JPH09221403A - Filler for root canal made of polyolefin - Google Patents
Filler for root canal made of polyolefinInfo
- Publication number
- JPH09221403A JPH09221403A JP8025503A JP2550396A JPH09221403A JP H09221403 A JPH09221403 A JP H09221403A JP 8025503 A JP8025503 A JP 8025503A JP 2550396 A JP2550396 A JP 2550396A JP H09221403 A JPH09221403 A JP H09221403A
- Authority
- JP
- Japan
- Prior art keywords
- root canal
- filler
- filling material
- wall
- canal filling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Dental Preparations (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は歯髄摘出(抜髄)後の歯
の根管に充填する根管充填材に関するもので、特に理化
学的に安定で、材質的に劣化が少なく長期にわたり生体
内に留置でき、根尖歯周組織に対して有害作用のない根
管充填材に関し、更に該根管充填材と根管壁の周囲に充
填するシーラーとからなる根管充填材料に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a root canal filling material for filling a root canal of a tooth after pulpectomy (extraction), which is particularly physicochemically stable and has little material deterioration and can be used in a living body for a long period of time. The present invention relates to a root canal filling material that can be placed and does not have a harmful effect on the apical periodontal tissue, and further relates to a root canal filling material including the root canal filling material and a sealer filling the periphery of the root canal wall.
【0002】[0002]
【従来の技術】う蝕は歯における細菌感染症であり、歯
垢中の細菌によって先ず歯の表面を覆っているエナメル
質が侵され、次いで、象牙質が侵される。更にう蝕が進
行すると歯髄に細菌感染が波及し、歯髄炎となる。この
歯髄炎の治療法としては、感染した歯髄を抜髄し、ここ
に根管充填材を充填する。図をもってこの状態を説明す
る。図3において、歯の表面はエナメル質1で覆われ、
このエナメル質1の下部に象牙質2がある。そして、そ
の中央部に歯髄3が存在し、その先端に根尖孔4があ
り、根尖歯周組織5につらなっている。歯髄炎の従来か
らの治療としては、感染した歯髄を抜髄し、空洞となっ
た歯の根管に針状のリーマ・ファイル6を挿入し、これ
をもって根管を適切な大きさに拡大し、ここに根管充填
材をシーラーとともに充填し、根尖孔を閉鎖する。この
処理により、口腔と根管、更には根尖歯周組織への感染
経路を遮断し根尖の治癒を計るのである。2. Description of the Related Art Dental caries is a bacterial infection in teeth, and bacteria in dental plaque first invade the enamel covering the surface of teeth and then dentin. When further caries progresses, bacterial infection spreads to the pulp, resulting in pulpitis. As a method for treating this pulpitis, the infected pulp is extracted and the root canal filling material is filled therein. This state will be described with reference to the drawings. In FIG. 3, the tooth surface is covered with enamel 1,
Below this enamel 1 is dentin 2. A pulp 3 is present at the center of the pulp, and an apical hole 4 is provided at the tip of the pulp 3 and is attached to the apical periodontal tissue 5. As a conventional treatment for pulpitis, the infected pulp is extracted and the needle-shaped reamer file 6 is inserted into the root canal of the hollowed tooth to expand the root canal to an appropriate size. The root canal filling material is filled therein with a sealer to close the apical foramen. By this treatment, the path of infection to the oral cavity, the root canal, and the apical periodontal tissue is blocked to cure the apex.
