JPH07249502A - Linear resistor - Google Patents

Linear resistor

Info

Publication number
JPH07249502A
JPH07249502A JP6039434A JP3943494A JPH07249502A JP H07249502 A JPH07249502 A JP H07249502A JP 6039434 A JP6039434 A JP 6039434A JP 3943494 A JP3943494 A JP 3943494A JP H07249502 A JPH07249502 A JP H07249502A
Authority
JP
Japan
Prior art keywords
resistor
weight
sintered body
clay
metal boride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6039434A
Other languages
Japanese (ja)
Inventor
Moritaka Shoji
守孝 庄司
Seiichi Yamada
誠一 山田
Shigeru Tanaka
田中  滋
Ken Takahashi
高橋  研
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP6039434A priority Critical patent/JPH07249502A/en
Publication of JPH07249502A publication Critical patent/JPH07249502A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To provide a linear resistor having a high stability and excellent linear current-voltage relations. CONSTITUTION:A linear resistor is composed of a sintered body 1 containing a metal boride by 4-40wt.%, clay by 20-70wt.%, insulating particles by 1.0-70wt.%, and a flux component by 0.1-20wt.% and electrodes 2 and 2' provided on facing surfaces of the sintered body 1 and is used for the closing resistor and neutral grounding resistor of a gas circuit breaker. This linear resistor has stability higher than ZnO-based resistors, carbon-based resistors, and metal boride-glass resistors, and has excellently linear current-voltage relation, and excellent temperature characteristic.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は電力機器、特に遮断器及
び変圧器における直線抵抗体に関する。
FIELD OF THE INVENTION The present invention relates to linear resistors in power equipment, especially circuit breakers and transformers.

【0002】[0002]

【従来の技術】従来の抵抗体は、特開昭56−4206号に記
載のような炭素系及び特開昭63−233502号に記載のよう
なZnO系が開示されていた。
2. Description of the Related Art As a conventional resistor, a carbon type as disclosed in JP-A-56-4206 and a ZnO type as disclosed in JP-A-63-233502 have been disclosed.

【0003】炭素系はAl23からなるマトリックス中
に炭素粉を分散させた構造を有する。この抵抗率は10
0〜1000Ωcmである。
The carbon system has a structure in which carbon powder is dispersed in a matrix made of Al 2 O 3 . This resistivity is 10
It is 0 to 1000 Ωcm.

【0004】他方、ZnO系はZnOを主成分として、
Al23,MgO,Y23,Sb23,SiO2 等を含む
結晶体である。この抵抗率も100〜1000Ωcmであ
って、適用機器によって使いわける。この系は、上記の
原料粉を混合後、有機バインダーを加えて造粒し、金型
で成形する。次いで、成形体を電気炉で焼成したあと、
相対する面に電極を付けて、抵抗体を作製する。
On the other hand, the ZnO-based materials are mainly composed of ZnO.
It is a crystal body containing Al 2 O 3 , MgO, Y 2 O 3 , Sb 2 O 3 , SiO 2 and the like. This resistivity is also 100 to 1000 Ωcm and can be used properly depending on the applied device. In this system, the above raw material powders are mixed, an organic binder is added, and the mixture is granulated and molded with a mold. Then, after firing the molded body in an electric furnace,
An electrode is attached to the opposing surfaces to produce a resistor.

【0005】なお、抵抗体として関連するものには、例
えば特公昭58−21402 号,特公昭59−51721号,特公平1
−147802号,特公平2−3524 号等が挙げられる。これは
厚膜組成物に関するもので、ガラスからなるマトリック
ス中に電気伝導性LaB6 を分散させた構造を有する。
更に、ZrB2 系を開示した特許には特開昭62−232901
号が挙げられる。これらの厚膜組成物は、アルミナ等の
基板上に導体ペーストと一緒にスクリーン印刷するため
に、有機ベヒクルを含有している。
[0005] Note that, as the related resistors, for example, Japanese Patent Publication No. 58-21402, Japanese Patent Publication No. 59-51721, and Japanese Patent Publication No.
-147802, Japanese Patent Publication No. 2-3524, and the like. This relates to a thick film composition and has a structure in which electrically conductive LaB 6 is dispersed in a glass matrix.
Further, a patent that discloses the ZrB 2 system is disclosed in Japanese Patent Laid-Open No. 232901/1987.
No. These thick film compositions contain an organic vehicle for screen printing with a conductor paste on a substrate such as alumina.

【0006】この回路基板の許容温度は高々150℃
で、電力機器のように大きなエネルギーが注入され、2
00℃以上に温度上昇する抵抗体としては用いられな
い。
The maximum allowable temperature of this circuit board is 150 ° C.
Then, a large amount of energy is injected like power equipment, and 2
It is not used as a resistor whose temperature rises above 00 ° C.

【0007】本発明者らは、温度特性,電流電圧特性及
び耐量を兼ね備えた新規な抵抗体を特開平5−41302号に
開示した。この抵抗体は金属ほう化物と非還元性ガラス
とからなる焼結体を用いるものである。
The present inventors have disclosed in Japanese Patent Laid-Open No. 5-41302 a new resistor having temperature characteristics, current-voltage characteristics and withstand capability. This resistor uses a sintered body made of metal boride and non-reducing glass.

【0008】[0008]

【発明が解決しようとする課題】電力用抵抗体は動作時
に大きなエネルギーが注入され、200℃まで温度上昇
する。この温度で抵抗値の低下が大きいと、過大電流が
流れ、抵抗体が破壊する。上記炭素系は抵抗値の温度係
数が負であるので、許容温度を低めに設定する必要があ
った。一方、ZnO系は電流電圧特性が悪い問題があっ
た。また、厚膜組成物は厚膜抵抗体に適用され、高エネ
ルギー容量の抵抗体としては考えられていない。
A large amount of energy is injected into the power resistor during operation, and the temperature rises to 200 ° C. If the resistance value greatly decreases at this temperature, an excessive current flows and the resistor is destroyed. Since the temperature coefficient of the resistance value of the carbon system is negative, it was necessary to set the allowable temperature to a low value. On the other hand, the ZnO system has a problem that the current-voltage characteristic is poor. Further, the thick film composition is applied to a thick film resistor and is not considered as a resistor having a high energy capacity.

