JPH10251724A - Production of metallic iron and producing equipment therefor - Google Patents

Production of metallic iron and producing equipment therefor

Info

Publication number
JPH10251724A
JPH10251724A JP9122626A JP12262697A JPH10251724A JP H10251724 A JPH10251724 A JP H10251724A JP 9122626 A JP9122626 A JP 9122626A JP 12262697 A JP12262697 A JP 12262697A JP H10251724 A JPH10251724 A JP H10251724A
Authority
JP
Japan
Prior art keywords
iron
heating
compact
strip
metallic iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP9122626A
Other languages
Japanese (ja)
Inventor
Osamu Tsuchiya
脩 土屋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from PCT/JP1997/000806 external-priority patent/WO1997034018A1/en
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Priority to JP9122626A priority Critical patent/JPH10251724A/en
Publication of JPH10251724A publication Critical patent/JPH10251724A/en
Withdrawn legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide a method, in which iron oxide is efficiently reduced to a metallic iron at the time of obtaining the metallic iron by heating and reducing the iron oxide of iron ore, etc., together with carbon quality reducing agent of carbonaceous material, etc., and also, the high quality metallic iron can efficiently be produced as molten iron by melting and smoothly separating slag component mixed as gangue component, etc., in the iron oxide source of iron ore, etc., and an equipment thereof. SOLUTION: At the time of producing the metallic iron by heating and reducing the formed body of iron oxide containing the carbon quality reducing agent, the metallic iron outer shell is produced and grown by heating and reducing while continuously shifting under condition of laying the formed body on an iron-made band plate 1, and the reduction is progressed until the iron oxide does not substantially exist. Further, the slag is produced in the inner part of the formed body, and after melting the formed body together with the iron- made band plate 1 by further heating this formed body is separated into the molten slag S and the molten iron F.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、鉄鉱石等の酸化鉄
を炭材等の炭素質還元剤と共に加熱還元して金属鉄を得
る技術の改良に関し、特に、鉄鉱石等の酸化鉄を炭材な
どの炭素質還元剤と共に加熱して還元し金属鉄を得る際
に、酸化鉄を金属鉄にまで効率よく還元すると共に、鉄
鉱石などの酸化鉄源中に脈石成分等として混入してくる
スラグ成分をうまく溶融分離し、高純度の金属鉄を溶融
鉄として効率よく製造することのできる方法および設備
に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an improvement in a technique for obtaining metallic iron by heating and reducing iron oxide such as iron ore together with a carbonaceous reducing agent such as carbonaceous material, and more particularly, to improving iron oxide such as iron ore. When reducing iron oxide by heating with a carbonaceous reducing agent such as wood, it efficiently reduces iron oxide to metallic iron and mixes it as a gangue component in iron oxide sources such as iron ore. The present invention relates to a method and equipment capable of effectively melting and separating a coming slag component and efficiently producing high-purity metallic iron as molten iron.

【0002】[0002]

【従来の技術】鉄鉱石や酸化鉄ペレット等の酸化鉄を炭
材や還元性ガスにより直接還元して還元鉄を得る直接製
鉄法としては、従来よりミドレックス法に代表されるシ
ャフト炉法が知られている。この種の直接製鉄法は、天
然ガス等から製造される還元ガスをシャフト炉下部の羽
口より吹き込み、その還元力を利用し酸化鉄を還元して
還元鉄を得る方法である。また最近では、天然ガスに代
わる還元剤として石炭等の炭材を使用する還元鉄製造プ
ロセスが注目されており、具体的には、鉄鉱石等の焼成
ペレットを石炭粉と共にロータリーキルンで加熱還元す
る、所謂SL/RN法がすでに実用化されている。
2. Description of the Related Art As a direct iron making method of directly reducing iron oxide such as iron ore and iron oxide pellets with a carbon material or a reducing gas to obtain reduced iron, a shaft furnace method represented by the Midrex method has been conventionally used. Are known. This type of direct iron making method is a method in which a reducing gas produced from natural gas or the like is blown from a tuyere at a lower portion of a shaft furnace, and iron oxide is reduced using the reducing power to obtain reduced iron. Recently, a reduced iron production process using a coal material such as coal as a reducing agent in place of natural gas has been attracting attention.Specifically, calcined pellets such as iron ore are reduced by heating in a rotary kiln together with coal powder, The so-called SL / RN method has already been put to practical use.

【0003】また他の還元鉄製造法として米国特許第
3,443,931号公報には、炭材と粉状酸化鉄を混
合して塊状化し、ロータリーハース上で加熱還元して還
元鉄を製造するプロセスが開示されている。このプロセ
スは、粉鉱石と粉炭を混合して塊状化し、これを高温雰
囲気下で加熱還元するものである。
As another method for producing reduced iron, US Pat. No. 3,443,931 discloses a method in which a carbon material and powdered iron oxide are mixed to form a lump and reduced by heating on a rotary hearth to produce reduced iron. A process is disclosed. In this process, fine ore and fine coal are mixed and agglomerated, and this is heated and reduced in a high-temperature atmosphere.

【0004】これらの方法で製造された還元鉄は、その
まま或はブリケット状等に成形してから電気炉へ装入
し、鉄源として用いられる。近年、鉄スクラップのリサ
イクルが活発化するにつれて、上記方法によって得られ
る還元鉄はスクラップ中に混入してくる不純物元素の希
釈材として注目されている。
[0004] The reduced iron produced by these methods is used as an iron source as it is or after being shaped into a briquette or the like, and then charged into an electric furnace. In recent years, as the recycling of iron scrap has become more active, reduced iron obtained by the above method has attracted attention as a diluent for impurity elements mixed into the scrap.

【0005】ところが従来の還元製鉄法によって得られ
る還元鉄には、原料として用いた酸化鉄(鉄鉱石など)
や炭材(石炭など)に含まれるSiO2 、Al23
CaO等のスラグ成分がそのまま混入してくるため、製
品の鉄品位(金属鉄としての純度)は低くなる。実用に
当たっては、次の精錬工程でこれらのスラグ成分は分離
除去されるが、スラグ量の増加は精錬溶湯の歩留りを低
下させるばかりでなく電気炉の操業コストにも大きな影
響を及ぼすので、鉄品位が高くスラグ成分含有量の少な
い還元鉄が求められているが、前述の如き従来の還元鉄
の製法でこうした要求に応えるには、還元鉄製造原料と
して鉄品位の高い鉄鉱石を使用しなければならず、実用
可能な製鉄原料の選択の幅を大幅に狭めることになる。
[0005] However, the reduced iron obtained by the conventional reduction iron making method includes iron oxide (such as iron ore) used as a raw material.
SiO 2, Al 2 O 3 contained in or carbonaceous material (such as coal),
Since the slag component such as CaO is directly mixed, the iron quality (purity as metallic iron) of the product is lowered. In practical use, these slag components are separated and removed in the next smelting process. In order to meet such demands with the conventional method of producing reduced iron as described above, it is necessary to use high-grade iron ore as a raw material for producing reduced iron. Rather, the range of choice of practicable iron-making raw materials is greatly reduced.

