JPH1043675A - Formation of patterned coating film giving metallic impression - Google Patents
Formation of patterned coating film giving metallic impressionInfo
- Publication number
- JPH1043675A JPH1043675A JP8204520A JP20452096A JPH1043675A JP H1043675 A JPH1043675 A JP H1043675A JP 8204520 A JP8204520 A JP 8204520A JP 20452096 A JP20452096 A JP 20452096A JP H1043675 A JPH1043675 A JP H1043675A
- Authority
- JP
- Japan
- Prior art keywords
- coating film
- paint
- base
- pattern
- metallic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
- B05D5/067—Metallic effect
- B05D5/068—Metallic effect achieved by multilayers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、例えばカラー原画
像などを自動車車体などの被塗物表面に描画すること
で、模様層を形成する模様塗膜の形成方法に関する。本
発明の模様塗膜の形成方法によれば、メタリック感を有
する鮮やかな模様塗膜を容易に形成することができる。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for forming a pattern coating film by forming a pattern layer by drawing, for example, an original color image on the surface of an object such as an automobile body. According to the method for forming a patterned coating film of the present invention, a bright patterned coating film having a metallic feeling can be easily formed.
【０００２】[0002]
【従来の技術】近年、コンピュータの印刷装置として、
インクジェット方式によるプリンタが用いられている。
このインクジェットプリンタは、コンピュータの記憶装
置に保存されている画像データの各画素の色調に応じて
赤青黄の色の３原色と黒色の４色のインク剤をそれぞれ
ノズルから吐出して印刷紙上にドット状に付着させ、印
刷紙上で重ね合わせることでその画素の色調を再現す
る。そしてノズルを左右方向に駆動させるとともに印刷
紙を垂直方向に駆動することにより、印刷紙上に画像デ
ータを描画することができる。2. Description of the Related Art In recent years, as a computer printing device,
Inkjet printers are used.
This ink jet printer discharges three primary colors of red, blue, yellow, and four colors of black from a nozzle in accordance with the color tone of each pixel of image data stored in a storage device of a computer from nozzles, and onto a printing paper. The color tone of the pixel is reproduced by attaching it in a dot shape and superimposing on a printing paper. By driving the nozzles in the left-right direction and the printing paper in the vertical direction, image data can be drawn on the printing paper.
【０００３】プリンタでは被塗物が紙状のものに限られ
ているが、例えば自動車車体などに画像データを直接描
画できれば、複雑な意匠であっても工業的に量産するこ
とが可能となる。そこで特開平１−１１０１５９号、特
開平１−１２８８４１号、特開平１−１３３８００号な
どの公報には、カラー原画像を拡大して壁面などに直接
プリントすることができる自動描画装置が提案されてい
る。この自動描画装置によれば、４つのノズルユニット
がＸ方向、Ｙ方向及びＺ方向の三次元方向に駆動される
ので、描画壁面に画像データを拡大して描画することが
可能となり、複雑な意匠であっても工業的に量産するこ
とが可能となる。したがってこれを自動車外板、バンパ
ー、モールなどの塗装に利用することにより、塗装意匠
の自由度が飛躍的に向上する。[0003] In a printer, an object to be coated is limited to a paper-like object. For example, if image data can be directly drawn on an automobile body or the like, even a complicated design can be mass-produced industrially. Therefore, Japanese Patent Application Laid-Open Nos. 1-110159, 1-128848, 1-133800, and the like disclose an automatic drawing apparatus capable of enlarging a color original image and directly printing it on a wall or the like. I have. According to this automatic drawing apparatus, since the four nozzle units are driven in the three-dimensional directions of the X direction, the Y direction, and the Z direction, it is possible to draw the image data while enlarging the image data on the drawing wall surface. However, it is possible to mass-produce industrially. Therefore, by using this for painting automobile outer panels, bumpers, moldings, and the like, the degree of freedom in painting designs is dramatically improved.
【０００４】ところで、自動車外板の塗装として、アル
ミニウム顔料やマイカ顔料を含む塗料を用いたメタリッ
ク塗装が広く普及している。このメタリック塗装は、中
塗り塗膜表面に先ずアルミニウム顔料やマイカ顔料を含
むベース塗料を塗装し、Ｗｅｔ−Ｏｎ−Ｗｅｔ塗装法に
よりさらにクリア塗料を塗装した後、加熱して二層の塗
膜を一体的に焼付乾燥させる２コート１ベイク法で塗装
されるのが一般的である。[0004] Metallic coating using a coating containing an aluminum pigment or a mica pigment is widely used as a coating for an automobile outer panel. In this metallic coating, first, a base coating containing an aluminum pigment or a mica pigment is applied to the surface of the intermediate coating film, a clear coating is further applied by a wet-on-wet coating method, and then the coating is heated to form a two-layer coating. It is common to apply a two-coat, one-bake method of integrally baking and drying.
【０００５】このようなメタリック塗装に上記インクジ
ェット方式による模様塗装を併用することにより、意匠
性が格段に向上することが期待される。そこで特開平７
−１０８２１６号公報には、中塗り塗膜表面に模様塗装
を施した後、ベース塗料とクリア塗料を塗装する方法が
開示されている。この方法によれば、模様塗料が塗布さ
れた模様層の存在する部分と存在しない部分とで表面性
状が異なるため、模様層の存在する部分と存在しない部
分とでベース塗膜中の光輝材の配向が異なり、独特の外
観意匠をもつ塗膜を形成することができる。[0005] By using the above-mentioned pattern coating by the ink jet method in combination with such metallic coating, it is expected that the design will be remarkably improved. Therefore, JP-A-7
Japanese Patent Application No. -108216 discloses a method in which a pattern paint is applied to the surface of an intermediate coating film, and then a base paint and a clear paint are applied. According to this method, since the surface properties are different between the portion where the pattern paint is applied and the portion where the pattern layer is not present, the glittering material in the base coating film is different between the portion where the pattern layer is present and the portion where the pattern layer is not present. A coating film having a different orientation and a unique appearance design can be formed.
【０００６】[0006]
【発明が解決しようとする課題】ところが特開平７−１
０８２１６号公報に開示された方法では、模様層の表面
をベース塗膜が覆うため、模様層の鮮やかな色調が損な
われるという不具合がある。また模様塗料中に光輝材を
混合する方法も考えられるが、インクジェット塗装に用
いられるノズルはその口径がきわめて小さいため、自動
車用に用いられている光輝材では粒径が大きすぎて用い
ることが困難である。そして光輝材の粒径をノズルから
吐出可能な程度まで小さくすると、光輝性が低下し所望
のメタリック感が得られない。SUMMARY OF THE INVENTION However, Japanese Patent Laid-Open No. 7-1
In the method disclosed in Japanese Patent Application Laid-Open No. 08216, there is a problem that the vivid color tone of the pattern layer is impaired because the surface of the pattern layer is covered with the base coating film. It is also conceivable to mix a glitter material in the pattern paint, but the nozzle used for ink-jet coating has a very small diameter, so it is difficult to use a glitter material used for automobiles because the particle size is too large. It is. If the particle size of the glittering material is reduced to such an extent that it can be ejected from the nozzle, the glittering property decreases and a desired metallic feeling cannot be obtained.
【０００７】本発明はこのような事情に鑑みてなされた
ものであり、鮮やかな色調とメタリック感とを併せ持
ち、高い意匠性を有する模様塗膜を形成することを目的
とする。The present invention has been made in view of such circumstances, and an object of the present invention is to form a patterned coating film having a vivid color tone and a metallic feeling and having high design properties.
【０００８】[0008]
【課題を解決するための手段】上記課題を解決する請求
項１に記載のメタリック感を有する模様塗膜の形成方法
の特徴は、光輝材を含有するベース塗料を塗装してベー
ス塗膜を形成し、ベース塗膜の表面に模様塗料をその隠
蔽膜厚未満の膜厚で塗装して模様層を形成することにあ
る。According to a first aspect of the present invention, there is provided a method for forming a patterned coating film having a metallic appearance, comprising the steps of: Another object of the present invention is to form a pattern layer by applying a pattern paint on the surface of the base coating film with a thickness less than the concealing film thickness.
【０００９】また同様に上記課題を解決する請求項２に
記載のメタリック感を有する模様塗膜の形成方法の特徴
は、光輝材を含有するベース塗料を塗装してベース塗膜
を形成し、ベース塗膜の表面にクリア塗料を塗装してク
リア塗膜を形成し、クリア塗膜の表面に模様塗料をその
隠蔽膜厚未満の膜厚で塗装して模様層を形成することに
ある。Another feature of the method for forming a patterned paint film having a metallic feeling according to the second aspect of the present invention is that a base paint containing a glittering material is applied to form a base paint film. An object of the present invention is to form a clear coating film by applying a clear paint on the surface of a coating film, and to apply a pattern coating material on the surface of the clear coating film with a thickness less than the concealing film thickness.
【００１０】さらに、請求項３に記載のように、光輝材
の平均粒径は１０〜３０μｍであり、光輝材はベース塗
料中にベース塗膜１００重量部に対して１０〜５０重量
％含有され、かつベース塗膜の明度がＬ値で２０以上で
あることが望ましい。また請求項４に記載のように、水
性塗料から形成された塗膜と溶剤型塗料から形成された
塗膜とを交互に形成することが望ましい。Further, as described in claim 3, the glittering material has an average particle size of 10 to 30 μm, and the glittering material is contained in the base paint in an amount of 10 to 50% by weight based on 100 parts by weight of the base coating film. It is desirable that the lightness of the base coating film be 20 or more in L value. As described in claim 4, it is desirable to alternately form a coating film formed from a water-based coating and a coating formed from a solvent-based coating.
