JPH0827538B2 - Photosensitive resin composition - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION [Industrial application] The present invention relates to a photosensitive polyimide resin composition having extremely high sensitivity.

[Prior Art] Conventionally, a polyimide resin having excellent heat resistance and excellent electrical characteristics and mechanical characteristics has been used for a surface protective film and an interlayer insulating film of a semiconductor element. Due to high integration of elements, large size, thinning and miniaturization of encapsulation resin package, transition to surface mounting method by solder reflow, heat cycle resistance, heat shock resistance, etc. are required to be significantly improved. Polyimide resins have become necessary.

On the other hand, a technique of imparting photosensitivity to the polyimide resin itself has recently attracted attention.

The use of these photosensitized polyimide resins not only has the effect of simplifying the pattern creation process compared to non-added polyimide resins, but it also saves the use of highly toxic etching liquids, so it is safe. It is also excellent in terms of pollution, and it is expected that photosensitization of polyimide resin will be an important technology.

As the photosensitive polyimide resin, for example, the following formula (A) A polyimide precursor composition having a photosensitive group with an ester group having the structure shown in (for example, JP-B-55-41422) or the following formula (B) A composition obtained by adding a compound containing a carbonic-carbon double bond which is dimerizable with actinic radiation or a polymerizable carbon-carbon double bond and an amino group or a quaternized salt thereof to a polyamic acid having the structure shown in (for example, Japanese Patent Publication No. 59- No. 52822) is known.

All of these are dissolved in a suitable organic solvent, applied in a varnish state, dried, irradiated with ultraviolet rays through a photomask, developed, rinsed to obtain a desired pattern, and further heated to form a polyimide. It is a film.

However, such conventional compositions have the following drawbacks. That is, in the composition shown in (A),
It was difficult to stabilize the product, because a remarkably complicated process of first producing an esterification reaction of tetracarboxylic dianhydride and an alcohol having a photosensitive group and then performing an amidation reaction with a diamine was performed. However, the ester bond has a strong bond strength and thus has an advantage that it can be spray-developed (a method of rapidly spraying a developing solution to rapidly develop in a short time). On the contrary, since the binding force is too strong, 40
Even at a high temperature of 0 ° C. or higher, the photosensitive group could not be completely removed, and the polyimide coating was blackened, and the physical properties (strength, elongation, etc.) of the coating deteriorated. On the other hand, in the composition shown in (B), since it is sufficient to add and mix the photosensitizer to the polyamic acid, the manufacturing process is extremely simple, but the ionic bond strength between the polyamic acid and the photosensitizer is extremely weak, Paddle development (a method of dropping a developing solution on a stationary film to be developed for development) has to be performed, which is a disadvantage that it takes a little time. Further, the viscosity of the varnish at room temperature is large and the storage stability is poor, so that it is insufficient for application to the semiconductor manufacturing process. On the other hand, since the bonding strength is weak, the photosensitive group is easily removed by heating, which is advantageous in that the film properties of the polyimide film are excellent. However, (A),
The exposure sensitivity of both (B) is 200 to 400 mJ / cm ² (i-line contact exposure machine, full spectrum, thickness 10 μm), which is not sufficient to meet the demand for higher sensitivity due to recent technological progress. Has become.

[Problems to be Solved by the Invention] The object of the present invention is to provide a remarkably simple method.
It is an object of the present invention to provide a photosensitive resin composition which is free from variations in quality, has extremely high sensitivity, and has excellent film properties.

[Means for Solving the Problems] The present invention provides (A) a polyamic acid compound [I] having an actinic radiation functional group P ^* at both ends. (In the formula, n = 2 to 5 R ₁ : H, CH ₃ R ₂ : organic residue) (In the formula, m is an integer of 10 to 10,000, R ₃ and R _{4 are} aromatic cyclic groups) (B) An amino acrylate compound represented by the following formula [II] (Wherein, X: -H or -CH ₃ radical Y: -CH ₃ or -CH ₂ CH ₃ group) (C) the polymerizable carbon with a solution like actinic radiation at room temperature for use in the synthesis of the polyamic acid compound An amide compound containing a carbon double bond, (D) absorption maximum wavelength (λ max)
A photosensitive resin composition comprising a sensitizer of 330 to 500 nm as an essential component.

