JPH0952751A - Planar regenerated building material and its production - Google Patents
Planar regenerated building material and its productionInfo
- Publication number
- JPH0952751A JPH0952751A JP20807095A JP20807095A JPH0952751A JP H0952751 A JPH0952751 A JP H0952751A JP 20807095 A JP20807095 A JP 20807095A JP 20807095 A JP20807095 A JP 20807095A JP H0952751 A JPH0952751 A JP H0952751A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- raw material
- mixture
- plate
- building material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Press-Shaping Or Shaping Using Conveyers (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、無機質系建築材料
廃材例えばけい酸カルシウム板、スレート、パーライト
板、スラグせっこう板、窯業系サイディング、抄造せっ
こう板、せっこうボード等の建築施工時に切断加工等に
より破材となった廃材並びに建築材料としての役目を果
たし終えた廃材を原料としてリサイクル建築材料として
再使用することができる板状再生建築材料及び板状再生
建築材料を芯材とし、その両面に面材を備えてなる複合
再生建築材料並びにその製造方法に関するものである。TECHNICAL FIELD The present invention relates to a waste material of an inorganic building material such as calcium silicate board, slate, perlite board, slag gypsum board, ceramic siding, papermaking gypsum board, gypsum board, etc. Recycled building materials and reclaimed building materials that can be reused as recycled building materials from waste materials that have been destroyed by processing, etc. and waste materials that have finished their role as building materials are used as core materials. The present invention relates to a composite recycled building material having face materials on both sides and a manufacturing method thereof.
【0002】[0002]
【従来の技術・課題】建築の発展に伴い、防火、耐火性
能の向上を図るために、無機質系不燃材料であるけい酸
カルシウム板、スレート、パーライト板、窯業系サイデ
ィング、抄造せっこう板、せっこうボード等の無機質系
建築材料が多く使用されている。しかしながら、建築施
工時に切断加工等により生ずる破材及び建築材料として
の役目を果たし終えた廃材はその一部が粉砕され、例え
ばけい酸カルシウム板廃材粉砕物であれば、けい酸カル
シウム板を製造する際の、スレート廃材粉砕物であれ
ば、スレートを製造する際の増量材としてそれぞれの材
質に活用されているが、その添加量は通常5重量%程
度、多くても7重量%程度であり、添加量を増すと生産
される建築材料の性能が低下するためにその使用量には
限界がある。[Prior Art / Problems] With the development of architecture, in order to improve fire prevention and fire resistance, inorganic noncombustible materials such as calcium silicate board, slate, perlite board, ceramic siding, papermaking gypsum board, and gypsum Many inorganic building materials such as wood boards are used. However, a part of the waste material that has been used as a building material and the destructive material caused by cutting during construction work is crushed. For example, if it is a crushed product of calcium silicate plate, a calcium silicate plate is manufactured. At this time, if it is a slate waste material crushed product, it is utilized for each material as an extender when manufacturing slate, but the addition amount is usually about 5% by weight, at most about 7% by weight, There is a limit to the amount of use because the performance of the building materials produced decreases as the amount added increases.
【0003】また、無機質系建築材料廃材はセメント原
料としても利用されているが、セメント組成の調整、品
質の安定性、設備の改良等の問題があり、再利用されて
いる量は微々たるもので、大部分は廃棄処分されてお
り、環境問題及び限りある資源の有効利用の点からも無
機質系建築材料廃材の再利用が切望されている。Further, although the inorganic building material waste materials are also used as a cement raw material, there are problems such as adjustment of cement composition, stability of quality, improvement of equipment, etc., and the amount reused is insignificant. However, most of them are discarded, and there is a strong demand for reuse of waste inorganic building materials from the viewpoint of environmental problems and effective use of limited resources.
【0004】従って、本発明の目的は、無機質系建築材
料廃材等のリサイクルを図り建築材料として使用できる
再生建築材料及び複合建築材料並びにその製造方法を提
供することにある。Therefore, an object of the present invention is to provide a recycled building material and a composite building material which can be used as a building material by recycling inorganic building material waste materials and the like, and a method for producing the same.
【0005】[0005]
【課題を解決するための手段】即ち、本発明は、無機質
系建築材料廃材粉砕物20〜90重量%及び結合剤10
〜80重量%よりなる配合物100重量部に対して補強
繊維を5重量部以下の量で含有してなる原料配合物を成
形することにより得られた板状再生建築材料にある。That is, according to the present invention, 20 to 90% by weight of a ground waste of an inorganic building material and a binder 10 are used.
It is a plate-like recycled building material obtained by molding a raw material mixture containing reinforcing fibers in an amount of 5 parts by weight or less with respect to 100 parts by weight of a mixture of -80% by weight.
【0006】また、本発明は、無機質系建築材料廃材粉
砕物20〜90重量%及び結合剤10〜80重量%より
なる構成される芯材と、該芯材の両面に接着された抄造
せっこう板、スレートボード、けい酸カルシウム板及び
紙からなる群から選択された面材を備えてなる板状複合
再生建築材料にある。Further, according to the present invention, a core material composed of 20 to 90% by weight of a pulverized waste material of an inorganic building material and 10 to 80% by weight of a binder, and a papermaking gypsum bonded to both sides of the core material A plate-like composite recycled building material comprising a face material selected from the group consisting of board, slate board, calcium silicate board and paper.
【0007】更に、本発明は、無機質系建築材料廃材粉
砕物20〜90重量%及び結合剤10〜80重量%より
なる配合物と、該配合物100重量部に対して5重量部
以下の量の補強繊維より構成される芯材と、該芯材の両
面に接着された抄造せっこう板、スレートボード、けい
酸カルシウム板及び紙からなる群から選択された面材を
備えてなる板状複合再生建築材料にある。Further, the present invention provides a mixture comprising 20 to 90% by weight of ground inorganic waste building materials and 10 to 80% by weight of a binder, and an amount of 5 parts by weight or less based on 100 parts by weight of the mixture. A plate-shaped composite comprising a core material composed of the reinforcing fiber of (1) and a face material selected from the group consisting of paper-made gypsum board, slate board, calcium silicate board and paper bonded to both sides of the core material. It is in recycled building materials.
