JPH0790762A - Heat-resistant non-woven fabric and production thereof - Google Patents

Heat-resistant non-woven fabric and production thereof

Info

Publication number
JPH0790762A
JPH0790762A JP19513593A JP19513593A JPH0790762A JP H0790762 A JPH0790762 A JP H0790762A JP 19513593 A JP19513593 A JP 19513593A JP 19513593 A JP19513593 A JP 19513593A JP H0790762 A JPH0790762 A JP H0790762A
Authority
JP
Japan
Prior art keywords
heat
fibers
woven fabric
resistant
polyphenylene sulfide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP19513593A
Other languages
Japanese (ja)
Other versions
JP2602166B2 (en
Inventor
Osamu Naito
内藤  治
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP5195135A priority Critical patent/JP2602166B2/en
Publication of JPH0790762A publication Critical patent/JPH0790762A/en
Application granted granted Critical
Publication of JP2602166B2 publication Critical patent/JP2602166B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Abstract

PURPOSE:To obtain a heat-resistant non-woven fabric having high air permeability and flexibility by using polyester fibers and/or polyphenylene sulfide fibers in an extremely low blending rate and pressing the produced web with a low pressure. CONSTITUTION:Wholly aromatic polyamide fibers as a main component are blended with 1-3wt.% of polyester fibers and/or polyphenylene sulfide fibers, and the formed web is heated with the irradiation of far IR light and subsequently pressed with a low pressure to produce the heat-resistant non-woven fabric in which the cross points of the fibers composing the non-woven fabric are thermally adhered.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、全芳香族ポリアミド繊
維を主構成とし、ポリエステル及び/またはポリフェニ
レンサルファイドからなる繊維を溶融成分とする耐熱性
不織布及びその製造方法に関し、本発明により得られた
不織布は耐熱性絶縁ワニス含浸性に優れた、プリント配
線用基材、耐熱性電気絶縁シート、耐熱性の必要なフィ
ルター、更には耐熱性・難燃性の必要な断熱材や保温材
など広い用途に使用される。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a heat-resistant non-woven fabric comprising a wholly aromatic polyamide fiber as a main constituent and a fiber composed of polyester and / or polyphenylene sulfide as a melting component, and a method for producing the same. Nonwoven fabric has a wide range of applications such as printed wiring base materials, heat-resistant electrical insulation sheets, heat-resistant filters, and heat-insulating and heat-insulating materials that require heat-resistant and flame-retardant properties, which have excellent heat-resistant insulation varnish impregnation properties. Used for.

【0002】[0002]

【従来の技術及び解決しようとする課題】耐熱性を有す
る不織布としては、耐熱性繊維である全芳香族ポリアミ
ド繊維を同種のパルプ状粒子と共に混抄した湿式による
紙状不織布が広く知られ、また特公昭59−1818号
公報には未延伸の全芳香族ポリアミド繊維を接着成分と
する熱圧着による耐熱性不織布の製造方法が示されてい
る。
BACKGROUND OF THE INVENTION As a nonwoven fabric having heat resistance, a wet type paper-like nonwoven fabric in which wholly aromatic polyamide fibers, which are heat resistant fibers, are mixed with pulp-like particles of the same kind are widely known. JP-A-59-1818 discloses a method for producing a heat-resistant nonwoven fabric by thermocompression bonding using unstretched wholly aromatic polyamide fibers as an adhesive component.

【0003】上記の全芳香族ポリアミド繊維とパルプと
からなる不織布は密度が高く、空隙が少ないために、通
気性が低く柔軟性が乏しいので、フィルターとして用い
た場合、液体や気体の通過抵抗が著しく高い。従って耐
熱絶縁ワニスの含浸性も低く、ワニス含浸絶縁紙やフィ
ルターの用途には不適当である。更に、この湿式法によ
るものは、厚手の不織布の作製が困難なため、厚手のも
のは複数の薄手シートを積層して作成するため、加熱に
よりそれらの層間が剥離して、バブリング現象が多発し
実用に耐えないという欠点があった。
The above-mentioned non-woven fabric composed of wholly aromatic polyamide fibers and pulp has high density and few voids, and therefore has low air permeability and poor flexibility. Therefore, when it is used as a filter, it has a resistance to liquid or gas passage. Remarkably high. Therefore, the impregnation property of the heat-resistant insulating varnish is low, and it is unsuitable for use as a varnish-impregnated insulating paper or a filter. In addition, since it is difficult to produce a thick non-woven fabric by this wet method, a thick one is produced by laminating a plurality of thin sheets, so that the layers are peeled off by heating and a bubbling phenomenon frequently occurs. It had the drawback of not being practical.

【0004】次に、芳香族ポリアミド繊維及びポリエス
テル繊維より成る不織布は耐熱性が良好で、かつ機械的
物性が優れることから従来より種々の用途に用いられて
いる。例えば特公昭52−27189号公報には芳香族
ポリアミド繊維と低配向ポリエステル繊維を含む不織布
に樹脂を含浸したシートが開示されている。
Next, since the nonwoven fabric made of aromatic polyamide fiber and polyester fiber has good heat resistance and excellent mechanical properties, it has been conventionally used for various purposes. For example, Japanese Patent Publication No. 52-27189 discloses a sheet obtained by impregnating a non-woven fabric containing aromatic polyamide fibers and low-oriented polyester fibers with a resin.

【0005】また特開昭60−126400号公報には
芳香族ポリアミド繊維と低配向ポリエステル繊維を混合
したスラリーを湿式抄紙した後、熱圧加工した紙状物が
開示されており、樹脂を含浸することにより、フレキシ
ブルプリント基板に応用できることが開示されている。
Japanese Unexamined Patent Publication No. 60-126400 discloses a paper-like material prepared by wet pressing a slurry prepared by mixing aromatic polyamide fibers and low-orientation polyester fibers and then hot-pressing the slurry, which is impregnated with a resin. Therefore, it can be applied to a flexible printed circuit board.

【0006】また特開昭64−40649号公報には芳
香族ポリアミド繊維と低配向ポリエステル繊維(該ポリ
エステル中に2〜30重量%のポリアミドを均一分散し
ている)との混合が50/50〜80/20であること
を特徴とする耐熱性不織布が開示されている。
Further, in Japanese Patent Laid-Open No. 64-40649, mixing of aromatic polyamide fiber and low orientation polyester fiber (wherein 2 to 30% by weight of polyamide is uniformly dispersed in the polyester) is mixed at 50/50. A heat-resistant non-woven fabric characterized by being 80/20 is disclosed.

