JPH0782559A - Slurrying material for earth pressure balanced shield driving method and earth pressure balanced driving method - Google Patents

Slurrying material for earth pressure balanced shield driving method and earth pressure balanced driving method

Info

Publication number
JPH0782559A
JPH0782559A JP25493393A JP25493393A JPH0782559A JP H0782559 A JPH0782559 A JP H0782559A JP 25493393 A JP25493393 A JP 25493393A JP 25493393 A JP25493393 A JP 25493393A JP H0782559 A JPH0782559 A JP H0782559A
Authority
JP
Japan
Prior art keywords
water
earth pressure
clay
driving method
pressure balanced
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP25493393A
Other languages
Japanese (ja)
Inventor
Atsushi Maeda
淳 前田
Kazuo Ito
一男 伊藤
Takashi Kamata
高志 鎌田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MATSUMURA SEKIYU KASEI KK
SHIMAZU MEKANITSUKUSU KK
Original Assignee
MATSUMURA SEKIYU KASEI KK
SHIMAZU MEKANITSUKUSU KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MATSUMURA SEKIYU KASEI KK, SHIMAZU MEKANITSUKUSU KK filed Critical MATSUMURA SEKIYU KASEI KK
Priority to JP25493393A priority Critical patent/JPH0782559A/en
Publication of JPH0782559A publication Critical patent/JPH0782559A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To obtain a slurring material improved in water retention, lubricating properties and flow by mixing water with a specified water-soluble organic polymeric compound and clay. CONSTITUTION:The material is prepared by mixing water with 1-80vol.% at least one water-soluble organic polymeric compound selected from among polysodium acrylate, polyacrylamide, carboxymethylcellulose, sodium carboxylmethyl cellulose, sodium alginate, PVA, starch, etc., and 100vol.% clay.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、トンネル掘進における
土圧系シールド工法や土圧系推進工法に使用する加泥材
に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a mud material used for earth pressure system shield construction method and earth pressure system propulsion construction method in tunnel excavation.

【0002】[0002]

【従来の技術】密閉型機械式掘削において、切羽面に加
泥材を注入、加圧して切羽の安定性を確保するととも
に、掘削土砂に加泥材を練り混ぜることによりその搬送
性を良くすることが行われている。従来の加泥材として
は、水とベントナイト等の粘土を主要構成材とする粘稠
性懸濁液が使用されている。しかし、この加泥材は、微
粒子タイプの高濃度加泥材であるので、砂礫部掘削にお
いては設備が大型化し、さらに、経時的に増粘するため
ポンプ圧送において圧力損失が大きくなったり、セメン
ト、塩分の混入による凝集現象から土砂の分離、土圧低
下、スクリューからの噴発等が発生する欠点があった。
2. Description of the Related Art In closed-type mechanical excavation, mud material is injected into the face of a face to pressurize the face to ensure stability of the face and to improve its transportability by mixing the mud material with the excavated soil. Is being done. A viscous suspension containing water and clay such as bentonite as main constituents is used as a conventional mud additive. However, since this mud material is a fine particle type high-concentration mud material, the equipment becomes large in the excavation of sand and gravel, and since it thickens with time, the pressure loss in pumping becomes large, and the cement However, there are drawbacks such as separation of earth and sand, reduction of earth pressure, and spouting from a screw due to the agglomeration phenomenon due to the inclusion of salt.

【0003】この他の加泥材として、典型的な繊維状物
質としての無機繊維、パルプ繊維等を使用したものもあ
った。しかし、これは繊維が大きいために多量に配合す
ることが不可能であるため、十分な保水性、潤滑性が得
られず、また容易に水と分離し、加泥材単独での保水性
が悪い問題があった。
Other mud-adding materials include those using inorganic fibers and pulp fibers as typical fibrous substances. However, since it is impossible to mix it in a large amount due to the large size of the fiber, sufficient water retention and lubricity cannot be obtained, and it easily separates from water and the water retention of the mud additive alone is I had a bad problem.

