JPH08175856A - Method for treating concrete waste material - Google Patents

Method for treating concrete waste material

Info

Publication number
JPH08175856A
JPH08175856A JP33673894A JP33673894A JPH08175856A JP H08175856 A JPH08175856 A JP H08175856A JP 33673894 A JP33673894 A JP 33673894A JP 33673894 A JP33673894 A JP 33673894A JP H08175856 A JPH08175856 A JP H08175856A
Authority
JP
Japan
Prior art keywords
concrete
aggregate
waste material
cement
concrete waste
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP33673894A
Other languages
Japanese (ja)
Other versions
JP3602588B2 (en
Inventor
Satoru Fujii
悟 藤井
Katsushi Ono
勝史 小野
Yasumi Matsunaga
保美 松永
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taiheiyo Cement Corp
Original Assignee
Chichibu Onoda Cement Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chichibu Onoda Cement Corp filed Critical Chichibu Onoda Cement Corp
Priority to JP33673894A priority Critical patent/JP3602588B2/en
Publication of JPH08175856A publication Critical patent/JPH08175856A/en
Application granted granted Critical
Publication of JP3602588B2 publication Critical patent/JP3602588B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/16Waste materials; Refuse from building or ceramic industry
    • C04B18/167Recycled materials, i.e. waste materials reused in the production of the same materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Civil Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

PURPOSE: To effectively recover an aggregate and having the same characteristics as those of an aggregate and a cement component from a concrete waste material. CONSTITUTION: A concrete waste material is coarsely ground into a concrete bulk, which is calcined preferably at 300-700 deg.C, ground, sieved into an aggregate part and a mortar part and recovered as a concrete aggregate and/or a cement raw material.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は、コンクリート廃材か
らコンクリート骨材及び/又はセメント用原料を分離、
回収する方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention This invention separates concrete aggregate and / or cement raw material from concrete waste material.
Regarding the method of collecting.

【0002】[0002]

【従来の技術】近年、コンクリート建造物の解体に伴
い、コンクリート廃材が大量に発生し、その処理が問題
となっている。その一部分は、埋め立て用や路盤舗装用
の材料として利用されているが、大部分は自然界に廃
棄、放置されたままとなっており環境問題を引き起こし
ている。また省資源の観点から、コンクリート廃材から
コンクリート骨材及び/又はセメント用原料を分離、回
収して新たなコンクリート原料として再利用することが
行われている。コンクリート廃材のリサイクル方法につ
いては、機械的破砕を行い、大径の骨材部分と微粉のモ
ルタル部分とに篩分けし、それぞれコンクリート骨材及
びセメント用原料として回収する方法が提案されてい
る。
2. Description of the Related Art In recent years, with the dismantling of concrete structures, a large amount of waste concrete is generated, and its treatment has become a problem. A part of it is used as a material for land reclamation and roadbed paving, but most of it is left in the natural world and left abandoned, causing environmental problems. Further, from the viewpoint of resource saving, concrete aggregates and / or raw materials for cement are separated and recovered from concrete waste materials and reused as new concrete raw materials. As a method for recycling concrete waste material, a method has been proposed in which mechanical crushing is performed, and the material is sieved into a large-diameter aggregate portion and a fine powder mortar portion, and then recovered as a concrete aggregate and a raw material for cement, respectively.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、従来の
処理方法のように単に物理的に破砕して篩分けする方法
では、回収骨材の表面にセメント水和物が残存してお
り、新骨材に比べて比重が小さく、吸水率が大きく、ま
たすりへりが大きなものとなる。同時に、セメント原料
の回収量も低下する。このように、従来の処理方法によ
り回収された骨材では、コンクリート用骨材としては耐
久性に欠けるため、その使用範囲もコンクリート品質を
低下させない使用量にとどめるとか、特に高強度を要求
されない構造物に使用する等、その用途が極めて限定さ
れている。従って、コンクリート廃材のリサイクル品の
大部分は、再生クラッシャーランや粒調砕石代替品等い
わゆる低処理品として利用されている現状にある。本発
明は上記の問題点に鑑みてなされたもので、コンクリー
ト廃材から新骨材と同等の特性を備える骨材並びにセメ
ント成分を有効に回収することを目的とする。
However, in the method of merely physically crushing and sieving as in the conventional treatment method, the cement hydrate remains on the surface of the recovered aggregate, and the new aggregate is Compared with, the specific gravity is smaller, the water absorption is larger, and the abrasion is larger. At the same time, the amount of cement raw material recovered also decreases. In this way, the aggregate recovered by the conventional treatment method lacks durability as an aggregate for concrete, so that the range of use is limited to the amount used that does not deteriorate the concrete quality, or a structure that does not particularly require high strength. Its use is extremely limited, such as when it is used in a product. Therefore, most of the recycled products of concrete waste materials are currently used as so-called low-treated products such as recycled crusher runs and grain-crushed stone substitutes. The present invention has been made in view of the above problems, and an object of the present invention is to effectively recover an aggregate and a cement component having the same properties as a new aggregate from a concrete waste material.

