JPH0730516B2 - Antifouling method for vinyl chloride resin cloth - Google Patents
Antifouling method for vinyl chloride resin clothInfo
- Publication number
- JPH0730516B2 JPH0730516B2 JP61132054A JP13205486A JPH0730516B2 JP H0730516 B2 JPH0730516 B2 JP H0730516B2 JP 61132054 A JP61132054 A JP 61132054A JP 13205486 A JP13205486 A JP 13205486A JP H0730516 B2 JPH0730516 B2 JP H0730516B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- vinyl chloride
- chloride resin
- antifouling
- based graft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
【発明の詳細な説明】 産業上の利用分野 本発明は、繊維布帛に塩化ビニル系樹脂による樹脂加工
を施した、トラックシート、野積シート、大型テント等
に使用される塩化ビニル系樹脂加工布の防汚加工方法に
関するものである。Description: TECHNICAL FIELD The present invention relates to a vinyl chloride resin-treated cloth used for truck seats, field sheets, large tents, etc., in which a fiber cloth has been subjected to resin processing with a vinyl chloride resin. The present invention relates to an antifouling processing method.
従来の技術 従来から、塩化ビニル系樹脂を被覆加工したテント、ト
ラックシートなどについてはよく知られている。これら
は、ビニロン、ポリアミド、ポリエステルなどの紡績糸
を用いて製編織した編織物基布に、塩化ビニル系樹脂を
用いて、ディッピング、コーティング、トッピング、ラ
ミネーティングなどの種々の方法により加工を施して製
造されている。塩化ビニル系樹脂が広く用いられている
理由としては、加工性がすぐれており、種々の加工方法
が採用でき、また可塑剤の調整により任意に樹脂の柔軟
性を調整できること、また軟質塩化ビニル系樹脂が高周
波誘電により発熱する特徴を利用し、高周波ウェルダ溶
着加工による縫製を行ない得ることなどがあげられる。2. Description of the Related Art Conventionally, tents, track sheets, and the like coated with vinyl chloride resin have been well known. These are knitted and woven fabric bases woven and knitted using spun yarn such as vinylon, polyamide, and polyester, using vinyl chloride resin, and processed by various methods such as dipping, coating, topping, and laminating. Being manufactured. The reason why vinyl chloride resin is widely used is that it has excellent processability, various processing methods can be adopted, and the flexibility of the resin can be arbitrarily adjusted by adjusting the plasticizer. Taking advantage of the fact that resin heats up due to high frequency dielectrics, it is possible to perform sewing by high frequency welder welding.
上記のごとく、塩化ビニル系樹脂加工布は、多くの長所
を有しているが、長期間野外で曝露されて使用されるた
め、汚れ易い。すなわち塩化ビニル系樹脂加工布は、塩
化ビニル系樹脂中の各種可塑剤の表面への移行が使用中
に徐々に進行し、粘着性をおびて、大気中の汚れが付着
しやすく、外観が著しく悪化する。このような問題を解
決する方法として種々提案されているが、その代表的な
ものとしては、加工布の表面をポリアクリル酸エステ
ル、ポリメタクリル酸エステル等のアクリル酸系樹脂あ
るいはウレタン系樹脂をコーティングする方法がある。As described above, the vinyl chloride resin-treated cloth has many advantages, but it is easily soiled because it is used by being exposed outdoors for a long period of time. That is, in the vinyl chloride resin-treated cloth, the migration of various plasticizers in the vinyl chloride resin to the surface gradually progresses during use, it becomes sticky, dirt in the air is easily attached, and the appearance is remarkable. Getting worse. Various proposals have been made as methods for solving such a problem. As a typical example thereof, the surface of the work cloth is coated with an acrylic resin such as polyacrylic acid ester or polymethacrylic acid ester or a urethane resin. There is a way to do it.
