JPH0826794A - Production of cement - Google Patents

Production of cement

Info

Publication number
JPH0826794A
JPH0826794A JP6182944A JP18294494A JPH0826794A JP H0826794 A JPH0826794 A JP H0826794A JP 6182944 A JP6182944 A JP 6182944A JP 18294494 A JP18294494 A JP 18294494A JP H0826794 A JPH0826794 A JP H0826794A
Authority
JP
Japan
Prior art keywords
cement
composition
concrete
crushed
mortar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6182944A
Other languages
Japanese (ja)
Inventor
Toru Saito
亨 斎藤
Shunichiro Uchida
俊一郎 宇智田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chichibu Onoda Cement Corp
Original Assignee
Chichibu Onoda Cement Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chichibu Onoda Cement Corp filed Critical Chichibu Onoda Cement Corp
Priority to JP6182944A priority Critical patent/JPH0826794A/en
Publication of JPH0826794A publication Critical patent/JPH0826794A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/24Cements from oil shales, residues or waste other than slag
    • C04B7/246Cements from oil shales, residues or waste other than slag from waste building materials, e.g. waste asbestos-cement products, demolition waste
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/38Preparing or treating the raw materials individually or as batches, e.g. mixing with fuel
    • C04B7/42Active ingredients added before, or during, the burning process
    • C04B7/421Inorganic materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding

Abstract

PURPOSE:To effectively utilize waste concrete and to raise the the value added by reproducing a fresh cement material from waste mortar and concrete. CONSTITUTION:Waste mortar and concrete are crushed, a calcareous compd., siliceous compd., alumina component, etc., are added to the crushed material, the composition is adjusted to attain the chemical composition of ordinary cement material, and the composition is calcined to produce a reproduced cement clinker. The clinker is crushed or mixed with other cement materials and used as a fresh cement material.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、セメントの製造方法、
特にモルタルやコンクリ−ト廃材から再生セメントを製
造する方法に関する。
FIELD OF THE INVENTION The present invention relates to a method for producing cement,
In particular, it relates to a method for producing recycled cement from mortar and concrete waste materials.

【0002】[0002]

【従来の技術】近年、道路や橋梁、上下水道、住宅等の
社会資本の整備や、ビルや工場等の高層化や大型化に伴
い、その建設土木工事に付随して発生する建設廃材は膨
大な量となっており、今後益々増加することが予想され
ている。特に、建設廃材のうち発生量が多いコンクリ−
ト廃材に関しては、その一部が路盤やアスファルト舗装
等の床材、あるいは山間部や海面の埋め立て用材料とし
て再利用されているものの、大部分はそのまま廃棄され
ているのが現状である。しかし、廃棄処理地の不足や遠
隔化、あるいはその管理等、廃材の処理に関する諸問題
が発生し、環境汚染とも関連して大きな社会問題となっ
ている。
2. Description of the Related Art In recent years, with the development of social capital such as roads, bridges, water and sewage systems, housing, etc., as well as the rise and increase in size of buildings and factories, the amount of construction waste that accompanies the construction works has been enormous. However, it is expected that it will increase more and more in the future. In particular, concrete that produces a large amount of construction waste
Regarding waste materials, some of them are reused as floor materials for roadbeds, asphalt pavements, etc., or as landfill materials for mountains and the sea surface, but most of them are currently discarded. However, various problems related to the disposal of waste materials such as shortage of waste disposal sites, remoteization, or management thereof have become a major social problem in connection with environmental pollution.

【0003】そこで、環境保護や省資源の面から、コン
クリ−ト廃材を有効に再利用する方法が強く望まれてお
り、これまでにも各種の方法が提案されている。例え
ば、特開昭53−126028号広報には、コンクリ−
ト廃材を粉砕して角を落とし、水洗乾燥後に樹脂系乳剤
で表面処理したものを、セメントや砂と混合して石材と
して加工する方法が開示されている。
Therefore, from the viewpoint of environmental protection and resource saving, there is a strong demand for a method for effectively recycling concrete waste materials, and various methods have been proposed so far. For example, in the publication of JP-A-53-126028, the concrete
A method is disclosed in which waste materials are crushed to remove horns, washed with water and dried, and then surface-treated with a resin emulsion, and mixed with cement or sand to be processed into stone materials.

