JPH09263759A - Grout for ground solidification - Google Patents

Grout for ground solidification

Info

Publication number
JPH09263759A
JPH09263759A JP9737496A JP9737496A JPH09263759A JP H09263759 A JPH09263759 A JP H09263759A JP 9737496 A JP9737496 A JP 9737496A JP 9737496 A JP9737496 A JP 9737496A JP H09263759 A JPH09263759 A JP H09263759A
Authority
JP
Japan
Prior art keywords
slag
alkali metal
water glass
grout
ground
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9737496A
Other languages
Japanese (ja)
Inventor
Kenji Kashiwabara
健二 栢原
Motomu Miwa
求 三輪
Takashi Nagoshi
崇 名越
Takashi Tabata
隆司 田畑
Kiyouji Wada
況巳 和田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kyokado Engineering Co Ltd
Adeka Corp
Fuji Chemical Co Ltd
Original Assignee
Kyokado Engineering Co Ltd
Fuji Chemical Co Ltd
Asahi Denka Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kyokado Engineering Co Ltd, Fuji Chemical Co Ltd, Asahi Denka Kogyo KK filed Critical Kyokado Engineering Co Ltd
Priority to JP9737496A priority Critical patent/JPH09263759A/en
Publication of JPH09263759A publication Critical patent/JPH09263759A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00732Uses not provided for elsewhere in C04B2111/00 for soil stabilisation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/70Grouts, e.g. injection mixtures for cables for prestressed concrete
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

PROBLEM TO BE SOLVED: To obtain a grout which is based on slag and water glass, is injected into a ground to solidify it, has a gel time easily extensible and controllable and good permeating properties, and gels without fail even at low temps. into a solid having high initial strengths and an excellent durability. SOLUTION: This grout contains slag, water glass, and an alkali metal aluminate as the gell time adjusting agent. If necessary, the grout further contains an alkali metal carbonate in addition to an alkali metal aluminate as the get time adjusting agent.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は地盤中に注入して該
地盤を固結するスラグ−水ガラス系グラウト材に係り、
特に、ゲル化時間を長く、かつ、容易に調整し得るのみ
ならず、浸透性が良く、しかも、低温でも確実にゲル化
して初期強度も大きく、耐久性にも優れた地盤固結用グ
ラウト材に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a slag-water glass-based grout material which is poured into the ground to consolidate the ground,
In particular, not only can the gelation time be long and can be easily adjusted, but it also has good penetrability, and it reliably gels even at low temperatures, has a large initial strength, and has excellent durability. Regarding

【0002】[0002]

【従来の技術】地盤中に注入して該地盤を固結するグラ
ウト材として、従来、セメント−水ガラス系グラウトが
知られているが、このグラウト材は硬化時間をあまり長
くすることができず、たとえできたとしても強度が小さ
くなって実用上問題となることが多かった。
2. Description of the Related Art Conventionally, a cement-water glass grout is known as a grout material which is poured into the ground to consolidate the ground, but this grout material cannot cure for a long time. However, even if it could be done, the strength was often reduced and there were many problems in practical use.

【0003】また、スラグと水ガラスからなるグラウト
材も知られているが、これはスラグからのカルシウムの
溶出が液温に大きく左右されるため、ゲル化時間の調整
が困難であった。特に、冬季では使用する水温が低いた
め、ゲル化を確実に行うことが困難であった。
Further, a grout material composed of slag and water glass is also known, but it is difficult to adjust the gelation time because the elution of calcium from the slag is greatly influenced by the liquid temperature. Especially in winter, the temperature of the water used was low, and it was difficult to ensure gelation.

【0004】そこで、上述のスラグ−水ガラス系グラウ
ト材にゲル化促進剤として消石灰、セメント等を添加す
ることも試みられているが、ゲル化時間が短くなり過ぎ
たり、ゲル化強度が小さくなったり等の問題を引き起
し、充分な目的を達成するには至らなかった。
Therefore, it has been attempted to add slaked lime, cement or the like as a gelation accelerator to the above slag-water glass grout material, but the gelation time becomes too short or the gelling strength becomes small. It caused problems such as sickness and did not reach the full purpose.

