JPH0791172B2 - 歯科材料を調製するための硬化性モノマー混合物 - Google Patents
歯科材料を調製するための硬化性モノマー混合物Info
- Publication number
- JPH0791172B2 JPH0791172B2 JP1319070A JP31907089A JPH0791172B2 JP H0791172 B2 JPH0791172 B2 JP H0791172B2 JP 1319070 A JP1319070 A JP 1319070A JP 31907089 A JP31907089 A JP 31907089A JP H0791172 B2 JPH0791172 B2 JP H0791172B2
- Authority
- JP
- Japan
- Prior art keywords
- curable monomer
- monomer mixture
- dental material
- value
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 12
- 239000000178 monomer Substances 0.000 title claims description 12
- 239000005548 dental material Substances 0.000 title claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- -1 oxypropylene, oxybutylene, oxyoctylene, oxydecylene Chemical group 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- 229920002959 polymer blend Polymers 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000006353 oxyethylene group Chemical group 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000012966 redox initiator Substances 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- GGSQMKDPESKTMD-UHFFFAOYSA-N (1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-yl) prop-2-enoate Chemical compound C=CC(=O)OC(C(F)(F)F)(C(F)(F)F)C1=CC=CC=C1 GGSQMKDPESKTMD-UHFFFAOYSA-N 0.000 description 1
- UGVKSFUTKAXDFO-UHFFFAOYSA-N (1,2,2,2-tetrafluoro-1-phenylethyl)benzene Chemical class C=1C=CC=CC=1C(F)(C(F)(F)F)C1=CC=CC=C1 UGVKSFUTKAXDFO-UHFFFAOYSA-N 0.000 description 1
- HSOOIVBINKDISP-UHFFFAOYSA-N 1-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(CCC)OC(=O)C(C)=C HSOOIVBINKDISP-UHFFFAOYSA-N 0.000 description 1
- RSVZYSKAPMBSMY-UHFFFAOYSA-N 2,2,3,3-tetrafluoropropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)C(F)F RSVZYSKAPMBSMY-UHFFFAOYSA-N 0.000 description 1
- PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical compound CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- GCTPMLUUWLLESL-UHFFFAOYSA-N benzyl prop-2-enoate Chemical class C=CC(=O)OCC1=CC=CC=C1 GCTPMLUUWLLESL-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical class C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- AQYSYJUIMQTRMV-UHFFFAOYSA-N hypofluorous acid Chemical compound FO AQYSYJUIMQTRMV-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- VHRYZQNGTZXDNX-UHFFFAOYSA-N methacryloyl chloride Chemical compound CC(=C)C(Cl)=O VHRYZQNGTZXDNX-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/62—Halogen-containing esters
- C07C69/65—Halogen-containing esters of unsaturated acids
- C07C69/653—Acrylic acid esters; Methacrylic acid esters; Haloacrylic acid esters; Halomethacrylic acid esters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
- C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C271/16—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by singly-bound oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F20/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
- C08F20/36—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/288—Compounds containing at least one heteroatom other than oxygen or nitrogen
- C08G18/2885—Compounds containing at least one heteroatom other than oxygen or nitrogen containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/81—Unsaturated isocyanates or isothiocyanates