【0004】[0004]

【発明が解決しようとする課題】記述したようにコンク
リ−ト廃材は、一部が路盤やアスファルト舗装等の床材
として再利用されているものの、その大部分は山間部や
海面の埋め立て用材料として利用されているだけであ
り、その利用範囲も狭く、付加価値も高いものではな
い。
As described above, although some concrete waste materials are reused as floor materials for roadbeds, asphalt pavements, etc., most of them are landfill materials for mountains and sea surfaces. It is only used as a product, its range of use is narrow, and its added value is not high.

【0005】本発明は、モルタルやコンクリ−ト廃材を
再生セメントに転化してモルタルやコンクリ−ト生成用
原料とすることにより、その利用範囲を広げると同時に
付加価値を高めることを目的とするものである。
It is an object of the present invention to expand the range of use and increase added value by converting mortar and concrete waste materials into recycled cement to obtain raw materials for mortar and concrete production. Is.

【0006】[0006]

【課題を解決するための手段】本発明者らは、モルタル
やコンクリ−ト廃材の再生に関する前記課題を解決すべ
く鋭意研究を重ねた結果、廃材破砕物から新たなセメン
トに転化できることを見いだし、本発明を完成するに至
った。即ち、前記課題は、(1)モルタル・コンクリ−
ト廃材を粉砕し、これをセメント原料の一部として焼成
すること、(2)モルタル・コンクリ−ト廃材を粉砕す
るとともに組成調整し、これをセメント原料として焼成
すること、(3)モルタル・コンクリ−ト廃材を粉砕す
るとともに組成調整し、これをセメント原料として焼成
した焼結体(クリンカ−)を他のセメントと混合使用す
ること、(4)組成調整に当たり、石灰質成分、ケイ酸
質成分、アルミナ質成分、鉄質成分の少なくとも一つ以
上を添加することを特徴とするセメントの製造方法によ
り解決することができる。
[Means for Solving the Problems] As a result of intensive studies to solve the above-mentioned problems concerning the regeneration of mortar and concrete waste materials, the present inventors have found that waste material crushed materials can be converted into new cement, The present invention has been completed. That is, the above-mentioned problems are (1) mortar concrete
(2) crushing the waste materials to be crushed and firing it as a part of the cement raw material; (2) crushing the mortar concrete waste material and adjusting the composition, and firing it as the cement raw material; (3) mortar concrete -To crush the waste material and adjust the composition, and mix and use a sintered body (clinker) obtained by firing this as a cement raw material with other cement. (4) In adjusting the composition, a calcareous component, a siliceous component, This can be solved by a method for producing cement, which is characterized by adding at least one of an alumina component and an iron component.

【0007】以下に、本発明に係るセメントの製造方法
を詳細に説明する。回収モルタルやコンクリ−ト廃材を
公知の粉砕機により破砕する。この粉砕物はセメントの
水和物及び骨材の混合物から構成されるが、骨材は川
砂、山砂、海砂の他、最近は石灰石骨材、人工骨材等種
々雑多な物が使用され、初期のCaO/SiO2モル比
が異なる他、モルタルやコンクリ−ト廃材の種類により
バラツキも大きい。
The method for producing cement according to the present invention will be described in detail below. The recovered mortar and concrete waste materials are crushed by a known crusher. This pulverized product is composed of a mixture of cement hydrate and aggregate, but recently various other substances such as river sand, mountain sand, sea sand, limestone aggregate and artificial aggregate are used. The initial CaO / SiO 2 molar ratio is different, and the variation is large depending on the type of mortar and concrete waste.