【0008】なお、本発明の板状複合再生建築材料は、
所定の形状の型枠の底部に、予め原料混合物と接する面
に接着剤を塗布してある面材を設置し、該型枠の面材上
に、原料配合物100重量部に対して5〜100重量部
の水を添加して半乾燥状態とした原料混合物を投入し、
次に、該原料混合物上に、予め原料混合物と接する面に
接着剤を塗布してある面材を設置し、所定の成形圧力に
て加圧成形し、脱型、養生硬化、乾燥することを特徴と
して製造することができる。The plate-shaped composite recycled building material of the present invention is
A face material having an adhesive applied to the surface in contact with the raw material mixture in advance is installed at the bottom of the mold having a predetermined shape, and 5 to 100 parts by weight of the raw material mixture is placed on the face material of the mold. Add 100 parts by weight of water to add a semi-dried raw material mixture,
Next, on the raw material mixture, a face material having an adhesive applied to the surface in contact with the raw material mixture in advance is placed, pressure molding is performed at a predetermined molding pressure, demolding, curing and drying. It can be manufactured as a feature.
【0009】[0009]
【発明の実施の形態】本発明の板状再生建築材料並びに
板状複合建築材料は、けい酸カルシウム板、スレート
(スレートボード、スレート波板等)、パーライト板、ス
ラグせっこう板、窯業系サイディング、抄造せっこう
板、せっこうボード等のような無機質系建築材料廃材を
原料としてリサイクルして再度建築材料として使用する
ものである。BEST MODE FOR CARRYING OUT THE INVENTION The plate-shaped recycled building material and plate-shaped composite building material of the present invention are calcium silicate plate and slate.
(Slate board, slate corrugated board, etc.), perlite board, slag gypsum board, ceramic siding, papermaking gypsum board, gypsum board, etc. To do.
【0010】本発明において、原料となる無機質系建築
材料廃材粉砕物は、無機質系建築材料廃材を例えばジョ
ークラッシャー、衝撃破砕機等により粗粉砕した後、衝
撃粉砕機等により粉砕することにより得ることができ
る。無機質系建築材料廃材粉砕物は、6メッシュ以上、
好ましくは32メッシュ以上にまで粉砕したものが好ま
しい。なお、無機質系建築材料廃材粉砕物は、2種以上
の無機質系建築材料廃材粉砕物の混合物であっても差し
支えない。In the present invention, the pulverized inorganic building material waste material as a raw material is obtained by coarsely pulverizing the inorganic building material waste material by, for example, a jaw crusher, an impact crusher or the like, and then pulverizing it by an impact crusher or the like. You can Inorganic building material waste material crushed product, 6 mesh or more,
It is preferable to pulverize to 32 mesh or more. The pulverized inorganic building material waste material may be a mixture of two or more pulverized inorganic building material waste materials.
【0011】また、無機質系建築材料廃材として、塗装
等によりカラー化粧してある廃材も用いることができ
る。本発明の板状再生建築材料の用途によっては、カラ
ー化粧廃材の色合いが好ましくない場合もあるが、この
場合には、得られる板状再生建築材料を建築物の表面に
現れないバッカー材として使用したり、本発明の板状複
合再生建築材料の芯材として用いれば良い。また、せっ
こうボード等には面材として紙が用いられているが、こ
の紙も粉砕されて解繊されるので何ら問題なく本発明の
原料として使用することができ、むしろ、粉砕されて解
繊された紙は補強繊維の一部として有効に利用すること
ができるために好ましい場合もある。As the inorganic building material waste material, it is also possible to use a waste material that has been color-decorated by painting or the like. Depending on the application of the plate-shaped recycled building material of the present invention, the shade of the color makeup waste material may not be preferable, in which case the obtained plate-shaped recycled building material is used as a backer material that does not appear on the surface of the building. Alternatively, it may be used as the core material of the plate-shaped composite recycled building material of the present invention. Further, paper is used as a face material for gypsum boards and the like, but since this paper is also crushed and defibrated, it can be used as the raw material of the present invention without any problems, and rather, it is crushed and crushed. In some cases, woven paper may be preferable because it can be effectively used as a part of the reinforcing fiber.
【0012】本発明に使用する結合剤としては、無機質
結合剤または有機質結合剤を挙げることができる。無機
質結合剤としては、例えば普通ポルトランドセメント、
アルミナセメント、早強セメント、フライアッシュセメ
ント、半水せっこう等の水硬性結合剤が好ましい。ま
た、有機質結合剤としては、SBR系ラテックス、アク
リル酸エステルのエマルジョンまたは粉末、酢酸ビニル
エマルジョン等を使用することができる。なお、本発明
に使用する無機質系建築材料廃材粉砕物との分散性、作
業性、価格などの点より、普通ポルトランドセメントを
結合剤として使用することが好ましい。The binder used in the present invention may be an inorganic binder or an organic binder. As the inorganic binder, for example, ordinary Portland cement,
Hydraulic binders such as alumina cement, early-strength cement, fly ash cement and semi-water gypsum are preferred. As the organic binder, SBR latex, acrylic ester emulsion or powder, vinyl acetate emulsion, or the like can be used. It is preferable to use ordinary Portland cement as a binder from the viewpoints of dispersibility with the pulverized waste material of the inorganic building material used in the present invention, workability, and cost.