【0004】近年、水膨潤性高分子物質に水を配合した
加泥材が開発されているが、砂礫部掘削において加圧に
より散逸し、粘度が低下したり、掘削土砂混合後に脱水
する欠点があり、加泥材として満足すべきものではな
い。さらに、これらの欠点を解決するために、水と高分
子ポリマー系珪酸塩とを配合した土圧系シールド工法用
加泥材が提案されている(特開平4−202998号参
照)。しかし、これによると、水を加えて調整する際に
継粉状になったり、1〜数日の間に粘度が低下したり、
掘削土との混合物が脱水する等の問題点のあることが指
摘されている。
[0004] In recent years, mud-adding materials in which water is mixed with a water-swelling polymeric substance have been developed. However, there are drawbacks in that they are dissipated by pressurization during excavation of sand and gravel, the viscosity is lowered, and dehydration is carried out after mixing excavated soil. Yes, it is not satisfactory as a mud material. Furthermore, in order to solve these drawbacks, a mud material for an earth pressure type shield construction method in which water and a high molecular polymer silicate are mixed has been proposed (see JP-A-4-202998). However, according to this, when adjusting by adding water, it becomes a powdery powder, the viscosity decreases in 1 to several days,
It has been pointed out that there are problems such as dehydration of the mixture with excavated soil.

【0005】[0005]

【発明が解決しようとする課題】上述したようなことか
ら、この種の加泥材には、より優れた保水性、潤滑性を
有し、機能低下のないものが要求されている。本発明
は、掘削土砂との混合状態で、保水性、潤滑性若しくは
流動性に優れ、機能低下のない加泥材を提供することを
目的とする。
From the above, there is a demand for this type of mud material that has more excellent water retention and lubricity and does not deteriorate in function. An object of the present invention is to provide a mud material which is excellent in water retention, lubricity or fluidity in a state of being mixed with excavated earth and sand and has no functional deterioration.

【0006】[0006]

【課題を解決するための手段】本発明の手段は、水に、
ポリアクリル酸ソーダ、ポリアクリルアミド、カルボキ
シメチルセルロース、カルボキシメチルセルロースソー
ダ塩、アルギン酸ソーダ、ポリビニルアルコール、澱粉
等の水溶性有機高分子化合物群の中の一種又は二種以上
と、粘土とを混入してなるものである。前記粘土は、特
に限定されるものではないが、モンモリロナイトをより
多く含有するものがよい。例えば、ベントナイト、クレ
ー、カオリン、木節粘土、ガイメロ粘土等のいずれでも
よいが、ベントナイトがより好ましい。水溶性有機高分
子化合物の添加量は、水溶性有機高分子化合物の種類や
粘土の種類によって異なり、特に限定しないが、体積比
で粘土100に対して1〜80程度である。
Means for Solving the Problem
A mixture of one or more water-soluble organic polymer compounds such as sodium polyacrylate, polyacrylamide, carboxymethyl cellulose, sodium carboxymethyl cellulose salt, sodium alginate, polyvinyl alcohol, starch, and clay. Is. The clay is not particularly limited, but it is preferable that the clay contains more montmorillonite. For example, any of bentonite, clay, kaolin, kibushi clay, geimelo clay and the like may be used, but bentonite is more preferable. The amount of the water-soluble organic polymer compound added varies depending on the type of the water-soluble organic polymer compound and the type of clay and is not particularly limited, but is about 1 to 80 with respect to 100 of the clay in volume ratio.

【0007】[0007]

【作用】水に前記水溶性有機高分子化合物及び粘土を混
入したときは、継粉になることなく、短時間で溶解膨潤
して粘性のある加泥材となる。前記水溶性有機高分子化
合物は、増粘剤、場合によっては保水剤として作用する
ものである。粘土は、岩石の風化作用により化学変化を
受けて生成した含水珪酸塩鉱物の集合体である。化学成
分は主として珪素、アルミニウム、鉄、マグネシウム、
アルカリ金属、アルカリ土類金属及び水である。粘土は
直径2μm 以下の微粒子(コロイド粒子)の集合体から
なっているから、粘着性、可塑性、吸着性、膨潤性、イ
オン交換性等の顕著なコロイド性を示す。本発明ではこ
のコロイド性を利用したものである。粘土の中でもベン
トナイトは、SiO2 、Al2 3 を主成分として、層
状の分子構造が著しく発達し、高いコロイド性を有する
モンモリロナイトの含有率が高い組成になっている。ま
た、粘土鉱物のなかでも特に大きい膨潤性を有する点に
特徴がある。このモンモリロナイトは、本発明の加泥材
の機能を向上させるために有効な成分である。
When the water-soluble organic polymer compound and clay are mixed in water, it does not become powdered and swells in a short time to form a viscous mud material. The water-soluble organic polymer compound acts as a thickener and, in some cases, a water retention agent. Clay is an aggregate of hydrated silicate minerals formed by chemical changes due to weathering of rocks. The chemical components are mainly silicon, aluminum, iron, magnesium,
Alkali metals, alkaline earth metals and water. Since clay is composed of an aggregate of fine particles (colloidal particles) having a diameter of 2 μm or less, it exhibits remarkable colloidal properties such as adhesiveness, plasticity, adsorptivity, swelling property and ion exchange property. The present invention utilizes this colloidal property. Among clays, bentonite is composed of SiO 2 and Al 2 O 3 as main components, has a layered molecular structure remarkably developed, and has a high content of montmorillonite having high colloidal properties. It is also characterized by having a particularly large swelling property among clay minerals. This montmorillonite is an effective component for improving the function of the mud additive of the present invention.

