JPH10202817A - Decorative sheet and its manufacture - Google Patents
Decorative sheet and its manufactureInfo
- Publication number
- JPH10202817A JPH10202817A JP9019608A JP1960897A JPH10202817A JP H10202817 A JPH10202817 A JP H10202817A JP 9019608 A JP9019608 A JP 9019608A JP 1960897 A JP1960897 A JP 1960897A JP H10202817 A JPH10202817 A JP H10202817A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- printing
- sheet
- resin
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】建材、家具等の表面化粧シー
ト及びその製造方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a surface decorative sheet for building materials, furniture and the like and a method for producing the same.
【０００２】[0002]
【従来の技術】図２は従来の盛り上げコート紙の断面図
である。建材、家具等に用いる表面化粧シート構成とし
ては、従来は図２に示すようにシート基材１′の表面に
ベタ印刷層２′、柄印刷層３′を順次設けた後、発泡タ
イプ盛り上げインキまたは塩ビゾルタイプ盛り上げイン
キを盛り上げ用版にて印刷し、盛り上げ印刷層５′を設
け、その上に表面を保護する為の透明熱硬化型樹脂層
４′を設けていた。前記発泡タイプまたは塩ビゾルタイ
プ盛り上げインクはいずれも硬度が低いため盛り上げ部
の耐磨耗性が不十分であった。そのため、表面を保護す
る透明熱硬化性樹脂層４′を設けていた。このような構
成からなる従来技術の化粧シートは、盛り上げインキの
上に透明熱硬化型樹脂４′による表面保護層を設けてい
たため、盛り上げ印刷した領域には、前記表面保護層が
付着するが、盛り上げ印刷部以外の領域には、前記表面
保護層４′が充分に形成されない。すなわち、盛り上げ
印刷のため、前記非印刷領域Ｂ′は窪みが大であり、前
記表面保護層４′を形成する透明熱硬化型樹脂４′が充
分転移しないために、盛り上げ印刷における凹部Ｂ′を
完全に被覆できず、図２に示すように、盛り上げ印刷部
Ｔ′以外の凹部に透明熱硬化性樹脂４′による被膜が形
成されないか、または、充分な被膜とならない場合があ
り、その結果、前記凹部領域において耐汚染性、耐溶剤
性が十分でない場合があった。また、その対策として表
面保護層、すなわち、前記透明熱硬化型樹脂層４′を厚
くすると凹凸感がなくなるのが問題であった。2. Description of the Related Art FIG. 2 is a sectional view of a conventional raised coated paper. Conventionally, as a construction of a surface decorative sheet used for building materials, furniture, etc., as shown in FIG. 2, a solid printing layer 2 'and a pattern printing layer 3' are sequentially provided on the surface of a sheet substrate 1 ', and then a foaming type embossing ink is formed. Alternatively, a polyvinyl chloride type embossing ink is printed on an embossing plate to provide an embossed print layer 5 ', and a transparent thermosetting resin layer 4' for protecting the surface is provided thereon. Since the foaming type or PVC sol type embossing ink has low hardness, the abrasion resistance of the embossed portion is insufficient. Therefore, a transparent thermosetting resin layer 4 'for protecting the surface is provided. In the decorative sheet of the prior art having such a configuration, since the surface protective layer made of the transparent thermosetting resin 4 'is provided on the raised ink, the surface protective layer adheres to the region where the raised printing is performed. The surface protective layer 4 'is not sufficiently formed in a region other than the raised print portion. That is, the non-printing area B 'has a large depression due to the emboss printing, and the transparent thermosetting resin 4' forming the surface protective layer 4 'does not sufficiently transfer. As shown in FIG. 2, the film cannot be completely covered, and as shown in FIG. 2, a film of the transparent thermosetting resin 4 ′ may not be formed in the concave portions other than the embossed print portion T ′, or may not be a sufficient film. In some cases, the contamination resistance and the solvent resistance in the concave area were not sufficient. Further, as a countermeasure, there is a problem that when the surface protective layer, that is, the transparent thermosetting resin layer 4 'is made thick, the feeling of unevenness disappears.
