JPH08124958A - Conductor for hybrid integrated circuit substrate - Google Patents

Conductor for hybrid integrated circuit substrate

Info

Publication number
JPH08124958A
JPH08124958A JP6083669A JP8366994A JPH08124958A JP H08124958 A JPH08124958 A JP H08124958A JP 6083669 A JP6083669 A JP 6083669A JP 8366994 A JP8366994 A JP 8366994A JP H08124958 A JPH08124958 A JP H08124958A
Authority
JP
Japan
Prior art keywords
foil
circuit
thickness
hybrid integrated
integrated circuit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6083669A
Other languages
Japanese (ja)
Inventor
Takeshi Shimizu
水 剛 清
Masayoshi Tadano
政 義 多々納
Yukio Uchida
田 幸 夫 内
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Denka Co Ltd
Original Assignee
Denki Kagaku Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Denki Kagaku Kogyo KK filed Critical Denki Kagaku Kogyo KK
Priority to JP6083669A priority Critical patent/JPH08124958A/en
Publication of JPH08124958A publication Critical patent/JPH08124958A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L24/00Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
    • H01L24/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L24/26Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
    • H01L24/31Structure, shape, material or disposition of the layer connectors after the connecting process
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/44Structure, shape, material or disposition of the wire connectors prior to the connecting process
    • H01L2224/45Structure, shape, material or disposition of the wire connectors prior to the connecting process of an individual wire connector
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/44Structure, shape, material or disposition of the wire connectors prior to the connecting process
    • H01L2224/45Structure, shape, material or disposition of the wire connectors prior to the connecting process of an individual wire connector
    • H01L2224/45001Core members of the connector
    • H01L2224/45099Material
    • H01L2224/451Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof
    • H01L2224/45117Material with a principal constituent of the material being a metal or a metalloid, e.g. boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te) and polonium (Po), and alloys thereof the principal constituent melting at a temperature of greater than or equal to 400°C and less than 950°C
    • H01L2224/45124Aluminium (Al) as principal constituent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805Shape
    • H01L2224/4809Loop shape
    • H01L2224/48091Arched
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481Disposition
    • H01L2224/48151Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48225Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
    • H01L2224/48227Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation connecting the wire to a bond pad of the item
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/484Connecting portions
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/485Material
    • H01L2224/48505Material at the bonding interface
    • H01L2224/48699Principal constituent of the connecting portion of the wire connector being Aluminium (Al)
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/73Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
    • H01L2224/732Location after the connecting process
    • H01L2224/73251Location after the connecting process on different surfaces
    • H01L2224/73265Layer and wire connectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/01Chemical elements
    • H01L2924/01013Aluminum [Al]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/01Chemical elements
    • H01L2924/01029Copper [Cu]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/10Details of semiconductor or other solid state devices to be connected
    • H01L2924/11Device type
    • H01L2924/14Integrated circuits

Landscapes

  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Wire Bonding (AREA)
  • Manufacturing Of Printed Wiring (AREA)
  • Weting (AREA)

Abstract

PURPOSE: To suppress the generation of side etching by a method wherein, between the Cu foil and Al foil constituting a double-layer foil which forms the conductor part of a hybrid integrated circuit, the thickness of the Al foil is controlled, and water-soluble resin, which dissolves in a specific pH alkaline aqueous solution, is formed on the surface of the Al foil. CONSTITUTION: On the conductive part 5 where Cu and Al laminated sheets of foil are formed in the order of Al, Cu and Al using Cu foil of 9 to 1000μm in thickness, Al foil of 0.5 to 30μm in thickness and water soluble resin 4 which easily dissolves in an alkaline aqueous solution of pH 8 or higher.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、Alワイヤーボンデン
グおよび高密度実装性に優れた混成集積回路基板用導体
に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a conductor for a hybrid integrated circuit board which is excellent in Al wire bonding and high-density mounting.

【0002】[0002]

【従来技術】従来、ワイヤーボンデングの機能を有する
基板を製造するには、Cu箔を用いて回路形成を行い、
その回路上に貴金属めっきもしくはNi等の卑金属めっ
きを施すか、またはCu箔上にAl片等のワイヤーボン
デイングが可能な金属片を接合する必要があった。
2. Description of the Related Art Conventionally, in order to manufacture a substrate having a function of wire bonding, a circuit is formed using Cu foil,
It has been necessary to apply noble metal plating or base metal plating such as Ni on the circuit, or to bond a wire bondable metal piece such as an Al piece on the Cu foil.

