in anticipation of the physiological effects of catechins, caffeine contained in a large amount of tea will be excessively consumed, which may cause loss of appetite, headache, and nervousness. In addition, since catechins have strong bitterness and astringency, they are an obstacle to ingesting catechins.

【0006】このため、本発明者らは、苦味・渋味がほ
とんどなくカテキン類の大量摂取が可能であり、カフェ
イン含量が少ないような飲食物を見出すべく鋭意研究し
たところ、カテキン類に対して、カフェインを特定量以
下の量で含有し、サイクロデキストリン特にβ-サイク
ロデキストリンを特定量で含有している飲食物によれ
ば、苦味・渋味をほとんど感じずにカテキンを摂取でき
る上、カテキン類の大量摂取による血圧上昇抑制作用な
どの生理作用が期待でき、しかもこのようにカテキン類
を大量摂取しても食欲喪失、頭痛、神経過敏症の発生も
ないことなどを見出して本発明を完成するに至った。
[0006] Therefore, the present inventors have conducted intensive research to find foods and drinks that have little bitterness and astringency, can consume a large amount of catechins, and have a low caffeine content. According to the food containing caffeine in a specific amount or less and cyclodextrin, particularly β-cyclodextrin in a specific amount, catechin can be ingested with almost no bitterness and astringency. It has been found that physiological effects such as an increase in blood pressure can be expected due to the large intake of catechins, and that the present invention does not cause loss of appetite, headache, or nervousness even when a large amount of catechins are consumed. It was completed.

【0007】なお、特開平5-279264号公報に
は、ポリフェノール類を含む茶抽出物をキチンに含有さ
せた茶抽出物組成物が記載され、ポリフェノール類とし
ては、カテキン、エピカテキン、ガロカテキン、エピカ
テキンガレート、エピガロカテキンガレートが挙げられ
ている。また、キチンとしては、ポリ(N-アセチル-D
-グルコサミン)、その脱アセチル化物、キトサン、キ
チンと酸類とで形成された塩などが挙げられている。
JP-A-5-279264 describes a tea extract composition in which a tea extract containing polyphenols is contained in chitin. Examples of the polyphenols include catechin, epicatechin, gallocatechin and epicatechin. Catechin gallate and epigallocatechin gallate are mentioned. As chitin, poly (N-acetyl-D
-Glucosamine), its deacetylated product, chitosan, and salts formed with chitin and acids.

【0008】しかしながら、この茶抽出物組成物中に含
有される、例えばポリN-アセチル-Dーグルコサミンの
脱アセチル化物は、特有の呈味を有しており経口摂取し
にくいとの問題点があった。
[0008] However, the deacetylated product of poly-N-acetyl-D-glucosamine, for example, contained in this tea extract composition has a unique taste and is difficult to ingest. there were.

【0009】また、特開平6-116258号公報に
は、茶抽出液をセラミック膜、限外濾過膜、逆浸透膜を
組み合わせて処理する低カフェインの茶葉カテキン類の
製造方法が記載され、この公報には、この方法によれば
茶葉からカテキン類を効率よく、連続的に、かつ有機溶
剤を使用することなく安全大量生産できる旨記載されて
いる。
Japanese Patent Application Laid-Open No. 6-116258 discloses a method for producing low-caffeine tea leaf catechins, which comprises treating a tea extract with a combination of a ceramic membrane, an ultrafiltration membrane, and a reverse osmosis membrane. The gazette states that according to this method, catechins can be efficiently and continuously produced from tea leaves safely and without using an organic solvent in a large amount.

【0010】しかしながら、該公報に記載の方法で得ら
れる茶葉カテキン類には、強い苦味・渋味があり、大量
摂取は困難であるとの問題点がある。なお、特開平7-
179489号公報には、特定の式で示される新規ポリ
フェノール配糖体が記載され、該配糖体によれば、従来
のポリフェノール類のもつ強い渋味・収斂味が効果的に
改善される旨記載されている。また、該公報には、この
新規ポリフェノール配糖体は、ガロカテキン、サイクロ
デキストリンなどの混合物にバチルス・ステアロサーモ
フィラス由来のサイクロデキストリングルカノトランス
フェラーゼを作用させることにより得られる旨記載さ
れ、さらにクロマトグラフィーなどを用いて特定の画分
を採取利用してもよい旨記載されている。さらに、その
実施例1には、(−)−エピガロカテキン5gとα-サ
イクロデキストリン100gとを酢酸緩衝液に溶解後、
上記酵素を添加し反応させたことが記載されている。
[0010] However, the tea catechins obtained by the method described in the publication have a problem that they have a strong bitterness and astringency and are difficult to take in large quantities. Note that Japanese Patent Application Laid-Open
No. 179489 describes a novel polyphenol glycoside represented by a specific formula, and describes that the glycoside effectively improves the strong astringency and astringency of conventional polyphenols. Have been. The publication also states that the novel polyphenol glycoside is obtained by allowing a cyclodextrin glucanotransferase derived from Bacillus stearothermophilus to act on a mixture of gallocatechin, cyclodextrin, and the like, It states that a specific fraction may be collected and used by using, for example, chromatography. Further, in Example 1, after dissolving 5 g of (−)-epigallocatechin and 100 g of α-cyclodextrin in an acetate buffer,
It is described that the enzyme was added and reacted.

【0011】しかしながら、該公報には、カテキン類に
α-サイクロデキストリンを作用させても、カテキン類
は包接されないが、β-サイクロデキストリンでは直接
作用(包接)させることができ、このようにβ-サイク
ロデキストリンによる作用(包接)をさせるにより、カ
テキン類の苦味・渋味を除去するとの技術的思想は、何
等開示も示唆もされていない。また、カフェインとカテ
キン類とを含有する茶抽出液に水蒸気賦活炭を作用させ
ればカフェインが効率よく除去可能であることも何等記
載も示唆もされていない。まして、カフェインとカテキ
ン類とを含有する茶抽出液に、β-サイクロデキストリ
ンの存在(共存)下に活性炭を作用させればカフェイン
が選択的に効率よく除去可能であることなど示唆すらさ
れていない。
However, according to the publication, even if catechins are allowed to act on α-cyclodextrin, catechins are not included, but β-cyclodextrin is allowed to act directly (inclusion). The technical idea of removing the bitterness and astringency of catechins by acting (inclusion) with β-cyclodextrin has not been disclosed or suggested at all. Moreover, there is no description or suggestion that caffeine can be efficiently removed by applying steam activated carbon to a tea extract containing caffeine and catechins. Furthermore, it has been suggested that if activated carbon is allowed to act on a tea extract containing caffeine and catechins in the presence (coexistence) of β-cyclodextrin, caffeine can be selectively and efficiently removed. Not.

