JPH10219287A - Detergent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain the subject composition, having low irritation to skin, good in foaming, excellent in creamy touch of foam and good in conditioning effects after cleaning by compounding a specific anionic surfactant with an anionic surfactant containing one chain and one polar group, a nonionic surfactant, etc. SOLUTION: This detergent composition comprises (A) an anionic surfactant containing two long-chain acyl groups and two polar groups e.g. N,N'-bis(2- lauramidoethyl)ethylenediamine-N,N'-di(sodium acetate)), (B) an anionic surfactant containing one chain and one polar group (e.g. sodium N- dodecanoylglutamate), (C) a nonionic surfactant (e.g. lauric acid diethanolamide), (D) an amphoteric surfactant (preferably lauramidopropyl betaine) and (E) a cationic polymer (e.g. a cationic cellulose) and/or a compound containing >=2 hydroxyl groups (e.g. glycerol).

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a detergent composition having low skin irritation, good foaming, excellent foam creaminess, and excellent conditioning effect after washing.

[0002]

2. Description of the Related Art Conventionally, a cleaning composition which has excellent foaming and foam creaminess and a good conditioning effect after cleaning has been studied. For example, in order to improve the feeling of rinsing during hair washing, an attempt has been made to mix a cationic polymer such as cationic cellulose with a normal (single-chain, one-polar group-containing) anionic surfactant which is a main component of a hair cleansing agent. It has been recognized that this formulation improves the rinsing feel. This is because an anionic surfactant for hair washing such as polyoxyethylene lauryl ether sulfate or alkyl sulfate forms a complex salt with a cationic polymer at the time of rinsing and is adsorbed on the hair. On the other hand, the blending of the cationic polymer has disadvantages such as hardening of the hair at the time of rinsing or finishing. Therefore, recently, a hair cleansing agent containing an amphoteric surfactant and a specific amphoteric polymer has been studied. When this is used, the conditioning effect after washing is good, but the foaming and the creaminess of the foam are not sufficiently satisfied. In order to solve these problems, a combination of an amphoteric surfactant, a quaternary ammonium, and a carboxyl group-containing anionic surfactant (Japanese Patent Application Laid-Open No.
2-288694), nonionic surfactants, No. 4
Combinations of quaternary ammonium and a carboxyl group-containing anionic surfactant (JP-A-63-317596, JP-A-8-325595) have been proposed. However, these cleaning agents all foamed, and were not satisfactory in terms of foam creaminess. In addition, skin irritation was not sufficient. As described above, a cleaning composition having low skin irritation, good foaming, excellent foam creaminess, and a good conditioning effect after washing has not yet been developed, and improvement thereof is desired. Was.

[0003]

The present inventor has made intensive studies to improve such disadvantages of the prior art, and as a result,
Specific acyl group 2 long chain bipolar group-containing anionic surfactant, single chain 1 polar group-containing anionic surfactant, nonionic surfactant, amphoteric surfactant, cationic polymer and / or The inventor has found that the incorporation of a compound having at least two hydroxyl groups in the molecule significantly improves the above-mentioned disadvantages, and has completed the present invention. That is, an object of the present invention is to provide a detergent composition having low skin irritation, good foaming, excellent foam creaminess, and a good conditioning effect after washing.

[0004]

The invention of claim 1 of the present invention comprises (A) an anionic surfactant containing two acyl groups and two long-chain polar groups, and (B) an anionic surfactant containing one chain and one polar group. (C) a nonionic surfactant, (D) an amphoteric surfactant, and (E) a cationic polymer and / or a compound having at least two hydroxyl groups in a molecule. Cleaning composition. Further, the invention of claim 2 of the present invention relates to (A) 1 to 40% by weight of an anionic surfactant containing an acyl group 2 long chain dipolar group and (B) an anionic surfactant containing a single chain 1 polar group. 1 to 60% by weight; (C) 1 to 8% by weight of a nonionic surfactant; (D) 1 to 8% by weight of an amphoteric surfactant;
A cleaning composition comprising 5% by weight and / or 0.5 to 40% by weight of a compound having at least two hydroxyl groups in a molecule. Claim 3 of the present invention
The invention of (A) 1 to 40% by weight of an anionic surfactant containing an acyl group 2 long chain bipolar group, (B) 1 to 60% by weight of an anionic surfactant containing one chain and one polar group, C) 1 to 8% by weight of a nonionic surfactant and (D) 1 to 8% by weight of an amphoteric surfactant.
8% by weight and (E) 0.05 to 5% by weight of a cationic polymer and / or 0.5 to 40% by weight of a compound having at least two hydroxyl groups in a molecule, and a weight ratio [(A) + (B)] / [(C) + (D)] is from 2 to 20.

