JPH08304270A - Near-infrared device for spectroscopic analysts - Google Patents
Near-infrared device for spectroscopic analystsInfo
- Publication number
- JPH08304270A JPH08304270A JP7110399A JP11039995A JPH08304270A JP H08304270 A JPH08304270 A JP H08304270A JP 7110399 A JP7110399 A JP 7110399A JP 11039995 A JP11039995 A JP 11039995A JP H08304270 A JPH08304270 A JP H08304270A
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- measurement
- light
- chamber
- cell
- Prior art date
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- Investigating Or Analysing Materials By Optical Means (AREA)
- Sampling And Sample Adjustment (AREA)
- Optical Measuring Cells (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、ＯＨ、ＣＨ、ＮＨ、Ｃ
Ｏ等の官能基の倍音、結合音振動によって起こる近赤外
域の光の吸光度変化を測定し、成分・性質分析（例え
ば、カロリー等）をオンラインで行う近赤外分光分析装
置に関し、更に詳しくは、原油やＣ重油の精度良い測定
を可能にした近赤外分光分析装置に関する。The present invention relates to OH, CH, NH, C
A near-infrared spectroscopic analyzer for measuring the change in absorbance of light in the near-infrared region caused by vibrations of overtones of functional groups such as O and combined sound, and performing component / property analysis (for example, calories) online. The present invention relates to a near-infrared spectroscopic analyzer that enables accurate measurement of crude oil and C heavy oil.
【０００２】[0002]
【従来の技術】図６は、従来の近赤外分光分析装置の概
念図である。１は被測定液が供給されるセル、２は近赤
外域の検査光を照射する光ファイバで、セル１を通過す
る被測定溶液にボールレンズ３を介して測定光を照射す
る。2. Description of the Related Art FIG. 6 is a conceptual diagram of a conventional near-infrared spectroscopic analyzer. Reference numeral 1 is a cell to which the solution to be measured is supplied, and 2 is an optical fiber for irradiating the inspection light in the near infrared region, and the solution to be measured passing through the cell 1 is irradiated with the measurement light via a ball lens 3.
【０００３】４は測定光の透過側に設けられたボールレ
ンズ、５はボールレンズ４を介して受光した透過光をＣ
ＰＵ（図省略）に導く光ファイバである。セル１を通過
した被測定液は、例えばボイラに供給され、ＣＰＵのデ
ータに基づいて、燃焼等が制御される。Reference numeral 4 denotes a ball lens provided on the transmission side of the measurement light, and 5 denotes C, which is the transmitted light received through the ball lens 4.
An optical fiber that leads to a PU (not shown). The liquid to be measured that has passed through the cell 1 is supplied to, for example, a boiler, and combustion and the like are controlled based on the data of the CPU.
【０００４】図７は、従来の近赤外分光分析装置の測定
室を抽出して示した構成図である。図６と同一作用をす
るものは同一符号を付けて説明する。以下、図面におい
ては同様とする。図中、７は円筒形をした取り付けキャ
ップで、セル１がボールレンズ３、４によって挟まれて
取り付けられる。８は取り付けキャップ７にボールレン
ズ３を固定するネジである。FIG. 7 is a block diagram showing an extracted measurement chamber of a conventional near infrared spectroscopic analysis device. Those having the same operations as those in FIG. 6 are described with the same reference numerals. Hereinafter, the same applies in the drawings. In the figure, 7 is a cylindrical mounting cap, and the cell 1 is mounted by being sandwiched by the ball lenses 3 and 4. Reference numeral 8 is a screw for fixing the ball lens 3 to the mounting cap 7.
【０００５】９はセルに被測定溶液を供給する継手で、
取り付けキャップ７の側面に設けられた穴７Ａから挿入
されセル１に押圧されて取り付けられる。セル１と継手
９との間はパッキンを介して接続されていて、継手９
は、ネジ１０を介して取り付けキャップ７に固定されて
いる。Reference numeral 9 is a joint for supplying the solution to be measured to the cell,
It is inserted through a hole 7A provided on the side surface of the mounting cap 7 and pressed against the cell 1 to be mounted. The cell 1 and the joint 9 are connected via a packing, and the joint 9
Are fixed to the mounting cap 7 via screws 10.