【0004】[0004]

【課題を解決するための手段】上記目的を達成するため
に、本発明に係るコンクリート廃材の処理方法は、コン
クリート廃材を粗砕したコンクリート塊を、仮焼処理し
た後、粉砕、篩分けして骨材部分とモルタル部分とに分
離し、コンクリート骨材及び/又はセメント原料として
回収することを特徴とする。同様の目的を達成するため
に、本発明に係るコンクリート廃材の処理方法は、前記
仮焼処理を300〜700℃の温度範囲で行うことを特
徴とする。
In order to achieve the above object, a method for treating a concrete waste material according to the present invention is a method in which a concrete mass obtained by roughly crushing a concrete waste material is calcined, then crushed and sieved. It is characterized in that it is separated into an aggregate part and a mortar part and recovered as a concrete aggregate and / or a cement raw material. In order to achieve the same object, the method for treating a concrete waste material according to the present invention is characterized in that the calcination treatment is performed in a temperature range of 300 to 700 ° C.

【0005】[0005]

【作用】従来技術の問題点は、骨材部分とセメント水和
物部分とが有効に分離できないことに起因する。即ち、
機械的破砕によってダウンサイジングは可能であるが、
その破砕物は(同一粒径群においても)、骨材とセメン
ト水和物の混合物であり、両者が分離できていない。そ
して、このような骨材とセメント水和物の混在により、
骨材としての特性(比重、吸水率、すりへり)低下が起
こり、骨材としての使用を限定したものにしている。本
発明に係るコンクリート廃材の処理方法によれば、コン
クリート廃材を粗砕した塊を300〜700℃、好まし
くは450〜600℃の温度範囲で仮焼することによ
り、コンクリート塊に熱的歪を与えてその強度を低下さ
せ、骨材とセメント間の付着力を小さくして破砕され易
い状態にした上で、これを機械的に解砕する。その結
果、解砕後の骨材表面に残存するセメント水和物の量が
従来に比べて大幅に減少して新骨材と同等の特性を備え
た骨材が得られるとともに、セメント成分も有効に回収
できる。
The problem with the prior art is that the aggregate part and the cement hydrate part cannot be effectively separated. That is,
Although downsizing is possible by mechanical crushing,
The crushed material (even in the same particle size group) is a mixture of aggregate and cement hydrate, and both cannot be separated. And, by mixing such aggregate and cement hydrate,
The characteristics (specific gravity, water absorption, abrasion) of the aggregate are deteriorated, which limits its use as an aggregate. According to the method for treating a concrete waste material according to the present invention, a lump obtained by roughly crushing the concrete waste material is calcined in a temperature range of 300 to 700 ° C., preferably 450 to 600 ° C., thereby giving a thermal strain to the concrete lump. Then, the strength of the aggregate is reduced, the adhesive force between the aggregate and the cement is reduced to make it easily crushed, and then this is mechanically crushed. As a result, the amount of cement hydrate remaining on the aggregate surface after crushing is greatly reduced compared to the previous one, and an aggregate with the same properties as the new aggregate is obtained, and the cement component is also effective. Can be collected.

