JPH0845420A - Electron emission element, electron source, image forming device and their manufacture - Google Patents

Abstract

PURPOSE:To prevent a substrate fracture, and provide an image display device using a good electron emission element by thermally treating an organic metal thin film at temperature equal to or above a level for forming a metallic oxide out of organic metal. CONSTITUTION:After a substrate 1 is sufficiently washed by use of a detergent, distilled water and an organic solvent, an element electrode material is stacked using the vapor deposition method, the sputter method or the like. Then, element electrodes 4 and 5 are formed on the substrate 1, using the photo-lithograph technology. Thereafter, organic metal solution is applied to the substrate 1 with the electrodes 4 and 5 laid and shelved, thereby communicating the electrodes 4 and 5 to each other and forming an organic metal thin film. Also, heating temperature at a plurality of coating and heating processes for the organic metal solution is set at a level equal to or higher than the melting temperature of organic metal, but equal to or lower than the thermal decomposition temperature. The organic metal thin film is thereby formed. This thin film is further heated and baked at temperature equal to or above the thermal decomposition temperature for the organic metal, thereby forming a metallic or metallic oxide thin film.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a surface conduction electron-emitting device, an electron source using a plurality of the surface conduction electron-emitting devices, an image forming apparatus such as a display device or an exposure device using the electron source, and further these. Manufacturing method.

[0002]

2. Description of the Related Art A surface conduction electron-emitting device utilizes a phenomenon in which electron emission occurs when a current is passed through a conductive thin film formed on an insulating substrate in parallel with the film surface.

As a typical example of the structure of the surface conduction electron-emitting device, a conductive thin film such as a metal oxide which connects between a pair of device electrodes provided on an insulating substrate is referred to as forming in advance. The thing which formed the electron emission part by the electricity supply process is mentioned. Forming is usually performed by applying a voltage to both ends of the conductive thin film, and the structure is changed by locally destroying, deforming or degrading the conductive thin film, and the electron emitting portion in an electrically high resistance state is formed. Is a process for forming. The electron emission is performed from the vicinity of the crack generated in the electron emitting portion by applying a voltage to the conductive thin film in which the electron emitting portion is formed and flowing a current.

Since the surface conduction electron-emitting device has a simple structure and is easy to manufacture, it has an advantage that a large number of arrays can be formed over a large area. Therefore, various applications for utilizing this feature are being researched. For example, it can be used for an image forming apparatus such as a display device.

Conventionally, as an example in which a large number of surface conduction electron-emitting devices are formed in an array, surface conduction electron-emitting devices are arranged in parallel and both ends (both device electrodes) of each surface conduction electron-emitting device are wired. An electron source in which a large number of rows connected by (also called common wiring) are arranged (also called a ladder arrangement) is disclosed (Japanese Patent Laid-Open Nos. 1-33132 and 1-2837).
No. 49, No. 1-275552). Further, particularly in the case of a display device, a large number of surface conduction electron-emitting devices can be used as a self-luminous display device that can be a flat panel display device similar to a display device using liquid crystal and does not require a backlight. A display device has been proposed in which an arranged electron source is combined with a phosphor that emits visible light when irradiated with an electron beam from the electron source (US Pat. No. 5,066,506).
883).

In order to obtain a high-quality, high-definition image on a large screen in a display device using the surface-conduction type electron-emitting devices, the number of rows and columns of the surface-conduction type electron-emitting devices is several hundreds, respectively. It is necessary to arrange a large number of surface conduction electron-emitting devices, which is several thousand. Therefore, it is desired that the electric characteristics of each surface conduction electron-emitting device be uniform and easy to control. For example, when driving an electron source in which a large number of surface conduction electron-emitting devices are arranged, a common voltage is applied to a plurality of surface conduction electron-emitting devices and the voltage is changed,
Luminance modulation is performed by changing the pulse width of the voltage while the applied voltage is constant.For each surface conduction electron-emitting device, there is a uniform change in the emission current due to changes in the applied voltage and changes in the pulse width. It is desired to be easy to obtain for each surface conduction electron-emitting device.

[0007]

In the surface conduction electron-emitting device, the state of the conductive thin film influences the forming process for forming the electron emission portion, and finally determines the electron emission characteristics of the surface conduction electron emission device. To do. As a method for forming the conductive thin film, an organometallic solution is applied to form an organometallic thin film because the process is simple and a large area can be easily produced. Means for forming an oxide thin film is generally used. As the organic metal, one that melts in the step of thermally decomposing to form a metal oxide is preferable from the viewpoint of homogeneity, and as such a metal, for example, an organometallic complex having an amino group as a ligand. However, the organic metal having such a group also has sublimability at the same time. Therefore, sublimation occurs in the coating / baking step and only an extremely thin film can be obtained in one coating / baking step, and this step is repeated a plurality of times to obtain a desired thickness. As a result, since the substrate is subjected to the baking process multiple times, the substrate may be damaged by thermal strain in the process of cooling the substrate to room temperature.
Had a problem.

An object of the present invention is to solve the above problems, prevent damage to the substrate in the step of forming a conductive thin film, and provide a good surface conduction electron-emitting device, and an image display using the surface conduction electron-emitting device. To provide a device.

[0009]

Means and Actions for Solving the Problems Claims 1 and 2
Is a method of manufacturing a surface conduction electron-emitting device,
A step of forming a conductive thin film, a step of forming an organic metal thin film by performing an operation of applying an organic metal solution and performing heat treatment at a temperature not lower than a melting temperature and lower than a thermal decomposition temperature of the organic metal,
It is characterized by comprising the step of heat-treating the organic metal thin film at a temperature not lower than the temperature at which a metal oxide is formed from the organic metal.

The inventions according to claims 3 to 5 are surface conduction electron-emitting devices manufactured by the above manufacturing method, and the inventions according to claims 6 and 7 use a plurality of the surface conduction electron-emitting devices. According to another aspect of the present invention, there is provided an image forming apparatus using the electron source.

A tenth aspect of the present invention is a method of manufacturing the electron source, and a tenth aspect of the invention is a method of manufacturing the image forming apparatus.

The structure and operation of each invention will be further described below.

The surface conduction electron-emitting device is classified into a flat type and a vertical type, and any surface conduction electron-emitting device can be used in the present invention. First, the basic structure of the planar surface conduction electron-emitting device will be described.

FIGS. 1A and 1B are views showing the basic structure of a flat surface conduction electron-emitting device.

In FIG. 1, 1 is a substrate, 2 is an electron emitting portion,
Reference numeral 3 is a conductive thin film, and 4 and 5 are device electrodes.

The substrate 1 is, for example, quartz glass or Na.
Examples thereof include glass having a reduced content of impurities such as blue glass, soda lime glass, a laminated body obtained by laminating SiO ₂ on soda lime glass by a sputtering method, and ceramics such as alumina.

The material of the opposing device electrodes 4 and 5 is as follows.
Common conductor materials are used, such as Ni, Cr, Au,
Metals or alloys such as Mo, W, Pt, Ti, Al, Cu, Pd and Pd, Ag, Au, RuO ₂ , Pd-Ag
A printed conductor composed of a metal or a metal oxide and glass, a transparent conductor such as In ₂ O ₃ —SnO ₂ and a semiconductor conductor material such as polysilicon are appropriately selected.

The element electrode interval L, the element electrode length W, the shape of the conductive thin film 3 and the like are designed according to the applied form.

The device electrode spacing L is preferably several hundred Å to several hundred μm, more preferably several μm to several depending on the voltage applied between the device electrodes 4 and 5 and the electric field strength capable of emitting electrons. It is 10 μm.

The device electrode length W is preferably several μm to several hundreds μm, and the device electrode thickness d is several hundred Å to several μm, considering the resistance value of the electrodes and electron emission characteristics.

In the surface conduction electron-emitting device shown in FIG. 1, the device electrodes 4, 5 and the conductive thin film 3 are laminated on the substrate 1 in this order. The conductive thin film 3 and the device electrodes 4 and 5 may be laminated in this order.

In order to obtain good electron emission characteristics, the conductive thin film 3 is particularly preferably a fine particle film composed of fine particles, and the thickness of the conductive thin film 3 depends on the step coverage to the device electrodes 4 and 5 and the device. It is appropriately selected depending on the resistance value between the electrodes 4 and 5 and the forming conditions described later. The thickness of the conductive thin film 3 is preferably several Å to several thousand Å, particularly preferably 10 Å to 500 Å, and its resistance value is 10
The sheet resistance value is ³ to 10 ⁷ Ω / □.

