JPH08100397A - Decorative paper having abrasion resistance - Google Patents

Decorative paper having abrasion resistance

Info

Publication number
JPH08100397A
JPH08100397A JP6233721A JP23372194A JPH08100397A JP H08100397 A JPH08100397 A JP H08100397A JP 6233721 A JP6233721 A JP 6233721A JP 23372194 A JP23372194 A JP 23372194A JP H08100397 A JPH08100397 A JP H08100397A
Authority
JP
Japan
Prior art keywords
decorative paper
printing
uneven pattern
layer
pattern
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6233721A
Other languages
Japanese (ja)
Other versions
JP3334365B2 (en
Inventor
Yutaka Takasaki
裕 高崎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Inc
Original Assignee
Toppan Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Toppan Printing Co Ltd filed Critical Toppan Printing Co Ltd
Priority to JP23372194A priority Critical patent/JP3334365B2/en
Publication of JPH08100397A publication Critical patent/JPH08100397A/en
Application granted granted Critical
Publication of JP3334365B2 publication Critical patent/JP3334365B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Paper (AREA)
  • Printing Methods (AREA)
  • Laminated Bodies (AREA)

Abstract

PURPOSE: To prepare a sheet of decorative paper, having abrasion resistance capable of receiving abrasion due to rubbing, etc., only with protruding parts of an uneven pattern without making a whitening phenomenon conspicuous due to scuff marks by forming the uneven pattern on a surface layer of the decorative paper according to the raised printing. CONSTITUTION: The characteristic of this sheet of decorative paper having abrasion resistance comprises a printing layer 12 prepared with an ink containing a urethane-based resin as a binder on a sheet of base paper 11 for the decorative paper and forming an uneven pattern 15 on the surface layer by the raised printing using a thermographic ink of a urethane-based resin, where the difference of level between the recessed parts 15b and protruding parts 15a of the uneven pattern 15 is regulated within the range of 15-50μm and the surface area of the protruding parts 15a accounts for 15-50% of the whole surface area.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、耐摩耗性を有する化粧
紙に関し、例えば、建物の壁紙用等の内装材、家具等の
収納棚、引き出しの内装等に用いる耐摩耗性を有する化
粧紙に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a wear-resistant decorative paper, for example, a wear-resistant decorative paper used as an interior material for wallpaper of buildings, a storage shelf for furniture, a drawer interior, and the like. It is about.

【0002】[0002]

【従来の技術】従来においては、表面層のトップコート
樹脂の塗布量を増加させ、塗膜を厚くするすることで耐
摩耗性を向上させた化粧紙が一般的であった。この塗布
量を増加させ塗膜を厚くする方法として、例えば、版深
の深いグラビア版を使用する。或いはリコート用樹脂を
使用して複数回の重ね塗りと乾燥を繰り返す、等の方法
により塗膜を厚くする方法が採用されていた。しかしな
がら、機械の乾燥能力に限界があり、可能な塗布量は限
られ、耐摩耗性等が不充分であった。
2. Description of the Related Art Conventionally, a decorative paper has been generally used in which the abrasion resistance is improved by increasing the coating amount of the top coat resin of the surface layer and thickening the coating film. As a method of increasing the coating amount and thickening the coating film, for example, a gravure plate having a deep plate depth is used. Alternatively, a method of thickening the coating film by using a recoating resin and repeating multi-coating and drying a plurality of times has been employed. However, the drying ability of the machine is limited, the possible coating amount is limited, and the abrasion resistance and the like are insufficient.