発明が解決しようとする問題点 塩化ビニル系樹脂加工布の使用中の汚染を防止するた
め、上記のごときアクリル酸系樹脂あるいはウレタン系
樹脂を表面にコーティングする方法では効果の持続性が
乏しく、その他の方法も含めて、防汚性能、耐久性、加
工性、コスト等を全て満足する方法は未だ見出されてい
ない。Problems to be Solved by the Invention In order to prevent contamination during use of a vinyl chloride resin-treated cloth, the method of coating the surface of the acrylic acid resin or urethane resin as described above has a poor effect persistence, and other Including the above method, a method that satisfies all of the antifouling performance, durability, processability, cost, etc. has not yet been found.
本発明は、塩化ビニル系樹脂加工布の防汚処理におい
て、従来方法における上記のごとき問題点を解決して、
耐久性のあるすぐれた防汚性を付与することができる防
汚加工方法を提供しようとするものである。The present invention, in the antifouling treatment of a vinyl chloride resin processed cloth, solves the above problems in the conventional method,
It is intended to provide a stainproofing method capable of imparting excellent durability and stainproofing property.
問題点を解決するための手段 本発明の塩化ビニル系樹脂加工布の防汚加工方法は、繊
維布帛に塩化ビニル系樹脂を主成分とする樹脂加工を施
した後、少なくとも片面に、溶剤可溶型のアクリル酸エ
ステル系樹脂およびウレタン系樹脂の少なくともいずれ
かを20〜50重量％と弗素系グラフト樹脂およびシリコン
系グラフト樹脂の少なくともいずれかを0.02〜５重量％
含有する溶液を、固形分として３〜50g/m2塗布し、加熱
乾燥することを特徴とするものである。Means for Solving the Problems A method for antifouling a vinyl chloride resin-treated cloth of the present invention is to apply a solvent treatment to a fiber cloth at least on one side after subjecting the fiber cloth to resin treatment containing a vinyl chloride resin as a main component. 20 to 50% by weight of at least one of acrylic ester resin and urethane resin and 0.02 to 5% by weight of at least one of fluorine-based graft resin and silicone-based graft resin
It is characterized in that the contained solution is applied in a solid content of 3 to 50 g / m 2 and dried by heating.
本発明を適用する塩化ビニル系樹脂加工布とする繊維布
帛は、綿、レーヨンおよびポリエステル、ポリアミド、
ビニロン等の合成繊維の紡績糸を用いて、所望の組織で
製編織した編織物である。また前記繊維布帛に加工する
塩化ビニル系樹脂は、塩化ビニル重合体、塩化ビニル−
酢酸ビニル共重合体、塩化ビニル−アクリル酸エステル
共重合体、塩化ビニル−塩化ビニリデン共重合体あるい
は前記重合体または共重合体の混合物に、安定剤、可塑
剤、防炎剤その他の添加剤を配合したものである。加工
方法としては、トッピング、コーティング、ディッピン
グ、ラミネーティングのいずれでもよく、樹脂処理後、
焼付け等の熱処理を行なう。The fiber cloth as the vinyl chloride resin-processed cloth to which the present invention is applied includes cotton, rayon and polyester, polyamide,
It is a knitted fabric that is knitted and woven with a desired structure using spun yarn of synthetic fiber such as vinylon. Further, the vinyl chloride resin to be processed into the fiber cloth is a vinyl chloride polymer, vinyl chloride-
Vinyl acetate copolymer, vinyl chloride-acrylic acid ester copolymer, vinyl chloride-vinylidene chloride copolymer or a mixture of the above-mentioned polymers or copolymers, stabilizers, plasticizers, flame retardants and other additives It is a mixture. The processing method may be any of topping, coating, dipping, laminating, and after resin treatment,
Perform heat treatment such as baking.