As the material forming the conductive thin film 3, for example, Pd, Ru, Ag, Ti, In, Cu, Cr, F
e, Zn, Sn, Ta, W, Pb and other metals, PdO, S
oxides such as nO ₂ , In ₂ O ₃ , PbO and Sb ₂ O ₃ ;
HfB ₂ , ZrB ₂ , LaB ₆ , CeB ₆ , YB ₄ , G
Borides such as dB ₄ , TiC, ZrC, HfC, TaC,
Carbides such as SiC and WC, nitrides such as TiN, ZrN, and HfN, semiconductors such as Si and Ge, carbon, and the like can be given. Among them, PdO is preferably used.

The fine particle film is a film in which a plurality of fine particles are aggregated, and its fine structure is not only in a state where the fine particles are dispersed and arranged but also in a state where the fine particles are adjacent to each other or overlap each other (island shape). Including). In the case of a fine particle film, the particle diameter of the fine particles is preferably several Å to several thousand Å, particularly preferably 10 Å to 200 Å.

The electron emitting portion 2 has a crack, and the electron is emitted from the vicinity of this crack. The electron emitting portion 2 including the crack and the crack itself are formed depending on the film thickness of the conductive thin film 3, the film quality, the material, the forming conditions described later, and the like. Therefore, the position and shape of the electron emitting portion 2 are not limited to the position and shape as shown in FIG.

The crack may have conductive fine particles having a particle diameter of several Å to several hundred Å. The conductive fine particles are the same as some or all of the elements of the material forming the conductive thin film 3. Further, the electron emitting portion 2 including a crack and the conductive thin film 3 in the vicinity thereof may contain carbon and a carbon compound.

Next, the basic structure of the vertical surface conduction electron-emitting device will be described.

FIG. 2 is a view showing the basic structure of a vertical surface conduction electron-emitting device, in which 21 is a step forming member,
Other reference numerals that are the same as those in FIG. 1 indicate the same members.

The substrate 1, the electron emitting portion 2, the conductive thin film 3 and the device electrodes 4 and 5 are made of the same material as that of the above-mentioned plane type surface conduction electron emitting device.

The step forming member 21 is formed by, for example, a vacuum vapor deposition method,
It is made of an insulating material such as SiO ₂ attached by a printing method, a sputtering method or the like. The film thickness of the step forming member 21 corresponds to the device electrode distance L (see FIG. 1) of the planar surface conduction electron-emitting device described above. It is set by the voltage applied between 5 and the electric field strength capable of emitting electrons, but is preferably several hundred Å to several tens of μm, and particularly preferably several hundred Å to several μm.

Since the conductive thin film 3 is usually formed after the device electrodes 4, 5 are formed, it is laminated on the device electrodes 4, 5, but after the conductive thin film 3 is formed, the device electrodes 4, 5 are formed. It is also possible to make it so that the device electrodes 4 and 5 are laminated on the conductive thin film 3. Further, as described in the description of the planar surface conduction electron-emitting device, the formation of the electron-emitting portion 2 depends on the film thickness of the conductive thin film 3, the film quality, the material, the forming conditions to be described later, and the like. The position and shape are not limited to the position and shape shown in FIG.

The following description is based on the above-mentioned planar surface conduction electron-emitting device and vertical surface conduction electron-emitting device.
A plane type will be described as an example, but a vertical type surface conduction electron-emitting device may be used instead of the plane type surface conduction electron-emitting device.

Various methods can be considered as a method of manufacturing the surface conduction electron-emitting device, and one example thereof will be described with reference to FIG. In FIG. 3, the same reference numerals as those in FIG. 1 denote the same members.

1) After the substrate 1 is thoroughly washed with a detergent, pure water and an organic solvent, an element electrode material is deposited by a vacuum evaporation method, a sputtering method or the like, and then an element is formed on the surface of the substrate 1 by a photolithography technique. The electrodes 4 and 5 are formed (FIG. 3A).

2) The element electrode 4 is formed by applying an organic metal solution on the substrate 1 on which the element electrodes 4 and 5 are provided and leaving it to stand.
And the device electrode 5 are connected to form an organometallic thin film. In the present invention, the organometallic thin film is formed by setting the heating temperature in the application / heating step of the organometallic solution performed a plurality of times to a temperature equal to or higher than the melting temperature of the organometallic and equal to or lower than the thermal decomposition temperature. Is baked at a temperature not lower than the thermal decomposition temperature of the organic metal to form a metal or metal oxide thin film.

In the present invention, the organic metal solution is, for example, a palladium salt alkylamine complex Pd ²⁺ [CH ₃ CO
O ⁻ ] ₂ [(C ₃ H ₇ ) ₂ NCH ₃ ] ₂ , palladium acetate, using an acetic acid ester organic solvent such as methyl acetate, ethyl acetate, butyl acetate, etc. 1
(wt%) or a mixture of palladium propionate and an appropriate concentration using an organic solvent such as methyl propionate, ethyl propionate and butyl propionate.

As described above, the metal oxide film obtained by coating / baking an organic metal having sublimability is repeatedly applied / baked a plurality of times to finally obtain a desired metal oxide film by stacking the metal oxide films in multiple layers. Was obtained. However, the present inventor has found that it is not necessary to form a complete metal oxide film every time in order to obtain a desired film thickness, and has achieved the present invention.

This will be described in detail with reference to FIG. FIG. 18 is a diagram showing a thermal analysis of an organopalladium complex preferable as the organometallic material used in the present invention. When such an organic metal is heated, an endothermic peak as indicated by a in the figure is observed. This is a peak generated when the organic metal melts. When heated further, b, c in the figure
An exothermic peak as shown by is observed. These are the peaks associated with the thermal decomposition of organometallics. Conventionally, in the figure e
All heating steps were carried out at the temperature shown by (3), that is, the temperature at which melting and thermal decomposition of the organic metal were completely completed and a thin film of a complete metal oxide was obtained.

However, the heating process after coating for adjusting the film thickness may be higher than the melting temperature shown by d in the figure, and after holding until the organic metal is completely melted and spread uniformly on the substrate. When the substrate is cooled to room temperature, a uniform organic metal thin film can be obtained. The organic metal thin film formed here has only a slight solubility in an organic metal solvent (eg, butyl acetate), and an organic metal solution using the same solvent is layered on the organic metal film. It is possible to apply and adjust the thickness of the organic metal film. Therefore, in the present invention, the heating temperature in each coating / heating step is set to a temperature higher than the melting temperature of the organic metal and lower than the thermal decomposition temperature.

The organic metal film formed as described above is heat-treated at a temperature at which a metal oxide is formed from the organic metal (a temperature indicated by e in the figure) to obtain a desired metal oxide thin film. Is obtained.

3) Subsequently, an energization process called forming is performed. When power is supplied from a power source (not shown) between the device electrodes 4 and 5, the electron emitting portion 2 having a changed structure is formed at the site of the conductive thin film 3 (FIG. 3C). By this energization treatment, the electroconductive thin film 3 is locally destroyed, deformed or altered, and the electron emission portion 3 is a portion whose structure is changed.

FIG. 4 shows an example of the voltage waveform of forming.

The voltage waveform is particularly preferably a pulse waveform,
There are a case of continuously applying a voltage pulse whose pulse peak value is a constant voltage (FIG. 4A) and a case of applying a voltage pulse while increasing the pulse peak value (FIG. 4B).

First, the case where the pulse peak value is a constant voltage will be described with reference to FIG.

In FIG. 4A, T ₁ and T ₂ are the pulse width and pulse interval of the voltage waveform, for example, T ₁ is 1 μm.
sec to 10 msec, T ₂ 10 μsec to 100 m
csec, the peak value (peak voltage during forming) is appropriately selected according to the form of the surface conduction electron-emitting device described above, and is applied for several seconds to several tens of minutes in a vacuum atmosphere with an appropriate degree of vacuum. The voltage waveform to be applied is not limited to the illustrated triangular wave, and a desired waveform such as a rectangular wave can be used.

Next, the case where the voltage pulse is applied while the pulse crest value is increased will be described with reference to FIG.