【0003】[0003]

【発明が解決しようとする課題】すなわち、表面層を必
要以上に厚く塗布することができないため耐摩耗性の問
題と、版深の深いグラビア版を使用して塗布量を増加さ
せる場合も、重ね塗りして塗膜を厚くする場合のいずれ
も、表面層におけるトップコート樹脂層は全面に塗工さ
れているため、擦過等による傷が付きやすく、しかもそ
の傷跡が白化現象(表面が平滑の場合、擦過傷により白
い筋傷に見える現象)を発生させる問題が残されてい
た。
That is, since the surface layer cannot be applied thicker than necessary, there is a problem of abrasion resistance, and even when the coating amount is increased by using a gravure plate having a deep plate depth, In both cases of coating to make the coating thicker, the topcoat resin layer in the surface layer is coated on the entire surface, so scratches due to scratches are likely to occur, and the scars are whitening (when the surface is smooth. However, the problem of causing white scratches due to scratches) remains.

【0004】そこで本発明は、化粧紙の表面層に盛り上
げ印刷により凹凸模様を形成し、摩擦等による摩耗も凹
凸模様の凸部のみで受け、しかも、擦過傷による白化現
象も目立つことがない耐摩耗性を有する化粧紙を提供す
ることを目的とする。
In view of the above, the present invention is a wear-resistant material in which an uneven pattern is formed on a surface layer of a decorative paper by a raised printing so that abrasion due to friction or the like is received only by the convex portions of the uneven pattern, and a whitening phenomenon due to abrasion is not noticeable. An object is to provide a decorative paper having properties.

【0005】[0005]

【課題を解決するための手段】本発明に於いて上記目的
を達成するために、化粧紙用の原紙(11)上に、ウレ
タン系樹脂をバインダーとしたインキにより印刷層(1
2)を設け、この表面層にウレタン系樹脂の盛り上げイ
ンキを用いて盛り上げ印刷により凹凸模様(15)を設
けた化粧紙であって、この凹凸模様(15)の凹部(1
5b)と凸部(15a)の高低差が15〜50μmの範
囲で、かつ、凸部(15a)の表面積の割合が、表面層
全体の15〜50%を占めることを特徴とする耐摩耗性
を有する化粧紙である。
In order to achieve the above object in the present invention, a printing layer (1) is formed on a base paper (11) for decorative paper with an ink using a urethane resin as a binder.
A decorative paper (2) is provided, and a concavo-convex pattern (15) is provided on the surface layer by means of engraving printing using a urethane resin embossing ink.
5b) and the height difference between the convex portions (15a) is in the range of 15 to 50 μm, and the surface area ratio of the convex portions (15a) accounts for 15 to 50% of the entire surface layer. It is a decorative paper having.

【0006】本発明を図に基づき詳細に説明する。本発
明の耐摩耗性を有する化粧紙の基本的な構成は、図1に
示すように、坪量20〜40g/m2 の薄葉紙と呼ばれ
る化粧紙用の原紙(11)を用いて、この上にウレタン
系樹脂をバインダーとした着色インキで印刷層(12)
を設け、この上に透明又は不透明のウレタン系樹脂イン
キを用いて、グラビア又はスクリーン印刷方式により盛
り上げ印刷で凹凸模様(15)を形成するものである。
The present invention will be described in detail with reference to the drawings. As shown in FIG. 1, the basic constitution of the abrasion-resistant decorative paper of the present invention is as follows, using a base paper (11) for decorative paper called a thin paper having a basis weight of 20 to 40 g / m 2. Printed layer with colored ink using urethane resin as binder (12)
And a transparent or opaque urethane-based resin ink is used to form the concavo-convex pattern (15) by gravure or screen printing by swelling printing.

【0007】この凹凸模様(15)は、凹部(15b)
の底面と凸部(15a)の表面との高低差が15〜50
μmの範囲で、かつ、凸部(15a)の表面積の割合
が、表面層全体の15〜50%を占めるように形成す
る。また、この盛り上げ印刷による凹凸模様(15)
は、網目状、点形状、線状等で導管模様等を模様状に形
成したもので、この形成は盛り上げするインキ層の調整
が容易なグラビア印刷方式が好適である。
This uneven pattern (15) is a recess (15b).
The height difference between the bottom surface of the and the surface of the convex portion (15a) is 15 to 50.
In the range of μm, the surface area ratio of the protrusions (15a) is formed so as to occupy 15 to 50% of the entire surface layer. In addition, this uneven printing pattern (15)
Is a mesh-shaped, dot-shaped, or line-shaped conduit pattern or the like formed in a pattern. For this formation, a gravure printing method is preferable because the ink layer to be raised can be easily adjusted.