【0012】なお、この特開平7-179489号公報
に記載の方法を採用しても、配糖体でないカテキン類へ
の糖付加は、容易でないという問題点がある。また、特
開平8-70772号公報には、緑茶・紅茶・ウーロン
茶・マテ茶等のカフェインを含む茶類を素材とした茶の
抽出時及び/又は抽出後、適量の活性炭を混合または添
加して、カフェインを低減した茶類抽出液を得る方法が
開示されている。
Even if the method described in JP-A-7-179489 is adopted, there is a problem that sugar addition to catechins which are not glycosides is not easy. JP-A-8-70772 discloses a method of mixing or adding an appropriate amount of activated carbon at the time of and / or after extracting tea using caffeine-containing teas such as green tea, black tea, oolong tea, and mate tea. Thus, a method for obtaining a tea extract with reduced caffeine is disclosed.

【0013】しかしながら、該公報には、活性炭として
どのようなものを用いると、茶抽出物中のカフェイン含
量を著しく低減できるかという点については何等記載も
示唆もされていない。まして、茶抽出液にサイクロデキ
ストリン共存下で活性炭を作用させればカフェインが選
択的に効率よく除去可能であることについては示唆すら
されていない。
However, the publication does not disclose or suggest what kind of activated carbon can be used to significantly reduce the caffeine content in the tea extract. Furthermore, there is no suggestion that caffeine can be selectively and efficiently removed if activated carbon is allowed to act on a tea extract in the presence of cyclodextrin.

【0014】[0014]

【発明の目的】本発明は、上記のような従来技術に伴う
問題点を解決しようとするものであって、カテキン類を
多量に含有しているにも拘らず苦味・渋味がほとんどな
く、しかもカフェイン含量が少なく、多量に摂取しやす
い飲食物を提供することを目的としている。
SUMMARY OF THE INVENTION The object of the present invention is to solve the problems associated with the prior art as described above, and has almost no bitterness or astringency despite containing a large amount of catechins. Moreover, it aims at providing a food and drink which has a low caffeine content and is easy to take in large quantities.

【0015】本発明は、カフェイン含量の少ないカテキ
ン類含有物を効率よく製造しうるような飲食物の製造方
法を提供することを目的としている。
[0015] It is an object of the present invention to provide a method for producing foods and drinks that can efficiently produce a catechin-containing substance having a low caffeine content.

【0016】[0016]

【発明の概要】本発明に係る飲食物(機能性飲食物)
は、カテキン類1(重量部)に対して、カフェインを
0.1重量部以下の量で含有し、サイクロデキストリン
を0.1〜20.0重量部、好ましくは0.1〜10.
0重量部、さらに好ましくは0.1〜7重量部の量で含
有していることを特徴としている。
SUMMARY OF THE INVENTION Food and drink according to the present invention (functional food and drink)
Contains caffeine in an amount of 0.1 part by weight or less and 0.1 to 20.0 parts by weight of cyclodextrin, preferably 0.1 to 10 parts by weight, based on 1 (part by weight) of catechins.
It is characterized in that it is contained in an amount of 0 parts by weight, more preferably 0.1 to 7 parts by weight.

【0017】本発明の好ましい態様においては、上記サ
イクロデキストリンは、β-サイクロデキストリンであ
ることが望ましい。このような飲食物中のカテキン類に
は、その酸化・重合物(例:プロアントシアニジンポリ
マー)が含まれていてもよい。
[0017] In a preferred embodiment of the present invention, the cyclodextrin is desirably β-cyclodextrin. Catechins in such foods and drinks may contain oxidized / polymerized products thereof (eg, proanthocyanidin polymers).

【0018】本発明においては、カテキン類およびカフ
ェインを含有する茶抽出液に水蒸気賦活活性炭(水蒸気
賦活炭)を作用させ、該茶抽出液中のカフェインをこの
活性炭に吸着させ除去することにより、上記飲食物を製
造することが好ましい。
In the present invention, steam activated carbon (steam activated carbon) is allowed to act on a tea extract containing catechins and caffeine, and caffeine in the tea extract is adsorbed to the activated carbon and removed. Preferably, the food or drink is produced.

【0019】本発明においては、上記カテキン類および
カフェインを含有する茶抽出液に、β-サイクロデキス
トリンの存在下に活性炭(例:塩化亜鉛賦活炭、水蒸気
賦活炭)を作用させることが好ましい。この際には、茶
抽出液中の固形分1重量部に対して、β-サイクロデキ
ストリンを0.1〜4.0重量部の量で用いることが好
ましい。また、この際用いられる上記活性炭は、水蒸気
賦活炭であることが望ましい。
In the present invention, it is preferable that activated tea (eg, zinc chloride activated carbon, steam activated carbon) is allowed to act on the above tea extract containing catechins and caffeine in the presence of β-cyclodextrin. In this case, it is preferable to use β-cyclodextrin in an amount of 0.1 to 4.0 parts by weight based on 1 part by weight of the solid content in the tea extract. The activated carbon used at this time is preferably steam activated carbon.

【0020】本発明によれば、カテキン類を多量に含有
しているにも拘らず苦味・渋味がほとんどなく、しかも
カフェイン含量が少なく、多量に摂取しやすい飲食物が
提供される。このような飲食物を大量に摂取すれば、抗
酸化作用、抗菌作用、コレステロールおよび脂質上昇抑
制作用、血圧上昇抑制作用、血糖値上昇抑制作用、抗腫
瘍作用などの生理活性作用が期待できる。なお、このよ
うなカフェイン量の少ない飲食物では、大量に摂取して
も、食欲喪失、頭痛、神経過敏症等の発生の虞は少な
い。
According to the present invention, there is provided a food or drink which is hardly bitter and astringent in spite of containing a large amount of catechins, has a low caffeine content, and is easy to take in a large amount. Ingestion of such foods and drinks in large quantities can be expected to have physiological activities such as antioxidant action, antibacterial action, cholesterol and lipid rise suppression action, blood pressure rise suppression action, blood sugar level rise suppression action, and antitumor action. It should be noted that such foods with a small amount of caffeine are less likely to cause loss of appetite, headache, nervousness, etc., even when ingested in large amounts.