【0008】本発明の加泥材は、溶解膨潤した前記水溶
性有機高分子化合物と粘土でミクロな繊維状物質を形成
している。この繊維状物質は、水溶性有機高分子化合物
と粘土を水に溶解膨潤させた時に凝集反応により生成し
たもので、通常数ミクロンから数ミリの長さである。こ
の繊維状物質が有効に作用する。この加泥材を土圧系シ
ールド工法あるいは土圧系推進工法に使用したときは、
加泥材と掘削土が混合して泥土となり、掘削土の土粒子
間に繊維状物質が混ざり込んでいるものとなる。この泥
土は、ジャッキの推力により圧力を受けて地山に加圧接
触しても地山側へ加泥材が移行することはない。これは
加泥材が地山表面に到達したとき、その初期において地
山表面で繊維状物質と水が分離して水のみが僅かに地山
側へ移行して繊維状物質が地山表面に残り、繊維状物質
が地山表面に不透水性の膜を形成するからである。この
ため、加泥材が水分を殆ど含まない砂層、礫層等の地山
に注入された場合には、加泥材が地山に吸収されること
を防止するように作用し、加泥材が含水比の高い土砂層
や地下水が流れている土砂層等の地山に注入された場合
には、加泥材が希釈されてその機能が低下することを防
止するように作用する。従って、これ以後は、その不透
水性の膜により加泥材も水も地山側へ移行することはな
く、また地山側の自由水が掘削土側へ移行することもな
く、地山は安定し、切羽の安定をもたらす。
The mud additive of the present invention forms a microfibrous substance by the dissolved and swollen water-soluble organic polymer compound and clay. This fibrous substance is produced by a coagulation reaction when a water-soluble organic polymer compound and clay are dissolved and swollen in water, and usually has a length of several microns to several millimeters. This fibrous substance works effectively. When using this mud material for earth pressure system shield method or earth pressure system propulsion method,
The mud material and excavated soil are mixed to form mud, and the fibrous material is mixed between the soil particles of the excavated soil. Even if the mud receives pressure from the thrust of the jack and comes into pressure contact with the ground, the mud material does not move to the ground side. This is because when the mud material reaches the rock surface, the fibrous material and water are separated on the rock surface in the initial stage, only water slightly moves to the rock surface side, and the fibrous material remains on the rock surface. This is because the fibrous substance forms an impermeable film on the ground surface. For this reason, when the mud material is injected into the ground such as a sand layer or a gravel layer that contains almost no water, it acts to prevent the mud material from being absorbed by the ground, When is injected into the ground such as a sediment layer having a high water content ratio or a sediment layer in which groundwater flows, it acts to prevent the mud material from being diluted and its function lowering. Therefore, after that, neither the mud material nor the water migrated to the ground side due to the impermeable membrane, and the free water on the ground side did not migrate to the excavated soil side, and the ground became stable. , Brings stability of the face.

【0009】また、この加泥材を混合した掘削土は、土
粒子間の粘着力が低減され、僅かな外力によって土粒子
間の結合が破壊されて変形し、さらに外力が加わると連
続的に変形するようになる。つまり、掘削土の塑性流動
性が増大するのである。そして、前記繊維状物質は保水
性が大きいことから、泥土からの脱水もなく、前記組成
流動性が持続し、チャンバー内の閉塞がなく、カッター
やスクリューコンベアーのトルクが軽減され、排泥管内
の摩擦抵抗も軽減される。本発明の加泥材は、土質に応
じて水と他の成分との混合割合を適当に変化させて使用
する。例えば、砂の多い土質であれば粘土を多く含むよ
うに、また、粘土を含む土質では粘土を少なくすること
ができる。
In addition, in the excavated soil mixed with the mud additive, the adhesive force between the soil particles is reduced, the bond between the soil particles is broken and deformed by a slight external force, and when an external force is further applied, the soil excels continuously. It will become deformed. In other words, the plasticity of excavated soil increases. And, since the fibrous substance has a large water retention, there is no dehydration from mud, the composition fluidity is maintained, there is no blockage in the chamber, the torque of the cutter or the screw conveyor is reduced, and the inside of the mud pipe Friction resistance is also reduced. The mud material of the present invention is used by appropriately changing the mixing ratio of water and other components depending on the soil quality. For example, soil with a lot of sand can contain a large amount of clay, and soil with a clay can contain a small amount of clay.