【0008】[0008]

【作用】本発明の耐摩耗性を有する化粧紙は、表面層に
グラビア印刷で盛り上げ印刷により凹凸模様(15)を
形成したものである。この凹凸模様(15)は凹部(1
5b)の底面と凸部(15a)の表面との高低差が15
〜50μmの範囲で、かつ、凸部の表面積の割合が、表
面層全体の15〜50%を占めるように形成すること
で、凹凸模様の凸部表面で擦過やこすれ等の摩擦を受け
るたが、凸部の塗膜がかなり厚いので柄消失にいたるま
での耐摩耗性に優れる。さらに、擦過等の傷跡を表面積
の少ない凹凸模様の凸部が受けるので、傷つく(白化す
る)面積が小さく目立ちにくい。
The decorative paper having abrasion resistance according to the present invention has the unevenness pattern (15) formed on the surface layer by the gravure printing and the rising printing. This uneven pattern (15) is a recess (1
The height difference between the bottom surface of 5b) and the surface of the protrusion (15a) is 15
In the range of up to 50 μm, and the surface area ratio of the protrusions occupies 15 to 50% of the entire surface layer, the protrusions having an uneven pattern are subject to friction such as rubbing or rubbing. Since the coating film on the convex portion is quite thick, it has excellent wear resistance until the pattern disappears. Further, since the scratches such as scratches are received by the projections of the uneven pattern having a small surface area, the area of damage (whitening) is small and it is not noticeable.

【0009】[0009]

【実施例】以下本発明の具体的な実施例を図に基づき詳
細に説明する。図1は、一実施例における耐摩耗性を有
する化粧紙を断面で表した説明図である。また、図2
は、他の実施例における耐摩耗性を有する化粧紙を断面
で表した説明図である。図に示すように、(11)は化
粧紙用の原紙、(12)は無色又は着色透明ウレタン系
樹脂コート剤による印刷層、(13)は硝化綿インキに
よる柄印刷層、(15)は盛り上げ印刷による凹凸模様
である。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Specific embodiments of the present invention will be described in detail below with reference to the drawings. FIG. 1 is an explanatory view showing a cross section of a wear-resistant decorative paper in one example. FIG.
FIG. 6 is an explanatory view showing a cross section of a decorative paper having abrasion resistance in another example. As shown in the figure, (11) is a base paper for decorative paper, (12) is a printing layer with a colorless or colored transparent urethane resin coating agent, (13) is a pattern printing layer with nitrified cotton ink, and (15) is raised. It is an uneven pattern due to printing.