T ₁ and T ₂ in FIG. 4B are shown in FIG.
Similar to (a), the crest value (peak voltage during forming) is increased by, for example, about 0.1 V step,
Application is performed in an appropriate vacuum atmosphere similar to the description of FIG.

During the pulse interval T ₂ , the conductive thin film 3 is
(See FIGS. 1 and 2) The element current is measured at a voltage that does not locally destroy, deform, or alter the properties, for example, a voltage of about 0.1 V to obtain a resistance value, and for example, when a resistance of 1 MΩ or more is exhibited. Finish forming.

4) Next, it is preferable to perform an activation process on the element which has completed the forming process.

The activation step is, for example, 10 ⁻⁴ to 10
^As with the description in the forming step, it refers to a process of repeating the application of pulses with a pulse peak value of a constant voltage at a vacuum degree of about ^-5 torr. It is possible to remove carbon and carbon compounds from organic substances present in a vacuum atmosphere. Is deposited on the electron emission portion 2 (see FIGS. 1 and 2), which is a process in which the states of the device current and the emission current can be significantly improved. It is effective to perform this activation step while measuring the device current and the emission current, for example, and to end it when the emission current is saturated, because it is effective. The pulse peak value in the activation step is preferably the peak value of the driving voltage.

The carbon and the carbon compound are graphite (both single crystal and polycrystal) and amorphous carbon (amorphous carbon and a mixture thereof with polycrystal graphite). The deposited film thickness is preferably 500 Å or less, more preferably 300 Å or less.

5) More preferably, the surface conduction electron-emitting device thus produced is operated and driven in a vacuum atmosphere having a vacuum degree higher than the vacuum degree in the forming step and the activation step. In addition, more preferably, operation is performed after heating at 80 ° C. to 150 ° C. in a vacuum atmosphere having a higher degree of vacuum.

A vacuum atmosphere having a vacuum degree higher than the vacuum degree subjected to the forming process and activation treatment is, for example, about 10 ^−6.
It is a vacuum degree having the above vacuum degree, and more preferably,
It is an ultra-high vacuum system, and the degree of vacuum is such that carbon and carbon compounds are not newly deposited.

By the step 5), further deposition of carbon and carbon compounds is suppressed, and the device current and the emission current are stabilized.

The basic characteristics of the surface conduction electron-emitting device thus obtained will be described below.

FIG. 5 is a schematic block diagram showing an example of a measurement / evaluation system for measuring the electron emission characteristics of the surface conduction electron-emitting device. First, this measurement / evaluation system will be described.

5, the same reference numerals as those in FIG. 1 indicate the same members. Further, 51 is a power supply for applying a device voltage V _f to the device, 50 is an ammeter for measuring a device current I _f flowing through the conductive thin film 3 between the device electrodes 4, 5 ′, and 54 is an electron emitting portion. An anode electrode for capturing the emitted emission current I _e , 53 is a high voltage power source for applying a voltage to the anode electrode 54, 52 is an ammeter for measuring the emission current I _e , 55 is a vacuum device, 56 is an exhaust pump.

The surface conduction electron-emitting device, the anode electrode 54 and the like are installed in a vacuum device 55.
Is equipped with necessary equipment such as a vacuum system (not shown),
The surface conduction electron-emitting device can be measured and evaluated under a desired vacuum.

The exhaust pump 56 is composed of a normal high vacuum system such as a turbo pump and a rotary pump, and an ultra high vacuum system such as an ion pump.
The entire vacuum device 55 and the substrate 1 of the surface conduction electron-emitting device can be heated up to about 200 ° C. by a heater. It should be noted that this measurement / evaluation system uses a vacuum device 55 for the display panel and the inside thereof at the stage of assembling the display panel (see 201 in FIG. 8) as described later.
And, by being configured as the inside thereof, it can be applied to side evaluation and processing in the above-mentioned forming step, activation step and later steps to be described later.

The basic characteristics of the surface conduction electron-emitting device described below are that the voltage of the anode electrode 54 of the above measurement and evaluation system is 1 kV to 10 kV, and the distance H between the anode electrode 54 and the surface conduction electron-emitting device is 2 to 8 mm. It is based on the measurement performed as.

First, the emission current I _e and the device current I _f ,
FIG. 6 shows a typical example of the relationship with the device voltage V _f . still,
In FIG. 6, the emission current I _e is markedly smaller than the device current I _f, and therefore is shown in arbitrary units.

As is apparent from FIG. 6, the surface conduction electron-emitting device has the following three characteristic characteristics with respect to the emission current I _e .

First, in the surface conduction electron-emitting device, when a device voltage V _f higher than a certain voltage (called threshold voltage: V _{th in} FIG. 6) is applied, the emission current I _e rapidly increases. ,
On the other hand, at the threshold voltage V _th or less, the emission current I _e is hardly detected. That is, it is a non-linear element having a clear threshold voltage V _th with respect to the emission current I _e .

Secondly, since the emission current I _e has a characteristic of monotonically increasing with respect to the device voltage V _f (referred to as MI characteristic), the emission current I _e can be controlled by the device voltage V _f .

Thirdly, the emitted charge trapped in the anode electrode 54 (see FIG. 5) depends on the time for applying the device voltage V _f . That is, the amount of charges captured by the anode electrode 54 can be controlled by the time for which the device voltage V _f is applied.

The emission current I _e is MI with respect to the device voltage V _f .
At the same time having a characteristic, it may have a MI characteristic with respect to the device current I _f also the device voltage V _f. An example of the characteristics of such a surface conduction electron-emitting device is the characteristics shown by the solid line in FIG. On the other hand, as indicated by a broken line in FIG. 6, the device current _If is different from the device voltage _Vf in the voltage-controlled negative resistance characteristic (VCN).
R characteristics). Which characteristic is exhibited depends on the manufacturing method of the surface conduction electron-emitting device and the measurement conditions at the time of measurement. However, the element current I _f is equal to the element voltage V _f
On the other hand, even in the surface conduction electron-emitting device having the VCNR characteristic, the emission current I _e has the MI characteristic with respect to the device voltage V _f .

Next, the arrangement of the surface conduction electron-emitting devices in the electron source of the present invention will be described.

As a method of arranging the surface conduction electron-emitting devices in the electron source of the present invention, in addition to the ladder arrangement as described in the section of the prior art, there are n Ys on m X-directional wirings. There is an arrangement method in which directional wirings are provided via an interlayer insulating layer and an X-direction wiring and a Y-direction wiring are connected to a pair of device electrodes of a surface conduction electron-emitting device, respectively. This is hereinafter referred to as a simple matrix arrangement. First, this simple matrix arrangement will be described in detail.

According to the basic characteristics of the surface conduction electron-emitting device described above, the emitted electrons in the surface conduction electron-emitting device arranged in the simple matrix are generated between the opposing device electrodes at a voltage exceeding the threshold voltage. It can be controlled by the peak value and pulse width of the applied pulsed voltage. On the other hand, almost no electrons are emitted below the threshold voltage. Therefore, even when a large number of surface conduction electron-emitting devices are arranged, if the pulsed voltage is appropriately applied to each device, the surface conduction electron-emitting device is selected according to the input signal and the electron emission amount thereof is selected. Can be controlled, and individual surface conduction electron-emitting devices can be selected and driven independently by simple matrix wiring.

The simple matrix arrangement is based on such a principle, and the structure of the electron source having the simple matrix arrangement, which is an example of the electron source of the present invention, will be further described with reference to FIG.

In FIG. 7, the substrate 1 is a glass plate or the like as already described, and the number and shape of the surface conduction electron-emitting devices 104 arranged on the substrate 1 are set appropriately according to the application. is there.

The m wirings in the X direction 102 have external terminals D _x1 , D _x2 , ..., D _xm , respectively.
It is a conductive metal or the like formed by a vacuum deposition method, a printing method, a sputtering method, or the like. In addition, a large number of surface conduction electron-emitting devices 10
4 so that the voltage is supplied to the 4 substantially evenly, the material, the film thickness,
The wiring width is set.

The n Y-direction wirings 103 have external terminals D _y1 , D _y2 , ..., D _yn , respectively.
It is created in the same way as 02.

These m X-direction wirings 102 and n Y-wirings
An interlayer insulating layer (not shown) is provided between the directional wirings 103 and electrically separated to form a matrix wiring. In addition, both m and n are positive integers.