[Function] The aromatic tetracarboxylic acid or its derivative used for obtaining the polyamic acid compound [I] in the present invention is represented by the following formula [III]: Pyromellitic dianhydride, benzene-1,2,3,4-tetracarboxylic dianhydride, 3,3 ', 4,4'-benzophenone tetracarboxylic dianhydride, 2,2', 3,3 ′ -Benzophenone tetracarboxylic acid dianhydride, 2,3,3 ′, 4′-benzophenone tetracarboxylic acid dianhydride, naphthalene-2,3,6,
7-Tetracarboxylic acid dianhydride, naphthalene-1,2,5,6-
Tetracarboxylic acid dianhydride, naphthalene-1,2,4,5-tetracarboxylic acid dianhydride, naphthalene-1,4,5,8-tetracarboxylic acid dianhydride, naphthalene-1,2,6,7 -Tetracarboxylic acid dianhydride, 4,8-dimethyl-1,2,3,5,6,7-hexahydronaphthalene-1,2,5,6-tetracarboxylic acid dianhydride, 4,8-dimethyl -1,2,3,5,6,7-hexahydronaphthalene-2,3,6,7-tetracarboxylic dianhydride, 2,6-
Dichloronaphthalene-1,4,5,8-tetracarboxylic dianhydride, 2,7-Dichloronaphthalene-1,4,5,8-tetracarboxylic dianhydride, 2,3,6,7-tetrachloro Naphthalene
1,4,5,8-Tetracarboxylic acid dianhydride, 1,4,5,8-Tetrachloronaphthalene-2,3,6,7-tetracarboxylic acid dianhydride, 3,3 ', 4,4 ′ -Diphenyltetracarboxylic dianhydride, 2,2 ′, 3,3′-diphenyltetracarboxylic dianhydride, 2,3,3 ′, 4′-diphenyltetracarboxylic dianhydride, 3,3 ″ , 4,4 "-p-terphenyltetracarboxylic dianhydride, 2,2", 3,3 "-p-terphenyltetracarboxylic dianhydride, 2,3,3", 4 "-p- Terphenyl tetracarboxylic acid dianhydride, 2,2-bis (2,3-dicarboxyphenyl) -propane dianhydride, 2,2-bis (3,4-dicarboxyphenyl) -propane dianhydride, bis (2,3-
Dicarboxyphenyl) ether dianhydride, bis (3,4
-Dicarboxyphenyl) ether dianhydride, bis (2,
3-dicarboxyphenyl) methane dianhydride, bis (3,4
-Dicarboxyphenyl) methane dianhydride, bis (2,3
-Dicarboxyphenyl) sulfone dianhydride, bis (3,
4-dicarboxyphenyl) sulfone dianhydride, 1,1-bis (2,3-dicarboxyphenyl) ethane dianhydride, 1,1
-Bis (3.4-dicarboxyphenyl) ethane dianhydride, perylene-2,3,8,9-tetracarboxylic dianhydride,
Perylene-3,4,9,10-tetracarboxylic dianhydride, perylene-5,10,11-tetracarboxylic dianhydride, perylene-5,6,11,12-tetracarboxylic dianhydride , Phenanthrene-1,2,7,8-tetracarboxylic dianhydride, phenanthrene-1,2,6,7-tetracarboxylic dianhydride, phenanthrene-1,2,9,10-tetracarboxylic dianhydride Product, cyclopentane-1,2,3,4-tetracarboxylic dianhydride,
Pyrazine-2,3,5,6-tetracarboxylic dianhydride, pyrrolidine-2,3,4,5-tetracarboxylic dianhydride, thiophene-2,3,4,5-tetracarboxylic dianhydride Can be given. Further, in use, one kind or a mixture of two or more kinds may be used.