【0010】<実施例1>図1に示すように、化粧紙用
の原紙(11)として天間特種製紙(株)社製、商品名
HPN晒タイプを用いて、この上にウレタン系樹脂をバ
インダーとしたインキ(大日精化(株)社製、商品名ウ
レタンエナメル白)で全面にベタで印刷層(12)を設
け乾燥した後に、ウレタン系樹脂を主とする盛り上げイ
ンキ(大日精化(株)社製、商品名KKBキュアUマッ
トメヂウム)を使用してグラビア印刷方式で盛り上げ印
刷により凹凸模様(15)を形成する。この際に、凹凸
模様の凹部(15b)の底面と凸部(15a)の表面の
高低差が15〜50μmの範囲で、凸部(15a)の表
面積の割合が、表面層全体の15〜50%になるように
グラビア版を調整する。この凹凸模様(15)の印刷に
用いた盛り上げ用インキの乾燥条件は、蒸気乾燥90℃
とIR乾燥340℃を併用し、乾燥ラインスピードは4
0m/分で行った。
<Example 1> As shown in FIG. 1, as a base paper (11) for decorative paper, a HPN bleach type manufactured by Tenma Tokushu Paper Co. A solid printing layer (12) was formed over the entire surface with ink (binder urethane enamel white, manufactured by Dainichiseika Co., Ltd.) as a binder and dried, and then a swelling ink mainly composed of urethane resin (Dainichi Seika ( A rugged pattern (15) is formed by gravure printing by a gravure printing method using KKB Cure U Matt Medium (trade name, manufactured by Co., Ltd.). At this time, when the height difference between the bottom surface of the concave and convex portion (15b) and the surface of the convex portion (15a) is 15 to 50 μm, the ratio of the surface area of the convex portion (15a) is 15 to 50 of the entire surface layer. Adjust the gravure plate so that it becomes%. The conditions for drying the ink for heaping used for printing the uneven pattern (15) are steam drying 90 ° C.
And IR drying 340 ° C are used together, and the drying line speed is 4
It was performed at 0 m / min.

【0011】<実施例2>図2に示すように、原紙(1
1)に天間特種製紙(株)社製、商品名HPN晒タイプ
を用いて、この上に硝化綿系樹脂をバインダーとしたイ
ンキ(東洋インキ製造(株)社製、商品名PC−92
1)を用いて柄印刷層(13)を設け、この上に透明ウ
レタンコート剤(日立化成ポリマー(株)社製、商品名
TU111)による印刷層(ウレタンコート層)(1
2)を設け、さらにこの上に実施例1と同様に盛り上げ
印刷による凹凸模様(15)を形成したものである。こ
の乾燥条件、凹凸模様の高低差、凸部の表面積の割合は
実施例1と同様に行った。なお、この実施例2における
化粧紙は、柄印刷層(13)と盛り上げ印刷による凹凸
模様(15)とを同調(凹凸模様と柄印刷層の柄印刷見
当が合致している)させることも可能である。
<Embodiment 2> As shown in FIG.
1) Ink using Tetanuma Tokushu Paper Co., Ltd., trade name HPN bleach type, with nitrified cotton resin as binder (Toyo Ink Mfg. Co., Ltd., trade name PC-92)
1) is used to form a pattern printing layer (13), and a printing layer (urethane coating layer) (1) made of a transparent urethane coating agent (Hitachi Chemical Polymer Co., Ltd., trade name TU111) is provided on the pattern printing layer (1).
2) is provided, and the concavo-convex pattern (15) is formed thereon by raised printing in the same manner as in Example 1. The drying conditions, the height difference of the uneven pattern, and the ratio of the surface area of the convex portion were the same as in Example 1. In the decorative paper in Example 2, the pattern printing layer (13) and the uneven pattern (15) by raised printing can be synchronized (the uneven pattern and the pattern printing register of the pattern printing layer match each other). Is.

