JPH0874007A - Pantagraph contact strip material for collecting current made of fe-base sintered alloy excellent in wear resistance - Google Patents

Pantagraph contact strip material for collecting current made of fe-base sintered alloy excellent in wear resistance

Info

Publication number
JPH0874007A
JPH0874007A JP23068694A JP23068694A JPH0874007A JP H0874007 A JPH0874007 A JP H0874007A JP 23068694 A JP23068694 A JP 23068694A JP 23068694 A JP23068694 A JP 23068694A JP H0874007 A JPH0874007 A JP H0874007A
Authority
JP
Japan
Prior art keywords
alloy
wear resistance
strip material
pantagraph
contact strip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP23068694A
Other languages
Japanese (ja)
Inventor
Masashi Koike
正志 小池
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP23068694A priority Critical patent/JPH0874007A/en
Publication of JPH0874007A publication Critical patent/JPH0874007A/en
Withdrawn legal-status Critical Current

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Abstract

PURPOSE: To produce a pantagraph contact strip material for collecting current made of an Fe-base sintered alloy excellent in wear resistance by mixing the powder of an Fe-base alloy having a specified compsn. and Fe-W alloy powder contg. TiC and W at a specified ratio and executing compacting and sintering. CONSTITUTION: The fine powder, 15 to 30%, of 1 to 150μm of an Fe-W alloy as a dispersed phase contg. 1 to 5% TiC, 60 to 90% W, and the balance Fe, and the balance powder of 1 to 150μm of an Fe-base alloy for a matrix contg. 0.1 to 0.5% C, 1 to 20% W, and the balance Fe are mixed, and this powdery mixed raw material is subjected to press molding into a sheet material, which is thereafter sintered at a high temp., e.g. of 1200 to 1250 deg.C. The pantagraph contact strip material for collecting current made of an Fe-base sintered alloy excellent in wear resistance, furthermore small in mating attackability and stably usable over a long period can be produced.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は、すぐれた耐摩耗性を
有し、かつ相手攻撃性の低いFe基焼結合金製集電用パ
ンタグラフすり板材に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an Fe-based sintered alloy pantograph sliding plate material for current collection, which has excellent wear resistance and low opponent attack.

【0002】[0002]

【従来の技術】従来、例えば特開平5−105994号
公報に記載されるように、Fe系合金の素地に硬質粒子
が分散相として存在する組織を有するFe基焼結合金で
構成された集電用パンタグラフすり板材が各種提案さ
れ、実用に供されている。
2. Description of the Related Art Conventionally, as described in, for example, Japanese Unexamined Patent Publication No. 5-105994, a current collector composed of an Fe-based sintered alloy having a structure in which hard particles exist as a dispersed phase in an Fe-based alloy matrix. Various pantograph sliding plate materials have been proposed and put to practical use.

【0003】[0003]

【発明が解決しようとする課題】一方、近年の電気車の
高速化はめざましく、これに伴ない、集電用パンタグラ
フすり板材(以下、集電すり板材という)にも耐摩耗性
の一段の向上が望まれているが、従来の集電すり板材に
おいては、耐摩耗性のすぐれたものは相手攻撃性が高
く、反対に相手攻撃性の低いものは耐摩耗性に劣るのが
現状である。
On the other hand, the speeding up of electric cars in recent years has been remarkable, and along with this, the wear resistance of pantograph slabs for current collection (hereinafter referred to as current slabs) has been further improved. However, in the conventional current collecting strip material, a material having excellent wear resistance has a high opponent attacking property, and a material having low opponent attacking property has a poor wear resistance.

