JPH07291732A - Polycrystalline cubic boron nitride sintered compact and use thereof - Google Patents

Abstract

PURPOSE:To obtain a polycrystalline cBN sintered compact, abrasive particles, a cutting tool and a sliding material each excellent in strength and wear resistance and having a long service life and high precision. CONSTITUTION:This polycrystalline cBN sintered compact has <=10ppm Al content. Each of abrasive particle, a cutting tool and a sliding material is made of this sintered compact.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a polycrystalline cubic boron nitride (polycrystalline cBN) sintered body and its use. The fields to which the polycrystalline cBN sintered body of the present invention is applied include metal-bonded grindstones for heavy grinding or high-speed grinding, grinding wheels such as electrodeposition grindstones, vitrified grindstones, cutting tools for high-speed cutting, and wear resistance. Are required for the sliding materials.

[0002]

2. Description of the Related Art cBN, which is a high-pressure phase of boron nitride, has hardness and thermal conductivity second only to diamond, and has a characteristic not present in diamond unless it reacts with an iron-based metal.
The utilization of iron-based metal as abrasive grains and cutting tools is being promoted.

In recent years, machining has tended to be labor-saving and unmanned. Heavy grinding, high-speed grinding, and high-speed cutting are used as the concrete methods, but the tool material itself has high strength and wear resistance because a heavy load is applied to the tool under such severe machining conditions. Is required.

[0004] For example, in grinding with a grindstone, a large load is applied to the abrasive grain portion, and therefore high-strength abrasive grains are required. A polycrystalline type is known as one of the high-strength cBN abrasive grains, and a part thereof is already commercially available. Polycrystalline type abrasive grains have a polycrystalline structure in which fine crystal grains are firmly bonded to each other, so that single particles cause major destruction such as cleavage like single crystal type abrasive grains composed of single crystals. It shows high strength. Polycrystalline abrasive grain is Japanese Examined Sho 63-444
As described in Japanese Patent Publication No. 17, unlike a single crystal type synthesized by using a catalyst, a sintered body obtained by a non-catalyst direct conversion method without using a catalyst is crushed to a desired particle size. Can be obtained by However, even if the polycrystalline abrasive grains obtained in this way are actually used as a grindstone under severe conditions such as heavy grinding and high-speed grinding, some of the abrasive grains on the surface of the grindstone will be destroyed or worn out. However, since the surface of the processed product becomes rough and the sharpness of the processed product deteriorates, there are problems such as frequent dressing and truing.

[0005]

SUMMARY OF THE INVENTION An object of the present invention is to provide a polycrystalline cBN sintered material which is a tool material having high strength and high wear resistance capable of withstanding severe working conditions such as heavy grinding, high speed grinding and high speed cutting. To provide a union. Another object of the present invention is to provide an abrasive grain, a cutting tool, and a sliding material that have high strength and excellent wear resistance. The present inventors have completed the present invention by finding out the following matters as a result of various studies for achieving the above object.

(1) As a result of observing individual abrasive grains after producing metal bond grindstones using various abrasive grains having different aluminum contents, a large number of cracks are generated in the abrasive grains having a large aluminum content. . (2) As a result of observing the state of each abrasive grain protruding from the surface of the stone before and after grinding by actually performing heavy grinding with a stone using various abrasive grains with different aluminum contents, the aluminum content is high. The surface of the abrasive grains is significantly worn, and the abrasive grains are liable to be greatly destroyed, and easily fall off from the surface of the grindstone during grinding. On the other hand, in the case of a grindstone with a small aluminum content, especially with abrasive particles of 10 PPM or less, it is difficult for such abrasive particles to be worn away or destroyed, and the life of the grindstone is significantly extended. Becomes smaller. (3) The same test was performed on the cutting tool and the sliding material, and as a result, the polycrystalline c with an aluminum content of 10 PPM or less was used.
Those made of BN sintered body have significantly better wear resistance than conventional products. (4) Polycrystalline cB with aluminum content of 10PPM or less
The N sintered body can be synthesized by devising the synthesis conditions in the catalyst-free direct conversion method.

[0007]

Means for Solving the Problems That is, the present invention comprises a polycrystalline cBN sintered body having an aluminum content of 10 PPM or less, and this polycrystalline cBN sintered body. Abrasive grains, cutting tools, and sliding materials.

The present invention will be described in more detail below.

The amount of aluminum contained in the polycrystalline cBN sintered body can be measured by various methods. For example, after removing impurities adhering to the surface of the sintered body by acid treatment, washing with pure water, etc., melting and decomposing treatment with sodium carbonate, plasma emission spectroscopy widely used as a quantitative analysis method for trace metal impurities, etc. Can be quantified with.