【0006】更に上記の様な従来法は、還元された固体
製品を中間製品として得ることを最終の目的としてお
り、実用化に当たっては、次の工程となる精練工程へ送
るまでに搬送、貯蔵、ブリケット化あるいは冷却といっ
た工程が必要であり、この間に大きなエネルギー損失が
生じたり、ブリケット化のための余分のエネルギーや特
殊な装置が必要になるといった欠点がある。
Further, the conventional method as described above has a final object of obtaining a reduced solid product as an intermediate product, and in practical use, conveys, stores, and stores it before sending it to the next scouring process. A process such as briquetting or cooling is required. During this process, there are disadvantages such as a large energy loss, extra energy for briquetting and special equipment.

【0007】他方、酸化鉄を直接還元して還元鉄を得る
方法としてDIOS法等の溶融還元法も知られている。
この方法は、酸化鉄を予め鉄純度で30〜50%程度に
まで予備還元しておき、その後、鉄浴中で炭素と直接還
元反応させることによって金属鉄にまで還元を行う方法
であるが、この方法は予備還元と鉄浴中での最終還元の
2工程が必須になるため作業が煩雑であるばかりでなく
で、鉄浴中に存在する溶融酸化鉄(FeO)と耐火物が
直接接触するため、耐火物の損耗が激しいという問題も
指摘される。
On the other hand, as a method of directly reducing iron oxide to obtain reduced iron, a smelting reduction method such as a DIOS method is also known.
In this method, iron oxide is preliminarily reduced to an iron purity of about 30 to 50%, and then reduced to metallic iron by direct reduction reaction with carbon in an iron bath. In this method, two steps of pre-reduction and final reduction in an iron bath are indispensable, so that not only the operation is complicated, but also the molten iron oxide (FeO) present in the iron bath comes into direct contact with the refractory. Therefore, a problem that refractory wear is severe is pointed out.

【0008】更に特公昭56−19366号公報には、
金属酸化物と固体炭素質材料およびスラグ形成材料を含
む集塊物を加熱・還元し、該集塊物の形状を保ちなが
ら、還元により生成した金属をスラグシェルで包む様な
状態を形成し、その後スラグシェルを溶融させて金属と
スラグを分離する方法を開示している。ところがこの方
法では、還元により生成した金属の再酸化を阻止するた
め、該金属を完全に包み込むに足る量のスラグを生成さ
せなければならず、スラグ形成材料の配合量が不足する
と金属の包み込みが不十分となって金属の再酸化が避け
られなくなる。しかも加熱還元条件によってはFeO濃
度の高いスラグが生成し、設備の内張り耐火物を著しく
損傷するという、実用化する上で大きな問題も生じてく
る。
Further, Japanese Patent Publication No. 56-19366 discloses that
Heating and reducing the agglomerate containing the metal oxide, the solid carbonaceous material and the slag forming material, while maintaining the shape of the agglomerate, forming a state in which the metal generated by the reduction is wrapped in a slag shell, Thereafter, a method of melting a slag shell to separate metal and slag is disclosed. However, in this method, in order to prevent re-oxidation of the metal generated by the reduction, it is necessary to generate a sufficient amount of slag to completely enclose the metal. It becomes insufficient and reoxidation of the metal becomes unavoidable. In addition, depending on the heating and reducing conditions, a slag having a high FeO concentration is generated, which significantly damages the refractory lining of the equipment, which poses a serious problem in practical use.

【0009】上記の様に、スラグ成分含有量の少ない金
属鉄を製造する方法の実現は、製品金属鉄としての付加
価値を高めるばかりでなく、電気炉を用いた製鉄コスト
の低減、更には金属鉄製造における使用原料の選択の柔
軟性という観点から極めて重要になってくる。また、加
熱・還元により副生するスラグ中の酸化鉄含有量を極力
少なくし、耐火物の溶損を抑えることは、この種の製鉄
法を工業的規模で実現可能にする上で極めて重要とな
る。
As described above, the realization of a method for producing metallic iron with a small slag component content not only increases the added value as a product metallic iron, but also reduces the cost of iron making using an electric furnace and further reduces the metallurgy. This becomes extremely important from the viewpoint of flexibility in selecting raw materials used in iron production. In addition, minimizing the iron oxide content in the slag by-produced by heating and reduction and suppressing the erosion of refractories is extremely important in making this type of ironmaking process feasible on an industrial scale. Become.

【0010】[0010]

【発明が解決しようとする課題】本発明者らはこうした
状況に着目し、鉄成分含有量の高い酸化鉄はもとより鉄
成分含有量の比較的低い鉄鉱石等からでも、耐火物の溶
損などを生じることなく鉄純度の極めて高い金属鉄を、
溶融鉄として簡単な処理で効率よく得ることのできる技
術の開発を期してかねてより研究を進めており、その研
究成果として下記の方法を開発し、先に特許出願を済ま
せた(特願平8−59801号)。
The present inventors have paid attention to such a situation, and have found that iron oxide having a high iron content as well as iron ore having a relatively low iron content, such as erosion of refractories, can be considered. Metal iron with extremely high iron purity without causing
We have been conducting research in advance of the development of a technology that can efficiently obtain molten iron with simple processing. As a result of this research, we have developed the following method, and have already filed a patent application (Japanese Patent Application Hei 8 No. 59801).

【0011】この先願発明は、炭素質還元剤が存在する
酸化鉄の成形体を加熱還元して金属鉄を製造する際に、 加熱還元により金属鉄外皮を生成且つ成長させて酸化
鉄が実質的に存在しなくなるまで還元を進めると共に、
成形体の内部にスラグの凝集物を生成させ、 加熱還元により金属鉄外皮を生成且つ成長させて酸化
鉄が実質的に存在しなくなるまで還元を進め、更に加熱
を続けて成形体の内部に生成するスラグを金属鉄外皮の
外側へ流出させ、 加熱還元により金属鉄外皮を生成且つ成長させて酸化
鉄が実質的に存在しなくなるまで還元を進め、更に加熱
を続けて金属鉄とスラグを溶融分離し、あるいは 加熱還元により金属鉄外皮を生成且つ成長させて酸化
鉄が実質的に存在しなくなるまで還元を進めると共に、
成形体の内部にスラグの凝集物を生成させ、次いで生成
スラグを金属鉄から分離するところに特徴を有してい
る。
[0011] In the prior invention, when the iron oxide molded body in which the carbonaceous reducing agent is present is heated and reduced to produce metallic iron, the metallic oxide is generated and grown by the thermal reduction to substantially reduce the iron oxide. And continue reducing until it no longer exists in
Slag agglomerates are formed inside the compact, heat reduction is used to generate and grow metallic iron hulls, and the reduction is advanced until iron oxide is substantially absent, and heating is continued to form inside the compact. Slag flowing out of the metallic iron shell, heat reduction to generate and grow the metallic iron shell, reduce it until iron oxide is virtually absent, and continue heating to melt and separate the metallic iron and slag Or reducing and heating the metal iron crust by heating and reducing it until iron oxide is substantially absent,
It is characterized in that agglomerates of slag are formed inside the molded body, and then the formed slag is separated from metallic iron.