本発明の防汚加工方法で用いる溶剤可溶型のアクリル酸
エステル系樹脂は、アクリル酸またはメタアクリル酸の
低級アルキルエステルの単独重合体又はそれらのアルキ
ルエステルを主成分とする共重合体があげられ、また溶
剤可溶型ウレタン系樹脂には、ポリエステル、ポリエー
テル等のジオール成分と脂肪族および芳香族ジイソシア
ネートからなるものがあげられる。溶剤としては、ヘキ
サン、シクロヘキサン、トリクロルエチレン、ベンゼ
ン、トルエン、アセトン、メチルエチルケトン、DMF、
ジオキサン等の有機溶剤あるいはそれらの混合物を用い
ることができる。Examples of the solvent-soluble acrylic ester-based resin used in the antifouling processing method of the present invention include homopolymers of lower alkyl esters of acrylic acid or methacrylic acid or copolymers containing these alkyl esters as the main components. Examples of the solvent-soluble urethane-based resin include those containing a diol component such as polyester and polyether and an aliphatic or aromatic diisocyanate. As the solvent, hexane, cyclohexane, trichloroethylene, benzene, toluene, acetone, methyl ethyl ketone, DMF,
An organic solvent such as dioxane or a mixture thereof can be used.
本発明においては、前記の溶剤可溶型のアクリル酸エス
テル系樹脂、ウレタン系樹脂の溶液に、弗素系グラフト
樹脂およびシリコン系グラフト樹脂の少なくともいずれ
かを添加するが、これら弗素系グラフト樹脂およびシリ
コン系グラフト樹脂は、グラフト成分に弗素原子、シリ
コン原子が存在し、市販品として弗素系グラフト樹脂は
アロンGF−150、アロンGF−300、シリコン系グラフト樹
脂はアロンGS−30（いずれも東亜合成化学工業K.K.製）
がある。これら弗素系グラフト樹脂およびシリコン系グ
ラフト樹脂は、従来の弗素系樹脂およびシリコン系樹脂
を添加した際均一に混合されず、分離を起こして均一な
皮膜形成が困難で、皮膜の剥離強度が著しく低下し、し
かも防汚性能も低いのに対し、相溶性が良く、界面移行
性も良好で、少量の添加で防汚効果がすぐれ、高撥水
性、高撥油性を示す。In the present invention, at least one of a fluorine-based graft resin and a silicon-based graft resin is added to the solution of the solvent-soluble acrylic ester-based resin or urethane-based resin. The fluorine-based graft resin has fluorine atoms and silicon atoms in the graft component. As commercially available products, the fluorine-based graft resin is Aron GF-150, Aron GF-300, and the silicon-based graft resin is Aron GS-30. Industrial KK)
There is. These fluorine-based graft resins and silicon-based graft resins are not mixed uniformly when conventional fluorine-based resins and silicon-based resins are added, causing separation and making it difficult to form a uniform film, and the peel strength of the film is significantly reduced. In addition, the antifouling property is low, but the compatibility is good and the interfacial migration is also good, and the antifouling effect is excellent with the addition of a small amount, and high water repellency and high oil repellency are exhibited.
前記の溶剤可溶型のアクリル酸エステル系樹脂および／
またはウレタン系樹脂の溶液は、塗布方法によっても若
干異なるが、固形分濃度を20〜50重量％の範囲とするこ
とが必要で、20重量％より低濃度とすると塩化ビニル系
樹脂加工布に所望の樹脂皮膜を形成することができず、
また50重量％より高濃度となる粘度が高くなり過ぎ、塗
布が困難となり、均一な皮膜を形成することができな
い。前記溶液には、必要に応じて架橋剤１〜10重量％程
度添加することもある。次に弗素系グラフト樹脂および
／またはシリコン系グラフト樹脂は、固形分濃度0.02〜
５重量％とすることが必要である。濃度が0.02重量％よ
り低いと所期の汚染効果が得られず、また５重量％より
高濃度となる泡立ちが顕著となって加工困難となり、効
果もあまり増大することもなく、いずれも不適当であ
る。The solvent-soluble acrylate resin and /
Or, the urethane resin solution may vary slightly depending on the coating method, but it is necessary to set the solid content concentration in the range of 20 to 50% by weight. Could not form the resin film of
Further, if the concentration becomes higher than 50% by weight, the viscosity becomes too high, and the coating becomes difficult, and a uniform film cannot be formed. If necessary, about 1 to 10% by weight of a crosslinking agent may be added to the solution. Next, the fluorine-based graft resin and / or the silicon-based graft resin has a solid content concentration of 0.02 to
It is necessary to set it to 5% by weight. If the concentration is lower than 0.02% by weight, the desired contamination effect cannot be obtained, and foaming with a concentration higher than 5% by weight becomes noticeable and processing becomes difficult, and the effect does not increase so much. Is.