【0012】<評価>次に、実施例1と実施例2で得ら
れた化粧紙を、日本農林規格(JAS)の物性試験に基
づき耐摩耗性の試験を行い評価した。JASの耐摩耗性試験の条件 B試験 (FWタイプ−主として耐久壁面等用、家具用に
供される) 試料・直径120mm円板、中心に10mmφの穴。 器具・テーパー型,アブレーザー,除塵装置,研磨紙J
ISR6252 AA180 番 試験法・500g荷重,25回転毎にチェックし印刷模
様の50%が消失したとき、無地の時は色の層が初めに
切り取られた時を終点とする。 判定・摩耗値50以上,摩耗量0.1g以下C試験 (Wタイプ−一般壁面等の用に供される) 試料、器具共にB試験と同様なもの(但し研磨紙は使用
しない)。 試験法・1000g荷重,他はB試験と同じ。 判定・摩耗値200以上,摩耗量測定せず。 以上耐摩耗性の試験結果を表1に示す。なお、実施例
1、実施例2で得られたサンプルの表面層に設けた盛り
上げ印刷による凹凸模様の塗膜厚は25μmであった。
<Evaluation> Next, the decorative papers obtained in Example 1 and Example 2 were evaluated for abrasion resistance based on the physical property test of Japanese Agricultural Standards (JAS). JAS abrasion resistance test condition B test (FW type-mainly used for durable wall surfaces, furniture, etc.) Sample / 120 mm diameter disk, 10 mmφ hole in the center. Equipment / taper type, abrazer, dust remover, abrasive paper J
ISR6252 AA180 No. test method ・ Check at every 25 rotations under a load of 500 g, and when 50% of the printed pattern disappears, when it is plain, the end is when the color layer is first cut off. Judgment / wear value 50 or more, wear amount 0.1 g or less C test (W type-used for general wall surface etc.) Both sample and equipment are the same as B test (however, abrasive paper is not used). Test method ・ 1000g load, otherwise the same as B test. Judgment ・ Wear value is 200 or more, wear amount is not measured. Table 1 shows the above abrasion resistance test results. In addition, the coating film thickness of the concavo-convex pattern formed on the surface layer of the samples obtained in Examples 1 and 2 by the embossing printing was 25 μm.

【0013】[0013]

【表1】 [Table 1]

【0014】[0014]

【発明の効果】本発明の耐摩耗性を有する化粧紙は、表
面層に盛り上げ印刷による凹凸模様を設けたことによ
り、摩耗が発生するところは凸部のみで、しかもこの面
積が表面層全体の15〜50%であることから、例え
ば、表面に擦過傷を受けても白化現象が目立たない。ま
た、盛り上げ印刷による凹凸模様の占める面積の割合が
表面層全体の15〜50%であることから、同等の乾燥
能力であっても全面塗工のものより凸部の厚塗りが可能
となり(凸部の塗膜厚は15〜50μm)、この塗膜厚
により、摩耗で柄印刷層まで消失することがない。さら
に、この化粧紙は、盛り上げ印刷による凹凸模様で独特
の意匠感が得られる等種々の優れた効果が生じる。
EFFECTS OF THE INVENTION The wear-resistant decorative paper of the present invention is provided with the uneven pattern formed by the raised printing on the surface layer, so that the wear occurs only on the convex portion, and this area is equal to that of the entire surface layer. Since it is 15 to 50%, for example, the whitening phenomenon is not noticeable even if the surface is scratched. Further, since the area occupied by the uneven pattern due to the raised printing is 15 to 50% of the entire surface layer, it is possible to apply thicker coating to the convex portion than that of the entire surface coating even with the same drying ability (convex pattern). The coating film thickness of the part is 15 to 50 μm), and this coating film thickness prevents the pattern printing layer from being lost by abrasion. Further, this decorative paper has various excellent effects such as a unique design feeling due to the uneven pattern formed by the raised printing.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例を示す、耐摩耗性を有する化
粧紙を断面で表した説明図である。
FIG. 1 is an explanatory view showing a cross section of a wear-resistant decorative paper showing an embodiment of the present invention.

【図2】本発明の他の実施例を示す、耐摩耗性を有する
化粧紙を断面で表した説明図である。
FIG. 2 is an explanatory view showing a cross section of a wear-resistant decorative paper showing another embodiment of the present invention.

【図3】従来の化粧紙の一例を示す断面で表した説明図
である。
FIG. 3 is an explanatory view showing an example of a conventional decorative paper in a cross section.