【0013】無機質系建築材料廃材粉砕物と結合剤の配
合割合は、無機質系建築材料廃材粉砕物20〜90重量
%、結合剤10〜80重量%の範囲内であるが、無機質
系建築材料廃材粉砕物40〜80重量%、結合剤20〜
60重量%の範囲内であることが好ましい。ここで、結
合剤の配合量が多い場合には、得られる板状再生建築材
料や板状複合再生建築材料の強度は上昇するが、無機質
系建築材料廃材を再利用する立場からは、無機質系建築
材料廃材の使用量が少ないためにリサイクルの効率が悪
くなるために好ましくない。また、逆に、無機質系建築
材料廃材の配合量を多くすると得られる板状再生建築材
料や板状複合再生建築材料の強度は低下して建築材料と
しては好ましくないものとなるために上記範囲内とする
ことが好ましい。The mixing ratio of the crushed inorganic building material waste material and the binder is in the range of 20 to 90% by weight of the inorganic building material waste material and 10 to 80% by weight of the binder. 40 to 80% by weight of pulverized product, 20 to binder
It is preferably within the range of 60% by weight. Here, when the amount of the binder compounded is large, the strength of the obtained plate-like recycled building material or plate-like composite recycled building material increases, but from the standpoint of recycling inorganic building material waste materials, It is not preferable because the amount of waste construction materials used is small and the recycling efficiency becomes poor. On the contrary, if the amount of the inorganic building material waste material is increased, the strength of the plate-like recycled building material or the plate-like composite recycled building material decreases and becomes unfavorable as a building material within the above range. It is preferable that
【0014】本発明において、補強繊維としては例えば
耐アルカリガラス繊維、ガラス繊維、カーボン繊維、石
綿等の無機質系繊維、セルロース繊維、ビニロン繊維、
ポリプロピレン繊維、ポリアミド繊維等の有機質繊維を
使用することができるが、価格、強度発現力及び得られ
る板状再生建築材料や板状複合再生建築材料の製品の安
定性の点から選択すれば良い。In the present invention, examples of the reinforcing fiber include alkali-resistant glass fiber, glass fiber, carbon fiber, inorganic fiber such as asbestos, cellulose fiber, vinylon fiber,
Organic fibers such as polypropylene fibers and polyamide fibers can be used, but they may be selected from the viewpoints of price, strength development ability, and stability of the product of the plate-like recycled building material or the plate-like composite recycled building material obtained.
【0015】補強繊維の配合量は、板状再生建築材料の
用途、ハンドリング性等により決定されるが、無機質系
建築材料廃材粉砕物と結合剤の合計量100重量部に対
して5重量部以下が好ましい。ここで、補強繊維の配合
量が5重量部を超えると原料混合の際に繊維同志が絡み
合いファイバーボール状等になり分散性が顕著に悪くな
り、補強繊維の効果が発揮できなく、また、コストも高
くなる等の欠点があるために好ましくない。なお、板状
複合再生建築材料の芯材として使用する場合には、芯材
の両面に面材が設置され、この面材は高強度を有するた
めに補強繊維を配合しなくても良い。The blending amount of the reinforcing fiber is determined depending on the use and handling property of the plate-like recycled building material, but is not more than 5 parts by weight based on 100 parts by weight of the total amount of the pulverized inorganic building material waste material and the binder. Is preferred. Here, when the amount of the reinforcing fiber is more than 5 parts by weight, the fibers are entangled with each other during the mixing of the raw materials to form a fiber ball shape or the like and the dispersibility is significantly deteriorated, and the effect of the reinforcing fiber cannot be exerted, and the cost is reduced. It is not preferable because of the drawbacks such as high cost. When used as a core material for a plate-like composite recycled building material, face materials are provided on both sides of the core material, and since the face material has high strength, it is not necessary to mix reinforcing fibers.
【0016】本発明の板状再生建築材料は、上記成分配
合を有する原料配合物100重量部に対して5〜100
重量部、好ましくは10〜60重量部の水を添加、混合
して原料混合物とし、この原料混合物を半乾式成形する
ことにより製造することができる。The plate-shaped recycled building material of the present invention is 5 to 100 parts by weight based on 100 parts by weight of the raw material mixture having the above-mentioned components.
It can be produced by adding and mixing 10 parts by weight of water, preferably 10 to 60 parts by weight, to prepare a raw material mixture, and semi-dry molding the raw material mixture.
【0017】本発明の板状再生建築材料の製造方法を更
に詳細に説明すると、まず、無機質系建築材料廃材粉砕
物、結合剤及び補強繊維を所定割合秤量して混合機等に
投入して乾式で均一に混合する。なお、補強繊維を添加
する際に、補強繊維の種類によりファイバーボール状態
に固まることがあるので、添加方法及び混合機を適宜選
択して均一に補強繊維を分散させることが望ましい。次
に、乾式混合しながら所定量の水を添加して充分に分散
するまで混合する。なお、水の添加を無造作に行うと、
混合物が継子状態となるので、水は噴霧状態で添加する
ことが望ましい。また、結合剤が液状の場合には、液状
結合剤と水の所定量を予め混合し、この混合物を噴霧状
態で添加、混合することが望ましい。このようにして半
乾燥状態の原料混合物を得る。The method for producing the plate-like recycled building material of the present invention will be described in more detail. First, a pulverized product of waste inorganic building material, a binder and a reinforcing fiber are weighed at a predetermined ratio and put into a mixer or the like to be dry-processed. Mix evenly with. When the reinforcing fiber is added, it may be solidified into a fiber ball state depending on the type of the reinforcing fiber. Therefore, it is desirable to appropriately select the addition method and the mixer to uniformly disperse the reinforcing fiber. Next, while dry mixing, a predetermined amount of water is added and mixed until sufficiently dispersed. If you add water randomly,
It is desirable to add water in a nebulized state as the mixture will be in a step state. Further, when the binder is liquid, it is desirable that the liquid binder and a predetermined amount of water are mixed in advance, and this mixture is added and mixed in a spray state. In this way, a semi-dried raw material mixture is obtained.
【0018】次に、得られた半乾燥状態の原料混合物を
所望の形状の型枠に投入し、加圧成形を行う。加圧成形
の成形圧力は、板状再生建築材料の密度及び曲げ強さに
関係する。成形圧力が小さい場合には、密度、曲げ強さ
は小さくなる。逆に、成形圧力が大きい場合には、密
度、曲げ強さ共大きくなる。従って、得られる板状再生
建築材料の用途、目的により密度、曲げ強さを設定し、
成形圧力を選択することが好ましい。加圧後圧力を解除
して型枠より取り出し、得られた成形体が硬化するまで
養生を行う。硬化養生の条件は、使用する結合剤により
異なり、使用する結合剤の硬化に最適な温度、時間等の
条件で行うことが望ましい。硬化養生後、乾燥すること
により本発明の板状再生建築材料を得ることができる。Next, the obtained semi-dried raw material mixture is put into a mold having a desired shape and pressure-molded. The molding pressure of the pressure molding is related to the density and bending strength of the plate-shaped recycled building material. When the molding pressure is low, the density and bending strength are low. On the contrary, when the molding pressure is large, both the density and the bending strength are large. Therefore, set the density and bending strength according to the purpose and purpose of the obtained plate-shaped recycled building material,
It is preferable to select the molding pressure. After pressurization, the pressure is released, the product is taken out of the mold, and curing is performed until the obtained molded product is cured. The curing and curing conditions differ depending on the binder used, and it is desirable to carry out the curing at the optimum temperature and time for curing the binder. After curing and curing, the plate-like recycled building material of the present invention can be obtained by drying.