前記溶液を塩化ビニル系樹脂加工布へ塗布する方法は、
コーティング、ディッピングの何れでもよく、常法によ
り片面または両面に行なえばよい。塗布量は、固形分で
３〜50g/m2とすることが必要であり、塗布量が3g/m2よ
り少なければ防汚効果が不十分で耐久性が劣り、また50
g/m2より塗布量が増すと目付が増大して実用的でなく、
硬化して風合が著しく低下し、いずれも不適当である。The method of applying the solution to the vinyl chloride resin-treated cloth is
Either coating or dipping may be performed, and one side or both sides may be coated by a conventional method. The coating amount is required to be 3 to 50 g / m 2 in solid coating amount is inferior is less if antifouling effect is insufficient durability than 3 g / m 2, also 50
If the coating amount is higher than g / m 2 , the basis weight increases and it is not practical,
It hardens and the texture decreases remarkably, and both are unsuitable.
前記溶液を塗布した後、乾燥、熱処理を行なうが、アク
リル酸エステル系樹脂およびウレタン系樹脂の一般的な
熱処理温度150〜170℃で加工することができるが、通常
の乾燥程度の加熱でも十分な効果を示す。After applying the solution, drying and heat treatment are carried out, but it can be processed at a general heat treatment temperature of 150 to 170 ° C. for acrylic ester-based resins and urethane-based resins, but heating at a normal dry degree is also sufficient. Show the effect.
上記のごとく防汚加工として得られた塩化ビニル樹脂加
工布は、屋外に長期間曝露して使用しても、非常に汚れ
にくく、また風雨等により汚れが除去され、かつこれら
の効果の耐久性が良好で、また耐光性、ウェルダ加工性
もすぐれている。The vinyl chloride resin-treated cloth obtained as an antifouling treatment as described above is extremely resistant to stains even when used outdoors for a long period of time, and stains are removed by wind and rain, and the durability of these effects Has good light resistance and excellent weldability.
作用 本発明において、塩化ビニル系樹脂加工布の表面に、ア
クリル酸エステル系樹脂および／またはウレタン系樹脂
に弗素系グラフト樹脂および／またはシリコン系グラフ
ト樹脂が混合された皮膜が形成され、塩化ビニル系樹脂
内部から表面への可塑剤のブリードが防止されるととも
に、形成した皮膜の表面に弗素系グラフト樹脂および／
またはシリコン系グラフト樹脂が効果的に移行して表面
が改質され、耐汚染性が付与されると同時に撥水性、撥
油性が向上して、付着した汚れも風雨により除去され
る。Action In the present invention, a film in which a fluorine-based graft resin and / or a silicon-based graft resin is mixed with an acrylic ester resin and / or a urethane resin is formed on the surface of a vinyl chloride resin-treated cloth, Bleed of the plasticizer from the inside of the resin to the surface is prevented and the surface of the formed film is treated with fluorine-based graft resin and / or
Alternatively, the silicon-based graft resin is effectively transferred to modify the surface, impart stain resistance, and at the same time improve water repellency and oil repellency, and remove the attached dirt by wind and rain.