【0008】そこで、市販のポルトランドセメントに比
べてCaO/SiO2モル比が低下している場合が多
く、主として石灰石粉末等の石灰質成分を添加してCa
O/SiO2モル比の調整を行う。このCaO/SiO2
モル比の最適値は、セメント水和物の組成や廃材の材令
(経時日数)によって異なるが、2.0〜5.0の範
囲、望ましくは2.3〜3.0の範囲、更に望ましくは
2.7〜2.9の範囲に設定されることが望ましい。C
aO量が多くなると水和熱や硬化体の膨張が大きくな
り、逆にモル比が小さくなるとセメント組成がC2S側
にシフトして石英成分が多く晶析し、いずれの場合もコ
ンクリ−トの機械的強度を低下させる要因となる。
Therefore, the CaO / SiO 2 molar ratio is often lower than that of commercially available Portland cement, and Ca is mainly added by adding calcareous components such as limestone powder.
The O / SiO 2 molar ratio is adjusted. This CaO / SiO 2
The optimum value of the molar ratio varies depending on the composition of the cement hydrate and the age of the waste material (the number of days elapsed), but is in the range of 2.0 to 5.0, preferably 2.3 to 3.0, and more preferably Is preferably set in the range of 2.7 to 2.9. C
When the amount of aO increases, the heat of hydration and expansion of the hardened product increase, and conversely, when the molar ratio decreases, the cement composition shifts to the C 2 S side and a large amount of quartz component crystallizes, and in either case, the concrete Cause a decrease in the mechanical strength of.

【0009】また、モルタルやコンクリ−ト廃材の種類
によっては、CaO分が多く含有されている場合があ
る。この場合は、石灰石の代わりに粘土やケイ石、ケイ
砂等のケイ酸質成分を添加してCaO/SiO2モル比
の調整を行う。更に、粘土やスラグ、フライアッシュ、
銅ガラミやAl(OH)3やFe(OH)3等のアルミナ
質成分や鉄質成分等を添加して、Al23やFe23
のセメント成分の組成調整を行い、CaO/(SiO2
+Al23+Fe23)モル比として2.0〜5.0、
望ましくは2.2〜3.0の範囲として、出来るだけ市
販のポルトランドセメントの化学組成に近づけることが
望ましい。このモル比調整済粉砕物を、1000〜14
50℃、好ましくは1350〜1450℃の高温で1〜
4時間焼成して、再生セメントクリンカ−を生成する。
Further, depending on the type of mortar or concrete waste material, a large amount of CaO may be contained. In this case, a CaO / SiO 2 molar ratio is adjusted by adding a siliceous component such as clay, silica stone, and silica sand instead of limestone. Furthermore, clay, slag, fly ash,
The composition of the cement components such as Al 2 O 3 and Fe 2 O 3 is adjusted by adding alumina components such as copper burrs and Al (OH) 3 and Fe (OH) 3 and iron components, and CaO / (SiO 2
+ Al 2 O 3 + Fe 2 O 3 ) molar ratio of 2.0 to 5.0,
Desirably, the range of 2.2 to 3.0 is set as close as possible to the chemical composition of commercially available Portland cement. The pulverized product with the adjusted molar ratio is 1000 to 14
1 at a high temperature of 50 ° C, preferably 1350 to 1450 ° C
Bake for 4 hours to produce a recycled cement clinker.

【0010】この再生セメントクリンカ−に、凝結調整
剤として重量比で数%程度、例えば1〜5重量%の二水
石膏を添加した後、ボ−ルミル等により粉砕して再生セ
メントを生成する。この時の再生セメントクリンカ−の
粉砕状態は、ブレ−ン比表面積で2700cm2/g程
度以上が望ましい。また、モルタルやコンクリ−ト廃材
の粉砕物は、これを組成調整し、あるいは組成調整する
ことなく、既存のセメント製造プラントにおいてセメン
ト原料の一部として15%程度以下添加、焼成してセメ
ントを製造することも可能である。
A few% by weight, for example 1 to 5% by weight, of gypsum dihydrate is added to the recycled cement clinker as a coagulation modifier and then crushed by a ball mill or the like to produce recycled cement. At this time, the crushed state of the recycled cement clinker is preferably about 2700 cm 2 / g or more in terms of the specific surface area of the brain. In addition, crushed mortar and concrete waste materials are either adjusted in composition or, without adjusting the composition, added in an existing cement manufacturing plant at a rate of about 15% or less as a part of cement raw material and fired to produce cement. It is also possible to do so.