【０００６】１１は取り付けキャップ７の外周を覆うカ
バーで、ネジ１２によって取り付けキャップ７に固定さ
れる。このように、セル１は、取り付けキャップ７及び
カバー１１によって覆われているため、外光が完璧に遮
光され、光ファイバ２、５を介してセルを通過する光は
影響を受けることがない。Reference numeral 11 is a cover for covering the outer periphery of the mounting cap 7, which is fixed to the mounting cap 7 with screws 12. As described above, since the cell 1 is covered by the mounting cap 7 and the cover 11, the outside light is completely shielded, and the light passing through the cell via the optical fibers 2 and 5 is not affected.
【０００７】[0007]
【発明が解決しようとする課題】このような従来の近赤
外分光分析装置は、測定物がＣ重油や原油等の場合、高
沸点物質等が検出器内で凝固して測定が不能という欠点
があった。また、これらの高沸点物質によってセルが汚
れてしまい正確な測定ができなくなってしまうという欠
点があった。The conventional near-infrared spectroscopic analyzer as described above has a drawback in that, when the object to be measured is C heavy oil or crude oil, the high boiling point substance is solidified in the detector and the measurement is impossible. was there. Further, there is a drawback that the high boiling point substance contaminates the cell and makes accurate measurement impossible.
【０００８】本発明は、このような点に鑑みてなされた
もので、セルと搬送経路を恒温に保つことで、測定する
高沸点物質等を測定の途中で凝固しないようにしたもも
のである。更に、これらの高沸点物質等によってセル中
が汚れてた場合に、セルを洗浄する手段を設けると共
に、セルの取り外しを容易なものとし、より完全にセル
の洗浄を行うことのできる近赤外分光分析装置を提供す
ることを目的としている。The present invention has been made in view of the above point, and is to prevent the solidification of the high boiling point substance or the like to be measured during the measurement by keeping the cell and the conveying path at a constant temperature. . Further, in the case where the inside of the cell is contaminated by these high boiling point substances, etc., a means for cleaning the cell is provided, and the removal of the cell is facilitated so that the cell can be cleaned more completely in the near infrared range. It is intended to provide a spectroscopic analysis device.
【０００９】[0009]
【課題を解決するための手段】このような目的を達成す
るために、本発明は、液化タンク内で加熱して液化した
被測定物を送液ポンプで測定室に導いて近赤外域の光を
照射し、照射した光の吸光度の変化を測定して前記被測
定物の成分を分析する近赤外分光分析装置において、前
記液化タンクと前記測定室及び前記被測定液を前記液化
タンクから前記測定室に移送する経路のそれぞれを一定
温度に保持する恒温化室、を設けたことを特長としてい
る。また、液化タンク内で加熱して液化した被測定物を
送液ポンプで測定室に導いて近赤外域の光を照射し、照
射した光の吸光度の変化を測定して前記被測定物の成分
を分析する近赤外分光分析装置において、前記測定室に
供給される被測定物を石油の低沸点成分に切替え、前記
測定室の近赤外域の光が透過する測定窓を洗浄する洗浄
手段、を設けたことを特長としている。更に、測定室に
導入した被測定物に近赤外域の測定光を照射し、照射し
た光の吸光度の変化を測定して前記被測定物の成分を分
析する近赤外分光分析装置において、前記測定室を形成
する収納ケースと、この収納ケース内に設けられてい
て、前記近赤外域の光が照射される第１のボールレンズ
と、この収納ケース内に設けられていて、前記第１のボ
ールレンズの光を受光する第２のボールレンズと、前記
収納ケースと着脱可能に取り付けられていて、前記第１
のボールレンズと前記第２のボールレンズとの間に設け
られ、前記被測定物が通過するセルと、前記測定室に被
測定物を導入する継手と前記セルを接続する接続手段
と、を具備し、前記被測定物を前記セルを導いて測定す
ることを特長としている。In order to achieve such an object, the present invention introduces a near-infrared region light by introducing an object to be measured which is heated and liquefied in a liquefaction tank into a measurement chamber by a liquid feed pump. In the near-infrared spectroscopic analyzer for analyzing the components of the object to be measured by measuring the change in the absorbance of the irradiated light, the liquefaction tank, the measurement chamber, and the liquid to be measured from the liquefaction tank It is characterized by the provision of a constant temperature chamber that keeps each of the paths transferred to the measurement chamber at a constant temperature. Further, the measurement object liquefied by heating in the liquefaction tank is guided to the measurement chamber by the liquid feed pump and irradiated with light in the near infrared region, and the change in the absorbance of the irradiated light is measured to measure the components of the measurement object. In the near-infrared spectroscopic analyzer for analyzing, the measurement object supplied to the measurement chamber is switched to a low boiling point component of petroleum, a cleaning means for cleaning the measurement window through which light in the near-infrared region of the measurement chamber is transmitted, It is characterized by the provision of. Further, in the near-infrared spectroscopic analyzer for irradiating the measurement object introduced into the measurement chamber with the measurement light in the near-infrared region, and measuring the change in the absorbance of the irradiated light to analyze the components of the measurement object, A storage case forming a measurement chamber, a first ball lens provided in the storage case and irradiated with light in the near-infrared region, and provided in the storage case, the first ball lens A second ball lens for receiving light from the ball lens, and the first case, which is detachably attached to the storage case,
A cell that is provided between the ball lens and the second ball lens, through which the object to be measured passes, and a connecting means that connects the cell and a joint for introducing the object to be measured into the measurement chamber. However, it is characterized in that the object to be measured is guided by the cell and measured.