実施例 実施例1. 経糸、緯糸共にポリエステルマルチフィラメント750d/7
0fを用い、織密度…経:20本／吋、緯:21本／吋の平織組
織の織物を製織し、生機を185℃、30秒間で幅出し、ヒ
ートセットを行ない、下記組成の塩化ビニル経樹脂組成
物によりトッピング加工を両面に施し（カレンダ加工機
加工温度170℃）、180℃で焼付け加工を行なって、塩化
ビニル系樹脂加工布を得た。Examples Example 1. Polyester multifilament 750d / 7 for both warp and weft
Using 0f, weaving a plain weave fabric with a weaving density of 20 warps / inch, weft: 21 threads / inch, weaving the weaving machine at 185 ° C for 30 seconds, heat setting, and vinyl chloride of the following composition Both sides were subjected to topping processing with a resin composition (calendering machine processing temperature 170 ° C.) and baked at 180 ° C. to obtain a vinyl chloride resin processed cloth.
塩化ビニル系樹脂コンパウンド （日本カーバイド） 100重量部 DOP（可塑剤） 60 〃 炭酸カルシウム（充填材） 20 〃 ステアリン酸鉛（安定剤） 30 〃 顔料 10 〃 次に下記組成の防汚加工溶液を上記の塩化ビニル系樹脂
加工布の片面にナイフコータを用いてコーティング加工
（固形分400g/m2）を行なった。Vinyl chloride resin compound (Japan Carbide) 100 parts by weight DOP (plasticizer) 60 〃 calcium carbonate (filler) 20 〃 lead stearate (stabilizer) 30 〃 pigment 10 〃 Coating processing (solid content: 400 g / m 2 ) was performed on one surface of the vinyl chloride resin-treated cloth of 1. using a knife coater.
アクリル酸エステル系樹脂 （ラックスキン6018:セイコー化成） 50重量％ 弗素系グラフト樹脂 （アロンGF−300:東亜合成化学） ２ 〃 シリコン系グラフト樹脂 （アロンGS−30:東亜合成化学） 0.5重量％ カルボン酸型グラフト樹脂 （アロンGC−10:東亜合成化学） １ 〃 架橋剤（コロネートHL:大日本インキ） ５ 〃 メチルエチルケトン−トルエン 41.5〃 乾燥（120℃、１分）後、170℃で１分間熱処理を行なっ
た。Acrylic ester-based resin (Lackskin 6018: Seiko Kasei) 50% by weight Fluorine-based graft resin (Aron GF-300: Toa Gosei) 2〃 Silicon-based graft resin (Aron GS-30: Toa Gosei) 0.5% by weight Carvone Acid type graft resin (Aron GC-10: Toagosei Kagaku) 1〃 Crosslinking agent (Coronate HL: Dainippon Ink) 5〃 Methyl ethyl ketone-toluene 41.5〃 After drying (120 ℃, 1 minute), heat treatment at 170 ℃ for 1 minute I did.
得られた防汚加工布を、下記組成の汚れコンパウンド中
に投入し、３ケ月間、100回／日の撹拌を行なって汚れ
の状態および水洗後の状態を観察した。また前記コーテ
ィング後のウェルダ性および耐光性および防水性を評価
した。その結果を第１表に掲げた。The obtained antifouling-treated cloth was put into a stain compound having the following composition, and the mixture was stirred 100 times / day for 3 months to observe the stain state and the state after washing with water. In addition, the weldability, light resistance and waterproofness after the coating were evaluated. The results are listed in Table 1.
実施例2. 実施例1.と同様に加工して得た塩化ビニル系樹脂加工布
を、防汚加工の溶液組成を下記のとおり変更するほか
は、前記実施例1.と全く同様の方法、条件で防汚加工を
行ない、同様に評価した。その結果を第１表に示す。 Example 2.Vinyl chloride resin-treated cloth obtained by processing in the same manner as in Example 1, except that the solution composition for antifouling treatment is changed as follows, the same method as in Example 1 above, Antifouling treatment was performed under the conditions, and the same evaluation was performed. The results are shown in Table 1.