【0012】上記の方法を実施するに当たっては、金
属鉄外皮の一部を溶融させることによって、成形体内部
の溶融スラグを金属鉄外皮外へ流出させればよく、この
際、あるいは前記の方法を実施するに当たり、金属鉄
外皮の一部もしくは全部を溶融させるには、金属外皮内
に存在する炭素質還元剤による浸炭を進めて当該金属外
皮の融点を降下させればよく、また上記〜の発明を
実施するに当たっては、加熱還元工程の最高加熱温度
を、生成スラグの融点以上で且つ生成する金属鉄外皮の
融点以下の温度に制御することによって、金属鉄生成反
応をより効率よく進めることができ、この還元工程で
は、固相還元により酸化鉄を低減し、更に液相還元によ
りFeOを主体とする酸化鉄が実質的に存在しなくなる
まで還元すれば、得られる金属鉄の品位をより効率よく
高めることが可能となる。
In carrying out the above method, the molten slag inside the molded body may be caused to flow out of the metal iron shell by melting a part of the metal iron shell. In carrying out the process, in order to melt a part or the whole of the metallic iron shell, the carburization by the carbonaceous reducing agent present in the metal shell may be advanced to lower the melting point of the metal shell, and the above-mentioned inventions In carrying out, by controlling the maximum heating temperature of the heating and reducing step to a temperature equal to or higher than the melting point of the generated slag and equal to or lower than the melting point of the metal iron shell to be generated, the metal iron generation reaction can proceed more efficiently. In this reduction step, if the iron oxide is reduced by solid-phase reduction and further reduced by liquid-phase reduction until iron oxide mainly composed of FeO substantially disappears, the resulting metal can be obtained. It is possible to enhance more efficiently the quality.

【0013】そして、固相状態での酸化鉄の還元をうま
く進めるには、還元工程で生成するスラグが、還元によ
って生成する金属鉄よりも低い温度で溶融することが必
要であり、そのためには、成形体中の酸化鉄や炭素質還
元剤等の中に含まれるスラグ生成成分の含有組成を事前
に調整し、生成スラグの融点が還元鉄の融点よりも低く
なる様、成形体の成形工程で必要によりAl23 、S
iO2 、CaOなどを追加調整することが望ましい。
[0013] In order to promote the reduction of iron oxide in the solid state, it is necessary that the slag generated in the reduction step be melted at a lower temperature than the metallic iron generated by the reduction. , The composition of the slag forming component contained in the iron oxide or carbonaceous reducing agent in the formed body is adjusted in advance, and the forming process of the formed body is performed so that the melting point of the formed slag is lower than the melting point of the reduced iron. Al 2 O 3 , S if necessary
It is desirable to additionally adjust iO 2 , CaO and the like.

【0014】尚上記先願発明において、「内部に酸化鉄
が実質的に存在しなくなるまで還元を進める」ことの好
ましい定量的基準は、加熱還元工程で、「FeOを主体
とする酸化鉄の含有率が5重量%以下、より好ましくは
2重量%以下となるまで還元を進めること」であり、ま
た別の観点からすると、還元反応によって生成する金属
鉄から分離される生成スラグ中のFeOを主体とする酸
化鉄の含有量が、5重量%以下、より好ましくは2重量
%以下となるまで還元を進めることが望ましい。
In the above-mentioned prior application, a preferable quantitative criterion for "producing reduction until substantially no iron oxide is present in the inside" is that the content of iron oxide mainly containing FeO is determined in the heating reduction step. The reduction is promoted until the rate becomes 5% by weight or less, more preferably 2% by weight or less. ”From another viewpoint, FeO in the produced slag separated from the metallic iron produced by the reduction reaction is mainly used. It is desirable to proceed with the reduction until the iron oxide content to be 5% by weight or less, more preferably 2% by weight or less.

【0015】そして、この方法によって得られる高純度
の金属鉄および生成スラグは、加熱溶融した状態で比重
差により分離すれば、金属化率で95%程度以上、更に
は98%以上といった非常に高純度の金属鉄を得ること
ができ、しかもこの先願発明によれば、生成スラグ中の
酸化鉄含有量を可及的に少なくすることができるので、
酸化鉄に起因する処理炉耐火物の溶損も起こらず、設備
保全の観点からしても極めて実用性の高い技術としてそ
の実用化が期待される。本発明は、上記先願発明の基本
的な技術思想を活用し、これを工業的規模で効率よく実
施することのできる製法および装置を提供しようとする
ものである。
The high-purity metallic iron and produced slag obtained by this method can be separated by a specific gravity difference in a heated and melted state, resulting in a very high metallization ratio of about 95% or more, and even 98% or more. Purity metallic iron can be obtained, and according to this prior invention, the iron oxide content in the produced slag can be reduced as much as possible.
There is no melting of the refractory of the processing furnace caused by iron oxide, and its practical application is expected as a highly practical technology from the viewpoint of facility maintenance. The present invention intends to provide a manufacturing method and an apparatus which can utilize the basic technical concept of the invention of the prior application and can efficiently carry out the same on an industrial scale.

【0016】[0016]

【課題を解決するための手段】上記課題を解決すること
のできた本発明に係る金属鉄の製法は、炭素質還元剤が
存在する酸化鉄の成形体を加熱還元して金属鉄を製造す
るに当たり、鉄製帯板上に上記成形体を載置した状態で
連続的に移動させながら加熱還元することにより、上記
成形体の表面に金属鉄外皮を生成且つ成長させて酸化鉄
が実質的に存在しなくなるまで還元を進めると共に、成
形体の内部にスラグを生成させ、更なる加熱によって成
形体(金属鉄外皮と生成スラグ)および上記鉄製帯板を
溶融させた後、溶融スラグと溶融鉄に分離するところに
要旨が存在する。
Means for Solving the Problems The method for producing metallic iron according to the present invention, which can solve the above-mentioned problems, relates to a method for producing metallic iron by heating and reducing an iron oxide formed body in which a carbonaceous reducing agent is present. By heating and reducing while continuously moving the molded body placed on an iron strip, a metallic iron skin is generated and grown on the surface of the molded body, and iron oxide is substantially present. While the reduction proceeds until it disappears, slag is generated inside the molded body, and the molded body (metallic iron shell and formed slag) and the iron strip are melted by further heating, and then separated into molten slag and molten iron. However, there is a gist.

【0017】この方法を実施するに当たっては、上記成
形体を帯状または棒状の成形体とし、これを鉄製帯板上
に載置した状態で略水平方向もしくは下り傾斜方向に移
送し、あるいは上記成形体として粒状、ペレット状もし
くは塊状の成形体を使用し、これを、両側縁部に成形体
落下防止壁を形成した鉄製帯板上に載置した状態で略水
平方向に移送しながら加熱還元を行なう方法を採用する
のがよい。
In carrying out this method, the above-mentioned formed body is formed into a band-shaped or rod-shaped formed body, which is transferred in a substantially horizontal direction or a downward inclined direction while being mounted on an iron strip, or As a granulated, pellet-shaped or lump-shaped compact, heat reduction is carried out while being transported in a substantially horizontal direction with the compact being placed on an iron strip having walls formed on both sides to prevent the compact from falling. It is better to adopt a method.

【0018】また上記成形体は、予め所定形状に成形し
てから鉄製帯板上に載置していくことも可能であるが、
該成形体供給位置の近傍に成形体の連続成形装置を設け
ておき、あるいは更に予備還元装置を設けておき、成形
体の成形と供給を連続的に行ない、あるいは更に成形体
の成形と予備還元および供給を連続的に行なうことも極
めて有効となる。
It is also possible to form the above-mentioned molded body in a predetermined shape before placing it on an iron strip.
A continuous molding device for the compact is provided near the supply position of the compact, or a pre-reduction device is further provided to continuously perform molding and supply of the compact, or to further form and pre-reduce the compact. It is also very effective to continuously supply and supply.