【0009】金属ほう化物系抵抗体は、200℃まで抵
抗値がほとんど減少することがなく、且つ電流電圧特性
の直線性が優れた直線抵抗体であるが、ガラス量が多い
ために機械的及び熱的強度が低く、耐量を損なってい
る。特に、パルス耐量が悪く、高圧パルスを印加する
と、導電パスが破壊し、抵抗値が変動する。
The metal boride-based resistor is a linear resistor whose resistance value hardly decreases up to 200 ° C. and has excellent linearity of current-voltage characteristics. The thermal strength is low and the withstand capability is impaired. In particular, the pulse resistance is poor, and when a high voltage pulse is applied, the conductive path is broken and the resistance value fluctuates.

【0010】本発明の目的は、金属ほう化物系抵抗体の
温度特性及び電流電圧特性の直線性を損なわず、耐量が
優れた直線抵抗体を提供することにある。
An object of the present invention is to provide a linear resistor having an excellent withstanding capability without impairing the linearity of the temperature characteristic and the current-voltage characteristic of the metal boride type resistor.

【0011】[0011]

【課題を解決するための手段】上記目的を達成するため
に、本発明は金属ほう化物と粘土と絶縁性粒子と融剤成
分とを含有する焼結体と該焼結体の相対する面の電極と
からなることを特徴とする。特に、金属ほう化物は4〜
40重量%,粘土は20〜70重量%,絶縁性粒子は
1.0〜70重量%,融剤成分は0.1〜20重量%が望
ましい。
In order to achieve the above object, the present invention provides a sintered body containing a metal boride, clay, insulating particles, and a fluxing agent, and a surface of the sintered body facing each other. It is characterized by comprising an electrode. In particular, metal boride is 4 to
40% by weight, 20 to 70% by weight of clay, 1.0 to 70% by weight of insulating particles, and 0.1 to 20% by weight of flux component are desirable.

【0012】焼成温度は1000℃〜1400℃の範囲
が適当である。1000℃以下では焼結しない。一方、
1400℃以上では変形を起して望ましくない。
The firing temperature is suitably in the range of 1000 ° C to 1400 ° C. It does not sinter below 1000 ° C. on the other hand,
Above 1400 ° C, deformation occurs, which is not desirable.

【0013】図1は本発明の円柱型金属ほう化物系抵抗
体の正面図を示す。1は金属ほう化物系焼結体で、この
両面にアルミニウム電極2,2′が付けてある。図2は
本発明のドーナツ型金属ほう化物系抵抗体の正面図を示
す。3は金属ほう化物系焼結体、4,4′はアルミニウ
ム電極であるが、抵抗体の中心に孔5が設けてある。ま
た、金属ほう化物は、LaB6,ZrB2,MoB,Ti
2,VB2,NbB2,TaB2,CrB2,CaB6,W2
5 より選ばれた1種以上の粒子が望ましい。絶縁性粒
子は非還元性酸化物または窒化物、特にアルミナを用い
た。融剤成分は非還元性ガラス,長石,けい酸アルミニ
ウムより選ばれた1種以上が望ましい。
FIG. 1 is a front view of a cylindrical metal boride-based resistor according to the present invention. Reference numeral 1 is a metal boride-based sintered body, and aluminum electrodes 2 and 2'are attached to both surfaces thereof. FIG. 2 shows a front view of a donut type metal boride-based resistor of the present invention. Reference numeral 3 is a metal boride-based sintered body, and 4 and 4 ′ are aluminum electrodes, but a hole 5 is provided at the center of the resistor. Metal borides include LaB 6 , ZrB 2 , MoB and Ti.
B 2, VB 2, NbB 2 , TaB 2, CrB 2, CaB 6, W 2
One or more kinds of particles selected from B 5 are desirable. The insulating particles used non-reducing oxides or nitrides, especially alumina. The flux component is preferably at least one selected from non-reducing glass, feldspar, and aluminum silicate.

【0014】さらに本発明はこの直線抵抗体を用いてガ
ス遮断器及び中性点接地抵抗器を構成したものである。
Further, according to the present invention, a gas circuit breaker and a neutral point grounding resistor are constructed by using this linear resistor.

【0015】[0015]

【作用】金属ほう化物はLaB6,ZrB2,MoB,T
iB2,VB2,NbB2,TaB2,CrB2,CaB6,W2
5等の化合物である。これらの粒子は電気伝導性を持
たせるために、必須の成分である。特に、LaB6 を用
いた抵抗体は、電流電圧特性が優れている。金属ほう化
物は4〜40重量%が適量である。4.0 重量%以下で
は抵抗率が5000Ωcm以上になり、電力機器に適合し
ない。一方、40重量%以上では抵抗率が10Ωcm以下
になり、やはり電力機器に適合しない。抵抗率は金属ほ
う化物の粒径によっても異なる。粒径が大きいと抵抗率
は大きくなる。
[Function] Metal borides are LaB 6 , ZrB 2 , MoB, T
iB 2 , VB 2 , NbB 2 , TaB 2 , CrB 2 , CaB 6 , W 2
It is a compound such as B 5 . These particles are essential components in order to have electrical conductivity. In particular, the resistor using LaB 6 has excellent current-voltage characteristics. A suitable amount of metal boride is 4 to 40% by weight. If it is less than 4.0% by weight, the resistivity becomes more than 5000 Ωcm and it is not suitable for electric power equipment. On the other hand, when it is 40% by weight or more, the resistivity becomes 10 Ωcm or less, which is not suitable for electric power equipment. The resistivity also depends on the particle size of the metal boride. The larger the particle size, the higher the resistivity.

【0016】粘土は可塑性粉体で、成形を容易にし、且
つ高温に加熱して焼結し、強度を増大し、ひいては耐量
を増大するために添加する。粘土は20〜70重量%が
適量である。20重量%以下では耐量が下り、一方、7
0重量%以上では耐量が下り、且つ焼結性が劣化する。
Clay is a plastic powder and is added to facilitate molding and to sinter by heating to a high temperature to increase strength and, consequently, durability. A suitable amount of clay is 20 to 70% by weight. When the amount is 20% by weight or less, the withstand capacity decreases, while the value of 7
If it is 0% by weight or more, the withstand amount is lowered and the sinterability is deteriorated.

