JPH081295A - Method for pouring molten steel into tundish for continuous casting - Google Patents

Method for pouring molten steel into tundish for continuous casting

Info

Publication number
JPH081295A
JPH081295A JP12861694A JP12861694A JPH081295A JP H081295 A JPH081295 A JP H081295A JP 12861694 A JP12861694 A JP 12861694A JP 12861694 A JP12861694 A JP 12861694A JP H081295 A JPH081295 A JP H081295A
Authority
JP
Japan
Prior art keywords
molten steel
slag
ladle
tundish
injection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP12861694A
Other languages
Japanese (ja)
Other versions
JP3323644B2 (en
Inventor
Takanori Ishii
孝宣 石井
Katsumi Amada
克己 天田
Katsuhiko Noro
克彦 野呂
Susumu Oshima
将 尾島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP12861694A priority Critical patent/JP3323644B2/en
Publication of JPH081295A publication Critical patent/JPH081295A/en
Application granted granted Critical
Publication of JP3323644B2 publication Critical patent/JP3323644B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE:To surely prevent the entrapment of slag at the time of pouring molten steel into a tundish in continuous casting. CONSTITUTION:At the time of executing the continuous casting by pouring molten steel into the tundish from a ladle, the molten steel pouring rate is decreased to such an extent that the development of eddy current of the molten steel is prevented at the end stage of the molten steel pouring, and even such the entrapment of a small quantity of the slag into the molten metal that can't be detected is prevented from occurring. Successively, the slag is detected at the position of the molten steel pouring nozzle in the ladle with the descent of the slag layer in the ladle and the molten metal pouring nozzle is closed based on this detected result.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、連続鋳造用タンディシ
ュへの溶鋼注入方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for pouring molten steel into a tundish for continuous casting.

【0002】[0002]

【従来の技術】鋼の連続鋳造に際しては、周知のごとく
バッファー機能を有する容器、即ちタンディシュ内へ複
数取鍋から交互に溶鋼を注入し、このタンディシュから
連続鋳造鋳型へ溶鋼を注入して連続鋳造するものであ
る。しかして、上記のごとく取鍋からタンディシュ内へ
の溶鋼注入末期においては、取鍋底部の溶鋼注入ノズル
の上部の溶鋼層で渦流が発生し、溶鋼表面に浮遊するス
ラグ層の一部が渦流に巻き込まれて溶鋼とともにタンデ
ィシュへ注入され、鋼製品の品質欠陥の原因となる。こ
のようにスラグを混入した溶鋼が溶鋼注入ノズルに位置
すると、電磁式スラグ流出検知器でスラグを検知し、こ
れに基づきノズルを閉めることが特開昭56−1226
56号、特開平5−277686号に開示されている。
このようなスラグの検出は、一般に2個のコイルを上ノ
ズル外周に配置し、一方のコイルに交流電流を付与して
磁界を発生させ、上ノズル内の溶鋼流にスラグが混入す
ると、コイル内部の透磁率が変化するために、他方のコ
イルに誘導起電力が発生する。この起電力を検出するこ
とによってスラグを検知するものである。
2. Description of the Related Art In continuous casting of steel, as is well known, molten steel is alternately poured from a plurality of ladles into a container having a buffer function, that is, a tundish, and the molten steel is poured from this tundish into a continuous casting mold to continuously cast the steel. To do. At the end of molten steel injection from the ladle into the tundish as described above, a vortex flow is generated in the molten steel layer above the molten steel injection nozzle at the bottom of the ladle, and part of the slag layer floating on the molten steel surface becomes vortex flow. It is caught and injected into the tundish together with molten steel, which causes quality defects of steel products. When the molten steel mixed with the slag is located at the molten steel injection nozzle, the electromagnetic slag outflow detector detects the slag and the nozzle is closed based on the detected slag.
No. 56 and JP-A-5-277686.
To detect such slag, generally, two coils are arranged on the outer circumference of the upper nozzle, an alternating current is applied to one coil to generate a magnetic field, and when the slag is mixed with the molten steel flow in the upper nozzle, the inside of the coil is detected. Induced electromotive force is generated in the other coil due to the change in the magnetic permeability of. The slag is detected by detecting this electromotive force.