[0005]

Next, an embodiment of the present invention will be described. The anionic surfactant containing an acyl group 2 long chain bipolar group as the component (A) in the present invention has an acyl group long chain having 18, 16, 14, 12, 10 or 8 carbon atoms and a polar group. May have any of a carboxyl group, a sulfonic acid group, and a sulfate group, and may have a molecular structure in which the connecting chain is an alkylene chain having 2 to 6 carbon atoms. As an example of the two-chain dipolar group-containing anionic surfactant (A),
N, N'-bis [2-lauramidoethyl) ethylenediamine-N, N'-di (sodium acetate).
A mixture with a homologue having a different hydrophobic group in the molecular structure of the compound is also blended within the scope of the present invention.
As the counter ion used here, a monovalent or divalent alkali metal ion, ammonium ion or organic ammonium ion is applied. However, basic amino acids such as lysine and arginine also correspond to the organic ammonium ion. Further, as an example of the component (A), N, N'-bis [2-myristoamilamidoethyl) ethylenediamine-
N, N'-di (sodium acetate), N, N'-bis [2
-Palmitoiramidoethyl) ethylenediamine-N,
N'-di (sodium acetate), N, N'-bis [2-lauramidoethyl) ethylenediamine-N, N'-di (sodium propionate), N, N'-bis [2-myristoylamidoethyl) Ethylenediamine-N, N'-di (sodium propionate), N, N'-bis [2-palmitoiramidoethyl) ethylenediamine-N, N'-
Di (sodium propionate), N, N'-bis (lauroylamide) ethane-N, N'-di (sodium acetate), N, N'-bis (myristoylamide) ethane-
N, N'-di (sodium acetate), N, N'-bis (palmitoylamide) ethane-N, N'-di (sodium acetate), N, N'-bis (lauroylamide) ethane-
N, N'-di (sodium propionate), N, N'-
Bis (myristoylamide) ethane-N, N′-di (sodium propionate), N, N′-bis (palmitoylamido) ethane-N, N′-di (sodium propionate), N, N′-bis ( Lauroylamide) butane-
N, N'-di (potassium acetate), N, N'-bis (myristoylamide) butane-N, N'-di (potassium acetate), N, N'-bis (palmitoylamide) butane-
N, N'-di (potassium acetate), N, N'-bis (lauroylamide) ethane-N, N'-di (potassium ethanesulfonate), N, N'-bis (myristoylamide)
Butane-N, N′-di (potassium ethanesulfonate),
N, N'-bis (palmitoylamide) ethane-N,
N′-di (sodium ethanesulfonate). The preferred component (A) in the present invention is that the acyl group-containing long-chain hydrophobic group has 14 or 12 carbon atoms, has a carboxyl group or a sulfonic acid group as a polar group, and has a linking chain of carbon atom. The compound with the number 2 is indicated. The content of these compositions is 0.1 to 40.
% By weight is preferred. If it is less than 0.1% by weight, sufficient foaming properties cannot be obtained, and if it exceeds 20% by weight, the conditioning effect may be reduced.

In the present invention, the component (B) anionic surfactant containing one polar group and one polar group may be any of a polar group having 8 to 20 carbon atoms, such as a hydrophobic group, a carboxyl group, a sulfonic group or a sulfate group. It has a monovalent or divalent alkali metal ion, ammonium ion or organic ammonium ion as a counter ion. The content in the present composition is preferably from 0.1 to 60% by weight. If it is less than 0.1% by weight, sufficient foaming properties cannot be obtained, and if it exceeds 60% by weight, the conditioning effect may be reduced.

The nonionic surfactant (C) in the present invention is a compound having an ionically neutral hydrophilic group and a hydrophobic group in the molecule, and the hydrophilic group is a sugar chain or a polyoxyethylene chain. Those having a hydroxyl group and a hydrophobic group having 8 to 20 carbon atoms are applied. The content of the nonionic surfactant (C) is preferably 1 to 8% by weight. 1
If it is less than 10% by weight, a sufficient synergistic effect with other components cannot be obtained, and the foam properties and the conditioning effect are not sufficient. If it exceeds 8% by weight, the use properties (conditioning effect) may be unfavorable.