【0021】また本発明に係る茶抽出物の製造方法によ
れば、カフェイン含量の少ないカテキン類含有物(飲食
物)を効率よく製造できる。
Further, according to the method for producing a tea extract according to the present invention, a catechin-containing substance (food and drink) having a low caffeine content can be efficiently produced.

【0022】[0022]

【発明の具体的説明】以下、本発明に係る飲食物および
その製造方法について具体的に説明する。[飲食物] 本発明に係る飲食物は、カテキン類1(重量
部)に対して、カフェインを0.1重量部以下、好まし
くは0〜0.04重量部の量で含有し、サイクロデキス
トリン好ましくはβ-サイクロデキストリンを0.1〜
20.0重量部、好ましくは0.1〜10.0重量部、
さらに好ましくは0.1〜7重量部の量で含有してい
る。このような飲食物では、カテキン類は、α-、β-、
γ-サイクロデキストリン好ましくはβ-サイクロデキス
トリンにて包接されて苦味・渋味がほとんどなくなって
いるのであろうと考えられる。なお、このカフェイン量
がカテキン類1重量部に対して0.1重量部を超える
と、該飲食物の大量摂取により食欲喪失、頭痛、神経過
敏症などが発生する傾向がある。また、このサイクロデ
キストリン(特にβ-サイクロデキストリン)量が0.
1重量部未満では、飲食物中に苦味・渋味が残存し、2
0.0重量部を超える量では、それ以上呈味はあまり向
上せず、また飲食物中のカテキン類含量が相対的に低減
され、単位摂取量当たりの上記生理活性作用(例:血圧
上昇抑制作用)が低下する傾向がある。 <サイクロデキストリン>上記飲食物に含有されるサイ
クロデキストリンとしては、α-、β-、γ-サイクロデ
キストリンが挙げられ、本発明ではβ-サイクロデキス
トリンが好ましい。本発明ではこのβ-サイクロデキス
トリンと、これ以外のα-サイクロデキストリン及び/
又はγ-サイクロデキストリンとを組み合わせて用いる
ことができる。本発明では、これらのサイクロデキスト
リンのうちでは、β-サイクロデキストリンが特に苦味
・渋味の低減効果に優れるため好ましい。なお、分岐α
-、β-、γ-サイクロデキストリンも上記のサイクロデ
キストリンと同様に用いることができ、この場合も、分
岐β-サイクロデキストリンが特に苦味・渋味の低減効
果に優れるため好ましい。 <カテキン類>カテキン類としては、カテキン、エピカ
テキン、エピガロカテキン、エピカテキンガレート、エ
ピガロカテキンガレート、これらの酸化、重合物(例:
プロアントシアニジンポリマー)などが挙げられる。
DETAILED DESCRIPTION OF THE INVENTION Hereinafter, the food and drink according to the present invention and the method for producing the same will be specifically described. [Food and Drink] The food and drink according to the present invention contains caffeine in an amount of 0.1 part by weight or less, preferably 0 to 0.04 part by weight, based on 1 (part by weight) of catechins, and cyclodextrin. Preferably β-cyclodextrin is 0.1 to
20.0 parts by weight, preferably 0.1 to 10.0 parts by weight,
More preferably, it is contained in an amount of 0.1 to 7 parts by weight. In such foods and drinks, catechins include α-, β-,
It is considered that bitterness and astringency are almost eliminated by inclusion with γ-cyclodextrin, preferably β-cyclodextrin. If the amount of caffeine exceeds 0.1 part by weight with respect to 1 part by weight of catechins, loss of appetite, headache, nervousness and the like tend to occur due to large intake of the food or drink. Further, the amount of this cyclodextrin (particularly β-cyclodextrin) is 0.
If the amount is less than 1 part by weight, bitterness and astringency remain in food and drink,
When the amount exceeds 0.0 parts by weight, the taste is not further improved, and the content of catechins in foods and drinks is relatively reduced. Action) tends to decrease. <Cyclodextrin> Examples of the cyclodextrin contained in the food and drink include α-, β-, and γ-cyclodextrin, and β-cyclodextrin is preferred in the present invention. In the present invention, the β-cyclodextrin and other α-cyclodextrin and / or
Alternatively, they can be used in combination with γ-cyclodextrin. In the present invention, among these cyclodextrins, β-cyclodextrin is preferred because it is particularly excellent in the effect of reducing bitterness and astringency. Note that the branch α
-, Β-, γ-cyclodextrin can also be used in the same manner as the above-mentioned cyclodextrin, and in this case, branched β-cyclodextrin is particularly preferred because of its excellent effect of reducing bitterness and astringency. <Catechins> Examples of the catechins include catechin, epicatechin, epigallocatechin, epicatechin gallate, epigallocatechin gallate, and oxidized and polymerized products thereof (eg:
Proanthocyanidin polymer) and the like.

【0023】本発明においては、カテキン類としては、
とくにその酸化重合物が多量に含まれていると、酸化重
合物の苦味・渋味がカテキン、エピカテキン、エピガロ
カテキンガレートよりかなり弱いので苦味・渋味低減に
要するサイクロデキストリン量は少なくて良い。
In the present invention, catechins include
Especially when the oxidized polymer is contained in a large amount, the bitterness / astringency of the oxidized polymer is considerably weaker than that of catechin, epicatechin, epigallocatechin gallate, so the amount of cyclodextrin required for reducing the bitterness / astringency may be small. .

【0024】なお、このような重合物の量は、製茶時
に、主に茶葉中の酸化酵素であるポリフェノールオキシ
ダーゼをカテキン類に作用させる度合い、すなわち茶葉
の発酵の程度によって変わってくる。
The amount of such a polymer varies depending on the degree of the action of polyphenol oxidase, which is an oxidase in tea leaves, on catechins during tea production, that is, the degree of fermentation of tea leaves.