【0019】なお、本発明の板状再生建築材料の製造方
法は、半乾式成形方法に限定されるものではなく、例え
ば無機質系建築材料廃材粉砕物、結合剤及び補強繊維に
水を多量に添加してペースト状とし、このペーストを加
圧脱水成形する方法や、更に多量の水を配合してスラリ
ー状態とし、このスラリーを湿式抄造する方法により成
形することもできる。しかし、いずれの場合にも、半乾
式成形方法に比較し、使用する水の量が多いので、水の
処理及び得られた成形体の乾燥に手間と費用が掛かる欠
点がある。The method for producing the plate-like recycled building material of the present invention is not limited to the semi-dry molding method. For example, a large amount of water is added to the pulverized waste of the inorganic building material, the binder and the reinforcing fiber. Alternatively, the paste may be formed into a paste, and the paste may be formed by pressure dehydration molding or a method in which a larger amount of water is mixed to form a slurry and the slurry is wet-paper-formed. However, in each case, compared to the semi-dry molding method, since the amount of water used is large, there is a drawback that treatment of water and drying of the obtained molded body are time-consuming and costly.
【0020】また、廃材粉砕物、結合剤及び補強繊維に
増粘剤、水等を加え、混練りした原料を押出成形方法に
より成形することもできるが、一般に建築材料として使
用する板状体建築材料は、巾910mm以上である。押
出成形方法での成形は、通常巾600mmを超えると成
形時巾方向に対する押出スピードが微妙に変化し、成形
体が蛇行したり、ひび割れするため正常な板状成形体を
得ることが困難である。It is also possible to add a thickener, water, etc. to the waste material crushed material, the binder and the reinforcing fiber, and knead the raw material to form it by an extrusion molding method. Generally, a plate-like construction used as a building material The material has a width of 910 mm or more. In the molding by the extrusion molding method, when the width exceeds 600 mm, the extrusion speed in the width direction at the time of molding slightly changes and the molded body meanders or cracks, so it is difficult to obtain a normal plate-shaped molded body. .
【0021】次に、本発明の板状複合再生建築材料は、
無機質系建築材料廃材粉砕物、結合剤及び補強繊維また
は無機質系建築材料廃材粉砕物及び結合剤よりなる芯材
の両面に面材を備えてなる構成のものである。面材とし
ては、例えばけい酸カルシウム板、抄造せっこう板、ス
レートボード、紙等を使用することができる。なお、面
材は化粧を施したものを使用することもできるが、化粧
面に擦り傷等を付けることがないように保護しながら製
造することは困難であるために、化粧する場合には通常
面材を芯材に設置した後に化粧を施すことが好ましい。Next, the plate-like composite recycled building material of the present invention is
This is a structure in which face materials are provided on both sides of a core material made of pulverized waste material of inorganic building material, binder and reinforcing fiber or pulverized waste material of inorganic building material and binder. As the face material, for example, a calcium silicate board, a papermaking gypsum board, a slate board, paper or the like can be used. It should be noted that the surface material may be used after applying makeup, but it is difficult to manufacture while protecting the makeup surface so that it does not scratch or the like. It is preferable to apply makeup after the material is placed on the core material.
【0022】本発明の板状複合再生建築材料は、所定の
形状の型枠の底部に、面材の原料混合物と接する面に予
め接着剤を塗布した面材を設置し、該面材上に、芯材を
形成する原料混合物を投入し、更に、面材の原料混合物
と接する面に予め接着剤を塗布した面材を設置し、原料
混合物を2枚の面材と共に半乾式成形することにより製
造することができる。面材と芯材となる原料混合物の接
着に用いる接着剤としては、ポリマーセメント、水ガラ
ス系接着剤、酢酸ビニル系接着剤、ウレタン系接着剤等
を用いることができ、接着剤の塗布量は、面材や芯材に
用いる材質及び接着剤の種類により異なるが、50〜2
00g/m2の割合で塗布することが好ましい。ここ
で、接着剤の塗布量が50g/m2未満であると、接着
力が発揮できず面材と芯材との剥離を生じ複合材として
の効果がなくなるために好ましくなく、また、200g
/m2を超えると、必要以上の塗布量となり接着力の更
なる向上は期待できず、コストのみが上昇するために好
ましくない。In the plate-like composite regenerated building material of the present invention, a face material having an adhesive applied in advance on the surface in contact with the raw material mixture of the face material is installed at the bottom of the mold having a predetermined shape, and the face material is placed on the face material. By adding the raw material mixture that forms the core material, and further installing the face material to which the adhesive is applied in advance on the surface of the face material that contacts the raw material mixture, the raw material mixture is semi-dry molded together with the two face materials. It can be manufactured. As the adhesive used for adhering the raw material mixture to be the face material and the core material, polymer cement, water glass adhesive, vinyl acetate adhesive, urethane adhesive, etc. can be used, and the amount of adhesive applied is , 50-2 depending on the material used for the face material and core material and the type of adhesive,
It is preferable to apply it at a rate of 00 g / m 2 . Here, if the amount of adhesive applied is less than 50 g / m 2, it is not preferable because the adhesive force cannot be exerted and the face material and the core material are peeled off to lose the effect as a composite material.
If it exceeds / m 2 , the coating amount becomes unnecessarily large and further improvement of the adhesive force cannot be expected, and only the cost increases, which is not preferable.
【0023】また、半乾式成形後、板状再生建築材料と
同様の方法により、硬化養生、乾燥を行うことにより、
本発明の板状複合再生建築材料を得ることができる。After the semi-dry molding, curing curing and drying are carried out in the same manner as in the plate-shaped recycled building material.
The plate-shaped composite recycled building material of the present invention can be obtained.