【0003】この根管充填材として具備すべき条件とし
て次のような性質が要求されている。 (1)不変性であること。収縮や腐敗分解することな
く、根尖組織に対して形態や性質に変化を起こさせない
ことが必要である。 (2)無刺激性であること。根尖部の歯周組織に有害性
のないものである。 (3)多孔性でないこと。即ち、緻密性であって、組織
液或いは細菌や毒素などの侵入を許さないことが必要で
ある。 (4)適合性を有すること。即ち、根尖孔付近まで容易
に充填でき、完全に根管及び根尖孔を閉鎖することが必
要である。 (5)密着性を有すること。根管壁に完全に接着して、
水分及び細菌などを根管に侵入さないことが必要であ
る。 (6)滅菌ができること。 (7)歯を着色させないこと (8)必要に応じて除去が可能であること (9)エックス線不透過性であること (10)組織親和性を有し、根尖部の骨性瘢痕治癒を促
進させるもの。 (11)取扱が容易であることThe following properties are required as conditions for the root canal filling material. (1) Being invariant. It is necessary that the apical tissue does not undergo changes in morphology or properties without contraction or decomposition. (2) Be non-irritating. It is not harmful to the periodontal tissues of the apex. (3) It is not porous. That is, it is necessary to be dense and not allow the invasion of tissue fluid or bacteria, toxins and the like. (4) Must be compatible. That is, it is necessary to easily fill the vicinity of the apical foramen and completely close the root canal and apical foramen. (5) It has adhesiveness. Completely adhere to the root canal wall,
It is necessary that water and bacteria do not enter the root canal. (6) Be able to sterilize. (7) Do not stain teeth (8) Can be removed as required (9) Be radiopaque (10) Have tissue affinity and heal bone scar at the apex What promotes. (11) Easy to handle
【0004】以上の要求される特性を要約すると、A)
物理的、化学的及び生物学的に安定であり、生体に無刺
激性なこと、B)緻密で多孔質でないこと、C)根尖孔
に容易に到達して根尖孔を閉鎖できるもの、D)滅菌で
きること、E)除去可能でエックス線造影性を有するこ
と、F)取扱い操作が容易であること等である。To summarize the above required characteristics, A)
Physically, chemically and biologically stable, non-irritating to living organisms, B) compact and non-porous, and C) capable of easily reaching and closing the apical foramen, D) Sterilization, E) Removable X-ray contrast, F) Easy handling.
【0005】ところで、根管充填には、糊剤と固形材が
あり、一般に固形材が多く用いられている。固形材とし
ては、主にゴム質と亜鉛からなるガッタパーチャポイン
トが用いられている。その他、銀ポイントがある。銀ポ
イントは根尖孔に密着性がなく、除去が非常に困難とい
う欠点があり、現在は殆ど使用されていない。ガッタパ
ーチャポイントは、エックス線に対して不透過性である
こと、一定の形状に作成できること等の理由によって広
く使用されている。しかし、ガッタパーチャポイントに
おいても不変性が完全なものではなく、通常の環境下で
も製品が劣化して脆くなり、生体内では異物として食作
用を受ける。更に、顕微鏡レベルでは多孔性である。ま
た医療用材料として滅菌困難なことが挙げられる。By the way, there are sizing agents and solid materials for root canal filling, and solid materials are generally used in many cases. Gutta-percha points mainly made of rubber and zinc are used as the solid material. In addition, there are silver points. The silver point has the drawback that it is not very adherent to the apical foramen and is very difficult to remove, so it is rarely used at present. The gutta-percha point is widely used because it is impermeable to X-rays and can be formed into a certain shape. However, even at the gutta-percha point, the invariance is not perfect, and the product deteriorates and becomes brittle even under normal environment, and is phagocytosed as a foreign substance in the living body. Furthermore, it is porous at the microscopic level. Further, it is difficult to sterilize as a medical material.
【0006】[0006]
【発明が解決しようとする課題】本発明者は従来使用さ
れている根管充填材より更に安定性を有し、また作業性
の良い根管充填材について種々検討した結果、本発明を
完成したもので、本発明の目的は、理化学的に安定で異
物性がなく、曲がった根管に挿入するための適度な硬さ
と弾力があり、材質的に劣化が少なく長期にわたり生体
内で留置でき、さらに滅菌が容易な根管充填剤を提供す
ることである。DISCLOSURE OF THE INVENTION The present inventors have completed the present invention as a result of various studies on a root canal filling material which is more stable than the conventionally used root canal filling material and has good workability. However, the object of the present invention is physicochemically stable, has no foreign matter, has appropriate hardness and elasticity for insertion into a curved root canal, and can be placed in a living body for a long period of time with little deterioration in material. Another object is to provide a root canal filling material that can be easily sterilized.