【0004】[0004]

【課題を解決するための手段】そこで、本発明者等は、
上述のような観点から、相手攻撃性を高めることなく、
耐摩耗性を向上させた集電すり板材を開発すべく研究を
行なった結果、集電すり板材を、重量%で(以下、%は
重量%で示す)、分散相として炭化チタン(以下、Ti
Cで示す):1〜5%、同じく分散相としてW:60〜
90%含有のFe−W合金:15〜30%、を含有し、
残りが素地を形成するFe系合金からなる組成を有し、
かつ前記Fe系合金が、C:0.1〜0.5%、
W:1〜20%、を含有し、残りがFeと不可避不純物
からなる組成を有するFe基焼結合金で構成すると、上
記分散相を構成するTiCはビッカース硬さで約320
0の高い硬さをもつことから、集電すり板材はすぐれた
耐摩耗性をもつようになり、また同じく分散相を構成す
る上記Fe−W合金は同じくビッカース硬さで約600
〜700を有し、この硬さは素地のもつビッカース硬さ
で約120の硬さと上記TiCの硬さの中間硬さである
ことから、前記TiCによる相手攻撃性を緩和するよう
に作用するほか、自身もTiCとの共存において耐摩耗
性の向上に寄与し、さらに素地中に固溶含有するC成分
とW成分は素地の強度を向上させると共に、それぞれT
iCおよびFe−W合金の素地に対する密着性を向上さ
せるように作用し、この結果集電すり板材は相手攻撃性
の低い状態で、すぐれた耐摩耗性をもつようになるとい
う研究結果を得たのである。
Therefore, the present inventors have
From the above viewpoint, without increasing the opponent's aggression,
As a result of research to develop a current collecting strip material having improved wear resistance, the current collecting strip material is expressed in% by weight (hereinafter,% means% by weight) and titanium carbide (hereinafter, Ti) as a dispersed phase.
(Indicated by C): 1 to 5%, similarly as a dispersed phase W: 60 to
Fe-W alloy containing 90%: 15 to 30%,
The rest has a composition consisting of a Fe-based alloy forming the matrix,
And the Fe-based alloy contains C: 0.1 to 0.5%,
When it is composed of a Fe-based sintered alloy having a composition of W: 1 to 20% and the balance of Fe and inevitable impurities, TiC constituting the dispersed phase has a Vickers hardness of about 320.
Since it has a high hardness of 0, the current collecting strip material has excellent wear resistance, and the Fe-W alloy also constituting the dispersed phase has a Vickers hardness of about 600.
The hardness is about 700, and this hardness is an intermediate hardness between the hardness of the Vickers hardness of the base material of about 120 and the hardness of the above TiC, and thus acts to mitigate the opponent attacking property by the TiC. , Also contributes to the improvement of wear resistance in the coexistence with TiC, and the C component and W component contained in the solid solution as a solid solution improve the strength of the base material, and the
It has been researched that it acts to improve the adhesion of the iC and Fe-W alloys to the base material, and as a result, the current collecting strip material has excellent wear resistance in the state of low opponent attack. Of.

【0005】この発明は、上記の研究結果にもとづいて
なされたものであって、分散相としてTiC:1〜5
%、同じく分散相としてW:60〜90%含有のFe−
W合金:15〜30%、を含有し、残りが素地を形成す
るFe系合金からなる組成を有し、かつ前記Fe系合金
が、C:0.1〜0.5%、 W:1〜20%、を
含有し、残りがFeと不可避不純物からなる組成を有す
るFe基焼結合金で構成してなる、耐摩耗性のすぐれた
Fe基焼結合金製集電すり板材に特徴を有するものであ
る。
The present invention has been made based on the above-mentioned research results, and TiC: 1 to 5 as a dispersed phase.
%, Similarly as a dispersed phase W: 60 to 90% Fe-
W alloy: 15 to 30%, and the rest is a Fe-based alloy forming a base, and the Fe-based alloy is C: 0.1 to 0.5%, W: 1 to Fe-based sintered alloy current collector plate material having excellent wear resistance, which is composed of an Fe-based sintered alloy having a composition of 20% and the balance of Fe and inevitable impurities Is.