【0003】しかしながら、貴金属めっきやNiめっき
は高価であるだけでなく、均一なめっき面を得ることが
難しく、ワイヤーボンデイング性能は不安定である。ま
た、金属片の接合では数が多いと、回路形成作業が煩雑
になるという問題があった。
However, precious metal plating and Ni plating are not only expensive, it is difficult to obtain a uniform plated surface, and the wire bonding performance is unstable. In addition, if the number of metal pieces joined is large, there is a problem that the circuit forming work becomes complicated.

【0004】一方、新しい方法として、特開昭58−4
8432号にみられるように、AlとCuとの複層箔を
張り合わせた基板を用い、エッチングによりAlの回路
を形成する方法が用いられてきている。このAlのボン
デイングパットの特徴は、 (1)工程の途中で、めっきの必要がないこと。 (2)めっきによるボンデイングパットのように、めっ
き表面の精度や厚みを管理する必要がないこと。 (3)エッチングにより、再現性良く、一度に多数のA
l回路を形成できること。 (4)Al線による超音波ボンデイングでは、AlとA
lとの結合となるため、ボンデイングの作業範囲が広
く、信頼性が高い。 等が挙げられる。
On the other hand, as a new method, JP-A-58-4
As seen in No. 8432, there has been used a method of forming a circuit of Al by etching using a substrate obtained by laminating a multi-layer foil of Al and Cu. The characteristic of this Al bonding pad is that (1) there is no need for plating during the process. (2) It is not necessary to control the precision and thickness of the plating surface unlike the bonding pad by plating. (3) Due to etching, a large number of A
Being able to form an l-circuit. (4) In ultrasonic bonding with Al wire, Al and A
Since it is combined with l, the working range of bonding is wide and the reliability is high. Etc.

【0005】[0005]

【発明が解決しようとする課題】ところが、前記回路形
成法にしたがってAlとCuとの複層箔で回路を形成し
た場合、Cu箔のエッチング時にAl箔部もエッチング
液と接触することから、Al箔部に微小の欠陥部でも存
在すると、そこに局部腐食が発生し、Al箔をとおして
下層のCu箔までエッチングされてしまう。その結果、
優れたAlワイヤーボンデイング性や平滑なCu回路が
得られないという問題が生じる。このAl箔部の欠陥を
Al箔の厚みで対応しようとすると、Al回路をアルカ
リエッチング液で形成する際に、サイドエッチングが激
しくなり高密度実装に適したAl回路を形成することが
困難になる。
However, when a circuit is formed by a multilayer foil of Al and Cu according to the above-mentioned circuit forming method, the Al foil portion also comes into contact with the etching solution when the Cu foil is etched. If minute defects are also present in the foil, local corrosion will occur there, and the lower Cu foil will be etched through the Al foil. as a result,
There arises a problem that excellent Al wire bondability and a smooth Cu circuit cannot be obtained. If the thickness of the Al foil is used to cope with the defects of the Al foil portion, side etching becomes severe when forming the Al circuit with an alkaline etching solution, and it becomes difficult to form the Al circuit suitable for high-density mounting. .

【0006】将来的に、プリント配線基板はさらに、高
集積化、高密度実装が要求され、回路には、より小さな
導体幅、導体間隔が形成可能な導体箔が必要となる。そ
のため、Al箔はできる限り薄いものを用いてサイドエ
ッチングの発生を抑え、かつCuエッチング液の接触に
よるAl箔部のエッチングも抑えられることが要求され
る。
In the future, printed wiring boards will be required to have higher integration and higher density packaging, and circuits will require conductor foils capable of forming smaller conductor widths and conductor intervals. Therefore, it is required that the Al foil be as thin as possible to suppress the occurrence of side etching and also suppress the etching of the Al foil portion due to the contact with the Cu etching solution.