【０００３】[0003]
【発明が解決しようとする課題】シャープな盛り上げ印
刷をし、さらに盛り上げ印刷した領域以外の表面物性
が、実用上問題のない耐汚染性、耐溶剤性及び耐磨耗性
を有している化粧シートおよびその製造方法を提供す
る。A cosmetic that is sharply printed and has surface properties other than the area in which the printed image is printed have stain resistance, solvent resistance and abrasion resistance that are practically acceptable. Provided are a sheet and a method for manufacturing the sheet.
【０００４】[0004]
【課題を解決する手段】シート基材表面にベタ印刷層、
柄印刷層及び透明熱硬化型樹脂層を設け、該透明熱硬化
型樹脂層の上に、少なくとも有機系、あるいは無機系充
填材を 5％以上含む熱硬化性インクにて盛り上げ部を設
ける事によりシャープな盛り上げ部を表現でき優れた耐
磨耗性、耐汚染性を有する化粧シートであって、前記シ
ート基材が、坪量15ｇ／ｍ2 〜 300ｇ／ｍ2 の建材用薄
用紙、あるいは熱可塑性樹脂シートであることを含む。A solid printing layer on the surface of a sheet substrate,
By providing a pattern printing layer and a transparent thermosetting resin layer, and providing a raised portion with a thermosetting ink containing at least 5% or more of an organic or inorganic filler on the transparent thermosetting resin layer. A decorative sheet capable of expressing a sharp raised portion and having excellent abrasion resistance and stain resistance, wherein the sheet base material has a basis weight of 15 g / m 2 to 300 g / m 2 or thin paper for building materials or heat. It includes being a plastic resin sheet.
【０００５】[0005]
【発明の実施の形態】本発明は、シャープな盛り上げ部
を表現でき優れた耐磨耗性、耐汚染性を有する化粧シー
トを得るために、シート基材表面にベタ印刷層、柄印刷
層及び透明熱硬化型樹脂層を設ける。前記基材として
は、建材用薄用紙、あるいは熱可塑性樹脂シート等を用
い、通常のグラビア輪転印刷機にて印刷を行うことによ
り実施することができる。図１は、本発明の化粧シート
の実施例の構成を示す断面図である。BEST MODE FOR CARRYING OUT THE INVENTION The present invention provides a solid printed layer, a patterned printed layer and a solid printed layer on the surface of a sheet substrate in order to obtain a decorative sheet capable of expressing sharp raised portions and having excellent abrasion resistance and stain resistance. A transparent thermosetting resin layer is provided. As the base material, thin paper for a building material, a thermoplastic resin sheet, or the like is used, and the printing can be performed by performing printing with a normal gravure rotary printing machine. FIG. 1 is a sectional view showing the configuration of an embodiment of the decorative sheet of the present invention.
【０００６】本発明に用いる基材としては、坪量15g/m2
〜 300g/m2の建材用薄用紙、あるいは25μｍ〜 500μｍ
の厚さ、好ましくは300 μｍ程度の熱可塑性樹脂シート
が使用できる。The substrate used in the present invention has a basis weight of 15 g / m 2
Building materials for thin paper ~ 300g / m 2 or 25μm~ 500μm,
Can be used, preferably a thermoplastic resin sheet having a thickness of about 300 μm.
【０００７】本発明のベタ印刷層２及び柄印刷層３を形
成するインキに添加する顔料としては、チタン白、亜鉛
華、弁柄、朱、群青、コバルトブルー、チタン黄、黄
鉛、カーボンブラック等の無機顔料、イソインドリノ
ン、ハンザイエローＡ、キナクリドン、パーマネントレ
ッド４Ｒ、フタロシアニンブルー、インダスレンブリー
ＲＳ、アニリンブラック等の有機顔料（あるいは染料も
含む）、アルミニウム、真鍮等の金属顔料、二酸化チタ
ン被覆雲母、塩基性炭酸鉛等の箔粉からなる真珠光沢
（パール）顔料等である。ベタ印刷層は、透明着色で
も、或いは不透明（隠蔽性）着色でもよい。前記箔粉
は、粉末或いは鱗片状箔片として添加、分散せしめられ
る。The pigments to be added to the ink for forming the solid printing layer 2 and the pattern printing layer 3 of the present invention include titanium white, zinc white, red pattern, vermilion, ultramarine blue, cobalt blue, titanium yellow, graphite, and carbon black. Inorganic pigments such as isoindolinone, Hansa Yellow A, Quinacridone, Permanent Red 4R, Phthalocyanine Blue, Indaslen Buri RS, and aniline black; or metallic pigments such as aluminum and brass; titanium dioxide Pearlescent (pearl) pigments made of foil powder such as coated mica and basic lead carbonate; The solid printing layer may be transparently colored or opaque (concealing) colored. The foil powder is added and dispersed as powder or scaly foil pieces.