【００１０】[0010]
【作用】本発明の各構成要素は次のような作用をする。
恒温化室は、液化タンクと測定室及び被測定液を液化タ
ンクから測定室に移送する経路のそれぞれを一定温度に
保持し、Ｃ重油や原油の成分を凝固しないようにしてい
る。洗浄手段は、測定室に供給される被測定物を石油の
低沸点成分に切替え、測定室の近赤外域の光が透過する
測定窓を洗浄する。被測定物が通過するセルは、収納ケ
ースと着脱可能に取り付けられていて、接続手段によっ
て、測定室に被測定物を導入する継手と接続されてい
る。Each component of the present invention has the following action.
The constant temperature chamber holds each of the liquefaction tank, the measurement chamber, and the path for transferring the liquid to be measured from the liquefaction tank to the measurement chamber at a constant temperature so that the components of the C heavy oil and crude oil are not solidified. The cleaning means switches the object to be measured supplied to the measurement chamber to a low boiling point component of petroleum, and cleans the measurement window of the measurement chamber through which light in the near infrared region passes. The cell through which the object to be measured passes is detachably attached to the storage case, and is connected to the joint for introducing the object to be measured into the measurement chamber by the connecting means.
【００１１】[0011]
【実施例】以下、図面を用いて本発明の一実施例を詳細
に説明する。図１は、本発明の近赤外分光分析装置の一
実施例を示した構成図である。図中、２０は恒温化室、
２１は高温水や蒸気の流量を制御する流量コントローラ
で、流量を制御して恒温化室２０を所定温度に昇温す
る。An embodiment of the present invention will be described in detail below with reference to the drawings. FIG. 1 is a block diagram showing an embodiment of the near infrared spectroscopy analyzer of the present invention. In the figure, 20 is a constant temperature chamber,
Reference numeral 21 denotes a flow rate controller that controls the flow rate of high-temperature water or steam, and controls the flow rate to raise the temperature of the thermostat chamber 20 to a predetermined temperature.
【００１２】２２は恒温化室２０に導入された被測定
物、例えばＣ重油や原油を液化する液化タンク、２３は
液化した被測定物を測定室２４に搬送するポンプであ
る。液化タンク２２で液化され、測定室２４に搬送され
た被測定物は、セル（図省略）を通過し、セルで近赤外
域の光を用いて測定された後ボイラ等に送出される。Reference numeral 22 is a liquefaction tank for liquefying the object to be measured introduced into the temperature-controlled chamber 20, for example, C heavy oil or crude oil, and 23 is a pump for conveying the liquefied object to be measured to the measuring chamber 24. The object to be measured liquefied in the liquefaction tank 22 and conveyed to the measurement chamber 24 passes through a cell (not shown), is measured by the cell using light in the near infrared region, and then sent to a boiler or the like.
【００１３】このように液化された被測定物を、恒温化
室２０でそのままの状態を保ちながら測定できるので高
沸点成分が凝固せず、プロセスを止めないで連続した測
定が可能となる。The liquefied object to be measured can be measured in the temperature-controlled chamber 20 while maintaining the state as it is, so that the high-boiling point component does not solidify and continuous measurement can be performed without stopping the process.