【0007】本発明は、このような問題点を解決するた
め鋭意検討した結果、従来の回路形成方法でもAlワイ
ヤーボンデイング性に優れ、かつ高密度実装を可能とし
た混成集積回路基板用導体を提供するものである。
As a result of extensive studies to solve the above problems, the present invention provides a conductor for a hybrid integrated circuit board, which is excellent in Al wire bondability even in the conventional circuit forming method and enables high-density mounting. To do.

【0008】[0008]

【課題を解決するための手段】本発明によれば、金属基
板に絶縁物層、CuとAlとの複層箔とからなる導体部
を順次積層して一体化してなる積層物の該箔を、エッチ
ングして配線回路を形成させ、露出したAl回路やCu
回路に半田を介してCu回路と半導体や他部材とを積層
し、かつ半導体とAl回路とをAlリード線を用いて固
着する混成集積回路において、CuとAlとの複層箔が
Al/Cu/Alの順に形成した導体部で、Cu箔の厚
みが9〜1000μm,Al箔の厚みが0.5〜30μ
mの範囲で、いずれか一方のAl箔表面側にpH8以上
のアルカリ性水溶液に対して容易に溶解する水可溶性樹
脂を乾燥膜厚で0.5〜10μm形成したことを特徴と
するAlワイヤーボンデイング性に優れた混成集積回路
基板用導体が提供される。
According to the present invention, there is provided a foil of a laminate obtained by sequentially laminating a conductor portion comprising an insulating layer and a multi-layer foil of Cu and Al on a metal substrate and integrating them. , Etching to form wiring circuit, exposed Al circuit and Cu
In a hybrid integrated circuit in which a Cu circuit and a semiconductor or other member are laminated on a circuit via solder, and the semiconductor and the Al circuit are fixed by using an Al lead wire, a multilayer foil of Cu and Al is Al / Cu. In the conductor portion formed in the order of / Al, the Cu foil has a thickness of 9 to 1000 μm, and the Al foil has a thickness of 0.5 to 30 μm.
In the range of m, the Al wire bondability is characterized in that a water-soluble resin that easily dissolves in an alkaline aqueous solution having a pH of 8 or more is formed in a dry film thickness of 0.5 to 10 μm on one of the Al foil surface sides. An excellent conductor for a hybrid integrated circuit board is provided.

【0009】[0009]

【作用】以下、図面により本発明を詳細に説明する。図
1は本発明により、作製された混成集積回路基板におけ
る導体部の断面図を示す。Cu箔1の両面にAl箔を有
した複層箔は導体部5であって、回路を形成する側のA
l箔2の表面には、pH8以上のアルカリ性水溶液に対
して容易に溶解する水可溶性樹脂4を積層し、他方のA
l箔3側を絶縁物層7上に積層して用いる。
The present invention will be described in detail below with reference to the drawings. FIG. 1 shows a cross-sectional view of a conductor portion in a hybrid integrated circuit board manufactured according to the present invention. The multi-layered foil having the Al foils on both sides of the Cu foil 1 is the conductor portion 5 and is A on the side where the circuit is formed.
On the surface of the foil 1, a water-soluble resin 4 that is easily dissolved in an alkaline aqueous solution having a pH of 8 or more is laminated.
The 1 foil 3 side is used by being laminated on the insulator layer 7.

【0010】図2は、図1記載の本発明の導体部5を用
いて、実際に回路形成用基板を作製したものの断面図で
ある。Al板をベース基板6に、絶縁物層7の樹脂を積
層し、その上に導体部5を積層する。このとき、回路形
成と反対側のCu箔1の表面のAl箔3は導体部5と絶
縁物層7との接合強度を向上させるためにあり、厚みは
0.5μm以上あれば十分である。そして、Al箔3表
面に陽極酸化処理によるAl酸化層を付与すれば、さら
に効果がある。しかし、水可溶性樹脂4がAl箔3表面
にあると、導体部5と絶縁物層7との接合強度が得られ
ないため、水可溶性樹脂4の形成は片面だけでよい。
FIG. 2 is a cross-sectional view of a circuit-forming substrate actually manufactured by using the conductor portion 5 of the present invention shown in FIG. The resin of the insulating layer 7 is laminated on the Al plate on the base substrate 6, and the conductor portion 5 is laminated thereon. At this time, the Al foil 3 on the surface of the Cu foil 1 on the side opposite to the circuit formation is for improving the bonding strength between the conductor portion 5 and the insulating layer 7, and the thickness of 0.5 μm or more is sufficient. Further, if an Al oxide layer is applied to the surface of the Al foil 3 by anodizing treatment, the effect is further enhanced. However, if the water-soluble resin 4 is present on the surface of the Al foil 3, the bonding strength between the conductor portion 5 and the insulator layer 7 cannot be obtained, so that the water-soluble resin 4 may be formed on only one side.

