JPH0733905A - Composition for balancing weight of instrument pointer - Google Patents

Composition for balancing weight of instrument pointer

Info

Publication number
JPH0733905A
JPH0733905A JP18275093A JP18275093A JPH0733905A JP H0733905 A JPH0733905 A JP H0733905A JP 18275093 A JP18275093 A JP 18275093A JP 18275093 A JP18275093 A JP 18275093A JP H0733905 A JPH0733905 A JP H0733905A
Authority
JP
Japan
Prior art keywords
weight
composition
balance weight
heavy metal
balancing weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP18275093A
Other languages
Japanese (ja)
Other versions
JP3144168B2 (en
Inventor
Masaru Nakano
中野  勝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyo Ink Mfg Co Ltd
Original Assignee
Toyo Ink Mfg Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Ink Mfg Co Ltd filed Critical Toyo Ink Mfg Co Ltd
Priority to JP18275093A priority Critical patent/JP3144168B2/en
Publication of JPH0733905A publication Critical patent/JPH0733905A/en
Application granted granted Critical
Publication of JP3144168B2 publication Critical patent/JP3144168B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Details Of Measuring And Other Instruments (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

PURPOSE:To provide the title composition which can easily be produced, has a high weight accuracy necessary for a balancing weight and has excellent surface smoothness. CONSTITUTION:The composition is one containing 86-96wt. % heavy metal powder having a mean particle diameter of 1-30mum and 4-14wt.% thermoplastic resin.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、例えば、自動車、オ−
トバイ等の振動環境下の車両用計器に取り付けられる計
器の指針のバランスウェイトに用いられる組成物に関
し、更には、成形が容易で、且つ重量精度の高いバラン
スウェイト用組成物に関するものである。
BACKGROUND OF THE INVENTION The present invention is applicable to, for example, automobiles and automobiles.
The present invention relates to a composition used for a balance weight of a pointer of an instrument attached to a vehicle instrument under a vibrating environment such as Toby, and further to a composition for a balance weight that is easy to mold and has high weight accuracy.

【0002】[0002]

【従来の技術】従来は、タングステン、モリブデン等の
重金属を主体に合金を鋳造して、単純な円盤形状のブロ
ックを作り、そのブロックより要求形状を旋盤加工によ
り、削り出す方法を取ることが一般的であった。
2. Description of the Related Art Conventionally, it has been a general practice to cast an alloy mainly of heavy metals such as tungsten and molybdenum to form a simple disk-shaped block, and then machine the required shape from the block by lathing. It was target.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、重金属
を円盤状のブロックに鋳造し、ブロックより要求形状、
及び要求重量に切削する従来方法では、切削量が多く、
材料に多くの無駄が生じる。しかも、切削加工に負担が
かかり、コストが割高となり、更に品質も安定しないと
いう問題点があった。本発明は、このような問題点を解
決するもので、車両用計器の指針のバランスウェイト
の、重金属の高充填における、表面の平滑性が優れ、且
つ成形性の良い重量精度の高い組成物を提供することを
目的とする。
However, when a heavy metal is cast into a disk-shaped block and the required shape is obtained from the block,
And in the conventional method of cutting to the required weight, the cutting amount is large,
There is much waste of material. In addition, there is a problem that the cutting process is burdened, the cost is high, and the quality is not stable. The present invention is to solve such problems, a balance weight of the pointer of the vehicle instrument, in the high filling of heavy metals, excellent surface smoothness, and a composition with high weight accuracy and good moldability, The purpose is to provide.

【0004】尚、自動巻き時計用重りとして重金属粉末
と熱可塑性樹脂を併用した組成物(特開昭60−244
888号公報)も知られているが、重金属の比率が高
く、従って重量精度が劣り、計器指針のバランスウェイ
トとしては実用に供し得ない
A composition using a combination of heavy metal powder and a thermoplastic resin as a weight for an automatic timepiece (Japanese Patent Laid-Open No. 60-244).
No. 888) is also known, but the proportion of heavy metals is high, and therefore the weight accuracy is poor, and it cannot be put to practical use as a balance weight for instrument pointers.