【００１４】図２は、本発明の近赤外分光分析装置の第
２の実施例を示した構成図である。図中、３０は洗浄液
タンク、３１は被測定液をオン／オフするバルブ、３２
は洗浄液タンク３０の洗浄液をオン／オフするバルブで
ある。洗浄液タンク３０中には、被測定液を加温するの
と略同じ温度に加温された例えば、軽油、トリクレン等
の低沸点成分の溶媒が貯溜されている。FIG. 2 is a block diagram showing a second embodiment of the near infrared spectroscopic analysis apparatus of the present invention. In the figure, 30 is a cleaning liquid tank, 31 is a valve for turning on / off the liquid to be measured, 32
Is a valve for turning on / off the cleaning liquid in the cleaning liquid tank 30. The cleaning liquid tank 30 stores a solvent having a low boiling point component, such as light oil or trichlene, which has been heated to substantially the same temperature as the liquid to be measured is heated.
【００１５】軽油は、一般にボイラたきつけように常備
されているため便利であり、測定室１のセル１Ａを洗浄
後は、ボイラに注入して焼却するようになっている。Light oil is convenient because it is generally stored in a boiler so that it can be struck. After cleaning the cell 1A of the measuring chamber 1, it is poured into the boiler and incinerated.
【００１６】セル１Ａの洗浄は、バルブ３１が閉じら
れ、開かれたバルフ３２より洗浄液がセル１Ａに導入さ
れる。セル１Ａに必要な洗浄液の量は、例えば、３００
ｃｃ程度が必要となる。このように、洗浄機能を持たせ
ることで、近赤外線でＣ重油や原油の測定が可能とな
る。このため、従来の燃焼法に比べ、測定時間が１５分
から１秒と９００倍も早くなった。また、測定精度も５
倍程度改善された。For cleaning the cell 1A, the valve 31 is closed and the cleaning liquid is introduced into the cell 1A from the opened valve 32. The amount of cleaning liquid required for the cell 1A is, for example, 300
About cc is required. Thus, by providing a cleaning function, it is possible to measure C heavy oil or crude oil with near infrared rays. Therefore, the measurement time was 15 minutes to 1 second, 900 times faster than that of the conventional combustion method. Also, the measurement accuracy is 5
It was improved about twice.
【００１７】図３は、本発明の近赤外分光分析装置の第
３の実施例を示した測定室の正面図、図４は、測定部の
セルの構成図、図５はセルの接続部分の拡大図である。
図中。４０は収納ケースで、上蓋を外した状態で示して
ある。４１は収納ケース４０にネジで取り付けられた継
手で、接続手段であるナットＮ1、Ｎ2を介してセル４２
と接続される。セル４２は、収納ケース４０の位置決め
ピン４３によって位置決めされた後、ネジ４４によって
収納ケース４０に固定される。FIG. 3 is a front view of a measuring chamber showing a third embodiment of the near-infrared spectroscopic analysis device of the present invention, FIG. 4 is a block diagram of a cell of a measuring section, and FIG. 5 is a cell connecting portion. FIG.
In the figure. A storage case 40 is shown with the upper lid removed. Reference numeral 41 is a joint attached to the storage case 40 with screws, and the cell 42 is connected via nuts N 1 and N 2 which are connection means.
Connected to The cell 42 is positioned by the positioning pin 43 of the storage case 40 and then fixed to the storage case 40 with the screw 44.
【００１８】ナットＮ1、Ｎ2は、セル４２が固定された
後に回転され、ナットＮ2の先端に設けられたテフロン
シールＴＦがセル４２に密着され、流路に漏れのないよ
うセットされる。セル４２が完全にセットされた後、ボ
ールレンズ３、４がセル４２の両側に取り付けられる。The nuts N 1 and N 2 are rotated after the cell 42 is fixed, and the Teflon seal TF provided at the tip of the nut N 2 is brought into close contact with the cell 42 and set so that there is no leakage in the flow path. . After the cell 42 is completely set, the ball lenses 3 and 4 are attached to both sides of the cell 42.
【００１９】ボールレンズ４５は、収納ケース４０の背
面からネジ（図省略）によって固定される。４６は測定
用の光ファイバ、４７はリファレンス用の光ファイバで
ある。リファレンス用の光ファイバ４７は、セル４２の
下部に設けられている穴（図省略）を通して接続されて
いる。The ball lens 45 is fixed from the back surface of the storage case 40 with screws (not shown). 46 is an optical fiber for measurement, and 47 is an optical fiber for reference. The reference optical fiber 47 is connected through a hole (not shown) provided in the lower portion of the cell 42.