【0007】然し、これらの不織布は何れも低配向ポリ
エステル繊維が15%以上の高配合であるため融点以上
の温度で熱処理されたときポリエステル繊維が溶融する
ため不織布の寸法安定性を保持できないという欠点があ
った。即ち、耐熱性が優れるといっても、ポリエステル
繊維の有する熱溶融温度以上の耐熱性は保持し得ないも
のであった。例えば不織布にエポキシ樹脂を含浸し更に
片面に銅箔を貼り合せて260〜270℃を越えるハン
ダ浴上に浮かべるとポリエステル繊維が溶融してエポキ
シ樹脂の表面に析出してくるため、フレキシブルプリン
ト基板として使用に耐えないものとなる。
However, in all of these non-woven fabrics, the low-orientation polyester fiber has a high blending ratio of 15% or more, so that the polyester fiber melts when heat-treated at a temperature above the melting point, so that the dimensional stability of the non-woven fabric cannot be maintained. was there. That is, although the heat resistance was excellent, the heat resistance above the heat melting temperature of the polyester fiber could not be maintained. For example, when a non-woven fabric is impregnated with epoxy resin and further copper foil is attached to one side and floated on a solder bath exceeding 260 to 270 ° C, polyester fibers are melted and deposited on the surface of the epoxy resin. It cannot be used.

【0008】一方、ポリフェニレンサルファイド樹脂
は、特公昭52−80609号公報や特開昭58−31
112号公報などに示される繊維化技術が知られ、ポリ
フェニレンサルファイド繊維を用いた耐熱性のニードル
パンチング法による短繊維フェルトや、特開昭57−1
6954号公報のスパンボンド法による長繊維不織布な
どが知られているが、何れも機械的絡合により形成され
るものであり、熱融着による結合がないために、高温で
長時間負担がかかる場合などの形態保持性が充分でな
い。熱融着結合点を付与するために不織布を熱圧着する
と全体がフィルム化し、通気性や柔軟性が大きく低下す
る。
On the other hand, polyphenylene sulfide resins are disclosed in Japanese Examined Patent Publication No. 52-80609 and Japanese Patent Laid-Open No. 58-31.
The fiberizing technique disclosed in Japanese Patent Application Laid-Open No. 112 etc. is known, and a short fiber felt by a heat-resistant needle punching method using polyphenylene sulfide fiber and JP-A-57-1 are used.
A long-fiber nonwoven fabric made by the spunbond method of 6954 is known, but all of them are formed by mechanical entanglement, and there is no bond by heat fusion, so that a load is applied for a long time at high temperature. In some cases, shape retention is not sufficient. When the non-woven fabric is thermocompression-bonded in order to provide the heat-bonding bonding points, the whole is formed into a film, and the air permeability and the flexibility are greatly reduced.

【0009】また8〜80%の高混率の未延伸ポリフェ
ニレンサルファイド繊維を融着成分として低温(183
〜257℃)かつ高線圧(30〜270kg/cm)で
プレスする方法が特開昭61−289162号公報に示
されている。この場合は非常に大きな圧力を必要とする
ので機械的制約があり、得られた不織布の通気性や柔軟
性が大きく低下して耐熱絶縁ワニスの含浸性が低下して
しまう。またフィルターの用途に用いた場合は液体や気
体の通気性が悪くなる。
Further, undrawn polyphenylene sulfide fiber having a high mixing ratio of 8 to 80% is used as a fusion component at a low temperature (183
The method of pressing at a high linear pressure (30 to 270 kg / cm) at ˜257 ° C.) is disclosed in JP-A-61-289162. In this case, a very large pressure is required, so that there is a mechanical restriction, and the air permeability and flexibility of the obtained nonwoven fabric are greatly reduced, so that the impregnation property of the heat resistant insulating varnish is reduced. Further, when it is used as a filter, the permeability of liquid or gas becomes poor.

【0010】また特開平3−137259号公報及び特
開平3−137260号公報による耐熱性不織布の製造
方法として、97〜92重量%の耐熱性繊維(全芳香族
ポリアミド繊維)と3〜8重量%の延伸ポリフェニレン
サルファイド繊維または未延伸ポリフェニレンサルファ
イド繊維とを混綿してウェブを形成し、245〜345
℃で加圧熱処理(2本の対金属ロールで線圧5〜100
kg/cm)でプレスする方法が開示されている。
Further, as a method for producing a heat-resistant nonwoven fabric according to JP-A-3-137259 and JP-A-3-137260, 97-92% by weight of heat-resistant fiber (whole aromatic polyamide fiber) and 3-8% by weight are used. 245-345 to form a web by blending with the stretched polyphenylene sulfide fiber or the unstretched polyphenylene sulfide fiber.
Pressure heat treatment at ℃ (2 to 100 rolls with linear pressure 5-100)
A method of pressing at (kg / cm) is disclosed.

【0011】ところで、厚手の不織布を製造する場合、
通気性や柔軟性を保持するために2本の対金属ロールで
低圧力でプレスしても不織布の内部にまで均等に加熱温
度が伝わり難い、即ち、不織布の表面温度と内部温度と
の隔差が発生して均一に熱融着しないため機械的物性が
充分でない。従って実用性のある厚手の不織布を製造す
る場合、厚さ(目付)に限界を生ずることになる。
By the way, when manufacturing a thick non-woven fabric,
Even if pressed with low pressure with two anti-metal rolls to maintain air permeability and flexibility, it is difficult to evenly transmit the heating temperature to the inside of the non-woven fabric, that is, the difference between the surface temperature of the non-woven fabric and the internal temperature. Mechanical properties are not sufficient because they are generated and do not heat-bond uniformly. Therefore, when manufacturing a practical thick nonwoven fabric, there is a limit in thickness (weight).

【0012】[0012]

【発明の目的】本発明はかかる問題点を解決するために
なされたものであり、極めて低い混率のポリアミド繊維
及び/またはポリフェニレンサルファイド繊維を用い、
しかも低圧力でプレスすることで通気性や柔軟性を保有
する耐熱性不織布が得られることを見出したものであ
る。
The present invention has been made to solve the above problems, and uses polyamide fibers and / or polyphenylene sulfide fibers having an extremely low mixing ratio,
Moreover, they have found that a heat-resistant nonwoven fabric having breathability and flexibility can be obtained by pressing at a low pressure.

