JPH08114340A - Ice heat storage device - Google Patents
Ice heat storage deviceInfo
- Publication number
- JPH08114340A JPH08114340A JP6251680A JP25168094A JPH08114340A JP H08114340 A JPH08114340 A JP H08114340A JP 6251680 A JP6251680 A JP 6251680A JP 25168094 A JP25168094 A JP 25168094A JP H08114340 A JPH08114340 A JP H08114340A
- Authority
- JP
- Japan
- Prior art keywords
- heat storage
- ice
- liquid
- water
- storage device
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
Landscapes
- Other Air-Conditioning Systems (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、空調システムに用いら
れる氷蓄熱装置に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an ice heat storage device used in an air conditioning system.
【0002】[0002]
【従来の技術】従来の蓄熱装置を有するシステムは、例
えば昼間に集中する冷房用電力負荷需要を低減するため
に、安価な深夜電力を利用して熱源機器の負荷を軽減さ
せ、ビル空調や地域熱供給の比較的大容量の空調システ
ムに適応されている。その中で、蓄熱媒体として水を用
い、氷の潜熱を利用した氷蓄熱装置を有する空調システ
ムの開発が盛んであり、いくつかが実用化されている。2. Description of the Related Art In a system having a conventional heat storage device, for example, in order to reduce the demand for cooling power load concentrated in the daytime, the load of heat source equipment is reduced by using inexpensive late-night power, and building air conditioning and local It is suitable for relatively large capacity air conditioning systems that supply heat. Among them, an air conditioning system having an ice heat storage device using water as a heat storage medium and utilizing latent heat of ice has been actively developed, and some have been put into practical use.
【0003】ところで、氷を生成する方法として、比重
1.7〜1.8のフッ素系不溶性液体を熱媒体として用
い、この熱媒体を冷凍機で0℃以下に冷却して水中で水
と直接接触させることで氷を生成する方法と、水を−1
〜−2℃の過冷却状態にしてこの過冷却水に衝撃を与
え、過冷却状態を解除することで氷を生成する方法があ
る。By the way, as a method for producing ice, a fluorine-based insoluble liquid having a specific gravity of 1.7 to 1.8 is used as a heat medium, and this heat medium is cooled to 0 ° C. or less by a refrigerator and directly mixed with water in water. The method of producing ice by contacting the water and -1
There is a method in which ice is generated by applying an impact to the supercooled water in a supercooled state of up to -2 ° C and releasing the supercooled state.
【0004】両者いずれの場合も、生成された氷は微細
な氷板を形成する。一方の直接接触熱交換による製氷で
は、常に0℃の水と接触し連続的に氷を製造することが
可能であり、他方の過冷却による製氷では、単位体積当
りの氷生成量が直接接触熱交換に比べて多く製氷効率が
高い特徴を有している。In both cases, the ice produced forms a fine ice plate. On the other hand, in the ice making by direct contact heat exchange, it is possible to continuously produce ice by constantly contacting with water at 0 ° C, and in the other ice making by supercooling, the amount of ice produced per unit volume is the direct contact heat. Compared with replacement, it has many characteristics that ice making efficiency is high.
【0005】[0005]
【発明が解決しようとする課題】しかしながら、実用と
して運用する際には以下に説明するような問題が生じる
ので、正常で安定した状態を維持する点で改良されるべ
き点がある。すなわち、過冷却による製氷では、過冷却
状態を解除する手段として過冷却水を空気中に放出し解
除板に当てて解除しているが、解除板に過冷却水を当て
た場合、解除板に過冷却解除されて生成した氷が次々と
着氷し、やがて氷が成長し過冷却水の吐出部に達して製
氷中止となってしまうという問題がある。However, in practical use, the following problems occur, and therefore there is a point to be improved in maintaining a normal and stable state. That is, in ice making by supercooling, as means for canceling the supercooled state, the supercooled water is released into the air and applied to the release plate to release, but when the supercooled water is applied to the release plate, the release plate is released. There is a problem that the ice generated after the supercooling is released successively lands on the ice, and eventually the ice grows to reach the discharge portion of the supercooled water and the ice making is stopped.