【００１１】[0011]
【発明の実施の形態】ベース塗料としては、アルミニウ
ム顔料、マイカ顔料、酸化チタン層などをもつパールマ
イカ顔料、銀などのメッキ層をもつマイカ顔料などの光
輝材を含む従来と同様のベース塗料を用いることができ
る。ベース塗料は、光輝材の平均粒径が１０〜３０μｍ
であることが望ましい。光輝材の平均粒径が１０μｍよ
り小さくなると十分なメタリック感が得られず、３０μ
ｍより大きくなると塗膜中で光輝材が平行に配向しにく
くなり十分なメタリック感が得られない。特に好ましい
範囲は１５〜２０μｍである。BEST MODE FOR CARRYING OUT THE INVENTION As a base paint, a conventional base paint containing a luster material such as an aluminum pigment, a mica pigment, a pearl mica pigment having a titanium oxide layer or the like, or a mica pigment having a plating layer of silver or the like is used. Can be used. The base paint has an average particle size of the brilliant material of 10 to 30 μm.
It is desirable that If the average particle size of the glittering material is smaller than 10 μm, a sufficient metallic feeling cannot be obtained,
When it is larger than m, it is difficult for the glittering material to be oriented in parallel in the coating film, and a sufficient metallic feeling cannot be obtained. A particularly preferred range is 15 to 20 μm.
【００１２】また光輝材は、ベース塗料中にベース塗料
の樹脂１００重量部に対して１０〜５０重量％含有され
ていることが望ましい。光輝材の量が１０重量％より少
ないと十分なメタリック感が得られず、５０重量％を超
えて含有しても量が多すぎて塗膜中で平行に配向しにく
くなり十分なメタリック感が得られない。さらに、ベー
ス塗膜の明度がＬ値で２０以上であることが望ましい。
Ｌ値が２０未満では、模様層を通して光輝材を見ること
が困難となり、十分なメタリック感が得られない。な
お、ベース塗膜の隠蔽性が低く下層が表出可能である場
合には、このＬ値は下層が表出した状態のベース塗膜の
Ｌ値をいう。It is desirable that the glitter material is contained in the base paint in an amount of 10 to 50% by weight based on 100 parts by weight of the resin of the base paint. If the amount of the brilliant material is less than 10% by weight, a sufficient metallic feeling cannot be obtained, and if the amount exceeds 50% by weight, the amount is too large and it is difficult to orient in parallel in the coating film, and a sufficient metallic feeling is obtained. I can't get it. Further, it is desirable that the lightness of the base coating film is 20 or more in L value.
When the L value is less than 20, it becomes difficult to see the glittering material through the pattern layer, and a sufficient metallic feeling cannot be obtained. In addition, when the hiding property of the base coating film is low and the lower layer can be exposed, this L value refers to the L value of the base coating film in a state where the lower layer is exposed.
【００１３】模様塗料としては特に制限されないが、例
えば従来のインクジェット塗装に用いられるインクを用
いることができる。この模様塗料の隠蔽膜厚は、その顔
料の種類及び顔料濃度によって決まり、模様塗料はその
隠蔽膜厚未満の膜厚に塗装される。これにより下地のベ
ース塗膜のメタリック感が模様層を通して表出するた
め、模様塗膜がメタリック感を有するようになる。The pattern paint is not particularly limited, but for example, inks used in conventional ink jet coating can be used. The concealed film thickness of the pattern paint is determined by the type and concentration of the pigment, and the pattern paint is applied to a thickness less than the concealed film thickness. As a result, the metallic feeling of the underlying base coating film is exposed through the pattern layer, so that the patterned coating film has a metallic feeling.
【００１４】なお、模様塗料の顔料濃度としては、樹脂
１００重量部に対して、黄色及び赤色顔料の場合には３
０〜７０重量部好ましくは４０〜５０重量部であり、青
色顔料の場合には１０〜６０重量部好ましくは２０〜３
０重量部であり、黒色顔料の場合には５〜３０重量部好
ましくは１０〜２０重量部である。顔料濃度が高すぎる
と隠蔽膜厚が薄くなりすぎてその膜厚未満に塗装するこ
とが困難となり、顔料濃度が低すぎると所望の色調に塗
装した場合にタレが生じる場合がある。顔料濃度をこの
範囲とすれば、吐出量を制御しながら各色を塗り重ねる
ことによって、所望の色調をタレが生じない最適の膜厚
で、しかも隠蔽膜厚未満に塗装することができる。The pigment concentration of the pattern paint is 3 parts for the yellow and red pigments per 100 parts by weight of the resin.
0 to 70 parts by weight, preferably 40 to 50 parts by weight, and in the case of a blue pigment, 10 to 60 parts by weight, preferably 20 to 3 parts by weight.
0 parts by weight, and in the case of a black pigment, 5 to 30 parts by weight, preferably 10 to 20 parts by weight. If the pigment concentration is too high, the concealing film thickness will be too thin, and it will be difficult to apply a coating having a thickness less than that thickness. If the pigment concentration is too low, sagging may occur when applying a desired color tone. When the pigment concentration is within this range, the desired color tone can be applied with an optimum film thickness that does not cause sagging and at a thickness less than the concealing film thickness by coating each color repeatedly while controlling the ejection amount.
【００１５】請求項１に記載の模様塗膜の形成方法で
は、先ずベース塗膜が形成され、次いで模様層が形成さ
れる。ベース塗膜は未硬化のウェット状態であってもよ
いし、予備加熱されてある程度硬化した状態であっても
よく、完全硬化した状態とすることもできる。そして模
様層を硬化させた状態で模様塗膜としてもよいし、模様
層の表面にさらにクリア塗膜を形成して模様塗膜とする
ことも好ましい。この場合には、模様層が未硬化の状態
でクリア塗料を塗布し、模様層とクリア塗膜を一体的に
焼付乾燥してもよいし、模様層を硬化させた後にクリア
塗膜を形成してもよい。In the method for forming a pattern coating film according to the first aspect, a base coating film is formed first, and then a pattern layer is formed. The base coating film may be in an uncured wet state, may be preliminarily heated and may have been cured to some extent, or may be in a completely cured state. And it is good also as a pattern coating film in the state which cured the pattern layer, and it is also preferable to form a clear coating film further on the surface of a pattern layer and to make it a pattern coating film. In this case, a clear paint may be applied in a state where the pattern layer is not cured, and the pattern layer and the clear coating may be integrally baked and dried, or a clear coating may be formed after the pattern layer is cured. You may.
【００１６】このようにして得られた塗膜では、模様層
は隠蔽膜厚未満に形成されているため、模様層を通して
ベース塗膜が表出する。つまり模様層を透過した光がベ
ース塗膜に到達し、光輝材で反射した光が模様層を透過
して目に入るため、模様層の色調の中にメタリック感が
加わった新規な意匠が得られる。またさらにクリア塗膜
を形成すれば、屈折率の変化によりメタリック感がさら
に向上し、模様層の保護も可能となる。In the coating film thus obtained, the base layer is exposed through the pattern layer because the pattern layer is formed to be less than the concealing film thickness. In other words, the light transmitted through the pattern layer reaches the base coating film, and the light reflected by the brilliant material passes through the pattern layer and enters the eyes, resulting in a new design with a metallic feel added to the color tone of the pattern layer. Can be Further, when a clear coating film is further formed, the metallic feeling is further improved by a change in the refractive index, and the pattern layer can be protected.
【００１７】請求項２に記載の模様塗膜の形成方法で
は、先ずベース塗膜とクリア塗膜が形成され、次いでク
リア塗膜表面に模様層が形成される。ベース塗膜とクリ
ア塗膜が硬化後に模様層を形成してもよいし、クリア塗
膜が未硬化のウェット状態で模様塗料を塗布しクリア塗
膜と一体的に硬化させてもよい。またベース塗膜、クリ
ア塗膜及び模様層を、３コート１ベイクで一体的に焼付
乾燥させることもできる。そして模様層の表面にさらに
クリア塗膜を形成してもよい。In the method for forming a patterned coating film according to the second aspect, first, a base coating film and a clear coating film are formed, and then a pattern layer is formed on the surface of the clear coating film. A pattern layer may be formed after the base coating film and the clear coating film are cured, or a pattern paint may be applied in a wet state where the clear coating film is not cured, and may be cured integrally with the clear coating film. Further, the base coating film, the clear coating film, and the pattern layer can be integrally baked and dried in three coats and one bake. Then, a clear coating film may be further formed on the surface of the pattern layer.
【００１８】このようにして得られた塗膜では、模様層
は隠蔽膜厚未満に形成されているため、クリア塗膜と模
様層を通してベース塗膜が表出する。つまり模様層を透
過した光がクリア塗膜を透過してベース塗膜に到達し、
光輝材で反射した光がクリア塗膜及び模様層を透過して
目に入るため、模様層の色調の中にメタリック感が加わ
った新規な意匠が得られる。またさらに第２のクリア塗
膜を形成すれば、屈折率の変化によりメタリック感がさ
らに向上し、模様層の保護も可能となる。In the coating film thus obtained, since the pattern layer is formed to be less than the concealing film thickness, the base coating film is exposed through the clear coating film and the pattern layer. In other words, the light transmitted through the pattern layer passes through the clear coating and reaches the base coating,
Since the light reflected by the brilliant material passes through the clear coating film and the pattern layer and enters the eyes, a new design with a metallic feeling added to the color tone of the pattern layer can be obtained. Further, when the second clear coating film is further formed, the metallic feeling is further improved by the change in the refractive index, and the pattern layer can be protected.