Examples of the compound having an actinic radiation-sensitive group P ^* used for obtaining the polyamic acid compound [I] in the present invention include pentaerythritol triacrylate, pentaerythritol trimethacrylate, pentaerythritol acrylate dimethacrylate, pentaerythritol diacrylate methacrylate, Dipentaerythritol pentaacrylate, dipentaerythritol pentamethacrylate, glycerol diacrylate, glycerol dimethacrylate, glycerol acrylate methacrylate, trimethylolpropane diacrylate, 1,3-diacryloylethyl-5-hydroxyethyl isocyanurate, 1,3-di Methacrylate-5
Examples thereof include, but are not limited to, hydroxyethyl isocyanurate, ethylene glycol-modified pentaerythritol triacrylate, propylene glycol-modified pentaerythritol triacrylate, trimethylolpropane diacrylate, and trimethylolpropane dimethacrylate. In using these, one kind or a mixture of two or more kinds may be used.

The aromatic diamine and / or its derivative used for obtaining the polyamic acid compound [I] in the present invention is represented by the following formula [IV]: (R ₄ : aromatic cyclic group, m = 0 to 2) Diamine with m = 0, diaminocarboxylic acid with m = 1, m =
The diaminodicarboxylic acid of 2 is used, and the amine component may be one kind or a mixture of two or more kinds. The types of amine used include m-phenylene-diamine, 1-isopropyl-2,4-phenylene-diamine,
p-phenylene-diamine, 4,4'-diamino-diphenylpropane, 3,3'-diamino-diphenylpropane, 4,4'-diamino-diphenylethane, 3,3'-diamino-diphenylethane, 4,4 ' -Diamino-diphenylmethane, 3,3'-diamino-diphenylmethane, 4,4 '
-Diamino-diphenyl sulfide, 3,3'-diamino-diphenyl sulfide, 4,4'-diamino-diphenyl sulfone, 3,3'-diamino-diphenyl sulfone,
4,4'-diamino-diphenyl ether, 3,3'-diamino-diphenyl ether, benzidine, 3,3'-diamino-biphenyl, 3,3'-dimethyl-4,4'-diamino-
Biphenyl, 3,3'-dimethoxy-benzidine, 4,4 "-
Diamino-p-terphenyl, 3,3 "-diamino-p-
Terphenyl, bis (p-amino-cyclohexyl) methane, bis (p-β-amino-t-butylphenyl) ether, bis (p-β-methyl-δ-aminopentyl)
Benzene, p-bis (2-methyl-4-amino-pentyl) benzene, p-bis (1,1-dimethyl-5-amino-pentyl) benzene, 1,5-diamino-naphthalene,
2,6-diamino-naphthalene, 2,4-bis (β-amino-
t-butyl) toluene, 2,4-diamino-toluene, m
-Xylene-2,5-diamine, p-xylene-2,5-diamine, m-xylylene-diamine, p-xylylene-diamine, 2,6-diamino-pyridine, 2,5-diamino-pyridine, 2,5 -Diamino-1,3,4-oxadiazole, 1,
4-diamino-cyclohexane, piperazine, methylene-diamine, ethylene-diamine, propylene-diamine, 2,2-dimethyl-propylene-diamine, tetramethylene-diamine, pentamethylene-diamine, hexamethylene-diamine, 2,5-dimethyl. -Hexamethylene-diamine, 3-methoxy-hexamethylene-diamine, heptamethylene-diamine, 2,5-dimethyl-heptamethylene-diamine, 3-methyl-heptamethylene-
Diamine, 4,4-dimethyl-heptamethylene-diamine, octamethylene-diamine, nonamethylene-diamine, 5-methyl-nonamethylene-diamine, 2,5-dimethyl-nonamethylene-diamine, decamethylene-diamine, 1,10-diamino- 1,10-dimethyl-decane, 2,11-
Diamino-dodecane, 1,12-diamino-octadecane,
2,12-diamino-octadecane, 2,17-diamino-icosane, diaminosiloxane, 2,6-diamino-4-carboxylic benzene, and 3,3'-diamino-4,4'-dicarboxylic benzidine. .

The amino acrylate compound used in the present invention is added to promote the photoreaction, and examples thereof include N,
Examples thereof include N-dimethylaminoethyl methacrylate, N, N-dimethylaminoethyl acrylate, N, N-diethylaminoethyl methacrylate and N, N-diethylaminoethyl acrylate. In use, one kind or a mixture of two or more kinds may be used. Furthermore, in order to further promote the photoreaction, an acrylate (methacrylate) compound having no amino group can be used in combination.