【0024】なお、本発明の板状複合再生建築材料の製
造方法は、半乾式成形方法に限定されるものではなく、
例えばせっこうボードを製造する際のように面材と面材
の間に原料混合物のペーストを投入し、ロール加圧成形
することにより成形体を得ることもできる。しかし、こ
の場合、半乾式成形方法に比較し、使用する水の量が多
いので、水の処理及び得られた成形体の乾燥に手間と費
用が掛かる欠点がある。The method for producing the plate-shaped composite recycled building material of the present invention is not limited to the semi-dry molding method.
For example, as in the case of manufacturing a gypsum board, the paste of the raw material mixture is put between the face materials and the roll pressure molding can be performed to obtain a molded body. However, in this case, compared to the semi-dry molding method, the amount of water used is large, so that there is a drawback that it takes time and money to treat the water and dry the obtained molded body.
【0025】[0025]
【実施例】以下に実施例を挙げて本発明の板状再生建築
材料及び板状複合再生建築材料を更に説明する。 実施例1 本発明の再生建築材料の原料となる無機質系建築材料廃
材粉砕物を、けい酸カルシウム板、スレートボード、窯
業系サイディング、抄造せっこう板、せっこうボードの
廃材をそれぞれ衝撃破砕機で粗砕し、次に、衝撃粉砕機
により粉砕することにより得た。得られた無機質系建築
材料廃材粉砕物の粉体特性並びに粒度を以下の表1に記
載する。EXAMPLES The plate-like recycled building material and the plate-like composite recycled building material of the present invention will be further described below with reference to examples. Example 1 A crushed material of an inorganic waste building material, which is a raw material of a recycled building material of the present invention, is subjected to a calcium silicate board, a slate board, a ceramic siding, a papermaking gypsum board, and a waste material of a gypsum board with an impact crusher. It was obtained by crushing and then crushing with an impact crusher. The powder characteristics and particle size of the obtained pulverized inorganic building material waste material are shown in Table 1 below.
【0026】[0026]
【表1】 [Table 1]
【0027】次に、結合剤として普通ポルトランドセメ
ントを用い、補強繊維として長さ13mmの耐アルカリ
ガラス繊維を使用し、表1に示す無機質系建築材料廃材
粉砕物を用いて表2に示す配合割合により、無機質系建
築材料廃材粉砕物、結合剤及び補強繊維を乾式で混合
し、更に、水を噴霧添加しながら均一に混合して半乾燥
状態の原料混合物を得た。なお、水の添加量は、無機質
系建築材料廃材粉砕物、結合剤及び補強繊維の合計量1
00重量部に対してけい酸カルシウム板廃材粉砕物の場
合には38重量部(粉砕物100重量%)、32重量部
(粉砕物70重量%)、27重量部(粉砕物27重量%)、
スレートボード廃材粉砕物の場合には29重量部(粉砕
物100重量%)、24重量部(粉砕物70重量%)、2
0重量部(粉砕物50重量%)、窯業系サイディングの場
合には45重量部(粉砕物100重量%)、34重量部
(粉砕物70重量%)、25重量部(粉砕物25重量%)、
抄造せっこう板廃材粉砕物の場合には23重量部(粉砕
物100重量%)、16重量部(粉砕物70重量%)、1
2重量部(粉砕物50重量%)、せっこうボード廃材粉砕
物の場合には25重量部(粉砕物100重量%)、21重
量部(粉砕物70重量%)、16重量部(粉砕物50重量
%)であった。得られた原料混合物を380mm×38
0mm×150mmの寸法の金型に投入し、それぞれの
配合割合の原料混合物について、成形圧力30kg/c
m2及び60kg/cm2として加圧成形し、次いで、脱
型することにより成形体を得た。得られた成形体を室温
で2週間水分が逃げないようにして養生硬化を行った。
養生硬化後、105℃にて乾燥して380mm×380
mm×厚さ約12mmの寸法の成形硬化体を得た。得ら
れた成形硬化体から巾250mm、長さ300mmの試
験片を切り出し、かさ比重及び曲げ強さ(スパン250
mm)の測定を行った。得られた結果を図1に示す。Next, ordinary Portland cement was used as the binder, 13 mm long alkali-resistant glass fibers were used as the reinforcing fibers, and the pulverized material of the inorganic building material shown in Table 1 was used. Thus, the pulverized material of waste inorganic building material, the binder and the reinforcing fiber were dry-mixed, and further uniformly mixed while spray-adding water to obtain a semi-dried raw material mixture. In addition, the amount of water added is the total amount of crushed inorganic building material waste, binder and reinforcing fiber 1
38 parts by weight (100% by weight of pulverized product), 32 parts by weight in the case of pulverized waste material of calcium silicate plate against 00 parts by weight
(Crushed material 70% by weight), 27 parts by weight (crushed material 27% by weight),
29 parts by weight (100% by weight of crushed product), 24 parts by weight (70% by weight of crushed product) in the case of slate board waste crushed products, 2
0 parts by weight (crushed product 50% by weight), in case of ceramic siding 45 parts by weight (crushed product 100% by weight), 34 parts by weight
(Crushed product 70% by weight), 25 parts by weight (crushed product 25% by weight),
23% by weight (100% by weight of pulverized material), 16% by weight (70% by weight of pulverized material) in the case of crushed waste of papermaking gypsum board, 1
2 parts by weight (crushed product 50% by weight), 25 parts by weight (crushed product 100% by weight), 21 parts by weight (crushed product 70% by weight), 16 parts by weight (crushed product 50 % By weight). The obtained raw material mixture is 380 mm x 38
It is put into a mold of 0 mm x 150 mm, and the molding pressure is 30 kg / c for each raw material mixture with each mixing ratio.
m 2 and 60 kg / cm 2 were pressure-molded and then demolded to obtain a molded body. The molded body thus obtained was cured at room temperature for 2 weeks so that water would not escape.
After curing and curing, it is dried at 105 ℃ to 380mm × 380
A molded cured product having a size of mm × thickness of about 12 mm was obtained. A test piece with a width of 250 mm and a length of 300 mm was cut out from the obtained molded and cured product, and the bulk specific gravity and bending strength (span 250
mm) was measured. The obtained results are shown in FIG.