【0006】本発明は、上記問題を解決するためになさ
れたもので、その目的は過冷却による直接接触熱交換に
比べて高い製氷効率を利用し、かつ解除板に氷が着氷・
成長し製氷を妨げることがなく連続製氷が可能な、安定
した氷蓄熱装置を提供することにある。The present invention has been made in order to solve the above problems, and its purpose is to use higher ice making efficiency than direct contact heat exchange by supercooling, and to release ice on the release plate.
An object of the present invention is to provide a stable ice heat storage device capable of continuous ice making without growing and hindering ice making.
【0007】[0007]
【課題を解決するための手段】上記目的を達成するため
に、本発明の請求項1の氷蓄熱装置は、蓄熱槽と、水を
過冷却状態にする過冷却器と、前記過冷却器と前記蓄熱
槽をつなぐ連通部と、前記蓄熱槽内の水を前記過冷却器
へ供給する循環ラインと、前記過冷却器内で水と熱交換
する水より凝固点が低くかつ互いに混合・化合すること
がなく不溶性である第2の液体と、前記第2の液体を前
記連通部途中で噴出させる噴出手段と、前記第2の液体
の貯留部より前記過冷却器へ循環させるポンプおよび冷
凍手段とを備えたことを特徴とする。In order to achieve the above object, an ice heat storage device according to claim 1 of the present invention comprises a heat storage tank, a subcooler for bringing water into a supercooled state, and the supercooler. A communication part that connects the heat storage tanks, a circulation line that supplies the water in the heat storage tanks to the subcooler, and a freezing point that is lower than that of water that exchanges heat with the water in the subcoolers and that is mixed and combined with each other. A second liquid which is insoluble and is insoluble, a jetting means for jetting the second liquid in the middle of the communication part, and a pump and a freezing means for circulating the second liquid from the storage part of the second liquid to the subcooler. It is characterized by having.
【0008】本発明の請求項2は、第1項記載の氷蓄熱
装置において、過冷却器より出た第2の液体の連通部へ
の噴出手段として、連通部に設置された複数個のノズル
より連通部周囲から中心方向に向かって噴出させること
を特徴とする。According to a second aspect of the present invention, in the ice heat storage device according to the first aspect, a plurality of nozzles installed in the communicating portion serve as a means for ejecting the second liquid discharged from the subcooler to the communicating portion. It is characterized in that it is ejected from the periphery of the communication portion toward the center.
【0009】本発明の請求項3は、第1項記載の氷蓄熱
装置において、過冷却器より出た第2の液体の連通部へ
の噴出手段として、連通部内部より連通部壁面方向に向
かって噴出させることを特徴とする。According to a third aspect of the present invention, in the ice heat storage device according to the first aspect, as means for ejecting the second liquid discharged from the subcooler to the communicating portion, the second liquid is directed from the inside of the communicating portion toward the wall surface of the communicating portion. It is characterized in that it is ejected.
【0010】本発明の請求項4は、第1項記載の氷蓄熱
装置において、過冷却器より出た第2の液体の連通部へ
の噴出手段として、連通部内部から過冷却器より出る水
の流れと逆向きに噴出させることを特徴とする。According to a fourth aspect of the present invention, in the ice heat storage device according to the first aspect, the water discharged from the subcooler from the inside of the communication section is used as a means for ejecting the second liquid discharged from the subcooler to the communication section. It is characterized in that it is ejected in the opposite direction to the flow of.