【0019】また本発明にかかる金属鉄の製造設備と
は、上記製法を実施する際に好ましく用いられる設備で
あって、その構成は、炭素質還元剤が存在する酸化鉄の
成形体を加熱還元して金属鉄を製造する設備において、
上記成形体を、鉄製帯板上に載置した状態で連続的に移
送する連続移送部材と、上記成形体を、移送過程で順次
加熱して還元及び溶融すると共に、鉄製帯板を加熱溶融
する加熱部材と、溶融した溶融スラグと溶融鉄を受け入
れてこれらを分離する分離部とを備えているところに要
旨がある。
Further, the equipment for producing metallic iron according to the present invention is equipment that is preferably used when carrying out the above-mentioned production method, and is constituted by heating and reducing an iron oxide compact in which a carbonaceous reducing agent is present. Equipment to produce metallic iron
A continuous transfer member for continuously transferring the compact in a state of being placed on an iron strip, and the compact is sequentially heated and reduced and melted in a transfer process, and the iron strip is heated and melted. The gist lies in that a heating member and a separation section for receiving the molten molten slag and the molten iron and separating them are provided.

【0020】この設備を用いて粒状、ペレット状あるい
は塊状の成形体の加熱還元を行なう場合は、上記鉄製帯
板の上記成形体載置位置もしくはその上流側に、該鉄製
帯板の両側縁に成形体落下防止壁を形成するための加工
部が設けておき、その上に上記成形体を載置して移送す
る様にすれば、該成形体が鉄製帯板上から脱落すること
がなくなるので好ましい。また、上記金属帯板上への成
形体載置位置の上流側に、成形体を成形するための成形
装置を設け、あるいは更に該成形体を予備還元するため
の予備還元装置を設けておけば、成形体の成形、更には
その予備還元を含めた一連の工程を連続的に実施可能な
設備とすることができるので好ましい。
In the case where a granular, pellet-like, or lump-shaped compact is heated and reduced by using this equipment, the iron-made strip is placed at the mounting position of the iron-made strip or on the upstream side thereof, and on both side edges of the iron-made strip. If a processing section for forming a wall for preventing the molded article from falling is provided, and the molded article is placed and transported thereon, the molded article does not fall off from the iron strip. preferable. In addition, if a forming device for forming a formed body is provided on the upstream side of the mounting position of the formed body on the metal strip, or a pre-reduction device for further pre-reducing the formed body is provided. It is preferable because a series of steps including molding of the molded body and further preliminarily reducing the same can be continuously performed.

【0021】[0021]

【発明の実施の形態】上記の様に本発明では、炭素質還
元剤が存在する酸化鉄の成形体を加熱還元して金属鉄を
製造する際に、鉄製帯板上に上記成形体を載置した状態
で連続的に移送しながら加熱還元することにより、金属
鉄外皮を生成且つ成長させて内部に生成スラグを形成さ
せ、更なる加熱によって上記金属鉄外皮とスラグ並びに
移送に用いた鉄製帯板を溶融させた後、溶融スラグと溶
融鉄に分離するところに特徴があり、この様な方法を採
用することによって、成形体の加熱還元、還元により生
成する金属鉄とスラグの分離の一連の工程を連続的に行
なうことが可能となる。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS As described above, according to the present invention, when heat-reducing an iron oxide formed body containing a carbonaceous reducing agent to produce metallic iron, the formed body is placed on an iron strip. By heating and reducing while continuously transferring in the placed state, a metal iron shell is generated and grown to form a generated slag inside, and further heating is used to form the metal iron shell and the slag and the iron band used for transfer. It is characterized in that after the plate is melted, it is separated into molten slag and molten iron.By adopting such a method, a series of steps of heat reduction of the molded body, separation of metallic iron and slag generated by reduction The process can be performed continuously.

【0022】また、金属帯板上への上記成形体載置位置
の上流側で、該成形体を連続的に成形し、あるいは更に
該成形体を予備還元できる様にしておけば、金属鉄の製
造原料となる成形体の成形(更にはその予備還元)から
加熱還元、還元により生成する金属鉄とスラグの加熱溶
融、更にはそれらの溶融分離の一連の工程を連続的に行
なうことが可能となる。
Further, if the formed body is continuously formed or the preformed body can be preliminarily reduced on the upstream side of the mounting position of the formed body on the metal strip, the metallic iron can be formed. It is possible to continuously perform a series of steps from forming of a molded material to be a production raw material (and further pre-reduction) to heat reduction, heat melting of metallic iron and slag generated by reduction, and furthermore, melting and separation of these. Become.

【0023】そして上記加熱還元工程では、まず成形体
の外周側で加熱還元が進行して金属鉄からなる外皮が形
成され、その後、該外皮の内側で炭素質還元剤自体およ
びその熱分解により生成する一酸化炭素による還元作用
によって、外皮内における酸化鉄の還元反応が効率よく
進行し、生成する金属鉄は互いに付着し合って集合する
と共に、生成スラグも互いに融け合って集合する。その
結果、この加熱還元工程での金属化率は著しく高まると
共に、生成スラグ中の酸化鉄混入量も著しく少なくな
る。
In the heat reduction step, first, heat reduction proceeds on the outer peripheral side of the formed body to form an outer cover made of metallic iron, and thereafter, the carbonaceous reducing agent itself and the thermal decomposition thereof are formed inside the outer cover. Due to the reducing action of carbon monoxide, the reduction reaction of iron oxide in the outer skin proceeds efficiently, and the generated metallic iron adheres to and aggregates with each other, and the generated slag fuses and aggregates with each other. As a result, the metallization rate in this heat reduction step is significantly increased, and the amount of iron oxide mixed in the produced slag is significantly reduced.

【0024】そして、上記加熱還元が行なわれる部分の
下流側では、更なる加熱によって上記金属鉄外皮および
スラグは溶融すると共に、移送に用いられた鉄製帯板も
溶融し、その下流側に設けられた分離部で比重差により
分離するので、高度に還元された金属鉄を溶融鉄として
効率よく得ることが可能となる。しかも、該加熱還元工
程で酸化鉄の還元が高度に進行する結果、副生する溶融
スラグ中に混入する酸化鉄の量も極めて少なくなり、酸
化鉄の混入による耐火物の溶損も可及的に抑えられるの
である。
Further, on the downstream side of the portion where the heat reduction is performed, the metal iron shell and the slag are melted by further heating, and the iron strip used for the transfer is also melted. Since the metal is separated by the specific gravity difference in the separated part, highly reduced metallic iron can be efficiently obtained as molten iron. In addition, as a result of the high reduction of iron oxide in the heat reduction step, the amount of iron oxide mixed into the molten slag by-produced is also extremely small, and the refractory erosion due to the mixing of iron oxide is also possible. It can be suppressed to.

【0025】以下、本発明にかかる製法および製造設備
を、一実施例を示す図面を参照しつつ具体的に説明する
が、本発明はもとより図示例に限定される訳ではなく、
前・後記の趣旨に適合し得る範囲で適当に変更を加えて
実施することも可能であり、それらはいずれも本発明の
技術的範囲に包含される。
Hereinafter, the production method and the production equipment according to the present invention will be specifically described with reference to the drawings showing one embodiment, but the present invention is not limited to the illustrated examples.
It is also possible to carry out the present invention with appropriate modifications within a range that can be adapted to the gist of the preceding and the following, and all of them are included in the technical scope of the present invention.