【０００８】模様印刷としては、グラビア印刷、オフセ
ット印刷、シルクスクリーン印刷、転写シートからの転
写印刷等公知の印刷法を用いインキ（或いは染料）にて
模様を形成する。As the pattern printing, a pattern is formed with ink (or dye) using a known printing method such as gravure printing, offset printing, silk screen printing, transfer printing from a transfer sheet.
【０００９】本発明の透明熱硬化型樹脂層４を形成する
樹脂としては、ポリエステル樹脂、エポキシ樹脂、ポリ
ウレタン樹脂、アミノアルキッド樹脂、メラミン樹脂、
グアナミン樹脂、尿素樹脂、熱硬化性アクリル樹脂等の
熱硬化型樹脂が挙げられる。中でもポリウレタン樹脂が
好適に使用できる。ポリウレタン樹脂とは、ポリオール
（多価アルコール）を主剤とし、シソシアネートを架橋
剤（硬化剤）とする樹脂である。ポリオールとしては、
分子中に２個以上の水酸基を有するもので、例えばポリ
エチレングリコール、ポリプロピレングリコール、アク
リルポリオール、ポリエーステルポリオール、ポリエー
テルポリオール、アルキッド変性アクリルポリオール等
が用いられる。中でもアルキッド変性アクリルポリオー
ルが好ましい。The resin forming the transparent thermosetting resin layer 4 of the present invention includes polyester resin, epoxy resin, polyurethane resin, amino alkyd resin, melamine resin, and the like.
A thermosetting resin such as a guanamine resin, a urea resin, and a thermosetting acrylic resin may be used. Among them, a polyurethane resin can be preferably used. The polyurethane resin is a resin having a polyol (polyhydric alcohol) as a main component and a sissocyanate as a crosslinking agent (curing agent). As a polyol,
Those having two or more hydroxyl groups in the molecule, for example, polyethylene glycol, polypropylene glycol, acrylic polyol, polyester polyol, polyether polyol, alkyd-modified acrylic polyol and the like are used. Among them, alkyd-modified acrylic polyols are preferred.
【００１０】又、イソシアネートとしては、分子中に２
個以上のイソシアネート基を有する多価イソシアネート
が用いられる。例えば、２−４トリレンジイソシアネー
ト、キシレンジイソシアネート、４−４ジフェニルメタ
ンジイソシアネート等の芳香族イソシアネート、或いは
ヘキサメチレンジイソシアネート、イソホロンジイソシ
アネート、水素添加トリレンジイソシアネート、水素添
加ジフェニルメタンジイソシアネート等の脂肪族イソシ
アネートが用いられる。[0010] Further, as the isocyanate, 2
A polyvalent isocyanate having at least two isocyanate groups is used. For example, aromatic isocyanates such as 2-4 tolylene diisocyanate, xylene diisocyanate, and 4-4 diphenylmethane diisocyanate, or aliphatic isocyanates such as hexamethylene diisocyanate, isophorone diisocyanate, hydrogenated tolylene diisocyanate, and hydrogenated diphenylmethane diisocyanate are used.