【0006】つぎに、この発明の集電すり板材におい
て、これを構成するFe基焼結合金の組成を上記の通り
に限定した理由を説明する。 (a) TiC TiC成分には、上記の通り素地に分散し、自身のもつ
高硬度によって耐摩耗性を著しく向上させる作用がある
が、その含有量が1%未満では所望のすぐれた耐摩耗性
を確保することができず、一方その含有量が5%を越え
ると相手攻撃性が増すようになることから、その含有量
を1〜5%、望ましくは1.5〜3.5%と定めた。
Next, the reason why the composition of the Fe-based sintered alloy constituting the current collecting strip material of the present invention is limited as described above will be explained. (A) TiC The TiC component disperses in the base material as described above and has the effect of significantly improving the wear resistance due to its high hardness, but if its content is less than 1%, the desired excellent wear resistance is obtained. Cannot be ensured, and on the other hand, if the content exceeds 5%, the opponent's aggression will increase, so the content is defined as 1 to 5%, preferably 1.5 to 3.5%. It was

【0007】(b) Fe−W合金 Fe−W合金成分には、上記の通り素地に分散し、Ti
C成分による相手攻撃性の緩和に寄与するほか、自身も
TiC成分との共存において耐摩耗性の向上に寄与する
作用があるが、その含有量が15%未満では前記作用に
所望の効果が得られず、一方その含有量が30%を越え
ると相手攻撃性が増すようになることから、その含有量
を15〜30%、望ましくは18〜25%と定めた。ま
た、Fe−W合金のW含有量は60〜90%にする必要
があり、これは、その含有量が60%未満では自身の硬
さが低下するようになって上記作用を満足に発揮させる
ことができず、一方その含有量が90%を越えると、硬
さが高くなって相手攻撃性増大の原因になるという理由
によるものであり、望ましくは70〜85%の含有がよ
い。
(B) Fe-W alloy The Fe-W alloy component is dispersed in the base material as described above, and Ti
In addition to contributing to the mitigation of opponent attack by the C component, it also contributes to improving wear resistance in the coexistence with the TiC component, but if the content is less than 15%, the desired effect can be obtained in the above action. On the other hand, if the content exceeds 30%, the aggression against the other party will increase. Therefore, the content is set to 15 to 30%, preferably 18 to 25%. Further, the W content of the Fe-W alloy needs to be 60 to 90%, and when the content is less than 60%, the hardness of the steel itself is lowered and the above-described action is satisfactorily exhibited. However, if the content exceeds 90%, the hardness becomes high, which causes the increase of the aggressiveness against the other party, and the content is preferably 70 to 85%.

【0008】(c) Fe系合金のC 素地を構成するFe系合金のC成分には、素地に固溶し
て強度を高めると共に、特にTiCの素地に対する密着
性を向上させる作用がるが、その含有量が素地に占める
割合で0.1%未満では前記作用に所望の向上効果が得
られず、一方その含有量が0.5%を越えると炭化物が
形成されるようになって素地の靭性が低下することか
ら、その含有量を0.1〜0.5%、望ましくは0.1
5〜0.35%と定めた。
(C) C component of the Fe-based alloy The C component of the Fe-based alloy has the function of forming a solid solution in the substrate to increase the strength and, in particular, to improve the adhesion of TiC to the substrate. If the content is less than 0.1% in the matrix, the desired effect of improving the above-mentioned action cannot be obtained, while if the content exceeds 0.5%, carbides are formed and Since the toughness decreases, its content is 0.1 to 0.5%, preferably 0.1.
It was set to 5 to 0.35%.

【0009】(d) Fe系合金のW 同じく素地を構成するFe系合金のW成分には、素地に
固溶して強度を向上させるほか、上記Fe−W合金の素
地に対する密着性を向上させる作用があるが、その含有
量が素地に占める割合で1%未満では前記作用に所望の
効果が得られず、一方その含有量が20%を越えると素
地の靭性が低下するようになることから、その含有量を
1〜20%、望ましくは1.5〜10%と定めた。
(D) W of Fe-based alloy The W component of the Fe-based alloy, which also constitutes the base material, forms a solid solution in the base material to improve the strength and also improves the adhesion of the Fe-W alloy to the base material. There is an action, but if the content is less than 1% in the matrix, the desired effect is not obtained, while if the content exceeds 20%, the toughness of the matrix decreases. The content was set to 1 to 20%, preferably 1.5 to 10%.