【0025】紅茶では、生葉が充分な発酵を受けて、生
葉中のカテキン、エピカテキン、エピガロカテキン、エ
ピカテキンガレート、エピガロカテキンガレートのかな
りの量(部分)が重合物(例:プロアントシアニジンポ
リマー)に変化している。
In black tea, fresh leaves undergo sufficient fermentation, and a considerable amount (part) of catechin, epicatechin, epigallocatechin, epicatechin gallate, epigallocatechin gallate in the fresh leaves is polymerized (eg, proanthocyanidins). Polymer).

【0026】中程度の半発酵茶であるウーロン茶では、
重合物の比率は紅茶の場合より少なく、カテキン、エピ
カテキン、エピガロカテキン、エピカテキンガレート、
エピガロカテキンガレート等の残存率が高い。
In oolong tea, which is a medium semi-fermented tea,
The proportion of polymer is lower than that of black tea, catechin, epicatechin, epigallocatechin, epicatechin gallate,
High residual rate of epigallocatechin gallate and the like.

【0027】緑茶では、生葉を蒸して茶葉中のポリフェ
ノールオキシダーゼを作用させずに作っているため、生
葉中に含まれ、強い苦味・渋味を有するカテキン類はそ
のままの形で含まれている。
Green tea is produced by steaming fresh leaves without causing the action of polyphenol oxidase in the tea leaves. Therefore, catechins having strong bitterness and astringency in fresh leaves are contained as they are.

【0028】[製法]このような飲食物を製造するに
は、例えば、上記紅茶、ウーロン茶、緑茶等から水、温
水、アルコールなどにて抽出して得られる、カテキン類
とカフェインとを含有する茶抽出液から溶剤による抽出
分離、クロマト分離、活性炭(例:塩化亜鉛賦活炭、水
蒸気賦活活性炭)による吸着処理などの方法で、好まし
くはβ−サイクロデキストリン共存下に活性炭、特に好
ましくはβ−サイクロデキストリン共存下に水蒸気賦活
炭にカフェインを吸着させてカフェインを分離除去す
る。
[Production Method] In order to produce such foods and drinks, for example, catechins and caffeine obtained by extracting the above-mentioned black tea, oolong tea, green tea and the like with water, hot water, alcohol and the like are contained. Activated carbon is preferably used in the presence of β-cyclodextrin, particularly preferably β-cyclo, by a method such as extraction separation with a solvent from a tea extract, chromatographic separation, adsorption treatment with activated carbon (eg, zinc chloride activated carbon, steam activated activated carbon) and the like. Caffeine is adsorbed on steam activated carbon in the presence of dextrin to separate and remove caffeine.

【0029】この際用いられる活性炭について詳述す
る。 <活性炭>活性炭は種々な炭素質物質を炭化、賦活する
ことによって製造されているが、活性炭のカフェイン吸
着処理能は、活性炭製造用の原料により異なるだけでな
くその製造方法によっても吸収特性が大きく異なること
が本発明者らによって見出されている。活性炭の製造方
法は薬品賦活法とガス賦活法の2つに分類され前者では
塩化亜鉛賦活、後者では水蒸気賦活が一般的である。塩
化亜鉛賦活炭、水蒸気賦活炭の何れもカフェイン、カテ
キン類を吸着するが、水蒸気賦活炭はカフェインをより
多く吸着し、カテキン類の吸着が少ないということを本
発明者らは見い出した。
The activated carbon used at this time will be described in detail. <Activated carbon> Activated carbon is produced by carbonizing and activating various carbonaceous substances. The ability of activated carbon to absorb caffeine not only depends on the raw material for producing activated carbon, but also depends on the production method. Significant differences have been found by the present inventors. Activated carbon production methods are classified into two, a chemical activation method and a gas activation method. The former is generally activated by zinc chloride and the latter is generally activated by steam. The present inventors have found that both zinc chloride activated carbon and steam activated carbon adsorb caffeine and catechins, but steam activated carbon adsorbs more caffeine and less catechins.

【0030】よって、本発明ではカテキン類およびカフ
ェインを含有する茶抽出液に活性炭を作用させる場合に
は水蒸気賦活炭を作用させることが好ましい。本発明で
はカテキン類およびカフェインを含有する茶抽出液にβ
−サイクロデキストリン共存下に活性炭を作用させる場
合には用いられる活性炭の賦活法にかかわらずいずれの
活性炭でも効率よくカフェインを分離除去できるが、水
蒸気賦活炭を使うことがより好ましい。
Therefore, in the present invention, when activated carbon is allowed to act on a tea extract containing catechins and caffeine, it is preferable to act on steam activated carbon. In the present invention, the tea extract containing catechins and caffeine contains β
-When activated carbon is allowed to act in the presence of cyclodextrin, caffeine can be efficiently separated and removed with any activated carbon regardless of the activated carbon activation method used, but steam activated carbon is more preferably used.

【0031】この際に用いられる活性炭の量の上限には
特に限界はないが、例えば、活性炭を、茶抽出液中の固
形分100重量部当たり、10〜500重量部、好まし
くは50〜200重量部程度の量で添加して、通常10
〜80℃、好ましくは20〜60℃[例:室温(25
℃)]程度の温度で、1〜360分間、好ましくは10
〜90分間攪拌すればよい。
There is no particular upper limit on the amount of activated carbon used at this time. For example, activated carbon is added in an amount of 10 to 500 parts by weight, preferably 50 to 200 parts by weight, per 100 parts by weight of solids in the tea extract. Parts, usually 10 parts
To 80 ° C, preferably 20 to 60 ° C [Example: room temperature (25
° C)], at a temperature of about 1 to 360 minutes, preferably 10 minutes.
Stir for ~ 90 minutes.

【0032】このようにカテキン類とカフェインとを含
有する茶抽出液に、活性炭を作用させると、該茶抽出液
中のカフェインとカテキン類も活性炭に吸着されるが、
活性炭の中でも水蒸気賦活炭はカフェインをより多く吸
着しカテキン類はこの活性炭には僅かな量しか吸着され
ない。そこで、このようにカフェインのみを選択的に吸
着した活性炭を濾過などの方法で分離除去すれば、カテ
キン類含量が多く、カフェイン量の低減された茶抽出物
(飲食物)が得られる。
When activated carbon is allowed to act on a tea extract containing catechins and caffeine, caffeine and catechins in the tea extract are also adsorbed on the activated carbon.
Among activated carbons, steam activated carbon adsorbs more caffeine and only a small amount of catechins is adsorbed on the activated carbon. Thus, if the activated carbon to which only caffeine is selectively adsorbed is separated and removed by a method such as filtration, a tea extract (food and drink) having a large content of catechins and a reduced amount of caffeine can be obtained.