The interlayer insulating layer (not shown) is SiO ₂ or the like formed by a vacuum deposition method, a printing method, a sputtering method or the like, and has a desired shape on the entire surface or a part of the substrate 1 on which the X-direction wiring 102 is formed. In particular, the film thickness, material, and manufacturing method are appropriately set so as to withstand the potential difference at the intersection of the X-direction wiring 102 and the Y-direction wiring 103.

Furthermore, the opposing device electrodes (not shown) of the surface conduction electron-emitting device 104 are m number of X-direction wirings 102.
, N Y-direction wirings 103, a vacuum deposition method, a printing method,
Connection 1 made of a conductive metal or the like formed by a sputtering method or the like
05 are electrically connected.

Here, even if some or all of the constituent elements of the m X-direction wirings 102, the n Y-direction wirings 103, the connection lines 105, and the opposing element electrodes are the same, Further, they may be different from each other, and are appropriately selected from the above-mentioned material of the element electrode and the like. Wirings to these element electrodes may be collectively referred to as element electrodes when the same material as the element electrodes is used. In addition, the surface conduction electron-emitting device 104
May be formed either on the substrate 1 or on an interlayer insulating layer (not shown).

Further, as will be described later in detail, a scanning signal is applied to the X-direction wiring 102 in order to scan the rows of the surface conduction electron-emitting devices 104 arranged in the X-direction according to an input signal. A scanning signal applying means (not shown) is electrically connected.

On the other hand, a modulation signal (not shown) is applied to the Y-direction wiring 103 in order to modulate each row of the surface conduction electron-emitting devices 104 arranged in the Y-direction according to an input signal. The signal generating means is electrically connected. Further, the drive voltage applied to each surface conduction electron-emitting device 104 is supplied as a difference voltage between the scanning signal and the modulation signal applied to the surface conduction electron-emitting device 104.

Next, an example of the image forming apparatus of the present invention using the electron source of the present invention having the above simple matrix arrangement will be described with reference to FIGS. Note that FIG. 8 is a basic configuration diagram of the display panel 201, FIG. 9 is a diagram showing the fluorescent film 114, and FIG. 10 is the display panel 201 of FIG.
It is a block diagram showing an example of a drive circuit for performing a television display according to a television signal of a TSC system.

In FIG. 8, 1 is a substrate of an electron source in which the surface conduction electron-emitting devices are arranged as described above, 111 is a rear plate to which the substrate 1 is fixed, and 116 is a glass substrate 1.
A face plate having a fluorescent film 114, a metal back 115 and the like formed on the inner surface of 13 and a support frame 112. Frit glass or the like is applied to the rear plate 111, the support frame 112, and the face plate 116, and the atmosphere or nitrogen is used. Then, the envelope 118 is configured by sealing by baking at 400 to 500 ° C. for 10 minutes or more.

In FIG. 8, 2 corresponds to the electron emitting portion in FIG. Reference numerals 102 and 103 denote X-direction wiring and Y-direction wiring connected to the pair of device electrodes 4 and 5 of the surface conduction electron-emitting device 104, respectively, and are external terminals D _{x1 to} D _xm and D _{y1 respectively.}
˜D _yn .

The envelope 118 is composed of the face plate 116, the support frame 112 and the rear plate 111 as described above. However, the rear plate 111 is provided mainly for the purpose of reinforcing the strength of the substrate 1, and when the substrate 1 itself has sufficient strength, the separate rear plate 111 is not necessary, and the rear plate 111 is directly supported on the substrate 1. 112 is sealed,
The envelope 118 may be composed of the face plate 116, the support frame 112, and the substrate 1. Further, by further installing a support body (not shown) called a spacer between the face plate 116 and the rear plate 111, it is possible to form the envelope 118 having sufficient strength against atmospheric pressure.

In the case of monochrome, the fluorescent film 114 is composed of only the phosphor 122, but in the case of the color fluorescent film 114, depending on the arrangement of the phosphors 122, a black stripe (FIG. 9A) or a black matrix (FIG. 9) is used. 9
(B)) Black conductive material 121 and phosphor 122, etc.
Composed of and. The purpose of providing the black stripes and the black matrix is to make the color mixture, etc., inconspicuous by making the coating portions between the phosphors 122 of the three primary colors necessary for color display black, and to reflect external light on the phosphor film 114. This is to suppress the decrease in contrast due to. As the material of the black conductive material 121, not only a commonly used material containing graphite as a main component, but also another material may be used as long as it is conductive and has little light transmission and reflection. it can.

As a method of applying the phosphor 122 to the glass substrate 113, a precipitation method or a printing method is used regardless of monochrome or color.

Further, as shown in FIG.
A metal back 115 is usually provided on the inner surface side of 4.
The purpose of the metal back 115 is to improve the brightness by specularly reflecting the light to the inner surface side of the light emission of the phosphor 122 (see FIG. 9) to the glass substrate 113 side, and to apply an electron beam acceleration voltage. Acting as an electrode,
For example, protection of the phosphor 122 from damage due to collision of negative ions generated in the envelope 118. Metal back 1
15 can be manufactured by performing smoothing processing (usually called filming) on the inner surface of the fluorescent film 114 after manufacturing the fluorescent film 114, and then depositing Al by vacuum evaporation or the like.

The face plate 116 may be provided with a transparent electrode (not shown) on the outer surface side of the fluorescent film 114 in order to further enhance the conductivity of the fluorescent film 114.

At the time of performing the above-mentioned sealing, in the case of a color, the phosphors 122 of the respective colors and the surface conduction electron-emitting device 104 must correspond to each other, so that it is necessary to perform sufficient alignment.

The inside of the envelope 118 is sealed to a vacuum degree of about 1 × 10 ⁻⁷ torr through an exhaust pipe (not shown). Also, the getter process may be performed immediately before or after the envelope 118 is sealed. This is a process of heating a getter (not shown) arranged at a predetermined position in the envelope 118 to form a vapor deposition film. The getter usually has Ba or the like as a main component, and is for maintaining a vacuum degree of, for example, 1 × 10 ⁻⁵ to 1 × 10 ⁻⁷ torr by the adsorption action of the vapor deposition film.

The above-described forming process and the subsequent manufacturing process of the surface conduction electron-emitting device are usually performed immediately before or after the encapsulation of the envelope 118, and the contents thereof are as described above. is there.

The above-mentioned display panel 201 is shown in FIG.
It can be driven by a driving circuit as shown in FIG.
In FIG. 10, 201 is a display panel, 202 is a scanning circuit, 203 is a control circuit, 204 is a shift register,
205 is a line memory, 206 is a sync signal separation circuit, 2
Reference numeral 07 is a modulation signal generator, and V _x and V _a are DC voltage sources.

As shown in FIG. 10, the display panel 20
1 is connected to an external electric circuit via the external terminals D _{x1 to} D _xm , the external terminals D _{y1 to} D _yn, and the high voltage terminal Hv.
Of these, the external terminals D _{x1 to} D _xm are connected to the display panel 201.
A scanning signal for sequentially driving the surface conduction electron-emitting devices provided therein, that is, the group of surface conduction electron-emitting devices arranged in a matrix of m rows and n columns in one row (n elements at a time). Is applied.

On the other hand, a modulation signal for controlling the output electron beam of each surface conduction electron-emitting device of one row selected by the scanning signal is applied to the external terminals D _{y1 to} D _yn . Further, a DC voltage of, for example, 10 kV is supplied from the DC voltage source V _a to the high voltage terminal Hv. This is an accelerating voltage for giving enough energy to excite the phosphor to the electron beam output from the surface conduction electron-emitting device.

The scanning circuit 202 is provided with m switching elements (schematically shown by S _{1 to} S _m in FIG. 10) inside, and each switching element S _{1 to} S _m is a DC voltage power supply V _x. Output voltage or 0 V (ground level) is selected and electrically connected to the external terminals D _{x1 to} D _{xm of} the display panel 201. Each of the switching elements S _{1 to} S _m operates based on the control signal T _scan output from the control circuit 203, and in practice, is easily configured by combining elements having a switching function such as FETs. It is possible.

The DC voltage source V _x in this example is driven by a drive voltage applied to an unscanned surface conduction electron-emitting device based on the characteristics (threshold voltage) of the surface conduction electron-emitting device. It is set to output a constant voltage that is less than or equal to the threshold voltage.