【００２０】収納ケース４０は、各部品のセットが完了
すると上蓋が取り付けられ、外光を遮断する。When the components of the storage case 40 are completely set, an upper lid is attached to block outside light.
【００２１】次に、セルの取り外しについて説明する。
先ず、被測定液の搬送を止める。被測液を止めた後、ナ
ットＮ1、Ｎ2を回して弛め、セル４２との接続を解く。
この状態で、ネジ４４を外せば、セル４２は自由にな
り、簡単に取り外すことができる。取り外したセル４２
は、光が透過するサファイヤガラス４６が外され、容易
に洗浄することができるようになる。Next, the removal of the cell will be described.
First, the conveyance of the liquid to be measured is stopped. After stopping the liquid to be measured, the nuts N 1 and N 2 are turned to loosen the connection with the cell 42.
In this state, if the screw 44 is removed, the cell 42 becomes free and can be easily removed. Cell 42 removed
The sapphire glass 46, through which light is transmitted, is removed so that it can be easily washed.
【００２２】このように、本発明のセルは、取付けが容
易で精度良い取り付けができる構成になっているため、
洗浄の前後で光軸に変動がなく、検量線の調整を必要と
しない。このため、洗浄作業に特別な訓練をする必要が
ない。As described above, the cell of the present invention has a structure that can be easily and accurately mounted.
There is no change in the optical axis before and after washing, and there is no need to adjust the calibration curve. Therefore, no special training is required for cleaning work.
【００２３】[0023]
【発明の効果】以上、詳細に説明したように本発明によ
れば、次に示すような効果がある。第１請求項記載の発
明によれば、恒温化室がセルと搬送経路を一定温度に保
っているので、測定の途中で高沸点物質が凝固すること
がなく、Ｃ重油や原油等を精度良く測定することができ
る。第２請求項記載の発明によれば、高沸点物質等によ
ってセル中が汚れた場合に、洗浄液によってセルを洗浄
するようにしているので、セルの汚れに影響を受けず精
度良い測定ができる。第３請求項記載の発明によれば、
セルの取り外しを容易なものとして、より完全にセルの
洗浄を行うことができるようにしているので、長期的な
汚れであっても除去でき、精度良い測定ができる。As described in detail above, the present invention has the following effects. According to the first aspect of the invention, since the constant temperature chamber keeps the cell and the transport path at a constant temperature, the high boiling point substance does not solidify during the measurement, and the C heavy oil, crude oil, etc. can be accurately measured. Can be measured. According to the invention described in the second aspect, when the inside of the cell is contaminated by a substance having a high boiling point or the like, the cell is cleaned with the cleaning liquid, and therefore, the measurement can be performed accurately without being affected by the contamination of the cell. According to the invention described in claim 3,
Since the cell can be easily removed and the cell can be washed more completely, even long-term stains can be removed and accurate measurement can be performed.
【図１】本発明の近赤外分光分析装置の一実施例を示し
た構成図である。FIG. 1 is a configuration diagram showing an embodiment of a near-infrared spectroscopic analysis device of the present invention.
【図２】本発明の近赤外分光分析装置の第２の実施例を
示した構成図である。FIG. 2 is a configuration diagram showing a second embodiment of the near-infrared spectroscopy analyzer of the present invention.
【図３】本発明の近赤外分光分析装置の第３の実施例を
示した測定室の正面図である。FIG. 3 is a front view of a measurement chamber showing a third embodiment of the near-infrared spectroscopy analyzer of the present invention.
【図４】測定部のセルの構成図である。FIG. 4 is a configuration diagram of a cell of a measurement unit.
【図５】セルの接続部分の拡大図である。FIG. 5 is an enlarged view of a cell connecting portion.
【図６】従来の近赤外分光分析装置の概念図である。FIG. 6 is a conceptual diagram of a conventional near infrared spectroscopy analyzer.
【図７】従来の近赤外分光分析装置の測定部を抽出して
示した構成図である。FIG. 7 is a block diagram showing a measurement unit of a conventional near-infrared spectroscopic analysis device.