【0026】図1(A)は、本発明の一実施例を示すも
ので、代表的な金属鉄の製法を、製造設備と共に説明す
るための概略縦断面説明図であり、図中1は鉄製帯板、
2は焼鈍炉、3は成形部、4は原料ホッパー、5は加熱
還元炉、6は加熱溶融炉、7は溶融分離炉を夫々示して
いる。
FIG. 1 (A) shows an embodiment of the present invention, and is a schematic longitudinal sectional explanatory view for explaining a typical method for producing metallic iron together with production equipment, where 1 is an iron-made one. Strip,
Reference numeral 2 denotes an annealing furnace, 3 denotes a forming section, 4 denotes a raw material hopper, 5 denotes a heating reduction furnace, 6 denotes a heating and melting furnace, and 7 denotes a melting and separating furnace.

【0027】本発明では、鉄製帯板1を原料成形体の移
送用として利用するもので、該鉄製帯板1を焼鈍炉2に
通して軟化焼鈍し、成形部3で両側縁を折り曲げて樋状
に成形[図1(B):一部横断面説明図]してから加熱
還元炉5内へ連続的に送り込む。そして、炭材等の炭素
質還元剤と鉄鉱石等の酸化鉄および必要により配合され
るバインダーの混合物を粒状、ペレット状、塊状など任
意の形状に成形した原料成形体を、該加熱還元炉5の最
上流側に設けられた原料ホッパー4から上記帯板1上に
載置し、加熱還元炉5内を図面の右方向へ連続的に移送
する。該加熱還元炉5の側壁あるいは天井部には加熱バ
ーナ(図示せず)が設けられており、該バーナによる加
熱によって成形体は加熱され、順次乾燥された後加熱還
元が行なわれる。
In the present invention, the iron strip 1 is used for transferring a raw material compact. The iron strip 1 is passed through an annealing furnace 2 to be softened and annealed. [FIG. 1 (B): partial cross-sectional explanatory view], and then continuously fed into the heating and reducing furnace 5. Then, a raw material compact obtained by molding a mixture of a carbonaceous reducing agent such as a carbonaceous material, an iron oxide such as iron ore, and a binder to be blended as required into granules, pellets, agglomerates, etc. Is placed on the strip 1 from the raw material hopper 4 provided on the most upstream side of the furnace, and is continuously transferred to the right in the drawing in the heating and reducing furnace 5. A heating burner (not shown) is provided on a side wall or a ceiling portion of the heating and reducing furnace 5, and the molded body is heated by heating by the burner, and is sequentially dried and then reduced by heating.

【0028】この加熱還元工程では、前述の如く各成形
体内に含まれる固体還元剤によって表層側から還元が進
行し、前述の如く生成する金属鉄により表面に金属鉄主
体の外皮が形成される。そしてその内側では、炭素質還
元剤およびその熱分解によって生成する一酸化炭素によ
って強い還元雰囲気が形成され、内部で酸化鉄の還元が
急速に進行していく。従って、加熱還元炉5の長さに応
じて帯板1の移動速度や加熱条件等を適正にコントロー
ルすれば、金属鉄外皮内の強い還元雰囲気によって内部
の酸化鉄は効率よく還元され、全体としての金属化率を
95%以上、更には98%以上といったレベルにまで高
められる。
In the heat reduction step, as described above, the reduction proceeds from the surface layer by the solid reducing agent contained in each molded body, and the metal iron generated as described above forms an outer shell mainly composed of metal iron on the surface. Inside, a strong reducing atmosphere is formed by the carbonaceous reducing agent and carbon monoxide generated by its thermal decomposition, and the reduction of iron oxide proceeds rapidly inside. Therefore, if the moving speed of the strip 1 and the heating conditions are appropriately controlled in accordance with the length of the heating and reducing furnace 5, the iron oxide inside is efficiently reduced by the strong reducing atmosphere in the metallic iron sheath, and as a whole, Can be increased to a level of 95% or more, and even 98% or more.

【0029】金属鉄の生成に伴って副生するスラグは、
該金属鉄外皮内で金属鉄よりも低温で溶融し、相互に融
着し合って金属鉄と分離された状態となるが、加熱還元
炉5の下流側に設けられた加熱溶融炉6で更なる加熱を
受けると、上記外皮を形成している金属鉄や生成スラグ
と共に鉄製帯板1も溶融し、順次溶融分離炉7方向へ流
出していく。そして溶融分離炉7では、比重の小さな溶
融スラグSが溶融鉄Fの表面に浮上分離するので、該溶
融分離炉7の湯面側から溶融スラグSを抜き出し、底部
から溶融鉄Fを抜き出せばよい。
The slag by-produced with the formation of metallic iron is:
The metal melts at a lower temperature than the metallic iron in the metallic iron shell, and is fused to each other to be separated from the metallic iron. However, the molten metal is further separated by the heating and melting furnace 6 provided downstream of the thermal reduction furnace 5. Upon receiving the heating, the iron strip 1 is melted together with the metallic iron and the generated slag forming the outer skin, and flows out toward the melting and separating furnace 7 sequentially. Then, in the melting and separating furnace 7, the molten slag S having a small specific gravity floats and separates on the surface of the molten iron F. Therefore, the molten slag S is extracted from the molten metal side of the melting and separating furnace 7, and the molten iron F may be extracted from the bottom. .

【0030】なお図中8は排ガス排出口を表わし、該排
出口8から排出される排ガスはそのまま放出してもよい
が、この排ガスは高温でしかも可燃性ガスを含んでいる
ので、加熱還元炉5や加熱溶融炉6等を加熱する為のバ
ーナへ燃料ガスとして供給し、或は燃焼用空気の予熱用
として有効利用することが望ましい。また、上記原料ホ
ッパー4から供給される原料成形体としては、予めペレ
ット状等に成形し予備乾燥したものを使用することが望
ましく、或は更に予備還元を行なったものを使用すれ
ば、加熱還元炉5を短縮することができるので好まし
い。また、ペレット等の原料成形体を成形するための成
形装置(図示せず)を前記ホッパー4の付近に設置して
おき、該成形装置で成形した原料成形体を連続的にホッ
パー4へ供給する構成とし、原料成形体の成形と加熱還
元を連続化することも可能である。
In the figure, reference numeral 8 denotes an exhaust gas outlet, and the exhaust gas discharged from the outlet 8 may be discharged as it is. However, since this exhaust gas is high in temperature and contains flammable gas, It is preferable to supply the fuel gas to a burner for heating the heating furnace 5 and the heating / melting furnace 6 or the like, or to effectively use the fuel gas for preheating combustion air. As the raw material compact supplied from the raw material hopper 4, it is desirable to use a material which has been formed into pellets or the like in advance and preliminarily dried. This is preferable because the furnace 5 can be shortened. In addition, a molding device (not shown) for molding a raw material compact such as a pellet is installed near the hopper 4, and the raw material molded by the molding device is continuously supplied to the hopper 4. It is also possible to make the constitution and to continuously form and heat-reduce the raw material molded body.