In the present invention, the amount of aluminum contained in the polycrystalline cBN sintered body is defined as 10 PPM or less.
This is because if it exceeds 10 PPM, the toughness of the polycrystalline cBN sintered body is remarkably lowered, and its wear resistance is remarkably lowered when it is used as a tool or a sliding material.

The polycrystalline cBN sintered body of the present invention is synthesized by using the non-catalyst direct conversion method as a basic technique and precisely controlling the raw material and the reaction chamber for generating high temperature / high pressure as described below. You can

The basic technique of the non-catalytic direct conversion method is widely known. For example, as described in Japanese Patent Publication No. 63-394, a high temperature at which cBN is thermodynamically stable when cBN is thermodynamically stable. / There is a method of processing under high pressure.

In the present invention, in the basic technique of such a non-catalytic direct conversion method, a high-purity material containing no aluminum is used as a raw material and a constituent material of the reaction chamber and its peripheral portion. If aluminum is contained in the raw materials and the constituent materials of the reaction chamber and its peripheral portion, polycrystalline type c
Aluminum diffuses inside the BN sintered body and is taken in as an impurity.

The raw material used in the present invention is high-purity low-pressure phase boron nitride such as pyrolytic boron nitride, and its aluminum content is preferably 1 PPM or less. Further, in order to prevent contamination during the high temperature / high pressure treatment process, it is preferable to wrap the raw material in a metal foil such as high-purity tantalum that does not react with BN and becomes a getter of impurities when the raw material is filled. .

As the material of the reaction chamber and its peripheral portion, a high-purity material containing no aluminum is used. That is, it is preferable to use high-purity carbon of 99.9% or more of the semiconductor grade as the heater for heating the reaction chamber. Further, a sleeve that does not contain aluminum is used as a sleeve positioned between the outer side of the carbon heater and the gasket. If the sleeve contains a large amount of aluminum, the aluminum easily diffuses and permeates through carbon, which is the material of the reaction chamber, at high temperature, and contaminates the raw material inside the reaction chamber and the generated cBN.

Conventionally, sleeves are made of natural minerals such as pyrophyllite, talc, burned products thereof, and N.
A molded body of aCl powder is used, but since these natural minerals contain aluminum of 100 PPM or more, they are unsuitable for the present invention. In the present invention, it is preferable that the sleeve is made of a material having an aluminum content of 8 PPM or less, for example, a molded body of high-purity pyrolytic boron nitride powder.

As a method for producing abrasive grains from the polycrystalline cBN sintered body of the present invention, the polycrystalline cBN sintered body is pulverized.
There is a method of classifying and obtaining a desired particle size. A general crusher such as a roll crusher may be used for crushing, and a sieve may be used for classification. Particle size is JIS B
4130, and one example is 80/1
00, 100/120 mesh, etc.

As a method for obtaining a cutting tool from the polycrystalline cBN sintered body of the present invention, a desired shape is cut out from the polycrystalline cBN sintered body by machining, and it is adhered to a pedestal with a brazing material or the like. Then, there is a method of making a tool tip for a cutting tool. A diamond tool may be used for machining, and a titanium-based brazing material generally used as a brazing material for diamond or cBN is used for brazing.

As a method of obtaining a sliding material from the polycrystalline cBN sintered body of the present invention, there is a method of processing the polycrystalline cBN sintered body into a desired shape.

[0020]

The reason why the polycrystalline cBN sintered body of the present invention and the abrasive grains, cutting tools, and sliding materials using the same are high in strength and excellent in wear resistance are as follows. In the case where the polycrystalline cBN sintered body of the present invention having a very small amount is exposed to high temperatures, its aluminum is inferior to the polycrystalline cBN sintered body in hardness, strength and density.
Since it does not function as a catalyst that transfers to hexagonal BN, which is a low-pressure phase, it does not transfer to it, and polycrystalline cBN still remains.
It is considered that the characteristics of the sintered body are retained.

That is, when producing a metal bond grindstone, a vitrified grindstone, etc., it is necessary to mold at a high temperature. Also, when manufacturing a cutting tool, it is exposed to a considerably high temperature during machining and brazing.

During grinding or cutting, a large amount of friction is generated between the abrasive grains or the cutting tool and the work piece, and grinding heat or cutting heat is generated. Further, frictional heat is generated in the sliding material. It is said that the abrasive grains on the surface of the grindstone and the cutting edge of the cutting tool, which are involved in the grinding, also reach a high temperature of 1000 ° C. or higher due to the generation of the grinding heat and the cutting heat. cBN is an unstable substance under normal pressure, and when it is treated at a high temperature of over 1000 ° C., it transforms to a low pressure phase of hexagonal BN. On the other hand, it is known that when a low-pressure phase BN is transferred to cBN under ultrahigh pressure and high temperature, the transfer is remarkably promoted by using a catalyst such as aluminum or its nitride. As a result, it is considered that when cBN is transformed into hexagonal BN, which is a low pressure phase, under normal pressure and high temperature, aluminum and its nitride function as a catalyst to promote the transformation.