【0011】[0011]
【作用】本発明によれば、過冷却器で冷却された過冷却
水は連通部を通って蓄熱部へ向かう水の流れを形成する
が、連通部途中に設置された第2の液体の噴出手段によ
り噴出した第2の液体は、連通部内部で液滴を形成し過
冷却水と衝突する。この第2の液体の液滴と衝突した過
冷却水は、この時点で解除され氷片を生成し、生成した
氷片は水の流れによって蓄熱槽へと運ばれる。一方、連
通部へ噴出した第2の液体は、水の流れとともに蓄熱槽
下部にある貯留部より回収され、循環ポンプ、冷凍機を
通って再び過冷却器へ供給される。また、過冷却水への
水の供給は、蓄熱槽側壁にある取水口より循環ポンプを
経て供給される。According to the present invention, the supercooled water cooled by the supercooler forms a flow of water passing through the communication section toward the heat storage section, but the second liquid jetted in the middle of the communication section is ejected. The second liquid ejected by the means forms droplets inside the communicating portion and collides with the supercooled water. The supercooled water that has collided with the droplets of the second liquid is released at this point to produce ice pieces, and the produced ice pieces are carried to the heat storage tank by the flow of water. On the other hand, the second liquid ejected to the communication part is recovered from the storage part in the lower part of the heat storage tank together with the flow of water, and is supplied to the subcooler again through the circulation pump and the refrigerator. Water is supplied to the supercooled water from a water intake on the side wall of the heat storage tank through a circulation pump.
【0012】[0012]
【実施例】以下、本発明の実施例を図を参照して説明す
る。図1は本発明の第1実施例(請求項1及び請求項2
対応)の断面図である。同図において、1は蓄熱槽で、
この蓄熱槽1は連通部1aを持ち底部を傾斜状とし、低
い方の底分に不凍液(第2の液体)の貯留部1bを形成
し、連通部1aと反対側の側壁1cには取水口1dを設
けている。貯留部1bには不凍液循環ポンプ2、冷凍機
3よりなる不凍液循環ラインが接続され、冷凍機3の出
口側は過冷却器4、不凍液配管5を経て不凍液噴出口6
へと接続される。Embodiments of the present invention will now be described with reference to the drawings. FIG. 1 shows a first embodiment of the present invention (claims 1 and 2).
FIG. In the figure, 1 is a heat storage tank,
This heat storage tank 1 has a communicating portion 1a and has an inclined bottom portion, an antifreezing liquid (second liquid) storage portion 1b is formed in a lower bottom portion, and a water intake port is provided on a side wall 1c opposite to the communicating portion 1a. 1d is provided. An antifreeze liquid circulation line consisting of an antifreeze liquid circulation pump 2 and a refrigerator 3 is connected to the storage portion 1b, and the outlet side of the refrigerator 3 passes through a subcooler 4 and an antifreeze liquid pipe 5 and an antifreeze liquid outlet 6
Connected to.
【0013】また、取水口1dには水循環ポンプ7が接
続され、水循環ポンプ7からは過冷却器4、連通部1
a、蓄熱槽1へとつながる循環ラインが形成されてい
る。図2は図1の連通部1aの断面図であり、不凍液噴
出口6より見た断面図である。連通部1aの周囲に設置
された複数個の不凍液噴出ノズル6aは、連通部1aの
中心方向へ噴出する構造としている。また、不凍液とし
ては熱交換する水より凝固点が低くかつ互いに混合・化
合することがなく不溶性である液体が使用される。Further, a water circulation pump 7 is connected to the water intake 1d, and from the water circulation pump 7, the subcooler 4 and the communicating portion 1 are connected.
a, a circulation line connected to the heat storage tank 1 is formed. FIG. 2 is a cross-sectional view of the communication portion 1 a of FIG. 1, and is a cross-sectional view seen from the antifreeze liquid ejection port 6. The plurality of antifreeze jet nozzles 6a installed around the communicating portion 1a have a structure for ejecting toward the center of the communicating portion 1a. Further, as the antifreeze liquid, a liquid which has a lower freezing point than water for heat exchange and is insoluble without being mixed and combined with each other is used.
【0014】次に、本実施例の作用を説明する。冷凍機
3によって0℃以下に冷却された不凍液(第2の液体)
8は、過冷却器4内で過冷却器4に供給された水と熱交
換を行い、過冷却水9を生成させる。熱交換を行った不
凍液8は次に不凍液配管5によって連通部1aの途中に
設置された不凍液噴出口6へ供給される。不凍液噴出口
6に達した不凍液8は不凍液噴出ノズル6aに送られ、
連通部1a内の中心方向に向かって噴出し不凍液液滴8
aを形成する。Next, the operation of this embodiment will be described. Antifreeze liquid (second liquid) cooled to 0 ° C or less by the refrigerator 3.