【0003】[0003]

【発明が解決しようとする課題】前記のごとく、取鍋か
らのスラグ流出は溶鋼注入末期に溶鋼注入ノズル上部の
溶鋼層に渦流が発生し、溶鋼表面に浮遊しているスラグ
が渦流に引き込まれ溶鋼とともにタンディシュへ注入さ
れる取鍋の残溶鋼量が多いときから少なくなるまで、径
が小さく鋭利な形状をした溶鋼渦流が長時間発生するた
め、これにともない少量のスラグが流出しつづける。こ
の間の溶鋼流出量にしめるスラグ流出量の比は、ほぼ一
定である。次に、溶鋼残量が非常に少なくなると渦流の
径は急激に大きくなり、溶鋼流出量にしめるスラグ流出
量の比は急激に上昇する。
As described above, the slag outflow from the ladle causes a vortex flow in the molten steel layer above the molten steel injection nozzle at the end of molten steel injection, and the slag floating on the molten steel surface is drawn into the vortex flow. Since the molten steel swirl with a small diameter and a sharp shape is generated for a long time from the time when the amount of residual molten steel in the ladle injected into the tundish together with the molten steel decreases to a small amount, a small amount of slag continues to flow out accordingly. During this period, the ratio of the slag outflow rate to the molten steel outflow rate is almost constant. Next, when the molten steel residual amount becomes very small, the diameter of the vortex flow rapidly increases, and the ratio of the slag outflow amount to the molten steel outflow amount rapidly increases.

【0004】ところが、上記のごとく取鍋の残溶鋼量が
多いときから少なくなるまで流出量の比がほぼ一定であ
ると、前記スラグ検出器コイル内の急激な透磁率の変化
がないためスラグ流出検知はできず、一方、多量のスラ
グが巻き込まれると急激な透磁率の変化が発生してスラ
グを検知するため、少量のスラグを巻き込んだ溶鋼のタ
ンディシュへの流出(注入)が多量のスラグが巻き込ま
れ検知されるまで長時間続くことになり、スラグの混入
による鋼製品の品質を著しく低下させる課題がある。本
発明はこのような課題を有利に解決するためなされたも
のであり、長時間少量のスラグ流出を確実に防止し、溶
鋼の注入がほとんど終了しスラグが溶鋼注入ノズル位置
に達したときスラグを検出し、これに基づき溶鋼注入ノ
ズルを閉めることによってスラグのタンディシュへの流
出を抑止することを提供するものである。
However, if the ratio of the outflow amount is almost constant from the time when the residual molten steel amount in the ladle is large to the time when it becomes small as described above, there is no abrupt change in the magnetic permeability in the slag detector coil, and the slag outflow occurs. On the other hand, when a large amount of slag is caught, a sudden change in magnetic permeability occurs and the slag is detected.Therefore, a large amount of slag flows out (injects) of molten steel containing a small amount of slag into the tundish. It will continue for a long time until it is caught and detected, and there is a problem that the quality of steel products is significantly reduced due to the inclusion of slag. The present invention has been made in order to advantageously solve such a problem, surely prevents a small amount of slag outflow for a long time, when the slag reaches the molten steel injection nozzle position almost completely the injection of molten steel. It is provided to prevent the slag from flowing out to the tundish by detecting and closing the molten steel injection nozzle based on the detection.

【0005】[0005]

【課題を解決するための手段】前記のような課題を解決
した本発明は、取鍋から溶鋼をタンディシュへ注入して
連続鋳造するに際し、取鍋からの溶鋼注入末期におい
て、溶鋼渦流発生を防止可能なまで溶鋼注入量を減少さ
せて、検出不可能な少量スラグの溶鋼への混入を防止
し、次いで、取鍋内スラグ層の降下にともない取鍋の溶
鋼注入ノズル位置で該スラグを検知し、この結果に基づ
き溶鋼注入ノズルを閉めることを特徴とする連続鋳造用
タンディシュへの溶鋼注入方法に関するものである。
SUMMARY OF THE INVENTION The present invention, which has solved the above problems, prevents molten steel eddy currents from being generated at the end of molten steel injection from a ladle when pouring molten steel from a ladle into a tundish for continuous casting. The molten steel injection amount is reduced as much as possible to prevent undetectable small amount of slag from mixing into the molten steel, and then the slag is detected at the molten steel injection nozzle position of the ladle as the slag layer in the ladle descends. The present invention relates to a method for injecting molten steel into a tundish for continuous casting, which is characterized in that the molten steel injecting nozzle is closed based on this result.