The control circuit 203 has a function of matching the operation of each part so that an appropriate display is performed based on an image signal input from the outside. Then, based on the synchronization signal T _sync sent from the synchronous signal separation circuit 206 to be described, T _{sc an,} to each unit, for generating a respective control signal T _sft and T _mry.

The sync signal separation circuit 206 is a circuit for separating a sync signal component and a luminance signal component from an NTSC television signal input from the outside, and as is well known, a frequency separation (filter). If you use a circuit,
It can be easily constructed. Sync signal separation circuit 206
As is well known, the sync signal separated by is composed of a vertical sync signal and a horizontal sync signal. here,
For convenience of explanation, it is shown as T _sync . Meanwhile, the luminance signal component of the image separated from the television signal is DAT for convenience.
A signal is illustrated. This DATA signal is input to the shift register 204.

The shift register 204 is for converting the DATA signal serially input in time series into serial / parallel conversion for each line of the image, and based on the control signal T _sft sent from the control circuit 203. Works. In other words, the control signal T _sft is the shift clock of the shift register 204. The data of one line of the serial / parallel-converted image (corresponding to the driving data of n elements of the surface conduction electron-emitting device) is converted into n parallel signals I _{d1 to} I _dn as the shift register 204. Will be output.

The line memory 205 is a storage device for storing data for one line of an image for a required time,
The contents of I _{d1 to} I _dn are appropriately stored according to the control signal T _mry sent from the control circuit 203. The stored content is I
_The signals are output as _{d'1 to} I _d'n and input to the modulation signal generator 207.

The modulation signal generator 207 is a signal source for appropriately driving and modulating each of the surface conduction electron-emitting devices in accordance with each of the image data I _{d'1 to} I _d'n , and outputs the signal. The signals are _transmitted through the terminals _{Doy1 to Doyn} to the display panel 20.
1 is applied to the surface conduction electron-emitting device.

As described above, the surface conduction electron-emitting device has a clear threshold voltage for electron emission, and electron emission occurs only when a voltage exceeding the threshold voltage is applied. Further, for a voltage exceeding the threshold voltage, the emission current also changes according to the change in the voltage applied to the surface conduction electron-emitting device. Material of surface conduction electron-emitting device,
The value of the threshold voltage and the degree of change of the emission current with respect to the applied voltage may change by changing the configuration and the manufacturing method. In any case, the following can be said.

That is, when a pulsed voltage is applied to the surface conduction electron-emitting device, no electron emission occurs even if a voltage below the threshold voltage is applied, but a voltage exceeding the threshold voltage is applied. If it does, electron emission occurs. At that time, firstly, it is possible to control the intensity of the output electron beam by changing the peak value of the voltage pulse. Secondly, it is possible to control the total amount of charges of the output electron beam by changing the width of the voltage pulse.

Therefore, as a method of modulating the surface conduction electron-emitting device according to the input signal, there are a voltage modulation method and a pulse width modulation method. In the case of performing the voltage modulation method, the modulation signal generator 207 uses a voltage modulation method circuit that generates a voltage pulse of a constant length, but can appropriately modulate the pulse peak value according to the input data. In the case of performing the pulse width modulation method, the modulation signal generator 207 generates a voltage pulse having a constant peak value, but a circuit of the pulse width modulation method capable of appropriately modulating the pulse width according to the input data is used. To use.

The shift register 204 and the line memory 20
5 may be of a digital signal type or an analog signal type as long as it can perform serial / parallel conversion and storage of an image signal at a predetermined speed.

When the digital signal type is used, it is necessary to convert the output signal DATA of the sync signal separation circuit 206 into a digital signal. This can be done by providing an A / D converter at the output of the sync signal separation circuit 206.

Further, in connection with this, the line memory 20
Depending on whether the output signal of 5 is a digital signal or an analog signal,
The circuit provided in the modulation signal generator 207 is slightly different.

That is, in the case of the voltage modulation method using a digital signal, for example, a well-known D / A conversion circuit may be used as the modulation signal generator 207, and an amplification circuit or the like may be added if necessary. Further, in the case of a pulse width modulation method using a digital signal, the modulation signal generator 207, for example, a high-speed oscillator and a counter (counter) that counts the number of waves output by the oscillator, and the output value of the counter and the output value of the memory. It can be easily configured by using a circuit in which comparators for comparison are combined. Further, if necessary, an amplifier for voltage-amplifying the pulse-width-modulated modulation signal output from the comparator to the drive voltage of the surface conduction electron-emitting device may be added.

On the other hand, in the case of the voltage modulation method using an analog signal, the modulation signal generator 207 may be, for example, an amplifier circuit using a well-known operational amplifier or the like, and a level shift circuit or the like may be added if necessary. May be. Further, in the case of the pulse width modulation method using an analog signal, for example, a well-known voltage controlled oscillation circuit (VCO) may be used, and the voltage is amplified to the drive voltage of the surface conduction electron-emitting device as necessary. May be added.

In the image forming apparatus of the present invention having the display panel 201 and the driving circuit as described above, necessary surface conduction type electron emission is obtained by applying a voltage from the terminals D _{x1 to} D _xm and D _{y1 to} D _yn. Electrons can be emitted from the device, a high voltage is applied to the metal back 115 or a transparent electrode (not shown) through the high voltage terminal Hv to accelerate the electron beam, and the accelerated electron beam collides with the fluorescent film 114. By the excitation / light emission generated in (1), television display can be performed according to an NTSC system television signal.

The above-described structure is a schematic structure necessary for obtaining the image forming apparatus of the present invention used for display or the like, and the detailed parts such as the material of each member are limited to the above contents. However, it is appropriately selected so as to suit the purpose of the image forming apparatus. Further, although the NTSC system has been described as the input signal, the image forming apparatus according to the present invention is not limited to this, and other systems such as PAL and SECAM systems may be used, and more scanning lines than these may be used. It is also possible to use a high-definition TV system such as a TV signal such as the MUSE system.

Next, an example of the above-mentioned ladder-type electron source and an image forming apparatus of the present invention using the electron source will be described with reference to FIGS. 11 and 12.

In FIG. 11, 1 is a substrate, 104 is a surface-conduction electron-emitting device, and 304 is a common wiring for connecting the surface-conduction electron-emitting device 104. Ten external wires D _{1 to} D ₁₀ are provided. have.

The surface conduction electron-emitting device 104 is the substrate 1
A plurality of them are arranged in parallel on the top. This is called an element row. A plurality of these element rows are arranged to form an electron source.

Each element row can be independently driven by applying an appropriate drive voltage between the common wiring 304 of each element row (for example, the common wiring 304 of the external terminals D ₁ and D ₂ ). That is, a voltage exceeding the threshold voltage may be applied to the element row where the electron beam is desired to be emitted, and a voltage lower than the threshold voltage may be applied to the element row where the electron beam is not desired to be emitted. Application of the driving voltage, the common wiring D ₂ to D ₉ located at each element rows, the external terminals D ₂ and D ₃ adjacent common wiring 304, i.e. each phase adjacent each phase, D ₄ and D ₅ , D ₆ and D ₇ , and D ₈ and D ₉ common wiring 304 can be integrated into the same wiring.

FIG. 11 is a diagram showing the structure of a display panel 301 having the above-mentioned ladder-type electron source, which is another example of the electron source of the present invention.

In FIG. 11, 302 is a grid electrode, 303 is an opening through which electrons pass, D _{1 to} D _m are external terminals for applying a voltage to each surface conduction electron-emitting device, and G ₁ to
G _n is an external terminal connected to the grid electrode 302. Further, the common wiring 304 between each element row is formed on the substrate 1 as an integrated single wiring.

In FIG. 12, the same reference numerals as those in FIG. 8 indicate the same members, and a big difference from the display panel 201 using the electron source of the simple matrix arrangement shown in FIG. The point is that the grid electrode 302 is provided between 116.

The grid electrode 302 is provided between the substrate 1 and the face plate 116 as described above. The grid electrode 302 is capable of modulating the electron beam emitted from the surface conduction electron-emitting device 104, and the electron beam is applied to the stripe-shaped electrode provided orthogonal to the device row in the ladder-type arrangement. To pass
A circular opening 303 is provided for each of the surface conduction electron-emitting devices 104.