【0028】[0028]
【表2】 [Table 2]
【0029】上述のように、半乾式成形方法で得られた
成形体のかさ比重と曲げ強さは、結合剤の添加量及び成
形圧力の増加に伴い上昇する。これらの値は、無機質系
建築材料廃材粉砕物の種類により異なるが、本実施例の
おいて、普通ポルトランドセメントを30及び50重量
%用い、成形圧力を30及び60kg/cm2とした場
合、かさ比重は0.97〜1.5、曲げ強さは11〜57
kg/cm2となった。As described above, the bulk specific gravity and bending strength of the molded product obtained by the semi-dry molding method increase with an increase in the amount of the binder added and the molding pressure. These values differ depending on the type of the pulverized material of the waste inorganic building material, but in the present example, when ordinary Portland cement was used at 30 and 50% by weight and the molding pressure was 30 and 60 kg / cm 2 , Specific gravity 0.97-1.5, bending strength 11-57
It became kg / cm 2 .
【0030】実施例2 板状複合再生建築材料の面材として、380mm×38
0mm、坪量0.2kg/m2の紙を用い、芯材との接着
面に接着剤として酢酸ビニルエマルジョンを130g/
m2の割合で塗布したものを使用し、芯材として表1に
示すけい酸カルシウム板廃材粉砕物70重量%及び普通
ポルトランドセメント30重量%を使用し、更に、水を
35重量部添加して得た半乾燥状態の原料混合物を使用
し、型枠の底部に面材を設置し、次に、面材上に原料混
合物を所定量投入し、更に、その上に面材を設置して3
0kg/cm2及び60kg/cm2の成形圧力で加圧成
形し、次いで脱型することにより成形体を得た。また、
比較のために、面材を用いず原料混合物のみを半乾式加
圧成形して成形体を得た。次いで、得られた成形体を室
温にて2週間水分が逃げないようにして養生硬化し、次
いで、105℃で乾燥して380mm×380mm×厚
さは、成形圧30kg/cm2の場合、12.6mm、6
0kg/cm2の場合11.7mmの寸法の成形硬化体を
得た。なお、面材を用いない成形硬化体の寸法は380
mm×380mm×厚さは、成形圧30kg/cm2の
場合、12.3mm、60kg/cm2の場合11.4m
mであった。得られた成形硬化体のかさ比重及び曲げ強
さの測定を行った。得られた結果を表3に示す。Example 2 As a face material for a plate-shaped composite recycled building material, 380 mm × 38
Using 0 mm and basis weight 0.2 kg / m 2 paper, vinyl acetate emulsion 130 g /
m 2 was used, and 70% by weight of the ground calcium silicate board waste material shown in Table 1 and 30% by weight of ordinary Portland cement were used as the core material, and 35 parts by weight of water was further added. Using the obtained semi-dried raw material mixture, a face material is placed on the bottom of the form, then a predetermined amount of the raw material mixture is put on the face material, and then the face material is placed on it.
0 kg / cm 2 and was pressure-molded at a molding pressure of 60 kg / cm 2, then to obtain a molded product by demolding. Also,
For comparison, only the raw material mixture was subjected to semi-dry pressure molding without using a face material to obtain a molded body. Then, the obtained molded body is cured at room temperature for 2 weeks so as to prevent moisture from escaping, and then dried at 105 ° C. to obtain 380 mm × 380 mm × thickness of 12 at a molding pressure of 30 kg / cm 2. .6 mm, 6
In the case of 0 kg / cm 2 , a molded and hardened product having a size of 11.7 mm was obtained. In addition, the dimension of the molded and cured product without using the face material is 380
mm × 380 mm × thickness when the molding pressure 30kg / cm 2, 12.3 mm in the case of 60 kg / cm 2 11.4 m
m. The bulk specific gravity and bending strength of the obtained molded and cured product were measured. Table 3 shows the obtained results.
【0031】[0031]
【表3】 [Table 3]
【0032】上記表3から明らかなように、成形圧力3
0kg/cm2で半乾式成形した場合、面材を使用しな
い成形硬化体のかさ比重は0.98g/cm3、曲げ強度
は12.2kg/cm2であるのに対し、芯材の両面に面
材として紙を設置した場合のかさ比重は0.99g/c
m3、曲げ強さは64.7kg/cm2となり、ほぼ同等
のかさ比重で曲げ強度の高い板状複合再生建築材料が得
られた。また、成形圧力60kg/cm2で半乾式成形
した場合、面材を使用しない成形硬化体のかさ比重は
1.08g/cm3、曲げ強度は20.5kg/cm2であ
るのに対し、芯材の両面に面材として紙を設置した場合
のかさ比重は1.07g/cm3、曲げ強さは93.5k
g/cm2となり、ほぼ同等のかさ比重で曲げ強度の高
い板状複合再生建築材料が得られた。As is apparent from Table 3 above, the molding pressure 3
When semi-dry molding is performed at 0 kg / cm 2 , the bulk specific gravity of the molded and cured product that does not use a face material is 0.98 g / cm 3 , and the bending strength is 12.2 kg / cm 2 , whereas both sides of the core material are Bulk specific gravity is 0.99g / c when paper is installed as the surface material.
m 3 and the bending strength were 64.7 kg / cm 2 , and a plate-like composite recycled building material having substantially the same bulk specific gravity and high bending strength was obtained. When semi-dry molding is carried out at a molding pressure of 60 kg / cm 2 , the bulk specific gravity of the molded and cured product without using the face material is 1.08 g / cm 3 and the bending strength is 20.5 kg / cm 2 , whereas the core is The bulk specific gravity is 1.07 g / cm 3 and the bending strength is 93.5 k when paper is installed as the surface material on both sides of the material.
The g / cm 2 was obtained, and a plate-like composite recycled building material having substantially the same bulk specific gravity and high bending strength was obtained.