【0007】[0007]
【課題を解決するための手段】本発明の要旨はポリオレ
フィン樹脂による根管充填材である。即ち、ポリオレフ
ィン樹脂、特にポリプロピレン樹脂は適度な硬さと曲げ
強さを持ち、成形性が良好で根管充填材としての国際規
格にのっとった形状に成形することができ、特にアイソ
タクチック プロピレンが好ましい。The gist of the present invention is a root canal filling material made of a polyolefin resin. That is, a polyolefin resin, particularly a polypropylene resin, has appropriate hardness and bending strength, has good moldability, and can be molded into a shape that complies with international standards as a root canal filler, and isotactic propylene is particularly preferable. .
【0008】根管充填材の好ましい条件は、物理化学的
に安定で、生体に対し異物性や毒性のなく、同時に根管
内に挿入するための適度な硬さと弾力が必要である。さ
らに挿入された根管充填材は根管壁と密着性の高いこと
が要求される。以上から、本発明の根管充填材は、上記
の根管充填材の好ましい条件をほぼ満たす、物理化学的
に安定で、生体に対し異物性や毒性のなく、曲がった根
管にも挿入できるような適度な硬さと弾力を有してい
る。さらに、本発明では根管充填材と根管壁の隙間を埋
め、根管壁と密着性の高めるシーラーとして、ペースト
状で根管内で短時間のうちに硬化しするシリコーンを開
発した。The preferred conditions for the root canal filling material are that it is physicochemically stable, has no foreign substance or toxicity to the living body, and at the same time has appropriate hardness and elasticity for insertion into the root canal. Furthermore, the inserted root canal filling material is required to have high adhesion to the root canal wall. From the above, the root canal filling material of the present invention substantially satisfies the preferable conditions of the root canal filling material described above, is physicochemically stable, has no foreign substance or toxicity to the living body, and can be inserted into a curved root canal. It has such appropriate hardness and elasticity. Furthermore, in the present invention, as a sealer that fills the gap between the root canal filling material and the root canal wall and enhances the adhesion to the root canal wall, a paste-like silicone that hardens within the root canal in a short time was developed.
【0009】本発明で使用するポリオレフィンとしては
ポリエチレン、ポリプロピレンまたはエチレンもしくは
プロピレンを主成分として含有する共重合体等である
が、好ましいポリオレフィンとしてはポリプロピレンで
あり、特にアイソタクティック構造を有するポリプロピ
レンが好ましい。The polyolefin used in the present invention is polyethylene, polypropylene or a copolymer containing ethylene or propylene as a main component, and the preferred polyolefin is polypropylene, and polypropylene having an isotactic structure is particularly preferred. .
【0010】ポリオレフィンは理化学的に強力な溌水性
を有し、非吸水性、熱安定性等があり、生体内で吸収さ
れることなく結合組織で安定した状態で被包される。以
上からポリオレフィン、特にアイソタクティックポリプ
ロピレンは、物性としても高い曲げ弾性率、剛性衝撃バ
ランス向上、低線膨張率化などの重要な力学的品質を持
つ。さらにレントゲン造影剤との複合化が可能である。
更に、ポリプロピレンは、耐薬品性、滅菌時の耐熱性、
耐放射線滅菌性、などの特徴から医療用材料として適し
ている。また成形が容易であるため、根管充填材の国際
規格に合った形状のものが容易に作成することができ
る。従って、ポリプロピレンは安全で安定した高分子化
合物による根管充填材といえる。しかも、本願発明の充
填材は国際規格に合った形状のものが出来るので、充填
した時に緊密に充填できる。Polyolefin has physicochemically strong water repellent property, non-water absorbing property, heat stability, etc., and is stably encapsulated in connective tissue without being absorbed in the living body. From the above, polyolefins, particularly isotactic polypropylene, have important physical properties such as high flexural modulus, improved rigidity impact balance, and low linear expansion coefficient. Further, it can be combined with an X-ray contrast medium.