The shape and arrangement position of the grid electrode 302 are
It does not necessarily have to be the one shown in FIG. 12, and a large number of openings 303 may be provided in a mesh shape, and the grid electrode 302 may be provided, for example, around or near the surface conduction electron-emitting device 104. Good.

The external terminals D _{1 to} D _m and G _{1 to} G _n are connected to a drive circuit (not shown). Then, by applying a modulation signal for one image line to the columns of the grid electrode 302 in synchronization with the sequential driving (scanning) of the element rows one column at a time, irradiation of each electron beam to the fluorescent film 114 is performed. The image can be displayed line by line.

As described above, the image forming apparatus of the present invention is
An image formation that can be obtained by using the electron source of the present invention in either a simple matrix arrangement or a trapezoidal arrangement and is suitable not only as a display device for the television broadcast described above but also as a display device for a video conference system, a computer, or the like. The device is obtained. Further, it can also be used as an exposure device of an optical printer configured with a photosensitive drum.

[0122]

【Example】

Example 1 As a first example of the present invention, the surface conduction electron-emitting device shown in FIG. 1 was manufactured according to the process of FIG. The manufacturing procedure will be specifically described below.

(1) As the substrate 1, a quartz substrate is thoroughly washed with a detergent, pure water and an organic solvent. A resist mask is formed on the surface of the insulating substrate 1 by a photolithography technique, and then P is used as a device electrode material by a vacuum deposition method.
After t was deposited by 1000Å, the device electrodes 4 and 5 were formed by lift-off (FIG. 3A). In this embodiment, the element electrode interval L is 2 μm, and the element electrode length W is 300 μm.
m and the film thickness d were 1000Å.

(2) A Cr film is formed on the entire surface of the substrate 1 by a vacuum evaporation method, and a resist film is further formed on the entire surface. Expose using an exposure mask that gives the desired pattern,
A resist pattern is formed, and by using it, Cr
Form the pattern of the film. An organic metal solution, in which organic Pd (ccp; manufactured by Okuno Chemical Industries Co., Ltd.) was dissolved in a butyl acetate solution, was applied thereon by a spinner coating method, heated at 150 ° C. for 10 minutes, and the first layer of organic metal solution A thin film was formed. Similarly, application and heating were repeated 4 times to deposit an organometallic thin film. Then, the substrate was put in an oven and heated and baked at 300 ° C. for 60 minutes in the atmosphere. As a result, the organic Pd film was decomposed and oxidized into a PdO fine particle film. After that, the Cr film is removed by the lift-off method, and the conductive thin film 3 for forming the electron emission portion is formed at a predetermined position (FIG. 3B).

(3) Subsequently, the electroconductive thin film 3 is subjected to a forming treatment to form the electron emitting portion 2 (FIG. 3).
(C)). The forming uses a triangular wave pulse, about 1 ×
It was performed for 60 seconds in a vacuum atmosphere of 10 ⁻⁶ torr. The peak value of the triangular wave was 5 V at maximum, the pulse width was 1 msec, and the pulse interval was 10 msec.

The electron emission characteristics of the surface conduction electron-emitting device of this example produced as described above were measured by the measurement evaluation system shown in FIG. The voltage of the anode electrode is 1 kV,
The distance H between the anode electrode and the element is 4 mm, 1 × 10 ⁻⁵
It was performed under a vacuum of not less than torr.

As a result, in the surface conduction electron-emitting device of this example, electrons started to be rapidly emitted at the device voltage of about 8 V, and
At V, the current I _f flowing through the device is 2 mA and I _e is 1 μA.
The electron emission efficiency I _e / I _f was 0.05%.

Example 2 An image forming apparatus having the simple matrix type display panel shown in FIG. 8 was manufactured. A plan view of a part of the electron source is shown in FIG. 14 is a cross-sectional view taken along the line AA 'in FIG. Furthermore, a method of manufacturing the electron source of this embodiment is shown in FIGS. However,
13 to 16 indicate the same members. In the figure, 1 is a substrate, 102 is a lower wiring in the X direction, 103 is an upper wiring in the Y direction, 3 is a conductive thin film, 4 and 5 are element electrodes, 141 is an interlayer insulating layer, 142 is an element electrode. 5 is a contact hole for electrical connection between the X-direction wiring 102 and 161 is a Cr film. Hereinafter, the manufacturing process will be specifically described in the order of processes.

Step-a On a substrate 1 in which a 0.5 μm-thick silicon oxide film is formed on a cleaned blue plate glass by a sputtering method, Cr having a thickness of 50 Å and Au having a thickness of 6000 Å are sequentially laminated by vacuum evaporation. After that, a photoresist (AZ1370; manufactured by Hoechst) is spin-coated by a spinner and baked, and then a photomask image is exposed and developed to form a resist pattern of the X-direction wiring 102, and an Au / Cr deposited film is wet. Etching is performed to form the X-direction wiring 102 having a desired shape (FIG. 15A).

Step-b Next, an interlayer insulating layer 141 made of a silicon oxide film having a thickness of 1.0 μm is deposited by the RF sputtering method (FIG. 15).
(B)).

Step-c Contact hole 1 is formed in the silicon oxide film deposited in Step b.
A photoresist pattern for forming 42 is formed, and the interlayer insulating layer 141 is etched using this as a mask to form a contact hole 142. The etching is RIE (Reactive) using CF ₄ and H ₂ gas.
Ion Etching) method. (Fig. 15
(C)).

Step-d A photoresist (RD-2000N-41; manufactured by Hitachi Chemical Co., Ltd.) was formed on the pattern to form the device electrodes 4 and 5 and the device electrode gap L, and Ti having a thickness of 50 Å was formed by a vacuum deposition method.
Ni having a thickness of 1000Å was sequentially deposited. The photoresist pattern was dissolved in an organic solvent and the Ni / Ti deposited film was lifted off to form device electrodes 4 and 5 having a device electrode gap L of 2 μm and a device electrode width W of 220 μm (FIG. 15).
(D)).

Step-e After forming a photoresist pattern for Y-direction wiring on the device electrodes 4 and 5, Ti with a thickness of 50Å and Au with a thickness of 5000Å are sequentially deposited by vacuum evaporation, and unnecessary portions are lifted off. After removal, the Y-direction wiring 103 having a desired shape was formed (FIG. 16E).

Step-f A Cr film 161 having a film thickness of 1000 Å is deposited and patterned by vacuum evaporation using a mask having an element electrode gap L and an opening in the vicinity thereof, and an organic Pd film is formed thereon under the same conditions as in Example 1. A 35Å coating was formed (FIG. 16 (f)).

Step-g The Cr film 161 is etched with an acid etchant to form C
By lifting off the organic Pd film on the r film 161, an acetic acid Pd film having a desired pattern was formed. Next, Example 1
In the same manner as the above, heat treatment and oxidation were performed to form the conductive thin film 3.
The width of the thin film is 100 μm. The fine particles of the conductive thin film 3 made of fine particles of Pd as the main element thus formed had an average particle diameter of 30 nm, a film thickness of 100 Å, and a sheet resistance value of 5 × 10 ⁴ Ω / □ (FIG. 16 (g )).

Process-h A pattern is formed so as to apply a resist other than the contact hole 142, and a 50 T thick T film is formed by vacuum evaporation.
i, 5000 Å thick Au were sequentially deposited. Contact holes 142 were buried by removing unnecessary portions by lift-off (FIG. 16 (h)).

Through the above steps, the X-direction wiring 102, the interlayer insulating layer 211, the Y-direction wiring 103, the device electrodes 4, 5 and the conductive thin film 3 were formed on the insulating substrate 1.

With the electron source manufactured as described above, as shown in FIG.
The display panel shown in 1 was constructed and an image forming apparatus was produced.

After fixing the unformed electron source substrate 1 produced in the above process to the rear plate 111, the electron source 1
5 mm above, a face plate 116 (a fluorescent film 114 and a metal back 116 are formed on the inner surface of the glass substrate 113) is sufficiently aligned and arranged via a support frame 112, and the face plate 116 is supported. Frame 11
2. Frit glass was applied to the joint portion of the rear plate 111, and baked at 400 ° C. to 500 ° C. for 10 minutes or more in the air to seal the frit glass. Further, the frit glass was used to fix the electron source substrate 1 to the rear plate 111.