【0006】[0006]

【作用】本発明等は、取鍋注入末期の溶鋼渦流発生に及
ぼす取鍋内残溶鋼量と、溶鋼注入量の影響を水モデルを
用いて定量的に調査した。その結果図3に示すごとく注
入最後まで溶鋼渦流を発生させない領域があることを見
出した。しかして図3の渦流発生限界ラインの左下領域
内に注入量を絞ることにより、注入最後まで溶鋼渦流に
よるスラグ流出を防止し、かつ注入最後に例えば電磁式
スラグ流出検知器の検知コイルを取り付けた取鍋底部の
注入ノズル内を流れる流体を、溶鋼からスラグへ一気に
変化させることことが可能となり、このときノズル内の
透磁率が急激に変化するため、スラグ流出検知が可能と
なり、この信号を基にノズルを閉める。これによって確
実にスラグ流出を防止することができる。
The present invention quantitatively investigated the influence of the residual molten steel amount in the ladle and the molten steel injection amount on the generation of the molten steel swirl flow in the final stage of the ladle injection using a water model. As a result, as shown in FIG. 3, it was found that there was a region where molten steel vortex flow was not generated until the end of the injection. Then, by restricting the injection amount in the lower left area of the eddy current generation limit line in FIG. 3, the slag outflow due to the molten steel vortex flow is prevented until the end of the injection, and the detection coil of the electromagnetic slag outflow detector is attached at the end of the injection. It is possible to change the fluid flowing in the injection nozzle at the bottom of the ladle from molten steel to slag all at once.At this time, the magnetic permeability in the nozzle changes abruptly, making it possible to detect the outflow of slag. Close the nozzle to. This can reliably prevent the slag from flowing out.

【0007】この絞り注入+電磁式スラグ流出検知器の
組み合わせでスラグ混入量は大幅に低減し、かつスラグ
早期検知性は大幅に向上する。もし何らかの理由で注入
量が図3の渦流発生限界ラインの右上の領域に入っても
注入最後(残溶鋼量3t以下)に注入量を3t/分以下
に絞れば前述したものと近い効果が得られる。なお渦流
発生限界ラインは取鍋底の形状やスライディングノズル
プレート位置の関係で若干の変化が生ずるので、設備仕
様毎にこれらの関係を把握しておくことが好ましい。
By the combination of the throttle injection and the electromagnetic slag outflow detector, the amount of slag mixed in is greatly reduced and the early detection of slag is greatly improved. Even if the injection amount falls into the upper right region of the vortex flow generation limit line in Fig. 3 for some reason, if the injection amount is reduced to 3t / min or less at the end of injection (residual molten steel amount of 3t or less), an effect similar to that described above can be obtained. To be Since the eddy current generation limit line changes slightly depending on the shape of the ladle bottom and the position of the sliding nozzle plate, it is preferable to understand these relationships for each equipment specification.

【0008】[0008]