【0017】抵抗体の熱的特性を改善し、注入エネルギ
ーを増大するには、素子の比熱を増大するのが望まし
い。このために、比熱の大きい絶縁性粒子を添加する。
比熱の大きい絶縁性粒子は抵抗率1010Ωcm以上の非還
元性酸化物または窒化物である。非還元性酸化物は窒素
等の還元性雰囲気中で焼成しても変質しない成分であ
り、Al23,MgO,TiO2 等が含まれる。一方、
比熱が大きい窒化物はSi34,AlN等である。この
絶縁性粒子は1.0 〜70重量%が望ましい。1.0 重
量%以下では耐量の増大効果がない。一方、70重量%
以上では焼結性が悪くなる。
In order to improve the thermal characteristics of the resistor and increase the implantation energy, it is desirable to increase the specific heat of the device. Therefore, insulating particles having a large specific heat are added.
The insulating particles having a large specific heat are non-reducing oxides or nitrides having a resistivity of 10 10 Ωcm or more. The non-reducing oxide is a component that does not deteriorate even when fired in a reducing atmosphere such as nitrogen, and includes Al 2 O 3 , MgO, TiO 2, and the like. on the other hand,
The nitride having a large specific heat is Si 3 N 4 , AlN or the like. The insulating particles are preferably 1.0 to 70% by weight. If it is less than 1.0% by weight, there is no effect of increasing the durability. On the other hand, 70% by weight
Above, the sinterability becomes poor.

【0018】融剤成分は非還元性ガラス,長石,けい酸
アルミニウムその他の粉体である。非還元性ガラスは、
SiO2,B23のほか、適宜Al23,ZrO2,Ca
O等を含んでおり、窒素,アルゴン等の還元性ないし不
活性ガス中で加熱しても還元されないガラスである。長
石はガラス質を形成し、焼結体を緻密化する。融剤成分
は0.1 重量%以下では焼結性が悪い。一方、20重量
%以上では高圧パルス耐量が劣化する。
The flux component is non-reducing glass, feldspar, aluminum silicate and other powders. Non-reducing glass is
In addition to SiO 2 , B 2 O 3 , Al 2 O 3 , ZrO 2 , Ca as appropriate
It is a glass that contains O and the like and is not reduced even when heated in a reducing or inert gas such as nitrogen or argon. Feldspar forms glass and densifies the sintered body. If the flux component is less than 0.1% by weight, the sinterability is poor. On the other hand, when the content is 20% by weight or more, the high voltage pulse withstand capability deteriorates.

【0019】バルク型直線抵抗体は厚膜型直線抵抗体と
区別して、成形加工後焼成した塊状直線抵抗体である。
金属ほう化物は粘土からなるマトリックス中に分散した
構造を有する。金属ほう化物自体は正の抵抗温度係数を
有する導電粒子である。電力用抵抗体は動作時に大きな
エネルギーが注入され、200℃まで温度上昇する。タ
ンク中には接続部や絶縁物があるため、この温度以上は
許容されない。本発明のバルク型直線抵抗体における抵
抗値の温度係数は、温度200℃で−1×10-3〜+5×
10-3/℃範囲が達成され、温度上昇しても抵抗値はほ
とんど変わらない。
The bulk type linear resistor is a bulk linear resistor which is distinguished from the thick film type linear resistor by firing after molding.
Metal borides have a structure dispersed in a matrix of clay. The metal boride itself is a conductive particle having a positive temperature coefficient of resistance. A large amount of energy is injected into the power resistor during operation, and the temperature rises to 200 ° C. Due to the connections and insulators in the tank, no more than this temperature is allowed. The temperature coefficient of resistance in the bulk linear resistor of the present invention is -1 x 10 -3 to +5 x at a temperature of 200 ° C.
The range of 10 −3 / ° C. is achieved, and the resistance value hardly changes even when the temperature rises.

【0020】電流電圧特性は、ZnO系と比べて直線性
が優れる。
The current-voltage characteristic is excellent in linearity as compared with the ZnO type.

【0021】変圧器の中性点接地用抵抗器では数乃至数
十Aの電流を数十秒乃至数分間通電して、損傷するまで
の通電時間を調べる耐量テストがある。本発明の直線抵
抗体はZnO系と比べて通電時間ははるかに長い。この
場合、抵抗体の温度は300℃以上に上昇する。このと
きに電流が増加して、熱暴走しないことが必要なのであ
る。本発明の直線抵抗体は300℃まで昇温しても機能
が正常に保持される。
For the neutral point grounding resistor of a transformer, there is a withstand test in which a current of several to several tens of amperes is passed for several tens of seconds to several minutes to examine the energization time until damage. The linear resistor of the present invention has a much longer energization time than the ZnO type. In this case, the temperature of the resistor rises to 300 ° C or higher. At this time, it is necessary to increase the current and prevent thermal runaway. The function of the linear resistor of the present invention is normally maintained even if the temperature is raised to 300 ° C.

【0022】[0022]

【実施例】以下、本発明の実施例を説明する。EXAMPLES Examples of the present invention will be described below.

【0023】<実施例1>LaB6 :120g(12.
0重量%),水簸木節粘土490g(49.0重量
%),Al23350g(35.0重量%)及び福島長
石40g(4.0重量%)を雷かい機で混合した。La
6 には粒径1μmの粉体を用いた。これにポリビニル
アルコール水溶液を80cc加え、造粒した。これを直径
50mmの金型で成形した。この成形体を電気炉に入れ、
窒素雰囲気中1300℃の温度に4h保持し、焼成し
た。最後に、この焼結体の両面にアルミニウムを溶射し
た。この抵抗体は直径43mm,厚さ10mmであった。こ
の抵抗体の電気抵抗は35Ω(430Ωcm)であった。
[0023] <Example 1> LaB 6: 120g (12 .
0% by weight), 490 g (49.0% by weight) of elutriated kibushi clay, 350 g (35.0% by weight) of Al 2 O 3 and 40 g (4.0% by weight) of Fukushima feldspar were mixed with a lightning striker. La
A powder having a particle size of 1 μm was used as B 6 . To this, 80 cc of an aqueous polyvinyl alcohol solution was added and granulated. This was molded with a die having a diameter of 50 mm. Put this molded body in an electric furnace,
In a nitrogen atmosphere, the temperature was maintained at 1300 ° C. for 4 hours, and firing was performed. Finally, aluminum was sprayed on both surfaces of this sintered body. This resistor had a diameter of 43 mm and a thickness of 10 mm. The electric resistance of this resistor was 35Ω (430Ωcm).