In this embodiment, the phosphor has a stripe shape (see FIG. 9A), the black stripe is made of a material containing graphite as a main component, and the glass substrate 11 is used.
A slurry method was used as a method for applying a phosphor to No. 3.

Further, the metal back 115 provided on the inner surface side of the fluorescent film 114 is subjected to a smoothing process (filming) on the inner surface side of the fluorescent film after the fluorescent film is produced, and then A
1 was vacuum-deposited. Face plate 1
16 may be provided with a transparent electrode on the outer surface side of the fluorescent film 114 in order to further increase the conductivity of the fluorescent film 114, but in this embodiment, sufficient conductivity was obtained only with the metal back 115. Omitted.

The atmosphere in the glass container completed as described above is exhausted by a vacuum pump through an exhaust pipe (not shown), and after reaching a sufficient degree of vacuum, the terminals D _{x1 to} D _xm to D _{y1 of the} container are reached. A voltage was applied between the device electrodes through D _yn to perform a forming process to form an electron emitting portion. At this time, the voltage waveform of the forming process is the same as that in FIG.
T ₁ was 1 msec, T ₂ was 10 msec, and the peak value of the triangular wave was 15 V, and the measurement was performed in a vacuum atmosphere of 1 × 10 ⁻⁶ torr.

The electron-emitting portion manufactured in this way is made of Pd.
Fine particles containing the element as a main component were dispersed and arranged, and the average particle diameter of the fine particles was 30Å.

Next, at a vacuum degree of about 1 × 10 ^−6.5 torr, an unillustrated exhaust pipe was heated and fused by a gas burner to seal the envelope 118.

Finally, in order to maintain the degree of vacuum after sealing, a getter process was performed by a high frequency heating method.

The container of the display panel manufactured as described above, the terminals D _{x1 to} D _xm to D _{y1 to} D _yn , and the high-voltage terminal H
Each v was connected to a required drive system to complete the image forming apparatus. Each surface conduction electron-emitting device has a container D _x1
It is no D _xm through D _y1 to D _yn, applied by applying respectively by the scan signal and a modulation signal (not shown) signal generating means performs electron emission through the high voltage terminal Hv, a high voltage of several kV to the metal back 115 Then, the electron beam was accelerated, collided with the fluorescent film 114, and excited and emitted to display a good image.

[Embodiment 3] FIG. 17 is an example of a display device in which the image forming apparatus of Embodiment 1 is configured to display image information provided from various image information sources such as television broadcasting. It is a figure for showing. 2 in the figure
80 is a display panel, 261 is a display panel drive circuit, 262 is a display controller, 2
63 is a multiplexer, 264 is a decoder, 265 is an input / output interface circuit, 266 is a CPU, 267 is an image generation circuit, 268, 269 and 270 are image memory interface circuits, 271 is an image input interface circuit, 272 and 273 are TV signal reception. Circuit, 27
Reference numeral 4 is an input unit. It should be noted that when the display device receives a signal including both video information and audio information, such as a television signal, it naturally reproduces audio at the same time as displaying video. Descriptions of circuits, speakers, etc. relating to reception, separation, reproduction, processing, storage, etc. of audio information not directly related to are omitted.

The respective parts will be described below along the flow of the image signal.

First, the TV signal receiving circuit 273 is a circuit for receiving a TV image signal transmitted using a wireless transmission system such as radio waves or spatial optical communication. The system of the TV signal to be received is not particularly limited, and various systems such as NTSC system, PAL system and SECAM system may be used. Further, a TV signal (for example, a so-called high-definition TV such as the MUSE method) including a larger number of scanning lines than these is suitable for taking advantage of the display panel suitable for a large area and a large number of pixels. It is a signal source. TV received by the TV signal receiving circuit 273
The signal is output to the decoder 264.

The image TV signal receiving circuit 272 is a circuit for receiving a TV image signal transmitted using a wired transmission system such as a coaxial cable or an optical fiber. Similar to the TV signal receiving circuit 273, the TV signal system to be received is not particularly limited, and the TV signal received by this circuit is also output to the decoder 264.

Further, the image input interface circuit 27
Reference numeral 1 denotes a circuit for capturing an image signal supplied from an image input device such as a TV camera or an image reading scanner, and the captured image signal is output to the decoder 264.

Further, the image memory interface circuit 2
70 is a video tape recorder (hereinafter abbreviated as VTR)
The circuit for fetching the image signal stored in is output to the decoder 264.

The image memory interface circuit 2
Reference numeral 69 denotes a circuit for capturing the image signal stored in the video disc, and the captured image signal is output to the decoder 264.

The image memory-interface circuit 268 is a circuit for fetching an image signal from a device that stores still image data, such as a so-called still image disc. The fetched still image data is decoded by the decoder 26.
4 is output.

Further, the input / output interface circuit 265
Is a circuit for connecting the display device to an external computer, a computer network, or an output device such as a printer. It is of course possible to input / output image data and character / graphic information, and in some cases, input / output control signals and numerical data between the CPU 266 of the display device and the outside.

Further, the image generation circuit 267 receives image data, character / graphic information, or CPU 266 input from the outside through the input / output interface circuit 265.
It is a circuit for generating display image data based on image data and character / graphic information output from the output. Inside this circuit, for example, a rewritable memory for accumulating image data and character / graphic information, a read-only memory that stores image patterns corresponding to character codes,
The circuits necessary for image generation, such as a processor for image processing, are incorporated.

The display image data generated by this circuit is output to the decoder 264, but in some cases, it can be output to an external computer network or printer via the input / output interface circuit 265.

Further, the CPU 266 mainly performs operations related to operation control of the display device and generation, selection and editing of a display image.

For example, a control signal is output to the multiplexer 263, and the image signals to be displayed on the display panel 280 are appropriately selected or combined. At that time, a control signal is generated for the display panel controller 262 according to the image signal to be displayed, and the screen display frequency, the scanning method (for example, interlaced or non-interlaced), the number of scanning lines in one screen, etc. are displayed. The operation of the device is controlled appropriately.

Image data or character / graphic information is directly output to the image generation circuit 267, or an external computer or memory is accessed via the input / output interface circuit 265 to generate image data or character / figure information.
Enter graphic information.

It should be noted that the CPU 266 may of course be involved in work for other purposes. For example, like a personal computer or word processor,
It may be directly related to the function of generating and processing information.

Alternatively, as described above, it may be connected to an external computer network through the input / output interface circuit 265, and work such as numerical calculation may be performed in cooperation with an external device.

The input unit 274 is the CPU 266.
The user inputs commands, programs, data, and the like, and various input devices such as a joystick, a bar code reader, and a voice recognition device can be used in addition to a keyboard and a mouse.

The decoder 264 converts various image signals input from the above 267 to 273 into three primary color signals,
Alternatively, it is a circuit for inverse conversion into a luminance signal, an I signal, and a Q signal. In addition, as shown by a dotted line in FIG.
It is preferable that 64 has an image memory therein. This is to handle a television signal that requires an image memory for reverse conversion, such as the MUSE method. Further, the provision of the image memory facilitates the display of a still image, or the image generation circuit 26.
This is because, in cooperation with the CPU 7 and the CPU 266, there is an advantage that image processing and editing such as image thinning, interpolation, enlargement, reduction, and composition can be easily performed.

Also, the multiplexer 263 is the CPU
The display image is appropriately selected based on the control signal input from 266. That is, the multiplexer 263 selects a desired image signal from the inversely converted image signals input from the decoder 264 and outputs it to the drive circuit 261. In that case, by switching and selecting image signals within one screen display time, it is possible to divide one screen into a plurality of areas and display different images depending on the areas, as in a so-called multi-screen television. .

Also, the display panel controller 2
Reference numeral 62 is a circuit for controlling the operation of the drive circuit 261 based on a control signal input from the CPU 266.

First, regarding the basic operation of the display panel, for example, a signal for controlling the operation sequence of the drive power source (not shown) for the display panel is output to the drive circuit 261.

Further, regarding the driving method of the display panel, for example, a signal for controlling the screen display frequency and the scanning method (for example, interlace or non-interlace) is output to the drive circuit 261.

In some cases, control signals relating to image quality adjustment such as brightness, contrast, color tone and sharpness of a display image may be output to the drive circuit 261.

The drive circuit 261 is a circuit for generating a drive signal to be applied to the display panel 280. The drive circuit 261 outputs an image signal input from the multiplexer 263 and a control signal input from the display panel controller 262. It operates based on.