The amide compound containing a carbon-carbon double bond that can be polymerized by solution-like actinic radiation at room temperature used in the present invention,
For example, N-methylacrylamide, N-ethylacrylamide, N-methylmethacrylamide, N-ethylmethacrylamide, N, N-dimethylacrylamide, N, N-diethylacrylamide, N, N-dibutylacrylamide, N-acryloylpiperidine, N -Acryloylmorpholine, N, N-dimethylmethacrylamide, N, N-diethylmethacrylamide, N, N-dimethylaminoethylmethacrylamide, N, N-dimethylaminopropylmethacrylamide, N-vinylpyrrolidone, etc. ℃
Examples of the liquid include liquids at a temperature of, but are not limited to these. In addition, even if you use one type, 2
It may be a mixture of more than one kind.

The polyamic acid [I] according to the present invention is An amide compound containing a carbon-carbon double bond that can be polymerized by actinic radiation at room temperature is synthesized using a reaction solvent. An example of the synthesis method is to synthesize a polyamic acid having a polymerization degree m of 1000. When you want to, acid anhydride [III] First, 1001 mol of the compound and 2 mol of the compound having the actinic radiation-sensitive group P ^* are reacted first, and then further diamine [IV] It can be obtained by reacting 1000 mol.

Since the polyamic acid [I] has a polyfunctional actinic radiation-sensitive group P ^* at both ends, the crosslink density of the exposed area increases,
In addition, the unexposed area is a non-crosslinking sensitive group P ^* with good solubility ^.
Therefore, the difference in solubility between the exposed portion and the unexposed portion can be increased, and the sensitivity can be increased. Further, since the end of the polyamic acid is protected by the actinic radiation-sensitive group P ^* , depolymerization of the polyamic acid does not occur, and thus a resin having good viscosity stability was obtained.

Further, conventionally, the use of the amide compound as a reaction system solvent has not been performed at all. A conventional reaction system solvent has been an organic polar solvent having a dipole moment whose functional group does not react with acid anhydrides and diamines.

Besides being inert to the system and being a solvent for the product, the organic polar solvent had to be a solvent for at least one, and preferably both, of the reaction components.

Typical solvents of this type are N, N-dimethylformamide, N, N-dimethylacetamide, N, N-diethylformamide, N, N-diethylacetamide, N, N-
Dimethyl methoxy acetamide, dimethyl sulfoxide, hexamethylphosphoramide, N-methyl-2-pyrrolidone, pyridine, dimethyl sulfone, tetramethylene sulfone, dimethyl tetramethylene sulfone, methyl formamide, N-acetyl-2-pyrrolidone, diethylene glycol monomethyl ether, There are diethylene glycol dimethyl ether and the like, and these solvents are used alone or in combination. In addition to these, as a solvent used in combination, benzene, benzonitrile, dioxane, butyrolactone, methyl cellosolve, ethyl cellosolve, butyl cellosolve, xylene, toluene,
A non-solvent such as cyclohexane was used together as a dispersion medium of the raw material, a reaction modifier, a volatilization modifier of the solvent from the product, a film smoothing agent, and the like. Conventional reaction system solvents have not been sensitive to light. Therefore, in manufacturing a conventional photosensitive resin, a photosensitive component to light is particularly added. However, since it is diluted with a large amount of the reaction system solvent, there is a limit in improving the concentration of the photosensitive group.

According to the method of using the amide compound as a solvent according to the present invention, since the solvent itself is 100% photosensitive, the concentration of the photosensitive group is remarkably high, and thus the photosensitivity can be remarkably increased. Further, since the method for producing a photosensitive resin according to the present invention only adds and mixes the respective components,
Remarkably easy, and the quality variation is extremely small.

The sensitizer used in the present invention is a compound having an absorption maximum wavelength (λ max) at 330 to 500 nm. When λ max is 330 nm or less, light is absorbed by the polyamic acid itself and a photoreaction cannot be performed, which is not preferable. Further, when it is 500 nm or more, it is not preferable because it causes a photoreaction with visible light and requires a work place such as a shield room, which lowers the handleability. The sensitizer of the present invention is, for example, However, the present invention is not limited to this.
In addition, one kind or a mixture of two or more kinds may be used.