【0033】実施例3 板状複合再生建築材料の面材として、380mm×38
0mm×厚さ6mmのけい酸カルシウム板及び380m
m×380mm、坪量0.2kg/m2の紙を用い、芯材
との結着面に接着剤として酢酸ビニルエマルジョンを1
30g/m2の割合で塗布したものを使用し、芯材とし
て表1に示すけい酸カルシウム板廃材粉砕物70重量
%、普通ポルトランドセメント30重量%並びに該粉砕
物と普通ポルトランドセメントの合計量100重量部に
対して1.0重量部の耐アルカリガラス繊維を使用し、
更に、水を35重量部添加して得た半乾式状態の原料混
合物を使用し、型枠の底部に面材を設置し、次に、原料
混合物を所定量投入し、更に、その上に面材を設置して
30kg/cm2の成形圧力で加圧成形し、次いで脱型
することにより成形体を得た。また、面材を用いず原料
混合物のみを半乾式加圧成形して成形体を得た。次い
で、得られた成形体を室温にて2週間水分が逃げないよ
うにして養生硬化し、次いで、105℃で乾燥して、面
材がけい酸カルシウム板使用の場合は380mm×38
0mm×24mm、面材が紙の場合は380mm×38
0mm×13mmの寸法の成形硬化体を得た。なお、面
材を用いない成形硬化体の寸法は380mm×380m
m×12.6mmであった。得られた成形硬化体のかさ
比重及び曲げ強さの測定を行った。得られた結果を表4
に示す。Example 3 As a face material of a plate-like composite recycled building material, 380 mm × 38
0 mm x 6 mm thick calcium silicate board and 380 m
m × 380 mm, basis weight 0.2 kg / m 2 paper, vinyl acetate emulsion 1 as an adhesive on the binding surface with the core material
Using the product coated at a rate of 30 g / m 2 , 70% by weight of a calcium silicate board waste material shown in Table 1 as a core material, 30% by weight of ordinary Portland cement, and the total amount of the pulverized product and ordinary Portland cement of 100 1.0 parts by weight of alkali-resistant glass fiber is used with respect to parts by weight,
Further, using a semi-dry raw material mixture obtained by adding 35 parts by weight of water, a face material is installed at the bottom of the mold, and then a predetermined amount of the raw material mixture is charged, and then a surface material is placed on the surface material. The material was installed, pressure molding was performed at a molding pressure of 30 kg / cm 2 , and then the mold was removed to obtain a molded body. Also, only the raw material mixture was subjected to semi-dry pressure molding without using a face material to obtain a molded body. Then, the obtained molded body is cured at room temperature for 2 weeks so as to prevent moisture from escaping, and then dried at 105 ° C., and when the surface material is a calcium silicate plate, it is 380 mm × 38.
0 mm x 24 mm, 380 mm x 38 if the surface material is paper
A molded and cured product having a size of 0 mm × 13 mm was obtained. In addition, the dimension of the molded and cured product without using the face material is 380 mm x 380 m.
It was m × 12.6 mm. The bulk specific gravity and bending strength of the obtained molded and cured product were measured. Table 4 shows the obtained results.
Shown in
【0034】[0034]
【表4】 [Table 4]
【0035】上記表4から明らかなように、面材を使用
しない成形硬化体のかさ比重は0.99g/cm3、曲げ
強度は15.5kg/cm2であるのに対し、芯材の両面
に面材として紙を設置した場合のかさ比重は1.00g
/cm3、曲げ強さは61.6kg/cm2、面材として
けい酸カルシウム板を設置した場合のかさ比重は0.9
5g/cm3、曲げ強さは61.6kg/cm2となり、
かさ比重が小さく、曲げ強度の高い板状複合再生建築材
料が得られた。なお、無機質系建築材料廃材粉砕物を使
用した芯材の両面に面材として薄く、引っ張り強度のあ
る紙、けい酸カルシウム板等を設置することにより、高
強度で軽量な板状複合再生建築材料を得ることができ
る。As is clear from Table 4 above, the molded and cured product without using the face material has a bulk specific gravity of 0.99 g / cm 3 and a bending strength of 15.5 kg / cm 2 , while the core material has both sides. Bulk specific gravity is 1.00g when paper is installed as the surface material
/ Cm 3 , bending strength is 61.6 kg / cm 2 , and the bulk specific gravity is 0.9 when a calcium silicate plate is installed as a face material.
5g / cm 3 , bending strength is 61.6kg / cm 2 ,
A plate-like composite recycled building material with a low bulk specific gravity and high bending strength was obtained. In addition, by installing thin, tensile strength paper, calcium silicate board, etc. as face material on both sides of the core material using crushed waste of inorganic building materials, high strength and lightweight plate-like composite recycled building materials Can be obtained.
【0036】[0036]
【発明の効果】本発明によれば、無機質系建築材料廃材
粉砕物を原料として、軽量で、強度の高い板状再生建築
材料及び板状複合再生建築材料を提供することができ
る。According to the present invention, it is possible to provide a lightweight and high-strength plate-like recycled building material and a plate-like composite recycled building material, which are made of pulverized waste materials of inorganic building materials.
【図1】実施例1において得られた板状再生建築材料の
原料となる無機質系建築材料廃材粉砕物の種類及び配合
割合と、得られた成形硬化体のかさ比重及び曲げ強さの
関係を示すものである。FIG. 1 shows the relationship between the type and blending ratio of pulverized pulverized inorganic building material, which is a raw material for the plate-like recycled building material obtained in Example 1, and the bulk specific gravity and bending strength of the obtained molded cured product. It is shown.
Claims (5)
重量%及び結合剤10〜80重量%よりなる配合物10
0重量部に対して補強繊維を5重量部以下の量で含有し
てなる原料配合物を成形することにより得られた板状再
生建築材料。1. A crushed product of waste inorganic building materials 20 to 90
Formulation 10 consisting of 10% by weight and 10-80% by weight of binder
A plate-like recycled building material obtained by molding a raw material mixture containing 0 part by weight of reinforcing fibers in an amount of 5 parts by weight or less.
重量%及び結合剤10〜80重量%より構成される芯材
と、該芯材の両面に接着された抄造せっこう板、スレー
トボード、けい酸カルシウム板及び紙からなる群から選
択された面材を備えてなる板状複合再生建築材料。2. Ground waste material of inorganic building material 20 to 90
%, And 10-80% by weight of a binder, and a face material selected from the group consisting of papermaking gypsum board, slate board, calcium silicate board and paper adhered to both sides of the core material. A plate-shaped composite recycled building material comprising.