【００１１】本発明の盛り上げ印刷層５を形成する熱硬
化型樹脂インキの、熱硬化型樹脂としては、ポリエステ
ル樹脂、エポキシ樹脂、ポリウレタン樹脂、アミノアル
キッド樹脂、メラミン樹脂、グアナミン樹脂、尿素樹
脂、熱硬化型アクリル樹脂等の熱硬化型樹脂等が挙げら
れる。中でもポリウレタン樹脂が好ましい。また、盛り
上げ印刷用インキに用いる充填剤としては、シリカ、水
酸化アルミニウム、炭酸カルシウム等の無機系充填剤あ
るいは有機系充填剤が挙げられる。充填剤の添加量は充
填剤の比重によって適量が異なり、比重が大きい程添加
量を多くする。例えば、シリカを充填剤とする場合は、
盛り上げ印刷インキ中5 〜15％が好ましい。また、盛り
上げ印刷用インキに用いる着色剤としては、各種無機、
有機の顔料を用いることができる。The thermosetting resin of the thermosetting resin ink for forming the raised print layer 5 of the present invention includes polyester resin, epoxy resin, polyurethane resin, aminoalkyd resin, melamine resin, guanamine resin, urea resin, and thermosetting resin. A thermosetting resin such as a curable acrylic resin may be used. Among them, a polyurethane resin is preferable. Examples of the filler used in the printing ink for printing include an inorganic filler such as silica, aluminum hydroxide, and calcium carbonate, or an organic filler. The appropriate amount of the filler depends on the specific gravity of the filler. The larger the specific gravity, the larger the amount of the filler. For example, when silica is used as the filler,
5 to 15% of the printing ink is preferred. In addition, as a coloring agent used in the ink for swelling printing, various inorganic,
Organic pigments can be used.
【００１２】次に、盛り上げ印刷用インキの粘度として
は、数100 〜数千CPS が妥当である。粘度調整は、一般
の有機溶剤を用いることができるが、ゲル化を促進する
という意味では極性の高いセロソルブ系が好ましい。印
刷方式としては、バターン状に盛り上げることができれ
ば何でも良いが、ウェブ状態で安定的に印刷でき、盛り
上げ効果を期待できる方式としては、グラビア印刷方式
が好ましい。Next, the viscosity of the printing ink for printing is suitably several hundred to several thousand CPS. For the viscosity adjustment, a general organic solvent can be used, but a cellosolve having a high polarity is preferable in terms of accelerating gelation. Any printing method may be used as long as it can be raised in a pattern, but a gravure printing method is preferable as a method capable of stably printing in a web state and expecting an effect of raising.
【００１３】この際グラビアシリンダーの版深として
は、45〜200 μｍ程度を用いる。スクリーンは有っても
無くてもどちらでも良い。一般的に言って、比較的繊細
なパターンで、凹凸が少ない場合は、インチ当り50線程
度の一般的なスクリーンやストライブ状の万線スクリー
ンや斜めストライブ状の斜め万線スクリーンが有った方
が転移状態が安定する。この場合セル幅と土手幅の比
は、用いるインキの粘度や転移率に依存するが、一般的
にこの場合は３以上が好ましい。転移したインキの凹凸
厚さは、デザインに応じて設計される。厚い程、立体感
のあるデザインを表現することができる。一方凹凸感よ
りも光沢感のみを期待する場合には、数ミクロンの厚さ
であっても良い。ただし、耐磨耗性を得るためには、10
ミクロン以上の厚さを有するのが好ましい。盛り上げ印
刷のパターンは、柄印刷層の印刷と同調させても良い
し、同調させずに柄の一部を形成させるようにしても良
い。At this time, the plate depth of the gravure cylinder is about 45 to 200 μm. The screen may or may not be present. Generally speaking, if the pattern is relatively delicate and has few irregularities, there is a general screen of about 50 lines per inch, a striped line screen, or a diagonally striped line screen. The more stable the metastatic state. In this case, the ratio of the cell width to the bank width depends on the viscosity and transfer rate of the ink used, but in this case, generally 3 or more is preferable. The thickness of the transferred ink unevenness is designed according to the design. The thicker, the more three-dimensional the design can be. On the other hand, when only glossiness is expected rather than unevenness, the thickness may be several microns. However, in order to obtain abrasion resistance, 10
Preferably, it has a thickness of a micron or more. The pattern of the embossed printing may be synchronized with the printing of the pattern printing layer, or a part of the pattern may be formed without tuning.