Therefore, when manufacturing a grindstone or a cutting tool,
When a polycrystalline cBN sintered body is exposed to high temperatures, such as when it is actually ground or cut as a tool, those containing a large amount of aluminum are hexagonal, which is a low-pressure phase compared to those not containing it. It becomes easy to transfer to BN. Unlike cBN, hexagonal BN, which is a low-pressure phase, has low hardness and strength, and its density is also low. Therefore, the transition to it reduces the strength and wear resistance of the polycrystalline cBN sintered body. However, in the polycrystalline cBN sintered body of the present invention, the transition can be significantly prevented.

Further, if there is a location where aluminum impurities are segregated inside the polycrystalline cBN sintered body, it is preferentially transformed to hexagonal BN, and volume expansion occurs due to local density decrease, causing cracking. Although it is the starting point, it does not exist in the polycrystalline cBN sintered body of the present invention.

[0025]

EXAMPLES Next, the present invention will be described more specifically by way of Examples and Comparative Examples.

Examples 1 to 3 Comparative Example 1 Commercially available pyrolytic boron nitride plates having various aluminum contents shown in Table 1 were obtained and used as a raw material for polycrystalline cBN.
A sintered body was synthesized.

That is, 20 discs having an outer diameter of 30 mm and a thickness of 2 mm were cut out from the raw material pyrolytic boron nitride plate and stacked, then wrapped with a metal foil of tantalum and filled in a carbon tube. This carbon tube functions as a heater that also serves as a reaction chamber and is 99.9% of semiconductor grade.
It is made of the above high-purity carbon. On the other hand, a molded body of pyrolytic boron nitride powder having an aluminum content of 1 PPM was arranged as a sleeve between the outer side of the carbon tube and the solid gasket. The inner diameter and outer diameter of the sleeve are 34 mm and 50 mm, respectively. These were loaded into a flat belt type ultra-high pressure and high temperature generator with an inner diameter of 60 mm, and the temperature was 2100 ° C.
A polycrystalline cBN sintered body was synthesized by a non-catalytic direct conversion method by treating for 120 minutes under a pressure of 7.7 GPa.

The obtained polycrystalline cBN sintered body was crushed with a roll crusher and classified to separate 60/80 mesh abrasive grains. 1 g of this abrasive grain was sampled by the method of JIS R6003, impurities on the surface of the abrasive grain were removed by acid treatment and pure water washing, and then alkali melting treatment with sodium carbonate was performed to determine the aluminum content by plasma emission spectroscopy. It was measured.

Then, using 100 carats of the abrasive grains obtained in the above Examples and Comparative Examples, a diameter of 200 mm, a thickness of 10 mm,
A vitrified bond grindstone with a concentration of 100 was prepared, and a test by the planar plunge cut method was performed for 60 minutes, and the grindstone wear amount and the surface roughness of the work piece obtained in the grinding test were measured. The results are shown in Table 1. The work material used in the test was bearing steel SUJ2, and the grinding conditions were grinding wheel peripheral speed 36
00m / min, Work material feed rate 9m / min, Grinding wheel depth 15μm
Is.

[0030]

[Table 1]

On the other hand, as for the cutting tool and the sliding material, as a result of testing the strength and the wear resistance, the cutting tool and the sliding material made of the polycrystalline cBN sintered body of the present invention were the same as in the case of the abrasive grains. The performance was remarkably superior to that of the one formed of the polycrystalline cBN sintered body of Comparative Example 1.

[0032]

According to the present invention, it is possible to obtain a polycrystal type cBN sintered body, an abrasive grain, a cutting tool, and a sliding material which are excellent in strength and wear resistance and have a long life and high accuracy.

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁶ Identification code Internal reference number FI technical display location C09K 3/14 550 DF 16C 33/24 A 6814-3J

Claims (4)

[Claims] 1. A polycrystalline cubic boron nitride sintered body having an aluminum content of 10 PPM or less. 2. An abrasive grain comprising the polycrystalline cubic boron nitride sintered body according to claim 1. 3. A cutting tool comprising the polycrystalline cubic boron nitride sintered body according to claim 1. 4. A sliding material comprising the polycrystalline cubic boron nitride sintered body according to claim 1.