【0024】図3は温度特性である。7は本発明のLa
6系抵抗体の曲線、8はLaB6−ガラス系抵抗体の曲
線、9は従来の炭素系抵抗体の曲線である。7のLaB
6 系は9の炭素系に優り、8のLaB6 −ガラス系並み
に昇温時の特性が良い。なお、10及び11は実施例2
及び3の試料の曲線である。
FIG. 3 shows temperature characteristics. 7 is La of the present invention
A curve of a B 6 type resistor, a curve 8 of a LaB 6 -glass type resistor, and a curve 9 of a conventional carbon type resistor. 7 LaB
The 6- system is superior to the 9-carbon system, and has the characteristics at the time of temperature rise as good as the LaB 6 -glass system of 8. In addition, 10 and 11 are Example 2
And curves of samples 3 and 3.

【0025】図4は抵抗値の電流密度依存性を示す図で
ある。本図は横軸に電流密度、縦軸に電気抵抗を目盛し
ている。7′は本発明のLaB6系、8′はLaB6−ガ
ラス系抵抗体の曲線、12は従来のZnO系抵抗体の曲
線である。7′のLaB6 系及び8′のLaB6 −ガラ
ス系は12のZnO系と比べて、直線性が優る。なお、
10′及び11′は実施例2及び3の試料の曲線であ
る。
FIG. 4 is a diagram showing the current density dependence of the resistance value. In this figure, the horizontal axis is the current density and the vertical axis is the electrical resistance. 7'is the LaB 6 series of the present invention, 8'is the curve of the LaB 6 -glass series resistor, and 12 is the curve of the conventional ZnO series resistor. The 7'LaB 6 system and the 8'LaB 6 -glass system are more linear than the 12 ZnO system. In addition,
10 'and 11' are curves of the samples of Examples 2 and 3.

【0026】図5はAC通電耐量である。抵抗体は、3
〜4Aの交流電流を通電すると、通電時間とともに30
0℃以上まで温度上昇し、最後に損傷する。図5は通電
時間による電流の変化を示したものである。7″は本発
明のLaB6系、8″はLaB6−ガラス系抵抗体の曲線、
12′は従来のZnO系抵抗体の曲線である。7″のL
aB6系は12′のZnO系より格段に通電時間が長
く、8″のLaB6−ガラス系よりも1.5 倍通電時間
が長い。なお、10″及び11″は実施例2及び3の試
料の曲線である。
FIG. 5 shows the AC current resistance. 3 resistors
When an AC current of ~ 4A is applied, it will increase to 30 with the energizing time.
The temperature rises above 0 ° C and finally damages. FIG. 5 shows a change in current depending on the energization time. 7 ″ is the LaB 6 series of the present invention, 8 ″ is the curve of the LaB 6 -glass series resistor,
12 'is a curve of a conventional ZnO-based resistor. 7 ″ L
The aB 6 system has a significantly longer energization time than the 12 'ZnO system, and a 1.5 times longer energization time than the 8 "LaB 6 -glass system. 10" and 11 "are the same as those in Examples 2 and 3. It is a curve of a sample.

【0027】<実施例2>LaB6 :120g(12.
0重量%),土岐口蛙目粘土600g(60.0重量
%)、Al23200g(20.0重量%)及び珪酸系
ガラス80g(8.0重量%)を雷かい機で混合し、実
施例1と同様にして抵抗体を作製した。焼成温度は11
50℃とした。この抵抗体の電気抵抗は29Ω(360
Ωcm)であった。本発明試料の温度特性,電流密度と抵
抗値との関係及びAC通電耐量を、それぞれ図3,4及
び5に併記した。10,10′及び10″は本発明試料
の曲線である。これらの特性は従来の炭素系及びZnO
系より優れている。
[0027] <Example 2> LaB 6: 120g (12 .
0% by weight), Tokiguchi Frogme clay 600 g (60.0% by weight), Al 2 O 3 200 g (20.0% by weight) and silicate glass 80 g (8.0% by weight) were mixed with a lightning machine. A resistor was prepared in the same manner as in Example 1. Firing temperature is 11
It was set to 50 ° C. The electric resistance of this resistor is 29Ω (360
Ωcm). The temperature characteristics, the relationship between the current density and the resistance value, and the AC current withstand capability of the samples of the present invention are also shown in FIGS. 3, 4 and 5, respectively. 10, 10 'and 10 "are the curves of the samples of the present invention. These characteristics are conventional carbon based and ZnO.
It is superior to the system.

【0028】<実施例3>ZrB2:180g(18.0
重量%),土岐口蛙目粘土620g(62.0重量
%),Al23150g(15.0重量%)及びAl2
3・3SiO2:50g(5.0 重量%)を雷かい機で混
合し、実施例1と同様にして抵抗体を作製した。焼成温
度は1350℃とした。この抵抗体の電気抵抗は28Ω
(350Ωcm)であった。
<Example 3> ZrB 2 : 180 g (18.0)
% By weight), Tokiguchi Frogme clay 620 g (62.0% by weight), Al 2 O 3 150 g (15.0% by weight) and Al 2 O
A resistor was prepared in the same manner as in Example 1 by mixing 50 g (5.0% by weight) of 3.3 SiO 2 with a lightning striker. The firing temperature was 1350 ° C. The electrical resistance of this resistor is 28Ω
(350 Ωcm).

【0029】本発明試料の温度特性,電流密度と抵抗値
との関係及びAC通電耐量を、それぞれ図3,図4及び
5に併記した。11,11′及び11″は本発明試料の
曲線である。これらの特性は従来の炭素系及びZnO系
より優れている。
The temperature characteristics, the relationship between the current density and the resistance value, and the AC current withstand capability of the samples of the present invention are also shown in FIGS. 3, 4 and 5, respectively. 11, 11 'and 11 "are curves of the samples of the present invention. These characteristics are superior to the conventional carbon-based and ZnO-based systems.