Furthermore, polypropylene has chemical resistance, heat resistance during sterilization,
It is suitable as a medical material due to its characteristics such as radiation sterilization resistance. In addition, since the molding is easy, a root canal filling material having a shape conforming to the international standard can be easily prepared. Therefore, polypropylene can be said to be a root canal filler made of a safe and stable polymer compound. Moreover, since the filler of the present invention can have a shape conforming to the international standard, it can be tightly filled when filled.
【0011】本発明にかかる根管充填材を使用するに際
しては、この根管充填材と根管壁との隙間にシーラーを
充填し、密着させることが必要である。シーラーとして
はジメチルポリシロキサンならなるシリコーン、或いは
亜鉛化ユウジノール製剤を用いる。シリコーンは通常は
重合禁止剤が加えられており、根管充填の際に硬化剤(c
atalyst)を加え、シーラーとして根管充填材とともに根
管内に充填するが、開始反応に始まり、停止反応に至る
経過をたどり、化学的に安定な不溶不融なシリコーンと
なり、根管充填材を根管壁の隙間を埋めて根管の封鎖性
を高める。また、亜鉛化ユウジノール製剤はガッタパー
チャ根管充填材のシーラーとして従来から用いられてい
るものである。When the root canal filling material according to the present invention is used, it is necessary to fill the gap between the root canal filling material and the root canal wall with a sealer and bring them into close contact. As the sealer, a silicone such as dimethylpolysiloxane or a zincated Yugenol preparation is used. A polymerization inhibitor is usually added to silicone, and a curing agent (c
Atalyst) is added and the root canal is filled as a sealer together with the root canal filling material, but the process from the initiation reaction to the termination reaction is followed to become a chemically stable insoluble and infusible silicone, and the root canal filling material is It fills the gaps in the root canal wall and enhances the root canal sealability. In addition, the zincated Yugenol preparation has been conventionally used as a sealer for a gutta-percha root canal filling material.
【0012】本発明にかかる根管充填材は従来の固形根
管充填材の場合と同様な形状を呈する。即ち、約0.3
〜1.4mmの直径を有し、約28mmの長さを有し、
適用する根管により種々選択する。そして、その先端部
は根尖孔を閉鎖しやすいように約75度の角度をもって
とがらせることが好ましい。この根管充填材は先に述べ
た根管充填材として要求される特性を有し、特に根管へ
の挿入が確実且つ容易であって、根尖部の根管壁の接着
性が高まるのである。The root canal filling material according to the present invention has the same shape as that of the conventional solid root canal filling material. That is, about 0.3
Having a diameter of ~ 1.4 mm and a length of about 28 mm,
Various selections are made depending on the applied root canal. Further, it is preferable that the tip end thereof is sharpened at an angle of about 75 degrees so that the apical hole can be easily closed. This root canal filling material has the properties required as the root canal filling material described above, and in particular, it is surely and easily inserted into the root canal, and the adhesiveness of the root canal wall of the root apex is enhanced. is there.
【0013】本発明にかかる根管充填材を図面を以って
説明する。図1は根管充填材の断面図であり、抜髄し、
拡大された根管内にシーラー8とともに根管充填材7を
挿入する。図2は根管充填材の形状を示し、この形状
は、規格化された太さと形状を有する根管拡大器、リー
マーと同一規格の形状のものである。このようなリーマ
ーと同一規格の形状のものを用いるため、ほぼ根管壁に
密着した状態で根管充填される。根管充填材と根管壁と
のわずかな隙間はシーラー8で埋められる。シーラーは
短時間で硬化し、根管壁と接着し、根管充填材とともに
固定される。A root canal filling material according to the present invention will be described with reference to the drawings. FIG. 1 is a cross-sectional view of a root canal filling material, which is extracted from
The root canal filling material 7 is inserted together with the sealer 8 into the enlarged root canal. FIG. 2 shows the shape of the root canal filling material, which has the same standard shape as the root canal expander and reamer having a standardized thickness and shape. Since the reamer having the same standard shape is used, the root canal is filled almost in close contact with the root canal wall. A slight gap between the root canal filling material and the root canal wall is filled with the sealer 8. The sealer hardens in a short time, adheres to the root canal wall and is fixed together with the root canal filling material.
