JPH09315843A - Composition for building exterior body - Google Patents

Composition for building exterior body

Info

Publication number
JPH09315843A
JPH09315843A JP13453196A JP13453196A JPH09315843A JP H09315843 A JPH09315843 A JP H09315843A JP 13453196 A JP13453196 A JP 13453196A JP 13453196 A JP13453196 A JP 13453196A JP H09315843 A JPH09315843 A JP H09315843A
Authority
JP
Japan
Prior art keywords
exterior body
building exterior
composition
fly ash
balloon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP13453196A
Other languages
Japanese (ja)
Inventor
Kazuyuki Komatsu
和幸 小松
Onori Fujita
大典 藤田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kubota Corp
Original Assignee
Kubota Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kubota Corp filed Critical Kubota Corp
Priority to JP13453196A priority Critical patent/JPH09315843A/en
Publication of JPH09315843A publication Critical patent/JPH09315843A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/08Flue dust, i.e. fly ash
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a composition capable of forming a building exterior body low in specific gravity and water absorption, excellent in strength and reduced in a production cost by using a cement, in which a fibrous material is incorporated as an essential raw material, and incorporating a specific lightweight aggregate. SOLUTION: The cement, in which the fibrous material (e.g. pulp fiber) is incorporated, is used as the essential raw material and 10-20wt.% fly as balloon is preferably incorporated as the lightweight aggregate. Since the fly ash balloon has high compression strength of >=10MPa compared to the conventional aggregate (e.g. perlite) and the 10MPa pressurization is applied to the molding of the building exterior body, the exterior body provided with a sufficient mechanical strength is obtained. Since the fly ash balloon contains 60% SiO2 , it causes the Pozzolan reaction with Ca(OH)2 liberated from C3 S (basic composition of A-lite) or C2 S (basic composition of B-lite) or C3 S2 H3 (afwilite) as the reaction product, thus the structure of the exterior body is densified.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、繊維材を混入した
セメントを主原料とすると共に、軽量骨材を含む屋根材
や壁材などの建物外装体用組成物に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a composition for a building exterior such as a roofing material or a wall material containing a lightweight aggregate as a main raw material and a cement mixed with a fiber material.

【0002】[0002]

【従来の技術】従来、この種の建物外装体用組成物の知
られた例では、前記軽量骨材としてパーライト、シラス
バルーン、蛭石、頁岩などが用いられていた。
2. Description of the Related Art Conventionally, in known examples of this type of building exterior composition, perlite, shirasu balloon, vermiculite, shale, etc. have been used as the lightweight aggregate.

【0003】[0003]

【発明が解決しようとする課題】ところが、上述した従
来例による建物外装体用組成物から得られる建物外装体
は、その含まれる軽量骨材の性状に起因して、比重が充
分に低下できていなかったり、或いは、吸水率が高い
(特に寒冷地では、吸水率が高すぎると建物外装体は凍
害を受けて損傷する)という欠点が見られた(これら従
来例で用いられている軽量骨材を、一般的な建物外装体
用組成物に各10%ずつ配合した場合に得られる建物外
装体の比重と吸水率とを、各軽量骨材別に示した表1を
参照)。すなわち、骨材として低比重であることと、吸
水率が低いということとは、概して相反する性質である
ため、これら従来例で用いられている軽量骨材は、比重
を下げて建物外装体を軽量化する効果は高いが、同時に
吸水率が高くなって耐久性に問題があったり(パーライ
ト、シラスバルーン、蛭石)、一方、吸水率を低く維持
することは出来るが、比重を下げて建物外装体を軽量化
する効果が低い(頁岩)という具合に、いずれも、建物
外装体を軽量化する効果と、低い吸水率を確保する能力
とが両立しない。本発明の目的は、上に例示した従来構
成の建物外装体用組成物に見られる上記欠点に鑑み、充
分に軽量化された、しかも、吸水率も充分に低い建物外
装体を与えることの可能な建物外装体用組成物を提供す
ることにある。
However, in the building exterior body obtained from the above-described conventional composition for building exterior body, the specific gravity can be sufficiently reduced due to the properties of the lightweight aggregate contained therein. Or there is a defect that the water absorption rate is high (especially in cold regions, if the water absorption rate is too high, the building exterior is damaged by frost damage and damaged) (the lightweight aggregate used in these conventional examples. (See Table 1 for each lightweight aggregate, showing the specific gravity and water absorption of the building exterior obtained when 10% of each is added to a general composition for building exterior). That is, since the low specific gravity as an aggregate and the low water absorption rate are properties that are generally contradictory to each other, the lightweight aggregates used in these conventional examples have a reduced specific gravity to form a building exterior body. Although the effect of weight reduction is high, at the same time there is a problem with durability due to high water absorption rate (perlite, shirasu balloon, vermiculite). On the other hand, it is possible to keep the water absorption rate low, but lower the specific gravity In both cases, the effect of reducing the weight of the exterior body is low (shale), and thus neither the effect of reducing the weight of the exterior body of the building nor the ability to secure a low water absorption rate are compatible with each other. The object of the present invention is to provide a building exterior body that is sufficiently lightweight and has a sufficiently low water absorption rate in view of the above drawbacks found in the above-described conventional composition for building exterior body. Another object of the present invention is to provide a composition for a building exterior body.