【0013】[0013]

【課題を解決するための手段】上記の問題を解決するた
め、本発明に係る製造方法は、不織布構成繊維の交点を
点接着させることにより耐熱絶縁ワニス含浸性に優れた
耐熱性不織布を得る製造方法において、前記不織布構成
繊維は全芳香族ポリアミド繊維を主構成とし、ポリエス
テル及び/またはポリフェニレンサルファイドの繊維で
あり、且つ前記点接着は、ポリエステル及び/またはポ
リフェニレンサルファイド繊維を1重量%以上3重量%
未満で混綿してウェブを形成し、軽い加圧と遠赤外線照
射による加熱処理の後、加圧して熱接着を行うことで形
成することを特徴とする。
In order to solve the above problems, the production method according to the present invention is a method for producing a heat-resistant non-woven fabric excellent in heat-insulating varnish impregnation property by spot-bonding the intersections of the non-woven fabric constituent fibers. In the method, the non-woven fabric-constituting fiber is a wholly aromatic polyamide fiber as a main component, and is a fiber of polyester and / or polyphenylene sulfide, and the point adhesion is 1 wt% or more and 3 wt% of the polyester and / or polyphenylene sulfide fiber.
It is characterized in that it is formed by kneading with less than the above to form a web, followed by light pressurization and heat treatment by irradiation with far infrared rays, and then pressurizing and thermally adhering.

【0014】本発明の好ましい実施態様は、不織布構成
繊維は全芳香族ポリアミド繊維を主構成とし、ポリエス
テル繊維及び/またはポリフェニレンサルファイド繊維
を1重量%以上3重量%未満で混綿してウェブを形成
し、不織布構成繊維の交点を点接着させるため、軽い加
圧(線圧0.2〜0.8kg/cm)を行うローラ搬送
手段による搬送中に遠赤外線照射より徐々に加熱し、前
記ウェブの温度が熱可塑性樹脂の熱溶融温度にまで上昇
した直後に線圧1〜100kg/cmで加圧することに
より耐熱絶縁ワニス含浸性に優れた耐熱性不織布を得る
製造方法である。
In a preferred embodiment of the present invention, the non-woven fabric-constituting fibers are composed mainly of wholly aromatic polyamide fibers, and polyester fibers and / or polyphenylene sulfide fibers are mixed in an amount of 1% by weight or more and less than 3% by weight to form a web. The temperature of the web is gradually increased by irradiation with far-infrared rays during conveyance by a roller conveying means that is lightly pressed (linear pressure 0.2 to 0.8 kg / cm) in order to point-bond the intersection points of the nonwoven fabric constituent fibers. Is a manufacturing method for obtaining a heat-resistant nonwoven fabric excellent in heat-insulating varnish impregnation by pressurizing at a linear pressure of 1 to 100 kg / cm immediately after the temperature rises to the heat melting temperature of the thermoplastic resin.

【0015】また、本発明に係る耐熱性不織布は、全芳
香族ポリアミド繊維を主構成とし、ポリエステル及び/
またはポリフェニレンサルファイド繊維を1重量%以上
3重量%未満で混綿してなる不織布構成繊維の交点が点
接着されていることを特徴とする。
The heat-resistant non-woven fabric according to the present invention comprises wholly aromatic polyamide fibers as a main constituent, and polyester and / or
Alternatively, it is characterized in that the intersection points of the non-woven fabric constituent fibers obtained by mixing polyphenylene sulfide fibers in an amount of 1% by weight or more and less than 3% by weight are point-bonded.

【0016】本発明に利用される全芳香族ポリアミド繊
維としては、ポリ−m−フェニレンイソフタルアミド繊
維とその変成品と、ポリ−p−フェニレンテレフタルア
ミド繊維及びその変成品などである。また前記ローラ搬
送手段による搬送中に複数個が配置された加熱手段によ
り徐々に加熱される。加熱手段の加熱方法としては遠赤
外線照射による加熱によりウェブは内外層とも均一に加
熱されるため表面が焦げることなくムラのない加熱がで
きる。従来の加熱方法では表面から順に熱が伝わってゆ
くのに対して遠赤外線は空気層等の媒体に熱が吸収され
ることなく被加熱物に直接到達し発熱する。即ち、雰囲
気温度を高めずにウェブをスポット加熱することがで
き、加熱装置を密閉する必要がない。従って加熱効率が
高いと共に温度制御が極めて容易である。
The wholly aromatic polyamide fibers used in the present invention include poly-m-phenylene isophthalamide fibers and modified products thereof, and poly-p-phenylene terephthalamide fibers and modified products thereof. Further, while being transported by the roller transporting means, a plurality of heating means are arranged to gradually heat the heating means. As a heating method of the heating means, the web is heated uniformly by the irradiation of far infrared rays, and the inner and outer layers are uniformly heated, so that the surface can be uniformly heated without burning. In the conventional heating method, heat is transmitted in sequence from the surface, whereas far infrared rays directly reach the object to be heated and generate heat without being absorbed by the medium such as the air layer. That is, the web can be spot-heated without raising the ambient temperature, and it is not necessary to seal the heating device. Therefore, the heating efficiency is high and the temperature control is extremely easy.

【0017】遠赤外線照射により徐々に加熱されたウェ
ブは、その温度が接着成分として用いられた熱可塑性樹
脂の熱溶融温度、例えばポリエステルでは260℃、ポ
リフェニレンサルファイドでは290℃にまで上昇した
後、熱カレンダーローラによって加圧される。熱カレン
ダーローラによる加圧は、線圧1〜100kg/cmの
範囲で、不織布の目付が100g/m2 未満の場合の線
圧は1〜10kg/cm、また100〜200g/m2
以下の場合の線圧は20〜50kg/cm、200g/
2 を越える場合の線圧は60〜100kg/cmで行
われる。該カレンダーローラの表面温度は、熱損失等を
考慮して前記熱溶融温度より僅かに高めに設定されるこ
とが好ましい。
The web gradually heated by irradiation with far-infrared rays is heated to a heat melting temperature of the thermoplastic resin used as an adhesive component, for example, 260 ° C. for polyester and 290 ° C. for polyphenylene sulfide, and then heated. It is pressed by a calendar roller. The pressure applied by the thermal calendar roller is in the range of linear pressure of 1 to 100 kg / cm, and when the basis weight of the nonwoven fabric is less than 100 g / m 2 , the linear pressure is 1 to 10 kg / cm, and 100 to 200 g / m 2.
The linear pressure in the following cases is 20-50 kg / cm, 200 g /
When the pressure exceeds m 2 , the linear pressure is 60 to 100 kg / cm. The surface temperature of the calender roller is preferably set slightly higher than the heat melting temperature in consideration of heat loss and the like.

【0018】[0018]

【発明の効果】本発明の耐熱性不織布の製造方法によれ
ば、不織布構成繊維の交点を点接着させることにより、
通気性や柔軟性に優れ、しかも耐熱絶縁ワニス含浸性が
良好で、かつ機械的物性が優れているので、プリント配
線用基材、耐熱性電気絶縁シート、耐熱性の必要なフィ
ルター、更には耐熱性及び難燃性の必要な断熱材や保温
材など広い用途に使用できる。
According to the method for producing a heat-resistant nonwoven fabric of the present invention, the point of intersection of the fibers constituting the nonwoven fabric is point-bonded to
It has excellent breathability and flexibility, good impregnation with heat resistant insulating varnish, and excellent mechanical properties, so it is used as a substrate for printed wiring, heat resistant electrical insulation sheets, filters that require heat resistance, and even heat resistance. It can be used in a wide range of applications such as heat insulating materials and heat insulating materials that require heat resistance and flame retardancy.