The amphoteric surfactant (D) in the present invention includes amide amino acid surfactants, carbobetaine surfactants, sulfobetaine surfactants, amide sulfobetaine surfactants, imidazoly Examples include an ammonium betaine surfactant, an amino acid betaine surfactant, a phosphobetaine surfactant, and alkylamine oxides. Among them, higher fatty acid amidopropyl acetate betaine, which is one of the carbobetaine surfactants, and in particular, amidopropyl betaine laurate is most suitable in terms of conditioning effect. The content of the amphoteric surfactant of the component (D) is preferably 1 to 8% by weight. 1
If the amount is less than 8% by weight, a sufficient conditioning effect may not be obtained, and if the amount is more than 8% by weight, a suitable conditioning effect may not be obtained. Component (E) contains at least 2 cationic polymers and / or hydroxyl groups in the molecule.
Examples of the compound having one or more include the following. First, as the cationic polymer, cationic cellulose, cationic starch, diallyl ammonium salt / acrylamide copolymer, quaternized polyvinylpyrrolidone derivative, quaternized vinylpyrrolidone / vinylimidazole polymer, polyglycol / amine condensate, Quaternized collagen polypeptide, polyethyleneimine, cationic silicone polymer, adipic acid / dimethylaminohydroxypropyldiethylenetriamine copolymer, polyaminopolyamide, cationic chitin derivative,
Cationic guar gum and quaternized polymers. The content of the cationic polymer is 0.05 to 5% by weight.
Is preferred. If it is less than 0.05% by weight, a sufficient conditioning effect may not be obtained, and if it exceeds 5% by weight, a conditioning effect corresponding thereto may not be obtained. Second, examples of the compound having at least two hydroxyl groups in a molecule include glycerin, diglycerin, propylene glycol, 1,3-butylene glycol, and a sugar derivative. The content of the compound having at least two hydroxyl groups in the molecule is preferably 0.5 to 40% by weight. If it is less than 0.5% by weight, a sufficient conditioning effect cannot be obtained, and if it exceeds 40% by weight, stickiness may become remarkable.

1 to 40% by weight of the anionic surfactant containing an acyl group 2 and a long chain bipolar group as the component (A), and 1 to 40% by weight of the component (B).
1 to 60% by weight of a chain 1 polar group-containing anionic surfactant,
(C) 1 to 8% by weight of a nonionic surfactant as a component,
1 to 8% by weight of the amphoteric surfactant of the component (D), 0.05 to 5% by weight of the cationic polymer of the component (E), and / or 0.5 to 0.5% of a compound having at least two hydroxyl groups in the molecule. When the weight ratio [(A) + (B)] / [(C) + (D)] is 2 to 20 in the present detergent composition containing ５０50% by weight, skin irritation, foaming, foaming It has an excellent effect on creaminess and conditioning effect after washing. Similarly, [(A) + (B)]
When / [(C) + (D)] is from 3 to 10, more excellent effects are exhibited in terms of skin irritation, foaming, foam creaminess, and conditioning effect after washing.

[0010] The detergent composition of the present invention has the composition as described above, but if necessary, other surfactants, emulsifying auxiliaries,
Flavors, colorants, preservatives, pigments, and the like can be appropriately blended within a range that achieves the object of the present invention. The cleansing composition of the present invention is applied to cleansing creams, liquid facial cleansers, body shampoos, shampoos, makeup removers, cleansing cosmetics and the like for cleaning skin or hair.

[0011]

EXAMPLES The present invention will be described below with reference to examples, but the present invention is not limited to these examples. In addition, the compounding amount is weight%. Detergent compositions having the compositions shown in the following table were prepared, and each was evaluated for feel to the hair and skin irritation. The results are shown in the table below. The formula weight% shown in the table is the value of the active ingredient of the active agent.

(Evaluation method) The feel of the hair was measured by 20 expert panelists using 20 g (15c) of the hair of a healthy Japanese woman.
1 g of the cleaning agent was applied to m), and was evaluated according to the following criteria at the time of lathering for 1 minute, the time of rinsing, and the time of drying with a dryer. The results are shown in the table from the average score of 20 subjects according to the following criteria. For evaluation of skin irritation, five cleaning compositions were applied to healthy guinea pig skin four times, and the fourth reaction was evaluated according to the following table. The results are shown in the table from the average score of 5 animals according to the following criteria.