【0005】[0005]

【発明が解決しようとする課題】一般に、グラウト材は
ゲル化時間が長過ぎたり、確実にゲル化しない場合に
は、地盤注入の後、注入領域から逸脱してしまう。した
がって、地盤の状況および注入目的に応じてゲル化時間
を調整し得るグラウト材が望まれている。
Generally, when the gelling time of the grout material is too long or the gelling does not occur reliably, the grout material deviates from the injection area after the ground injection. Therefore, there is a demand for a grout material capable of adjusting the gelation time depending on the condition of the ground and the purpose of injection.

【0006】特に、超微粒子スラグを用いたグラウトは
浸透性を重視しており、ゲル化時間を長く調整し得るこ
とが必要であった。このため、スラグ−水ガラス系グラ
ウト材として、特に、ゲル化時間の調整が容易であり、
かつ、ゲル化時間を長くしても確実にゲル化するグラウ
ト材の出現が望まれていた。
Particularly, the grout using the ultrafine particle slag attaches great importance to the permeability, and it was necessary to adjust the gelation time for a long time. Therefore, as the slag-water glass-based grout material, it is particularly easy to adjust the gelling time,
Moreover, it has been desired to develop a grout material that surely gels even if the gelation time is extended.

【0007】本発明者等はスラグ−水ガラス系グラウト
材において、アルミン酸アルカリ金属塩がゲル化時間調
整剤として働くことを見いだし、すなわち、液温の高い
場合には遅延剤として働き、液温が低い場合には促進剤
として働くことを見いだし、本発明を完成するに至っ
た。
The present inventors have found that in the slag-water glass grout material, the alkali metal aluminate acts as a gelling time adjusting agent, that is, it acts as a retarding agent when the liquid temperature is high, and When it was low, they found to act as an accelerator, and completed the present invention.

【0008】また、スラグ−水ガラス系グラウトは冬季
では硬化物の強度発現が遅い。この場合には、硬化物か
らアルカリが溶脱して最終強度が充分に達しない恐れも
ある。これに対して、本発明者等はスラグ−水ガラス系
グラウト材にアルミン酸アルカリ金属塩を併用すること
により、冬季でも初期強度の発現が早く、最終強度に問
題が生じないばかりでなく、掘削等の次工程がある場合
には速やかに次工程に着手し得ることを見いだし、本発
明を完成するに至った。
In the slag-water glass grout, the strength of the cured product is delayed in winter. In this case, alkali may be leached from the cured product and the final strength may not be sufficiently reached. On the other hand, the present inventors, by using the alkali metal aluminate salt in combination with the slag-water glass-based grout material, early development of early strength even in winter, not only does not cause a problem in final strength, but also excavation It was found that the next step can be promptly started when there is the next step, and the present invention has been completed.

【0009】そこで、本発明の目的はスラグ−水ガラス
系グラウト材において、ゲル化時間を長く、かつ、容易
に調整し得るのみならず、浸透性が良く、しかも低温で
も確実にゲル化して初期強度も大きく、耐久性にも優
れ、上述の公知技術に存する欠点を改良した地盤固結用
グラウト材を提供することにある。
Therefore, the object of the present invention is not only to provide a long slag-water glass grout material with a long gelation time and to be easily adjusted, but also to have a good permeability and to be surely gelled even at a low temperature. It is an object of the present invention to provide a ground-consolidating grout material that has high strength and excellent durability and has improved the above-mentioned drawbacks of the known art.

【0010】[0010]

【課題を解決するための手段】上述の目的を達成するた
め、本発明によれば、スラグと、水ガラスと、ゲル化時
間調整剤としてのアルミン酸アルカリ金属塩とを含有す
ることを特徴とする。
In order to achieve the above object, according to the present invention, slag, water glass, and an alkali metal aluminate salt as a gelling time adjusting agent are contained. To do.

【0011】[0011]

【発明の実施の形態】以下、本発明を具体的に詳述す
る。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.

【0012】本発明の特徴は上述のとおり、スラグと、
水ガラスと、アルミン酸アルカリ金属塩を含有すること
に存するが、この調製は例えば、スラグを水に懸濁させ
る際に、これにアルミン酸アルカリ金属塩を添加混合
し、得られる懸濁液と水ガラス液を混合することにより
行われ、この混合によりゲル化が起こり、地盤を固結す
る。
As described above, the features of the present invention are as follows:
Although it consists in containing water glass and an alkali metal aluminate, this preparation, for example, when suspending slag in water, by adding and mixing an alkali metal aluminate to this, a suspension obtained It is performed by mixing water glass liquid, and this mixing causes gelation and solidifies the ground.