【0019】[0019]

【実施例】以下、実施例により本発明を具体的に説明す
る。 実施例1 繊度2デニール、繊維長51mmの全芳香族ポリアミド
繊維(デュポン社製、商品名「ノーメックス(登録商
標)」)97.5重量%と繊度1.3デニール、繊維長
38mmの延伸ポリエステル繊維2.5重量%とをそれ
ぞれオープナーで充分開繊した後に混綿装置で均一に混
綿し、ローラーカードで配向したウェブを形成する。一
方、別系列のローラーカードにてウェブ化し、クロスレ
イヤーにてウェブを積層し、続いてウェブドラフターに
よってドラフト倍率を1.5〜2.5倍行ってウェブの
目付を調整した上で、上記の配向したウェブに重ね合わ
せて目付100g/m2 のウェブを形成した。次に、遠
赤外線セラミックヒーター方式の加熱装置によってポリ
エステルの溶融温度265℃まで上昇したウェブを熱カ
レンダーローラの表面温度270℃、線圧50kg/c
mで熱圧着して所期の耐熱性不織布を得た。この不織布
の物性を表1に示す。表1から、この不織布は強度が高
く、通気性があり柔軟で耐熱絶縁ワニスの含浸性もよ
く、熱収縮率及び重量減率が低く、耐熱性電気絶縁基材
や耐熱性フィルター、断熱材、保温材として優れている
ことが判る。
EXAMPLES The present invention will be specifically described below with reference to examples. Example 1 97.5% by weight of wholly aromatic polyamide fiber having a fineness of 2 denier and a fiber length of 51 mm (manufactured by DuPont, trade name "Nomex (registered trademark)"), a fineness of 1.3 denier and a stretched polyester fiber having a fiber length of 38 mm 2.5% by weight and each of them are sufficiently opened by an opener and then uniformly mixed by a mixing device to form an oriented web by a roller card. On the other hand, after making a web with a roller card of another series, laminating the web with a cross layer, and then performing a draft ratio of 1.5 to 2.5 times with a web drafter to adjust the basis weight of the web, The oriented web was superposed to form a web having a basis weight of 100 g / m 2 . Next, the web in which the polyester melting temperature was raised to 265 ° C. was heated by a far infrared ceramic heater type heating device, and the surface temperature of the thermal calendar roller was 270 ° C. and the linear pressure was 50 kg / c.
The desired heat resistant nonwoven fabric was obtained by thermocompression bonding with m. Table 1 shows the physical properties of this nonwoven fabric. From Table 1, this non-woven fabric has high strength, breathability, flexibility, good impregnation with heat resistant insulating varnish, low heat shrinkage and weight loss, heat resistant electrical insulating base material, heat resistant filter, heat insulating material, It turns out that it is excellent as a heat insulating material.

【0020】比較例1 実施例1と同様の配合及び方法によりウェブを形成し、
前記遠赤外線セラミックヒーター方式の加熱装置を使用
せずに、熱カレンダーローラの表面温度280℃、線圧
300kg/cmで熱圧着したところ、圧着条件が高温
且つ高圧であることから、全体がフィルム化し、通気
性、ワニス含浸性が低く、また柔軟性も乏しく取扱性が
不良であった。
Comparative Example 1 A web was formed by the same composition and method as in Example 1,
When thermocompression bonding was performed without using the far infrared ceramic heater type heating device at a surface temperature of a thermal calendar roller of 280 ° C. and a linear pressure of 300 kg / cm, the whole pressure was formed into a film because the pressure bonding conditions were high temperature and high pressure. The air permeability and varnish impregnation were low, and the flexibility was poor and the handling was poor.

【0021】比較例2 湿式法によって全芳香族ポリアミド不織布を得た。表1
に示す通りワニス含浸性が著しく劣っている。
Comparative Example 2 A wholly aromatic polyamide nonwoven fabric was obtained by a wet method. Table 1
As shown in, the varnish impregnation property is remarkably poor.

【0022】実施例2 繊度1.5デニール、繊維長47mmの全芳香族ポリア
ミド繊維(デュポン社製、商品名「ケブラー(登録商
標)」)98重量%と繊度2デニール、繊維長51mm
の延伸ポリフェニレンサルファイド繊維(東洋紡績社
製、商品名「プロコン(登録商標)」2重量%とを実施
例1と同様の方法で目付74g/m2 のウェブを形成
し、加熱装置で溶融温度290℃まで上昇させたウェブ
を熱カレンダーローラの表面温度300℃、線圧8kg
/cmで熱圧着して耐熱性不織布を得た。
Example 2 98% by weight of wholly aromatic polyamide fiber having a fineness of 1.5 denier and a fiber length of 47 mm (manufactured by DuPont, trade name "Kevlar (registered trademark))" and a fineness of 2 denier and a fiber length of 51 mm
In the same manner as in Example 1, a stretched polyphenylene sulfide fiber (manufactured by Toyobo Co., Ltd., trade name “Procon (registered trademark)” 2% by weight was used to form a web having a basis weight of 74 g / m 2 and a melting temperature of 290 with a heating device. The temperature of the web raised to ℃ is 300 ℃ on the surface of the thermal calendar roller, and the linear pressure is 8kg.
Thermocompression bonding was performed at a pressure of / cm to obtain a heat resistant nonwoven fabric.

【0023】実施例3 繊度1.5デニール、繊維長47mmの全芳香族ポリア
ミド繊維(デュポン社製、商品名「ケブラー(登録商
標)」)99重量%と繊度1.3デニール、繊維長38
mmの延伸ポリエステル繊維1重量%とを実施例1と同
様の方法で目付77g/m2 のウェブを形成し、加熱装
置で溶融温度265℃まで上昇させたウェブを熱カレン
ダーローラの表面温度270℃、線圧10kg/cmで
熱圧着して耐熱性不織布を得た。
Example 3 99% by weight of wholly aromatic polyamide fiber having a fineness of 1.5 denier and a fiber length of 47 mm (trade name "Kevlar (registered trademark)" manufactured by DuPont), a fineness of 1.3 denier and a fiber length of 38
mm stretched polyester fiber 1% by weight was used to form a web having a basis weight of 77 g / m 2 in the same manner as in Example 1, and the web heated to a melting temperature of 265 ° C. was heated by a heating device. Then, thermocompression bonding was performed at a linear pressure of 10 kg / cm to obtain a heat resistant nonwoven fabric.