【0030】<実施例4>粒径1,4,10μmのLa
6及び粒径1μmのLaB6に10%の超微粉LaB6
を加えた混合粉の4種類のLaB6に、それぞれAl2
312.0重量%、福島長石15.0 重量%及び水簸木節
粘土を加え、雷かい機で混合し、実施例1と同様にして
抵抗体を作製した。焼成温度は1100〜1300℃と
した。
Example 4 La having a particle size of 1, 4, 10 μm
B 6 and LaB 6 having a particle size of 1 μm, 10% ultrafine LaB 6
Al 2 O was added to each of the four LaB 6 mixed powders
3 12.0% by weight, Fukushima feldspar 15.0% by weight, and elutriated kibushi clay were added and mixed by a thunderbolt machine to prepare a resistor in the same manner as in Example 1. The firing temperature was 1100 to 1300 ° C.

【0031】図6はLaB6 量による抵抗率の変化であ
る。14,15,16及び17は、それぞれ粒径1,
4,10μmのLaB6及び粒径1μmのLaB6に10
%の超微粉LaB6 を加えた混合粉を用いた試料の曲線
である。これらの曲線は、粒径が小さくなるほど抵抗率
は小さくなる。5000Ωcmの抵抗率は、17では4.0
重量%,14では10.0 重量%,15では20.0重
量%,16では27.0重量%で達成される。一方、1
0Ωcmの抵抗率は、17では7.5 重量%、14では1
5.0重量%,15では30.0重量%,16では40.
0 重量%で達成される。LaB6 量は4〜40重量%
が適量である。
FIG. 6 shows the change in resistivity with the amount of LaB 6 . 14, 15, 16 and 17 have particle sizes of 1 and 1, respectively.
The LaB 6 in the LaB 6 and particle size 1μm of 4,10Myuemu 10
5 is a curve of a sample using the mixed powder to which the ultrafine powder LaB 6 was added. In these curves, the smaller the particle size, the smaller the resistivity. The resistivity of 5000 Ωcm is 4.0 at 17
% By weight, 10.0 by 10% by weight, 15 by 20.0% by weight, and 16 by 27.0% by weight. On the other hand, 1
The resistivity of 0 Ωcm is 7.5% by weight for 17 and 1 for 14
5.0% by weight, 15: 30.0% by weight, 16: 40.
Achieved at 0% by weight. LaB 6 amount is 4 to 40% by weight
Is an appropriate amount.

【0032】<実施例5>粒径4μmのLaB6 ,Al
23及び福島長石に、水簸木節粘土量を変えて加え、雷
かい機で混合し、実施例1と同様にして抵抗体を作製し
た。焼成温度は1100〜1400℃とした。
Example 5 LaB 6 , Al having a particle size of 4 μm
2 O 3 and Fukushima feldspar were added at different amounts of elutriated wood knot clay and mixed with a thunder pad to prepare a resistor in the same manner as in Example 1. The firing temperature was 1100-1400 ° C.

【0033】図7は粘土量による累積注入エネルギーの
変化である。18はAC通電耐量試験から求めた累積注
入エネルギーである。一方、19はAC放電耐量試験か
ら求めた累積注入エネルギーである。AC放電耐量試験
は遮断器用抵抗体に適用する試験法で、継続時間10ms
の高圧AC波を1〜6波放電したときの抵抗体の損傷の
有無を調べ、且つ累積注入エネルギーを求める試験法で
ある。AC通電耐量試験から求めた累積注入エネルギー
は粘土量25重量%以下では耐量が下り、一方、70重
量%以上では焼結性が劣化するとともに耐量が下る。一
方、AC放電耐量試験から求めた累積注入エネルギーは
粘土量20重量%以下及び50重量%以上で耐量が下
る。
FIG. 7 shows a change in cumulative injection energy depending on the amount of clay. 18 is a cumulative injection energy obtained from the AC current resistance test. On the other hand, 19 is the cumulative injection energy obtained from the AC discharge withstanding test. The AC discharge withstand test is a test method applied to a resistor for a circuit breaker, with a duration of 10 ms.
Is a test method for investigating the presence or absence of damage to the resistor when discharging 1 to 6 high-voltage AC waves and determining the cumulative injection energy. With respect to the cumulative injection energy obtained from the AC energization resistance test, the resistance decreases when the amount of clay is 25% by weight or less, while the sinterability is deteriorated and the resistance decreases when it is 70% by weight or more. On the other hand, the cumulative injection energy obtained from the AC discharge withstand test decreases when the amount of clay is 20% by weight or less and 50% by weight or more.

【0034】<実施例6>粒径4μmのLaB6 ,水簸
木節粘土及び福島長石に、Al23量を変えて加え、雷
かい機で混合し、実施例1と同様にして抵抗体を作製し
た。焼成温度は1100〜1400℃とした。
<Example 6> LaB 6 having a particle size of 4 μm, elutriated kibushi clay and Fukushima feldspar were added at different amounts of Al 2 O 3 and mixed with a thunderbolt machine, and the same resistance as in Example 1 was applied. The body was made. The firing temperature was 1100-1400 ° C.

【0035】図8はAl23量による累積注入エネルギ
ーの変化である。18′はAC通電耐量試験から求めた
累積注入エネルギーで、19′はAC放電耐量試験から
求めた累積注入エネルギーである。AC通電耐量試験か
ら求めた累積注入エネルギーはAl231.0 〜50重
量%範囲で耐量が高い。一方、AC放電耐量試験から求
めた累積注入エネルギーはAl2330〜70重量%範
囲で耐量が高い。Al23は1.0 重量%以下では耐量
の増大効果はなく、一方70重量%以上では焼結性が劣
化するとともに耐量が下る。
FIG. 8 shows changes in the cumulative implantation energy depending on the amount of Al 2 O 3 . 18 'is a cumulative injection energy obtained from the AC withstand voltage test, and 19' is a cumulative injection energy obtained from the AC discharge withstand test. The cumulative implantation energy obtained from the AC energization withstanding test is high in the range of Al 2 O 3 1.0 to 50% by weight. On the other hand, the cumulative implantation energy obtained from the AC discharge withstand test has a high withstand amount in the range of 30 to 70% by weight of Al 2 O 3 . When Al 2 O 3 is 1.0% by weight or less, there is no effect of increasing the resistance, while when it is 70% by weight or more, the sinterability deteriorates and the resistance decreases.

