JPS62187735A - Composition for outer trim of timepiece - Google Patents
Composition for outer trim of timepieceInfo
- Publication number
- JPS62187735A JPS62187735A JP2950486A JP2950486A JPS62187735A JP S62187735 A JPS62187735 A JP S62187735A JP 2950486 A JP2950486 A JP 2950486A JP 2950486 A JP2950486 A JP 2950486A JP S62187735 A JPS62187735 A JP S62187735A
- Authority
- JP
- Japan
- Prior art keywords
- metal powder
- resin
- weight
- lubricant
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 229910052751 metal Inorganic materials 0.000 claims abstract description 36
- 239000002184 metal Substances 0.000 claims abstract description 36
- 239000000843 powder Substances 0.000 claims abstract description 36
- 229920005989 resin Polymers 0.000 claims abstract description 23
- 239000011347 resin Substances 0.000 claims abstract description 23
- 239000000314 lubricant Substances 0.000 claims abstract description 14
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 9
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 6
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims abstract description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 4
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 4
- 239000010935 stainless steel Substances 0.000 claims abstract description 4
- 239000011521 glass Substances 0.000 claims abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract 2
- 229920003776 Reny® Polymers 0.000 claims abstract 2
- 229910052802 copper Inorganic materials 0.000 claims abstract 2
- 239000010949 copper Substances 0.000 claims abstract 2
- 229910052742 iron Inorganic materials 0.000 claims abstract 2
- 239000002245 particle Substances 0.000 claims abstract 2
- 239000012756 surface treatment agent Substances 0.000 claims description 9
- 238000001746 injection moulding Methods 0.000 claims description 6
- 229920006122 polyamide resin Polymers 0.000 claims description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 4
- 239000013078 crystal Substances 0.000 claims description 4
- 229910000077 silane Inorganic materials 0.000 claims description 4
- 229920002292 Nylon 6 Polymers 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 229910010272 inorganic material Inorganic materials 0.000 claims description 3
- 239000011147 inorganic material Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- IEKHISJGRIEHRE-UHFFFAOYSA-N 16-methylheptadecanoic acid;propan-2-ol;titanium Chemical compound [Ti].CC(C)O.CC(C)CCCCCCCCCCCCCCC(O)=O.CC(C)CCCCCCCCCCCCCCC(O)=O.CC(C)CCCCCCCCCCCCCCC(O)=O IEKHISJGRIEHRE-UHFFFAOYSA-N 0.000 claims 1
- 229920000299 Nylon 12 Polymers 0.000 claims 1
- 229920002302 Nylon 6,6 Polymers 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims 1
- 238000000465 moulding Methods 0.000 abstract description 4
- 238000005453 pelletization Methods 0.000 abstract description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract description 2
- 238000004898 kneading Methods 0.000 abstract description 2
- 229920001778 nylon Polymers 0.000 abstract description 2
- 229920006038 crystalline resin Polymers 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 1
- 230000005484 gravity Effects 0.000 description 5
- 230000003746 surface roughness Effects 0.000 description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 5
- 229910052721 tungsten Inorganic materials 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- 239000003365 glass fiber Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 229920006039 crystalline polyamide Polymers 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000005300 metallic glass Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
Landscapes
- Reinforced Plastic Materials (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、基本組成がポリアミド樹脂と金属粉末、繊維
状あるいは粉末状無４ａ物、滑剤１表面処理剤からなる
時計用外装部品組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a watch exterior component composition whose basic composition is a polyamide resin, a metal powder, a fibrous or powdery non-4A material, a lubricant, and a surface treatment agent. .
本発明は、時計用外装部品組成物に於いて、結品性樹脂
に表面処理した球形金属粉末、滑剤、無機充填剤を混合
射出成形することにより高強度性と高比重、高流動性、
高外観性（面粗度）を向上させ大巾にコストダウンをは
かったものである。The present invention provides an exterior component composition for a watch that has high strength, high specific gravity, high fluidity, and high strength, high specific gravity, and high fluidity by injection molding a binding resin with surface-treated spherical metal powder, a lubricant, and an inorganic filler.
This improves the appearance (surface roughness) and significantly reduces costs.
ポリアミド樹脂は、エンジニアリングプラスチックとし
て熱可塑性樹脂の中で高い機械的強度に優れ、耐摩耗性
、耐薬品性、熱的性質にも優れていて広い範囲に用いら
れているが、時計用外装部品に用いる場合、高い機械的
強度が必要であり、ガラス繊維、あるいは金属粉末等を
充填し、高強度性を出している。しかしこれ等を充填す
る場合樹脂の分子量が多いと充填しにくいばかりが樹脂
の流動性が悪くなり成形肌を悪くしている。As an engineering plastic, polyamide resin has the highest mechanical strength among thermoplastic resins, as well as excellent abrasion resistance, chemical resistance, and thermal properties, and is used in a wide range of applications. When used, high mechanical strength is required, and it is filled with glass fiber, metal powder, etc. to provide high strength. However, when filling these materials, if the molecular weight of the resin is high, it is difficult to fill the resin, and the fluidity of the resin deteriorates, resulting in poor molding surface.