【0033】本発明では、上記茶抽出液に活性炭を作用
させる際に、β-サイクロデキストリンの共存(存在)
させることが好ましい。すなわち、茶抽出液に予めβ-
サイクロデキストリンを作用させてから、活性炭を作用
させるか(イ)、茶抽出液にβ-サイクロデキストリンと活
性炭とを同時に添加して活性炭に茶抽出液中のカフェイ
ンを吸着(作用)させること(ロ)が好ましく、特に前者
(イ)が好ましい。
In the present invention, when activated charcoal is allowed to act on the above tea extract, the coexistence (presence) of β-cyclodextrin
Preferably. That is, β-
Activate the activated carbon after the cyclodextrin is activated (b) or simultaneously add β-cyclodextrin and activated carbon to the tea extract to adsorb (act) the caffeine in the tea extract to the activated carbon ( B) is preferred, and the former is particularly preferred.
(A) is preferred.

【0034】このようにβ-サイクロデキストリン共存
下に、活性炭を茶抽出液に作用させると、茶抽出液中の
カフェインが特異的に優先して活性炭に吸着される傾向
が高くなり、カテキン類は活性炭により吸着されにくく
なる。
When activated carbon is allowed to act on a tea extract in the presence of β-cyclodextrin, caffeine in the tea extract is more likely to be specifically and preferentially adsorbed on the activated carbon, and catechins Is hardly adsorbed by activated carbon.

【0035】そのため、カフェイン含量がより低減さ
れ、カテキン類含量のより多い処理物が得られる傾向が
ある。このようにしてカフェインを吸着した活性炭は、
ろ過等の方法にて分離除去される。また、例えば、得ら
れた濾液(カテキン類が高濃度に含有され、カフェイン
量が低減された茶抽出液)中に残存するβ-サイクロデ
キストリンは、必要により、濃縮して沈澱させて分別す
れば良い。また、この際濃縮液を冷却[例:0〜10℃
程度]すると、β-サイクロデキストリンの溶解度が低
下し、β-サイクロデキストリンが析出しやすくなり、
濾液中のβ-サイクロデキストリンの除去を迅速に行う
ことができる。
Therefore, there is a tendency that the content of caffeine is further reduced and a processed product having a higher content of catechins is obtained. Activated carbon adsorbing caffeine in this way
It is separated and removed by a method such as filtration. For example, β-cyclodextrin remaining in the obtained filtrate (a tea extract containing a high concentration of catechins and a reduced amount of caffeine) may be concentrated, precipitated, and separated as necessary. Good. At this time, the concentrated solution is cooled [Example: 0 to 10 ° C]
Degree], the solubility of β-cyclodextrin decreases, and β-cyclodextrin tends to precipitate,
Β-cyclodextrin in the filtrate can be rapidly removed.

【0036】なお、このようにして得られた、カフェイ
ンが低減・除去されたカテキン類含有液(カテキン類含
有液[I]、脱カフェイン茶抽出物とも言う。)中のβ
-サイクロデキストリンは、カテキン類や茶抽出物中の
他の成分に由来する苦味・渋味を低減させるので、処理
液中にある程度残存させておくことが好ましい。
It should be noted that β in the catechin-containing solution (catechin-containing solution [I], also referred to as decaffeinated tea extract) thus obtained, from which caffeine has been reduced and removed, is obtained.
-Since cyclodextrin reduces bitterness and astringency derived from catechins and other components in tea extract, it is preferable that cyclodextrin is left in the treatment liquid to some extent.

【0037】このようなカテキン類含有液[I]には、
通常、カフェインは、カテキン類1重量部に対して、
0.1重量部以下、好ましくは0〜0.04重量部の量
で、換言すれば、カテキン類含有液[I]中の固形分
(100重量%)中に、4重量%以下、好ましくは0〜
1重量%の量で含まれていることが望ましい。
Such a catechin-containing liquid [I] includes:
Usually, caffeine is added to 1 part by weight of catechins.
0.1 parts by weight or less, preferably 0 to 0.04 parts by weight, in other words, 4% by weight or less, preferably 4% by weight in the solid content (100% by weight) in the catechin-containing liquid [I]. 0 to
Desirably, it is contained in an amount of 1% by weight.

【0038】また、カテキン類は、カテキン類含有液
[I]中の固形分(100重量%)中に、1〜90重量
%、好ましくは10〜40重量%の量で含まれているこ
とが望ましい。
The catechins may be contained in the solid content (100% by weight) in the catechin-containing liquid [I] in an amount of 1 to 90% by weight, preferably 10 to 40% by weight. desirable.

【0039】本発明では、上記茶抽出液のカフェインを
低減・除去する処理の際にβ-サイクロデキストリンを
共存させない場合には、次いで、このようにして得られ
たカテキン類含有液[I]に、サイクロデキストリン、
好ましくはβ-サイクロデキストリンを添加・混合(攪
拌)することが好ましい。
In the present invention, if β-cyclodextrin is not co-present during the treatment for reducing and removing caffeine in the above tea extract, then the catechin-containing solution [I] thus obtained is obtained. , Cyclodextrin,
Preferably, β-cyclodextrin is added and mixed (stirred).

【0040】このようにすれば、苦味・渋味がほとんど
ないカテキン類含有液[II]が得られる。なお、この
ようにカテキン類含有液[I]にサイクロデキストリ
ン、好ましくはβ-サイクロデキストリンを添加混合す
ると、カテキン類は該サイクロデキストリンにて包接さ
れるために、カテキン類の苦味・渋味はほとんどなくな
るのであろうと考えられる。
In this manner, a catechin-containing liquid [II] having almost no bitterness or astringency can be obtained. When cyclodextrin, preferably β-cyclodextrin is added to and mixed with the catechin-containing liquid [I], the catechins are included in the cyclodextrin, and the bitterness and astringency of the catechins are reduced. It is thought that it will almost disappear.