【0013】本発明に用いられるスラグは製鉄の際に副
生する急冷高炉スラグであり、ガラス化率90%以上、塩
基度1.6以上が好ましく、これを微粉砕し、比表面積60
00cm2/g以上、好ましくは10000cm2/g以上の微粉末と
して本発明に用いられる。
The slag used in the present invention is a quenched blast furnace slag produced as a by-product during iron making, preferably having a vitrification rate of 90% or more and a basicity of 1.6 or more.
It is used in the present invention as a fine powder of 00 cm 2 / g or more, preferably 10,000 cm 2 / g or more.

【0014】また、本発明に用いられる水ガラスはSi
2 /Na2 Oが2.8以下、好ましくは1.5〜2.4のモ
ル比の水ガラスである。
The water glass used in the present invention is Si.
O 2 / Na 2 O is a water glass having a molar ratio of 2.8 or less, preferably 1.5 to 2.4.

【0015】さらに、本発明に用いられるゲル化時間調
製剤としてのアルミン酸アルカリ金属塩としては、粉末
状のアルミン酸ソーダが好ましいが、この他に液状のア
ルミン酸ソーダ、あるいはアルミン酸カリ等も使用に供
される。
Further, as the alkali metal aluminate as the gelling time adjusting agent used in the present invention, powdery sodium aluminate is preferable, but in addition to this, liquid sodium aluminate, potassium aluminate and the like are also available. Be used.

【0016】なお、本発明に用いられるゲル化時間調整
剤として上述のアルミン酸アルカリ金属塩にさらに、ア
ルカリ金属炭酸塩を併用することもでき、この併用によ
ってゲル化時間の微調整が可能となる。この種のアルカ
リ金属炭酸塩として、好ましくは重炭酸ソーダ、重炭酸
カリが挙げられ、これらに炭酸ソーダ、炭酸カリを併用
することもできる。
As the gelling time adjusting agent used in the present invention, it is also possible to use an alkali metal carbonate in combination with the above-mentioned alkali metal aluminate, and this combination enables fine adjustment of the gelling time. . As the alkali metal carbonates of this type, sodium bicarbonate and potassium bicarbonate are preferred, and sodium carbonate and potassium carbonate can be used in combination therewith.

【0017】上述の成分を含む本発明にかかるグラウト
材は調製に際して、まず、水ガラスを水で希釈してA液
を調製し、さらに、スラグを水で懸濁してB液を調製す
る。このB液を調製するときに、水の中にあらかじめア
ルミン酸アルカリ金属塩、おにび必要に応じてアルカリ
金属炭酸塩を添加しておく。この添加順序はスラグを添
加する前であっても、後であっても、いずれでも良い
が、添加の際には水を攪拌して行う方が好ましい。次い
で、前述のA液およびB液を混合して地盤に注入し、地
盤の強化、止水を図る。なお、上述A、B液に使用され
る水は通常真水であるが、海水を使用しても構わない。
In preparing the grout material according to the present invention containing the above-mentioned components, first, water glass is diluted with water to prepare a solution A, and then slag is suspended in water to prepare a solution B. When this solution B is prepared, an alkali metal aluminate salt and, if necessary, an alkali metal carbonate salt are added to water in advance. The order of addition may be either before or after the addition of slag, but it is preferable to stir water during the addition. Next, the solutions A and B are mixed and poured into the ground to strengthen the ground and stop water. The water used for the liquids A and B is usually fresh water, but seawater may be used.

【0018】水ガラスの使用量はA液中の濃度として30
(容量)%以上が好ましく、水ガラス濃度によりゲル化
時間を長くする場合には、水ガラス濃度が60〜90(容
量)%と大きい方が良いが、経済性および硬化物の耐久
性等の面から40〜60(容量)%が好ましい。
The amount of water glass used is 30 as the concentration in liquid A.
(Volume)% or more is preferable, and when the gelation time is lengthened depending on the water glass concentration, the water glass concentration is preferably as high as 60 to 90 (volume)%, but it is economical and durability of the cured product From the viewpoint, 40 to 60 (volume)% is preferable.

【0019】スラグの使用量は目的とする地盤の改良度
合いにより異なるが、B液中の濃度として18〜50(重
量)%が好ましい。また、通常A、B液は1:1(容
量)で混合するが、ゲル化時間が長い場合には上記配合
となるように1液で調製使用することもできる。
The amount of slag used varies depending on the degree of improvement of the desired ground, but the concentration in solution B is preferably 18 to 50 (weight)%. Further, the solutions A and B are usually mixed at a ratio of 1: 1 (volume), but when the gelation time is long, they can be prepared and used as a single solution so as to have the above composition.