8 exchanges heat with the water supplied to the subcooler 4 in the subcooler 4 to generate supercooled water 9. The antifreeze liquid 8 that has undergone heat exchange is then supplied by the antifreeze liquid pipe 5 to the antifreeze liquid jet port 6 installed in the middle of the communication portion 1a. The antifreeze liquid 8 that has reached the antifreeze liquid ejection port 6 is sent to the antifreeze liquid ejection nozzle 6a,
Antifreeze liquid droplets 8 ejected toward the center in the communication portion 1a
a is formed.
【0015】一方、過冷却水9は連通部1aを通る途中
で、不凍液噴出ノズル6aより噴出された不凍液液滴8
aと衝突し過冷却状態が解除される。このとき過冷却水
9より氷片10を生成し、生成した氷片10は連通部1
aを通って蓄熱槽1へ達し、浮力によって蓄熱槽1の上
方に堆積する。On the other hand, the supercooled water 9 is sprayed from the antifreeze liquid ejecting nozzle 6a while the antifreeze liquid droplets 8 are flowing through the communicating portion 1a.
It collides with a and the supercooled state is released. At this time, ice pieces 10 are generated from the supercooled water 9, and the generated ice pieces 10 are connected to the communicating portion 1
It reaches the heat storage tank 1 through a and is accumulated above the heat storage tank 1 by buoyancy.
【0016】図3は本発明の第2実施例(請求項1及び
請求項3対応)の断面図、図4は図3の不凍液噴出口6
を連通部1aより見た断面図である。本実施例が前記第
1実施例と異なる構成は、過冷却器4から不凍液配管
5、不凍液噴出口6へとつながるラインが、連通部1a
内部に設置された点のみであり、それ以外の構成は前記
第1実施例と同じ構成であるので、同一構成部分には同
一符号を付して重複説明は省略する。FIG. 3 is a sectional view of a second embodiment of the present invention (corresponding to claim 1 and claim 3), and FIG. 4 is an antifreeze jet port 6 of FIG.
FIG. 3 is a cross-sectional view seen from a communication portion 1a. This embodiment is different from the first embodiment in that the line connecting the subcooler 4 to the antifreeze pipe 5 and the antifreeze jet 6 has a communicating portion 1a.
Only the points are installed inside, and the other configurations are the same as those of the first embodiment, and therefore, the same reference numerals are given to the same components and the duplicate description will be omitted.
【0017】本実施例では、不凍液配管5より供給され
た不凍液8は、不凍液噴出ノズル6aより連通部1a中
心より壁面に向かって噴出される構造としている。すな
わち、過冷却器4より出た不凍液8は連通部1a内部に
設置された不凍液配管5より不凍液噴出口6に達し、不
凍液噴出ノズル6aより噴出され、不凍液液滴8aを形
成する。In this embodiment, the antifreeze liquid 8 supplied from the antifreeze liquid pipe 5 is ejected from the antifreeze liquid ejecting nozzle 6a toward the wall surface from the center of the communicating portion 1a. That is, the antifreeze liquid 8 discharged from the supercooler 4 reaches the antifreeze liquid jet port 6 through the antifreeze liquid pipe 5 installed inside the communication portion 1a and is jetted from the antifreeze liquid jet nozzle 6a to form an antifreeze liquid droplet 8a.
【0018】また、過冷却水9は連通部1aを通る途中
で、不凍液噴出ノズル6aより噴出された不凍液液滴8
aと衝突し過冷却状態が解除される。このとき過冷却水
9により氷片10を生成し、生成した氷片10は連通部
1aを通って蓄熱槽1へ達し浮力によって蓄熱槽1の上
方に堆積する。Further, the supercooled water 9 is sprayed from the antifreeze liquid droplets 8 from the antifreeze liquid jet nozzle 6a while passing through the communicating portion 1a.