流動性を良くするためには、分子量の低い樹脂の選定、
あるいは滑剤添加等で流動性の良い樹脂に改良したり、
タングステン等比重の高い金属粉末を用い金属粉末の各
社を減じ樹脂の特性を損なわない様改良している。In order to improve fluidity, it is necessary to select a resin with a low molecular weight,
Or improve the resin to have good fluidity by adding a lubricant, etc.
We use metal powders with high specific gravity, such as tungsten, and reduce the amount of metal powder used by various manufacturers to improve the resin properties.
しかし前述の従来技術では、樹脂の分子量を下げると充
填性は良くなるが射出成形時に成形パリを誘発し機械強
度も落ちる。However, in the above-mentioned conventional technology, lowering the molecular weight of the resin improves the filling property, but it also induces molding flash during injection molding and lowers the mechanical strength.
又タングステン等高比重金属粉末は非常に高額な金属粉
末であり実用上問題となる。Further, high specific gravity metal powder such as tungsten is a very expensive metal powder and poses a practical problem.
そこで本発明はこの様な問題点を解決するものでその目
的とするところは高分子量のポリアミド樹脂を用いて、
金槁粉末、ガラス、チタン酸カリウム繊維を高充填し高
強度性、高成形性（高流動性）を保ちかつ成形肌を向上
させる時計用外装部品組成物を提供することを特徴とす
る。Therefore, the present invention aims to solve these problems, and its purpose is to use a high molecular weight polyamide resin,
The present invention is characterized by providing an exterior component composition for a watch that is highly filled with gold powder, glass, and potassium titanate fibers, maintains high strength, high moldability (high fluidity), and improves the molding surface.
本発明の時計用外装部品組成物は、熱可塑性結晶樹脂１
０〜４０重量％、繊維、粉末状無機物５〜４０重艦％、
金属粉末３０〜７０重量％、滑剤［１１〜５重祉部／樹
脂１表面処理剤０．１〜５重量部／金属粉末からなる混
合物を周知の混線機、バンバリーミキサ−など溶融混線
法により混練したものをペレット化し射出成形する方法
によって、達成される。The exterior parts composition for a watch of the present invention comprises thermoplastic crystal resin 1
0 to 40% by weight, fiber, powdered inorganic matter 5 to 40% by weight,
A mixture consisting of 30 to 70% by weight of metal powder, 11 to 5 parts of lubricant, 1 part of resin, 0.1 to 5 parts by weight of surface treatment agent, and metal powder is kneaded by a melt mixing method such as a well-known mixer or Banbury mixer. This is accomplished by pelletizing the pellets and injection molding them.
本発明に使用する結晶性ポリアミド樹脂は熱可塑性であ
れば何でもよいが分子［１５０００〜２００００の６ナ
イロンが望ましく、又金属粉末は、５〜８０μｍの球状
が望ましい。The crystalline polyamide resin used in the present invention may be of any type as long as it is thermoplastic, but it is preferably nylon 6 with a molecular weight of 15,000 to 20,000, and the metal powder is preferably spherical with a size of 5 to 80 μm.
ポリアミド樹脂と繊維状あるいは粉末状無機物。Polyamide resin and fibrous or powdered inorganic material.
滑剤をあらかじめ混合機で混合したものと、あらかじめ
表面処理した球形金属粉末とを同時に混線機に投入混練
したものをペレタイザーでペレット化し射出成形した樹
脂成形物を用いたことを特徴とする。It is characterized by using a resin molded product that is made by mixing a lubricant in a mixer in advance and spherical metal powder that has been surface-treated in advance and kneading it at the same time in a mixer, pelletizing it with a pelletizer and injection molding.