【0011】以上説明したように、本発明によると、モ
ルタルやコンクリ−ト廃材から新たなセメントを再生す
ることができるため、コンクリ−ト廃材の有効利用に加
えて、その付加価値を高めることが出来る。
As described above, according to the present invention, since new cement can be regenerated from mortar and concrete waste material, the added value can be increased in addition to the effective use of concrete waste material. I can.

【0012】[0012]

【実施例】本発明に係るコンクリ−ト廃材の処理方法に
関して、実施例を基により詳細に説明する。但し、本発
明は以下に記載される実施例に限定されずに、種々の変
更が可能である。 〔実施例1〕20年経過した建築物の改修工事現場から
採取した天然川砂を骨材としたコンクリ−ト廃材を、1
00μm以下に粉砕した。この粉砕物をJIS R 5
202に準拠して化学分析を行った。分析結果を表1−
(1)に示す。表1−(1)から明らかなように骨材成
分よりCaO/SiO2モル比は、0.212程度にま
で低下しており、X線解析を行ったところ石英のピ−ク
が大きく認められた。この粉砕物に石灰石粉末及びフラ
イアッシュ粉末を添加して、CaO/SiO2モル比を
2.8に調整した後、1450℃で1時間焼成して再生
セメントクリンカ−を得た。得られた再生セメントクリ
ンカ−の化学分析値(JIS R 5202に準拠)を
表2に示す。表2には比較のために普通ポルトランドセ
メントの化学分析値を併記するが、同表から本発明によ
る再生セメントクリンカ−は普通ポルトランドセメント
に比し、CaO及びSiO2をやや多く含むが、略め同
一の組成である。
EXAMPLES The method for treating concrete waste material according to the present invention will be described in detail based on examples. However, the present invention is not limited to the examples described below, and various modifications can be made. [Example 1] A concrete waste material containing natural river sand as an aggregate, which was collected from a building repair work site 20 years old
It was crushed to a size of 00 μm or less. This crushed product is JIS R 5
Chemical analysis was performed according to 202. The analysis results are shown in Table 1-
It shows in (1). As is clear from Table 1- (1), the CaO / SiO 2 molar ratio was reduced to about 0.212 compared with the aggregate component, and when X-ray analysis was performed, a large peak of quartz was recognized. It was Limestone powder and fly ash powder were added to this crushed product to adjust the CaO / SiO 2 molar ratio to 2.8, and then the mixture was fired at 1450 ° C. for 1 hour to obtain a recycled cement clinker. Table 2 shows the chemical analysis values (according to JIS R 5202) of the obtained recycled cement clinker. Table 2 also shows chemical analysis values of ordinary Portland cement for comparison. From the same table, the recycled cement clinker according to the present invention contains CaO and SiO 2 in a relatively large amount as compared with ordinary Portland cement, but is omitted. It has the same composition.

【0013】再生セメントクリンカ−に二水石膏(脱硫
石膏)を再生セメントクリンカ−に対して3重量%添加
し、これをスチ−ルボ−ルミルを用いてブレ−ン値35
00cm3/gにまで粉砕して再生セメントを得た。得
られた再生セメントをJIS R 5201に準拠して
凝結及び強度試験を実施し、普通ポルトランドセメント
との比較検討を行った。
Gypsum dihydrate (desulfurized gypsum) was added to the recycled cement clinker in an amount of 3% by weight based on the recycled cement clinker, and this was blown with a steel ball mill to a brain value of 35.
The recycled cement was obtained by crushing to a size of 00 cm 3 / g. The obtained regenerated cement was subjected to a setting and strength test in accordance with JIS R 5201, and a comparative study with ordinary Portland cement was carried out.