【0006】以下、本発明を詳細に説明する。図1は、
本発明に係るコンクリート廃材の処理方法を示す工程図
である。コンクリート廃材は、先ず解砕機により適当な
径の塊に粗砕される。この粗砕によるコンクリート塊の
大きさは特に限定されるものではないが、後述される仮
焼処理の効率を考慮すると小径であることが好ましい。
The present invention will be described in detail below. Figure 1
It is process drawing which shows the processing method of the concrete waste material based on this invention. The concrete waste material is first crushed by a crusher into lumps having an appropriate diameter. The size of the lump of concrete obtained by this crushing is not particularly limited, but it is preferably small in diameter in consideration of the efficiency of the calcination treatment described later.

【0007】次いで、このコンクリート塊は仮焼炉に投
入され、所定温度で所定時間仮焼処理される。コンクリ
ートは加熱されると、一般にその加熱温度に比例して脆
弱になる。その原因としては、コンクリート中に含まれ
るセメントペーストの水和物が約300℃で脱水を起こ
し、また約500℃付近で消石灰が熱分解を起こすこと
が知られており、水和物の脱水や消石灰が生石灰に変換
する際の体積減少により空隙が発生し、その結果コンク
リート中の細孔が拡大したり、クラックが発生してセメ
ント成分と骨材との付着力が低下するものと考えられ
る。従って、300℃以下では長時間加熱しないと十分
に脱水しないばかりか、完全脱水しても空隙が少なく、
セメントペーストと骨材とを容易に分離可能とする程の
付着力の低下を実現できない。一方700℃以上の高温
での加熱では、コンクリートは脆弱になりペースト部、
細及び粗骨材の分離は容易となるものの、骨材として砂
岩や花崗岩系骨材が使用されている場合、これらが熱劣
化を起こすため好ましくない。特に最近では、粗骨材と
して石灰石の使用が多くなっており、700℃以上の高
温では熱分解破壊を起こす。
Next, this concrete block is put into a calcining furnace and calcined at a predetermined temperature for a predetermined time. When concrete is heated, it generally becomes brittle in proportion to its heating temperature. It is known that the hydrate of cement paste contained in concrete causes dehydration at about 300 ° C, and that slaked lime thermally decomposes at about 500 ° C. It is considered that voids are generated due to the volume reduction when slaked lime is converted into quick lime, and as a result, pores in the concrete are expanded or cracks are generated to reduce the adhesive force between the cement component and the aggregate. Therefore, if it is not heated at a temperature below 300 ° C. for a long time, it will not be sufficiently dehydrated, but even if it is completely dehydrated, there will be few voids,
It is not possible to reduce the adhesive strength to such an extent that the cement paste and the aggregate can be easily separated. On the other hand, when heated at a high temperature of 700 ° C or higher, the concrete becomes brittle and the paste part,
Although it is easy to separate fine and coarse aggregates, when sandstone or granite type aggregates are used as aggregates, they are not preferable because they cause thermal deterioration. Particularly recently, limestone is increasingly used as coarse aggregate, and pyrolysis fracture occurs at high temperatures of 700 ° C. or higher.

【0008】図2は、コンクリート供試体(直径100
mm、高さ200mmの円筒体)を仮焼温度を変えて2
時間仮焼した場合の圧縮強度比を示すグラフであるが、
同図から明らかなように、仮焼温度が高くなるのに伴い
圧縮強度比が逓減しており、仮焼の効果が確認された。
また図3は、同一仮焼条件における供試体のすりへり試
験による減量を示すグラフであるが、仮焼温度が高くな
るのに伴いすりへり減量も増大しているのが判る。
FIG. 2 shows a concrete specimen (diameter 100
2 mm by changing the calcination temperature.
It is a graph showing the compression strength ratio when calcined for a time,
As is clear from the figure, the compressive strength ratio gradually decreases with increasing calcination temperature, confirming the effect of calcination.
Further, FIG. 3 is a graph showing the weight loss of the test piece under the same calcination condition by the abrasion test, and it can be seen that the abrasion loss increases as the calcination temperature increases.