- C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
- C08G18/8116—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group esters of acrylic or alkylacrylic acid having only one isocyanate or isothiocyanate group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Epidemiology (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dental Preparations (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3841617.4 | 1988-12-10 | ||
| DE3844619A DE3844619A1 (de) | 1988-12-10 | 1988-12-10 | Verwendung von perfluoroalkylgruppen aufweisenden (meth-)acrylsaeureestern in der dentaltechnik |
| DE3841617A DE3841617C1 (enExample) | 1988-12-10 | 1988-12-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02202850A JPH02202850A (ja) | 1990-08-10 |
| JPH0791172B2 true JPH0791172B2 (ja) | 1995-10-04 |
Family
ID=25874996
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1319070A Expired - Lifetime JPH0791172B2 (ja) | 1988-12-10 | 1989-12-11 | 歯科材料を調製するための硬化性モノマー混合物 |
| JP1319069A Expired - Lifetime JPH0739382B2 (ja) | 1988-12-10 | 1989-12-11 | マクロモノマーフルオルアルキル基を有する（メタ）アクリル酸エステルおよびその製法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1319069A Expired - Lifetime JPH0739382B2 (ja) | 1988-12-10 | 1989-12-11 | マクロモノマーフルオルアルキル基を有する（メタ）アクリル酸エステルおよびその製法 |
Country Status (5)
| Country | Link |
|---|---|
| EP (2) | EP0373384B1 (enExample) |
| JP (2) | JPH0791172B2 (enExample) |
| DE (3) | DE3844619A1 (enExample) |
| ES (2) | ES2053923T3 (enExample) |
| GR (2) | GR3006881T3 (enExample) |
Families Citing this family (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1270818B (it) * | 1993-04-28 | 1997-05-13 | Ausimont Spa | Coatings a base di perfluoropolieteri contenenti gruppi acrilici |
| US5662887A (en) * | 1994-12-01 | 1997-09-02 | Minnesota Mining And Manufacturing Company | Fluorocarbon containing coatings, compositions and methods of use |
| DE4445266A1 (de) * | 1994-12-19 | 1996-06-20 | Thera Ges Fuer Patente | Fluoridabgebende Composite-Massen |
| FR2749170B1 (fr) * | 1996-05-30 | 1998-08-21 | Bellesort Stephane | Protheses dentaires modifiees en surface et procede d'obtention |
| DE60018044T2 (de) * | 1999-02-18 | 2005-12-29 | Commonwealth Scientific And Industrial Research Organisation | Neue biomaterialien |
| DE60005423T2 (de) | 1999-03-03 | 2004-07-22 | KURARAY CO., LTD, Kurashiki | Unterfütterungsmaterial für Zahnprothesen |
| WO2000078830A1 (en) * | 1999-06-22 | 2000-12-28 | Novartis Ag | Process for the manufacture of moldings |
| US6773261B2 (en) | 2002-06-28 | 2004-08-10 | 3M Innovative Properties Company | Processes for forming dental materials |
| US7134875B2 (en) | 2002-06-28 | 2006-11-14 | 3M Innovative Properties Company | Processes for forming dental materials and device |
| US20040206932A1 (en) | 2002-12-30 | 2004-10-21 | Abuelyaman Ahmed S. | Compositions including polymerizable bisphosphonic acids and methods |
| US7632098B2 (en) | 2003-08-12 | 2009-12-15 | 3M Innovative Properties Company | Self-adhesive dental compositions and methods |
| US7026367B2 (en) | 2003-09-26 | 2006-04-11 | 3M Innovative Properties Company | Photoiniators having triarylsulfonium and arylsulfinate ions |