【0014】標準軟度のペ−ストを作成するための水/
セメント混合比は、普通ポルトランドセメントが0.2
7であったのに対し、再生セメントでは0.28であっ
た。また、凝結時間に関しては普通ポルトランドセメン
トは、始発90分及び終結150分であったのに対し
て、再生セメントは始発85分及び終結150分であっ
た。尚、両者ともに偽凝結は起こらなかった。
Water for making a paste of standard softness /
The cement mixing ratio is 0.2 for ordinary Portland cement.
It was 7 while it was 0.28 in the recycled cement. Regarding the setting time, the ordinary Portland cement had a starting time of 90 minutes and a finishing time of 150 minutes, whereas the regenerated cement had a starting time of 85 minutes and a finishing time of 150 minutes. Neither of them caused false condensation.

【0015】このように、再生セメントは、普通ポルト
ランドセメントと同様の凝結特性を示すことが確認され
た。また、再生セメント及び普通ポルトランドセメント
について、セメント/標準砂重量比0.5及びセメント
/水重量比0.65の割合で配合してモルタルを作成
し、圧縮強度を測定した。28日圧縮強度を比較する
と、普通ポルトランドセメントが約385kgf/cm
2であるのに対し、再生セメントは約160kgf/c
2であり、普通ポルトランドセメントの1/3〜1/
2であった。
As described above, it was confirmed that the regenerated cement exhibits the setting property similar to that of the ordinary Portland cement. Reclaimed cement and ordinary Portland cement were mixed at a cement / standard sand weight ratio of 0.5 and a cement / water weight ratio of 0.65 to prepare mortar, and the compressive strength was measured. Comparing the 28-day compressive strength, normal Portland cement is about 385 kgf / cm
2 , whereas recycled cement is about 160 kgf / c
m 2 which is 1/3 to 1/1 of that of ordinary Portland cement
It was 2.

【0016】そこで、前記コンクリ−ト廃材粉末に、粘
土、ケイ石、銅ガラミ粉末をそれぞれ添加し、CaO/
(SiO2+Al23+Fe23)モル比が2.47に
なるように普通ポルトランドセメントのモル比2.44
に近づけたところ、28日圧縮強度が約360kgf/
cm2にまで増加した。また、再生セメントと普通ポル
トランドセメントとを同量の割合で混合してモルタルを
作成したところ、28日圧縮強度が約375kgf/c
2にまで増加した。 〔実施例2〕普通ポルトランドセメントと豊浦ケイ石標
準砂(300μm以上1%、106μm以上95%)
を、セメント/標準砂重量比0.5及びセメント/水重
量比0.65の割合で配合して作成したセメント−ケイ
石系モルタル(材令1年)を、実施例1と同様に粉砕し
て、化学分析を行った。分析結果を表1−(2)に併記
する。実施例1と同様に、CaO/SiO2モル比は
0.314まで低下しているのが確認された。この粉砕
物に、石灰石粉末(関東化学(株)製)と各種フライア
ッシュを添加してCaO/SiO2モル比を2.7に調
整した後、1450℃で1時間焼成して再生セメントク
リンカ−を得た。得られた再生セメントクリンカ−を、
実施例1と同様の化学分析を行った。分析結果を、表2
に併記する。
Therefore, clay, silica stone, and copper lice powder are added to the concrete waste material powder, respectively, and CaO /
The molar ratio of ordinary Portland cement is 2.44 so that the molar ratio of (SiO 2 + Al 2 O 3 + Fe 2 O 3 ) is 2.47.
, The 28-day compressive strength was about 360 kgf /
increased to cm 2 . Moreover, when mortar was prepared by mixing recycled cement and ordinary Portland cement in the same ratio, the 28-day compressive strength was about 375 kgf / c.
up to m 2 . Example 2 Normal Portland cement and Toyoura silica stone standard sand (300 μm or more 1%, 106 μm or more 95%)
Cement-silica mortar (age 1 year) prepared by blending the above in a ratio of cement / standard sand weight ratio 0.5 and cement / water weight ratio 0.65 was crushed in the same manner as in Example 1. Then, a chemical analysis was performed. The analysis results are also shown in Table 1- (2). As in Example 1, it was confirmed that the CaO / SiO 2 molar ratio had dropped to 0.314. Limestone powder (manufactured by Kanto Kagaku Co., Ltd.) and various fly ash were added to this crushed product to adjust the CaO / SiO 2 molar ratio to 2.7, and then the mixture was fired at 1450 ° C. for 1 hour to regenerate cement clinker. Got The regenerated cement clinker obtained was
The same chemical analysis as in Example 1 was performed. The analysis results are shown in Table 2.
Also described in.