【0024】実施例2及び3の耐熱性不織布は表1に示
す如く、耐熱絶縁ワニスの含浸性に優れ、破壊電圧も高
く、更にアレニウス式による耐熱引張強度劣化試験の結
果、国際電気技術委員会の定めるH種に適合するもの
で、耐熱性電気絶縁シートとして好適である。また、誘
電率、誘電正接、絶縁抵抗等の電気特性に優れた機能を
有し、プリント配線用基材として特に有用である。
As shown in Table 1, the heat-resistant non-woven fabrics of Examples 2 and 3 are excellent in impregnation property of heat-resistant insulating varnish, have high breakdown voltage, and have been subjected to the heat-resistant tensile strength deterioration test by the Arrhenius method. It is suitable as a heat-resistant electrical insulating sheet, as it is compatible with the H type specified by Further, it has a function excellent in electrical properties such as dielectric constant, dielectric loss tangent, and insulation resistance, and is particularly useful as a substrate for printed wiring.

【0025】比較例3 湿式法によって全芳香族ポリアミド繊維の紙状不織布を
得た。表1に示す通り電気特性は優れているが、ワニス
含浸性が著しく劣っている。
Comparative Example 3 A paper-like nonwoven fabric of wholly aromatic polyamide fiber was obtained by a wet method. As shown in Table 1, the electrical properties are excellent, but the varnish impregnation property is remarkably poor.

【0026】[0026]

【表1】 (註) 1.物性値はいずれも縦方向と横方向の平均値である。 2.厚み及び密度はJIS−8118に基づいて測定す
る。 3.強伸度試験はJIS−P−8113に基づいて測定
する。 4.熱収縮率及び重量減率は300℃の熱湯で30分間
暴露し、常温に戻した時の値である。 5.通気度はフラジール型通気度試験機を用いてJIS
−L−1096(1990A法)に従って行った。 6.ヒマシ油含浸性の測定方法は試料を18×18mm
に各4枚ずつ裁断し、ヒマシ油の温度を30±0.5℃
にする。試験片の表面又は裏面を上にして、ヒマシ油の
液面と平行に落下させる。液面に落下した時から液が完
全に浸透して沈下するまでの時間をストップウォッチで
測定し、1/10秒単位で読み取る(表面裏面各2枚の
計4枚の平均値の秒数)。 7.シリコンオイル含浸性の測定方法は試料を12.5
×200mmに裁断し、シリコンの粘度(100cs、
1,000cs、10,000cs)に試片6mm浸け
て、1時間後の吸い上げ高さ(mm)を読み取る。 8.絶縁破壊電圧、誘電率、誘電正接の試験はJIS−
C−2111に基づいて測定する。 9.絶縁抵抗(体積抵抗率)はJIS−C−6521に
基づいて測定する。
[Table 1] (Note) 1. All physical property values are average values in the vertical and horizontal directions. 2. Thickness and density are measured based on JIS-8118. 3. The strength and elongation test is measured according to JIS-P-8113. 4. The heat shrinkage rate and the weight loss rate are values when exposed to hot water of 300 ° C. for 30 minutes and returned to room temperature. 5. The air permeability is JIS using a Frazier type air permeability tester.
-L-1096 (Method 1990A). 6. The method of measuring castor oil impregnation is 18 x 18 mm.
Cut into 4 pieces each and heat the castor oil to 30 ± 0.5 ℃
To Drop the test piece with the front or back surface facing upward, parallel to the liquid surface of castor oil. Measure the time from the time it falls on the liquid surface to the time when the liquid completely penetrates and sinks, and read it in units of 1/10 seconds (the number of seconds of the average value of a total of 4 sheets, 2 on each of the front and back sides) . 7. The measuring method of silicon oil impregnation is 12.5 for the sample.
Cut into × 200mm, the viscosity of silicon (100cs,
The test piece is soaked in 6 mm in 1,000 cs and 10,000 cs, and the suction height (mm) after 1 hour is read. 8. JIS-for dielectric breakdown voltage, dielectric constant and dielectric loss tangent tests
It measures based on C-2111. 9. The insulation resistance (volume resistivity) is measured based on JIS-C-6521.

─────────────────────────────────────────────────────
─────────────────────────────────────────────────── ───

【手続補正書】[Procedure amendment]

【提出日】平成5年8月25日[Submission date] August 25, 1993

【手続補正2】[Procedure Amendment 2]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】特許請求の範囲[Name of item to be amended] Claims

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【特許請求の範囲】[Claims]

【手続補正3】[Procedure 3]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0001[Correction target item name] 0001

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【0001】[0001]

【産業上の利用分野】本発明は、全芳香族ポリアミド繊
維を主構成とし、ポリエステル及び/またはポリフェニ
レンサルファイドからなる繊維を溶融成分とする耐
織布及びその製造方法に関し、本発明により得られた不
織布は耐絶縁ワニス含浸性に優れた、プリント配線用
基材、耐熱性電気絶縁シート、耐熱性の必要なフィルタ
ー、更には耐熱性・難燃性の必要な断熱材や保温材など
広い用途に使用される。
The present invention relates to a wholly aromatic polyamide fibers as the main structure, relates polyester and / or polyphenylene Heat resistance not <br/> woven and manufacturing method thereof The fiber and molten component comprising sulfide, nonwoven fabric obtained by the present invention has excellent resistance to thermal insulating varnish impregnation, printed wiring substrate, heat-resistant electrically insulating sheet, heat resistance of the required filter, even necessary insulation heat resistance and flame retardancy It is used for a wide range of purposes such as heat insulation materials.

【手続補正4】[Procedure amendment 4]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0008[Correction target item name] 0008

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【0008】一方、ポリフェニレンサルファイド樹脂
は、特公昭52−80609号公報や特開昭58−31
112号公報などに示される繊維化技術が知られ、ポリ
フェニレンサルファイド繊維を用いた耐熱性のニードル
パンチング法による短繊維フェルトや、特開昭57−1
6954号公報のスパンボンド法による長繊維不織布な
どが知られているが、何れも機械的絡合により形成され
るものであり、熱融着による結合がないために、高温で
長時間負がかかる場合などの形態保持性が充分でな
い。熱融着結合点を付与するために不織布を熱圧着する
と全体がフィルム化し、通気性や柔軟性が大きく低下す
る。
On the other hand, polyphenylene sulfide resins are disclosed in Japanese Examined Patent Publication No. 52-80609 and Japanese Patent Laid-Open No. 58-31.
The fiberizing technique disclosed in Japanese Patent Application Laid-Open No. 112 etc. is known, and a short fiber felt by a heat-resistant needle punching method using polyphenylene sulfide fiber and JP-A-57-1 are used.
Such as long-fiber nonwoven fabric by spun bond method 6954 JP are known, both are those formed by mechanical entanglement, because there is no binding by thermal fusion, a long time load at high temperature In such cases, the shape retention is not sufficient. When the non-woven fabric is thermocompression-bonded in order to provide the heat-bonding bonding points, the whole is formed into a film, and the air permeability and the flexibility are greatly reduced.