重量%及び結合剤10〜80重量%よりなる配合物と、
該配合物100重量部に対して5重量部以下の量の補強
繊維より構成される芯材と、該芯材の両面に接着された
抄造せっこう板、スレートボード、けい酸カルシウム板
及び紙からなる群から選択された面材を備えてなる板状
複合再生建築材料。3. Ground waste material 20-90 of inorganic building material
A formulation consisting of 10% by weight and 10 to 80% by weight of a binder,
From a core material composed of reinforcing fibers in an amount of 5 parts by weight or less with respect to 100 parts by weight of the mixture, and a papermaking gypsum board, a slate board, a calcium silicate board and paper adhered to both surfaces of the core material. A plate-like composite recycled building material comprising a face material selected from the group consisting of:
製造方法において、所定の形状の型枠の底部に、予め原
料混合物と接する面に接着剤を塗布してある面材を設置
し、該型枠の面材上に、無機質系建築材料廃材粉砕物2
0〜90重量%及び結合剤10〜80重量%よりなる原
料配合物に、該原料配合物100重量部に対して5〜1
00重量部の水を添加して半乾燥状態とした原料混合物
を投入し、次に、該原料混合物上に、予め原料混合物と
接する面に接着剤を塗布してある面材を設置し、所定の
成形圧力にて加圧成形し、脱型、養生硬化、乾燥するこ
とを特徴とする板状複合再生建築材料の製造方法。4. The method for manufacturing a plate-like composite recycled building material according to claim 2, wherein a face material having an adhesive applied to the surface in contact with the raw material mixture is installed at the bottom of the mold having a predetermined shape. , Crushed material of waste inorganic building materials on the surface material of the mold 2
0 to 90% by weight and 10 to 80% by weight of binder in a raw material mixture, and 5-1 to 100 parts by weight of the raw material mixture.
A raw material mixture, which is made semi-dried by adding 00 parts by weight of water, is introduced, and then a face material having an adhesive applied to the surface in contact with the raw material mixture in advance is placed on the raw material mixture. A method for producing a plate-shaped composite regenerated building material, which comprises press-molding at a molding pressure of, demolding, curing and drying.
製造方法において、所定の形状の型枠の底部に、予め原
料混合物と接する面に接着剤を塗布してある面材を設置
し、該型枠の面材上に、無機質系建築材料廃材粉砕物2
0〜90重量%及び結合剤10〜80重量%よりなる配
合物に、該配合物100重量部に対して5重量部以下の
量の補強繊維よりなる原料配合物に、該原料配合物10
0重量部に対して5〜100重量部の水を添加して半乾
燥状態とした原料混合物を投入し、次に、該原料混合物
上に、予め原料混合物と接する面に接着剤を塗布してあ
る面材を設置し、所定の成形圧力にて加圧成形し、脱
型、養生硬化、乾燥することを特徴とする板状複合再生
建築材料の製造方法。5. The method for manufacturing a plate-like composite recycled building material according to claim 3, wherein a face material having an adhesive applied to the surface in contact with the raw material mixture is provided at the bottom of the mold having a predetermined shape. , Crushed material of waste inorganic building materials on the surface material of the mold 2
0 to 90% by weight and 10 to 80% by weight of a binder, to 100% by weight of the composition, to 5% by weight or less of a reinforcing fiber in a raw material mixture,
5 to 100 parts by weight of water is added to 0 parts by weight of the raw material mixture, and the mixture is put in a semi-dried state. Then, an adhesive is applied onto the surface of the raw material mixture in advance in contact with the raw material mixture. A method for producing a plate-shaped composite recycled building material, which comprises placing a face material, press-molding it at a predetermined molding pressure, demolding, curing and drying.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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JP20807095A JP3753388B2 (en) | 1995-08-15 | 1995-08-15 | Method for manufacturing plate-shaped composite recycled building material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP20807095A JP3753388B2 (en) | 1995-08-15 | 1995-08-15 | Method for manufacturing plate-shaped composite recycled building material |
Publications (2)
Publication Number | Publication Date |
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JPH0952751A true JPH0952751A (en) | 1997-02-25 |
JP3753388B2 JP3753388B2 (en) | 2006-03-08 |
Family
ID=16550154
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JP20807095A Expired - Fee Related JP3753388B2 (en) | 1995-08-15 | 1995-08-15 | Method for manufacturing plate-shaped composite recycled building material |
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JP (1) | JP3753388B2 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09132447A (en) * | 1995-11-02 | 1997-05-20 | Daiko Bussan Kk | Treatment for reusing building waste material |
JP2001048630A (en) * | 1999-06-02 | 2001-02-20 | Asano Slate Co Ltd | Inorganic bearing face material and its production |
JP2001226156A (en) * | 1999-12-08 | 2001-08-21 | Sekisui Chem Co Ltd | Inorganic powder, its manufacturing method, inorganic hardenable composition, inorganic hardened body, its manufacturing method, gypsum-base hardened body and cement-base hardened body |
JP2014133666A (en) * | 2013-01-08 | 2014-07-24 | Tokai Carbon Co Ltd | Method for manufacturing a porous carbonaceous material |
CN110218043A (en) * | 2019-05-31 | 2019-09-10 | 湖南省博一节能防水工程有限公司 | A kind of environment-friendly type utilizes the mortar and preparation method thereof of regenerated resources |
-
1995
- 1995-08-15 JP JP20807095A patent/JP3753388B2/en not_active Expired - Fee Related
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09132447A (en) * | 1995-11-02 | 1997-05-20 | Daiko Bussan Kk | Treatment for reusing building waste material |
JP2001048630A (en) * | 1999-06-02 | 2001-02-20 | Asano Slate Co Ltd | Inorganic bearing face material and its production |
JP2001226156A (en) * | 1999-12-08 | 2001-08-21 | Sekisui Chem Co Ltd | Inorganic powder, its manufacturing method, inorganic hardenable composition, inorganic hardened body, its manufacturing method, gypsum-base hardened body and cement-base hardened body |
JP2014133666A (en) * | 2013-01-08 | 2014-07-24 | Tokai Carbon Co Ltd | Method for manufacturing a porous carbonaceous material |
CN110218043A (en) * | 2019-05-31 | 2019-09-10 | 湖南省博一节能防水工程有限公司 | A kind of environment-friendly type utilizes the mortar and preparation method thereof of regenerated resources |
Also Published As
Publication number | Publication date |
---|---|
JP3753388B2 (en) | 2006-03-08 |
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