【0017】再生セメントクリンカ−を、実施例1と同
様にして再生セメントを生成し、この再生セメントをも
とにモルタルを作成して同様の強度試験を行った。28
日圧縮強度は、約290kgf/cm2であり、ポルト
ランドセメントの2/3程度の強度を示した。 〔実施例3〕異なる各地の建築物改修工事現場から採取
した材令、使用骨材が雑多に混在するコンクリ−ト廃材
を、実施例1と同様に粉砕して化学分析を行った。分析
結果を、表1−(3)に併記する。この破砕物に石灰石
粉末を添加して、CaO/SiO2モル比を2.74に
調整した後、1450℃で1時間焼成して再生セメント
クリンカ−を得た。得られた再生セメントクリンカ−
を、実施例1と同様に化学分析を行った。分析結果を、
表2に併記する。
Regenerated cement clinker was produced in the same manner as in Example 1, and mortar was prepared based on this regenerated cement and the same strength test was conducted. 28
The daily compressive strength was about 290 kgf / cm 2 , which was about 2/3 that of Portland cement. [Example 3] Concrete waste materials, which were mixed in various ages and aggregates used, collected from different sites of building repair work were ground and subjected to chemical analysis in the same manner as in Example 1. The analysis results are also shown in Table 1- (3). Limestone powder was added to this crushed product to adjust the CaO / SiO 2 molar ratio to 2.74, and then the mixture was fired at 1450 ° C. for 1 hour to obtain a recycled cement clinker. Obtained recycled cement clinker
Was subjected to a chemical analysis in the same manner as in Example 1. Analysis results
It is also shown in Table 2.

【0018】再生セメントクリンカ−を、実施例1と同
様にして再生セメントを生成し、この再生セメントをも
とにモルタルを作成して同様の強度試験を行った。28
日圧縮強度は、約275kgf/cm2であった。そこ
で、実施例1と同様にコンクリ−ト廃材の粉末に、石灰
石粉末に加えて、フライアッシュ、粘土、ケイ石、銅ガ
ラミ粉末をそれぞれ添加してCaO/(SiO2+Al2
3+Fe23)モル比の成分調整を行ったところ、4
11kgf/cm2の圧縮強度を得た。
Regenerated cement clinker was produced in the same manner as in Example 1, and mortar was prepared based on this regenerated cement and the same strength test was conducted. 28
The daily compressive strength was about 275 kgf / cm 2 . Then, in the same manner as in Example 1, in addition to limestone powder, fly ash, clay, silica stone, and copper lice powder were added to the powder of concrete waste material, and CaO / (SiO 2 + Al 2
When the components of O 3 + Fe 2 O 3 ) molar ratio were adjusted, 4
A compressive strength of 11 kgf / cm 2 was obtained.

【0019】[0019]

【表1】 [Table 1]

【0020】[0020]

【表2】 [Table 2]

【0021】[0021]