【0004】[0004]

【課題を解決するための手段】上記目的を達成するため
に、本発明に係る建物外装体用組成物では、前記軽量骨
材としてフライアッシュバルーンを配合してあることを
特徴構成としている。
In order to achieve the above object, the composition for a building exterior according to the present invention is characterized in that fly ash balloons are blended as the lightweight aggregate.

【0005】〔発明の効果〕上記の特徴構成のために、
本発明に係る建物外装体用組成物では、低比重であるこ
とと、吸水率が低いということとは、相反する性質とい
う骨材の通例に反して、低比重、低吸水率という二つの
相反する性質を併せ持つフライアッシュバルーンを用い
ているので、同様に表1に示されたような、充分に軽量
化された、しかも、吸水率も充分に低い建物外装体を与
えることが出来るという独特の効果が得られた。また、
フライアッシュバルーンの圧縮強度は10MPa以上
と、上記従来例で用いられていた軽量骨材(これらの圧
縮強度は約2.7〜7MPa)に比べて高いため、建物
外装体の成型工程でプレス成型を用いる場合のプレス圧
として、10MPaを越える圧力を採用できるので、充
分な機械的強度を備えた建物外装体が得られるという効
果も得られた。さらに、フライアッシュバルーンはSi
2 成分を約60%含むので、建物外装体用組成物に含
まれるセメントが水和反応する時に、フライアッシュバ
ルーン中の前記SiO2 成分が、C3 S(エーライトの
基本組成)やC2 S(ビーライトの基本組成)から遊離
したCa(OH)2 、或いは反応生成物としてのC3
2 3 (アフィライト)とポゾラン反応を起こし、建物
外装体の組織がより緻密になるという効果も得られた。
尚、前記フライアッシュバルーンの含有量を10〜20
重量%の範囲とすれば、建物外装体としての強度が充分
で、且つ、製造コストも比較的低い建物外装体用組成物
が得られ、更に好都合である。
[Advantages of the Invention] Due to the above-mentioned characteristic configuration,
The composition for a building exterior body according to the present invention has a low specific gravity.
The fact that the water absorption is low is a conflicting property.
Contrary to the custom of carcass aggregate, it has two characteristics: low specific gravity and low water absorption.
Using a fly ash balloon that also has conflicting properties
Therefore, it is also light enough as shown in Table 1.
The exterior of the building that has
The unique effect of being able to obtain is obtained. Also,
The compressive strength of fly ash balloon is 10 MPa or more
And the lightweight aggregates used in the above-mentioned conventional
The compressive strength is higher than about 2.7-7 MPa)
Pressing pressure when using press molding in the exterior body molding process
As a pressure higher than 10 MPa can be adopted,
The effect that a building exterior body with sufficient mechanical strength can be obtained
The fruit was also obtained. Furthermore, the fly ash balloon is made of Si
OTwoSince it contains about 60% of the component, it is included in the composition for building exterior.
When the cement to be hydrated undergoes a hydration reaction, fly ash bar
Said SiO in the runesTwoIngredient is CThreeS (of Alite
Basic composition) and CTwoFree from S (the basic composition of Belite)
Ca (OH)Two, Or C as a reaction productThreeS
TwoHThree(Affilites) and pozzolanic reaction, building
It was also possible to obtain the effect of making the structure of the outer package more dense.
The content of the fly ash balloon is 10 to 20.
If it is in the weight% range, the strength as a building exterior is sufficient.
And composition for building exteriors, which is relatively low in manufacturing cost
Is obtained, which is more convenient.