【0041】なお、上記のようにβ-サイクロデキスト
リンを添加するに際しては、用いられるカテキン類含有
液[I]中の固形分濃度を、必要により、0.1〜40
重量%、好ましくは2〜10重量%程度に調整して用い
てもよい。
In addition, when β-cyclodextrin is added as described above, the solid concentration in the catechin-containing solution [I] used may be adjusted to 0.1 to 40, if necessary.
% By weight, preferably about 2 to 10% by weight.

【0042】また、サイクロデキストリン好ましくはβ
-サイクロデキストリンは、カテキン類含有液[I]中
のカテキン類1重量部に対して、通常、0.1〜20重
量部、好ましくは0.1〜10重量部、さらに好ましく
は0.1〜5重量部程度の量で用いることが望ましい。
また、カテキン類含有液[I]に、サイクロデキストリ
ンを添加・混合して、通常10〜80℃、好ましくは2
0〜60℃程度の温度で、1〜360分間、好ましくは
10〜90分間攪拌下に保持することが望ましい。
Cyclodextrin, preferably β
-Cyclodextrin is generally used in an amount of 0.1 to 20 parts by weight, preferably 0.1 to 10 parts by weight, more preferably 0.1 to 10 parts by weight, based on 1 part by weight of the catechins in the catechin-containing liquid [I]. It is desirable to use about 5 parts by weight.
Further, cyclodextrin is added to and mixed with the catechin-containing liquid [I], and the mixture is usually 10 to 80 ° C., preferably 2 to 80 ° C.
It is desirable to keep the mixture at a temperature of about 0 to 60 ° C. with stirring for 1 to 360 minutes, preferably 10 to 90 minutes.

【0043】なお、このようにカテキン類にサイクロデ
キストリン、好ましくはβ-サイクロデキストリンを作
用させるには、上記のようにカテキン類含有液[I]に
サイクロデキストリンを添加混合してもよく、また例え
ば、サイクロデキストリンにカテキン類含有液[I]を
添加混合してもよく、また少量ずつあるいは一度にこれ
らの成分(すなわちカテキン類とサイクロデキストリ
ン)を全量添加混合してもよく、カテキン類含有液
[I]とサイクロデキストリンとの混合方法は、特に限
定されない。
In order to cause cyclodextrin, preferably β-cyclodextrin, to act on catechins as described above, cyclodextrin may be added to and mixed with catechin-containing liquid [I] as described above. The catechin-containing liquid [I] may be added to and mixed with the cyclodextrin, or these components (ie, catechins and cyclodextrin) may be added and mixed little by little or at once, and the catechin-containing liquid [ The method of mixing [I] with cyclodextrin is not particularly limited.

【0044】なお、上記のようにサイクロデキストリン
を添加混合するカテキン類含有液[I]としては、カフ
ェインが除去された上記カテキン類含有液[I]を、濾
過し濃縮し乾燥し、得られた茶抽出物(粉末状あるいは
塊状の固形物)を、再び水、温水等に溶解させたもので
あってもよい。
The catechin-containing solution [I] to which cyclodextrin is added and mixed as described above is obtained by filtering, concentrating and drying the catechin-containing solution [I] from which caffeine has been removed. The tea extract (powder or lump solid) thus obtained may be dissolved again in water, hot water or the like.

【0045】このようにして得られた飲食物には、カテ
キン類1(重量部)に対して、カフェインは0.1重量
部以下、好ましくは0〜0.04重量部の量で含有さ
れ、サイクロデキストリン、好ましくはβ-サイクロデ
キストリンは、0.1〜20.0重量部、好ましくは
0.1〜10.0重量部、さらに好ましくは0.1〜7
重量部の量で含有されていることが望ましい。
The food and beverage thus obtained contains caffeine in an amount of 0.1 part by weight or less, preferably 0 to 0.04 part by weight, based on 1 part by weight of the catechins. , Cyclodextrin, preferably β-cyclodextrin is 0.1 to 20.0 parts by weight, preferably 0.1 to 10.0 parts by weight, more preferably 0.1 to 7 parts by weight.
Desirably, it is contained in an amount of parts by weight.

【0046】このような方法によれば、苦味・渋味のな
いカテキン類を多量に含有しており、かつカフェイン含
量の少ない飲食物が、サイクロデキストリングルカノト
ランスフェラーゼ等による酵素処理にて糖転移させて調
製する場合に比して、簡単に得られる。
According to such a method, a food or beverage containing a large amount of catechins having no bitterness or astringency and having a low content of caffeine can be subjected to glycosyltransferase by enzymatic treatment with cyclodextrin glucanotransferase or the like. It is easier to obtain than when prepared by

【0047】[0047]

【発明の効果】本発明に係る機能性飲食物(飲食物)
は、カテキン類を多量に含有しているにも拘らず苦味・
渋味がほとんどなく、カフェイン含量が少なく、多量に
摂取可能である。従って、このようなカテキン類が多量
に含有された飲食物の摂取量を増やすことによって、カ
テキン類の抗酸化作用、抗菌作用、コレステロールおよ
び脂質上昇抑制作用、血圧上昇抑制作用、血糖値上昇抑
制作用、抗腫瘍作用などの生理活性作用が期待できる。
EFFECT OF THE INVENTION The functional food and drink according to the present invention (food and drink)
Has a bitter taste despite containing a large amount of catechins
Has little astringency, low caffeine content, and can be consumed in large quantities. Therefore, by increasing the intake of foods and drinks containing a large amount of such catechins, the antioxidant action, antibacterial action, cholesterol and lipid elevation suppression action, blood pressure elevation suppression action, blood glucose elevation inhibition action of catechins Bioactive effects such as antitumor effects can be expected.

【0048】なお、このようなカフェイン量の少ない飲
食物では、大量に摂取しても、食欲喪失、頭痛、神経過
敏症等の発生の虞は少ない。また本発明に係る茶抽出物
の製造方法によれば、カフェイン含量の少ないカテキン
類含有物(飲食物)を効率よく製造できる。
In the case of such foods with a small amount of caffeine, there is little risk of loss of appetite, headache, nervousness, etc., even if ingested in large amounts. Further, according to the method for producing a tea extract according to the present invention, a catechin-containing substance (food and drink) having a low caffeine content can be efficiently produced.

【0049】[0049]

【実施例】以下、本発明について実施例に基づいてさら
に具体的に説明するが、本発明は、かかる実施例により
何等限定されるものではない。
EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples, but the present invention is not limited to these examples.