【0036】<実施例7>粒径4μmのLaB6 ,水簸
木節粘土及びAl23に、福島長石量を変えて加え、雷
かい機で混合し、実施例1と同様にして抵抗体を作製し
た。焼成温度は1000〜1400℃とした。
[0036] <Example 7> LaB 6 particle size 4 [mu] m, elutriation kibushi clay and Al 2 O 3, was added by changing the Fukushima feldspar amount, were mixed in a lightning paddle machine, in the same manner as in Example 1 resistance The body was made. The firing temperature was 1000 to 1400 ° C.

【0037】図9は福島長石量による累積注入エネルギ
ーの変化である。18′はAC通電耐量試験から求めた
累積注入エネルギーで、19′はAC放電耐量試験から
求めた累積注入エネルギーである。AC通電耐量試験か
ら求めた累積注入エネルギーは福島長石0.1 〜20重
量%範囲で耐量が高い。一方、AC放電耐量試験から求
めた累積注入エネルギーは0.1 〜10重量%範囲で耐
量が高い。福島長石は0.1 重量%以下で焼結性が悪い
上に耐量が増大しない。一方、20重量%以上では耐量
が下る。
FIG. 9 shows changes in the cumulative implantation energy depending on the amount of Fukushima feldspar. 18 'is a cumulative injection energy obtained from the AC withstand voltage test, and 19' is a cumulative injection energy obtained from the AC discharge withstand test. The cumulative injection energy obtained from the AC current resistance test is high in the range of 0.1 to 20% by weight of Fukushima feldspar. On the other hand, the cumulative injection energy obtained from the AC discharge withstand test is high in the range of 0.1 to 10% by weight. Fukushima feldspar has a sinterability of less than 0.1% by weight and does not increase the withstand capacity. On the other hand, when the amount is 20% by weight or more, the withstand amount decreases.

【0038】<実施例8>図10は図2のドーナツ型抵
抗体をガス遮断器(GCB)投入抵抗用に応用したもの
である。これには、実施例1の工程で作製した抵抗率2
00Ωcmの抵抗体を適用している。組成にはLaB6
2.6,粘土25,Al2360.4 ,珪酸系ガラス2.
0(重量%)を用いた。21は抵抗体素子、22は絶縁
棒、23は絶縁筒、24は抵抗体、25は抵抗接点、2
6は主接点、27は開閉操作用ピストン、28は油ダッ
シュポット、29は空気タンク、30はブッシングであ
る。遮断抵抗は500Ωにした。
<Embodiment 8> FIG. 10 is an application of the doughnut-type resistor of FIG. 2 for a gas circuit breaker (GCB) closing resistance. This includes a resistivity of 2 produced in the process of Example 1.
A 00 Ωcm resistor is used. The composition LaB 6 1
2.6, clay 25, Al 2 O 3 60.4, silicate glass 2.
0 (% by weight) was used. 21 is a resistor element, 22 is an insulating rod, 23 is an insulating cylinder, 24 is a resistor, 25 is a resistance contact, 2
6 is a main contact, 27 is an opening / closing operation piston, 28 is an oil dash pot, 29 is an air tank, and 30 is a bushing. The breaking resistance was 500Ω.

【0039】遮断動作は、主接点26が開き、抵抗体
24に電流が流れ、抵抗接点25が開き、完了する。
一方、投入動作は、抵抗接点25が閉じ、抵抗体24
に電流が流れ、主接点26が閉じ、完了する。抵抗体
24は、主接点26を開いたとき、数十msのAC放電
電流が流れ、且つ過電圧を吸収する。
The breaking operation is completed when the main contact 26 opens, a current flows through the resistor 24, and the resistance contact 25 opens.
On the other hand, in the closing operation, the resistance contact 25 is closed and the resistor 24
A current flows through the main contact 26, and the main contact 26 is completed. When the main contact 26 is opened, the resistor 24 carries an AC discharge current of several tens of ms and absorbs an overvoltage.

【0040】ここに用いた本発明の抵抗体素子の比熱は
3.0J/cc・℃ 、単位体積当りの注入エネルギーは7
50J/ccで、従来の金属ほう化物−ガラス系の2.5
J/cc・℃、460J/ccを上回った。
The specific heat of the resistor element of the present invention used here is 3.0 J / cc · ° C., and the implantation energy per unit volume is 7.
50 J / cc, 2.5 of the conventional metal boride-glass system
J / cc · ℃, exceeded 460 J / cc.

【0041】本発明によれば耐量が大きいほか、抵抗値
の直線性及び温度特性が優れているため、従来の金属ほ
う化物−ガラス系を用いたガス遮断器と比べて、抵抗体
の個数を50%低減する。実施例で説明した数値を用い
ると、耐量が1.4 倍大きいために個数を70%低減,
高電流域での抵抗値が10%増大するために個数を10
%低減,高温での抵抗値が20%増大するために個数を
20%低減できる。 <実施例9>図11は図2のドーナツ型抵抗体を変圧器
の中性点接地抵抗器に応用したものである。これには、
実施例1の工程で作製した抵抗率430Ωcmの大型抵抗
体を適用している。組成にはLaB612.3,粘土5
5.0,Al2320.0,珪酸系ガラス12.7(重量
%)を用いた。21′は抵抗体素子、22′は絶縁棒、
30′はブッシング、35はタンク、36は接地点であ
る。
According to the present invention, the resistance is large and the linearity of the resistance value and the temperature characteristic are excellent. Therefore, the number of resistors is smaller than that of the conventional gas circuit breaker using a metal boride-glass system. 50% reduction. Using the numerical values described in the examples, the number of products is reduced by 70% because the withstand capacity is 1.4 times larger.
In order to increase the resistance value by 10% in the high current region, the number is 10
%, And the resistance value at high temperature increases by 20%, so the number can be reduced by 20%. <Embodiment 9> FIG. 11 is an application of the donut type resistor of FIG. 2 to a neutral point grounding resistor of a transformer. This includes
A large resistor having a resistivity of 430 Ωcm manufactured in the process of Example 1 is applied. The composition is LaB 6 12.3, clay 5
5.0, Al 2 O 3 20.0, and silicate glass 12.7 (wt%) were used. 21 'is a resistor element, 22' is an insulating rod,
30 'is a bushing, 35 is a tank, and 36 is a grounding point.