| US7250452B2 (en) | 2003-09-26 | 2007-07-31 | 3M Innovative Properties Company | Dental compositions and methods with arylsulfinate salts |
| US7030169B2 (en) | 2003-09-26 | 2006-04-18 | 3M Innovative Properties Company | Arylsulfinate salts in initiator systems for polymeric reactions |
| US7090721B2 (en) | 2004-05-17 | 2006-08-15 | 3M Innovative Properties Company | Use of nanoparticles to adjust refractive index of dental compositions |
| US7090722B2 (en) | 2004-05-17 | 2006-08-15 | 3M Innovative Properties Company | Acid-reactive dental fillers, compositions, and methods |
| US7649029B2 (en) | 2004-05-17 | 2010-01-19 | 3M Innovative Properties Company | Dental compositions containing nanozirconia fillers |
| US7156911B2 (en) | 2004-05-17 | 2007-01-02 | 3M Innovative Properties Company | Dental compositions containing nanofillers and related methods |
| US8465284B2 (en) | 2004-07-08 | 2013-06-18 | 3M Innovative Properties Company | Dental methods, compositions, and kits including acid-sensitive dyes |
| JP4879894B2 (ja) | 2004-07-14 | 2012-02-22 | スリーエム イノベイティブ プロパティズ カンパニー | カルボシランポリマーを含有する歯科用組成物 |
| AU2005275246B2 (en) | 2004-07-14 | 2011-10-06 | 3M Deutschland Gmbh | Dental compositions containing carbosilane monomers |
| EP1784155B1 (en) | 2004-08-11 | 2011-09-28 | 3M Innovative Properties Company | Self-adhesive compositions including a plurality of acidic compounds |
| EP1819313B1 (en) | 2004-11-16 | 2010-12-29 | 3M Innovative Properties Company | Dental fillers and compositions including phosphate salts |
| KR101240883B1 (ko) | 2004-11-16 | 2013-03-07 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 카제이네이트를 포함하는 치과용 충전제, 방법, 조성물 |
| US8957126B2 (en) | 2004-11-16 | 2015-02-17 | 3M Innovative Properties Company | Dental compositions with calcium phosphorus releasing glass |
| CA2587556A1 (en) | 2004-11-16 | 2006-05-26 | 3M Innovative Properties Company | Dental fillers including a phosphorus containing surface treatment, and compositions and methods thereof |
| CN102512329A (zh) | 2005-05-09 | 2012-06-27 | 3M创新有限公司 | 含有杂化单体的牙科组合物 |
| EP1909742B1 (en) | 2005-08-05 | 2010-07-14 | 3M Espe AG | Dental compositions containing a surface-modified filler |
| EP1787627A1 (en) | 2005-11-17 | 2007-05-23 | 3M Innovative Properties Company | Anti-microbial dental impression material |
| US7896650B2 (en) | 2005-12-20 | 2011-03-01 | 3M Innovative Properties Company | Dental compositions including radiation-to-heat converters, and the use thereof |
| US8026296B2 (en) | 2005-12-20 | 2011-09-27 | 3M Innovative Properties Company | Dental compositions including a thermally labile component, and the use thereof |
| US7776940B2 (en) | 2005-12-20 | 2010-08-17 | 3M Innovative Properties Company | Methods for reducing bond strengths, dental compositions, and the use thereof |
| US8071662B2 (en) | 2005-12-29 | 2011-12-06 | 3M Innovative Properties Company | Dental compositions with surface-treated filler for shelf stability |
| WO2007079070A1 (en) | 2005-12-29 | 2007-07-12 | 3M Innovative Properties Company | Dental compositions and initiator systems with polycyclic aromatic component |
| EP1881010B1 (en) | 2006-05-31 | 2010-08-11 | 3M Innovative Properties Company | Polymerizable compositions containing salts of barbituric acid derivatives |