【手続補正5】[Procedure Amendment 5]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0009[Correction target item name] 0009

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【0009】また8〜80%の高混率の未延伸ポリフェ
ニレンサルファイド繊維を融着成分として低温(183
〜257℃)かつ高線圧(30〜270kg/cm)で
プレスする方法が特開昭61−289162号公報に示
されている。この場合は非常に大きな圧力を必要とする
ので機械的制約があり、得られた不織布の通気性や柔軟
性が大きく低下して耐熱絶縁ワニスの含浸性が低下して
しまう。またフィルターの用途に用いた場合は液体や気
体の通性が悪くなる。
Further, undrawn polyphenylene sulfide fiber having a high mixing ratio of 8 to 80% is used as a fusion component at a low temperature (183
The method of pressing at a high linear pressure (30 to 270 kg / cm) at ˜257 ° C.) is disclosed in JP-A-61-289162. In this case, a very large pressure is required, so that there is a mechanical restriction, and the air permeability and flexibility of the obtained nonwoven fabric are greatly reduced, so that the impregnation property of the heat resistant insulating varnish is reduced. In the case of using the application of the filter becomes poor passing over sexual liquid or gas.

【手続補正6】[Procedure correction 6]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0012[Correction target item name] 0012

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【0012】[0012]

【発明の目的】本発明はかかる問題点を解決するために
なされたものであり、極めて低い混率のポリエステル
維及び/またはポリフェニレンサルファイド繊維を用
い、しかも低圧力でプレスすることで通気性や柔軟性を
保有する耐熱性不織布が得られることを見出したもので
ある。
SUMMARY OF THE INVENTION The present invention has been made to solve the above problems, and it is possible to use polyester fibers and / or polyphenylene sulfide fibers having an extremely low mixing ratio and by pressing at a low pressure. It has been found that a heat-resistant nonwoven fabric having breathability and flexibility can be obtained.

【手続補正7】[Procedure Amendment 7]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0013[Correction target item name] 0013

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【0013】[0013]

【課題を解決するための手段】上記の問題を解決するた
め、本発明に係る製造方法は、不織布構成繊維の交点を
点接着させることにより耐熱絶縁ワニス含浸性に優れた
耐熱性不織布を得る製造方法において、前記不織布構成
繊維は全芳香族ポリアミド繊維を主構成とし、ポリエス
テル及び/またはポリフェニレンサルファイドの繊維で
あり、且つ前記点接着は、ポリエステル及び/またはポ
リフェニレンサルファイド繊維を1重量%以上3重量
%未満で混綿してウェブを形成し、軽い加圧と遠赤外線
照射による加熱処理の後、加圧して熱接着を行うことで
形成することを特徴とする。
In order to solve the above problems, the production method according to the present invention is a method for producing a heat-resistant non-woven fabric excellent in heat-insulating varnish impregnation property by spot-bonding the intersections of the non-woven fabric constituent fibers. in the method, the nonwoven fabric constituting fibers as a main constituting the wholly aromatic polyamide fibers are fibers of polyester and / or polyphenylene sulfide, and said point bonding, polyester and / or polyphenylene sulfide fibers 3 wt 1 wt% or more of de % To form a web, which is lightly pressed and heat-treated by irradiation with far infrared rays, and then pressure-bonded for thermal bonding.

【手続補正8】[Procedure Amendment 8]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0015[Name of item to be corrected] 0015

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【0015】また、本発明に係る耐熱性不織布は、全芳
香族ポリアミド繊維を主構成とし、ポリエステル及び/
またはポリフェニレンサルファイド繊維を1重量%以
上3重量%未満で混綿してなる不織布構成繊維の交点が
点接着されていることを特徴とする。
The heat-resistant non-woven fabric according to the present invention comprises wholly aromatic polyamide fibers as a main constituent, and polyester and / or
Or polyphenylene sulfide fiber cotton mixing with the intersection of the nonwoven fabric constituent fiber comprising less than 1 wt% to 3 wt%, characterized in that it is point bonded.

【手続補正9】[Procedure Amendment 9]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0016[Correction target item name] 0016

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【0016】本発明に利用される全芳香族ポリアミド繊
維としては、ポリ−m−フェニレンイソフタルアミド繊
及びその変成品と、ポリ−p−フェニレンテレフタル
アミド繊維及びその変成品などである。また前記ローラ
搬送手段による搬送中に複数個が配置された加熱手段に
より徐々に加熱される。加熱手段の加熱方法としては遠
赤外線照射による加熱によりウェブは内外層とも均一に
加熱されるため表面が焦げることなくムラのない加熱が
できる。従来の加熱方法では表面から順に熱が伝わって
ゆくのに対して遠赤外線は空気層等の媒体に熱が吸収さ
れることなく被加熱物に直接到達し発熱する。即ち、雰
囲気温度を高めずにウェブをスポット加熱することがで
き、加熱装置を密閉する必要がない。従って加熱効率が
高いと共に温度制御が極めて容易である。
The wholly aromatic polyamide fibers used in the present invention include poly-m-phenylene isophthalamide fibers and modified products thereof, and poly-p-phenylene terephthalamide fibers and modified products thereof. Further, while being transported by the roller transporting means, a plurality of heating means are arranged to gradually heat the heating means. As a heating method of the heating means, the web is heated uniformly by the irradiation of far infrared rays, and the inner and outer layers are uniformly heated, so that the surface can be uniformly heated without burning. In the conventional heating method, heat is transmitted in sequence from the surface, whereas far infrared rays directly reach the object to be heated and generate heat without being absorbed by the medium such as the air layer. That is, the web can be spot-heated without raising the ambient temperature, and it is not necessary to seal the heating device. Therefore, the heating efficiency is high and the temperature control is extremely easy.