【0010】[0010]

【実施例】この発明の一実施例を次に説明する。水溶性
有機高分子化合物として、ポリアクリル酸ソーダ3Kg、
カルボキシメチルセルロースソーダ塩3Kgと、粘土14
Kgとを、1,000リットルの水に混合し、よく攪拌し
て分散せしめると、約10分後に粘度が3,000cps
の粘性のある加泥材が得られる。この実施例と比較のた
めに、比較例として前記実施例の配合から水溶性有機高
分子化合物を除き、粘土を100Kgに増加させた加泥材
を作った。その粘度は3,000cps であった。この両
者について、保水性と、潤滑性との比較テストを行った
内容及び結果を以下に示す。
An embodiment of the present invention will be described below. As a water-soluble organic polymer compound, sodium polyacrylate 3 kg,
Carboxymethyl cellulose soda salt 3Kg and clay 14
Kg and 1,000 liters of water are mixed and stirred well to disperse. After about 10 minutes, the viscosity becomes 3,000 cps.
A viscous mud material can be obtained. For comparison with this example, as a comparative example, a water-soluble organic polymer compound was removed from the formulation of the above-mentioned example, and a mud material was prepared in which clay was increased to 100 kg. Its viscosity was 3,000 cps. The contents and results of a comparative test of water retention and lubricity for both of these are shown below.

【0011】保水性テストには、図1(a)に示すよう
に、内径76mm、長さ150mmのステンレス製の円筒圧
力容器1を用いた。容器1は、底部が排水口8付きの着
脱可能な底板2、底板2で周辺部を固定された60メッ
シュの金網3、金網3の上側に配置されて金網3ととも
に固定された濾紙4で形成され、上部が圧縮空気供給口
5を有し、圧力計6を設けられた蓋7で気密に閉じられ
るようになっている。保水性テストは、容器1に夫々実
施例の加泥材と比較例の加泥材等量を別々に収容し、3
kg/cm2の空気圧を作用させて、始めから30分迄の間に
排水口8から流出する濾過水の量を測定した。その結果
を表2に示す。この結果から、実施例では繊維状物質が
濾紙の目をふさいで水の流出を阻止する作用に大きく貢
献していて保水性の優れていることがることが分かる。
For the water retention test, as shown in FIG. 1 (a), a stainless steel cylindrical pressure vessel 1 having an inner diameter of 76 mm and a length of 150 mm was used. The container 1 is formed of a removable bottom plate 2 having a drainage port 8 at the bottom, a 60-mesh wire net 3 whose peripheral portion is fixed by the bottom plate 2, and a filter paper 4 arranged above the wire net 3 and fixed together with the wire net 3. The upper part has a compressed air supply port 5 and is closed airtight by a lid 7 provided with a pressure gauge 6. In the water retention test, the container 1 was separately stored with the same amount of the added mud material of the example and the comparative example, and 3
The air pressure of kg / cm 2 was applied to measure the amount of filtered water flowing out from the drainage port 8 during the first 30 minutes. The results are shown in Table 2. From these results, it can be seen that in the examples, the fibrous substance greatly contributes to the action of blocking the outflow of water by closing the eyes of the filter paper, and that the water retention is excellent.

【0012】潤滑性テストには、図1(b)に示すよう
に、前記容器1の底部を交換した容器1aを使用した。
容器1aの底部は、回転軸9が貫通しておりその軸の内
側端に回転体10を設け、外部にトルク検出器11を有
する回転駆動部12を設けた構成である。潤滑性テスト
は、物性を表1に示すテスト用土砂に、実施例の加泥材
と比較例の加泥材を別々に容積比で20%を混合したも
のを準備して、容器1aに別々に等量を収容し、1kg/c
m2の空気圧を作用させてトルクを測定した。その結果を
表2に示す。この結果から、実施例では比較例よりも潤
滑性の優れていることが分かる。
For the lubricity test, as shown in FIG. 1 (b), a container 1a in which the bottom of the container 1 was replaced was used.
The bottom of the container 1a has a structure in which a rotary shaft 9 penetrates, a rotary body 10 is provided at the inner end of the rotary shaft 9, and a rotary drive unit 12 having a torque detector 11 is provided outside. The lubricity test was carried out by preparing a mixture of the test mud of which physical properties are shown in Table 1 and mixing the mud additive of the example and the mud additive of the comparative example in an amount of 20% by volume and separately in the container 1a. 1kg / c
The torque was measured by applying air pressure of m 2 . The results are shown in Table 2. From this result, it is understood that the example has better lubricity than the comparative example.