【0020】アルミン酸アルカリ金属塩の使用量は液温
と目的とするゲル化時間により決定されるが、スラグに
対して0.2〜10.0(重量)%の範囲で使用するのが好
ましい。特に、冬季ではアルミン酸アルカリ金属塩の使
用量は2〜8(重量)%が好ましい。また、この配合に
おいて、ゲル化時間を長くしたい場合には、アルカリ金
属炭酸塩を使用するが、その使用量は0.1〜9.0(重
量)%が好ましい。
The amount of alkali metal aluminate used is determined by the liquid temperature and the desired gelling time, but it is preferably used in the range of 0.2 to 10.0 (wt)% with respect to the slag. . Particularly in winter, the amount of alkali metal aluminate used is preferably 2 to 8 (wt)%. Further, in this formulation, when it is desired to prolong the gelation time, an alkali metal carbonate is used, and the amount used is preferably 0.1 to 9.0 (wt)%.

【0021】上述の本発明グラウト材は次の作用を呈す
る。すなわち、スラグと水ガラスを混合すると、水ガラ
スのアルカリによりスラグからカルシウムが溶出して水
ガラスがゲル化する。これにアルミン酸アルカリ金属塩
を添加すると、これがカルシウムと反応するが、アルミ
ン酸アルカリ金属塩の添加量と液温により、水ガラスと
アルミン酸アルカリ金属塩との間にカルシウムとの反応
速度に差が生じるため、アルミン酸アルカリ金属塩が遅
延剤として働いたり、促進剤として働いたりするものと
思われる。
The above-described grout material of the present invention exhibits the following effects. That is, when slag and water glass are mixed, calcium is eluted from the slag by the alkali of the water glass and the water glass gels. When alkali metal aluminate salt is added to this, it reacts with calcium, but the reaction rate with calcium between water glass and alkali metal aluminate differs depending on the amount of alkali metal aluminate salt added and the liquid temperature. Therefore, it is considered that the alkali metal aluminate acts as a retarder or an accelerator.

【0022】また、アルミン酸アルカリ金属塩とカルシ
ウムが反応し、この反応により生成したカルシウムアル
ミネートがスラグと結合してスラグの硬化を促進し、こ
のため、初期強度の発現が早くなるものと思われる。
Also, it is considered that the alkali metal aluminate salt reacts with calcium, and the calcium aluminate produced by this reaction binds with the slag to accelerate the hardening of the slag, and therefore the initial strength is developed faster. Be done.

【0023】[0023]

【発明の実施例】以下、本発明を実施例により詳述す
る。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail with reference to Examples.

【0024】1.使用材料 (1)スラグ 高炉スラグを微粉砕したもので、比表面積12000cm2/g
の超微粒子スラグを用いる。
1. Materials used (1) Slag Finely crushed blast furnace slag with a specific surface area of 12000 cm 2 / g
The ultrafine particle slag of is used.

【0025】(2)水ガラス 表1に示す組成の水ガラスを使用する。(2) Water glass Water glass having the composition shown in Table 1 is used.

【0026】[0026]

【表1】 [Table 1]

【0027】(3)アルミン酸ソーダ 表2に示す組成の粉末アルミン酸ソーダを用いる。(3) Sodium aluminate A powdered sodium aluminate having the composition shown in Table 2 is used.

【0028】[0028]

【表2】 [Table 2]

【0029】2.AB混合液のゲル化時間 表3に示すA液およびB液を混合したときのゲル化時間
を測定し、結果を表3に示した。
2. Gelation time of AB mixed solution The gelation time when the solutions A and B shown in Table 3 were mixed was measured, and the results are shown in Table 3.

【0030】[0030]

【表3】 [Table 3]

【0031】また、表3の配合の中から表4に示される
代表的な例を取り出し、これらについて硬化物の水中養
生における一軸圧縮強度(kgf/cm2)を測定し、結果を表
4に示した。
Representative examples shown in Table 4 were taken out of the formulations of Table 3, and uniaxial compressive strength (kgf / cm 2 ) of the cured products in water under curing was measured. The results are shown in Table 4. Indicated.