ウレタン系樹脂 （クリスボン8226:大日本インキ） 40 重量部 弗素系グラフト樹脂 （アロンGF−300:東亜合成化学） 0.8 〃 ジメチルホルムアミド 40 〃 メチルエチルケトン 15 〃 比較例1. 実施例1.と同様に加工して得た塩化ビニル系樹脂加工布
を、実施例1.と全く同様に各種性能を評価した。その結
果を第１表に示す。Urethane resin (Crisbon 8226: Dainippon Ink) 40 parts by weight Fluorine-based graft resin (Aron GF-300: Toagosei Kagaku) 0.8〃 Dimethylformamide 40〃 Methyl ethyl ketone 15〃 Comparative example 1. Processed in the same manner as in Example 1. The vinyl chloride resin-treated cloth thus obtained was evaluated for various performances in exactly the same manner as in Example 1. The results are shown in Table 1.
比較例2. 実施例1.と同様に加工して得た塩化ビニル系樹脂加工布
を、実施例1.で用いた防汚加工溶液の組成のうち、弗素
系グラフト樹脂およびシリコン系グラフト樹脂を添加し
ないほかは、全く同一の組成の溶液で実施例1.と同様の
方法、条件で加工し、同様に評価した。その結果を第１
表に示す。Comparative Example 2. A vinyl chloride resin-treated cloth obtained by processing in the same manner as in Example 1 was treated with a fluorine-based graft resin and a silicon-based graft resin in the composition of the antifouling processing solution used in Example 1. Except that it was not added, a solution having exactly the same composition was processed under the same method and conditions as in Example 1 and evaluated in the same manner. The result is first
Shown in the table.
比較例3.〜4. 実施例1.と同様に加工して得た塩化ビニル系樹脂加工布
を、防汚加工の溶液組成を下記のとおり変更するほか
は、前記実施例1.と全く同様の方法、条件で防汚加工を
行ない、同様に評価した。その結果を第１表に示す。Comparative Examples 3 to 4. The vinyl chloride resin-treated cloth obtained by processing in the same manner as in Example 1 was completely the same as in Example 1 except that the solution composition for antifouling treatment was changed as follows. The antifouling treatment was carried out according to the method and conditions described in 1 above and evaluated in the same manner. The results are shown in Table 1.
比較例3. アクリル酸エステル系樹脂 （ラックスキン6018:セイコー化成） 50 重量％ 弗素系グラフト樹脂 （アロンGF−300:東亜合成化学） 0.01 〃 カルボン酸系グラフト樹脂 （アロンGC−10:東亜合成化学） １ 〃 架橋剤（コロネートHL:大日本インキ） ５ 〃 メチルエチルケトン−トルエン 43.9 〃 比較例4. アクリル酸エステル系樹脂 （ラックスキン6018:セイコー化成） 50重量％ 弗素系グラフト樹脂 （アロンGF−300:東亜合成化学） ７ 〃 カルボン酸系グラフト樹脂 （アロンGC−10:東亜合成化学） １重量％ 架橋剤（コロネートHL:大日本インキ） ５ 〃 メチルエチルケトン−トルエン 37 〃 上記比較例4.では、防汚加工溶液の発泡が著しく、加工
が困難であった。Comparative Example 3. Acrylic ester-based resin (Lackskin 6018: Seiko Kasei) 50% by weight Fluorine-based graft resin (Aron GF-300: Toa Gosei) 0.01 〃 Carboxylic acid-based graft resin (Aron GC-10: Toa Gosei) ) 1 〃 Cross-linking agent (Coronate HL: Dainippon Ink) 5 〃 Methyl ethyl ketone-toluene 43.9 〃 Comparative example 4. Acrylic ester resin (Lackskin 6018: Seiko Kasei) 50% by weight Fluorine-based graft resin (Aron GF-300: Toa Gosei Co., Ltd. 7 〃 Carboxylic acid type graft resin (Aron GC-10: Toa Gosei Kagaku) 1% by weight Crosslinking agent (Coronate HL: Dainippon Ink) 5 〃 Methyl ethyl ketone-toluene 37 〃 Antifouling in Comparative Example 4 above. Foaming of the processing solution was remarkable and processing was difficult.