【００１４】本発明の化粧シートは、図１に示すよう
に、透明熱硬化性樹脂４からなる表面保護層の上に、盛
り上げ印刷インキにより、盛り上げ印刷層５が形成さ
れ、前記盛り上げ印刷用のインキが、耐汚染性、耐溶剤
性及び耐磨性を有しているため、盛り上げ印刷凸部Ｔ、
盛り上げ印刷凹部Ｂともに表面保護性の点から優れた耐
汚染性、耐溶剤性を示す構造となった。In the decorative sheet of the present invention, as shown in FIG. 1, a raised printing layer 5 is formed on a surface protective layer made of a transparent thermosetting resin 4 by a raised printing ink. Since the ink has stain resistance, solvent resistance and abrasion resistance, the raised printing convex portion T,
Both the raised printing concave portions B had a structure showing excellent stain resistance and solvent resistance in terms of surface protection.
【００１５】〔実施例１〕キッチン用表面化粧シートを
次の条件で作成した。30g/m2の薄葉紙（ＧＦ６０１ 興
人株式会社製 商品名）に、１色目（ベタ印刷）、２色
目（柄印刷）をグラビア輪転印刷機にて印刷をした。 ベタインキ: 樹脂: アクリルポリオールとイソシアネートからなるウ
レタン樹脂（ＵＥ株式会社 昭和インク工業所 商品
名） 柄インキ: 樹脂: ニトロセルロース樹脂とアルキッド樹脂の混合樹
脂（ＫＬ−ＭＡＸザ・インクテック株式会社製 商品
名） 続く３色目（透明熱硬化性樹脂層）を次の組成のインキ
として印刷し、その塗布量は 8ｇ／ｍ2 ・dry を得た。 透明熱硬化性樹脂用のインキ： 樹脂: アルキッド変性ポリオールとイソシアネートから
なるウレタン樹脂（ＫＲ−７００ ザ・インクテック株
式会社製 商品名）60％ 溶剤: 酢酸エチル40％ ４色目（盛り上げ印刷）において、次の組成のインキお
よびその他の条件にて盛り上げ印刷を行った。 盛り上げ印刷インキ： 樹脂：アクリルポリオールとイソシアネートからなるウ
レタン樹脂（ＫＫＢキュアＵメジュウム 大日精化株式
会社製 商品名）55％ 添加剤: シリカ 5％ 溶剤: 酢酸エチル 40％ インキ粘度: 2000cps 得られた化粧シートをパーティクルボードの成形品にラ
ミネートして、キッチン前面の壁材とした。外観として
は、極めてシャープな凹凸感を感じさせる壁材であり、
また、その表面の耐汚染性、耐溶剤性においても優れた
結果を示した。Example 1 A surface decorative sheet for kitchen was prepared under the following conditions. The first color (solid printing) and the second color (pattern printing) were printed on a 30 g / m 2 thin paper (trade name of GF601 Kojin Co., Ltd.) using a gravure rotary printing press. Solid ink: Resin: Urethane resin composed of acrylic polyol and isocyanate (trade name of Showa Ink Industries, Ltd. UE) Pattern ink: Resin: Mixed resin of nitrocellulose resin and alkyd resin (KL-MAX The Inktec Co., Ltd.) The subsequent third color (transparent thermosetting resin layer) was printed as an ink having the following composition, and the coating amount was 8 g / m 2 · dry. Ink for transparent thermosetting resin: Resin: Urethane resin composed of alkyd-modified polyol and isocyanate (trade name of KR-700, manufactured by The Inktech Co., Ltd.) 60% Solvent: Ethyl acetate 40% In the fourth color (uplift printing), Emboss printing was performed with an ink having the following composition and other conditions. Embossed printing ink: Resin: Urethane resin composed of acrylic polyol and isocyanate (KKB Cure U Medium, manufactured by Dainichi Seika Co., Ltd.) 55% Additive: Silica 5% Solvent: Ethyl acetate 40% Ink viscosity: 2000cps The obtained decorative sheet was laminated on a particle board molded product to form a wall material on the front of the kitchen. As an external appearance, it is a wall material that makes you feel extremely sharp unevenness,
In addition, excellent results were shown in the stain resistance and solvent resistance of the surface.