The photosensitive resin composition according to the present invention may contain an adhesive aid, a leveling agent, and various other fillers.

The method of using the photosensitive resin composition according to the present invention is as follows.
The composition is applied to a suitable support such as a silicon wafer, ceramic, aluminum substrate or the like. The coating method is spin coating using a spinner, spray coating using a spray coater, dipping, printing, roll coating, or the like. Next, after prebaking at a low temperature of 60 to 80 ° C. to dry the coating film, a desired pattern shape is irradiated with actinic rays. As actinic rays, X-rays, electron rays, ultraviolet rays, visible rays and the like can be used, but those having a wavelength of 200 to 500 nm are preferable.

Next, a relief pattern is obtained by dissolving and removing the unirradiated portion with a developing solution. As a developing solution, N-methyl-
2-Pyrrolidone, N, N-dimethylacetamide, N, N-dimethylformamide and the like, methanol, isopropyl alcohol, water and the like are used alone or in combination. As a developing method, a method such as spraying, paddle, dipping, or ultrasonic wave can be used.

Next, the relief pattern formed by development is rinsed. As the rinse liquid, methanol, ethanol,
Use isopropyl alcohol, butyl acetate, etc.
Next, heat treatment is performed to form an imide ring, and a final pattern having high heat resistance is obtained.

The photosensitive resin composition according to the present invention is useful not only for semiconductor applications but also as an interlayer insulating film of a multilayer circuit, a cover coat of a flexible copper clad board, a solder resist film, a liquid crystal alignment film, and the like.

 The present invention will be specifically described below with reference to examples.

(Example 1) 322 g (1.0 mol) of 3,3 ', 4,4'-benzophenone tetracarboxylic acid dianhydride and glycerol dimethacrylate
11.4 g (0.05 mol) of N, N-dimethylacrylamide 289
It was charged into 0 g and reacted at 50 ° C. for 16 hours. Then 4,4 ′
-200 g (1.0 mol) of diaminodiphenyl ether was added and reacted at 20 ° C for 6 hours.

612 g of the obtained polyamic acid solution (100 g in solid content)
And 20 g of N, N-dimethylaminoethyl methacrylate,
5 g of Michler's ketone (λ max 356 nm) was added and dissolved at room temperature. The obtained composition was applied onto a silicon wafer with a spinner and dried with a dryer at 50 ° C. for 1 hour to give about 10 μm.
m film was obtained.

This film has Kodak Photographic Step Tablet No2, 21 steps (In this gray scale, the amount of transmitted light increases as the number of steps increases. The higher the residual stage after development, the better the sensitivity.), Irradiate with 1000 mJ / cm ² of ultraviolet light, and then N-methyl-2-
After development with a developing solution consisting of 60 g of pyrrolidone and 40 g of methanol and further rinsing with isopropyl alcohol, the pattern remains up to 16 steps and the exposure sensitivity is 10 mJ / cm ²
It turns out that the sensitivity is high.

Further, when a pattern was separately prepared by the same operation with a resolution measuring mask made by Toppan Printing (Topographic test chart No. 1), the pattern was resolved up to 4 μm, and it was found that the resolution was high.

Next, separately coat on an aluminum plate, expose the entire surface, perform the steps of developing and rinsing, and further perform 30 steps at 150, 250, and 350 ° C, respectively.
After heat curing for a minute, remove the aluminum plate by etching,
I got a film.

The tensile strength (JIS K-6760) of the obtained film is 14 kg / m.
large as m ² (better large), the thermal decomposition temperature (TG
A) was as high as 405 ℃ (higher is better).

(Comparative Example 1) Instead of N, N-dimethylaminoethyl methacrylate used in Example 1, diethylene glycol dimethacrylate was used to obtain a resin, and the same evaluation was performed.
Since the photosensitizer does not have an amino group, it has poor compatibility with polyamic acid [I], and the step tablet has 9 steps and the exposure sensitivity is as low as 70 mJ / cm ² .