【0009】このように、仮焼温度はコンクリート原料
の種類に関わらず概ね300〜700℃の範囲が好まし
い。また骨材に悪影響を与えることなくペースト部、細
及び粗骨材を回収可能にすることを考慮する場合には、
450〜600℃の範囲とすることが望ましい。また、
仮焼時間は特に限定されるものでなく、粗砕コンクリー
ト塊の大きさや処理量等により適宜設定される。
Thus, the calcination temperature is preferably in the range of approximately 300 to 700 ° C. regardless of the type of concrete raw material. When considering making it possible to recover the paste portion, fine and coarse aggregate without adversely affecting the aggregate,
It is desirable to set it in the range of 450 to 600 ° C. Also,
The calcination time is not particularly limited, and is appropriately set depending on the size of the crushed concrete lump, the treatment amount, and the like.

【0010】仮焼後、コンクリート塊は再び解砕機によ
り破砕され、所定粒径群に篩分けされ、粒径に応じて骨
材およびセメント原料としてそれぞれ回収される。この
篩分けにより、例えば粒度0.15mm以下の成分をセ
メント原料として、また粒度0.6mm以上の成分を骨
材として回収する。
After the calcination, the concrete mass is crushed again by a crusher, sieved to a predetermined particle size group, and collected as an aggregate and a cement raw material according to the particle size. By this sieving, for example, a component having a particle size of 0.15 mm or less is recovered as a cement raw material, and a component having a particle size of 0.6 mm or more is recovered as an aggregate.

【0011】[0011]

【実施例】以下、実施例により本発明を更に明確にする
ことができる。 〔実施例1〕骨材として川砂及び川砂利を用いた打設後
約40年経過した建設物のコンクリート廃材を解砕機に
より粗砕し、550℃で仮焼処理した後、その廃材塊3
00kgを内径1000mm×長さ1500mmの空ミ
ルに投入して回転数30rpmで30分間回転した。回
転後、コンクリート廃材を排出して各粒群に篩分け、粒
群中のCaO量を測定した。測定結果を表1に示す。
The present invention can be further clarified by the following examples. [Example 1] A concrete waste material of a construction about 40 years after casting using river sand and river gravel as an aggregate was roughly crushed by a crusher and calcined at 550 ° C, and then the waste material lump 3
00 kg was put into an empty mill having an inner diameter of 1000 mm and a length of 1500 mm and rotated at a rotation speed of 30 rpm for 30 minutes. After the rotation, the waste concrete material was discharged and sieved into each particle group, and the amount of CaO in the particle group was measured. Table 1 shows the measurement results.

【0012】[0012]

【表1】 [Table 1]

【0013】表1から、粒度0.6mm以上の大径粒群
は骨材成分となるが、CaO含有割合が極めて少ないこ
とから、セメント水和物が表面に殆ど残存せず、骨材部
分とモルタル部分とが極めて良好に分離されていること
がわかる。また、骨材試験に供したところ、回収骨材は
コンクリート用材料として十分使用可能であることが確
認された。また、粒度0.6mm以下の粒群はモルタル
成分であるが、特に粒度0.15mm以下の粒群はCa
O含有割合が高く、セメント原料として充分に再利用可
能である。
From Table 1, large-diameter particles having a particle size of 0.6 mm or more are aggregate components, but since the CaO content is extremely low, almost no cement hydrate remains on the surface and the aggregate part is It can be seen that the mortar part and the mortar part are separated very well. In addition, when subjected to an aggregate test, it was confirmed that the recovered aggregate was sufficiently usable as a concrete material. Further, particles having a particle size of 0.6 mm or less are mortar components, but particles having a particle size of 0.15 mm or less are Ca.
It has a high O content and can be sufficiently reused as a cement raw material.

【0014】〔実施例2〕材令約20年の砕石コンクリ
ート廃材を解砕機により粗砕し、600℃で仮焼処理し
た後、その廃材塊350kgと30mmφの鉄ボール5
0個とを内径1000mm×長さ1500mmの空ミル
に投入して回転数30rpmで10分間回転した。回転
後、コンクリート廃材を排出して各粒群に篩分け、粒群
中のCaO量を測定した。測定結果を表2に示す。
[Example 2] A crushed concrete waste material of about 20 years old was roughly crushed by a crusher and calcined at 600 ° C, and then 350 kg of the waste material and an iron ball 5 of 30 mmφ
0 pieces were put into an empty mill having an inner diameter of 1000 mm and a length of 1500 mm, and were rotated at a rotation speed of 30 rpm for 10 minutes. After the rotation, the waste concrete material was discharged and sieved into each particle group, and the amount of CaO in the particle group was measured. The measurement results are shown in Table 2.