【００１９】模様層の下地となるベース塗膜又はクリア
塗膜がウェットの状態のときには、模様塗料を塗布した
時に模様塗料が下地と混ざり合う場合がある。また模様
層の表面にクリア塗料が塗布されても、模様層がクリア
塗料と混ざり合う場合がある。このようになると、特に
インクジェットにより模様層を形成する場合には細かな
ドットの重なりで色調を表現するために、模様層の色調
や輪郭が不明瞭となるという不具合が生じる。When the base coating film or the clear coating film serving as the base of the pattern layer is in a wet state, when the pattern coating is applied, the pattern coating may be mixed with the base. Even when the clear paint is applied to the surface of the pattern layer, the pattern layer may be mixed with the clear paint. In this case, in particular, when the pattern layer is formed by ink jet, since the color tone is expressed by the overlapping of fine dots, the color tone and the contour of the pattern layer become unclear.
【００２０】そこで、請求項４に記載されているよう
に、水性塗料から形成された塗膜と溶剤型塗料から形成
された塗膜とを交互に形成することが望ましい。このよ
うにすれば各塗膜の層間における混ざり合いが抑制され
るため、滲みのない鮮明な模様層を形成することができ
る。Therefore, as described in claim 4, it is desirable to alternately form a coating film formed from an aqueous paint and a coating film formed from a solvent-based paint. By doing so, mixing between the layers of the coating films is suppressed, so that a clear pattern layer without bleeding can be formed.
【００２１】[0021]
【実施例】以下、実施例及び比較例により本発明を具体
的に説明する。 （実施例１）鋼板に電着塗装、中塗り塗装を施した塗板
に、アルミニウム粉末１４重量％、青色顔料１重量％、
黒色顔料微量を含有する固形分４０重量％のアクリルメ
ラミン系のシルバーメタリック色溶剤型ベース塗料を、
膜厚約１５μｍとなるように塗装した。The present invention will be specifically described below with reference to examples and comparative examples. (Example 1) 14% by weight of aluminum powder, 1% by weight of blue pigment,
Acrylic melamine-based silver metallic color solvent-based base paint with a solid content of 40% by weight containing a small amount of black pigment,
The coating was performed to a thickness of about 15 μm.
【００２２】これを８０℃で５分間加熱して予備硬化さ
せ、その表面に表１に示す組成の水性インクを用いて、
イメージスキャナーで読みとった花の写真のイメージデ
ータを用い、インクジェット方式により花の模様塗装を
行った。なお形成された模様層の膜厚は最大で約１．５
μｍであり、隠蔽膜厚未満となっている。This was pre-cured by heating at 80 ° C. for 5 minutes, and an aqueous ink having the composition shown in Table 1 was used on the surface thereof.
Using the image data of a photograph of a flower read by an image scanner, a flower pattern was painted by an ink jet method. The thickness of the formed pattern layer is about 1.5 at the maximum.
μm, which is less than the concealing film thickness.
【００２３】[0023]
【表１】 次いで、形成された模様層表面及び模様層の形成されて
いないベース塗膜の表面に、アクリルメラミン系の溶剤
型クリア塗料を約３０μｍの膜厚となるように塗装し、
１４０℃で３０分間焼付乾燥して模様塗膜を形成した。[Table 1] Next, on the surface of the formed pattern layer and the surface of the base coating film on which the pattern layer is not formed, an acrylic melamine-based solvent-type clear paint is applied so as to have a thickness of about 30 μm,
It was baked and dried at 140 ° C. for 30 minutes to form a patterned coating film.
【００２４】得られた模様塗膜の模式的断面図を図１に
示す。この模様塗膜は、中塗り塗膜１表面に形成された
ベース塗膜２と、ベース塗膜２表面に形成された模様層
３と、模様層３及びベース塗膜２の表面に形成されたク
リア塗膜４とから構成されている。この模様塗膜では、
クリア塗膜４を通して模様層３が見え、さらに模様層３
を通してベース塗膜２が見える。また模様層３が形成さ
れていない部分では、クリア塗膜４を通してベース塗膜
２が見える。すなわち、ベース塗膜２のシルバーメタリ
ック色の中に模様層３の花の意匠が鮮やかに見え、かつ
模様層３の中にアルミニウム顔料によるメタリックの輝
きが表出しているので、従来にない意匠性をもつ模様塗
膜であった。FIG. 1 shows a schematic cross-sectional view of the obtained patterned coating film. The pattern coating film was formed on the surface of the base coating film 2 formed on the surface of the intermediate coating film 1, the pattern layer 3 formed on the surface of the base coating film 2, and the surfaces of the pattern layer 3 and the base coating film 2. And a clear coating film 4. In this pattern coating,
The pattern layer 3 can be seen through the clear coating film 4 and further the pattern layer 3
Through which the base coating film 2 is visible. In a portion where the pattern layer 3 is not formed, the base coating film 2 can be seen through the clear coating film 4. That is, since the design of the flower of the pattern layer 3 is clearly visible in the silver metallic color of the base coating film 2 and the metallic shine of the aluminum pigment is exposed in the pattern layer 3, a design that has never existed before is obtained. It was a patterned coating film.
【００２５】（実施例２）ベース塗料を塗装後１４０℃
で３０分間焼付乾燥したこと以外は実施例１と同様にし
て模様塗膜を形成した。その結果、実施例１と同様の意
匠をもつ模様塗膜が形成された。 （実施例３）ベース塗料を塗装後、予備加熱することな
く模様塗装を行い、さらにクリア塗料を塗装後１４０℃
で３０分間加熱して３層を一体化したこと以外は実施例
１と同様にして模様塗膜を形成した。その結果、実施例
１に比べると模様層の滲みにより若干のぼけが生じてい
たものの、従来にない意匠をもつ模様塗膜が形成され
た。Example 2 140 ° C. after application of base paint
, And a pattern coating film was formed in the same manner as in Example 1 except that the pattern was dried by baking for 30 minutes. As a result, a patterned coating film having the same design as in Example 1 was formed. (Example 3) After applying the base paint, pattern painting was performed without preheating, and then 140 ° C. after applying the clear paint.
For 30 minutes to form a patterned coating film in the same manner as in Example 1 except that the three layers were integrated. As a result, although a slight blurring occurred due to the bleeding of the pattern layer as compared with Example 1, a patterned coating film having a design which had never existed before was formed.
【００２６】（実施例４）塩素化ポリプロピレンを主体
とするプライマーが塗装されたポリプロピレン製の板材
に、アルミニウム顔料２重量％、マイカ顔料６重量％、
赤色顔料２０重量％を含有する固形分４０重量％のアク
リルメラミン系のレッドマイカメタリック色の溶剤型ベ
ース塗料を膜厚約１５μｍとなるように塗装した。Example 4 2% by weight of aluminum pigment, 6% by weight of mica pigment and 2% by weight of a polypropylene plate coated with a primer mainly composed of chlorinated polypropylene.
An acrylic melamine-based red mica metallic color solvent-type base paint containing 20% by weight of a red pigment and having a solid content of 40% by weight was applied to a film thickness of about 15 μm.
【００２７】次いでアクリルメラミン系の溶剤型クリア
塗料を膜厚約３０μｍとなるように塗装し、１２０℃で
３０分加熱することによりベース塗膜とクリア塗膜を一
体的に焼付乾燥した。その後、実施例１と同様の組成の
インクを用いて、インクジェット方式によりコンピュー
タ上で作成した幾何学模様をクリア塗膜の表面に塗装し
た。模様層の膜厚は最大で約２μｍであり、隠蔽膜厚未
満となっている。さらにその表面に、アクリルメラミン
系の溶剤型クリア塗料を膜厚約３０μｍとなるように塗
装した。そして１２０℃で３０分加熱し、本実施例の模
様塗膜を形成した。Next, an acrylic melamine-based solvent-type clear coating was applied so as to have a thickness of about 30 μm, and heated at 120 ° C. for 30 minutes to integrally bake and dry the base coating and the clear coating. Thereafter, using an ink having the same composition as in Example 1, a geometric pattern created on a computer by an ink jet method was applied to the surface of the clear coating film. The maximum thickness of the pattern layer is about 2 μm, which is less than the concealment thickness. Further, an acrylic melamine-based solvent-type clear paint was applied on the surface so as to have a thickness of about 30 μm. And it heated at 120 degreeC for 30 minutes, and formed the pattern coating film of this example.
【００２８】この模様塗膜では、図２に示すようにクリ
ア塗膜４を通して模様層３が見え、さらに模様層３及び
中間クリア塗膜５を通してベース塗膜２が見える。また
模様層３が形成されていない部分では、クリア塗膜４及
び中間クリア塗膜５を通してベース塗膜２が見える。す
なわち、ベース塗膜２のレッドマイカメタリック色の中
に模様層３の幾何学模様の意匠が鮮やかに見え、かつ模
様層３の中にアルミニウム顔料及びマイカ顔料によるメ
タリックの輝きが表出しているので、従来にない意匠性
をもつ模様塗膜であった。As shown in FIG. 2, the pattern layer 3 can be seen through the clear coating film 4 and the base coating film 2 can be seen through the pattern layer 3 and the intermediate clear coating film 5 as shown in FIG. In a portion where the pattern layer 3 is not formed, the base coating film 2 can be seen through the clear coating film 4 and the intermediate clear coating film 5. That is, the design of the geometric pattern of the pattern layer 3 is clearly seen in the red mica metallic color of the base coating film 2, and the metallic shine of the aluminum pigment and the mica pigment appears in the pattern layer 3. This was a pattern coating film having a design property never before seen.