【0006】[0006]

【表1】 [Table 1]

【0007】[0007]

【発明の実施の形態】図1は、本発明の建物外装体の一
例としての屋根材150を製造する装置の概略を示す。
スラリー100は、先ず湿式抄造装置1で抄造され、成
型装置2にて成型され、自然養生後、オートクレーブ3
で更に高温高圧蒸気養生されて完成された製品としての
屋根材150となる。スラリー100は、図1に記され
ているように、珪砂、マイカ、セメント、パルプ繊維、
及びフライアッシュバルーンからなる固形部と、水とか
らなる。湿式抄造装置1は、バット12、バット12内
に回転可能に納められた丸網シリンダ14、フェルト製
のコンベアベルト10、吸引脱水機構16、及び回転可
能に設けられたメーキングロール20を備えている。成
型装置2は、主にプレス200からなる。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS FIG. 1 schematically shows an apparatus for manufacturing a roofing material 150 as an example of a building exterior body of the present invention.
The slurry 100 is first made into a paper by the wet paper making device 1, formed by the forming device 2, and after natural curing, the autoclave 3
Then, the roofing material 150 is obtained as a finished product that is further cured by high-temperature and high-pressure steam. The slurry 100 includes silica sand, mica, cement, pulp fibers, as shown in FIG.
And a solid part consisting of fly ash balloons and water. The wet papermaking apparatus 1 is provided with a vat 12, a cylinder cylinder 14 rotatably housed in the vat 12, a conveyor belt 10 made of felt, a suction dewatering mechanism 16, and a rotatably making roll 20. . The molding device 2 mainly comprises a press 200.

【0008】予め調整され、良く混合、脱気されたスラ
リー100は、バット12に導入され、図1で反時計回
りに回転する丸網シリンダ14の外周面によって膜状に
抄上げられた後、そのまま、丸網シリンダ14の周速度
と略等しい速度で移動しているコンベアベルト10に転
位され、前記転位されたスラリー100は、コンベアベ
ルト10上に形成された連続帯状の種膜110となる。
種膜110は、吸引脱水機構16によって適宜脱水され
た後、メーキングロール20によって所定の厚みを獲得
するまで巻回、積層された後、ワイヤーによって切開さ
れて、平らに延ばされ、更に適当な長さに切断された単
位被成型体130となる。単位被成型体130は、成型
装置2のプレス200によって10MPaを越える圧力
で圧縮成型され、所定の形状と密度を獲得した成型体1
40となる。成型体140は、約一日間の自然養生の
後、オートクレーブ3に収納される。オートクレーブ3
を、150〜180℃の温度条件下に8〜20時間保持
することにより、オートクレーブ3内部で高温高圧蒸気
に晒された成型体140は、配合中のセメントの水和反
応が急速に進み、低い収縮率で高密度、高強度の建物外
装体用組成物の一例としての屋根材150が得られる。
The slurry 100, which has been preliminarily adjusted, well mixed and degassed, is introduced into the vat 12, and after being made into a film by the outer peripheral surface of the cylinder cylinder 14 rotating counterclockwise in FIG. As it is, it is transferred to the conveyor belt 10 moving at a speed substantially equal to the peripheral speed of the round net cylinder 14, and the transferred slurry 100 becomes a continuous strip-shaped seed film 110 formed on the conveyor belt 10.
The seed film 110 is appropriately dehydrated by the suction dehydration mechanism 16, and then wound and laminated by the making roll 20 until a predetermined thickness is obtained, and then cut by a wire and flattened, and further suitable. The unit molded body 130 is cut into lengths. The unit molded body 130 is compression-molded by the press 200 of the molding apparatus 2 at a pressure exceeding 10 MPa to obtain a predetermined shape and density.
It will be 40. The molded body 140 is stored in the autoclave 3 after being naturally cured for about one day. Autoclave 3
Is maintained at a temperature condition of 150 to 180 ° C. for 8 to 20 hours, the molded body 140 exposed to the high temperature and high pressure steam inside the autoclave 3 has a low hydration reaction of the cement being compounded rapidly. A roofing material 150, which is an example of a building exterior body composition having a high shrinkage and a high density, can be obtained.