| CN101516319B (zh) | 2006-09-13 | 2015-11-25 | 3M创新有限公司 | 包含有机凝胶因子的牙科用组合物、产品及方法 |
| US9539065B2 (en) | 2006-10-23 | 2017-01-10 | 3M Innovative Properties Company | Assemblies, methods, and kits including a compressible material |
| US20080096150A1 (en) | 2006-10-23 | 2008-04-24 | 3M Innovative Properties Company | Dental articles, methods, and kits including a compressible material |
| JP5507256B2 (ja) | 2006-12-13 | 2014-05-28 | スリーエム イノベイティブ プロパティズ カンパニー | 酸性成分及び光退色性染料を有する歯科用組成物の使用方法 |
| EP2114351B1 (en) | 2006-12-28 | 2016-07-13 | 3M Innovative Properties Company | Dental compositions with natural tooth fluorescence |
| WO2008082929A2 (en) | 2006-12-28 | 2008-07-10 | 3M Innovative Properties Company | Adhesive composition for hard tissue |
| JP5512280B2 (ja) | 2006-12-28 | 2014-06-04 | スリーエム イノベイティブ プロパティズ カンパニー | 歯科充填剤及び方法 |
| EP2203144A2 (en) | 2007-10-01 | 2010-07-07 | 3M Innovative Properties Company | Orthodontic composition with polymeric fillers |
| JP5461415B2 (ja) | 2007-11-01 | 2014-04-02 | スリーエム イノベイティブ プロパティズ カンパニー | 歯科用組成物及び色安定アミン電子供与体を有する開始剤系 |
| WO2009075977A1 (en) | 2007-12-13 | 2009-06-18 | 3M Innovative Properties Company | Orthodontic article having partially hardened composition and method of its use and manufacture |
| CN102224106A (zh) | 2008-10-15 | 2011-10-19 | 3M创新有限公司 | 具有氧化锆和二氧化硅纳米粒子的填料和复合材料 |
| BRPI0914427C8 (pt) | 2008-10-15 | 2018-07-24 | 3M Innovative Properties Co | composição dental endurecível |
| WO2010068359A1 (en) | 2008-12-11 | 2010-06-17 | 3M Innovative Properties Company | Surface-treated calcium phosphate particles suitable for oral care and dental compositions |
| WO2012021442A1 (en) | 2010-08-11 | 2012-02-16 | 3M Innovative Properties Company | Coated dental crows and method of making the same |
| US20130130203A1 (en) | 2010-08-11 | 2013-05-23 | 3M Innovative Properties Company | Polymer coated dental articles and method of making the same |
| EP2603159A1 (en) | 2010-08-11 | 2013-06-19 | 3M Innovative Properties Company | Aesthetic and abrasion resistant coated dental articles and methods of making the same |
| CN103281986B (zh) | 2010-12-30 | 2016-08-17 | 3M创新有限公司 | 包括可压缩材料的可粘合牙科用组件和方法 |
| EP2688508A1 (en) | 2011-03-24 | 2014-01-29 | 3M Innovative Properties Company | Dental adhesive comprising a coated polymeric component |
| KR102186225B1 (ko) | 2013-03-19 | 2020-12-03 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 자유 라디칼 중합 방법 및 그에 의한 물품 |
| EP3013868B1 (en) | 2013-06-28 | 2017-10-18 | 3M Innovative Properties Company | Acid-modified nanoparticles, dual part polymerizable compositions, and methods |
| CN105705112B (zh) | 2013-10-04 | 2018-02-27 | 3M创新有限公司 | 牙科研磨坯料、牙科修复体以及形成牙科研磨坯料的方法 |
| US20170190937A1 (en) | 2014-06-24 | 2017-07-06 | 3M Innovative Properties Company | Adhesive precursor composition, two-part adhesive kit, and method of making an adhesive composition |
| KR102407089B1 (ko) | 2014-07-22 | 2022-06-10 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 자유 라디칼 중합 방법 및 그에 의한 물품 |
| EP3194455B1 (en) | 2014-09-16 | 2019-02-06 | 3M Innovative Properties Company | Free-radical polymerization methods and articles thereby |