【0050】なお、以下の実施例、比較例におけるHP
LC分析条件は、以下の通り。HPLC分析条件 カラム:C18 溶離液:アセトニトリル/酢酸エチル/0.05%リン
酸水=12/2/86 検出:280nm 温度:40℃ 流速:1.0mL/分
The HP in the following Examples and Comparative Examples
LC analysis conditions are as follows. HPLC analysis conditions Column: C18 Eluent: acetonitrile / ethyl acetate / 0.05% phosphoric acid water = 12/2/86 Detection: 280 nm Temperature: 40 ° C. Flow rate: 1.0 mL / min

【0051】[0051]

【実施例1】緑茶から得た茶抽出物[固形物:該固形物
中にカテキン類50重量%、カフェイン10重量%含
有]100gを、水2リットルに溶解し、次いで水蒸気
賦活炭100gを加え、室温25℃で30分間攪拌して
から濾過した。この濾液を濃縮乾燥して69gの脱カフ
ェイン抽出物(A)を得た。
Example 1 100 g of a tea extract obtained from green tea [solid matter: containing 50% by weight of catechins and 10% by weight of caffeine in the solid matter] was dissolved in 2 liters of water, and then 100 g of steam activated carbon was added. The mixture was stirred at room temperature of 25 ° C. for 30 minutes and filtered. The filtrate was concentrated and dried to obtain 69 g of a decaffeinated extract (A).

【0052】本品をHPLC分析した結果は、次の通り
である。 カテキン類:39.8重量% カフェイン:0.8重量% このようにして得られた脱カフェイン茶抽出物(A)1
gを、温水200mlに溶解させ、α-サイクロデキス
トリン4gを加えて、10分間攪拌して液状の飲食物
[(B)液]を得た。
The result of HPLC analysis of this product is as follows. Catechins: 39.8% by weight Caffeine: 0.8% by weight Decaffeinated tea extract (A) 1 thus obtained
g was dissolved in 200 ml of warm water, 4 g of α-cyclodextrin was added, and the mixture was stirred for 10 minutes to obtain a liquid food and drink [solution (B)].

【0053】[0053]

【実施例2】実施例1において、α-サイクロデキスト
リンに代えて、β-サイクロデキストリンを用いた以外
は、実施例1と同様にして液状の飲食物[(C)液]を
得た。
Example 2 A liquid food and drink [solution (C)] was obtained in the same manner as in Example 1 except that β-cyclodextrin was used instead of α-cyclodextrin.

【0054】[0054]

【実施例3】実施例1において、α-サイクロデキスト
リンに代えて、γ-サイクロデキストリンを用いた以外
は、実施例1と同様にして液状の飲食物[(D)液]を
得た。
Example 3 A liquid food and drink [(D) solution] was obtained in the same manner as in Example 1 except that γ-cyclodextrin was used instead of α-cyclodextrin.

【0055】[0055]

【評価試験】15名のパネラーで、実施例1〜3で得ら
れた(A)、(B)、(C)液の呈味を評価した。
[Evaluation Test] The taste of the liquids (A), (B) and (C) obtained in Examples 1 to 3 was evaluated by 15 panelists.

【0056】結果を、表1に示す。(表1中、ブランク
は、脱カフェイン茶抽出物(A)1gを、温水200m
lに溶解させただけのもの。)
Table 1 shows the results. (In Table 1, blank is 1 g of decaffeinated tea extract (A) and 200 m of warm water.
l. )

【0057】[0057]

【表1】 [Table 1]

【0058】[0058]

【実施例4】緑茶から得られた茶抽出物[固形物:該固
形物中にカテキン類50重量%、カフェイン10重量%
含有]100gを水2リットルに溶解し、β-サイクロ
デキストリン200gを加え、40℃に加温下、30分
間攪拌した。次いで得られた混合物に水蒸気賦活活性炭
100gを加え、室温25℃で30分間攪拌してから濾
過した。
Example 4 Tea extract obtained from green tea [Solid matter: 50% by weight of catechins and 10% by weight of caffeine in the solid matter]
Was dissolved in 2 liters of water, 200 g of β-cyclodextrin was added, and the mixture was stirred at 40 ° C. for 30 minutes. Next, 100 g of steam activated carbon was added to the obtained mixture, and the mixture was stirred at room temperature of 25 ° C. for 30 minutes, and then filtered.

【0059】この濾液を濃縮乾燥して278gの脱カフ
ェイン茶抽出物(E)を得た。本品を、HPLCで分析
した結果は、次の通りである。 カテキン類:15.7% カフェイン:0.1% カテキン類の濃度が上記評価試験の場合と同様になるよ
うに、(E)粉末2.5gを分取し、40℃の温水20
0mlに溶解し、15名のパネラーで呈味を調べた。
The filtrate was concentrated and dried to obtain 278 g of decaffeinated tea extract (E). The result of analyzing this product by HPLC is as follows. Catechins: 15.7% Caffeine: 0.1% (E) 2.5 g of powder was fractionated and the temperature of 40 ° C warm water 20 was adjusted so that the concentration of catechins was the same as in the above evaluation test.
It was dissolved in 0 ml and taste was examined by 15 panelists.

【0060】その結果、この水溶液ではまったく、苦味
・渋味が感じられず、実施例2の(C)液と同じ呈味で
あった。
As a result, this aqueous solution did not show any bitterness or astringency, and had the same taste as the solution (C) of Example 2.

【0061】[0061]

【実施例5】緑茶から得られた茶抽出物[固形物:該固
形物中にカテキン類(総量)50重量%、カフェイン1
0重量%含有]10gを、水400mlに60℃の温度
で溶解させた。次いで、得られた茶抽出物溶液にβ-サ
イクロデキストリン5.0gを添加し、40℃の温度で
溶解させた。次いで、得られたβ-サイクロデキストリ
ン含有液に粉末カーボン4.0gを添加して、40℃の
温度で15分間攪拌した。
Example 5 Tea extract obtained from green tea [Solid matter: 50% by weight of catechins (total amount) in the solid matter, caffeine 1
0% by weight] was dissolved in 400 ml of water at a temperature of 60 ° C. Next, 5.0 g of β-cyclodextrin was added to the obtained tea extract solution and dissolved at a temperature of 40 ° C. Next, 4.0 g of powdered carbon was added to the obtained β-cyclodextrin-containing liquid, and the mixture was stirred at a temperature of 40 ° C. for 15 minutes.