【００２９】（実施例５〜１４）模様塗料として用いた
インクの顔料濃度を表２に示すように変化させたこと以
外は実施例１と同様にして、実施例５〜９の模様塗膜を
形成した。また模様塗料として用いたインクの顔料濃度
を表２に示すように変化させたこと以外は実施例４と同
様にして、実施例１０〜１４の模様塗膜を形成した。Examples 5 to 14 The pattern coatings of Examples 5 to 9 were prepared in the same manner as in Example 1 except that the pigment concentration of the ink used as the pattern paint was changed as shown in Table 2. Formed. Further, pattern coating films of Examples 10 to 14 were formed in the same manner as in Example 4 except that the pigment concentration of the ink used as the pattern paint was changed as shown in Table 2.
【００３０】[0030]
【表２】 [Table 2]
【００３１】表２より、塗り重ね部でも隠蔽膜厚未満で
あり、従来にない意匠性をもつ模様塗膜が得られた。 （実施例１５）ベース塗料として、平均粒径１５μｍの
アルミニウム顔料４．４重量％と、平均粒径１８μｍの
ホワイトマイカ顔料４．３重量％と、赤色顔料０．１重
量％と、黄色顔料０．２重量％及び白色顔料３．４重量
％を含有し、固形分４０重量％のアクリルメラミン系の
マイカメタリックベース塗料を用いたこと以外は実施例
４と同様にして、模様塗膜を形成した。なお、ベース塗
膜の明度はＬ値で５５であり、模様層の膜厚は最大で約
２μｍであって隠蔽膜厚未満となっている。From Table 2, it can be seen that a pattern coating film having an unprecedented design was obtained even in the overcoated portion with a thickness less than the concealing film thickness. (Example 15) As a base paint, 4.4% by weight of an aluminum pigment having an average particle size of 15 μm, 4.3% by weight of a white mica pigment having an average particle size of 18 μm, 0.1% by weight of a red pigment, and 0% of a yellow pigment A patterned coating film was formed in the same manner as in Example 4 except that an acrylic melamine-based mica metallic base paint containing 0.2% by weight and a white pigment 3.4% by weight and having a solid content of 40% by weight was used. . The lightness of the base coating film is 55 in L value, and the maximum thickness of the pattern layer is about 2 μm, which is less than the concealing film thickness.
【００３２】得られた模様塗膜は、マイカメタリック塗
装の上に独特のメタリック感を有する花が描かれ、従来
の塗装では得られない意匠を有していた。 （実施例１６）ベース塗料として、平均粒径１１μｍの
アルミニウム顔料１．０重量％と、平均粒径１５μｍの
レッドマイカ顔料３．０重量％と、赤色顔料８．０重量
％を含有し、固形分４０重量％のアクリルメラミン系の
マイカメタリックベース塗料を用いたこと以外は実施例
４と同様にして、模様塗膜を形成した。なお、ベース塗
膜の明度はＬ値で２５であり、模様層の膜厚は最大で約
２μｍであって隠蔽膜厚未満となっている。The resulting patterned coating film had a unique metallic appearance on the mica metallic coating, and had a design that could not be obtained by conventional coating. (Example 16) As a base coating material, containing 1.0% by weight of an aluminum pigment having an average particle size of 11 μm, 3.0% by weight of a red mica pigment having an average particle size of 15 μm, and 8.0% by weight of a red pigment, A patterned coating film was formed in the same manner as in Example 4 except that an acrylic melamine-based mica metallic base paint of 40% by weight was used. The lightness of the base coating film is 25 in L value, and the maximum thickness of the pattern layer is about 2 μm, which is less than the concealing film thickness.
【００３３】得られた模様塗膜は、レッドマイカメタリ
ック塗装の上に独特のメタリック感を有する花が描か
れ、従来の塗装では得られない意匠を有していた。 （実施例１７）ベース塗料として、平均粒径１１μｍの
アルミニウム顔料１９．０重量％と、青色顔料１．０重
量％及び微量の黒色顔料を含有し、固形分４０重量％の
アクリルメラミン系のメタリックベース塗料を用いたこ
と以外は実施例４と同様にして、模様塗膜を形成した。
なお、ベース塗膜の明度はＬ値で７４であり、模様層の
膜厚は最大で約２μｍであって隠蔽膜厚未満となってい
る。The resulting patterned coating film had a unique metallic appearance on the red mica metallic coating, and had a design that could not be obtained by conventional coating. (Example 17) As a base paint, an acrylic melamine-based metallic material containing 19.0% by weight of an aluminum pigment having an average particle diameter of 11 μm, 1.0% by weight of a blue pigment and a trace amount of a black pigment, and having a solid content of 40% by weight. A patterned coating film was formed in the same manner as in Example 4 except that the base paint was used.
The lightness of the base coating film is 74 in L value, and the maximum thickness of the pattern layer is about 2 μm, which is less than the concealing film thickness.
【００３４】得られた模様塗膜は、青色メタリック塗装
の上に独特のメタリック感を有する花が描かれ、従来の
塗装では得られない意匠を有していた。 （実施例１８）ベース塗料として、平均粒径２２μｍの
アルミニウム顔料４．２重量％と、青色顔料１．０重量
％と、白色顔料４．０重量％とを含有し、固形分４０重
量％のアクリルメラミン系のメタリックベース塗料を用
いたこと以外は実施例４と同様にして、模様塗膜を形成
した。なお、ベース塗膜の明度はＬ値で６８であり、模
様層の膜厚は最大で約２μｍであって隠蔽膜厚未満とな
っている。The resulting patterned coating film had a unique metallic appearance on a blue metallic coating, and had a design that could not be obtained by conventional coating. (Example 18) As a base coating material, containing 4.2% by weight of an aluminum pigment having an average particle size of 22 μm, 1.0% by weight of a blue pigment, and 4.0% by weight of a white pigment, and having a solid content of 40% by weight. A patterned coating film was formed in the same manner as in Example 4 except that an acrylic melamine-based metallic base paint was used. The lightness of the base coating film is 68 in L value, and the maximum thickness of the pattern layer is about 2 μm, which is less than the concealing film thickness.
【００３５】得られた模様塗膜は、青色メタリック塗装
の上に独特のメタリック感を有する花が描かれ、従来の
塗装では得られない意匠を有していた。 （実施例１９）ベース塗料として、平均粒径１５μｍの
レッドマイカ顔料１０．０重量％と、赤色顔料９．０重
量％を含有し、固形分４０重量％のアクリルメラミン系
のマイカメタリックベース塗料を用いたこと以外は実施
例４と同様にして、模様塗膜を形成した。なお、ベース
塗膜の明度はＬ値で４６であり、模様層の膜厚は最大で
約２μｍであって隠蔽膜厚未満となっている。The resulting patterned coating film had a unique metallic appearance on a blue metallic coating, and had a design that could not be obtained by conventional coating. (Example 19) As a base paint, an acrylic melamine-based mica metallic base paint containing 10.0% by weight of a red mica pigment having an average particle diameter of 15 μm and 9.0% by weight of a red pigment and having a solid content of 40% by weight was used. A patterned coating film was formed in the same manner as in Example 4 except that the coating film was used. The lightness of the base coating film was 46 in L value, and the maximum thickness of the pattern layer was about 2 μm, which was less than the concealing film thickness.
【００３６】得られた模様塗膜は、レッドマイカメタリ
ック塗装の上に独特のメタリック感を有する花が描か
れ、従来の塗装では得られない意匠を有していた。 （実施例２０）鋼板に電着塗装、中塗り塗装を施した塗
板に、ポリエステルメラミン系の白色塗装を行い１４０
℃で３０分間焼付けた。その表面に、平均粒径１８μｍ
のホワイトマイカ顔料を６．０重量％含有し固形分４０
重量％のマイカベース塗料を約１５μｍの膜厚となるよ
うに塗装したこと以外は実施例４と同様にして、模様塗
膜を形成した。なお、白色塗膜上のベース塗膜の明度は
Ｌ値で７９であり、模様層の膜厚は最大で約２μｍであ
って隠蔽膜厚未満となっている。The resulting patterned coating film had a unique metallic appearance on the red mica metallic coating, and had a design that could not be obtained by conventional coating. (Example 20) A white sheet of polyester melamine was applied to a steel sheet which had been subjected to electrodeposition coating and intermediate coating.
Bake at 300C for 30 minutes. The surface has an average particle size of 18 μm
Containing 6.0% by weight of a white mica pigment having a solid content of 40%
A patterned coating film was formed in the same manner as in Example 4 except that the mica base paint was applied to a thickness of about 15 μm by weight. The lightness of the base coating film on the white coating film was 79 in L value, and the maximum thickness of the pattern layer was about 2 μm, which was less than the concealing film thickness.