【0011】本発明に用いるCu箔1とAl箔2との複
層箔である導体部5の材質としては、Al、Cuともに
高純度のものでも合金のものいずれでもよい。導体部5
の作製方法としては、AlとCuの圧着クラッド法、C
uを被めっき体とした電気Alめっき法、または蒸着A
lめっき法等があり、どの方法で作成したものでもよ
い。
As the material of the conductor portion 5 which is a multilayer foil of the Cu foil 1 and the Al foil 2 used in the present invention, both Al and Cu of high purity or alloys may be used. Conductor part 5
As a manufacturing method of C, a pressure bonding clad method of Al and Cu, C
Electric Al plating method using u as the object to be plated or vapor deposition A
There is a plating method, etc., and any method may be used.

【0012】本発明の導体部5におけるCu箔1の厚み
は、9〜1000μmが適用範囲であり、とくに大電流
用途には、35〜1000μmが好ましく、制御用の小
電流用途には、9〜70μmの箔厚が好ましい。
The thickness of the Cu foil 1 in the conductor portion 5 of the present invention is in the range of 9 to 1000 .mu.m, preferably 35 to 1000 .mu.m particularly for large current applications, and 9 to 1000 .mu.m for small current applications for control. A foil thickness of 70 μm is preferred.

【0013】図3は、厚み300μmのCu箔1の両面
に厚み5μmのAl箔を形成した導体部5を、ベース基
板6と絶縁物層7とに張り合わせた後、従来の回路形成
法に従って回路を形成したときのAl箔2の表面に塗布
した水可溶性樹脂4の乾燥膜厚と、導体部のうちAl箔
2のCuエッチング液に対する耐食性を調査したもので
ある。Al箔2表面の水可溶性樹脂4を乾燥膜厚として
0.5μm以上となるように塗布すると、Cuエッチン
グ液に対するAl箔2の耐食性が向上する。また、水可
溶性樹脂4の厚みが厚くなった場合には、Alワイヤー
ボンデイング性の低下が考えられるが、このような回路
形成ではAlワイヤーボンデイングを施す前に、形成し
た回路上の洗浄を目的として、アルカリ脱脂またはバフ
研磨を施すため、塗布する樹脂厚による不都合もなく、
本来とくに上限は規定されない。しかしながら、経済的
効果を考えると水可溶性樹脂4の乾燥膜厚は0.5〜1
0μmで十分である。
FIG. 3 shows a circuit in which a conductor portion 5 having a thickness of 5 μm and an Al foil formed on both sides of a Cu foil 1 having a thickness of 300 μm is attached to a base substrate 6 and an insulating layer 7, and then a circuit is formed according to a conventional circuit forming method. The dry film thickness of the water-soluble resin 4 applied to the surface of the Al foil 2 when the film was formed and the corrosion resistance of the Al foil 2 in the conductor portion to the Cu etching solution were investigated. When the water-soluble resin 4 on the surface of the Al foil 2 is applied so as to have a dry film thickness of 0.5 μm or more, the corrosion resistance of the Al foil 2 against the Cu etching solution is improved. Further, when the water-soluble resin 4 becomes thicker, the Al wire bonding property may be deteriorated. However, in such circuit formation, the purpose is to clean the formed circuit before performing the Al wire bonding. Since alkali degreasing or buffing is applied, there is no inconvenience due to the thickness of the applied resin,
Originally, no upper limit is specified. However, considering the economic effect, the dry film thickness of the water-soluble resin 4 is 0.5 to 1
0 μm is sufficient.