| WO2016053877A1 (en) | 2014-09-30 | 2016-04-07 | 3M Innovative Properties Company | Free-radical polymerization methods and articles thereby |
| CN107108571A (zh) | 2014-12-22 | 2017-08-29 | 3M创新有限公司 | 立体受阻烷基和烷氧基胺光稳定剂 |
| EP3237381A1 (en) | 2014-12-22 | 2017-11-01 | 3M Innovative Properties Company | Sterically hindered amine and oxyalkyl amine light stabilizers |
| JP6659716B2 (ja) | 2015-03-05 | 2020-03-04 | スリーエム イノベイティブ プロパティズ カンパニー | セラミック繊維を有する複合材料 |
| JP6497350B2 (ja) * | 2016-04-15 | 2019-04-10 | 信越化学工業株式会社 | 含フッ素アクリル組成物及びその製造方法、含フッ素活性エネルギー線硬化性組成物並びに物品 |
| WO2021191773A1 (en) | 2020-03-25 | 2021-09-30 | 3M Innovative Properties Company | Dental appliance with graphic image |
| WO2022064292A1 (en) | 2020-09-25 | 2022-03-31 | 3M Innovative Properties Company | Photopolymerizable compositions and reaction products thereof |
| EP4271322A1 (en) | 2020-12-30 | 2023-11-08 | 3M Innovative Properties Company | Bondable orthodontic assemblies and methods for bonding |
| WO2022162488A1 (en) | 2021-01-29 | 2022-08-04 | 3M Innovative Properties Company | Dental appliances from multilayer films having discrete structures covered by an ion permeable release layer |
| EP4308571A1 (en) | 2021-03-17 | 2024-01-24 | 3M Innovative Properties Company | Polymerizable 4,4'-spirobi[chromane]-2,2'-diones and curable compositions including the same |
| EP4355794A1 (en) | 2021-06-16 | 2024-04-24 | 3M Innovative Properties Company | Free-radically polymerizable copolymer, free-radically polymerizable composition containing the same, and polymerized reaction product therefrom |
| CN117836333A (zh) | 2021-09-01 | 2024-04-05 | 3M创新有限公司 | 可自由基聚合的组合物、其聚合的方法以及聚合的组合物 |
| WO2023073444A1 (en) | 2021-10-28 | 2023-05-04 | 3M Innovative Properties Company | Photopolymerizable composition, methods of bonding and sealing, and at least partially polymerized composition |
| CN118525068A (zh) | 2021-12-14 | 2024-08-20 | 3M创新有限公司 | 粘合剂组合物的可固化前体 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL266570A (enExample) * | 1960-07-09 | |||
| CH1753669D (enExample) * | 1968-11-25 | |||
| US3660360A (en) * | 1970-06-24 | 1972-05-02 | Nat Starch Chem Corp | Water- and oil repellency agents |
| US4508916A (en) * | 1979-04-11 | 1985-04-02 | Minnesota Mining And Manufacturing Company | Curable substituted urethane acrylates |
| JPS60146810A (ja) * | 1984-01-05 | 1985-08-02 | Kureha Chem Ind Co Ltd | 軟質義歯床裏装材料 |
| US4616073A (en) * | 1984-08-09 | 1986-10-07 | The United States Of America As Represented By The Department Of Health And Human Services | Hydrophobic dental composites based on a polyfluorinated dental resin |
| US4612356A (en) * | 1984-10-01 | 1986-09-16 | Ciba-Geigy Corporation | Homo- and co- (addition) polymers of di-perfluoroalkyl carbamyl group containing (meth) acrylate monomers |
| JPS61111309A (ja) * | 1984-11-02 | 1986-05-29 | Daikin Ind Ltd | α−フルオロアクリル酸誘導体ポリマ− |
| IT1185520B (it) * | 1985-02-22 | 1987-11-12 | Montefluos Spa | Poliacrilati e poliacrilammidi fluorurati a grado di reticolazione controllato e loro procedimento di preparazione |
| JPH01305052A (ja) * | 1988-06-01 | 1989-12-08 | Nippon Oil & Fats Co Ltd | ポリフルオロアルキルポリオキシアルキレン（メタ）アクリレート |
-
1988