【0005】[0005]

【課題を解決するための手段】本発明は、平均粒径1μ
m〜30μmの重金属の粉末86〜96重量%、及び熱
可塑性樹脂4〜14重量%を含むことを特徴とする計器
指針のバランスウェイト用組成物に関するものである。
本発明の車両計器の指針のバランスウェイト用組成物の
基本組成は、平均粒径1μm〜30μmの重金属の粉末
であり、30μm超えると成形品表面の凹凸が10μm
以上となり、好ましくない。又、粒子が1μm未満であ
れば流動性が悪くなり成形加工性に困難が伴う。
The present invention has an average particle size of 1 μm.
The present invention relates to a balance weight composition for measuring instruments, comprising 86 to 96% by weight of a heavy metal powder of m to 30 μm and 4 to 14% by weight of a thermoplastic resin.
The basic composition of the balance weight composition of the pointer of the vehicle instrument of the present invention is a heavy metal powder having an average particle size of 1 μm to 30 μm, and if it exceeds 30 μm, the unevenness of the surface of the molded product is 10 μm.
The above is not preferable. Further, if the particles are less than 1 μm, the fluidity is deteriorated and molding processability is difficult.

【0006】使用する熱可塑性樹脂としてはポリオレフ
ィン系樹脂、ポリアミド系樹脂、ポリカ−ボネ−ト系樹
脂、及びPBT系樹脂の樹脂で溶融時の粘度が1000
0cps以下であることが好ましい。10000cps
以上であれば、重金属粉末との混練時に充分に含浸でき
ず、含浸残りや気泡が発しやすい。重金族としては、比
重が19以上のものが好ましい。比重が19以上の重金
属を用いることにより、熱可塑性樹脂と併用しても、バ
ランスウェイトとして必要な比重5〜10を保持するこ
とができる。
The thermoplastic resin used is a polyolefin resin, a polyamide resin, a polycarbonate resin, or a PBT resin, and has a viscosity of 1000 when melted.
It is preferably 0 cps or less. 10,000 cps
If it is above, it cannot be sufficiently impregnated at the time of kneading with the heavy metal powder, and the impregnation residue and bubbles are likely to occur. The heavy metals preferably have a specific gravity of 19 or more. By using a heavy metal having a specific gravity of 19 or more, the specific gravity of 5 to 10 required as a balance weight can be maintained even when used in combination with a thermoplastic resin.

【0007】重金属粉末としては、タングステン、金、
又は、白金が好ましい。更にタングステンが粉末として
粒径を揃え易く、及び経済上優位であることから望まし
い。例えばタングステン粉末と樹脂との混合比率は、タ
ングステン粉末86重量%〜96重量%、樹脂4重量%
〜14重量%で、タングステン粉末86重量%未満であ
れば、組成物の比重が5以下となり、バランスウェイト
の体積が大きくなり実用に適しない。また、タングステ
ン粉末が96重量%以上であると、成形加工性が悪く強
度が低下する。
Heavy metal powders include tungsten, gold,
Alternatively, platinum is preferred. Further, tungsten is desirable because it is easy to make the particle diameter uniform as a powder and is economically superior. For example, the mixing ratio of tungsten powder and resin is 86% by weight to 96% by weight of tungsten powder and 4% by weight of resin.
If it is ˜14 wt% and less than 86 wt% of the tungsten powder, the specific gravity of the composition becomes 5 or less, and the volume of the balance weight becomes large, which is not suitable for practical use. Further, when the content of the tungsten powder is 96% by weight or more, the moldability is poor and the strength is lowered.

【0008】又、使用する熱可塑性樹脂には、樹脂の熱
劣化防止用の添加剤、例えば高分子量型フェノール系化
合物、より具体的にはテトラキス〔メチレン{3−
(3,5ジtertブチル−4−ヒドロキシフェニル)
pロパノート}〕メタン、及びタングステン粉末と樹脂
とのぬれ向上用として、シラン系、チタン系のカップリ
ング剤等を必要に応じて添加してもよい。
In addition, the thermoplastic resin used may be an additive for preventing thermal deterioration of the resin, such as a high molecular weight phenolic compound, more specifically tetrakis [methylene {3-
(3,5 ditert butyl-4-hydroxyphenyl)
p-lopanote}] A silane-based or titanium-based coupling agent or the like may be added, if necessary, for the purpose of improving the wettability between methane and tungsten powder and the resin.

【0009】[0009]

【実施例】以下、実施例に基づき本発明をさらに詳細に
説明する。 実施例1 平均粒径6.0μmのタングステン粉末90重量%、ポ
リプロピレン樹脂9重量%、その他に酸化防止剤等を1
重量%添加し、混合した後二軸押出機にて混練造粒を行
い、このペレットにより射出成形機にてバランスウェイ
トを成形した成形品の平均比重は6.25、比重のバラ
ツキの標準偏差は0.01以下であり、実用上充分満足
できる重量精度であった。表面平滑性に優れ、外観上の
問題はなく車両用の計器指針のバランスウェイトに用い
たところ、充分に使用に耐え得た。
The present invention will be described in more detail based on the following examples. Example 1 90% by weight of tungsten powder having an average particle diameter of 6.0 μm, 9% by weight of polypropylene resin, and 1% of an antioxidant and the like.
After adding and mixing by weight, the mixture was kneaded and granulated by a twin-screw extruder, and the pellets were molded into a balance weight by an injection molding machine. It was 0.01 or less, and the weight accuracy was sufficiently satisfactory for practical use. It was excellent in surface smoothness and had no problem in appearance, and when used as a balance weight for instrument pointers for vehicles, it was sufficiently durable to use.