熱可塑性結晶ナイロン６樹脂 １ａＯ重社％ガラス繊
維 ２′Ｌ５重量％チタン酸カリ
ウムウィスカー ２．２重蓋％球形ステンレス金属
粉末 ５７．３重置％シラン系表面処理剤
ａ３重量部／金属粉高級カルボン酸金属鉛滑剤ＣＬ３ｆ
ｆｉ量部／樹脂を用いた実施例において、
８０℃３時間以上で乾燥した熱可塑性結晶６ナイロン樹
脂と金属鉛系滑剤、無機ガラス繊維、チタン酸カリウム
、ウィスカーを混合機で混合し二軸混練押出機のスクリ
ーーホッパーから供給する。またあらかじめシラン系表
面処理剤で処理しである球形ステンレスの金属粉末をテ
ーブルフィーダーで供給混練しペレタイザーでペレット
化したものをテストピースに成形あるいは時計用外装ケ
ースに成形して機械物性値（引張強度２曲げ強度、曲げ
弾性率、ＩＺＯＤ衝撃値、比重）を測定。Thermoplastic crystalline nylon 6 resin 1aO Jusha% Glass fiber 2'L5% by weight Potassium titanate whiskers 2.2% by weight Spherical stainless metal powder 57.3% by weight Silane surface treatment agent
a3 parts by weight/metal powder high grade carboxylic acid metal lead lubricant CL3f
In the example using fi part/resin, thermoplastic crystal 6 nylon resin dried at 80°C for 3 hours or more, metallic lead-based lubricant, inorganic glass fiber, potassium titanate, and whiskers were mixed in a mixer and biaxially kneaded. Feed from the extruder's scree hopper. In addition, spherical stainless steel metal powder, which has been previously treated with a silane-based surface treatment agent, is fed and kneaded using a table feeder and pelletized using a pelletizer, which is then molded into a test piece or a watch case to obtain mechanical properties (tensile strength). 2 Measurement of bending strength, bending modulus, IZOD impact value, specific gravity).
又射出成形の加工性を７０−テスター（荷重１６０ＫＰ
、温度２８０℃、φ１ ｔ＝Ｉ Ｑｒｔａｎダイ）を用
い＠ｔ／Ｓで流動値を測定評価した結果を第−表に示す
。In addition, we tested the processability of injection molding using a 70-tester (load: 160 KP).
Table 1 shows the results of measuring and evaluating the flow value at @t/S using a φ1 t=I Qrtan die at a temperature of 280°C.
〔実施例２〕
実施例１の組成で金属粉末を不定形ステンレス金属粉に
し同一方法で測定評価した結果を第−表に示す。[Example 2] The metal powder was made into amorphous stainless metal powder with the composition of Example 1, and the results were measured and evaluated using the same method, and the results are shown in Table 1.
〔実施例３〕
実施例１の組成で金属粉末を不定形ステンレス金属粉末
と不定形タングステン金属粉末の混合金属粉末にし同一
方法で測定評価した結果を第−表に示す。[Example 3] A mixed metal powder of amorphous stainless metal powder and amorphous tungsten metal powder was used as the metal powder with the composition of Example 1, and the results were measured and evaluated using the same method, and the results are shown in Table 1.
第−表であきらかのごとく球状金属粉末を用いることに
よりＩ ＺＯＤ衝激値、流動性の切性に有意差を生じる
。As shown in Table 1, the use of spherical metal powder produces significant differences in IZOD impact value and fluidity.
また成形肌については不定形ステンレス＋タングステン
混合金属粉未使用の面粗さに比較し若干落ちるが、不定
形ステンレス金属粉面粗さに比較して充分有意差が認め
られる。Furthermore, the surface roughness of the molded surface is slightly lower than the surface roughness of amorphous stainless steel + tungsten mixed metal powder, but a sufficiently significant difference is recognized compared to the surface roughness of the amorphous stainless metal powder.
以上述べたように、本発明によれば時計用外装部品組成
物に結晶性熱可塑性樹脂１０〜４０重ｆａｎ％、高級カ
ーボン酸金属鉛滑剤０．１〜５重２部／樹脂、繊維状無
機物５〜４０重鼠％、単数もしくは複数の球状金属粉末
５０〜７０重Ｎ％、シラン糸表面処理剤０．１〜５重量
部／金属粉末、を添加する組成物にしたことにより、機
械的強度を落すことなく流動性、耐衝微性を良くシ、成
形肌も重金属粉使用のものと比較し若干荒いが不定形金
属粉末よりはるかに面粗度が良くなる効果が認められる
。特に重金属のタングステンを用いないので多大なコス
トダウンになる効果を有するものである。As described above, according to the present invention, a watch exterior component composition contains 10 to 40 weight fan% of a crystalline thermoplastic resin, 0.1 to 5 parts of a high carbon acid metal lead lubricant/resin, and a fibrous inorganic material. Mechanical strength is improved by creating a composition containing 5-40% by weight, 50-70% by weight of one or more spherical metal powders, and 0.1-5 parts by weight of a silane thread surface treatment agent/metal powder. The molded surface is slightly rougher than those using heavy metal powder, but the surface roughness is much better than that of amorphous metal powder. In particular, since the heavy metal tungsten is not used, it has the effect of greatly reducing costs.