It collides with a and the supercooled state is released. At this time, ice pieces 10 are generated by the supercooled water 9, and the generated ice pieces 10 reach the heat storage tank 1 through the communicating portion 1a and are accumulated above the heat storage tank 1 by buoyancy.
【0019】図5は本発明の第3実施例(請求項1及び
請求項4対応)の断面図であり、本実施例が前記第1実
施例と異なる構成は、過冷却器4から接続される不凍液
配管5が、連通部1aの外部を通って連通部1a内に接
続され、しかも不凍液噴出口6に接続された不凍液噴出
ノズル6aの噴出方向が過冷却水9の流れと逆向きに噴
出させる点のみであり、それ以外の構成は前記第1実施
例と同じ構成であるので、同一構成部分には同一符号を
付して重複説明は省略する。FIG. 5 is a sectional view of a third embodiment of the present invention (corresponding to claim 1 and claim 4). The structure of this embodiment different from that of the first embodiment is connected from the subcooler 4. The antifreezing liquid pipe 5 is connected to the inside of the communicating part 1a through the outside of the communicating part 1a, and the antifreezing liquid ejecting nozzle 6a connected to the antifreezing liquid ejecting port 6 ejects the subcooling water 9 in the opposite direction. Since the other points are the same as those of the first embodiment, the same reference numerals are given to the same components and duplicate description will be omitted.
【0020】本実施例では、過冷却器4より出た不凍液
8は連通部1a内部に設置された不凍液配管5より不凍
液噴出口6に達し、不凍液噴出ノズル6aより噴出さ
れ、不凍液液滴8aを形成する。また、過冷却水9は連
通部1aを通る途中で、不凍液噴出ノズル6aより噴出
された不凍液液滴8aと衝突し過冷却状態が解除され
る。このとき過冷却水9より氷片10を生成し、生成し
た氷片10は連通部1aを通って蓄熱槽1へ達し浮力に
よって蓄熱槽1の上方に堆積する。In this embodiment, the antifreeze liquid 8 discharged from the subcooler 4 reaches the antifreeze liquid jet port 6 from the antifreeze liquid pipe 5 installed inside the communication part 1a, and is jetted from the antifreeze liquid jet nozzle 6a to form the antifreeze liquid droplets 8a. Form. Further, the supercooled water 9 collides with the antifreeze liquid droplets 8a ejected from the antifreeze liquid ejecting nozzle 6a while passing through the communication portion 1a, and the supercooled state is released. At this time, ice pieces 10 are generated from the supercooled water 9, and the generated ice pieces 10 reach the heat storage tank 1 through the communication portion 1a and are accumulated above the heat storage tank 1 by buoyancy.
【0021】[0021]
【発明の効果】以上説明したように、本発明によれば、
過冷却水の解除手段として第2の液体を噴出し、形成さ
れた液滴と過冷却水を衝突させているので、解除板を使
用したときのように生成した氷が着氷・成長することが
なく連続製氷が可能となる。また、0℃以下に冷却され
た不凍液は過冷却器を出た後も0℃以下であるので、過
冷却解除時にさらに直接接触による熱交換も行い氷を生
成するため、過冷却による製氷および水との直接接触に
よる製氷に比べて製氷効率の高い氷蓄熱装置を提供でき
る。As described above, according to the present invention,
Since the second liquid is ejected as the means for releasing the supercooled water and the formed droplets are made to collide with the supercooled water, the ice generated as when the release plate is used is iced and grows. There is no need for continuous ice making. In addition, since the antifreeze liquid cooled to 0 ° C or less is 0 ° C or less even after it leaves the subcooler, when the supercooling is released, heat is further exchanged by direct contact to generate ice. It is possible to provide an ice heat storage device having high ice-making efficiency as compared with ice-making by direct contact with.
【図1】本発明の第1実施例の断面図。FIG. 1 is a sectional view of a first embodiment of the present invention.
【図2】図1の不凍液噴出口の断面図。FIG. 2 is a cross-sectional view of the antifreeze jet port of FIG.
【図3】本発明の第2実施例の断面図。FIG. 3 is a sectional view of a second embodiment of the present invention.