【0009】さらに、本発明に係る建物外装体用組成物
を用いた屋根材150では、フライアッシュバルーンが
用いられていることに起因して、オートクレーブ3内に
おける前記高温高圧蒸気養生において、フライアッシュ
バルーンを構成するSiO2成分が、C3 S(エーライ
トの基本組成)やC2 S(ビーライトの基本組成)から
遊離したCa(OH)2 、或いは反応生成物としてのC
3 2 3 (アフィライト)とポゾラン反応を起こし、
屋根材150の組織がより緻密になる。
Further, in the roofing material 150 using the composition for a building exterior according to the present invention, fly ash is used in the high temperature and high pressure steam curing in the autoclave 3 due to the fact that the fly ash balloon is used. The SiO 2 component forming the balloon is Ca (OH) 2 liberated from C 3 S (basic composition of alite) or C 2 S (basic composition of belite), or C as a reaction product.
Pozzolanic reaction with 3 S 2 H 3 (affylite),
The structure of the roofing material 150 becomes finer.

【0010】〔別実施形態〕 〈1〉上述した実施形態に示したような、スラリー10
0を湿式抄造装置1によって抄造する工程の代わりに、
同様のスラリー100’をフローオン方式によって一層
状、或いは多層状に形成しても良い。前記一層状に形成
する場合を例にとって、この別実施形態による製法に必
要な設備の例を図2に示す。図2で、図1と類似の方法
で調整されたスラリー100’は、ヘッドタンク30に
一旦貯蔵され、そこから流量計32と流量調整弁34の
制御下でフローボックス36に供給される。フローボッ
クス36の下部には矩形の排出口が設けられており、こ
の排出口から一定量で排出されるスラリー100’は紙
面右側に進行するフェルト製のベルトコンベアー38に
よって前記右方に搬送されることで左右に長く延びた薄
い連続体110’となる。連続体110’は、ベルトコ
ンベアー38の下部に設けられた吸引脱水機構16’に
よって所定レベルまで脱水された後、ベルトコンベアー
38の上方に設けられたプレスロール40によって更に
絞られて脱水されると同時に所定の寸法に厚みを調整さ
れた連続体112となる。次に連続体112はカッター
機構50によって適宜切断されて、複数の所定長さの単
位被成形体114とされた後、成型装置200によって
プレス成型されて、成型体140’が得られる。以降の
工程は図1と同様で、自然養生と、オートクレーブ3に
よる高温高圧蒸気養生の後、屋根材150’が得られ
る。 〈2〉本発明に係る建物外装体用組成物は、繊維の量、
スラリー濃度、成型体の形状等を適宜調節することによ
って、壁材としても適用可能である。
[Another Embodiment] <1> The slurry 10 as shown in the above-described embodiment.
0 in place of the step of papermaking by the wet papermaking apparatus 1,
The same slurry 100 ′ may be formed in a single layer or multiple layers by the flow-on method. FIG. 2 shows an example of the equipment required for the manufacturing method according to this another embodiment, taking the case of forming the layer as one example. In FIG. 2, the slurry 100 ′ prepared in the same manner as in FIG. 1 is once stored in the head tank 30 and then supplied to the flow box 36 under the control of the flow meter 32 and the flow rate adjusting valve 34. A rectangular discharge port is provided in the lower part of the flow box 36, and the slurry 100 ′ discharged from the discharge port in a constant amount is conveyed to the right by a belt conveyor 38 made of felt which advances to the right side of the drawing. As a result, a thin continuous body 110 'that extends long right and left is formed. When the continuous body 110 ′ is dehydrated to a predetermined level by the suction dehydration mechanism 16 ′ provided on the lower part of the belt conveyor 38, it is further squeezed by the press roll 40 provided on the upper part of the belt conveyor 38 to be dehydrated. At the same time, it becomes a continuous body 112 whose thickness is adjusted to a predetermined dimension. Next, the continuous body 112 is appropriately cut by the cutter mechanism 50 into a plurality of unit molded bodies 114 having a predetermined length, and then press-molded by the molding apparatus 200 to obtain a molded body 140 ′. The subsequent steps are the same as those in FIG. 1, and after the natural curing and the high temperature and high pressure steam curing by the autoclave 3, the roofing material 150 ′ is obtained. <2> The composition for a building exterior body according to the present invention comprises the amount of fibers,
It can be applied as a wall material by appropriately adjusting the slurry concentration, the shape of the molded body, and the like.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明に係る屋根材製造装置の概略図FIG. 1 is a schematic view of a roof material manufacturing apparatus according to the present invention.