【実施例】次に、本発明の実施例をあげる。図1におい
て、取鍋1内に転炉(図示せず)から出鋼し、表面に浮
遊スラグ2の層を有する溶鋼3を満たしてこれを連続鋳
造用タンディシュ4へ位置せしめる。次に、取鍋1の溶
鋼注入ノズル5の上プレート6及び下プレート7からな
るノズル開閉装置を開き、ロングノズル8を介してタン
ディシュ4内へ溶鋼3を注入し、タンディシュ4の下部
に連設した連続鋳造鋳型(図示せず)へ溶鋼3を注入し
て連続鋳造するに際し、取鍋1からの溶鋼注入末期の溶
鋼注入ノズル5の上部の溶鋼3に渦流が発生し、電磁式
スラグ流出検知器で検出不可能な少量のスラグ2を巻き
込むような溶鋼3の層厚(溶鋼量)と順次溶鋼量減少に
ともなう渦流発生を抑止することのできる溶鋼注入量
(溶鋼注入減量)を予め制御器9へ入力しておき、ロー
ドセル10により取鍋1内の溶鋼3の量を常時計測し、こ
の結果を制御器9へ導いて溶鋼注入末期に至り渦流の発
生する溶鋼量になったとき、制御器9から渦流発生を抑
止できる通常の溶鋼注入量から減少溶鋼注入量に調整す
るように油圧ユニット11へ指示して下プレート7を移動
(スライド)させ、ノズルの面積を縮小せしめて溶鋼注
入量を減少し、渦流を確実に抑止してスラグ2を巻き込
みによるタンディシュ4への注入(排出)を抑止しつつ
鋳造する。そして、取鍋1内の溶鋼3の注入が終了しス
ラグ2がノズル5位置へ降下すると、検知器12によりス
ラグ2を検知し、この結果を制御器9へ導き制御器9か
ら油圧ユニット11へノズル5の閉塞を指示し、下プレー
ト7を移動してノズル5を閉にする。このようにしてス
ラグ2のタンディシュ4への排出を抑止しつつ溶鋼3の
注入を終了したならば取鍋1を移動させ、新たな溶鋼を
満たした取鍋を位置させ上記のごとく溶鋼の注入を施
す。
EXAMPLES Next, examples of the present invention will be given. In FIG. 1, steel is tapped from a converter (not shown) in a ladle 1, filled with molten steel 3 having a layer of floating slag 2 on its surface, and placed in a tundish 4 for continuous casting. Next, the nozzle opening / closing device including the upper plate 6 and the lower plate 7 of the molten steel injection nozzle 5 of the ladle 1 is opened, the molten steel 3 is injected into the tundish 4 through the long nozzle 8, and the tundish 4 is continuously provided at the lower part. When the molten steel 3 is injected into the continuous casting mold (not shown) for continuous casting, a vortex flow is generated in the molten steel 3 above the molten steel injection nozzle 5 at the end of the molten steel injection from the ladle 1, and electromagnetic slag outflow detection is performed. A controller for controlling the layer thickness of molten steel 3 (amount of molten steel) that entrains a small amount of slag 2 that cannot be detected by a vessel, and the amount of molten steel injected (amount of molten steel injection reduced) that can suppress the generation of eddies associated with a sequential decrease in the amount of molten steel. 9 is input, the amount of molten steel 3 in the ladle 1 is constantly measured by the load cell 10, and the result is led to the controller 9 to reach the end of molten steel injection and when the amount of molten steel in which vortex flow is generated, control is performed. Suppress eddy current generation from the vessel 9 The normal molten steel injection amount can be reduced to instruct the hydraulic unit 11 to move (slide) the lower plate 7 to reduce the molten steel injection amount, reduce the molten steel injection amount, and ensure the vortex flow. The casting is performed while suppressing the injection (discharging) to the tundish 4 due to the inclusion of the slag 2 in the above manner. Then, when the injection of the molten steel 3 in the ladle 1 is completed and the slag 2 descends to the nozzle 5 position, the detector 12 detects the slag 2 and guides this result to the controller 9 to the hydraulic unit 11. Instructing the nozzle 5 to be closed, the lower plate 7 is moved to close the nozzle 5. In this way, when the injection of the molten steel 3 is completed while suppressing the discharge of the slag 2 to the tundish 4, the ladle 1 is moved and a ladle filled with new molten steel is positioned to inject the molten steel as described above. Give.