【００３７】得られた模様塗膜は、パールマイカメタリ
ック塗装の上に独特のメタリック感を有する花が描か
れ、従来の塗装では得られない意匠を有していた。 （実施例２１）ベース塗料として、平均粒径１５μｍの
アルミニウム顔料３．０重量％と、赤色顔料０．１重量
％、黄色顔料０．２重量％及び白色顔料３．４重量％を
含有し、固形分４０重量％のアクリルメラミン系のメタ
リックベース塗料を用いたこと以外は実施例４と同様に
して、模様塗膜を形成した。なお、ベース塗膜の明度は
Ｌ値で４８であり、模様層の膜厚は最大で約２μｍであ
って隠蔽膜厚未満となっている。The resulting patterned coating film had a unique metallic appearance on the pearl mica metallic coating, and had a design that could not be obtained by conventional coating. (Example 21) As a base coating material, containing 3.0% by weight of an aluminum pigment having an average particle size of 15 μm, 0.1% by weight of a red pigment, 0.2% by weight of a yellow pigment, and 3.4% by weight of a white pigment, A patterned coating film was formed in the same manner as in Example 4 except that an acrylic melamine-based metallic base paint having a solid content of 40% by weight was used. The lightness of the base coating film is 48 in L value, and the maximum thickness of the pattern layer is about 2 μm, which is less than the concealing film thickness.
【００３８】得られた模様塗膜は、メタリック塗装の上
に独特のメタリック感を有する花が描かれ、実施例１５
〜２０には及ばないものの、従来の塗装では得られない
意匠を有していた。 （実施例２２）ベース塗料として、平均粒径１１μｍの
アルミニウム顔料２５．０重量％と、赤色顔料０．１重
量％、黄色顔料０．２重量％及び白色顔料３．４重量％
を含有し、固形分４０重量％のアクリルメラミン系のメ
タリックベース塗料を用いたこと以外は実施例４と同様
にして、模様塗膜を形成した。なお、ベース塗膜の明度
はＬ値で６５であり、模様層の膜厚は最大で約２μｍで
あって隠蔽膜厚未満となっている。In the obtained patterned coating film, a flower having a unique metallic feeling was drawn on the metallic coating.
It had a design that could not be obtained by conventional painting, although it was less than -20. Example 22 25.0% by weight of an aluminum pigment having an average particle diameter of 11 μm, 0.1% by weight of a red pigment, 0.2% by weight of a yellow pigment, and 3.4% by weight of a white pigment as base paints
And a patterned coating film was formed in the same manner as in Example 4 except that an acrylic melamine-based metallic base paint having a solid content of 40% by weight was used. The lightness of the base coating film is 65 in L value, and the maximum thickness of the pattern layer is about 2 μm, which is less than the concealing film thickness.
【００３９】得られた模様塗膜は、メタリック塗装の上
に独特のメタリック感を有する花が描かれ、実施例１５
〜２０には及ばないものの、従来の塗装では得られない
意匠を有していた。 （実施例２３）ベース塗料として、平均粒径８μｍのア
ルミニウム顔料２０．０重量％と、赤色顔料０．１重量
％、黄色顔料０．２重量％及び白色顔料３．４重量％を
含有し、固形分４０重量％のアクリルメラミン系のメタ
リックベース塗料を用いたこと以外は実施例４と同様に
して、模様塗膜を形成した。なお、ベース塗膜の明度は
Ｌ値で５２であり、模様層の膜厚は最大で約２μｍであ
って隠蔽膜厚未満となっている。In the obtained patterned coating film, a flower having a unique metallic feeling was drawn on the metallic coating.
It had a design that could not be obtained by conventional painting, although it was less than -20. (Example 23) As a base coating material, containing 20.0% by weight of an aluminum pigment having an average particle size of 8 μm, 0.1% by weight of a red pigment, 0.2% by weight of a yellow pigment, and 3.4% by weight of a white pigment, A patterned coating film was formed in the same manner as in Example 4 except that an acrylic melamine-based metallic base paint having a solid content of 40% by weight was used. The lightness of the base coating film is 52 in L value, and the maximum thickness of the pattern layer is about 2 μm, which is less than the concealing film thickness.
【００４０】得られた模様塗膜は、メタリック塗装の上
に独特のメタリック感を有する花が描かれ、実施例１５
〜２０には及ばないものの、従来の塗装では得られない
意匠を有していた。 （実施例２４）ベース塗料として、平均粒径３５μｍの
レッドマイカ顔料１０．０重量％と、赤色顔料９．０重
量％を含有し、固形分４０重量％のアクリルメラミン系
のマイカメタリックベース塗料を用いたこと以外は実施
例４と同様にして、模様塗膜を形成した。なお、ベース
塗膜の明度はＬ値で３４であり、模様層の膜厚は最大で
約２μｍであって隠蔽膜厚未満となっている。In the obtained patterned coating film, a flower having a unique metallic feeling was drawn on the metallic coating.
It had a design that could not be obtained by conventional painting, although it was less than -20. (Example 24) As a base paint, an acrylic melamine-based mica metallic base paint containing 10.0% by weight of a red mica pigment having an average particle diameter of 35 μm and 9.0% by weight of a red pigment and having a solid content of 40% by weight was used. A patterned coating film was formed in the same manner as in Example 4 except that the coating film was used. The lightness of the base coating film is 34 in L value, and the maximum thickness of the pattern layer is about 2 μm, which is less than the concealing film thickness.
【００４１】得られた模様塗膜は、メタリック塗装の上
に独特のメタリック感を有する花が描かれ、実施例１５
〜２０には及ばないものの、従来の塗装では得られない
意匠を有していた。 （実施例２５）ベース塗料として、平均粒径１７μｍの
ホワイトマイカ顔料３．０重量％と、平均粒径１７μｍ
のブルーマイカ顔料３．０重量％、黒色顔料２．０重量
％、緑色顔料０．２重量％及び青色顔料２．０重量％を
含有し、固形分４０重量％のアクリルメラミン系のマイ
カメタリックベース塗料を用いたこと以外は実施例４と
同様にして、模様塗膜を形成した。なお、ベース塗膜の
明度はＬ値で１４であり、模様層の膜厚は最大で約２μ
ｍであって隠蔽膜厚未満となっている。In the obtained patterned coating film, a flower having a unique metallic feeling was drawn on the metallic coating.
It had a design that could not be obtained by conventional painting, although it was less than -20. (Example 25) As a base coating material, 3.0% by weight of a white mica pigment having an average particle size of 17 µm and an average particle size of 17 µm
Acrylic melamine mica metallic base containing 3.0% by weight of blue mica pigment, 2.0% by weight of black pigment, 0.2% by weight of green pigment and 2.0% by weight of blue pigment and having a solid content of 40% by weight A pattern coating film was formed in the same manner as in Example 4 except that a paint was used. The lightness of the base coating film is 14 in L value, and the thickness of the pattern layer is about 2 μm at the maximum.
m, which is less than the concealed film thickness.
【００４２】得られた模様塗膜は、メタリック塗装の上
に独特のメタリック感を有する花が描かれ、実施例１５
〜２０には及ばないものの、従来の塗装では得られない
意匠を有していた。上記実施例１５〜２５に用いたベー
ス塗料の光輝材の含有量、粒径及びベース塗膜のＬ値を
表３にまとめて示す。In the obtained patterned coating film, a flower having a unique metallic feeling was drawn on the metallic coating.
It had a design that could not be obtained by conventional painting, although it was less than -20. Table 3 collectively shows the content of the brilliant material, the particle size, and the L value of the base coating film of the base paint used in Examples 15 to 25.
【００４３】[0043]
【表３】 上記の結果より、光輝材の含有量は１０〜５０重量％が
望ましく、光輝材の平均粒径は１０〜３０μｍが望まし
く、ベース塗膜のＬ値は２０以上が望ましいと考えられ
る。[Table 3] From the above results, it is considered that the content of the glittering material is desirably 10 to 50% by weight, the average particle diameter of the glittering material is desirably 10 to 30 μm, and the L value of the base coating film is desirably 20 or more.
【００４４】（実施例２６）ポリプロピレン製板材に塩
素化ポリプロピレンを主体とするプライマーを塗装し、
１２０℃で５分間予備加熱した後、アルミニウム顔料１
４重量％、青色顔料１重量％及び微量の黒色顔料を含有
する固形分４０重量％のアクリルメラミン系の溶剤型シ
ルバーメタリック色ベース塗料を約１５μｍの膜厚とな
るように塗装し、次いでアクリルメラミン系の溶剤型ク
リア塗料を約３０μｍの膜厚となるように塗装して、１
２０℃で３０分間焼付けた。(Example 26) A primer mainly composed of chlorinated polypropylene was applied to a polypropylene plate material.
After preheating at 120 ° C. for 5 minutes, the aluminum pigment 1
An acrylic melamine-based solvent-based silver metallic color base paint containing 4% by weight, a blue pigment 1% by weight, and a solid content of 40% by weight containing a small amount of black pigment is applied so as to have a film thickness of about 15 μm. Of the solvent type clear paint to a film thickness of about 30 μm.
Bake at 20 ° C. for 30 minutes.
【００４５】次に、顔料濃度は表１と同様の水性インク
を用い、実施例１と同様にイメージスキャナーで読みと
った花の写真のイメージデータを用いて、インクジェッ
ト方式により花の模様塗装を行った。なお形成された模
様層の膜厚は最大で約１．５μｍであり、隠蔽膜厚未満
となっている。次いでアクリルメラミン系の溶剤型クリ
ア塗料を約３０μｍの膜厚となるように塗装し、１２０
℃で３０分間焼付けて模様塗膜を形成した。その結果、
シルバーメタリック色の中に独特のメタリック感を有す
る花が鮮明に描かれ、従来の塗装では得られない意匠を
有していた。Next, using a water-based ink having the same pigment concentration as in Table 1, a flower pattern was painted by an ink-jet method using image data of a photograph of a flower read by an image scanner in the same manner as in Example 1. . The maximum thickness of the formed pattern layer is about 1.5 μm, which is less than the concealment thickness. Next, an acrylic melamine-based solvent-type clear paint is applied so as to have a thickness of about 30 μm.