【0032】なお、表4において、液温15℃以上でゲル
化させた硬化物は水温20℃で養生し、それ以外の硬化物
は水温10℃で養生した(以下、同じ)。また、B液は水
にスラグを添加した後にアルミン酸ソーダおよび重炭酸
ソーダを添加した。液温はA、B両液を同じにした。
In Table 4, cured products gelled at a liquid temperature of 15 ° C. or higher were aged at a water temperature of 20 ° C., and other cured products were aged at a water temperature of 10 ° C. (hereinafter the same). For solution B, slag was added to water and then sodium aluminate and sodium bicarbonate were added. The liquid temperature was the same for both liquids A and B.

【0033】[0033]

【表4】 [Table 4]

【0034】3.AB液の水として海水を用いた例 海水を用いた表5に示すA液、B液を調製し、これらA
B液を混合して得られる硬化物についてゲル化時間を測
定し、結果を表5に示した。
3. Example in which seawater is used as water for the AB liquid. A liquids and B liquids shown in Table 5 were prepared using seawater.
The gelation time of the cured product obtained by mixing the liquid B was measured, and the results are shown in Table 5.

【0035】表5のB液は海水にスラグを添加した後に
アルミン酸ソーダおよび重炭酸ソーダを添加した。ま
た、液温はA、B両液とも同じに調整した。
Solution B in Table 5 was prepared by adding slag to seawater and then adding sodium aluminate and sodium bicarbonate. The liquid temperature was adjusted to be the same for both liquids A and B.

【0036】[0036]

【表5】 [Table 5]

【0037】表5の配合について、硬化物の水中養生に
おける一軸圧縮強度(kgf/cm2)を測定し、結果を表6に
示した。
With respect to the formulations of Table 5, the uniaxial compressive strength (kgf / cm 2 ) of the cured product in water was measured, and the results are shown in Table 6.

【0038】[0038]

【表6】 [Table 6]

【0039】表3からわかるように、B液にアルミン酸
ソーダを添加することにより、低温でもゲル化は確実で
あり、また、ゲル化時間の長いところでも重炭酸ソーダ
を併用することにより、ゲル化時間を微調整することが
できる。
As can be seen from Table 3, by adding sodium aluminate to the solution B, gelation is sure at low temperature, and by using sodium bicarbonate together even at a long gelation time, gelation time can be improved. Can be fine-tuned.

【0040】また、表4から分かるように、B液にアル
ミン酸ソーダを添加することにより、初期(表4では7
日)強度は大きくなっており、さらに重炭酸ソーダを添
加しても強度に及ぼす影響は少ない。
Further, as can be seen from Table 4, by adding sodium aluminate to solution B, the initial (7 in Table 4)
(Day) Strength is high, and addition of sodium bicarbonate has little effect on strength.

【0041】さらに、表5からわかるように、A、B液
に用いる水として海水を使用した場合には、真水の場合
よりゲル化時間が長いにもかかわらず、アルミン酸ソー
ダと重炭酸ソーダによりゲル化時間を、容易に調整する
ことができる。
Furthermore, as can be seen from Table 5, when seawater is used as the water used for the liquids A and B, the gelation time increases with sodium aluminate and sodium bicarbonate despite the gelation time being longer than that of fresh water. The time can be easily adjusted.

【0042】表6からわかるように、海水を使用して得
られる硬化物は長期間強度が低下しない。
As can be seen from Table 6, the strength of the cured product obtained by using seawater does not decrease for a long period of time.

【0043】[0043]

【発明の効果】上述の本発明にかかるグラウト材は次の
効果を奏し得る。 1.B液に、スラグに加えてアルミン酸ソーダを添加す
ることにより、低温でも確実にゲル化させることができ
る。
The grout material according to the present invention described above can exhibit the following effects. 1. By adding sodium aluminate in addition to slag to the liquid B, it is possible to surely cause gelation even at a low temperature.

【0044】2.B液に、スラグに加えてアルミン酸ソ
ーダを用いることにより、あるいは必要に応じて重炭酸
ソーダを併用することにより、ゲル化時間を微調整する
ことができる。
2. The gelling time can be finely adjusted by using sodium aluminate in addition to the slag in the solution B, or by using sodium bicarbonate in combination as necessary.