- 1988-12-10 DE DE3844619A patent/DE3844619A1/de not_active Ceased
- 1988-12-10 DE DE3841617A patent/DE3841617C1/de not_active Expired - Lifetime
-
1989
- 1989-11-20 EP EP89121422A patent/EP0373384B1/de not_active Expired - Lifetime
- 1989-11-20 EP EP89121424A patent/EP0373385B1/de not_active Expired - Lifetime
- 1989-11-20 DE DE8989121424T patent/DE58903288D1/de not_active Expired - Fee Related
- 1989-11-20 ES ES89121424T patent/ES2053923T3/es not_active Expired - Lifetime
- 1989-11-20 ES ES89121422T patent/ES2052867T3/es not_active Expired - Lifetime
- 1989-12-11 JP JP1319070A patent/JPH0791172B2/ja not_active Expired - Lifetime
- 1989-12-11 JP JP1319069A patent/JPH0739382B2/ja not_active Expired - Lifetime
-
1993
- 1993-01-26 GR GR920403056T patent/GR3006881T3/el unknown
- 1993-02-11 GR GR920402397T patent/GR3007024T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GR3006881T3 (enExample) | 1993-06-30 |
| JPH02202866A (ja) | 1990-08-10 |
| DE3841617C1 (enExample) | 1990-05-10 |
| ES2052867T3 (es) | 1994-07-16 |
| GR3007024T3 (enExample) | 1993-07-30 |
| EP0373385B1 (de) | 1993-01-13 |
| JPH0739382B2 (ja) | 1995-05-01 |
| EP0373384A1 (de) | 1990-06-20 |
| DE58903288D1 (de) | 1993-02-25 |
| JPH02202850A (ja) | 1990-08-10 |
| EP0373385A1 (de) | 1990-06-20 |
| ES2053923T3 (es) | 1994-08-01 |
| DE3844619A1 (de) | 1990-07-12 |
| EP0373384B1 (de) | 1992-10-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0791172B2 (ja) | 歯科材料を調製するための硬化性モノマー混合物 | |
| US5026902A (en) | Dental compsition of perfluoroalkyl group-containing (meth-)acrylate esters | |
| Moszner et al. | A partially aromatic urethane dimethacrylate as a new substitute for Bis-GMA in restorative composites | |
| US6057383A (en) | Dental material based on polymerizable waxes | |
| US5076844A (en) | Perfluoroalkyl group-containing (meth-)acrylate esters, their synthesis and use in dental technology | |
| JP2555365B2 (ja) | トリシクロ〔５．２．１．０▲上２▼・▲上６▼〕デカン類のアクリル酸誘導体又はメタクリル酸誘導体 | |
| JP2880455B2 (ja) | 液晶モノマーベースの歯科用材料 | |
| Ge et al. | Synthesis and photopolymerization of low shrinkage methacrylate monomers containing bulky substituent groups | |
| US3810938A (en) | Novel diacrylic and dimethacrylic acid esters | |
| JP2588534B2 (ja) | アクリル酸エステルおよびメタクリル酸エステル | |
| WO1989000170A1 (fr) | Composition polymerisable | |
| Tauscher et al. | Evaluation of alternative monomers to HEMA for dental applications | |
| JPS61293960A (ja) | （メタ）アクリル酸エステル類 | |
| US20040229972A1 (en) | Low shrinking polymerizable dental material | |
| CA2207351C (en) | Dental material based on polymerizable waxes | |
| AU6170598A (en) | Low shrinking polymerizable dental material | |
| JPH10511354A (ja) | 重合性化合物および組成物 | |
| EP1879544B1 (en) | Materials and dental composites made therefrom | |
| EP0943601B1 (de) | Vinylcyclopropan-(Meth) acrylate und deren Verwendung | |
| US5132335A (en) | Acrylic and methacrylic esters of substituted 1,2-bis(phenoxy)-3,3,4,4,5,5-hexafluoro-1-cyclopentenes | |
| JP2023135159A (ja) | 歯科用接着性組成物 | |
| JP7851010B2 (ja) | 歯科用接着性組成物 | |
| WO2026042014A1 (en) | A photocurable acrylate resin monomer and the use thereof | |
| JPH0674235B2 (ja) | 含フッ素ビスフェノール基を骨格とするジアクリレートまたはジメタクリレートおよびこれらを成分とする高分子材料 | |
| JP2024045938A (ja) | 歯科用接着性組成物及びポリマー |