【0010】実施例2 平均粒径6.0μmのタングステン粉末90重量%、平
均粒径1.0μmのタングステン粉末4重量%、ポリア
ミド樹脂5.5重量%、その他添加剤0.5重量%を混
合した後、二軸押出機にて混練造粒を行い、このペレッ
トにより射出成形にてバランスウェイトを成形した。成
形品の平均比重は9.34であった。比重のバラツキ標
準偏差は0.02で、バランスウェイトとして品質上良
好であった。
Example 2 90% by weight of tungsten powder having an average particle size of 6.0 μm, 4% by weight of tungsten powder having an average particle size of 1.0 μm, 5.5% by weight of polyamide resin and 0.5% by weight of other additives were mixed. After that, kneading and granulation was performed with a twin-screw extruder, and a balance weight was formed by injection molding from the pellets. The average specific gravity of the molded product was 9.34. The standard deviation of variation in specific gravity was 0.02, which was a good balance weight in terms of quality.

【0011】[0011]

【発明の効果】本発明のバランスウェイト用組成物は、
製造が容易であり、且つバランスウェイトとして必要な
重量精度が高く、表面が平滑なものが得られる。つま
り、従来法の切削によらずに、通常の射出成形で重量精
度の高いバランスウェイトが得られる。
The composition for balance weight of the present invention is
It is easy to manufacture, has a high weight accuracy required as a balance weight, and has a smooth surface. That is, a balance weight with high weight accuracy can be obtained by ordinary injection molding without using the conventional method of cutting.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 平均粒径1μm〜30μmの重金属の粉
末86〜96重量%及び熱可塑性樹脂4〜14重量%を
含むことを特徴とする計器指針のバランスウェイト用組
成物。
1. A balance weight composition for measuring instruments, comprising 86 to 96% by weight of a heavy metal powder having an average particle size of 1 to 30 μm and 4 to 14% by weight of a thermoplastic resin.
【請求項2】 重金属の粉末がタングステン、金、白金
から選ばれる少なくとも1種の粉末であることを特徴と
する計器指針のバランスウェイト用組成物。
2. A balance weight composition for measuring instruments, wherein the heavy metal powder is at least one powder selected from tungsten, gold and platinum.
JP18275093A 1993-07-23 1993-07-23 Composition and balance weight for balance weight of instrument pointer Expired - Fee Related JP3144168B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP18275093A JP3144168B2 (en) 1993-07-23 1993-07-23 Composition and balance weight for balance weight of instrument pointer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP18275093A JP3144168B2 (en) 1993-07-23 1993-07-23 Composition and balance weight for balance weight of instrument pointer

Publications (2)

Publication Number Publication Date
JPH0733905A true JPH0733905A (en) 1995-02-03
JP3144168B2 JP3144168B2 (en) 2001-03-12

Family

ID=16123786

Family Applications (1)

Application Number Title Priority Date Filing Date
JP18275093A Expired - Fee Related JP3144168B2 (en) 1993-07-23 1993-07-23 Composition and balance weight for balance weight of instrument pointer

Country Status (1)

Country Link
JP (1) JP3144168B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001154661A (en) * 1999-11-25 2001-06-08 Kawai Musical Instr Mfg Co Ltd Keyboard
JP2007271539A (en) * 2006-03-31 2007-10-18 Nippon Tungsten Co Ltd Resin tungsten composite material
KR101407340B1 (en) * 2012-05-11 2014-06-13 (주)케비워 Balance weight that can be reused for washing of the preparation method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001154661A (en) * 1999-11-25 2001-06-08 Kawai Musical Instr Mfg Co Ltd Keyboard
JP4644327B2 (en) * 1999-11-25 2011-03-02 株式会社河合楽器製作所 keyboard
JP2007271539A (en) * 2006-03-31 2007-10-18 Nippon Tungsten Co Ltd Resin tungsten composite material
KR101407340B1 (en) * 2012-05-11 2014-06-13 (주)케비워 Balance weight that can be reused for washing of the preparation method

Also Published As

Publication number Publication date
JP3144168B2 (en) 2001-03-12

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