【0015】[0015]

【表2】 [Table 2]

【0016】実施例1と同様、表2から骨材部分とモル
タル部分とが極めて良好に分離されていることがわか
る。
As in Example 1, it can be seen from Table 2 that the aggregate portion and the mortar portion are separated very well.

【0017】[0017]

【発明の効果】以上説明したように、本発明に係るコン
クリート廃材の処理方法によれば、コンクリート廃材を
粗砕した塊を仮焼することにより、コンクリート塊に熱
的歪を与えてその強度を低下させ、骨材とセメント間の
付着力を小さくして破砕され易い状態にした上で、これ
を機械的解砕する結果、解砕後の骨材表面に残存するセ
メント水和物の量が従来に比べて大幅に減少して新骨材
と同等の特性を備えた骨材が得られるとともに、セメン
ト成分も有効に回収できる。
As described above, according to the method for treating a concrete waste material according to the present invention, a lump obtained by roughly crushing the concrete waste material is calcined to give a thermal strain to the concrete lump to increase its strength. The amount of cement hydrate remaining on the aggregate surface after crushing was reduced as a result of mechanically crushing it after reducing the adhesive force between the aggregate and cement to make it crushable. The aggregate is significantly reduced compared to the conventional one, and an aggregate having the same characteristics as the new aggregate can be obtained, and the cement component can also be effectively recovered.

【図面の簡単な説明】[Brief description of drawings]

【図1】 本発明に係るコンクリート廃材の処理方法を
示す工程図である。
FIG. 1 is a process drawing showing a method for treating a concrete waste material according to the present invention.

【図2】 コンクリート試供体の仮焼温度に対する圧縮
強度比を測定したグラフである。
FIG. 2 is a graph in which a compressive strength ratio with respect to a calcination temperature of a concrete sample is measured.

【図3】 コンクリート試供体の仮焼温度に対するすり
へり減量を測定したグラフである。
FIG. 3 is a graph in which the amount of abrasion loss with respect to the calcination temperature of a concrete sample is measured.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 コンクリート廃材を粗砕したコンクリー
ト塊を、仮焼処理した後、粉砕、篩分けして骨材部分と
モルタル部分とに分離し、コンクリート骨材及び/又は
セメント原料として回収することを特徴とするコンクリ
ート廃材の処理方法。
1. A method of calcination, crushing and sieving a concrete block obtained by roughly crushing waste concrete to separate it into an aggregate part and a mortar part, and recovering as concrete aggregate and / or cement raw material. A method for treating a concrete waste material, which is characterized by:
【請求項2】 前記仮焼処理を、300〜700℃の温
度範囲で行うことを特徴とする請求項1記載のコンクリ
ート廃材の処理方法。
2. The method for treating concrete waste according to claim 1, wherein the calcination treatment is performed in a temperature range of 300 to 700 ° C.
JP33673894A 1994-12-26 1994-12-26 Concrete waste treatment method Expired - Fee Related JP3602588B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP33673894A JP3602588B2 (en) 1994-12-26 1994-12-26 Concrete waste treatment method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP33673894A JP3602588B2 (en) 1994-12-26 1994-12-26 Concrete waste treatment method

Publications (2)

Publication Number Publication Date
JPH08175856A true JPH08175856A (en) 1996-07-09
JP3602588B2 JP3602588B2 (en) 2004-12-15

Family

ID=18302271

Family Applications (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010143656A1 (en) * 2009-06-09 2010-12-16 株式会社竹中工務店 Hydraulic cement composition
JP2016198737A (en) * 2015-04-13 2016-12-01 ニッポウ興産株式会社 Method for treating waste gravestone

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010143656A1 (en) * 2009-06-09 2010-12-16 株式会社竹中工務店 Hydraulic cement composition
JP2010285302A (en) * 2009-06-09 2010-12-24 Tokyo Institute Of Technology Hydraulic cement composition
JP2016198737A (en) * 2015-04-13 2016-12-01 ニッポウ興産株式会社 Method for treating waste gravestone

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