【発明の効果】以上説明したとおり、本発明に係るセメ
ントの製造方法は、種々雑多な骨材成分を含むモルタル
やコンクリ−ト廃材から新たなセメントとして再生する
ものであり、それらの使用範囲が広がり、付加価値も高
いものとなる。また、再生されるセメントの品質も良好
であり、コンクリ−トとした場合に実用的な強度が得ら
れる。
As described above, the method for producing cement according to the present invention is to regenerate a new cement from mortar or concrete waste material containing various aggregate components, and the range of use thereof is Spread and high added value. In addition, the quality of the recycled cement is good, and when it is made into a concrete, a practical strength can be obtained.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 モルタル・コンクリ−ト廃材を粉砕し、
これをセメント原料の一部として焼成することを特徴と
するセメントの製造方法。
1. A mortar concrete waste material is crushed,
A method for producing cement, which comprises firing this as a part of a cement raw material.
【請求項2】 モルタル・コンクリ−ト廃材を粉砕する
とともに組成調整し、これをセメント原料として焼成す
ることを特徴とするセメントの製造方法。
2. A method for producing cement, which comprises crushing a mortar concrete waste material, adjusting the composition thereof, and firing the mortar concrete waste material as a cement raw material.
【請求項3】 モルタル・コンクリ−ト廃材を粉砕する
とともに組成調整し、これをセメント原料として焼成し
た焼結体(クリンカ−)を他のセメントと混合使用する
ことを特徴とするセメントの製造方法。
3. A method for producing a cement, characterized in that a mortar concrete waste material is pulverized and its composition is adjusted, and a sintered body (clinker) obtained by firing the mortar concrete waste material as a cement raw material is mixed with another cement. .
【請求項4】 組成調整に当たり、石灰質成分、ケイ酸
質成分、アルミ質成分、鉄質成分の少なくとも一つ以上
を添加することを特徴とする請求項2もしくは請求項3
に記載のセメントの製造方法。
4. The composition according to claim 2 or 3, wherein at least one of a calcareous component, a siliceous component, an aluminous component, and a ferrous component is added in adjusting the composition.
The method for producing the cement according to 1.
JP6182944A 1994-07-12 1994-07-12 Production of cement Pending JPH0826794A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6182944A JPH0826794A (en) 1994-07-12 1994-07-12 Production of cement

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6182944A JPH0826794A (en) 1994-07-12 1994-07-12 Production of cement

Publications (1)

Publication Number Publication Date
JPH0826794A true JPH0826794A (en) 1996-01-30

Family

ID=16127102

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6182944A Pending JPH0826794A (en) 1994-07-12 1994-07-12 Production of cement

Country Status (1)

Country Link
JP (1) JPH0826794A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2741615A1 (en) * 1995-11-29 1997-05-30 Commissariat Energie Atomique Hydraulic binder production
JP2004315360A (en) * 2003-03-31 2004-11-11 Mie Prefecture Method for manufacturing hydraulic material utilizing waste material of ceramic-based building material
WO2006059718A1 (en) 2004-12-03 2006-06-08 Mitsubishi Materials Corporation Cement clinker and process for producing the same
KR100597621B1 (en) * 2005-03-04 2006-07-10 한국후라이애쉬시멘트공업(주) Admixture using waste-concrete powder and mortar comprising the same
JP2012006812A (en) * 2010-06-28 2012-01-12 Tokyo Institute Of Technology Regenerated cement raw material and regenerated cement composition using the same
WO2021164798A1 (en) * 2020-02-20 2021-08-26 ERC-TECH a.s. Blended cement
CN116023048A (en) * 2023-03-28 2023-04-28 湖南创速新材料有限公司 Cement clinker and method for preparing cement by using same

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2741615A1 (en) * 1995-11-29 1997-05-30 Commissariat Energie Atomique Hydraulic binder production
JP2004315360A (en) * 2003-03-31 2004-11-11 Mie Prefecture Method for manufacturing hydraulic material utilizing waste material of ceramic-based building material
JP4565126B2 (en) * 2003-03-31 2010-10-20 三重県 Method for producing hydraulic materials using waste materials from ceramics building materials
WO2006059718A1 (en) 2004-12-03 2006-06-08 Mitsubishi Materials Corporation Cement clinker and process for producing the same
KR100597621B1 (en) * 2005-03-04 2006-07-10 한국후라이애쉬시멘트공업(주) Admixture using waste-concrete powder and mortar comprising the same
JP2012006812A (en) * 2010-06-28 2012-01-12 Tokyo Institute Of Technology Regenerated cement raw material and regenerated cement composition using the same
WO2021164798A1 (en) * 2020-02-20 2021-08-26 ERC-TECH a.s. Blended cement
CN116023048A (en) * 2023-03-28 2023-04-28 湖南创速新材料有限公司 Cement clinker and method for preparing cement by using same

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