Baking at 30 ° C. for 30 minutes to form a patterned coating film. as a result,
Flowers having a unique metallic feeling were clearly drawn in the silver metallic color, and had designs that could not be obtained by conventional painting.
【００４６】（実施例２７）シルバーメタリックベース
塗料を塗装した後、溶剤型のインクを用いて模様層を塗
装し、アクリルメラミン系の水性クリア塗料を用いてク
リア塗膜を形成したこと以外は実施例２７と同様にし
て、模様塗膜を形成した。その結果、シルバーメタリッ
ク色の中に独特のメタリック感を有する花が鮮明に描か
れ、従来の塗装では得られない意匠を有していた。(Example 27) After applying a silver metallic base coating material, a pattern layer was applied using a solvent type ink, and a clear coating film was formed using an acrylic melamine-based aqueous clear coating material. 27, a pattern coating film was formed. As a result, flowers having a unique metallic feeling were clearly drawn in the silver metallic color, and had designs that could not be obtained by conventional painting.
【００４７】（実施例２８）ポリプロピレン製板材に塩
素化ポリプロピレンを主体とするプライマーを塗装し、
１２０℃で５分間予備加熱した後、アルミニウム顔料１
４重量％、青色顔料１重量％及び微量の黒色顔料を含有
する固形分４０重量％のアクリルメラミン系の溶剤型シ
ルバーメタリック色ベース塗料を約１５μｍの膜厚とな
るように塗装し、１２０℃で５分間予備加熱をおこなっ
た。(Example 28) A primer mainly composed of chlorinated polypropylene was applied to a polypropylene plate material,
After preheating at 120 ° C. for 5 minutes, the aluminum pigment 1
An acrylic melamine-based solvent-type silver metallic color base paint containing 4% by weight, 1% by weight of a blue pigment and 40% by weight of a solid content containing a small amount of a black pigment is applied so as to have a thickness of about 15 μm. Preheating was performed for minutes.
【００４８】次に顔料濃度は表１と同様の水性インクを
用い、実施例１と同様にイメージスキャナーで読みとっ
た花の写真のイメージデータを用いて、インクジェット
塗装により花の模様塗装を行った。なお形成された模様
層の膜厚は最大で約１．５μｍであり、隠蔽膜厚未満と
なっている。次いでアクリルメラミン系の溶剤型クリア
塗料を約３０μｍの膜厚となるように塗装し、１２０℃
で３０分間焼付けて模様塗膜を形成した。その結果、シ
ルバーメタリック色の中に独特のメタリック感を有する
花が鮮明に描かれ、従来の塗装では得られない意匠を有
していた。Next, the pigment concentration was determined by using the same water-based ink as in Table 1 and, in the same manner as in Example 1, using the image data of a flower photograph read by an image scanner to paint a flower pattern by ink-jet coating. The maximum thickness of the formed pattern layer is about 1.5 μm, which is less than the concealment thickness. Next, an acrylic melamine-based solvent-type clear paint is applied so as to have a thickness of about 30 μm.
For 30 minutes to form a patterned coating. As a result, flowers having a unique metallic feeling were clearly drawn in the silver metallic color, and had designs that could not be obtained by conventional painting.
【００４９】（実施例２９）シルバーメタリック塗膜の
予備乾燥を行わずに水性インクを用いて模様塗装を行っ
たこと以外は実施例２８と同様である。その結果、シル
バーメタリック色の中に独特のメタリック感を有する花
が鮮明に描かれ、従来の塗装では得られない意匠を有し
ていた。(Example 29) The same as Example 28, except that the pattern coating was performed using the aqueous ink without performing the preliminary drying of the silver metallic coating film. As a result, flowers having a unique metallic feeling were clearly drawn in the silver metallic color, and had designs that could not be obtained by conventional painting.
【００５０】（実施例３０）シルバーメタリック塗料に
水性塗料を用い、模様塗装に溶剤型インクを用い、かつ
水性クリア塗料を用いたこと以外は実施例２８と同様で
ある。その結果、シルバーメタリック色の中に独特のメ
タリック感を有する花が鮮明に描かれ、従来の塗装では
得られない意匠を有していた。Example 30 The procedure was the same as that of Example 28, except that an aqueous paint was used for the silver metallic paint, a solvent type ink was used for the pattern coating, and an aqueous clear paint was used. As a result, flowers having a unique metallic feeling were clearly drawn in the silver metallic color, and had designs that could not be obtained by conventional painting.
【００５１】（実施例３１）シルバーメタリック塗料に
水性塗料を用い、模様塗装に溶剤型インクを用い、かつ
水性クリア塗料を用い、かつシルバーメタリック塗膜の
予備乾燥を行わずに模様塗装を行ったこと以外は実施例
２８と同様である。その結果、シルバーメタリック色の
中に独特のメタリック感を有する花が鮮明に描かれ、従
来の塗装では得られない意匠を有していた。(Example 31) Except that a water-based paint was used for a silver metallic paint, a solvent-based ink was used for a pattern paint, an aqueous clear paint was used, and the pattern paint was performed without pre-drying the silver metallic paint film. Is the same as in Example 28. As a result, flowers having a unique metallic feeling were clearly drawn in the silver metallic color, and had designs that could not be obtained by conventional painting.
【００５２】（実施例３２）模様塗装に溶剤型インクを
用い、かつ溶剤型クリア塗料を用いたこと以外は実施例
２６と同様である。その結果、実施例２６〜３１には及
ばないものの、シルバーメタリック色の中に独特のメタ
リック感を有する花が鮮明に描かれ、従来の塗装では得
られない意匠を有していた。Example 32 The procedure was the same as that of Example 26 except that a solvent type ink was used for the pattern coating and a solvent type clear coating was used. As a result, flowers having a unique metallic feeling were clearly drawn in the silver metallic color, though not as good as Examples 26 to 31, and had designs that could not be obtained by conventional painting.
【００５３】（実施例３３）模様塗装に水性インクを用
い、かつ水性クリア塗料を用いたこと以外は実施例２６
と同様である。その結果、実施例２６〜３１には及ばな
いものの、シルバーメタリック色の中に独特のメタリッ
ク感を有する花が鮮明に描かれ、従来の塗装では得られ
ない意匠を有していた。Example 33 Example 26 was repeated except that an aqueous ink was used for the pattern coating and an aqueous clear paint was used.
Is the same as As a result, flowers having a unique metallic feeling were clearly drawn in the silver metallic color, though not as good as Examples 26 to 31, and had designs that could not be obtained by conventional painting.
【００５４】（実施例３４）溶剤型のシルバーメタリッ
ク塗料を用い、模様塗装に溶剤型インクを用い、かつ水
性クリア塗料を用いたこと以外は実施例２８と同様であ
る。その結果、実施例２６〜３１には及ばないものの、
シルバーメタリック色の中に独特のメタリック感を有す
る花が鮮明に描かれ、従来の塗装では得られない意匠を
有していた。Example 34 The same procedure as in Example 28 was carried out except that a solvent type silver metallic paint was used, a solvent type ink was used for pattern painting, and an aqueous clear paint was used. As a result, although it does not reach Examples 26 to 31,
Flowers having a unique metallic feeling were clearly drawn in the silver metallic color, and had designs that could not be obtained by conventional painting.
【００５５】（実施例３５）溶剤型のシルバーメタリッ
ク塗料を用い、模様塗装に水性インクを用い、かつ水性
クリア塗料を用いたこと以外は実施例２８と同様であ
る。その結果、実施例２６〜３１には及ばないものの、
シルバーメタリック色の中に独特のメタリック感を有す
る花が鮮明に描かれ、従来の塗装では得られない意匠を
有していた。(Example 35) The same as Example 28 except that a solvent type silver metallic paint was used, an aqueous ink was used for the pattern coating, and an aqueous clear paint was used. As a result, although it does not reach Examples 26 to 31,
Flowers having a unique metallic feeling were clearly drawn in the silver metallic color, and had designs that could not be obtained by conventional painting.
【００５６】（実施例３６）水性のシルバーメタリック
塗料を用い、模様塗装に水性インクを用い、かつ溶剤型
クリア塗料を用いたこと以外は実施例２８と同様であ
る。その結果、実施例２６〜３１には及ばないものの、
シルバーメタリック色の中に独特のメタリック感を有す
る花が鮮明に描かれ、従来の塗装では得られない意匠を
有していた。Example 36 The procedure was the same as that of Example 28, except that an aqueous silver metallic paint was used, an aqueous ink was used for the pattern coating, and a solvent type clear paint was used. As a result, although it does not reach Examples 26 to 31,
Flowers having a unique metallic feeling were clearly drawn in the silver metallic color, and had designs that could not be obtained by conventional painting.
【００５７】（実施例３７）溶剤型シルバーメタリック
塗料を用い、模様塗装に溶剤型インクを用い、かつ水性
クリア塗料を用い、さらにシルバーメタリック塗膜の予
備乾燥を行わずに模様塗装を行ったこと以外は実施例２
８と同様である。その結果、実施例２６〜３１には及ば
ないものの、シルバーメタリック色の中に独特のメタリ
ック感を有する花が鮮明に描かれ、従来の塗装では得ら
れない意匠を有していた。Example 37 A solvent-type silver metallic paint was used, a solvent-type ink was used for pattern painting, an aqueous clear paint was used, and the pattern painting was performed without further drying the silver metallic coating film. Example 2
Same as 8. As a result, flowers having a unique metallic feeling were clearly drawn in the silver metallic color, though not as good as Examples 26 to 31, and had designs that could not be obtained by conventional painting.