(Comparative Example 2) 3,3-Dimethyl-4-methoxybenzophenone was used in place of the Michler's ketone used in Example 1. However, since the λ max of this sensitizer was 296 nm, the photoinitiating reaction was efficiently performed. I can not do it, all the patterns flow during development,
It turned out to be impractical.

(Comparative Example 3) A tetraphenylporphyrin zinc complex was used in place of the Michler's ketone used in Example 1, but since the λ max of this sensitizer was 650 nm, it caused a photoreaction during the work, and therefore, it was not developed. I couldn't get the pattern.

(Comparative Example 4) N-methyl-2-pyrrolidone was used in place of the N, N-dimethylacrylamide used in Example 1, and all other components were compounded in the same manner, but there was no photosensitivity at all. Therefore, 60 parts by weight of dimethylaminoethyl methacrylate was further added as a compound having a carbon-carbon double bond and an amino group which were dimerizable or polymerizable by actinic radiation. The same treatment and evaluation as in Example 1 were carried out, but the step tablet was 5
There was only a step, and the exposure sensitivity was as low as 300 mJ / cm ² .
Further, when the change in viscosity at room temperature (23 ° C.) was measured, the viscosity decreased by 20% after 3 days.

Comparative Example 5 290 g of 3,3 ′, 4,4′-benzophenone tetracarboxylic dianhydride and 244 g of 2-hydroxyethyl methacrylate
Was dissolved in γ-butyrolactone, and pyridine was used as a catalyst.
150 g was added and reacted at 20 ° C. for 24 hours to obtain an esterified product. Next, after adding 370 g of dicyclohexylcarbodiimide as an amidation catalyst, 200 g of 4,4'-diaminodiphenyl ether was added and reacted at 20 ° C for 8 hours. Next, the slurry was filtered and the filtrate was dropped into 350 liters of ethanol with vigorous stirring to precipitate a polymer, which was then left to stand for 12 hours. The precipitate was filtered off, dried and ground. The molecular weight of the obtained polymer was 6500, which was considerably smaller than expected. Then, a polymer was synthesized again by the same method, but in this case as well, the molecular weight remained at 11,000. It was found that this method not only requires a long process and is complicated, but also has a large variation.

Next, this polymer was dissolved in N-methyl-2-pyrrolidone, the same sensitizer as in Example 1 was added to obtain a photosensitive resin composition, and the same evaluation was performed. There were only 4 steps, and the exposure sensitivity was low at 360 mJ / cm ² .

EFFECTS OF THE INVENTION The photosensitive resin composition according to the present invention is produced by a special method in which an amide compound having a carbon-carbon double bond polymerizable with actinic radiation and having excellent solubility in polyamic acid is used as a solvent. The solvent itself is 100% photosensitive, the ends of the polyamide are photosensitive, and the addition of an amino acrylate compound and a sensitizer that have an affinity for polyamic acid results in extremely high It has been found that a sensitive resin composition can be easily produced.

Continuation of the front page (51) Int.Cl. ⁶ Identification number Internal reference number FI Technical indication H05K 3/06 H (56) Reference JP-A-49-40349 (JP, A) JP-A-54-102393 ( JP, A-113748 (JP, A) JP-A-55-121435 (JP, A) JP-A-60-135457 (JP, A) JP-A-61-118423 (JP, A) JP-A Sho 55-9538 (JP, A) JP-A-4-70661 (JP, A)

Claims (1)

[Claims] 1. A polyamic acid compound [I] having (A) an actinic radiation functional group P ^* at both ends. (In the formula, n = 2 to 5 R ₁ : H, CH ₃ R ₂ : organic residue) (In the formula, m is an integer of 10 to 10,000, R ₃ and R _{4 are} aromatic cyclic groups) (B) An amino acrylate compound represented by the following formula [II] (Wherein, X: -H or -CH ₃ radical Y: -CH ₃ or -CH ₂ CH ₃ group) (C) the polymerizable carbon with a solution like actinic radiation at room temperature for use in the synthesis of the polyamic acid compound An amide compound containing a carbon double bond, (D) absorption maximum (λmax) of 330 to
A photosensitive resin composition comprising a sensitizer having a wavelength of 500 nm as an essential component.