【手続補正10】[Procedure Amendment 10]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0017[Correction target item name] 0017

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【0017】遠赤外線照射により徐々に加熱されたウェ
ブは、その温度が接着成分として用いられた熱可塑性樹
脂の熱溶融温度、例えばポリエステルでは265℃、ポ
リフェニレンサルファイドでは290℃にまで上昇した
後、熱カレンダーローラによって加圧される。熱カレン
ダーローラによる加圧は、線圧1〜100kg/cmの
範囲で、不織布の目付が100g/m未満の場合の線
圧は1〜10kg/cm、また100〜200g/m
以下の場合の線圧は20〜50kg/cm、200g/
を越える場合の線圧は60〜100kg/cmで行
われる。該カレンダーローラの表面温度は、熱損失等を
考慮して前記熱溶融温度より僅かに高めに設定されるこ
とが好ましい。
The web gradually heated by far-infrared irradiation rises in temperature to a heat melting temperature of the thermoplastic resin used as an adhesive component, for example, 265 ° C. for polyester and 290 ° C. for polyphenylene sulfide, and then the heat is applied. It is pressed by a calendar roller. The pressure applied by the thermal calendar roller is in the range of 1 to 100 kg / cm of linear pressure. When the basis weight of the nonwoven fabric is less than 100 g / m 2 , the linear pressure is 1 to 10 kg / cm, and 100 to 200 g / m 2.
The linear pressure in the following cases is 20-50 kg / cm, 200 g /
When the pressure exceeds m 2 , the linear pressure is 60 to 100 kg / cm. The surface temperature of the calender roller is preferably set slightly higher than the heat melting temperature in consideration of heat loss and the like.

【手続補正11】[Procedure Amendment 11]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0026[Correction target item name] 0026

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【0026】[0026]

【表1】 1.物性値はいずれも縦方向と横方向の平均値である。 2.厚み及び密度はJIS−8118に基づいて測定す
る。 3.強伸度試験はJIS−P−8113に基づいて測定
する。 4.熱収縮率及び重量減率は300℃の乾熱で30分間
暴露し、常温に戻した時の値である。 5.通気度はフラジール型通気度試験機を用いてJIS
−L−1096(1990A法)に従って行った。 6.ヒマシ油含浸性の測定方法は試料を18×18mm
に各4枚ずつ裁断し、ヒマシ油の温度を30±0.5℃
にする。試験片の表面又は裏面を上にして、ヒマシ油の
液面と平行に落下させる。液面に落下した時から液が完
全に浸透して沈下するまでの時間をストップウォッチで
測定し、1/10秒単位で読み取る(表面裏面各2枚の
計4枚の平均値の秒数)。 7.シリコンオイル含浸性の測定方法は試料を12.5
×200mmに裁断し、シリコンの粘度100cs、
1,000cs、10,000cs)に試片6mm浸け
て、1時間後の吸い上げ高さ(mm)を読み取る。 8.絶縁破壊電圧、誘電率、誘電正接の試験はJIS−
C−2111に基づいて測定する。 9.絶縁抵抗(体積抵抗率)はJIS−C−6521に
基づいて測定する。 ─────────────────────────────────────────────────────
[Table 1] 1. All physical property values are average values in the vertical and horizontal directions. 2. Thickness and density are measured based on JIS-8118. 3. The strength and elongation test is measured according to JIS-P-8113. 4. The heat shrinkage rate and the weight loss rate are values when exposed to dry heat of 300 ° C. for 30 minutes and returned to room temperature. 5. The air permeability is JIS using a Frazier type air permeability tester.
-L-1096 (Method 1990A). 6. The method of measuring castor oil impregnation is 18 x 18 mm.
Cut into 4 pieces each and heat the castor oil to 30 ± 0.5 ℃
To Drop the test piece with the front or back surface facing upward, parallel to the liquid surface of castor oil. Measure the time from the time it falls on the liquid surface to the time when the liquid completely permeates and sinks, and read it in units of 1/10 seconds (the number of seconds of the average value of a total of 4 sheets on each of the front and back sides) . 7. The measuring method of silicon oil impregnation is 12.5 for the sample.
Cut into 200 mm, the viscosity of silicon is 100 cs,
The test piece is soaked in 6 mm in 1,000 cs and 10,000 cs, and the suction height (mm) after 1 hour is read. 8. JIS-for dielectric breakdown voltage, dielectric constant and dielectric loss tangent tests
It measures based on C-2111. 9. The insulation resistance (volume resistivity) is measured based on JIS-C-6521. ─────────────────────────────────────────────────── ───

【手続補正書】[Procedure amendment]

【提出日】平成6年1月10日[Submission date] January 10, 1994

【手続補正1】[Procedure Amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0024[Name of item to be corrected] 0024

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【0024】実施例2及び3の耐熱性不織布は表1に示
す如く、耐熱絶縁ワニスの含浸性に優れ、破壊電圧も高
く、またアレニウス式による耐熱引張強度劣化試験にお
いて、国際電気技術委員会の定めるH種に適合するもの
と思われる。従って、耐熱性電気絶縁シートとして好適
である。また、誘電率、誘電正接、絶縁抵抗等の電気特
性に優れた機能を有し、プリント配線用基材として特に
有用である。
As shown in Table 1, the heat-resistant non-woven fabrics of Examples 2 and 3 are excellent in impregnation with a heat-resistant insulating varnish, have a high breakdown voltage, and have been subjected to the Arrhenius type heat-resistant tensile strength deterioration test.
And conforms to the H-class specified by the International Electrotechnical Commission
I think that the. Therefore, it is suitable as a heat resistant electrical insulating sheet. Further, it has a function excellent in electrical properties such as dielectric constant, dielectric loss tangent, and insulation resistance, and is particularly useful as a substrate for printed wiring.

【手続補正2】[Procedure Amendment 2]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0026[Correction target item name] 0026

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【0026】[0026]