【図4】図3の不凍液噴出口の断面図。FIG. 4 is a cross-sectional view of the antifreeze jet port of FIG.
【図5】本発明の第3実施例の断面図。FIG. 5 is a sectional view of a third embodiment of the present invention.
1…蓄熱槽、1a…連通部、1b…貯留部、1c…側
壁、1d…取水口、2…不凍液循環ポンプ、3…冷凍
機、4…過冷却器、5…不凍液配管、6…不凍液噴出
口、6a…不凍液噴出ノズル、7…水循環ポンプ、8…
不凍液、8a…不凍液液滴、9…過冷却水、10…氷
片。DESCRIPTION OF SYMBOLS 1 ... Heat storage tank, 1a ... Communication part, 1b ... Storage part, 1c ... Side wall, 1d ... Intake port, 2 ... Antifreeze circulation pump, 3 ... Refrigerator, 4 ... Supercooler, 5 ... Antifreeze pipe, 6 ... Antifreeze jet Outlet, 6a ... Antifreeze jet nozzle, 7 ... Water circulation pump, 8 ...
Antifreeze liquid, 8a ... Antifreeze liquid droplets, 9 ... Supercooled water, 10 ... Ice chips.
Claims (4)
器と、前記過冷却器と前記蓄熱槽をつなぐ連通部と、前
記蓄熱槽内の水を前記過冷却器へ供給する循環ライン
と、前記過冷却器内で水と熱交換する水より凝固点が低
くかつ互いに混合・化合することがなく不溶性である第
2の液体と、前記第2の液体を前記連通部途中で噴出さ
せる噴出手段と、前記第2の液体の貯留部より前記過冷
却器へ循環させるポンプおよび冷凍手段とを備えたこと
を特徴とする氷蓄熱装置。1. A heat storage tank, a subcooler for bringing water into a supercooled state, a communication section connecting the supercooler and the heat storage tank, and a circulation for supplying water in the heat storage tank to the subcooler. A line, a second liquid that has a lower freezing point than water that exchanges heat with water in the subcooler, and is insoluble without being mixed and combined with each other, and the second liquid is ejected in the middle of the communicating portion. An ice heat storage device comprising: a jetting means, a pump and a freezing means for circulating the second liquid from a storage portion to the subcooler.
却器より出た第2の液体の連通部への噴出手段として、
連通部に設置された複数個のノズルより連通部周囲から
中心方向に向かって噴出させることを特徴とする氷蓄熱
装置。2. The ice heat storage device according to claim 1, wherein the second liquid ejected from the subcooler is ejected to the communicating portion.
An ice heat storage device, characterized in that a plurality of nozzles installed in a communication section ejects the nozzle toward the center from the periphery of the communication section.
却器より出た第2の液体の連通部への噴出手段として、
連通部内部より連通部壁面方向に向かって噴出させるこ
とを特徴とする氷蓄熱装置。3. The ice heat storage device according to claim 1, wherein the second liquid ejected from the subcooler is ejected to the communicating portion.
An ice heat storage device characterized in that it is ejected from the inside of the communication portion toward the wall surface of the communication portion.
却器より出た第2の液体の連通部への噴出手段として、
連通部内部から過冷却器より出る水の流れと逆向きに噴
出させることを特徴とする氷蓄熱装置。4. The ice heat storage device according to claim 1, wherein the second liquid ejected from the subcooler is ejected to the communicating portion.
An ice heat storage device characterized in that the water is ejected from the inside of the communication section in a direction opposite to the flow of water flowing out from the subcooler.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6251680A JPH08114340A (en) | 1994-10-18 | 1994-10-18 | Ice heat storage device |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6251680A JPH08114340A (en) | 1994-10-18 | 1994-10-18 | Ice heat storage device |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH08114340A true JPH08114340A (en) | 1996-05-07 |
Family
ID=17226418
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6251680A Pending JPH08114340A (en) | 1994-10-18 | 1994-10-18 | Ice heat storage device |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH08114340A (en) |
-
1994
- 1994-10-18 JP JP6251680A patent/JPH08114340A/en active Pending
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