２０ 高温化室 ３０ 洗浄液タンク ４０ 収納ケース ４２ セル ４３ 位置決めピン Ｎ1、Ｎ2 ナット20 High Temperature Chamber 30 Cleaning Liquid Tank 40 Storage Case 42 Cell 43 Positioning Pins N 1 and N 2 Nuts
フロントページの続き (72)発明者 星野 直子 東京都品川区東品川５丁目６番22号 東京 電力株式会社大井火力発電所内 (72)発明者 中桐 由紀子 東京都品川区東品川５丁目６番22号 東京 電力株式会社大井火力発電所内 (72)発明者 高橋 重男 東京都武蔵野市中町２丁目９番32号 横河 電機株式会社内 (72)発明者 清部 政一郎 東京都武蔵野市中町２丁目９番32号 横河 電機株式会社内 (72)発明者 田中 秀子 東京都武蔵野市中町２丁目９番32号 横河 電機株式会社内 (72)発明者 大畑 勝太郎 東京都武蔵野市中町２丁目９番32号 横河 電機株式会社内Front Page Continuation (72) Inventor Naoko Hoshino 5-6-22 Higashi-Shinagawa, Shinagawa-ku, Tokyo Inside Oi Thermal Power Station, Tokyo Electric Power Co., Inc. (72) Yukiko Nakagiri 5-6-22 Higashi-Shinagawa, Shinagawa-ku, Tokyo Tokyo Electric Power Company Oi Thermal Power Plant (72) Inventor Shigeo Takahashi 2-9-32 Nakamachi, Musashino-shi, Tokyo Yokogawa Electric Co., Ltd. (72) Seiichiro Kiyobe 2-chome Nakamachi, Musashino-shi, Tokyo No. 32 Yokogawa Electric Co., Ltd. (72) Inventor Hideko Tanaka 2-932 Nakamachi, Musashino-shi, Tokyo No. 32 Yokogawa Electric Co., Ltd. (72) Inventor Katsutaro Ohata 2-3-9 Nakamachi, Musashino-shi, Tokyo Yokogawa Electric Co., Ltd.
Claims (3)
物を送液ポンプで測定室に導いて近赤外域の光を照射
し、照射した光の吸光度の変化を測定して前記被測定物
の成分を分析する近赤外分光分析装置において、 前記液化タンクと前記測定室及び前記被測定液を前記液
化タンクから前記測定室に移送する経路のそれぞれを一
定温度に保持する恒温化室、 を設けたことを特長とした近赤外分光分析装置。1. An object to be measured, which is liquefied by heating in a liquefaction tank, is guided to a measurement chamber by a liquid feed pump, irradiated with light in the near infrared region, and a change in absorbance of the irradiated light is measured. In the near-infrared spectroscopic analyzer for analyzing the components of the object, the liquefaction tank and the measurement chamber and a constant temperature chamber that holds each of the paths for transferring the liquid to be measured from the liquefaction tank to the measurement chamber at a constant temperature, Near-infrared spectroscopic analyzer characterized by having
物を送液ポンプで測定室に導いて近赤外域の光を照射
し、照射した光の吸光度の変化を測定して前記被測定物
の成分を分析する近赤外分光分析装置において、 前記測定室に供給される被測定物を石油の低沸点成分に
切替え、前記測定室の近赤外域の光が透過する測定窓を
洗浄する洗浄手段、 を設けたことを特長とした近赤外分光分析装置。2. The object to be measured, which is heated and liquefied in a liquefaction tank, is guided to a measurement chamber by a liquid feed pump, irradiated with light in the near infrared region, and a change in absorbance of the irradiated light is measured. In a near-infrared spectroscopic analyzer for analyzing the components of an object, the object to be measured supplied to the measurement chamber is switched to a low boiling point component of petroleum, and the measurement window in the near-infrared region of the measurement chamber where light is transmitted is washed. A near-infrared spectroscopic analyzer featuring cleaning means.