【0010】[0010]

【実施例】つぎに、この発明の集電すり板材を実施例に
より具体的に説明する。原料粉末として、いずれも1〜
150μmの範囲内の所定の平均粒径を有し、かつ1〜
95%の範囲内の所定のW含有量の各種のFe−W合金
粉末、およびTiC粉末、さらに平均粒径:150μm
のアトマイズ鉄粉および同10μmの黒鉛粉末を用意
し、これら原料粉末を所定の配合組成に配合し、V型ミ
キサーで30分間混合した後、6ton /cm2 の圧力で圧
粉体にプレス成形し、この圧粉体を真空中、温度:12
00〜1250℃に80分間保持の条件で焼結すること
により表1に示される組成並びに理論密度比を有し、か
つ幅25mm×厚さ:10mm×長さ:80mmの寸法をもっ
た本発明集電すり板材1〜14および比較集電すり板材
1〜6をそれぞれ製造した。なお、比較集電すり板材1
〜6は、これを構成するFe基焼結合金が、これの構成
成分のうち、特に耐摩耗性および相手攻撃性に影響を及
ぼす成分含有量(第2表に※印を付す)がこの発明の範
囲から外れた組成をもつものである。
EXAMPLES Next, the current collecting strip material of the present invention will be specifically described by way of examples. As raw material powder, 1 to
Has a predetermined average particle size within the range of 150 μm, and 1 to
Various Fe-W alloy powders with a predetermined W content within the range of 95%, and TiC powders, and an average particle size: 150 μm.
Atomized iron powder and graphite powder of 10 μm were prepared, and these raw material powders were mixed in a predetermined composition and mixed with a V-type mixer for 30 minutes, and then pressed into a green compact at a pressure of 6 ton / cm 2. , This powder compact in vacuum, temperature: 12
The present invention having the composition and theoretical density ratio shown in Table 1 by sintering at a temperature of 00 to 1250 ° C. for 80 minutes and having dimensions of width 25 mm × thickness: 10 mm × length: 80 mm. Current collecting strips 1 to 14 and comparative current collecting strips 1 to 6 were manufactured, respectively. It should be noted that the comparative current collecting plate 1
Nos. 6 to 6 show that the Fe-based sintered alloy constituting the present invention has a content of components (marked with * in Table 2) that particularly influences wear resistance and opponent attacking property of the present invention. The composition is out of the range.

【0011】ついで、この結果得られた各種集電すり板
材について加速摩耗試験を行なった。加速摩耗試験は、
モータの水平回転軸に中心を固定することにより直立支
持された外径:2.2mの円板の前記固定側とは反対の
側面に、模擬トロリ線として外径:2m×幅:5mm×厚
さ:15mmの硬銅リング(JIS・C1100・BB−
H)を50mm偏心して取付けた装置を用い、上記硬銅リ
ングの直径線上の両側にそれぞれ上記集電すり板材を5
kgの押付力で長さ:80mm×幅:25mmの寸法面を面接
触させ、上記模擬トロリ線と集電すり板材間に200A
の電流を流しながら、上記円板の回転を5分で250km
/hrの回転速度に上げ、この速度に5分間保持した後、
5分かけて停止を1サイクルとし、これを5回繰り返す
ことにより行ない、集電すり板材の比摩耗量と相手材で
ある模擬トロリ線の摩耗深さを測定した。この測定結果
を表1,2に示した。
Next, an accelerated wear test was carried out on the various current collecting strips obtained as a result. The accelerated wear test is
Outer diameter: 2m x width: 5mm x thickness as a simulated trolley wire on the side opposite to the fixed side of a disc with an outer diameter of 2.2m supported upright by fixing the center to the horizontal rotation shaft of the motor. S: 15 mm hard copper ring (JIS / C1100 / BB-
H) is installed with an eccentricity of 50 mm, and the above-mentioned current collecting strips are installed on both sides of the diameter line of the above hard copper ring.
With a pressing force of kg, the dimension surface of length: 80 mm × width: 25 mm is brought into surface contact, and 200 A is applied between the simulated trolley wire and the current collecting strip plate material.
Rotate the above disk for 5 minutes while flowing the current of 250 km
After increasing the rotation speed to / hr and maintaining this speed for 5 minutes,
Stopping was performed for 5 minutes as one cycle, and this was repeated 5 times to measure the specific wear amount of the current collecting strip material and the wear depth of the mating trolley wire as the mating material. The measurement results are shown in Tables 1 and 2.