【0014】本発明に用いられる水可溶性樹脂として
は、酸性のCuエッチング液や雨水,水道水といった一
般生活水等の接触による溶解を避けることができ、かつ
アルカリ性のエッチング液でAl回路を形成する際に、
速やかにAlとともに溶解することが要求されるため、
pHが8以上のアルカリ水溶液だけに溶解する水可溶性
樹脂でなければならない。
As the water-soluble resin used in the present invention, it is possible to avoid dissolution due to contact with acidic Cu etching solution, general domestic water such as rain water and tap water, and to form an Al circuit with an alkaline etching solution. When
Since it is required to dissolve with Al quickly,
It must be a water-soluble resin that can be dissolved only in an alkaline aqueous solution having a pH of 8 or higher.

【0015】図4は、厚み300μmのCu箔1両面
に、厚み0.1〜50μmの範囲でAl箔を形成した導
体部5を、ベース基板6と絶縁物層7とに張り合わせた
後、従来の回路形成法に従って回路を形成したときのA
l箔の厚みと、Al回路8の作製可能な最小回路パター
ン幅および最小回路パターン間隔の関係について、Al
箔2の表面に水可溶性樹脂4を乾燥膜厚として1μm形
成して調査した結果を示す。なお、最小回路パターン
幅,最小回路パターン間隔とは、プリント配線回路にお
ける高密度実装化の目安となるもので、従来のAlとC
uとの複層箔ではAl回路8の作成可能な最小回路パタ
ーン幅ならびに最小回路パターン間隔は400μmより
も大きかった。また、ここでは最小回路パターン幅、最
小回路パターン間隔ともほぼ同等の値を示したことか
ら、最小回路パターン幅のみを示している。
In FIG. 4, a conductor portion 5 in which an Al foil is formed in a thickness range of 0.1 to 50 μm on both surfaces of a Cu foil 1 having a thickness of 300 μm is bonded to a base substrate 6 and an insulating layer 7, and then the conventional structure is used. A when a circuit is formed according to the circuit forming method
Regarding the relationship between the thickness of the foil and the minimum circuit pattern width and the minimum circuit pattern interval that can be produced by the Al circuit 8,
The results of an investigation conducted by forming the water-soluble resin 4 as a dry film thickness of 1 μm on the surface of the foil 2 are shown. The minimum circuit pattern width and the minimum circuit pattern interval are used as a guideline for high-density mounting in a printed wiring circuit.
In the multi-layer foil with u, the minimum circuit pattern width and the minimum circuit pattern interval capable of forming the Al circuit 8 were larger than 400 μm. Further, here, since the minimum circuit pattern width and the minimum circuit pattern interval have almost the same values, only the minimum circuit pattern width is shown.

【0016】図4からわかるように、Al箔2の厚みが
30μmを越えると、Al回路8の作製可能な最小回路
パターン幅を400μm以下にすることができない。ま
た、水可溶性樹脂4を形成しても、Al箔2の厚みが
0.5μm未満であると、良好なAlワイヤーボンデイ
ング性を有するAl回路8を得ることができない。した
がって、作製可能な最小回路パターン幅を400μm以
下にして高密度実装化を実現するには、Al箔2の表面
にpH8以上のアルカリ水溶液に溶解する水可溶性樹脂
を乾燥膜厚で0.5μm以上形成して、Al箔2の厚み
は0.5〜30μmにすることが好ましい。
As can be seen from FIG. 4, if the thickness of the Al foil 2 exceeds 30 μm, the minimum circuit pattern width of the Al circuit 8 that can be manufactured cannot be 400 μm or less. Even if the water-soluble resin 4 is formed, if the thickness of the Al foil 2 is less than 0.5 μm, the Al circuit 8 having good Al wire bondability cannot be obtained. Therefore, in order to realize a high-density packaging with a minimum circuit pattern width of 400 μm or less, a water-soluble resin dissolved in an alkaline aqueous solution having a pH of 8 or more on the surface of the Al foil 2 has a dry film thickness of 0.5 μm or more. After being formed, the thickness of the Al foil 2 is preferably 0.5 to 30 μm.