【0013】[0013]

【表1】 [Table 1]

【0014】[0014]

【表2】 [Table 2]

【0015】[0015]

【発明の効果】本発明の加泥材は、土圧系シールド工法
及び土圧系推進工法に使用したとき、従来の加泥材に比
べて保水性、流動性若しくは潤滑性に優れているため、
加泥材が掘削土砂と混合されると、切羽面を境に掘削土
側と地山の間の止水性を保持するから、切羽の安定を確
保でき、更に掘削土砂の流動性がよくなり、掘削土砂の
粘着力が低減するから、掘削土砂を容易に排出できると
いう効果を奏する。また、掘削土砂を容易に排出できる
ことから、掘削土砂を排出する装置の駆動部を小型化で
き、エネルギー消費も少なくなる効果を奏する。
The mud additive of the present invention is superior to the conventional mud additive in water retention, fluidity or lubricity when used in the earth pressure shield method and the earth pressure propulsion method. ,
When the mud material is mixed with the excavated earth and sand, it maintains the water stop between the excavated soil side and the ground with the cutting face as a boundary, so that the stability of the cutting face can be secured and the fluidity of the excavated sand and sand is improved, Since the adhesive force of the excavated earth and sand is reduced, the excavated earth and sand can be easily discharged. Further, since the excavated earth and sand can be easily discharged, the drive unit of the device for discharging the excavated earth and sand can be downsized, and energy consumption can be reduced.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の実施例と従来例の比較テストに使用し
た装置の概略の構造を示し、(a)は潤滑性テスト装置
の縦断面図、(b)は潤滑性テスト装置の縦断面図であ
る。
FIG. 1 shows a schematic structure of an apparatus used for a comparative test of an example of the present invention and a conventional example, (a) is a longitudinal sectional view of a lubricity test apparatus, and (b) is a longitudinal section of a lubricity test apparatus. It is a figure.

【符号の説明】[Explanation of symbols]

1 容器 1a 容器 3 金網 4 濾紙 8 排水口 10 回転体 11 トルク検出器 1 Container 1a Container 3 Wire Mesh 4 Filter Paper 8 Drainage Port 10 Rotating Body 11 Torque Detector

───────────────────────────────────────────────────── フロントページの続き (71)出願人 593189140 鎌田 高志 愛知県海部郡弥富町大字西中地字五右60− 30 (72)発明者 前田 淳 兵庫県神戸市西区高塚台2丁目1番4号 松村石油化成株式会社内 (72)発明者 伊藤 一男 愛知県海部郡弥富町大字五之三字川平269 の5 (72)発明者 鎌田 高志 愛知県海部郡弥富町大字西中地字五右60− 30 ─────────────────────────────────────────────────── ─── Continuation of front page (71) Applicant 593189140 Takashi Kamada 60-30, Nishinakaji, Yatomi-cho, Kaifu-gun, Aichi Prefecture 60-30 (72) Inventor Atsushi Maeda 2-4 Takazukadai, Nishi-ku, Kobe-shi, Hyogo Prefecture No. Matsumura Sekiyu Kasei Co., Ltd. (72) Inventor Kazuo Ito Gonosan, Yatomi-cho, Aichi Prefecture, Goto-san, 5 letters 269 5 (72) Inventor Takashi Kamada Yatomi-cho, Kaifu-gun, Aichi Pref. Nishinakaji Gogo 60 − 30