【0009】次に、本発明方法の操業例を比較例ととも
に挙げる。 操業例 一般に用いられている容量250tの取鍋にC:0.04%、M
n:0.25%、P:0.01%、S:0.01%、SolAl :0.04
%、残Fe及びその他不純物から1560℃の溶鋼をタンディ
シュへ12t/分で注入し、鋳片(巾1000mm、厚み245 mm)
を連続鋳造し、溶鋼注入末期の取鍋内溶鋼残留量が13t
(層厚180 mm)になったとき、溶鋼注入量を10t/分に減
少せしめ溶鋼注入ノズル上部の溶鋼渦流を抑止しつつ鋳
造し、以降取鍋内溶鋼が無くなるまで順次注入量を減少
せしめ最少量注入量3t/分まで減少し、溶鋼残留量が0
になったときスラグを検知してノズルを閉にした。
Next, an operation example of the method of the present invention will be given together with a comparative example. Example of operation In a commonly used ladle with a capacity of 250t, C: 0.04%, M
n: 0.25%, P: 0.01%, S: 0.01%, SolAl: 0.04
%, Residual Fe and other impurities, molten steel at 1560 ° C was injected into the tundish at 12 t / min and cast (width 1000 mm, thickness 245 mm).
Continuous casting, the residual amount of molten steel in the ladle at the end of molten steel injection was 13t
When the layer thickness reaches 180 mm, the molten steel injection rate is reduced to 10 t / min, casting is performed while suppressing the molten steel vortex flow at the upper part of the molten steel injection nozzle, and then the injection rate is gradually reduced until the molten steel in the ladle is exhausted. Small injection amount decreased to 3t / min and residual amount of molten steel was 0
When it became, the slag was detected and the nozzle was closed.

【0010】このように連々鋳(取鍋交換による連続鋳
造)を施したところ、図2に示すごとくタンディシュ内
の溶鋼表面に浮遊するスラグ層厚は僅かであり、鋳造後
通常工程で連続熱間圧延−冷間圧延−連続焼鈍−調質圧
延によって0.25mm厚のブリキ原板を製造したところ、取
鍋当りの溶鋼歩留り99.9%、スラグ混入の原因による表
面疵等品質欠陥での製品格落率は0.11%と優れた効果を
もたらした。
When continuous casting (continuous casting by ladle exchange) is performed in this manner, as shown in FIG. 2, the slag layer thickness floating on the molten steel surface in the tundish is small, and continuous hot rolling is performed in the normal process after casting. When a tin plate with a thickness of 0.25 mm was manufactured by rolling-cold rolling-continuous annealing-tempered rolling, the yield of molten steel per ladle was 99.9%, and the product degradation rate due to quality defects such as surface defects due to slag inclusion was It brought an excellent effect of 0.11%.

【0011】比較例 上記実施例と同条件の溶鋼注入量を12t/分で注入して連
続鋳造し、溶鋼注入ノズル位置で溶鋼の渦流陥没部が大
になり巻き込みスラグを検知してノズルを閉にし連々鋳
を施したところ、図2に示すごとくタンディシュ内の溶
鋼表面に浮遊するスラグ層厚は、本発明方法(操業例)
に比べ極端に大きくなり取鍋当りの溶鋼歩留り99.5%、
ブリキ原板に加工した製品格落率0.68%と大幅格落し
た。
Comparative Example Under the same conditions as in the above-mentioned example, the molten steel was injected at a rate of 12 t / min for continuous casting. At the molten steel injection nozzle position, the swirl depression of the molten steel became large and the entrained slag was detected and the nozzle was closed. As shown in FIG. 2, the thickness of the slag layer floating on the molten steel surface in the tundish was determined by the method of the present invention (operation example).
It is extremely larger than that of molten steel yield per ladle 99.5%,
The downgrade rate for products processed into tin plate was 0.68%.

【0012】[0012]

【発明の効果】本発明方法によりスラグ流出を確実に防
止し、かつ溶鋼を確実に注ぎきれるため鋳片の品質が大
幅に向上し、しかも溶鋼歩留りも大幅に向上させること
ができる。また本発明方法は操業上大きな負荷を要する
ことがないうえに新たな付帯装置を必要としないので、
工業的規模で容易にかつ確実にできる等の優れた効果が
得られるものである。
According to the method of the present invention, the slag outflow can be surely prevented and the molten steel can be poured completely, so that the quality of the slab can be greatly improved and the yield of the molten steel can be greatly improved. Further, since the method of the present invention does not require a large load in operation and does not require a new auxiliary device,
It is possible to obtain excellent effects such as being able to easily and surely on an industrial scale.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明方法の一例を説明するための一連装置の
側面図である。
FIG. 1 is a side view of a series of devices for explaining an example of the method of the present invention.