測定光を照射し、照射した光の吸光度の変化を測定して
前記被測定物の成分を分析する近赤外分光分析装置にお
いて、 前記測定室を形成する収納ケースと、 この収納ケース内に設けられていて、前記近赤外域の光
が照射される第１のボールレンズと、 この収納ケース内に設けられていて、前記第１のボール
レンズの光を受光する第２のボールレンズと、 前記収納ケースと着脱可能に取り付けられていて、前記
第１のボールレンズと前記第２のボールレンズとの間に
設けられ、前記被測定物が通過するセルと、 前記測定室に被測定物を導入する継手と前記セルとを接
続する接続手段と、 を具備し、前記被測定物を前記セルを導いて測定するこ
とを特長とした近赤外分光分析装置。3. A near-infrared spectroscopic analyzer for irradiating an object to be measured introduced into a measuring chamber with measurement light in the near-infrared region and measuring a change in absorbance of the irradiated light to analyze the components of the object to be measured. In the storage case forming the measurement chamber, a first ball lens provided in the storage case and irradiated with light in the near infrared region, and provided in the storage case, A second ball lens for receiving the light of the first ball lens; and a second ball lens which is detachably attached to the storage case and is provided between the first ball lens and the second ball lens. A cell through which the object to be measured passes, and a connecting means for connecting the joint and the cell for introducing the object to be measured into the measurement chamber, and measuring the object to be measured by guiding the cell. And near infrared spectroscopy analyzer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7110399A JPH08304270A (en) | 1995-05-09 | 1995-05-09 | Near-infrared device for spectroscopic analysts |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7110399A JPH08304270A (en) | 1995-05-09 | 1995-05-09 | Near-infrared device for spectroscopic analysts |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001337482A Division JP2002181703A (en) | 2001-11-02 | 2001-11-02 | Near infrared spectroscopic analyser |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH08304270A true JPH08304270A (en) | 1996-11-22 |
Family
ID=14534827
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7110399A Pending JPH08304270A (en) | 1995-05-09 | 1995-05-09 | Near-infrared device for spectroscopic analysts |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH08304270A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002533714A (en) * | 1998-12-28 | 2002-10-08 | エス ケー コーポレイション | Automatic analysis of crude oil using spectroscopy |
| JP2009042217A (en) * | 2007-08-07 | 2009-02-26 | Korea Research Inst Of Standards & Science | Spectrum analyzer capable of performing real-time process diagnosis |
| CN114138033A (en) * | 2021-11-25 | 2022-03-04 | 西安石油大学 | Constant temperature control method and device for quick-opening ball collecting barrel |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5560838A (en) * | 1978-10-31 | 1980-05-08 | Sanuki Kogyo Kk | Flow cell supporter |
| JPS60174853U (en) * | 1984-04-27 | 1985-11-19 | 株式会社島津製作所 | Oil concentration measuring device |
| JPS63181848U (en) * | 1987-11-09 | 1988-11-24 | ||
| JPH05118986A (en) * | 1991-10-01 | 1993-05-14 | Calsonic Corp | Detector for oil deterioration |
| JPH06167445A (en) * | 1992-07-21 | 1994-06-14 | Western Atlas Internatl Inc | Method for enhancement of estimation of infrared analysis by automatic compensation with reference to instrumental instability |
| JPH06281565A (en) * | 1993-03-29 | 1994-10-07 | Yokogawa Electric Corp | Absorbance type analyzer |
| JPH0712723A (en) * | 1992-09-30 | 1995-01-17 | Mitsubishi Heavy Ind Ltd | Device for measuring degradation degree of lubrication oil |
-
1995
- 1995-05-09 JP JP7110399A patent/JPH08304270A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5560838A (en) * | 1978-10-31 | 1980-05-08 | Sanuki Kogyo Kk | Flow cell supporter |
| JPS60174853U (en) * | 1984-04-27 | 1985-11-19 | 株式会社島津製作所 | Oil concentration measuring device |
| JPS63181848U (en) * | 1987-11-09 | 1988-11-24 | ||
| JPH05118986A (en) * | 1991-10-01 | 1993-05-14 | Calsonic Corp | Detector for oil deterioration |
| JPH06167445A (en) * | 1992-07-21 | 1994-06-14 | Western Atlas Internatl Inc | Method for enhancement of estimation of infrared analysis by automatic compensation with reference to instrumental instability |
| JPH0712723A (en) * | 1992-09-30 | 1995-01-17 | Mitsubishi Heavy Ind Ltd | Device for measuring degradation degree of lubrication oil |
| JPH06281565A (en) * | 1993-03-29 | 1994-10-07 | Yokogawa Electric Corp | Absorbance type analyzer |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002533714A (en) * | 1998-12-28 | 2002-10-08 | エス ケー コーポレイション | Automatic analysis of crude oil using spectroscopy |
| JP2009042217A (en) * | 2007-08-07 | 2009-02-26 | Korea Research Inst Of Standards & Science | Spectrum analyzer capable of performing real-time process diagnosis |
| CN114138033A (en) * | 2021-11-25 | 2022-03-04 | 西安石油大学 | Constant temperature control method and device for quick-opening ball collecting barrel |
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