【0031】図2(A)は本発明の他の実施例を示す概
略縦断面説明図であり、図中1は鉄製帯板、3は成形
部、9は原料混練押出し機、5は加熱還元炉、6は加熱
溶融炉、7は溶融分離炉を夫々示している。
FIG. 2A is a schematic longitudinal sectional view showing another embodiment of the present invention, in which 1 is an iron strip, 3 is a forming section, 9 is a material kneading extruder, and 5 is a heating reduction. Furnace, 6 is a heating and melting furnace, and 7 is a melting and separating furnace.

【0032】本例も、鉄製帯板1を原料成形体の移送用
として利用するものであるが、該鉄製帯板1上に載置す
る成形体を長尺物とし、これを連続的に成形しつつ鉄製
帯板1上に載置して連続的に加熱還元炉5へ送り込む様
に構成している。即ち本例では、図示する如く成形部3
に臨んで原料混練押出し機9が設けられており、該混練
押出し機9に、炭素質還元剤と酸化鉄およびバインダを
供給して混練しつつ、その先端から成形部3方向へ押し
出す。この成形部3には鉄製帯板1も連続的に供給され
ており、該成形部3で、該鉄製帯板1上に上記混練物が
供給されると共に、任意の断面形状に整形[図2
(B):一部横断面説明図]され、帯板1と共に加熱還
元炉5方向へ送り込まれる。このときの成形体の断面は
平板状や棒状であっても構わないが、表面積を大きくし
て乾燥と加熱還元を効率よく進め得る様、長手方向に筋
状の凹凸を有する形状にしておくことが望ましい。
Also in this embodiment, the iron strip 1 is used for transferring a raw material compact, but the compact placed on the iron strip 1 is made to be a long object, which is continuously formed. While being placed on the iron strip 1 and continuously fed into the heating and reducing furnace 5. That is, in this example, as shown in the figure,
, A raw material kneading extruder 9 is provided, and a carbonaceous reducing agent, iron oxide, and a binder are supplied to the kneading extruder 9 and kneaded, and the mixture is extruded from the tip to the forming section 3. The iron strip 1 is also continuously supplied to the molding part 3, and the kneaded material is supplied onto the iron strip 1 in the molding part 3 and shaped into an arbitrary cross-sectional shape [FIG.
(B): Partial cross-sectional explanatory view] and sent in the direction of the heating and reducing furnace 5 together with the strip 1. The cross section of the molded body at this time may be a flat plate or a rod shape, but it should have a shape having streaky irregularities in the longitudinal direction so that the surface area can be increased and drying and heat reduction can be efficiently promoted. Is desirable.

【0033】この実施例では、成形体が長尺物として連
続的に鉄製帯板1上に載置されることになり、成形体が
帯板1上を転がり落ちる様な恐れがないので、帯板1は
平板状のままで差し支えなく、また帯板1の移送方向
も、水平方向の他、適当な角度に傾斜させて移送がより
円滑に行なわれる様にすることが可能である。
In this embodiment, the formed body is continuously placed as a long object on the iron strip 1 and there is no fear that the formed body rolls down on the strip 1. The plate 1 may be in the form of a flat plate, and the transfer direction of the strip 1 may be inclined at an appropriate angle in addition to the horizontal direction so that the transfer can be performed more smoothly.

【0034】加熱還元炉5は、最上流側を乾燥部、その
下流側を加熱還元部として構成され、各部の側壁や天井
部には加熱バーナ(図示せず)が設けられており、該バ
ーナによる加熱によって成形体は加熱され、順次乾燥さ
れた後加熱還元が行なわれる。この加熱還元工程では、
前記と同様にして長尺成形体内に含まれる固体還元剤に
よって表層側から還元が進行し、前述の如く生成する金
属鉄により表面に金属鉄主体の外皮が形成される。そし
てその内側では、炭素質還元剤およびその熱分解によっ
て生成する一酸化炭素によって強い還元雰囲気が形成さ
れ、内部で酸化鉄の還元が急速に進行していく。従っ
て、加熱還元炉5の長さに応じて帯板1の移動速度や加
熱条件等を適正にコントロールすれば、金属鉄外皮内の
強い還元雰囲気によって内部の酸化鉄は効率よく還元さ
れる。
The heating and reducing furnace 5 has a drying section on the most upstream side and a heating and reducing section on the downstream side, and a heating burner (not shown) is provided on a side wall or a ceiling of each section. The molded body is heated by the heating of, and is sequentially dried and then reduced by heating. In this heating reduction step,
In the same manner as described above, the reduction proceeds from the surface layer side by the solid reducing agent contained in the elongated molded body, and the metallic iron generated as described above forms an outer shell mainly composed of metallic iron on the surface. Inside, a strong reducing atmosphere is formed by the carbonaceous reducing agent and carbon monoxide generated by its thermal decomposition, and the reduction of iron oxide proceeds rapidly inside. Therefore, if the moving speed of the strip 1 and the heating conditions are appropriately controlled in accordance with the length of the heating and reducing furnace 5, the iron oxide inside is efficiently reduced by the strong reducing atmosphere in the metallic iron sheath.

【0035】金属鉄の生成に伴って副生するスラグは、
該金属鉄外皮内で金属鉄よりも低温で溶融し、相互に融
着し合って分離された状態となるが、加熱還元炉5の下
流側に設けられた加熱溶融炉6で更なる加熱を受ける
と、上記外皮を形成している金属鉄や生成スラグと共に
鉄製帯板1も溶融し、順次溶融分離炉7方向へ流出して
いく。そして溶融分離炉7では、前記と同様にして溶融
スラグSと溶融鉄Fの分離が行なわれる。
The slag by-produced with the production of metallic iron is:
The metal melts at a lower temperature than the metal iron in the metal iron shell, and is fused and separated from each other. However, the heating and melting furnace 6 provided on the downstream side of the heat reduction furnace 5 further heats the metal. When it is received, the iron strip 1 is melted together with the metallic iron and the formed slag forming the outer skin, and flows out toward the melting and separating furnace 7 sequentially. In the melting and separating furnace 7, the molten slag S and the molten iron F are separated in the same manner as described above.

【0036】これらの方法を実施する際の具体的な設備
の設計に当たっては、上記の趣旨に適合し得る範囲で適
当に設計変更を加えることも勿論可能であり、それらも
当然本発明の技術的範囲に含まれる。また設備の操業に
当たっても、前述の如く或は以下に説明する如く様々の
条件設定(操業温度、炭素質還元剤の使用量や添加形
態、排ガスの利用など)を適宜選択して同様に適用する
ことができる。
In designing the specific equipment for implementing these methods, it is, of course, possible to make appropriate design changes within a range that can be adapted to the above-mentioned purpose. Included in the range. In the operation of the equipment, various conditions (operation temperature, amount of carbonaceous reducing agent and addition form, utilization of exhaust gas, etc.) are appropriately selected and applied similarly as described above or as described below. be able to.