【図2】本発明方法の操業例と比較例による連続鋳造回
数とタンディシュ内溶鋼表面のスラグ層厚を示す図表で
ある。
FIG. 2 is a chart showing the number of continuous castings and the slag layer thickness on the surface of molten steel in a tundish according to an operation example and a comparative example of the method of the present invention.

【図3】本発明方法による渦流発生限界ラインを示す図
表である。
FIG. 3 is a table showing eddy current generation limit lines according to the method of the present invention.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 尾島 将 愛知県東海市東海町5−3 新日本製鐵株 式会社名古屋製鐵所内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Masaru Ojima 5-3 Tokai-cho, Tokai City, Aichi Prefecture Nippon Steel Co., Ltd. Nagoya Steel Works

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 取鍋から溶鋼をタンディシュへ注入して
連続鋳造するに際し、取鍋からの溶鋼注入末期におい
て、溶鋼渦流発生を防止可能なまで溶鋼注入量を減少さ
せて、検出不可能な少量スラグの溶鋼への混入を防止
し、次いで、取鍋内スラグ層の降下にともない取鍋の溶
鋼注入ノズル位置で該スラグを検知し、この結果に基づ
き溶鋼注入ノズルを閉めることを特徴とする連続鋳造用
タンディシュへの溶鋼注入方法。
1. When a molten steel is poured from a ladle into a tundish and continuously cast, the molten steel injection amount is reduced until the occurrence of molten steel vortex flow at the end of the molten steel injection from the ladle, and an undetectable small amount. Continuation characterized by preventing slag from mixing into molten steel, then detecting the slag at the molten steel injection nozzle position of the ladle as the slag layer in the ladle descends, and closing the molten steel injection nozzle based on this result Method of pouring molten steel into tundish for casting.
JP12861694A 1994-06-10 1994-06-10 Method of pouring molten steel into tundish for continuous casting Expired - Fee Related JP3323644B2 (en)

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JP12861694A JP3323644B2 (en) 1994-06-10 1994-06-10 Method of pouring molten steel into tundish for continuous casting

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Application Number Priority Date Filing Date Title
JP12861694A JP3323644B2 (en) 1994-06-10 1994-06-10 Method of pouring molten steel into tundish for continuous casting

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JPH081295A true JPH081295A (en) 1996-01-09
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5082756A (en) * 1989-02-16 1992-01-21 Minolta Camera Kabushiki Kaisha Photosensitive member for retaining electrostatic latent images
JP2009241077A (en) * 2008-03-28 2009-10-22 Kurosaki Harima Corp Stopping control method for sliding nozzle device and plate used in the method
CN107282908A (en) * 2017-08-10 2017-10-24 北京首钢自动化信息技术有限公司 A kind of optimization method of slab Lower proterozoic group ladle slide gate in billet control
JP2020007419A (en) * 2018-07-04 2020-01-16 Dic株式会社 Neutralized product of polyester polyol, resin composition, and method for producing neutralized product of polyester polyol

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5082756A (en) * 1989-02-16 1992-01-21 Minolta Camera Kabushiki Kaisha Photosensitive member for retaining electrostatic latent images
JP2009241077A (en) * 2008-03-28 2009-10-22 Kurosaki Harima Corp Stopping control method for sliding nozzle device and plate used in the method
CN107282908A (en) * 2017-08-10 2017-10-24 北京首钢自动化信息技术有限公司 A kind of optimization method of slab Lower proterozoic group ladle slide gate in billet control
JP2020007419A (en) * 2018-07-04 2020-01-16 Dic株式会社 Neutralized product of polyester polyol, resin composition, and method for producing neutralized product of polyester polyol

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