【図2】図1の別実施形態の概略図FIG. 2 is a schematic view of another embodiment of FIG.

【符号の説明】[Explanation of symbols]

10 コンベアベルト 12 バット 14 丸網シリンダ 20 メーキングロール 100 スラリー 110 種膜 150 屋根材 10 Conveyor Belt 12 Bat 14 Circular Cylinder 20 Making Roll 100 Slurry 110 Seed Membrane 150 Roofing Material

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 繊維材を混入したセメントを主原料とす
ると共に、軽量骨材を含む建物外装体用組成物であっ
て、 前記軽量骨材としてフライアッシュバルーンを配合して
ある建物外装体用組成物。
1. A composition for a building exterior body, which is mainly composed of cement mixed with a fibrous material and which also contains a lightweight aggregate, for a building exterior body containing fly ash balloons as the lightweight aggregate. Composition.
【請求項2】 前記フライアッシュバルーンの含有量が
10〜20重量%の範囲である請求項1に記載の建物外
装体用組成物。
2. The composition for a building exterior body according to claim 1, wherein the content of the fly ash balloon is in the range of 10 to 20% by weight.
JP13453196A 1996-05-29 1996-05-29 Composition for building exterior body Pending JPH09315843A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13453196A JPH09315843A (en) 1996-05-29 1996-05-29 Composition for building exterior body

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13453196A JPH09315843A (en) 1996-05-29 1996-05-29 Composition for building exterior body

Publications (1)

Publication Number Publication Date
JPH09315843A true JPH09315843A (en) 1997-12-09

Family

ID=15130506

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13453196A Pending JPH09315843A (en) 1996-05-29 1996-05-29 Composition for building exterior body

Country Status (1)

Country Link
JP (1) JPH09315843A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005263579A (en) * 2004-03-19 2005-09-29 Misawa Homes Co Ltd Concrete material, concrete member and method for manufacturing the same
JP2012091945A (en) * 2010-10-25 2012-05-17 Misawa Homes Co Ltd Calcium silicate hydrate-based building material
JP2014125420A (en) * 2012-12-27 2014-07-07 Hokuriku Electric Power Co Inc:The Mortar or concrete composition and molding of the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005263579A (en) * 2004-03-19 2005-09-29 Misawa Homes Co Ltd Concrete material, concrete member and method for manufacturing the same
JP2012091945A (en) * 2010-10-25 2012-05-17 Misawa Homes Co Ltd Calcium silicate hydrate-based building material
JP2014125420A (en) * 2012-12-27 2014-07-07 Hokuriku Electric Power Co Inc:The Mortar or concrete composition and molding of the same

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