【符号の説明】[Explanation of symbols]

11,21…原紙 12,22…印刷層(ウレタンコート層) 13…柄印刷層 15…盛り上げ印刷による凹凸模様 15a…凸部 15b…凹部 25…トップコート層 11, 21 ... Base paper 12, 22 ... Printing layer (urethane coat layer) 13 ... Pattern printing layer 15 ... Concavo-convex pattern by raised printing 15a ... Convex portion 15b ... Recessed portion 25 ... Top coat layer

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 E04F 13/00 B 9127−2E ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Office reference number FI technical display location E04F 13/00 B 9127-2E

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】化粧紙用の原紙上に、ウレタン系樹脂をバ
インダーとしたインキにより印刷層を設け、この表面層
にウレタン系樹脂の盛り上げインキを用いて盛り上げ印
刷による凹凸模様を設けた化粧紙であって、この凹凸模
様の凹部と凸部の高低差が15〜50μmの範囲で、か
つ、凸部表面積の割合が、表面層全体の15〜50%を
占めることを特徴とする耐摩耗性を有する化粧紙。
1. A decorative paper in which a printing layer is formed on a base paper for decorative paper with an ink using a urethane resin as a binder, and an uneven pattern is formed on the surface layer of the urethane resin by a rising ink. The wear resistance is characterized in that the height difference between the concave and convex portions of the uneven pattern is in the range of 15 to 50 μm, and the proportion of the surface area of the convex portion occupies 15 to 50% of the entire surface layer. Paper with.
JP23372194A 1994-09-28 1994-09-28 Decorative paper with wear resistance Expired - Lifetime JP3334365B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP23372194A JP3334365B2 (en) 1994-09-28 1994-09-28 Decorative paper with wear resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23372194A JP3334365B2 (en) 1994-09-28 1994-09-28 Decorative paper with wear resistance

Publications (2)

Publication Number Publication Date
JPH08100397A true JPH08100397A (en) 1996-04-16
JP3334365B2 JP3334365B2 (en) 2002-10-15

Family

ID=16959527

Family Applications (1)

Application Number Title Priority Date Filing Date
JP23372194A Expired - Lifetime JP3334365B2 (en) 1994-09-28 1994-09-28 Decorative paper with wear resistance

Country Status (1)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003101734A1 (en) 2002-05-30 2003-12-11 Dai Nippon Printing Co., Ltd. Decorative material and decorative sheet
JP2008087158A (en) * 2006-09-29 2008-04-17 Dainippon Printing Co Ltd Decorative sheet
JP2008087156A (en) * 2006-09-29 2008-04-17 Dainippon Printing Co Ltd Decorative sheet
JP2009234159A (en) * 2008-03-28 2009-10-15 Dainippon Printing Co Ltd Decorative film for molding

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4994912A (en) * 1973-01-25 1974-09-09
JPS5259783U (en) * 1975-10-28 1977-04-30
JPS5668195A (en) * 1979-11-02 1981-06-08 Toppan Printing Co Ltd Embossed pattern paper and method
JPS63249799A (en) * 1987-03-31 1988-10-17 大日本印刷株式会社 Production of water resistant decorative sheet

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4994912A (en) * 1973-01-25 1974-09-09
JPS5259783U (en) * 1975-10-28 1977-04-30
JPS5668195A (en) * 1979-11-02 1981-06-08 Toppan Printing Co Ltd Embossed pattern paper and method
JPS63249799A (en) * 1987-03-31 1988-10-17 大日本印刷株式会社 Production of water resistant decorative sheet

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003101734A1 (en) 2002-05-30 2003-12-11 Dai Nippon Printing Co., Ltd. Decorative material and decorative sheet
US8497011B2 (en) 2002-05-30 2013-07-30 Dai Nippon Printing Co., Ltd. Decorative material and decorative sheet
EP2671721A1 (en) 2002-05-30 2013-12-11 Dai Nippon Printing Co., Ltd. Decorative material and decorative sheet
JP2008087158A (en) * 2006-09-29 2008-04-17 Dainippon Printing Co Ltd Decorative sheet
JP2008087156A (en) * 2006-09-29 2008-04-17 Dainippon Printing Co Ltd Decorative sheet
JP2009234159A (en) * 2008-03-28 2009-10-15 Dainippon Printing Co Ltd Decorative film for molding

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