【0037】たとえば本発明を実施するに当たり、上記
成形体内に含有される炭素質還元剤は、加熱還元工程で
まず酸化鉄の還元と該還元により生成した金属鉄の浸炭
に消費されるが、溶融前の固体状態の還元鉄はポーラス
で再酸化を受け易い。従って該還元鉄の再酸化を防止す
るには、再酸化を防止し得るに足る炭素質還元剤を成形
体中に含有させておき、該炭素質還元剤の燃焼によって
生成するCOガスによって、加熱還元炉5内を降下する
成形体の周辺を非酸化性雰囲気に維持することが必要と
なる。そのためには、成形体中に含まれる炭素質還元剤
の量が、少なくとも[原料酸化鉄の還元に必要なC量+
還元鉄の浸炭に消費されるC量+炉内の酸化損失量]以
上となる様に、その配合量を調整することが望まれる。
この他、還元鉄の再酸化を防止するための他の手段とし
て、加熱還元炉5の下流側あるいは加熱溶融炉6や溶融
分離炉7で不足分の炭素質還元剤やCOを補給すること
も可能である。
For example, in carrying out the present invention, the carbonaceous reducing agent contained in the molded body is first consumed in the heat reduction step for reducing iron oxide and carburizing the metallic iron produced by the reduction. The previous solid state reduced iron is porous and susceptible to re-oxidation. Therefore, in order to prevent the reoxidation of the reduced iron, a carbonaceous reducing agent sufficient to prevent the reoxidation is contained in the molded body, and heating is performed by CO gas generated by combustion of the carbonaceous reducing agent. It is necessary to maintain a non-oxidizing atmosphere around the molded body descending in the reduction furnace 5. For this purpose, the amount of the carbonaceous reducing agent contained in the molded body is at least [C amount required for reduction of the raw material iron oxide +
It is desired to adjust the amount of the reduced iron so as to be equal to or more than the amount of C consumed for carburization of the reduced iron + the amount of oxidation loss in the furnace.
In addition, as another means for preventing the reoxidation of the reduced iron, a shortage of the carbonaceous reducing agent or CO may be supplied downstream of the heating reduction furnace 5 or in the heating melting furnace 6 or the melting separation furnace 7. It is possible.

【0038】そして、炭素質還元剤を加熱溶融炉6や溶
融分離炉7で補給する方法を採用し、あるいは成形体に
予め余分の炭素質還元剤を配合しておけば、加熱還元炉
5で完全に還元しきれなかった酸化鉄が加熱溶融炉6や
溶融分離炉7へ送られてきた場合でも、これらの炉の部
分で該未還元状態の酸化鉄の還元を完結させことができ
るので好ましい。
Then, a method of replenishing the carbonaceous reducing agent in the heating / melting furnace 6 or the melting / separating furnace 7 is employed, or if an excess carbonaceous reducing agent is previously added to the molded body, the heating / reducing furnace 5 Even when the iron oxide that cannot be completely reduced is sent to the heating / melting furnace 6 or the melting / separating furnace 7, it is preferable because the reduction of the unreduced iron oxide can be completed in these furnace parts. .

【0039】また本発明を実施する際には、固相状態で
の酸化鉄の還元をうまく進めるため、前述の如く加熱還
元工程で生成するスラグが、還元によって生成する金属
鉄よりも低い温度で溶融することが必要であり、そのた
めには、成形体中のスラグ生成々分(酸化鉄源として一
般的に用いられる鉄鉱石や炭素質還元剤中に混入してく
る脈石成分)の組成を事前に調整し、生成スラグの融点
が還元鉄やその浸炭物の融点よりも低くなる様に制御す
ることが必要となる。従って、上記脈石成分の組成によ
っては、成形体の成形工程で必要によりAl23 やS
iO2 、CaOなどを補給し、溶融温度の低いスラグを
生成させることが望ましい。
In practicing the present invention, in order to promote the reduction of iron oxide in a solid state, the slag generated in the heat reduction step is at a lower temperature than the metallic iron generated by the reduction as described above. It is necessary to melt, and for that purpose, the composition of slag formation components (gangue components mixed in iron ore or carbonaceous reducing agent generally used as an iron oxide source) in the compact is required. It is necessary to adjust in advance and control the melting point of the produced slag to be lower than the melting point of reduced iron or its carburized product. Therefore, depending on the composition of the gangue component, Al 2 O 3 or S
It is desirable to replenish iO 2 , CaO and the like to generate slag having a low melting temperature.

【0040】また上記図示例では、成形体をそのまま加
熱還元炉5へ送って加熱還元を行なう例を示したが、該
加熱還元炉5の長さを短縮して加熱還元をより短時間で
進めるため、成形体を予め予備還元してから加熱還元炉
5へ送り込む様にすることも極めて有効となる。その場
合は、当然のことながら原料ホッパー4の上流側に予備
還元装置が設けられることになる。
Further, in the illustrated example, an example is shown in which the compact is sent to the heating reduction furnace 5 as it is to perform the heating reduction. However, the length of the heating reduction furnace 5 is shortened and the heating reduction is advanced in a shorter time. Therefore, it is extremely effective to preliminarily reduce the molded body and then feed the molded body into the heating reduction furnace 5. In this case, a preliminary reduction device is naturally provided upstream of the raw material hopper 4.

【0041】また、溶融分離炉7内に潜り堰を設け、比
重の小さい溶融スラグSを該潜り堰でせき止めて湯面側
から抜き出すと共に、該潜り堰をくぐってくる比重の大
きい溶融鉄Fを下流側から抜き出す様にすれば、溶融鉄
Fと溶融スラグSをより効率よく分離できるので好まし
く、溶融分離炉7にバーナー加熱や電気加熱設備を付設
し、これによって溶融スラグSや溶融鉄Fを更に高温に
加熱してそれらの流動性を高めてやれば、スラグSと溶
融鉄Fの分離・排出を一層容易にすることができるので
好ましい。
A submerged weir is provided in the melting and separating furnace 7, and the molten slag S having a small specific gravity is dammed by the submerged weir to be drawn out from the molten metal surface, and molten iron F having a large specific gravity passing through the submerged weir is removed. It is preferable that the molten iron F and the molten slag S be separated more efficiently because the molten iron F and the molten slag S are separated from the downstream side. It is preferable to further increase the fluidity by heating to a high temperature because the separation and discharge of the slag S and the molten iron F can be further facilitated.

【0042】[0042]

【発明の効果】本発明は以上の様に構成されており、先
願発明で提案した新しい金属鉄の製造技術を、実用規模
で効率よく実現可能とし、鉄含有量の高い酸化鉄はもと
より、鉄含有量の低い鉄鉱石等の鉄源からでも、金属化
率で95%以上、更には98%以上といった極めて高純
度の金属鉄を、連続方式で生産性よく製造することがで
きる。また、この方法および設備を使用すれば、加熱還
元工程で副生するスラグへの酸化鉄の混入量も著しく低
減することができ、溶融分離炉などの内張り耐火物の該
溶融酸化鉄による溶損も可及的に抑えることが可能とな
る。
The present invention is configured as described above, and enables the new metal iron production technology proposed in the prior application invention to be efficiently realized on a practical scale. In addition to iron oxide having a high iron content, Even from an iron source such as iron ore having a low iron content, extremely high-purity metallic iron having a metallization ratio of 95% or more, and even 98% or more, can be produced in a continuous manner with high productivity. In addition, if this method and equipment are used, the amount of iron oxide mixed into the slag by-produced in the heating and reducing step can be significantly reduced, and the refractory lining of a melting separation furnace or the like is damaged by the molten iron oxide. Can be suppressed as much as possible.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明にかかる金属鉄の製法および製造設備の
代表例を示す概略断面説明図である。
FIG. 1 is a schematic sectional explanatory view showing a typical example of a method and a facility for producing metallic iron according to the present invention.