【００１６】[0016]
【発明の効果】従来の盛り上げコート紙と比較して盛り
上げ印刷凸部、盛り上げ印刷凹部ともに耐汚染性、耐溶
剤性、耐磨耗性の良好な盛り上げコート紙が製造でき
た。その凹凸感もシャープであり、化粧シートとして優
れた特性を有するものを得ることができた。According to the present invention, a raised coated paper having good stain resistance, solvent resistance, and abrasion resistance can be produced for both raised printing convex portions and raised printing concave portions as compared with conventional raised coated paper. The unevenness was also sharp, and a sheet having excellent characteristics as a decorative sheet could be obtained.
【図１】本発明の化粧シートの実施例の構成を示す断面
図FIG. 1 is a sectional view showing the configuration of an embodiment of a decorative sheet according to the present invention.
【図２】従来の技術による化粧シートの実施例の構成を
示す断面図FIG. 2 is a cross-sectional view showing a configuration of an embodiment of a decorative sheet according to a conventional technique.
１ 基材シート ２ ベタ印刷層 ３ 柄印刷層 ４ ４′透明熱硬化型樹脂層 ５，５′盛り上げ印刷層 Ｔ，Ｔ′盛り上げ印刷凸部 Ｂ，Ｂ′盛り上げ印刷凹部 DESCRIPTION OF SYMBOLS 1 Base sheet 2 Solid printing layer 3 Pattern printing layer 4 4 'Transparent thermosetting resin layer 5, 5' raised printing layer T, T 'raised printing convex part B, B' raised printing concave part
───────────────────────────────────────────────────── フロントページの続き (72)発明者 田中 清人 東京都新宿区市谷加賀町一丁目１番１号 大日本印刷株式会社内 ────────────────────────────────────────────────── ─── Continued on the front page (72) Inventor Kiyoto Tanaka 1-1-1 Ichigaya Kagacho, Shinjuku-ku, Tokyo Inside Dai Nippon Printing Co., Ltd.
Claims (4)
及び透明熱硬化型樹脂層が積層され、前記透明熱硬化型
樹脂層の上に、少なくとも有機系、あるいは無機系充填
材を 5％以上含む熱硬化性インクにて盛り上げ部が形成
されたシャープな凹凸感を表現できて、かつ、優れた耐
磨耗性、耐汚染性を有する事を特徴とする化粧シート。1. A solid printing layer, a pattern printing layer and a transparent thermosetting resin layer are laminated on a sheet substrate surface, and at least an organic or inorganic filler is provided on the transparent thermosetting resin layer. %. A decorative sheet characterized by being able to express a sharp unevenness in which a raised portion is formed with a thermosetting ink containing at least%, and having excellent abrasion resistance and stain resistance.
00ｇ／ｍ2 の建材用薄用紙、あるいは熱可塑性樹脂シー
トであることを特徴とする請求項１記載の化粧シ2. The method according to claim 1, wherein the sheet base has a basis weight of 15 g / m 2 to 3 g.
2. A decorative sheet according to claim 1, wherein the sheet is a thin paper for building materials of 00 g / m 2 or a thermoplastic resin sheet.
及び透明熱硬化型樹脂層を設け、該透明熱硬化型樹脂層
の上に、少なくとも有機系、あるいは無機系充填材を 5
％以上含む熱硬化性インクにて盛り上げ部を設ける事を
特徴とする化粧シートの製造方法。3. A solid printing layer, a pattern printing layer and a transparent thermosetting resin layer are provided on the surface of the sheet substrate, and at least an organic or inorganic filler is provided on the transparent thermosetting resin layer.
%. A method for producing a decorative sheet, wherein a raised portion is provided with a thermosetting ink containing at least%.
00ｇ／ｍ2 の建材用薄用紙、あるいは熱可塑性樹脂シー
トであることを特徴とする請求項３記載の化粧シートの
製造方法。4. The method according to claim 1, wherein the sheet base has a basis weight of 15 g / m 2 to 3 g.