【0017】[0017]

【実施例1】以下、実施例により本発明を詳細に説明す
る。まず、厚み300μmの圧延Cu箔1の両面に電気
めっき法で厚み5μmのAlめっきを施して、AlとC
uとの複層箔を作製した。この複層箔の回路形成側に使
用するAl箔2表面に、酸価が100のアクリル系樹脂
(水可溶性樹脂4)を乾燥塗膜として1μmとなるよう
に塗布、形成し、混成集積回路の導体部5を作製した。
ここで、酸価とは、有機樹脂中に含まれる遊離脂肪酸を
中和するのに要する水酸化カリウムのミリグラム数のこ
とである。
EXAMPLE 1 The present invention will be described in detail below with reference to examples. First, both sides of the rolled Cu foil 1 having a thickness of 300 μm are plated with Al having a thickness of 5 μm by an electroplating method to form Al and C.
A multi-layer foil with u was produced. An acrylic resin (water-soluble resin 4) having an acid value of 100 was applied and formed as a dry coating film on the surface of the Al foil 2 used for the circuit forming side of this multilayer foil so as to have a thickness of 1 μm. The conductor part 5 was produced.
Here, the acid value is the number of milligrams of potassium hydroxide required to neutralize the free fatty acids contained in the organic resin.

【0018】このようにして作製した、図1に示すよう
な本発明に係る混成集積回路の導体部5を、ベース基板
6の厚さ1.5mmのAl板に、厚み100μmのシリ
カ含有エポキシ樹脂層からなる絶縁物層7を介して積層
し、図2に示すような構成の回路形成用基板を作製し
た。
The conductor portion 5 of the hybrid integrated circuit according to the present invention as shown in FIG. 1 produced in this manner is formed on an Al plate having a thickness of 1.5 mm of a base substrate 6 and a silica-containing epoxy resin having a thickness of 100 μm. The layers were laminated with the insulating layer 7 interposed therebetween to prepare a circuit-forming substrate having a structure as shown in FIG.

【0019】この回路形成用基板を用いて図5に示すよ
うな混成集積回路基板を作製した。まず、導体部5の回
路形成側Al箔2上に形成した水可溶性樹脂4にスクリ
ーン印刷法でレジストを施し、pHが12の水酸化ナト
リウム水溶液で露出した樹脂4とAl箔2をともに溶解
させ、Cu箔1を露出させた。レジスト剥離後、Cuエ
ッチング液により、露出したCu箔1を取り除き、Al
回路8を必要とする部分の水可溶性樹脂4上に再びレジ
ストを施して、水酸化ナトリウム水溶液で選択的に不必
要なAl箔2,3を取り除き、Al回路8およびCu回
路9を形成した。その後、レジストおよびAl回路8上
の水可溶性樹脂4を除去し、Cu回路9上に半田10を
介して半導体11やチップ抵抗等を搭載し、半導体11
とAl回路8とを、Alリード線12により超音波振動
法で固着したものである。
A hybrid integrated circuit board as shown in FIG. 5 was produced using this circuit-forming board. First, a resist is applied to the water-soluble resin 4 formed on the Al foil 2 on the circuit formation side of the conductor portion 5 by a screen printing method, and the exposed resin 4 and Al foil 2 are both dissolved with an aqueous sodium hydroxide solution having a pH of 12. , Cu foil 1 was exposed. After removing the resist, the exposed Cu foil 1 is removed with a Cu etching solution to remove Al.
A resist was applied again to the water-soluble resin 4 in the portion requiring the circuit 8, and the unnecessary Al foils 2 and 3 were selectively removed with an aqueous sodium hydroxide solution to form the Al circuit 8 and the Cu circuit 9. After that, the resist and the water-soluble resin 4 on the Al circuit 8 are removed, and the semiconductor 11, the chip resistor, etc. are mounted on the Cu circuit 9 via the solder 10.
And an Al circuit 8 are fixed to each other by an ultrasonic vibration method with an Al lead wire 12.

【0020】[0020]

【実施例2】厚み500μmのCu箔の両面に電気めっ
き法で、厚み5μmのAlめっきを施した複層箔を圧延
して、厚み300μmのCu箔1と厚み3μmのAl箔
2にしたもので、本発明の混成集積回路の導体部5を作
製した以外は、実施例1とまったく同様の方法で混成集
積回路基板を作製した。
Example 2 A copper foil having a thickness of 500 μm and an aluminum foil having a thickness of 5 μm, which were subjected to electroplating on both sides, were rolled to obtain a Cu foil 1 having a thickness of 300 μm and an Al foil 2 having a thickness of 3 μm. Then, a hybrid integrated circuit substrate was produced by the same method as in Example 1 except that the conductor portion 5 of the hybrid integrated circuit of the present invention was produced.