The function of each unit has been described above. With the configuration illustrated in FIG. 17, the display panel 2 displays image information input from various image information sources in this display device.
70 can be displayed. That is, various image signals such as television broadcasts are inversely converted by the decoder 264, appropriately selected by the multiplexer 263, and input to the drive circuit 261. On the other hand, the display controller 262 generates a control signal for controlling the operation of the drive circuit 261 according to the image signal to be displayed. The drive circuit 261 applies a drive signal to the display panel 280 based on the image signal and the control signal. As a result, the image is displayed on the display panel 280. These series of operations are performed by the CPU 2
It is totally controlled by 66.

Further, in this display device, an image memory built in the decoder 264 and an image generation circuit 267 are provided.
With the involvement of the CPU 266, not only the selected one of the plurality of image information is displayed, but also the image information to be displayed is enlarged, reduced, rotated, moved, edge emphasized, thinned, interpolated, or the like. It is also possible to perform image processing such as color conversion and aspect ratio conversion of images, and image editing such as combining, erasing, connecting, replacing, and fitting. Further, in the description of this embodiment,
Although not particularly mentioned, a dedicated circuit for processing and editing audio information may be provided as in the above-mentioned image processing and image editing.

Therefore, the display device is a display device for television broadcasting, a terminal device for video conference, an image editing device for handling still images and moving images, a computer terminal device, an office terminal device such as a word processor, and a game. It is possible to combine the functions of a machine, etc., and has a very wide range of applications for industrial or consumer use.

It is needless to say that FIG. 17 shows only an example of the image forming apparatus of the present invention, and the present invention is not limited to this. For example, of the constituent elements of FIG. 17, circuits relating to functions that are unnecessary for the purpose of use may be omitted. On the contrary, the constituent elements may be added depending on the purpose of use. For example, when the display device is applied as a videophone, it is preferable to add a television camera, a voice microphone, an illuminator, a transmission / reception circuit including a modem, and the like to the constituent elements.

In this display device, in particular, since it is easy to thin the display panel using the surface conduction electron-emitting device as an electron source, the depth of the display device can be reduced. In addition, a display panel using surface conduction electron-emitting devices as an electron source can easily make a large screen, has high brightness, and has excellent viewing angle characteristics, so that this display device provides a realistic and powerful image. It can be displayed well.

Further, since the electron source of the present invention has uniform electron emission characteristics among the surface conduction electron-emitting devices, the quality of the image formed is high and a high-definition image can be displayed. .

[0177]

As described above, according to the present invention, the conductive thin film can be formed by the conventional coating method without damaging the substrate in the manufacturing process of the surface conduction electron-emitting device. The reliability and the yield in the manufacturing of an electron source including an electron-emitting device and a plurality of surface-conduction electron-emitting devices, and an image forming apparatus using the electron source are improved.

[Brief description of drawings]

FIG. 1 is a cross-sectional view showing an embodiment of a surface conduction electron-emitting device of the present invention.

FIG. 2 is a cross-sectional view showing another embodiment of the surface conduction electron-emitting device of the present invention.

FIG. 3 is a diagram showing an example of a manufacturing process of a surface conduction electron-emitting device of the present invention.

FIG. 4 is a diagram showing a voltage waveform of an energization process for manufacturing the surface conduction electron-emitting device of the present invention.

FIG. 5 is a diagram showing a measurement evaluation system for evaluating electron emission characteristics of the surface conduction electron-emitting device of the present invention.

FIG. 6 is a diagram showing electron emission characteristics of the surface conduction electron-emitting device of the present invention.

FIG. 7 is a schematic diagram of a simple matrix electron source of the present invention.

FIG. 8 is a diagram showing an embodiment of a display panel of the image forming apparatus of the present invention.

FIG. 9 is a diagram showing a fluorescent film used in the image forming apparatus of the present invention.

FIG. 10 is a block diagram of an embodiment of the image forming apparatus of the present invention.

FIG. 11 is a schematic view of a ladder type electron source of the present invention.

FIG. 12 is a diagram showing a display panel of an image forming apparatus of the present invention using a ladder type electron source.

FIG. 13 is a diagram showing an electron source used in the image forming apparatus according to the second embodiment of the present invention.

FIG. 14 is a partial sectional view of an electron source according to a second embodiment of the present invention.

FIG. 15 is a manufacturing process diagram of the electron source according to the second embodiment.

FIG. 16 is a manufacturing process diagram of the electron source according to the second embodiment.

FIG. 17 is a block diagram of an image forming apparatus according to a third embodiment of the present invention.

FIG. 18 is a diagram showing thermal analysis of an organic Pd complex according to the present invention.

[Explanation of symbols]

 1 Insulating Substrate 2 Electron Emitting Section 3 Conductive Thin Film 4, 5 Element Electrode 21 Step Forming Member 50 Ammeter 51 Power Supply 52 Ammeter 53 High Voltage Power Supply 54 Anode Electrode 55 Vacuum Device 56 Exhaust Pump 102 X Direction Wiring 103 Y Direction Wiring 104 Surface conduction electron-emitting device 105 Connection 111 Rear plate 112 Support frame 113 Glass substrate 114 Fluorescent film 115 Metal back 116 Face plate 118 Envelope 121 Black conductive material 122 Fluorescent substance 141 Interlayer insulating layer 142 Contact hole 161 Cr film 201 Indication Panel 202 Scan circuit 203 Control circuit 204 Shift register 205 Line memory 206 Synchronous signal separation circuit 207 Modulation signal generator 261 Drive circuit 262 Display panel controller 263 Multiplexer 264 Decoder 65 Input / output interface 266 CPU 267 Image generation circuit 268 Image memory interface 269 Image memory interface 270 Image memory interface 271 Image input memory interface 272 TV signal receiving circuit 273 TV signal receiving circuit 274 Input section 280 Display panel 301 Display panel 302 Grid electrode 303 Opening 304 Common wiring

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁶ Identification code Office reference number FI technical display location H04N 5/66 101 Z

Claims (12)

[Claims] 1. A method of manufacturing an electron-emitting device comprising a pair of device electrodes formed on an insulating substrate and a conductive thin film formed across the device electrodes and provided with an electron-emitting portion. In the step of forming the conductive thin film, a step of forming an organic metal thin film by performing a plurality of operations of applying an organic metal solution to the entire substrate and performing a heat treatment at a temperature not lower than a melting temperature of the organic metal and lower than a thermal decomposition temperature, A method of manufacturing an electron-emitting device, characterized in that the organic metal thin film is heat-treated at a temperature at which a metal or a metal oxide is formed from the organic metal. 2. The method for manufacturing an electron-emitting device according to claim 1, wherein the organic metal is organic palladium. 3. An electron-emitting device manufactured by the manufacturing method according to claim 1. 4. The electron-emitting device according to claim 3, wherein the device electrodes are flat devices formed on the same surface. 5. The electron-emitting device according to claim 3, wherein the device electrodes are vertically arranged with an insulating layer interposed therebetween, and a conductive thin film is formed on a side surface of the insulating layer. 6. A ladder-shaped arrangement for driving each element, comprising at least one element row formed by arranging and connecting a plurality of electron-emitting elements according to claim 3 in parallel. An electron source characterized by being stored. 7. An electron column having a plurality of electron-emitting devices according to claim 3 is arranged in at least one line, and wirings for driving the device are arranged in a matrix. Electron source. 8. An image forming apparatus comprising the electron source according to claim 6, an image forming member, and a control electrode for controlling an electron beam emitted from each element according to an information signal. 9. An image forming apparatus comprising the electron source according to claim 7 and an image forming member. 10. A method of manufacturing an electron source, comprising forming a plurality of electron-emitting devices on the same substrate by the method of manufacturing according to claim 1. 11. An electron source is manufactured by the manufacturing method according to claim 10, and the obtained electron source is irradiated with an electron beam emitted from the electron source and a control electrode for controlling an electron beam emitted from the electron source. A method for manufacturing an image forming apparatus, characterized in that the method is combined with an image forming member for forming an image. 12. An image produced by manufacturing an electron source by the manufacturing method according to claim 10, and combining the obtained electron source with an image forming member which forms an image by irradiation of an electron beam from the electron source. Manufacturing method of forming apparatus.