【0014】[0014]
【実施例及び比較例】次に実例をもって本発明を具体的
に説明する。 実施例1 抜髄され、根尖部が0.5mmの太さで根管拡大された
歯の根管内に、同じ太さの国際規格の形状を有するポリ
プロピレン根管充填材をシーラーと共に挿入した結果、
術者の挿入時の感触では緊密な充填が得られた。更に、
エックス線撮影でもシーラー中に含まれている造影剤の
観察から緊密な充填が証明された。EXAMPLES AND COMPARATIVE EXAMPLES Next, the present invention will be specifically described with reference to actual examples. Example 1 Results of inserting a polypropylene root canal filling material having the same thickness and having an internationally standardized shape into a root canal of a tooth that had been demyelinated and had a root canal expanded with a thickness of 0.5 mm, together with a sealer. ,
A close packing was obtained by the feel of the operator during insertion. Furthermore,
The tight packing was proved by the observation of the contrast agent contained in the sealer even in the X-ray photography.
【0015】[0015]
【発明の効果】以上述べたように、本発明の根管充填材
はポリオレフィンで構成されているので、有害作用はな
く、従来の根管充填材に比して次のような効果を奏す
る。 1.根管壁に対して良好な密着性を有し、ほぼ完全な根
管の封鎖性を有する。 2.材料学的に化学的、物理的にはるかに安定な根管充
填材である。 3.生体内で異物性がはるかに少なく、食作用を受けに
くい根管充填材である。 4.弾力性を有し、折れにくく曲がった根管に対しても
明らかに充填しやすい。 5.歯の再治療の場合には根管充填材を取り出す必要が
あるが、本研究の根管充填材はちぎれにくく、更に生体
内で組織癒着しないので容易に取り出すことができる。 6.滅菌が容易である。As described above, since the root canal filling material of the present invention is made of polyolefin, it has no harmful effect and exhibits the following effects as compared with the conventional root canal filling materials. 1. It has good adhesion to the root canal wall and almost complete root canal sealing. 2. It is a root canal filling material that is much more stable chemically, physically and physically. 3. It is a root canal filling material that is far less foreign in vivo and less susceptible to phagocytosis. 4. It has elasticity and it is easy to fill even a root canal that is hard to break and bent. 5. It is necessary to take out the root canal filling material in the case of retreatment of teeth, but the root canal filling material of the present study is difficult to tear and can be easily taken out because it does not adhere to tissues in the living body. 6. Easy to sterilize.
【図1】本発明の根管充填材とシーラーを充填する説明
図FIG. 1 is an explanatory view of filling a root canal filling material and a sealer of the present invention.
【図2】国際規格50号で作成されたポリオレフィン樹
脂製の根管充填材[Fig. 2] Root canal filling material made of polyolefin resin created according to International Standard No. 50
【図3】歯髄炎治療のため根管を拡大する説明図FIG. 3 is an explanatory view of enlarging a root canal for treating pulpitis.