【0045】3.B液に、スラグに加えてアルミン酸ソ
ーダを添加することにより、硬化物の初期強度を大きく
することができる。
3. By adding sodium aluminate in addition to the slag to the liquid B, the initial strength of the cured product can be increased.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 栢原 健二 東京都文京区本郷2丁目15番10号 強化土 エンジニヤリング株式会社内 (72)発明者 三輪 求 東京都荒川区東尾久7丁目2番35号 旭電 化工業株式会社内 (72)発明者 名越 崇 東京都荒川区東尾久7丁目2番35号 旭電 化工業株式会社内 (72)発明者 田畑 隆司 岐阜県中津川市茄子川字中垣外1683−1880 富士化学株式会社内 (72)発明者 和田 況巳 岐阜県中津川市茄子川字中垣外1683−1880 富士化学株式会社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Kenji Kasahara, 2-15-10 Hongo, Bunkyo-ku, Tokyo Within Reinforced Soil Engineering Co., Ltd. (72) Inventor Miwa, 7-35, Higashiokyu, Arakawa-ku, Tokyo Asahi Denka Kogyo Co., Ltd. (72) Inventor Takashi Nagoshi 7 2-35 Higashiohisa, Arakawa-ku, Tokyo Asahi Denka Kogyo Co., Ltd. (72) Takashi Tabata Takashi Tabata 1683-1880 Nakagaki, Nakatsugawa, Gifu Prefecture In Fuji Chemical Co., Ltd.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 スラグと、水ガラスと、ゲル化時間調整
剤としてのアルミン酸アルカリ金属塩とを含んでなる地
盤固結用グラウト材。
1. A ground-consolidating grout material containing slag, water glass, and an alkali metal aluminate salt as a gelling time adjusting agent.
【請求項2】 前記ゲル化時間調整剤としてアルミン酸
アルカリ金属塩にさらにアルカリ金属炭酸塩を併用して
なる請求項1に記載の地盤固結用グラウト材。
2. The ground-consolidating grout material according to claim 1, wherein an alkali metal aluminate and an alkali metal carbonate are further used in combination as the gelling time adjusting agent.
JP9737496A 1996-03-28 1996-03-28 Grout for ground solidification Pending JPH09263759A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9737496A JPH09263759A (en) 1996-03-28 1996-03-28 Grout for ground solidification

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9737496A JPH09263759A (en) 1996-03-28 1996-03-28 Grout for ground solidification

Publications (1)

Publication Number Publication Date
JPH09263759A true JPH09263759A (en) 1997-10-07

Family

ID=14190743

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9737496A Pending JPH09263759A (en) 1996-03-28 1996-03-28 Grout for ground solidification

Country Status (1)

Country Link
JP (1) JPH09263759A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09316449A (en) * 1996-06-03 1997-12-09 Kyokado Eng Co Ltd Chemical for grouting

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5218013A (en) * 1975-08-01 1977-02-10 Fudo Construction Co Grout agent of water glass and sodium aluminate
JPS5686984A (en) * 1979-12-17 1981-07-15 Nitto Chem Ind Co Ltd Stabilization of soil
JPH07119138A (en) * 1993-10-20 1995-05-09 Kyokado Eng Co Ltd Grout
JPH0860153A (en) * 1994-08-19 1996-03-05 Kyokado Eng Co Ltd Method for grouting
JPH0859314A (en) * 1994-08-12 1996-03-05 Kyokado Eng Co Ltd Concreting material
JPH0867876A (en) * 1994-08-27 1996-03-12 Kyokado Eng Co Ltd Chemical for injecting into ground
JPH0873850A (en) * 1994-08-31 1996-03-19 Kyokado Eng Co Ltd Water glass grout material

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5218013A (en) * 1975-08-01 1977-02-10 Fudo Construction Co Grout agent of water glass and sodium aluminate
JPS5686984A (en) * 1979-12-17 1981-07-15 Nitto Chem Ind Co Ltd Stabilization of soil
JPH07119138A (en) * 1993-10-20 1995-05-09 Kyokado Eng Co Ltd Grout
JPH0859314A (en) * 1994-08-12 1996-03-05 Kyokado Eng Co Ltd Concreting material
JPH0860153A (en) * 1994-08-19 1996-03-05 Kyokado Eng Co Ltd Method for grouting
JPH0867876A (en) * 1994-08-27 1996-03-12 Kyokado Eng Co Ltd Chemical for injecting into ground
JPH0873850A (en) * 1994-08-31 1996-03-19 Kyokado Eng Co Ltd Water glass grout material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09316449A (en) * 1996-06-03 1997-12-09 Kyokado Eng Co Ltd Chemical for grouting

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