【0012】[0012]

【表1】 [Table 1]

【0013】[0013]

【表2】 [Table 2]

【0014】[0014]

【発明の効果】表1,2に示される結果から、本発明集
電すり板材1〜14は、いずれも低い相手攻撃性を保持
した状態で、すぐれた耐摩耗性を示すのに対して、比較
集電すり板材1〜6に見られるように、これを構成する
Fe基焼結合金におけるTiC含有量およびFe−W合
金含有量、さらにFe−W合金におけるW含有量がこの
発明の範囲から外れると耐摩耗性または相手攻撃性の劣
ったものになることが明らかである。上述のように、こ
の発明の集電すり板材は、すぐれた耐摩耗性ときわめて
低い相手攻撃性を具備しているものであり、電気車の高
速化に十分満足に対応でき、長期に亘ってすぐれた性能
を発揮するのである。
From the results shown in Tables 1 and 2, the current collecting and sliding board materials 1 to 14 of the present invention all show excellent wear resistance in the state of maintaining low opponent attacking property. As can be seen from the comparative current collecting strip materials 1 to 6, the TiC content and the Fe-W alloy content in the Fe-based sintered alloy constituting the same and the W content in the Fe-W alloy are within the range of the present invention. It is clear that if it comes off, it will be inferior in wear resistance or opponent attack. As described above, the current collecting strip material of the present invention has excellent wear resistance and extremely low opponent attacking ability, and can satisfactorily correspond to the speeding up of the electric vehicle and can be used for a long period of time. It exhibits excellent performance.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 重量%で、 分散相として炭化チタン:1〜5%、 同じく分散相としてW:60〜90%含有のFe−W合
金:15〜30%、を含有し、残りが素地を形成するF
e系合金からなる組成を有し、かつ前記Fe系合金が、 C:0.1〜0.5%、 W:1〜20%、を含有
し、残りがFeと不可避不純物からなる組成を有するF
e基焼結合金で構成したことを特徴とする耐摩耗性のす
ぐれたFe基焼結合金製集電用パンタグラフすり板材。
Claims: 1. By weight%, titanium carbide: 1 to 5% as a dispersed phase, Fe: W alloy containing W: 60 to 90% as a dispersed phase: 15 to 30%; Forming F
The composition has an e-based alloy, and the Fe-based alloy contains C: 0.1 to 0.5%, W: 1 to 20%, and the balance is Fe and inevitable impurities. F
An Fe-based sintered alloy current collector pantograph sliding plate material having excellent wear resistance, characterized by being composed of an e-based sintered alloy.
JP23068694A 1994-08-31 1994-08-31 Pantagraph contact strip material for collecting current made of fe-base sintered alloy excellent in wear resistance Withdrawn JPH0874007A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP23068694A JPH0874007A (en) 1994-08-31 1994-08-31 Pantagraph contact strip material for collecting current made of fe-base sintered alloy excellent in wear resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23068694A JPH0874007A (en) 1994-08-31 1994-08-31 Pantagraph contact strip material for collecting current made of fe-base sintered alloy excellent in wear resistance

Publications (1)

Publication Number Publication Date
JPH0874007A true JPH0874007A (en) 1996-03-19

Family

ID=16911729

Family Applications (1)

Application Number Title Priority Date Filing Date
JP23068694A Withdrawn JPH0874007A (en) 1994-08-31 1994-08-31 Pantagraph contact strip material for collecting current made of fe-base sintered alloy excellent in wear resistance

Country Status (1)

Country Link
JP (1) JPH0874007A (en)

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Date Code Title Description
A300 Withdrawal of application because of no request for examination

Free format text: JAPANESE INTERMEDIATE CODE: A300

Effective date: 20011106