【００５８】（実施例３８）溶剤型シルバーメタリック
塗料を用い、模様塗装に水性インクを用い、かつ水性ク
リア塗料を用い、さらにシルバーメタリック塗膜の予備
乾燥を行わずに模様塗装を行ったこと以外は実施例２８
と同様である。その結果、実施例２６〜３１には及ばな
いものの、シルバーメタリック色の中に独特のメタリッ
ク感を有する花が鮮明に描かれ、従来の塗装では得られ
ない意匠を有していた。Example 38 A solvent-type silver metallic paint was used, a water-based ink was used for the pattern coating, an aqueous clear paint was used, and the pattern coating was performed without pre-drying the silver metallic coating film. Example 28
Is the same as As a result, flowers having a unique metallic feeling were clearly drawn in the silver metallic color, though not as good as Examples 26 to 31, and had designs that could not be obtained by conventional painting.
【００５９】（実施例３９）水性シルバーメタリック塗
料を用い、模様塗装に水性インクを用い、かつ溶剤型ク
リア塗料を用い、さらにシルバーメタリック塗膜の予備
乾燥を行わずに模様塗装を行ったこと以外は実施例２８
と同様である。その結果、実施例２６〜３１には及ばな
いものの、シルバーメタリック色の中に独特のメタリッ
ク感を有する花が鮮明に描かれ、従来の塗装では得られ
ない意匠を有していた。Example 39 A water-based silver metallic paint was used, a water-based ink was used for pattern painting, a solvent-type clear paint was used, and the pattern was painted without pre-drying the silver metallic coating. Example 28
Is the same as As a result, flowers having a unique metallic feeling were clearly drawn in the silver metallic color, though not as good as Examples 26 to 31, and had designs that could not be obtained by conventional painting.
【００６０】（実施例４０）溶剤型シルバーメタリック
塗料を用い、模様塗装に溶剤型インクを用い、かつ溶剤
型クリア塗料を用いたこと以外は実施例２８と同様であ
る。その結果、実施例２６〜３１には及ばないものの、
シルバーメタリック色の中に独特のメタリック感を有す
る花が鮮明に描かれ、従来の塗装では得られない意匠を
有していた。Example 40 The same as Example 28 except that a solvent-type silver metallic paint was used, a solvent-type ink was used for pattern painting, and a solvent-type clear paint was used. As a result, although it does not reach Examples 26 to 31,
Flowers having a unique metallic feeling were clearly drawn in the silver metallic color, and had designs that could not be obtained by conventional painting.
【００６１】（実施例４１）溶剤型シルバーメタリック
塗料を用い、模様塗装に溶剤型インクを用い、かつ溶剤
型クリア塗料を用い、さらにシルバーメタリック塗膜の
予備乾燥を行わずに模様塗装を行ったこと以外は実施例
２８と同様である。その結果、実施例２６〜３１には及
ばないものの、シルバーメタリック色の中に独特のメタ
リック感を有する花が鮮明に描かれ、従来の塗装では得
られない意匠を有していた。(Example 41) Except that a solvent-type silver metallic paint was used, a solvent-type ink was used for the pattern coating, a solvent-type clear paint was used, and the pattern coating was performed without further drying the silver-metallic coating film. Is the same as in Example 28. As a result, flowers having a unique metallic feeling were clearly drawn in the silver metallic color, though not as good as Examples 26 to 31, and had designs that could not be obtained by conventional painting.
【００６２】（実施例４２）水性シルバーメタリック塗
料を用い、模様塗装に水性インクを用い、かつ水性クリ
ア塗料を用いたこと以外は実施例２８と同様である。そ
の結果、実施例２６〜３１には及ばないものの、シルバ
ーメタリック色の中に独特のメタリック感を有する花が
鮮明に描かれ、従来の塗装では得られない意匠を有して
いた。Example 42 Example 28 was the same as Example 28 except that a water-based silver metallic paint was used, a water-based ink was used for pattern painting, and a water-based clear paint was used. As a result, flowers having a unique metallic feeling were clearly drawn in the silver metallic color, though not as good as Examples 26 to 31, and had designs that could not be obtained by conventional painting.
【００６３】（実施例４３）水性シルバーメタリック塗
料を用い、模様塗装に水性インクを用い、かつ水性クリ
ア塗料を用い、さらにシルバーメタリック塗膜の予備乾
燥を行わずに模様塗装を行ったこと以外は実施例２８と
同様である。その結果、実施例２６〜３１には及ばない
ものの、シルバーメタリック色の中に独特のメタリック
感を有する花が鮮明に描かれ、従来の塗装では得られな
い意匠を有していた。(Example 43) An aqueous silver metallic paint was used, an aqueous ink was used for the pattern application, an aqueous clear paint was used, and the pattern was applied without preliminary drying of the silver metallic coating. Same as 28. As a result, flowers having a unique metallic feeling were clearly drawn in the silver metallic color, though not as good as Examples 26 to 31, and had designs that could not be obtained by conventional painting.
【００６４】[0064]
【発明の効果】すなわち請求項１及び請求項２に記載の
本発明のメタリック感を有する模様塗膜の形成方法によ
れば、従来にない独特のメタリック感を有し、かつ鮮明
な模様を容易に形成することができる。また請求項３に
記載の模様塗膜の形成方法によれば、模様層中に表出す
るメタリック感が一層鮮明になり、請求項４に記載の模
様塗膜の形成方法によれば滲みが発生しないので模様層
の色調及び輪郭を一層鮮明とすることができる。According to the method for forming a patterned paint film having a metallic feeling according to the present invention as described in the first and second aspects, a clear metallic pattern having a unique metallic feeling and a clear pattern can be easily obtained. Can be formed. Further, according to the method for forming a patterned coating film according to the third aspect, the metallic feeling appearing in the pattern layer becomes clearer, and according to the method for forming a patterned coated film according to the fourth aspect, bleeding occurs. As a result, the color tone and contour of the pattern layer can be further sharpened.
【図１】本発明の実施例１で形成された模様塗膜の模式
的断面図である。FIG. 1 is a schematic sectional view of a patterned coating film formed in Example 1 of the present invention.
【図２】本発明の実施例４で形成された模様塗膜の模式
的断面図である。FIG. 2 is a schematic sectional view of a patterned coating film formed in Example 4 of the present invention.
１：中塗り塗膜 ２：ベース塗膜
３：模様層 ４：クリア塗膜 ５：中間クリア塗膜1: Intermediate coating 2: Base coating
3: Pattern layer 4: Clear coating film 5: Intermediate clear coating film
───────────────────────────────────────────────────── フロントページの続き (72)発明者 杉浦 護 愛知県豊田市トヨタ町１番地 トヨタ自動 車株式会社内 (72)発明者 堀部 恭一 神奈川県平塚市東八幡４丁目17番１号 関 西ぺイント株式会社内 (72)発明者 林 由紀子 神奈川県平塚市東八幡４丁目17番１号 関 西ぺイント株式会社内 ──────────────────────────────────────────────────続 き Continuing from the front page (72) Inventor Mamoru Sugiura 1 Toyota Town, Toyota City, Aichi Prefecture Inside Toyota Motor Corporation (72) Inventor Kyoichi Horibe 4-171-1, Higashi-Hachiman, Hiratsuka City, Kanagawa Prefecture Kansai West Point Inside (72) Inventor Yukiko Hayashi 4-1-1, Higashi-Hachiman, Hiratsuka-shi, Kanagawa
Claims (4)
ベース塗膜を形成し、該ベース塗膜の表面に模様塗料を
その隠蔽膜厚未満の膜厚で塗装して模様層を形成するこ
とを特徴とするメタリック感を有する模様塗膜の形成方
法。1. A base paint containing a glittering material is applied to form a base coat, and a pattern paint is applied on the surface of the base coat with a thickness less than the concealing thickness to form a pattern layer. A method for forming a patterned coating film having a metallic feeling.
ベース塗膜を形成し、該ベース塗膜の表面にクリア塗料
を塗装してクリア塗膜を形成し、該クリア塗膜の表面に
模様塗料をその隠蔽膜厚未満の膜厚で塗装して模様層を
形成することを特徴とするメタリック感を有する模様塗
膜の形成方法。2. A base paint containing a glittering material is applied to form a base paint film, and a clear paint is applied to the surface of the base paint film to form a clear paint film. A method for forming a patterned coating film having a metallic feeling, wherein a patterned layer is formed by applying a patterned paint with a thickness less than the concealing thickness.
であり、該光輝材は該ベース塗料中に該ベース塗膜１０
０重量部に対して１０〜５０重量％含有され、かつ該ベ
ース塗膜の明度がＬ値で２０以上であることを特徴とす
る請求項１または請求項２記載のメタリック感を有する
模様塗膜の形成方法。3. The glitter material has an average particle size of 10 to 30 μm.
And the glittering material is contained in the base paint in the base paint.
3. The patterned paint film having a metallic feeling according to claim 1 or 2, wherein the paint film is contained in an amount of 10 to 50% by weight based on 0 parts by weight, and the lightness of the base coat is 20 or more in L value. Formation method.