Decorative sheet manufacturing method of claim 3, wherein it is 200 g / m 2 of building materials for thin paper or a thermoplastic resin sheet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP01960897A JP4011663B2 (en) | 1997-01-20 | 1997-01-20 | Decorative sheet and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP01960897A JP4011663B2 (en) | 1997-01-20 | 1997-01-20 | Decorative sheet and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH10202817A true JPH10202817A (en) | 1998-08-04 |
| JP4011663B2 JP4011663B2 (en) | 2007-11-21 |
Family
ID=12003916
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP01960897A Expired - Fee Related JP4011663B2 (en) | 1997-01-20 | 1997-01-20 | Decorative sheet and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4011663B2 (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001038854A (en) * | 1999-07-29 | 2001-02-13 | Toppan Printing Co Ltd | Decorative sheet |
| KR20030035897A (en) * | 2001-10-19 | 2003-05-09 | 데이코쿠 잉키 세이조 가부시키가이샤 | Resin molded product having metallic luster surface |
| JP2008087155A (en) * | 2006-09-29 | 2008-04-17 | Dainippon Printing Co Ltd | Decorative sheet |
| JP2008087156A (en) * | 2006-09-29 | 2008-04-17 | Dainippon Printing Co Ltd | Decorative sheet |
| JP2008087158A (en) * | 2006-09-29 | 2008-04-17 | Dainippon Printing Co Ltd | Decorative sheet |
| JP2008087157A (en) * | 2006-09-29 | 2008-04-17 | Dainippon Printing Co Ltd | Decorative sheet |
| KR101091477B1 (en) | 2011-05-19 | 2011-12-08 | 주식회사 피엔씨코리아 | Chemical embossing method on the coating paper |
| JP2017024318A (en) * | 2015-07-24 | 2017-02-02 | 凸版印刷株式会社 | Decorative sheet and decorative plate |
| JP2017024319A (en) * | 2015-07-24 | 2017-02-02 | 凸版印刷株式会社 | Decorative sheet and decorative plate |
| KR20180017175A (en) * | 2015-07-24 | 2018-02-20 | 도판 인사츠 가부시키가이샤 | Decorative sheet and veneer |
| JP2020075414A (en) * | 2018-11-08 | 2020-05-21 | 凸版印刷株式会社 | Decorative sheet |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61202839A (en) * | 1985-03-06 | 1986-09-08 | 大日本印刷株式会社 | "uzukuri"-like grain decorative wood |
-
1997
- 1997-01-20 JP JP01960897A patent/JP4011663B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61202839A (en) * | 1985-03-06 | 1986-09-08 | 大日本印刷株式会社 | "uzukuri"-like grain decorative wood |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001038854A (en) * | 1999-07-29 | 2001-02-13 | Toppan Printing Co Ltd | Decorative sheet |
| KR20030035897A (en) * | 2001-10-19 | 2003-05-09 | 데이코쿠 잉키 세이조 가부시키가이샤 | Resin molded product having metallic luster surface |
| JP2008087155A (en) * | 2006-09-29 | 2008-04-17 | Dainippon Printing Co Ltd | Decorative sheet |
| JP2008087156A (en) * | 2006-09-29 | 2008-04-17 | Dainippon Printing Co Ltd | Decorative sheet |
| JP2008087158A (en) * | 2006-09-29 | 2008-04-17 | Dainippon Printing Co Ltd | Decorative sheet |
| JP2008087157A (en) * | 2006-09-29 | 2008-04-17 | Dainippon Printing Co Ltd | Decorative sheet |
| KR101091477B1 (en) | 2011-05-19 | 2011-12-08 | 주식회사 피엔씨코리아 | Chemical embossing method on the coating paper |
| JP2017024318A (en) * | 2015-07-24 | 2017-02-02 | 凸版印刷株式会社 | Decorative sheet and decorative plate |
| JP2017024319A (en) * | 2015-07-24 | 2017-02-02 | 凸版印刷株式会社 | Decorative sheet and decorative plate |
| KR20180017175A (en) * | 2015-07-24 | 2018-02-20 | 도판 인사츠 가부시키가이샤 | Decorative sheet and veneer |
| JP2020075414A (en) * | 2018-11-08 | 2020-05-21 | 凸版印刷株式会社 | Decorative sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4011663B2 (en) | 2007-11-21 |
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