【表1】 (注) 1.物性値はいずれも縦方向と横方向の平均値である。 2.厚み及び密度はJIS−8118に基づいて測定す
る。 3.強伸度試験はJIS−P−8113に基づいて測定
する。 4.熱収縮率及び重量減率は300℃の乾熱で30分間
暴露し、常温に戻した時の値である。 5.通気度はフラジール型通気度試験機を用いてJIS
−L−1096(1990A法)に従って行った。 6.ヒマシ油含浸性の測定方法は試料を18×18mm
に各4枚ずつ裁断し、ヒマシ油の温度を30±0.5℃
にする。試験片の表面又は裏面を上にして、ヒマシ油の
液面と平行に落下させる。液面に落下した時から液が完
全に浸透して沈下するまでの時間をストップウォッチで
測定し、1/10秒単位で読み取る(表面裏面各2枚の
計4枚の平均値の秒数)。 7.シリコンオイル含浸性の測定方法は試料を12.5
×200mmに裁断し、シリコンの粘度(100cs、
1,000cs、10,000cs)に試片6mm浸け
て、1時間後の吸い上げ高さ(mm)を読み取る。 8.絶縁破壊電圧、誘電率、誘電正接の試験はJIS−
C−2111に基づいて測定する。 9.絶縁抵抗(体積抵抗率)はJIS−C−6521に
基づいて測定する。
[Table 1] (Note) 1. All physical property values are average values in the vertical and horizontal directions. 2. Thickness and density are measured based on JIS-8118. 3. The strength and elongation test is measured according to JIS-P-8113. 4. The heat shrinkage rate and the weight loss rate are values when exposed to dry heat of 300 ° C. for 30 minutes and returned to room temperature. 5. The air permeability is JIS using a Frazier type air permeability tester.
-L-1096 (Method 1990A). 6. The method of measuring castor oil impregnation is 18 x 18 mm.
Cut into 4 pieces each and heat the castor oil to 30 ± 0.5 ℃
To Drop the test piece with the front or back surface facing upward, parallel to the liquid surface of castor oil. Measure the time from the time it falls on the liquid surface to the time when the liquid completely penetrates and sinks, and read it in units of 1/10 seconds (the number of seconds of the average value of a total of 4 sheets, 2 on each of the front and back sides) . 7. The measuring method of silicon oil impregnation is 12.5 for the sample.
Cut into × 200mm, the viscosity of silicon (100cs,
The test piece is soaked in 6 mm in 1,000 cs and 10,000 cs, and the suction height (mm) after 1 hour is read. 8. JIS-for dielectric breakdown voltage, dielectric constant and dielectric loss tangent tests
It measures based on C-2111. 9. The insulation resistance (volume resistivity) is measured based on JIS-C-6521.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】不織布構成繊維の交点を点接着させること
により耐熱絶縁ワニス含浸性に優れた耐熱性不織布を得
る製造方法において、前記不織布構成繊維は全芳香族ポ
リアミド繊維を主構成とし、ポリエステル及び/または
ポリフェニレンサルファイドの繊維であり、且つ前記点
接着は、ポリエステル及び/またはポリフェニレンサル
ファイド繊維を1重量%以上3重量%未満で混綿してウ
ェブを形成し、軽い加圧と遠赤外線照射による加熱処理
の後、加圧して熱接着を行うことで形成することを特徴
とする耐熱性不織布の製造方法。
1. A method for producing a heat-resistant non-woven fabric excellent in impregnation with a heat-resistant insulating varnish by spot-bonding intersection points of non-woven fabric constituting fibers, wherein the non-woven fabric-constituting fibers mainly consist of wholly aromatic polyamide fibers, and polyester and And / or polyphenylene sulfide fibers, and the point bonding is a heat treatment by light pressure and far infrared irradiation by blending polyester and / or polyphenylene sulfide fibers in an amount of 1% by weight or more and less than 3% by weight. After that, the heat-resistant nonwoven fabric is formed by applying pressure and heat-bonding.
【請求項2】前記不織布の熱接着は軽い加圧を行うロー
ラ搬送手段による搬送中に遠赤外線照射により徐々に加
熱し、前記ウェブの温度が熱可塑性樹脂の熱溶融温度に
まで上昇した後、線圧1〜100kg/cmで加圧する
ことを特徴とする請求項1記載の耐熱性不織布の製造方
法。
2. The thermal bonding of the non-woven fabric is gradually heated by far-infrared irradiation during transportation by a roller transporting means for applying light pressure, and after the temperature of the web is raised to the heat melting temperature of the thermoplastic resin, The method for producing a heat-resistant nonwoven fabric according to claim 1, wherein the pressure is applied at a linear pressure of 1 to 100 kg / cm.
【請求項3】前記軽い加圧が、線圧0.2〜0.8kg
/cmであることを特徴とする請求項1または2記載の
耐熱性不織布の製造方法。
3. The light pressure is a linear pressure of 0.2 to 0.8 kg.
It is / cm, The manufacturing method of the heat resistant nonwoven fabric of Claim 1 or 2 characterized by the above-mentioned.
【請求項4】全芳香族ポリアミド繊維を主構成とし、ポ
リエステル及び/またはポリフェニレンサルファイド繊
維を1重量%以上3重量%未満で混綿してなる不織布構
成繊維の交点が点接着されていることを特徴とする耐熱
性不織布。
4. A non-woven fabric comprising, as main constituent, wholly aromatic polyamide fibers and containing polyester and / or polyphenylene sulfide fibers in an amount of 1% by weight or more and less than 3% by weight, and the point of intersection of the fibers constituting the nonwoven fabric is point-bonded. Heat resistant non-woven fabric.
JP5195135A 1993-07-12 1993-07-12 Heat-resistant nonwoven fabric and method for producing the same Expired - Lifetime JP2602166B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5195135A JP2602166B2 (en) 1993-07-12 1993-07-12 Heat-resistant nonwoven fabric and method for producing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5195135A JP2602166B2 (en) 1993-07-12 1993-07-12 Heat-resistant nonwoven fabric and method for producing the same

Publications (2)

Publication Number Publication Date
JPH0790762A true JPH0790762A (en) 1995-04-04
JP2602166B2 JP2602166B2 (en) 1997-04-23

Family

ID=16336053

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP2602166B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2853903A1 (en) * 2003-04-16 2004-10-22 Saint Gobain Isover A sizing composition for the manufacture of mineral fiber thermal and/or acoustic insulation products comprises a carboxylic polyacid with 2-500 groups reactive with an amine and a polyamine with 2-200 amine groups
US8021592B2 (en) 2001-11-27 2011-09-20 Propex Operating Company Llc Process for fabricating polypropylene sheet
US8052913B2 (en) 2003-05-22 2011-11-08 Propex Operating Company Llc Process for fabricating polymeric articles
CN103668778A (en) * 2013-12-10 2014-03-26 吴江市品信纺织科技有限公司 Anti-radiation non-woven fabric

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0368408A (en) * 1989-08-04 1991-03-25 Kureha Tec Kk Method for surfacing nonwoven fabric for filter cloth

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0368408A (en) * 1989-08-04 1991-03-25 Kureha Tec Kk Method for surfacing nonwoven fabric for filter cloth

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8021592B2 (en) 2001-11-27 2011-09-20 Propex Operating Company Llc Process for fabricating polypropylene sheet
FR2853903A1 (en) * 2003-04-16 2004-10-22 Saint Gobain Isover A sizing composition for the manufacture of mineral fiber thermal and/or acoustic insulation products comprises a carboxylic polyacid with 2-500 groups reactive with an amine and a polyamine with 2-200 amine groups
US8052913B2 (en) 2003-05-22 2011-11-08 Propex Operating Company Llc Process for fabricating polymeric articles
US8268439B2 (en) 2003-05-22 2012-09-18 Propex Operating Company, Llc Process for fabricating polymeric articles
US8871333B2 (en) 2003-05-22 2014-10-28 Ian MacMillan Ward Interlayer hot compaction
US9403341B2 (en) 2003-05-22 2016-08-02 Propex Operating Company Llc Interlayer hot compaction
US10850479B2 (en) 2003-05-22 2020-12-01 Canco Hungary Investment Ltd. Process for fabricating polymeric articles
CN103668778A (en) * 2013-12-10 2014-03-26 吴江市品信纺织科技有限公司 Anti-radiation non-woven fabric

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