【0021】[0021]

【比較例1】混成集積回路の導体部5を形成する複層箔
のAl箔2表面に、pH8以上のアルカリ水溶液に溶解
する水可溶性樹脂を形成しなかった以外は、実施例1と
まったく同様の方法で混成集積回路基板を作製した。こ
の混成集積回路基板は所望の部位にAl回路がないた
め、Alワイヤーボンデイング性が不良であった。
Comparative Example 1 Exactly the same as Example 1 except that a water-soluble resin that dissolves in an alkaline aqueous solution having a pH of 8 or more was not formed on the surface of the Al foil 2 of the multilayer foil that forms the conductor portion 5 of the hybrid integrated circuit. A hybrid integrated circuit board was manufactured by the method described in 1. Since this hybrid integrated circuit substrate does not have an Al circuit at a desired portion, the Al wire bondability was poor.

【0022】[0022]

【比較例2】混成集積回路の導体部5を形成する複層箔
のAl箔2の厚みを50μmとした以外は、実施例1と
まったく同一の方法で混成集積回路基板を作製した。こ
の混成集積回路基板は、Al回路8の回路パターン幅が
300μm必要な部位で、Alワイヤーボンデイング性
が不良であった。
[Comparative Example 2] A hybrid integrated circuit board was manufactured in exactly the same manner as in Example 1 except that the thickness of the Al foil 2 of the multilayer foil forming the conductor portion 5 of the hybrid integrated circuit was set to 50 µm. In this hybrid integrated circuit substrate, the Al wire bonding property was poor at the site where the circuit pattern width of the Al circuit 8 was required to be 300 μm.

【0023】[0023]

【発明の効果】以上述べたとおり、本発明は、混成集積
回路の導体部5を形成するCu箔1とAl箔2との複層
箔のうち、Al箔2の厚みを制御し、かつAl箔2の表
面にpHが8以上のアルカリ水溶液に溶解する水可溶性
樹脂4を形成することにより、Alワイヤーボンデング
性に優れ、高密度実装に適した混成集積回路基板を作製
できる混成集積回路の導体を提供することが可能となっ
た。
As described above, the present invention controls the thickness of the Al foil 2 among the multilayer foils of the Cu foil 1 and the Al foil 2 which form the conductor portion 5 of the hybrid integrated circuit, and By forming a water-soluble resin 4 that dissolves in an alkaline aqueous solution having a pH of 8 or more on the surface of the foil 2, a hybrid integrated circuit substrate that has excellent Al wire bondability and is suitable for high-density mounting can be manufactured. It has become possible to provide a conductor.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の混成集積回路の導体部の断面図を示
す。
FIG. 1 shows a cross-sectional view of a conductor portion of a hybrid integrated circuit of the present invention.

【図2】本発明の混成集積回路の導体部を用いた混成集
積回路基板の断面図を示す。
FIG. 2 shows a cross-sectional view of a hybrid integrated circuit board using a conductor portion of the hybrid integrated circuit of the present invention.

【図3】厚み300μmのCu箔1両面に厚み5μmの
Al箔を形成した複層箔の導体部5を用いて、回路を形
成したときのAl箔2の表面に塗布した水可溶性樹脂4
の塗膜厚とAl回路8のCuエッチング液に対する耐食
性の関係を調査したものである。
FIG. 3 is a water-soluble resin 4 applied to the surface of an Al foil 2 when a circuit is formed by using a conductor portion 5 of a multilayer foil in which a Cu foil 1 having a thickness of 300 μm and an Al foil having a thickness of 5 μm are formed on both surfaces.
The relationship between the thickness of the coating film and the corrosion resistance of the Al circuit 8 to the Cu etching solution was investigated.