【図2】本発明にかかる金属鉄の製法および製造設備の
他の例を示す概略断面説明図である。
FIG. 2 is a schematic cross-sectional explanatory view showing another example of the method for producing metallic iron and the production equipment according to the present invention.

【符号の説明】[Explanation of symbols]

1 鉄製帯板 2 焼鈍炉 3 成形部 4 原料ホッパー 5 加熱還元炉 6 加熱溶融炉 7 溶融分離炉 8 排ガス排出口 9 混練押出し機 F 溶鉄 S 溶融スラグ DESCRIPTION OF SYMBOLS 1 Iron strip 2 Annealing furnace 3 Forming part 4 Raw material hopper 5 Heat reduction furnace 6 Heat melting furnace 7 Melt separation furnace 8 Exhaust gas discharge port 9 Kneading extruder F Molten iron S Melting slag

Claims (12)

【特許請求の範囲】[Claims] 【請求項1】 炭素質還元剤が存在する酸化鉄の成形体
を加熱還元して金属鉄を製造するに当たり、鉄製帯板上
に上記成形体を載置した状態で連続的に移動させながら
加熱還元することにより、上記成形体の表面に金属鉄外
皮を生成且つ成長させて酸化鉄が実質的に存在しなくな
るまで還元を進めると共に、該成形体の内部にスラグを
生成させ、更なる加熱によって該成形体および上記鉄製
帯板を溶融させた後、溶融スラグと溶融鉄に分離するこ
とを特徴とする金属鉄の製法。
When producing a metallic iron by heating and reducing an iron oxide compact in which a carbonaceous reducing agent is present, heating is performed while continuously moving the compact while placing the compact on an iron strip. By reducing, a metal iron skin is generated and grown on the surface of the molded body, and the reduction is advanced until iron oxide is substantially absent, and slag is generated inside the molded body, and further heating is performed. A method for producing metallic iron, comprising: melting the formed body and the iron strip and then separating the molten slag and molten iron.
【請求項2】 上記成形体が、帯状または棒状の成形体
である請求項1に記載の金属鉄の製法。
2. The method for producing metallic iron according to claim 1, wherein the molded body is a band-shaped or rod-shaped molded body.
【請求項3】 上記成形体を略水平方向もしくは下り傾
斜方向に移送しながら加熱還元を行なう請求項2記載の
金属鉄の製法。
3. The method for producing metallic iron according to claim 2, wherein the heat reduction is carried out while transferring the compact in a substantially horizontal direction or a downwardly inclined direction.
【請求項4】 上記成形体が、粒状、ペレット状もしく
は塊状の成形体である請求項1記載の金属鉄の製法。
4. The method for producing metallic iron according to claim 1, wherein the compact is a granular, pellet-like or massive compact.
【請求項5】 上記成形体を略水平方向に移送しながら
加熱還元を行なう請求項4記載の金属鉄の製法。
5. The method for producing metallic iron according to claim 4, wherein the heat reduction is carried out while transferring the compact in a substantially horizontal direction.
【請求項6】 上記鉄製帯板の両側縁部に成形体落下防
止壁を形成し、該鉄製帯板上に上記成形体を載置する請
求項5記載の金属鉄の製法。
6. The method for producing metallic iron according to claim 5, wherein walls for preventing the compact from being formed are formed on both side edges of the steel strip, and the compact is mounted on the iron strip.
【請求項7】 上記成形体を予め予備還元してから供給
する請求項1〜6のいずれかに記載の金属鉄の製法。
7. The method for producing metallic iron according to claim 1, wherein the compact is preliminarily reduced and then supplied.
【請求項8】 成形体を連続的に成形しながら鉄製帯板
上に載置していく請求項1〜7のいずれかに記載の金属
鉄の製法。
8. The method for producing metallic iron according to claim 1, wherein the molded body is placed on an iron strip while being continuously molded.
【請求項9】 炭素質還元剤が存在する酸化鉄の成形体
を加熱還元して金属鉄を製造する設備において、 上記成形体を、鉄製帯板上に載置した状態で連続的に移
送する連続移送部材と、 上記成形体を、移送過程で順次加熱して還元及び溶融す
ると共に、鉄製帯板を加熱溶融する加熱部材と、 生成した溶融スラグと溶融鉄を受け入れてこれらを分離
する分離装置とを備えていることを特徴とする金属鉄の
製造設備。
9. A facility for producing metallic iron by heating and reducing an iron oxide compact in which a carbonaceous reducing agent is present, wherein the compact is continuously transferred while being placed on an iron strip. A continuous transfer member, a heating member for sequentially heating and reducing and melting the formed body in the transfer process, and a heating member for heating and melting the iron strip, and a separation device for receiving the generated molten slag and the molten iron and separating them. And a production facility for metallic iron.
【請求項10】 鉄製帯板の上記成形体載置位置もしく
はその上流側に、該鉄製帯板の両側縁に成形体落下防止
壁を形成するための加工部が設けられている請求項9記
載の製造設備。
10. A processing portion for forming a molded article falling prevention wall on both side edges of the iron strip at the mounting position of the iron strip or at the upstream side thereof. Manufacturing equipment.
【請求項11】 金属帯板上への成形体載置位置の上流
側に、成形体を成形するための成形装置が設けられてい
る請求項9または10記載の製造設備。
11. The manufacturing equipment according to claim 9, wherein a molding device for molding a molded body is provided upstream of a position where the molded body is placed on the metal strip.
【請求項12】 金属帯板上への成形体載置位置の上流
側に、成形体を成形するための成形装置と、該成形体を
予備還元するための予備還元装置が設けられている請求
項9または10記載の製造設備。
12. A forming device for forming a formed body and a pre-reduction device for pre-reducing the formed body are provided upstream of a position where the formed body is placed on the metal strip. Item 11. The manufacturing equipment according to Item 9 or 10.
JP9122626A 1997-03-13 1997-05-13 Production of metallic iron and producing equipment therefor Withdrawn JPH10251724A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9122626A JPH10251724A (en) 1997-03-13 1997-05-13 Production of metallic iron and producing equipment therefor

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
PCT/JP1997/000806 WO1997034018A1 (en) 1996-03-15 1997-03-13 Method and apparatus for making metallic iron
WO97/00806 1997-03-13
JP9122626A JPH10251724A (en) 1997-03-13 1997-05-13 Production of metallic iron and producing equipment therefor

Publications (1)

Publication Number Publication Date
JPH10251724A true JPH10251724A (en) 1998-09-22

Family

ID=26438153

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9122626A Withdrawn JPH10251724A (en) 1997-03-13 1997-05-13 Production of metallic iron and producing equipment therefor

Country Status (1)

Country Link
JP (1) JPH10251724A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007083450A1 (en) * 2006-01-17 2007-07-26 Kabushiki Kaisha Kobe Seiko Sho Process for producing metallic iron

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007083450A1 (en) * 2006-01-17 2007-07-26 Kabushiki Kaisha Kobe Seiko Sho Process for producing metallic iron
AU2006335814B2 (en) * 2006-01-17 2011-04-14 Kabushiki Kaisha Kobe Seiko Sho Method for manufacturing metallic iron

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