(Criteria) (1) Feeling at the time of whipping Evaluation and score: No squeak, very good finger passage, very large creaminess (score 4) No squeak, good finger passage, large creamy (score 3) A. Creaminess is slightly poor (score 2). Squeaking is strong, fingering and creaminess are poor (score 1). Average score and judgment: Average score 3.1 or more (（) Average score 2.5 to 3.0 (○) Average score 1.5 to 2.4 (△) Average score 1.0 to 1.4 (×) (2) Feeling when rinsed A. Evaluation and score: No squeak, very smooth (score 4) No squeak, smooth (score 3) Slight stiffness, slightly poor smoothness (score 2) Strong squeak, poor (score 1) Average score and judgment: Average score 3.1 or more (（) Average score 2.5 to 3.0 (○) Average score 1.5 to 2.4 (△) Average score 1.0 to 1.4 (×) (3) Feeling after drying the hair A. Evaluation and score: good finger passing, very smooth (score 4) good finger passing, smooth (score 3) poor finger passing, slightly poor smoothness (score 2) poor finger passing (score 1) B. Average score and judgment: Average score 3.1 or more (（) Average score 2.5 to 3.0 (○) Average score 1.5 to 2.4 (△) Average score 1.0 to 1.4 (×) (4) Skin irritation A. Evaluation and score: Non-irritant (score 5) Minor irritant (score 4) Mild irritant (score 3) Medium irritant (score 2) Strong irritant (score 1) Average score and judgment: Average score 3.1 or more (（) Average score 2.5 to 3.0 (○) Average score 1.5 to 2.4 (△) Average score 1.0 to 1.4 (×)

Examples 1 to 43 and Comparative Examples 1 to 8 Tables show the compositions of the cleaning compositions (test samples) of the present invention.
The formulations shown here show the following: (1) Anionic surfactant containing a two-chain dipolar group of component (A) to be blended A1: N, N'-bis (lauroylamide) ethane-
N, N'-di (sodium sulfonate) A2: N, N'-bis (lauroylamide) ethane-
N, N'-di (sodium propionate) (2) One-chain monopolar anionic surfactant of component (B) to be compounded B1: Sodium N-dodecanoylglutamate (3) Compounded (C) Component nonionic surfactant C1: lauric acid diethanolamide (4) amphoteric surfactant D1: lauric acid amidopropyl betaine (5) cationic polymer and compound having at least two or more hydroxyl groups in the molecule E1: cationic JR E2 : Glycerin

[0015]

[Table 1]

[0016]

[Table 2]

[0017]

[Table 3]

[0018]

[Table 4]

[0019]

[Table 5]

[0020]

[Table 6]

From the results shown in Tables 1 to 6, it can be seen that when the hair was washed using the cleaning composition of the present invention, all of the above evaluation items were excellent. On the other hand, it can be seen that the performance of the cleaning composition of the comparative example lacking any one of the components of the cleaning composition of the present invention is much worse than that of the cleaning composition of the present invention.

[0022]

As described above, it is apparent that the present invention provides a detergent composition having low skin irritation, good foaming, excellent creamy feeling of foam, and excellent conditioning effect after washing. is there.

Claims (4)

[Claims] (A) an anionic surfactant containing two acyl groups and two long-chain bipolar groups; (B) an anionic surfactant containing one chain and one polar group; and (C) a nonionic surfactant. A cleaning composition comprising (D) an amphoteric surfactant and (E) a cationic polymer and / or a compound having at least two hydroxyl groups in a molecule. 2. (A) 1 to 40% by weight of an anionic surfactant containing an acyl group 2 and a long chain bipolar group, and (B) 1 to 60% by weight of an anionic surfactant containing a single chain and 1 polar group. (C) 1 to 8% by weight of a nonionic surfactant, (D) 1 to 8% by weight of an amphoteric surfactant, and (E) 0.05 to 10% of a cationic polymer.
A cleaning composition comprising 5% by weight and / or 0.5 to 40% by weight of a compound having at least two hydroxyl groups in a molecule. (A) 1 to 40% by weight of an anionic surfactant containing an acyl group 2 and a long chain bipolar group, and (B) 1 to 60% by weight of an anionic surfactant containing a single chain and one polar group. (C) 1 to 8% by weight of a nonionic surfactant, (D) 1 to 8% by weight of an amphoteric surfactant, and (E) 0.05 to 10% of a cationic polymer.
5% by weight and / or 0.5 to 40% by weight of a compound having at least two hydroxyl groups in the molecule, and the weight ratio [(A) + (B)] / [(C) + (D)] is A cleaning composition comprising 2 to 20. (A) 1 to 40% by weight of an anionic surfactant containing an acyl group 2 and a long chain bipolar group, and (B) 1 to 60% by weight of an anionic surfactant containing a single chain and one polar group. (C) 1 to 8% by weight of a nonionic surfactant, (D) 1 to 8% by weight of an amphoteric surfactant, and (E) 0.05 to 10% of a cationic polymer.
5% by weight and / or 0.5 to 40% by weight of a compound having at least two hydroxyl groups in the molecule, and the weight ratio [(A) + (B)] / [(C) + (D)] is A cleaning composition comprising 3 to 10.