JPH07230081A - Method for recovering glass substrate - Google Patents

Method for recovering glass substrate

Info

Publication number
JPH07230081A
JPH07230081A JP2022494A JP2022494A JPH07230081A JP H07230081 A JPH07230081 A JP H07230081A JP 2022494 A JP2022494 A JP 2022494A JP 2022494 A JP2022494 A JP 2022494A JP H07230081 A JPH07230081 A JP H07230081A
Authority
JP
Japan
Prior art keywords
color filter
glass substrate
substrate
black matrix
manufacturing process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2022494A
Other languages
Japanese (ja)
Inventor
Shuzo Imai
修三 今井
Masami Shiroyama
正己 白山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Inc
Original Assignee
Toppan Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toppan Printing Co Ltd filed Critical Toppan Printing Co Ltd
Priority to JP2022494A priority Critical patent/JPH07230081A/en
Publication of JPH07230081A publication Critical patent/JPH07230081A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C23/00Other surface treatment of glass not in the form of fibres or filaments
    • C03C23/0075Cleaning of glass

Landscapes

  • Liquid Crystal (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)
  • Optical Filters (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

PURPOSE:To recover a glass substrate formed with a black matrix and to reuse this substrate in a production stage by immersing the defective substrate of color filters into a specific aq. alkaline soln. and peeling color filter layers and overcoating layers. CONSTITUTION:The defective substrate of the color filters for liquid crystal displays, etc., generated in the production stage is immersed into a concd. sulfuric acid at need. The substrate is, thereafter immersed into the specific aq. alkaline soln. to peel the color filter layers and the overcoating layers. The glass substrate formed with the black matrix is recovered. This aq. alkaline soln. is prepd. by dissolving an alkyl diol [for example, propylene glycol (HO- CH2-C(-CH3)H-OH)] and glycol ether [for example, ethylene glycol monomethyl ether (CH3-O-CH2-OH)] and sodium hydroxide (NOH) in water and heating the soln.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、製造工程で発生した液
晶ディスプレイ用などのカラーフィルターの不良基板
の、カラーフィルター層とオーバーコート層とを剥離し
て、ブラックマトリックスを形成したガラス基板を回収
する、製造工程で再利用できるガラス基板の回収方法に
関するものである。
FIELD OF THE INVENTION The present invention collects a glass substrate having a black matrix formed by peeling off a color filter layer and an overcoat layer from a defective substrate for a color filter such as a liquid crystal display generated in a manufacturing process. The present invention relates to a method for recovering a glass substrate that can be reused in a manufacturing process.

【0002】[0002]

【従来の技術】現在の、例えば顔料分散法による液晶デ
ィスプレイ用などのカラーフィルター基板の、一般的な
製造工程については、ブラックマトリックスを形成し
たガラス基板の洗浄工程と、適宜の感光性樹脂に顔料
を分散した顔料分散レジストの塗布工程と、温風で顔
料分散レジスト塗布層を定着固化させるプリベーク工程
と、フォトマスクを用いて、例えばRedパターンを露
光現像するRedパターニング工程と、同様にから
を繰返す、例えばGreenパターニング工程と、また同
様にからを繰返す、例えばBlueパターニング工程
と、最終的な検査,修正工程とオーバーコート層の形
成工程とを経て、完成した液晶ディスプレイ用などのカ
ラーフィルター基板が、次工程の透明電極(ITO)層の
形成工程に供給されるものである。
2. Description of the Related Art At present, a general manufacturing process of a color filter substrate for a liquid crystal display, for example, by a pigment dispersion method, includes a washing process of a glass substrate on which a black matrix is formed and an appropriate photosensitive resin pigment. Steps of applying a pigment-dispersed resist having dispersed therein, a pre-baking step of fixing and solidifying the pigment-dispersed resist coating layer with warm air, a Red patterning step of exposing and developing, for example, a Red pattern using a photomask, and repeating the same steps. After the green patterning process, for example, the blue patterning process, the final patterning process, the repairing process, and the overcoat layer forming process, the completed color filter substrate for a liquid crystal display is completed. It is supplied to the next step of forming the transparent electrode (ITO) layer.

【0003】また現在の、例えば印刷法による液晶ディ
スプレイ用などのカラーフィルター基板の、一般的な製
造工程については、ブラックマトリックスを形成した
ガラス基板の洗浄工程と、適宜の印刷インキを用いた
凹版オフセット印刷法などの、例えばRedパターンの印
刷工程と、同様の、例えばGreenパターンの印刷工程
と、また同様の、例えばBlueパターンの印刷工程
と、温風でそれぞれの印刷インキ層を定着固化させる
ポストベーク工程と、最終的な検査,修正工程とオー
バーコート層の形成工程とを経て、完成した液晶ディス
プレイ用などのカラーフィルター基板が、同様に次工程
の透明電極(ITO)層の形成工程に供給されるものであ
る。
[0003] At present, for example, a general manufacturing process of a color filter substrate for a liquid crystal display by a printing method includes a cleaning process of a glass substrate on which a black matrix is formed and an intaglio offset using an appropriate printing ink. For example, a printing process such as a Red pattern printing process, a similar printing process such as a Green pattern printing process, and a similar printing process such as a Blue pattern printing process, and a post-baking process in which each printing ink layer is fixed and solidified with warm air. After the steps, the final inspection, the correction step and the overcoat layer forming step, the completed color filter substrate for liquid crystal display is similarly supplied to the next step of forming the transparent electrode (ITO) layer. It is something.