【0042】本発明によれば抵抗体の耐量,抵抗値の直
線性及び温度特性が優れているため、従来の金属ほう化
物−ガラス系を用いたガス遮断器と比べて、抵抗体の個
数を約50%低減する。実施例で説明した数値を用いる
と、耐量が1.5 倍大きいために個数を70%低減,高
温での抵抗値が20%増大するために個数を20%低減
できる。
According to the present invention, since the resistance of the resistor is excellent, the linearity of the resistance value and the temperature characteristic are excellent, the number of resistors is smaller than that of the conventional gas breaker using the metal boride-glass system. About 50% reduction. Using the numerical values described in the examples, the number can be reduced by 70% because the withstand capacity is 1.5 times larger, and the number can be reduced by 20% because the resistance value at high temperature is increased by 20%.

【0043】[0043]

【発明の効果】本発明はZnO系乃至炭素系と比べて、
耐量が極めて大きいのみならず、電流電圧特性の直線性
及び温度特性も優れているので、温度特性,電流電圧特
性及び耐量を兼ね備えた新規な抵抗体を提供できる効果
がある。更に、この抵抗体を応用して、中性点接地用抵
抗器及びガス遮断器用投入抵抗器を50%小型化でき、
抵抗体の個数を低減できる。
According to the present invention, compared with ZnO-based or carbon-based
Not only the withstand voltage is extremely large, but also the linearity of the current-voltage characteristic and the temperature characteristic are excellent. Therefore, there is an effect that a novel resistor having both the temperature characteristic, the current-voltage characteristic and the withstand voltage can be provided. Furthermore, by applying this resistor, the neutral point grounding resistor and the gas circuit breaker closing resistor can be downsized by 50%,
The number of resistors can be reduced.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の円柱型金属ほう化物系抵抗体の正面
図。
FIG. 1 is a front view of a cylindrical metal boride-based resistor of the present invention.

【図2】本発明のドーナツ型金属ほう化物系抵抗体の正
面図。
FIG. 2 is a front view of a toroidal metal boride-based resistor of the present invention.

【図3】温度特性図。FIG. 3 is a temperature characteristic diagram.

【図4】抵抗値の電流密度依存図。FIG. 4 is a current density dependence diagram of resistance values.

【図5】AC通電耐量変化図。FIG. 5 is a diagram showing changes in withstand current of AC energization.

【図6】本発明におけるLaB6 量による抵抗率の変化
図。
FIG. 6 is a diagram showing a change in resistivity according to the amount of LaB 6 in the present invention.

【図7】粘土量による累積注入エネルギーの変化図。FIG. 7 is a diagram showing a change in cumulative injection energy depending on the amount of clay.

【図8】Al23量による累積注入エネルギーの変化
図。
FIG. 8 is a diagram showing a change in cumulative implantation energy according to the amount of Al 2 O 3 .

【図9】累積注入エネルギーの変化図。FIG. 9 is a change diagram of accumulated implantation energy.

【図10】ドーナツ型金属ほう化物系抵抗体を用いたガ
ス遮断器用投入抵抗器。
FIG. 10 is a closing resistor for a gas circuit breaker using a donut type metal boride-based resistor.

【図11】ドーナツ型金属ほう化物系抵抗体を用いたS
6ガス絶縁中性点接地。
FIG. 11: S using a donut-shaped metal boride-based resistor
F 6 gas insulation neutral point grounding.

【符号の説明】[Explanation of symbols]

1…金属ほう化物系焼結体、2,2′…アルミニウム電
極、3…金属ほう化物系焼結体、4,4′…アルミニウ
ム電極、5…孔、7,7′,7″…本発明のLaB6
抵抗体の曲線、8,8′,8″…LaB6 −ガラス系抵
抗体の曲線、9…炭素系抵抗体の曲線、10,10′,
10″…本発明のLaB6 系抵抗体の曲線、11,1
1′,11″…ZrB2 系抵抗体の曲線、12,12′
…ZnO系抵抗体の曲線、14…粒径1μmの試料の曲
線、15…粒径4μmの試料の曲線、16…粒径10μ
mの試料の曲線、17…LaB6 超微粉を加えた試料の
曲線、18,18′,18″…AC通電耐量試験から求
めた累積注入エネルギー、19,19′,19″…AC
放電耐量試験から求めた累積注入エネルギー、21,2
1′…抵抗体、22…ブッシング、23,23′…絶縁
ロッド、24…コンデンサ、25…遮断部、26…油ダ
ッシュポット、27…開閉操作用ピストン、28…空気
タンク、29…ブッシング、30…タンク、31…接地
点。
1 ... Metal boride-based sintered body, 2, 2 '... Aluminum electrode, 3 ... Metal boride-based sintered body, 4, 4' ... Aluminum electrode, 5 ... Hole, 7, 7 ', 7 "... Present invention LaB 6 series resistor curve, 8, 8 ′, 8 ″ ... LaB 6 -glass series resistor curve, 9 ... Carbon series resistor curve 10, 10 ′,
10 ″ ... Curve of LaB 6 series resistor of the present invention, 11, 1
1 ', 11 "... Curve of ZrB 2 system resistor, 12, 12'
... curve of ZnO-based resistor, 14 ... curve of sample with particle size of 1 µm, 15 ... curve of sample with particle size of 4 µm, 16 ... particle size of 10 µm
m sample curve, 17 ... LaB 6 ultrafine powder sample curve, 18, 18 ', 18 "... AC cumulative injection energy obtained from AC current resistance test, 19, 19', 19" ... AC
Cumulative injection energy calculated from discharge withstand test, 21,2
1 '... Resistor, 22 ... Bushing, 23, 23' ... Insulating rod, 24 ... Capacitor, 25 ... Breaking part, 26 ... Oil dash pot, 27 ... Opening / closing piston, 28 ... Air tank, 29 ... Bushing, 30 ... tank, 31 ... grounding point.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 高橋 研 茨城県日立市大みか町七丁目1番1号 株 式会社日立製作所日立研究所内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Ken Takahashi 7-1, 1-1 Omika-cho, Hitachi-shi, Ibaraki Hitachi Ltd. Hitachi Research Laboratory

Claims (12)