第１表に示した結果から明らかなごとく、各実施例で得
られた防汚加工布は、比較例4.を除く各比較例で得られ
た加工布に比べて汚れの付着も少なく、その除去も容易
であり、高耐水圧で耐光性が良く、ウエルダ性を有して
いた。比較例4.で得た加工布は耐汚染性および他の性能
は良好であるが、前記のごとく防汚加工溶液の発泡が著
しく、加工が困難であった。 As is clear from the results shown in Table 1, the antifouling processed cloths obtained in the respective examples have less stain adhesion than the processed cloths obtained in the respective comparative examples except Comparative Example 4. It was easy to remove, had high water pressure resistance, good light resistance, and had weldability. The processed cloth obtained in Comparative Example 4 had good stain resistance and other performances, but as described above, the foaming of the antifouling processing solution was remarkable and the processing was difficult.
発明の効果 本発明により、塩化ビニル系樹脂加工布に対して、屋外
に長期間曝露しても汚れの付着が少なく、しかも雨水等
によって除去されやすいという、すぐれた防汚性を付与
することができ、しかも塩化ビニル系樹脂表面に形成さ
れる皮膜の接着性が良好で剥離を生じることもなく、耐
久性のある防汚性が与えられ、得られた防汚加工布は、
トラックシート、野積シート、テント、簡易ハウス等の
多岐にわたる用途に適用することができる。EFFECTS OF THE INVENTION According to the present invention, it is possible to impart excellent antifouling property to a vinyl chloride resin-processed cloth, which has less dirt attached even when exposed outdoors for a long time and is easily removed by rainwater or the like. In addition, the film formed on the surface of the vinyl chloride resin has good adhesiveness and does not peel off, and is provided with durable antifouling properties.
It can be applied to various uses such as truck seats, open-air seats, tents, and simple houses.
Claims (1)
る樹脂加工を施した後、少なくとも片面に、溶剤可溶型
のアクリル酸エステル系樹脂およびウレタン系樹脂の少
なくともいずれかを20〜50重量％と弗素系グラフト樹脂
およびシリコン系グラフト樹脂の少なくともいずれかを
0.02〜５重量％含有する溶液を、固形分として３〜50g/
m2塗布し、加熱乾燥することを特徴とする塩化ビニル系
樹脂加工布の防汚加工方法。1. A fiber cloth is treated with a resin containing a vinyl chloride resin as a main component, and then at least one surface thereof is coated with at least one of a solvent-soluble acrylic ester resin and a urethane resin in an amount of 20 to 50. % By weight and at least one of fluorine-based graft resin and silicon-based graft resin
A solution containing 0.02 to 5% by weight is used as a solid content of 3 to 50 g /
A method for antifouling a vinyl chloride resin-treated cloth, which comprises applying m 2 and heating and drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61132054A JPH0730516B2 (en) | 1986-06-06 | 1986-06-06 | Antifouling method for vinyl chloride resin cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61132054A JPH0730516B2 (en) | 1986-06-06 | 1986-06-06 | Antifouling method for vinyl chloride resin cloth |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62289680A JPS62289680A (en) | 1987-12-16 |
| JPH0730516B2 true JPH0730516B2 (en) | 1995-04-05 |
Family
ID=15072442
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61132054A Expired - Lifetime JPH0730516B2 (en) | 1986-06-06 | 1986-06-06 | Antifouling method for vinyl chloride resin cloth |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0730516B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5544033B1 (en) * | 2013-03-19 | 2014-07-09 | 東洋紡株式会社 | Resin coated nonwoven fabric |
| JP7150323B2 (en) * | 2018-11-15 | 2022-10-11 | 平岡織染株式会社 | transparent flexible sheet |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5844789B2 (en) * | 1980-06-05 | 1983-10-05 | 平岡織染株式会社 | Method for manufacturing non-breathable waterproof fabric |
-
1986
- 1986-06-06 JP JP61132054A patent/JPH0730516B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62289680A (en) | 1987-12-16 |
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