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 水に、ポリアクリル酸ソーダ、ポリアク
リルアミド、カルボキシメチルセルロース、カルボキシ
メチルセルロースソーダ塩、アルギン酸ソーダ、ポリビ
ニルアルコール、澱粉等の水溶性有機高分子化合物群の
中の一種又は二種以上と、粘土とを混入してなる土圧系
シールド工法及び土圧系推進工法用加泥材。
1. In water, one or more selected from the group of water-soluble organic polymer compounds such as sodium polyacrylate, polyacrylamide, carboxymethylcellulose, sodium carboxymethylcellulose, sodium alginate, polyvinyl alcohol, and starch, Earth pressure system shield method and clay additive mixed with clay for earth pressure system propulsion method.
JP25493393A 1993-09-16 1993-09-16 Slurrying material for earth pressure balanced shield driving method and earth pressure balanced driving method Pending JPH0782559A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP25493393A JPH0782559A (en) 1993-09-16 1993-09-16 Slurrying material for earth pressure balanced shield driving method and earth pressure balanced driving method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP25493393A JPH0782559A (en) 1993-09-16 1993-09-16 Slurrying material for earth pressure balanced shield driving method and earth pressure balanced driving method

Publications (1)

Publication Number Publication Date
JPH0782559A true JPH0782559A (en) 1995-03-28

Family

ID=17271879

Family Applications (1)

Application Number Title Priority Date Filing Date
JP25493393A Pending JPH0782559A (en) 1993-09-16 1993-09-16 Slurrying material for earth pressure balanced shield driving method and earth pressure balanced driving method

Country Status (1)

Country Link
JP (1) JPH0782559A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007084651A (en) * 2005-09-21 2007-04-05 Daicel Chem Ind Ltd Additive for rot-prevented mud pressurizing shield method
CN103074070A (en) * 2013-01-28 2013-05-01 中国地质大学(北京) Earth pressure balance shield slurry conditioner and preparation method thereof
CN103897704A (en) * 2014-04-16 2014-07-02 郑州帝益生态农业科技工程有限责任公司 Water-retention soil-loosening soil conditioning agent and preparation method
JP2015093977A (en) * 2013-11-14 2015-05-18 栗田工業株式会社 Method of forming friction-reducing coat, formation agent and method of treating water-containing particle/muddy matter
CN108048106A (en) * 2017-12-15 2018-05-18 苏州纳贝通环境科技有限公司 One kind efficiently goes saline and alkaline retaining soil moisture modifying agent and preparation method and application
CN108164184A (en) * 2018-02-08 2018-06-15 苏州中材建设有限公司 Environment-friendly type high-moisture viscosity soil consolidator and its application method
CN109054842A (en) * 2018-08-01 2018-12-21 中铁四局集团有限公司 A kind of earth pressure balanced shield, EPBS sediment improvement foaming agent and preparation method thereof
CN109762534A (en) * 2019-01-30 2019-05-17 中国地质大学(武汉) One kind being suitable for large diameter tunneling shield mud system and preparation method
CN113105897A (en) * 2021-04-02 2021-07-13 中电建铁路建设投资集团有限公司 Universal muck modifier for earth pressure balance shield and muck modification method

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007084651A (en) * 2005-09-21 2007-04-05 Daicel Chem Ind Ltd Additive for rot-prevented mud pressurizing shield method
CN103074070A (en) * 2013-01-28 2013-05-01 中国地质大学(北京) Earth pressure balance shield slurry conditioner and preparation method thereof
JP2015093977A (en) * 2013-11-14 2015-05-18 栗田工業株式会社 Method of forming friction-reducing coat, formation agent and method of treating water-containing particle/muddy matter
CN103897704A (en) * 2014-04-16 2014-07-02 郑州帝益生态农业科技工程有限责任公司 Water-retention soil-loosening soil conditioning agent and preparation method
CN108048106A (en) * 2017-12-15 2018-05-18 苏州纳贝通环境科技有限公司 One kind efficiently goes saline and alkaline retaining soil moisture modifying agent and preparation method and application
CN108164184A (en) * 2018-02-08 2018-06-15 苏州中材建设有限公司 Environment-friendly type high-moisture viscosity soil consolidator and its application method
CN108164184B (en) * 2018-02-08 2020-09-04 苏州中材建设有限公司 Environment-friendly high-water-content clay curing agent and use method thereof
CN109054842A (en) * 2018-08-01 2018-12-21 中铁四局集团有限公司 A kind of earth pressure balanced shield, EPBS sediment improvement foaming agent and preparation method thereof
CN109762534A (en) * 2019-01-30 2019-05-17 中国地质大学(武汉) One kind being suitable for large diameter tunneling shield mud system and preparation method
CN113105897A (en) * 2021-04-02 2021-07-13 中电建铁路建设投资集团有限公司 Universal muck modifier for earth pressure balance shield and muck modification method

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