【特許請求の範囲】[Claims] 【請求項1】金属ほう化物,粘土,絶縁性粒子及び融剤
成分を含有する焼結体を含むことを特徴とする直線抵抗
体。
1. A linear resistor comprising a sintered body containing a metal boride, clay, insulating particles and a flux component.
【請求項2】4〜40重量%の金属ほう化物と20〜7
0重量%の粘土と1.0 〜70重量%の絶縁性粒子と
0.1 〜20重量%の融剤成分を含有する焼結体を含む
ことを特徴とする直線抵抗体。
2. A boride of 4 to 40% by weight and 20 to 7
A linear resistor comprising a sintered body containing 0% by weight of clay, 1.0 to 70% by weight of insulating particles, and 0.1 to 20% by weight of a fluxing agent component.
【請求項3】金属ほう化物と粘土と絶縁性粒子と融剤成
分とを含有する焼結体と該焼結体の相対する面の電極と
からなることを特徴とする直線抵抗体。
3. A linear resistor comprising a sintered body containing a metal boride, clay, insulating particles and a flux component, and electrodes on opposite surfaces of the sintered body.
【請求項4】4〜40重量%の金属ほう化物と20〜7
0重量%の粘土と1.0 〜70重量%の絶縁性粒子と
0.1 〜20重量%の融剤成分を含有する焼結体と該焼
結体の相対する面の電極とからなることを特徴とする直
線抵抗体。
4. 4 to 40% by weight of metal boride and 20 to 7
It comprises a sintered body containing 0% by weight of clay, 1.0 to 70% by weight of insulating particles, and 0.1 to 20% by weight of a fluxing agent component, and electrodes on opposite surfaces of the sintered body. A linear resistor characterized by.
【請求項5】請求項1ないし4のいずれかに記載の前記
金属ほう化物はLaB6,ZrB2,MoB,TiB2
VB2,NbB2,TaB2,CrB2,CaB6,W25
より選ばれた1種以上の粒子であることを特徴とするバ
ルク型直線抵抗体。
5. The metal boride according to claim 1, which is LaB 6 , ZrB 2 , MoB, TiB 2 ,
VB 2 , NbB 2 , TaB 2 , CrB 2 , CaB 6 , W 2 B 5
A bulk type linear resistor, which is one or more kinds of particles selected from the following.
【請求項6】請求項1ないし4のいずれかに記載の前記
絶縁性粒子は非還元性酸化物または窒化物であることを
特徴とする直線抵抗体。
6. A linear resistor according to claim 1, wherein the insulating particles are non-reducing oxides or nitrides.
【請求項7】請求項1ないし4のいずれかに記載の前記
絶縁性粒子はアルミナであることを特徴とする直線抵抗
体。
7. A linear resistor characterized in that the insulating particles according to any one of claims 1 to 4 are alumina.
【請求項8】請求項1ないし4のいずれかに記載の前記
融剤成分は非還元性ガラス,長石,けい酸アルミニウム
より選ばれた1種以上であることを特徴とする直線抵抗
体。
8. A linear resistor, wherein the flux component according to any one of claims 1 to 4 is at least one selected from non-reducing glass, feldspar, and aluminum silicate.
【請求項9】タンクに収納された遮断部と投入抵抗器と
を含むガス遮断器において、投入抵抗器には4〜40重
量%の金属ほう化物と20〜50重量%の粘土と30〜
70重量%の絶縁性粒子と0.1 〜10重量%の融剤成
分を含有する焼結体を含むことを特徴とするガス遮断
器。
9. A gas circuit breaker including a breaker housed in a tank and a closing resistor, wherein the closing resistor has 4 to 40% by weight of metal boride, 20 to 50% by weight of clay and 30 to 30% by weight.
A gas circuit breaker comprising a sintered body containing 70% by weight of insulating particles and 0.1 to 10% by weight of a flux component.
【請求項10】タンクに収納された遮断部と投入抵抗器
とを含むガス遮断器において、投入抵抗器には4〜40
重量%の金属ほう化物と20〜50重量%の粘土と30
〜70重量%の絶縁性粒子と0.1 〜10重量%の融剤
成分を含有する焼結体と該焼結体の相対する面の電極と
からなる直線抵抗体を使用することを特徴とするガス遮
断器。
10. A gas circuit breaker including a circuit breaker housed in a tank and a closing resistor, wherein the closing resistor is 4-40.
Wt% metal boride and 20-50 wt% clay and 30
A linear resistor composed of a sintered body containing ˜70% by weight of insulating particles and 0.1˜10% by weight of a flux component, and electrodes on opposite surfaces of the sintered body is used. A gas circuit breaker.
【請求項11】タンクに収納された抵抗器を含む中性点
接地抵抗器において、抵抗器には4〜40重量%の金属
ほう化物と25〜70重量%の粘土と1.0 〜55重量
%の絶縁性粒子と0.1 〜20重量%の融剤成分を含有
する焼結体を含むことを特徴とする中性点接地抵抗器。
11. A neutral grounding resistor including a resistor housed in a tank, wherein the resistor comprises 4 to 40 wt% metal boride, 25 to 70 wt% clay and 1.0 to 55 wt%. % Of the insulating particles and 0.1 to 20% by weight of the sintered body containing the flux component, a neutral grounding resistor.
【請求項12】タンクに収納された抵抗器を含む中性点
接地抵抗器において、抵抗器には4〜40重量%の金属
ほう化物と25〜70重量%の粘土と1.0 〜55重量
%の絶縁性粒子と0.1 〜20重量%の融剤成分を含有
する焼結体と該焼結体の相対する面の電極とからなる直
線抵抗体を使用することを特徴とする中性点接地抵抗
器。
12. A neutral grounding resistor including a resistor housed in a tank, wherein the resistor comprises 4 to 40 wt% metal boride, 25 to 70 wt% clay and 1.0 to 55 wt%. % Of insulating particles and 0.1 to 20% by weight of a flux component, a linear resistor comprising a sintered body and electrodes on opposite surfaces of the sintered body is used. Point grounding resistor.
JP6039434A 1994-03-10 1994-03-10 Linear resistor Pending JPH07249502A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6039434A JPH07249502A (en) 1994-03-10 1994-03-10 Linear resistor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6039434A JPH07249502A (en) 1994-03-10 1994-03-10 Linear resistor

Publications (1)

Publication Number Publication Date
JPH07249502A true JPH07249502A (en) 1995-09-26

Family

ID=12552900

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6039434A Pending JPH07249502A (en) 1994-03-10 1994-03-10 Linear resistor

Country Status (1)

Country Link
JP (1) JPH07249502A (en)

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