1 エナメル質 2 象牙質 3 根管
(歯髄部) 4 根管孔 5 根尖歯周組織 6 針状
のリーマー 7 根管充填材 8 シーラー1 Enamel 2 Dentin 3 Root canal (dental pulp) 4 Root canal hole 5 Apical periodontal tissue 6 Needle-like reamer 7 Root canal filling material 8 Sealer
───────────────────────────────────────────────────── フロントページの続き (72)発明者 山崎 康夫 東京都国立市中1−6−47 (72)発明者 椎木 一雄 福島県いわき市内郷御厨町1の201 ─────────────────────────────────────────────────── ─── Continuation of front page (72) Inventor Yasuo Yamazaki 1-6-47 1-6-47 Kunitachi, Tokyo (72) Inventor Kazuo Shiiki 201, 1-20, Mikitacho, Iwaki city, Fukushima prefecture
Claims (2)
徴とする根管充填材。1. A root canal filling material comprising a polyolefin resin.
ーラーがシリコーン樹脂であることを特徴とする根管充
填材。2. A root canal filling material, wherein a sealer filling a gap between the root canal filling material and the root canal wall is a silicone resin.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP02550396A JP3924687B2 (en) | 1996-02-13 | 1996-02-13 | Root canal filling material made of polyolefin resin |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP02550396A JP3924687B2 (en) | 1996-02-13 | 1996-02-13 | Root canal filling material made of polyolefin resin |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH09221403A true JPH09221403A (en) | 1997-08-26 |
JP3924687B2 JP3924687B2 (en) | 2007-06-06 |
Family
ID=12167876
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP02550396A Expired - Lifetime JP3924687B2 (en) | 1996-02-13 | 1996-02-13 | Root canal filling material made of polyolefin resin |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3924687B2 (en) |
-
1996
- 1996-02-13 JP JP02550396A patent/JP3924687B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JP3924687B2 (en) | 2007-06-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6500004B2 (en) | Endodontic sealing compositions and methods for using such compositions | |
Kim et al. | Critical review on methacrylate resin–based root canal sealers | |
US7780449B2 (en) | Hydrophilic endodontic sealing compositions and methods for using such compositions | |
JP4657102B2 (en) | Dental filler | |
US7750063B2 (en) | Dental filling material | |
US6024569A (en) | Root canal filling point | |
Thirawat et al. | The sealing ability of materials used as retrograde root fillings in endodontic surgery | |
US9486393B2 (en) | Single component tooth root sealer | |
US11957529B2 (en) | Endodontic point containing ultrasonic deformable material | |
US20020088372A1 (en) | Powder for glass ionomer-based sealer for root canal | |
KR100696161B1 (en) | Integral Gutta Percha Technique | |
Bawazir et al. | Apical microleakage of primary teeth root canal filling materials | |
JP3924687B2 (en) | Root canal filling material made of polyolefin resin | |
JP3174944B2 (en) | Root canal filling material made of polypropylene resin | |
EP2168560B1 (en) | Dental root canal-filling composition | |
JP5439642B2 (en) | Bactericidal root canal sealer and preparation kit | |
JP2003286176A (en) | Calcium hydroxide based root canal filling material | |
JPH08245332A (en) | Root canal filler | |
US20040053201A1 (en) | Antibacterial sponges for use in endodontic procedures and methods of use | |
JPH1149626A (en) | Filler for root canal, cement for root canal restoration and root canal restoration | |
Devarajan et al. | “COMPARATIVE EVALUATION OF DENTINAL P SEALERS”-SCANNING EL | |
JP4425374B2 (en) | Sealer composition for root canal filling | |
Iswariya | An In-vitro evaluation of push-out bond strength of two different fiber reinforced composite post systems using two different luting cements | |
Kurtzman et al. | ENDODONTICS-Fiberfill: A Fiber Reinforced Adhesively Bonded Endodontic Obturator and Post System | |
Chandler | Root canal filling |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20040802 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20050125 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20050324 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20061024 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20061212 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20070116 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20070214 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100309 Year of fee payment: 3 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110309 Year of fee payment: 4 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110309 Year of fee payment: 4 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120309 Year of fee payment: 5 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120309 Year of fee payment: 5 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130309 Year of fee payment: 6 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140309 Year of fee payment: 7 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
EXPY | Cancellation because of completion of term |