【図4】厚み300μmのCu箔1の両面に、Al箔を
形成した複層箔の導体部5を用いて、回路を形成したと
きのAl箔の厚みと、Al回路8の作製可能な最小回路
パターン幅および最小回路パターン間隔の関係を、Al
箔2の表面に水可溶性樹脂4を1μm形成して調査した
ものである。
FIG. 4 shows the thickness of an Al foil when a circuit is formed by using a conductor portion 5 of a multilayer foil in which an Al foil is formed on both surfaces of a Cu foil 1 having a thickness of 300 μm, and the minimum possible production of an Al circuit 8. The relationship between the circuit pattern width and the minimum circuit pattern interval is
The water-soluble resin 4 having a thickness of 1 μm was formed on the surface of the foil 2 and investigated.

【図5】本発明の導体部5を積層した回路基板で回路を
形成し、半導体を実装した混成集積回路基板の断面図で
ある。
FIG. 5 is a cross-sectional view of a hybrid integrated circuit board in which a circuit is formed by stacking conductor portions 5 of the present invention and a semiconductor is mounted.

【符号の説明】[Explanation of symbols]

1 Cu箔 2 Al箔(回路形成側) 3 Al箔(絶縁物層との張り合わせ側) 4 水可溶性樹脂 5 導体部(AlとCuとの複層箔) 6 ベース基板 7 絶縁物層 8 Al回路 9 Cu回路 10 半田 11 半導体 12 Alリード線(ワイヤー) 1 Cu Foil 2 Al Foil (Circuit Forming Side) 3 Al Foil (Laminating Side with Insulator Layer) 4 Water-Soluble Resin 5 Conductor Part (Multilayer Foil of Al and Cu) 6 Base Substrate 7 Insulator Layer 8 Al Circuit 9 Cu circuit 10 Solder 11 Semiconductor 12 Al lead wire (wire)

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 H05K 3/38 E 7511−4E ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI technical indication H05K 3/38 E 7511-4E

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】金属基板に絶縁物層、CuとAlとの複層
箔とからなる導体部を順次積層して一体化してなる積層
物の該箔を、エッチングして配線回路を形成させ、露出
したAl回路やCu回路に半田を介してCu回路と半導
体や他部材とを積層し、かつ半導体とAl回路とをAl
リード線を用いて固着する混成集積回路において、Cu
とAlとの複層箔がAl/Cu/Alの順に形成した導
体部で、Cu箔の厚みが9〜1000μm,Al箔の厚
みが0.5〜30μmの範囲で、いずれか一方のAl箔
表面側にpH8以上のアルカリ性水溶液に対して容易に
溶解する水可溶性樹脂を乾燥膜厚で0.5〜10μm形
成したことを特徴とするAlワイヤーボンデイング性に
優れた混成集積回路基板用導体。
1. A foil of a laminate obtained by sequentially stacking and integrating a conductor portion composed of an insulating layer and a multilayer foil of Cu and Al on a metal substrate to form a wiring circuit, The Cu circuit and the semiconductor or other member are laminated on the exposed Al circuit or Cu circuit via solder, and the semiconductor and the Al circuit are formed by Al.
In a hybrid integrated circuit that is fixed using lead wires, Cu
A multilayer foil of Al and Cu is a conductor portion formed in the order of Al / Cu / Al, and the Cu foil has a thickness of 9 to 1000 μm and the Al foil has a thickness of 0.5 to 30 μm. A conductor for a hybrid integrated circuit board excellent in Al wire bondability, characterized in that a water-soluble resin that is easily dissolved in an alkaline aqueous solution having a pH of 8 or more is formed on the surface side to have a dry film thickness of 0.5 to 10 μm.
JP6083669A 1994-03-31 1994-03-31 Conductor for hybrid integrated circuit substrate Pending JPH08124958A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6083669A JPH08124958A (en) 1994-03-31 1994-03-31 Conductor for hybrid integrated circuit substrate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6083669A JPH08124958A (en) 1994-03-31 1994-03-31 Conductor for hybrid integrated circuit substrate

Publications (1)

Publication Number Publication Date
JPH08124958A true JPH08124958A (en) 1996-05-17

Family

ID=13808887

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6083669A Pending JPH08124958A (en) 1994-03-31 1994-03-31 Conductor for hybrid integrated circuit substrate

Country Status (1)

Country Link
JP (1) JPH08124958A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101923910A (en) * 2010-09-10 2010-12-22 中南大学 High-temperature anticorrosive conducting composite material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101923910A (en) * 2010-09-10 2010-12-22 中南大学 High-temperature anticorrosive conducting composite material

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