【0062】その後、フィルターにて濾過して得られた
濾液と、フィルター中の残渣を洗浄して得られた洗液と
を一緒にして、1000mlに定容してHPLC分析を
行った。
Thereafter, the filtrate obtained by filtration through the filter and the washing liquid obtained by washing the residue in the filter were combined, and the volume was adjusted to 1000 ml to carry out HPLC analysis.

【0063】その結果、カフェインの残存率は、42.
1%であり、その残存量は、全固形物13.6g中に
0.42g[3.1重量%/得られた固形物中]であ
り、カテキン類の総残存率は、89%であり、その量
は、得られた全固形物13.6g中に4.5g[33重
量%/得られた全固形物中]となり、EgCg(エピガ
ロカテキンガレート)の残存率は、89.5%であり、
その量は、該カテキン類総量4.5g中に2.9g[2
1重量%/得られた固形物中]であり、ECg(エピカ
テキンガレート)の残存率は、87.8%であり、その
量は、該カテキン類総量4.5g中に0.7g[5.1
重量%/得られた全固形物中]となった。
As a result, the residual ratio of caffeine was 42.
The residual amount was 0.42 g [3.1% by weight / in the obtained solid] in 13.6 g of the total solid, and the total residual ratio of catechins was 89%. The amount was 4.5 g [33% by weight / in the total solid obtained] in 13.6 g of the total solid obtained, and the residual ratio of EgCg (epigallocatechin gallate) was 89.5%. And
The amount is 2.9 g [2 in the total amount of 4.5 g of the catechins.
1% by weight / in the obtained solid matter], the residual ratio of ECg (epicatechin gallate) is 87.8%, and the amount is 0.7 g [5 in 5 g of the total amount of the catechins. .1
% Of the total solids obtained].

【0064】結果を表3に併せて示す。また、茶抽出物
の使用量、β-サイクロデキストリン(β-CD)の添加
量、活性炭(水蒸気賦活炭)の添加量を表2に示す。
The results are shown in Table 3. Table 2 shows the amount of tea extract used, the amount of β-cyclodextrin (β-CD) added, and the amount of activated carbon (steam activated carbon) added.

【0065】[0065]

【実施例6〜12、比較例1】実施例5において、β-
サイクロデキストリン、活性炭(水蒸気賦活炭)の使用
量を表2に示すように代え、また、実施例8では、β-
サイクロデキストリンが溶解しにくかったため、60℃
に加熱して行った以外は、実施例5と同様にして行っ
た。
Examples 6 to 12 and Comparative Example 1 In Example 5, β-
The amounts of cyclodextrin and activated carbon (steam activated carbon) used were changed as shown in Table 2, and in Example 8, β-
Because cyclodextrin was difficult to dissolve, 60 ° C
The procedure was performed in the same manner as in Example 5 except that the heating was performed.

【0066】結果を表3に示す。Table 3 shows the results.

【0067】[0067]

【比較例2】実施例10において、水蒸気賦活活性炭に
代えて塩化亜鉛賦活炭を用いた以外は、実施例10と同
様に行った。
Comparative Example 2 The procedure of Example 10 was repeated, except that zinc chloride activated carbon was used in place of the steam activated activated carbon.

【0068】結果を表3に併せて示す。The results are shown in Table 3.

【0069】[0069]

【実施例13】実施例11において、水蒸気賦活活性炭
に代えて塩化亜鉛賦活炭を用いた以外は、実施例11と
同様に行った。
Example 13 The procedure of Example 11 was repeated, except that zinc chloride activated carbon was used instead of steam activated carbon.

【0070】結果を表3に併せて示す。The results are shown in Table 3.

【0071】[0071]

【表2】 [Table 2]

【0072】[0072]

【表3】 [Table 3]

Claims (7)

【特許請求の範囲】[Claims] 【請求項1】カテキン類1重量部に対して、カフェイン
を0.1重量部以下の量で含有し、サイクロデキストリ
ンを0.1〜20.0重量部の量で含有していることを
特徴とする飲食物。
(1) Caffeine is contained in an amount of 0.1 part by weight or less and cyclodextrin is contained in an amount of 0.1 to 20.0 parts by weight based on 1 part by weight of catechins. Food and drink characterized.
【請求項2】サイクロデキストリンがβ-サイクロデキ
ストリンであることを特徴とする請求項1に記載の飲食
物。
2. The food or drink according to claim 1, wherein the cyclodextrin is β-cyclodextrin.
【請求項3】カテキン類が、プロアントシアニジンポリ
マーを含むことを特徴とする請求項1または2に記載の
飲食物。
3. The food or drink according to claim 1, wherein the catechins include a proanthocyanidin polymer.
【請求項4】カテキン類およびカフェインを含有する茶
抽出液に水蒸気賦活炭を作用させ、該茶抽出液中のカフ
ェインを水蒸気賦活炭に吸着させ除去することを特徴と
する飲食物の製造方法。
4. A method for producing food or drink, wherein steam activated carbon is allowed to act on a tea extract containing catechins and caffeine, and caffeine in the tea extract is adsorbed on the steam activated carbon and removed. Method.
【請求項5】カテキン類およびカフェインを含有する茶
抽出液に、β-サイクロデキストリンの存在下に活性炭
を作用させ、該茶抽出液中のカフェインを活性炭に吸着
させ除去することを特徴とする飲食物の製造方法。
5. A tea extract containing catechins and caffeine, wherein activated carbon is allowed to act in the presence of β-cyclodextrin, and caffeine in the tea extract is adsorbed to the activated carbon and removed. To produce food and drink.
【請求項6】茶抽出液中の固形分1重量部に対して、β
-サイクロデキストリンを0.1〜4.0重量部の量で
用いる請求項5に記載の方法。
6. A method according to claim 1, wherein 1 part by weight of solids in the tea extract is β
6. The method according to claim 5, wherein the cyclodextrin is used in an amount of 0.1 to 4.0 parts by weight.
【請求項7】活性炭が水蒸気賦活炭であることを特徴と
する請求項5〜6の何れかに記載の方法。
7. The method according to claim 5, wherein the activated carbon is steam activated carbon.
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