又時計用外装部品以％、電子機器、１−＃報機器等の分
野に於いてもこの組成物の応用は可能であり充分効果を
見い出せるものである。Furthermore, this composition can be applied to the fields of exterior parts for watches, electronic equipment, 1-# information equipment, etc., and can be found to be sufficiently effective.
Claims (6)
いは粉末状無機物５〜４０重量％、金属粉末３０〜７０
重量％、滑剤０．１〜５重量部／樹脂、表面処理剤０．
１〜５重量部／金属粉末からなる混合物を射出成形した
樹脂成形物を用いたことを特徴とする時計用外装部品組
成物。(1) Thermoplastic crystal resin 10-40% by weight, fibrous or powdered inorganic material 5-40% by weight, metal powder 30-70%
Weight %, lubricant 0.1 to 5 parts by weight/resin, surface treatment agent 0.
An exterior part composition for a watch, characterized in that it uses a resin molded product obtained by injection molding a mixture of 1 to 5 parts by weight/metal powder.
０のナイロン６、６６、１２、レニー樹脂等ポリアミド
樹脂から選ばれた、特許請求の範囲第１項記載の時計用
外装部品組成物。(2) Thermoplastic crystal resin has a molecular weight of 8000 to 3000
The exterior part composition for a watch according to claim 1, which is selected from polyamide resins such as nylon 6, 66, 12, and Reny resin.
カーボン、チタン酸カリウムウイスカー等一種若しくは
複数の無機物である特許請求の範囲第１項記載の時計用
外装部品組成物。(3) Glass in which the inorganic substance is in the form of fibers or powder;
The exterior component composition for a watch according to claim 1, which is one or more inorganic substances such as carbon and potassium titanate whiskers.
のステンレス、鉄、銅等の一種若しくは複数の金属粉末
である特許請求の範囲第１項記載の時計用外装部品組成
物。(4) The watch exterior component composition according to claim 1, wherein the metal powder is a spherical metal powder of one or more of stainless steel, iron, copper, etc., with a particle size of 0.2 μm to 500 μm.
鉛系滑剤である特許請求の範囲第１項記載の時計用外装
部品組成物。(5) The exterior component composition for a watch according to claim 1, wherein the lubricant is a high carbon acid metal lead-based lubricant such as zinc stearate.
系表面処理剤、イソプロプルトリイソステアロイルチタ
ネート等チタネート系表面処理剤から１種または複数の
選ばれた特許請求の範囲第１項記載の時計用外装部品組
成物。(6) A watch according to claim 1, wherein the surface treatment agent is one or more selected from silane surface treatment agents such as vinyltrimethoxysilane and titanate surface treatment agents such as isopropyl triisostearoyl titanate. Exterior parts composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2950486A JPS62187735A (en) | 1986-02-13 | 1986-02-13 | Composition for outer trim of timepiece |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2950486A JPS62187735A (en) | 1986-02-13 | 1986-02-13 | Composition for outer trim of timepiece |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62187735A true JPS62187735A (en) | 1987-08-17 |
Family
ID=12277917
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2950486A Pending JPS62187735A (en) | 1986-02-13 | 1986-02-13 | Composition for outer trim of timepiece |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62187735A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0298020A (en) * | 1988-10-03 | 1990-04-10 | Mitsubishi Electric Corp | Switch |
| EP1099722A3 (en) * | 1999-11-12 | 2001-08-16 | Junghans Uhren GmbH | Plastic article having a metallic appearance, particularly radio wristwatch housings |
| JP2012154925A (en) * | 2011-01-27 | 2012-08-16 | Eta Sa Manufacture Horlogere Suisse | Oscillating weight |
| JP2020101534A (en) * | 2018-12-24 | 2020-07-02 | ザ・スウォッチ・グループ・リサーチ・アンド・ディベロップメント・リミテッド | Ornament formed of heavy composite material |
-
1986
- 1986-02-13 JP JP2950486A patent/JPS62187735A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0298020A (en) * | 1988-10-03 | 1990-04-10 | Mitsubishi Electric Corp | Switch |
| EP1099722A3 (en) * | 1999-11-12 | 2001-08-16 | Junghans Uhren GmbH | Plastic article having a metallic appearance, particularly radio wristwatch housings |
| JP2012154925A (en) * | 2011-01-27 | 2012-08-16 | Eta Sa Manufacture Horlogere Suisse | Oscillating weight |
| JP2020101534A (en) * | 2018-12-24 | 2020-07-02 | ザ・スウォッチ・グループ・リサーチ・アンド・ディベロップメント・リミテッド | Ornament formed of heavy composite material |
| US11042125B2 (en) | 2018-12-24 | 2021-06-22 | The Swatch Group Research And Development Ltd | Decorative item made of a heavy composite material |
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