料から形成された塗膜とを交互に形成することを特徴と
する請求項１または請求項２記載のメタリック感を有す
る模様塗膜の形成方法。4. The patterned paint film having a metallic feeling according to claim 1, wherein a paint film formed from a water-based paint and a paint film formed from a solvent-based paint are alternately formed. Formation method.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8204520A JPH1043675A (en) | 1996-08-02 | 1996-08-02 | Formation of patterned coating film giving metallic impression |
| CA002211726A CA2211726A1 (en) | 1996-08-02 | 1997-07-30 | Process for forming decorative paint film exhibiting metallic effect |
| EP97113357A EP0822011B1 (en) | 1996-08-02 | 1997-08-01 | Process for forming decorative paint film exhibiting metallic effect |
| KR1019970036800A KR100244574B1 (en) | 1996-08-02 | 1997-08-01 | Forming decorative paint film exhibiting metallic effect |
| DE69717556T DE69717556T2 (en) | 1996-08-02 | 1997-08-01 | Process for the production of lacquer coating with metallic gloss effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8204520A JPH1043675A (en) | 1996-08-02 | 1996-08-02 | Formation of patterned coating film giving metallic impression |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH1043675A true JPH1043675A (en) | 1998-02-17 |
Family
ID=16491900
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8204520A Pending JPH1043675A (en) | 1996-08-02 | 1996-08-02 | Formation of patterned coating film giving metallic impression |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0822011B1 (en) |
| JP (1) | JPH1043675A (en) |
| KR (1) | KR100244574B1 (en) |
| CA (1) | CA2211726A1 (en) |
| DE (1) | DE69717556T2 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030042765A (en) * | 2001-11-23 | 2003-06-02 | 주식회사 엘지이아이 | Painting method of refrigerator door |
| JP2007154431A (en) * | 2005-11-30 | 2007-06-21 | Kubota Matsushitadenko Exterior Works Ltd | Decorative building board |
| JP2011131186A (en) * | 2009-12-25 | 2011-07-07 | Kansai Paint Co Ltd | Method of forming multilayer coating film |
| US8071170B2 (en) | 2006-01-23 | 2011-12-06 | Kansai Paint Co., Ltd. | Method of forming multi-layered patterned coating film |
| JP2016000815A (en) * | 2007-01-29 | 2016-01-07 | セイコーエプソン株式会社 | Ink set, inkjet recording method and recorded matter |
| US9616675B2 (en) | 2007-03-01 | 2017-04-11 | Seiko Epson Corporation | Ink set, ink-jet recording method, and recorded material |
| US9790386B2 (en) | 2006-11-30 | 2017-10-17 | Seiko Epson Corporation | Ink composition, two-pack curing ink composition set, and recording method and recorded matter using these |
| US11241889B2 (en) | 2008-10-24 | 2022-02-08 | Dürr Systems GmbH | Coating device and associated coating method |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6376016B1 (en) | 2000-06-14 | 2002-04-23 | Ford Global Tech., Inc. | Method for painting a vehicle with at least two colors |
| US6451117B1 (en) | 2000-08-11 | 2002-09-17 | Ford Global Tech., Inc. | Paint mask and a method for utilizing the same |
| FR2905914B1 (en) * | 2006-09-20 | 2008-11-14 | Renault Sas | MOTOR VEHICLE WITH BODY COVERED BY AN OUTSIDE DECORATION AND PROTECTION ASSEMBLY |
| US8507077B1 (en) | 2012-09-12 | 2013-08-13 | Krow Innovation, Llc | Camouflage branding system and method |
| DE102013002433A1 (en) * | 2013-02-11 | 2014-08-14 | Dürr Systems GmbH | Painting process and painting plant for decorative stripes |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS591111B2 (en) * | 1979-02-28 | 1984-01-10 | 凸版印刷株式会社 | Decorative board manufacturing method |
| US4551491A (en) * | 1983-07-29 | 1985-11-05 | Inmont Corporation | Pearlescent automotive paint compositions |
| JPS60118266A (en) * | 1983-11-29 | 1985-06-25 | Toyota Motor Corp | Two-tone coating method |
| US4598015A (en) * | 1984-12-11 | 1986-07-01 | Inmont Corporation | Multilayer satin finish automotive paint system |
| JPS62216671A (en) * | 1986-03-17 | 1987-09-24 | Nippon Paint Co Ltd | Metallic coating method |
| CA2010818A1 (en) * | 1989-03-22 | 1990-09-22 | Sol Panush | Coating system exhibiting color travel and opalescent color effects |
| AU5138090A (en) * | 1989-03-22 | 1990-09-27 | Basf Corporation | Coating system with metallic basecoat exhibiting dichromatic hue shift effects |
| US5106682A (en) * | 1989-03-25 | 1992-04-21 | Sumitomo Electric Industries Ltd. | Fluororesin-coated article |
| US4971841A (en) * | 1989-06-08 | 1990-11-20 | Basf Corporation | Reflective automotive coating compositions |
| JPH0312263A (en) * | 1989-06-12 | 1991-01-21 | Nissan Motor Co Ltd | Method for forming urushi like film |
| GB2257929A (en) * | 1991-06-19 | 1993-01-27 | Tudor Hart George Henry | Distressed paint finishes |
| JPH07108216A (en) * | 1993-10-08 | 1995-04-25 | Toyota Auto Body Co Ltd | Metallic painted product and production thereof |
-
1996
- 1996-08-02 JP JP8204520A patent/JPH1043675A/en active Pending
-
1997
- 1997-07-30 CA CA002211726A patent/CA2211726A1/en not_active Abandoned
- 1997-08-01 EP EP97113357A patent/EP0822011B1/en not_active Expired - Lifetime
- 1997-08-01 DE DE69717556T patent/DE69717556T2/en not_active Expired - Fee Related
- 1997-08-01 KR KR1019970036800A patent/KR100244574B1/en not_active IP Right Cessation
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030042765A (en) * | 2001-11-23 | 2003-06-02 | 주식회사 엘지이아이 | Painting method of refrigerator door |
| JP2007154431A (en) * | 2005-11-30 | 2007-06-21 | Kubota Matsushitadenko Exterior Works Ltd | Decorative building board |
| US8071170B2 (en) | 2006-01-23 | 2011-12-06 | Kansai Paint Co., Ltd. | Method of forming multi-layered patterned coating film |
| US9790386B2 (en) | 2006-11-30 | 2017-10-17 | Seiko Epson Corporation | Ink composition, two-pack curing ink composition set, and recording method and recorded matter using these |
| JP2016000815A (en) * | 2007-01-29 | 2016-01-07 | セイコーエプソン株式会社 | Ink set, inkjet recording method and recorded matter |
| JP2018109182A (en) * | 2007-01-29 | 2018-07-12 | セイコーエプソン株式会社 | Ink set, inkjet recording method and recorded matter |
| JP2021011112A (en) * | 2007-01-29 | 2021-02-04 | セイコーエプソン株式会社 | Inkjet recording method, and inkjet printer |
| US9616675B2 (en) | 2007-03-01 | 2017-04-11 | Seiko Epson Corporation | Ink set, ink-jet recording method, and recorded material |
| US11241889B2 (en) | 2008-10-24 | 2022-02-08 | Dürr Systems GmbH | Coating device and associated coating method |
| JP2011131186A (en) * | 2009-12-25 | 2011-07-07 | Kansai Paint Co Ltd | Method of forming multilayer coating film |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2211726A1 (en) | 1998-02-02 |
| EP0822011B1 (en) | 2002-12-04 |
| EP0822011A2 (en) | 1998-02-04 |
| DE69717556T2 (en) | 2003-04-17 |
| KR19980018278A (en) | 1998-06-05 |
| DE69717556D1 (en) | 2003-01-16 |
| KR100244574B1 (en) | 2000-02-15 |
| EP0822011A3 (en) | 1999-05-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH1043675A (en) | Formation of patterned coating film giving metallic impression | |
| JP2002086057A (en) | Double-layered metallic coating film formation method | |
| JP2004188291A (en) | Method for coating resin component | |
| CN1057047C (en) | Method for transferring designs and patterns | |
| JPH11140346A (en) | Brilliant coating composition and method for forming brilliant composite coating film | |
| JPH11106686A (en) | Metallic finishing | |
| JPH11147069A (en) | Method for forming coating film of three-coating one-baking type high saturation metallic color | |
| JP2823147B2 (en) | How to apply metallic paint | |
| JPH10156279A (en) | Deep color metallic tone coating method and coated material | |
| JP3217467B2 (en) | Transfer sheet | |
| JP4079468B2 (en) | Metallic coating structure and method for forming metallic coating | |
| US6412939B1 (en) | Method for printing on non-porous surfaces | |
| KR102404801B1 (en) | Decoration having ink receptive layer for concealing substrate and method for manufacturing the same | |
| JPS6136360Y2 (en) | ||
| JP2001327916A (en) | Method for forming laminated pearl coating film | |
| JP3069848U (en) | Pearlescent paper | |
| JP2000095973A (en) | Clear coating composition for contaier outside surface | |
| JP3069862B2 (en) | Transfer sheet | |
| JP2849012B2 (en) | Painting method | |
| JP3430330B2 (en) | Decorative metal panels and decorative metal decorative panels | |
| JP2002224616A (en) | Coating film forming method and base material having coating film by coating film forming method | |
| JP3232370B2 (en) | Pattern paint film structure | |
| JPH0445171A (en) | Paint composition and formation of painted film | |
| JPS61100491A (en) | Recording material | |
| JP2001105529A (en) | Decorative panel and production method therefor |