【0004】[0004]

【発明が解決しようとする課題】前述した、液晶ディス
プレイ用などのカラーフィルター基板の製造工程におい
ては、厳重に管理された無塵室内で慎重に製造されてい
るにもかかわらず、種々の原因によって、カラーフィル
ター基板の欠陥発生が避けられないものであって、最終
的なカラーフィルター基板の収率は、決して高いもので
はなかった。
In the above-described manufacturing process of the color filter substrate for liquid crystal displays, etc., due to various causes, despite being carefully manufactured in a tightly controlled dust-free room. The occurrence of defects in the color filter substrate is unavoidable, and the final yield of the color filter substrate was not high.

【0005】本発明は、製造工程で多量に発生して従来
は廃棄処分していた、液晶ディスプレイ用やプロジェク
ション用や撮像デバイス用などの、カラーフィルターの
不良基板の、カラーフィルター層とオーバーコート層と
を剥離して、ブラックマトリックスを形成したガラス基
板を回収する、製造工程で再利用できるガラス基板の回
収方法を提供するものである。
The present invention provides a color filter layer and an overcoat layer of a defective color filter substrate for a liquid crystal display, a projection, an image pickup device, etc., which was generated in a large amount in the manufacturing process and was conventionally discarded. The present invention provides a method for recovering a glass substrate on which a black matrix has been formed by recovering and removing the glass substrate, which can be reused in a manufacturing process.

【0006】[0006]

【課題を解決するための手段】本発明は、製造工程で発
生した液晶ディスプレイ用などのカラーフィルターの不
良基板を、必要に応じて濃硫酸に浸漬した後に、構造式
HO-R1-OH(式中のR1はCn2n(nは2〜6)を示
す)のアルキルジオールと、構造式R2-(O-CH2-C(-
3)H)n-OR4(式中のR2はアルキル基又はアリル基、
3はH又はメチル基、R4はH又はアルキル基又はアリ
ル基、nは正の整数を示す)のグリコールエーテルと、を
含有したアルカリ水溶液に浸漬して、カラーフィルター
層とオーバーコート層とを剥離して、ブラックマトリッ
クスを形成したガラス基板を回収する、製造工程で再利
用できるガラス基板の回収方法である。
According to the present invention, a defective substrate of a color filter such as for a liquid crystal display generated in a manufacturing process is immersed in concentrated sulfuric acid as needed, and then the structural formula HO-R 1 -OH ( In the formula, R 1 is an alkyl diol of C n H 2n (n is 2 to 6) and a structural formula R 2 — (O—CH 2 —C (—
R 3 ) H) n —OR 4 (wherein R 2 is an alkyl group or an allyl group,
R 3 is H or a methyl group, R 4 is H or an alkyl group or an allyl group, and n is a positive integer), and is immersed in an alkaline aqueous solution containing a color filter layer and an overcoat layer. Is a method of recovering a glass substrate on which a black matrix is formed by recovering the glass substrate, which can be reused in the manufacturing process.

【0007】本発明のガラス基板の回収方法における、
アルキルジオールとグリコールエーテルとを含有したア
ルカリ水溶液については、アルキルジオール(例えばプ
ロピレングリコール(HO-CH2-C(-CH3)H-OH))
の20〜30重量部と、グリコールエーテル(例えばエ
チレングリコールモノメチルエーテル(CH3-O-CH2-
CH2-OH))の5〜20重量部と、水酸化ナトリウム
(NaOH)の10〜20重量部とを、30〜65重量部
の水(H2O)に溶解して、55℃程度に加温したもので
ある。
In the glass substrate recovery method of the present invention,
For an alkaline aqueous solution containing an alkyl diol and a glycol ether, an alkyl diol (for example, propylene glycol (HO-CH 2 -C (-CH 3 ) H-OH))
20 to 30 parts by weight of glycol ether (eg ethylene glycol monomethyl ether (CH 3 —O—CH 2
CH 2 -OH)) and 20 parts by weight of sodium hydroxide
10 to 20 parts by weight of (NaOH) was dissolved in 30 to 65 parts by weight of water (H 2 O) and heated to about 55 ° C.

【0008】[0008]

【作用】本発明のガラス基板の回収方法においては、製
造工程で発生した液晶ディスプレイ用などのカラーフィ
ルターの不良基板を、前述したアルキルジオールとグリ
コールエーテルとを含有したアルカリ水溶液に、10〜
15分間程度浸漬することによって、ガラス基板と定着
固化させたカラーフィルター層との密着力及びこのカラ
ーフィルター層とオーバーコート層との密着力が低下し
て、それぞれ剥離するものであって、硼珪酸ガラス製の
ガラス基板に変質や損傷などを与えないで、支障なく製
造工程で再利用できる状態で、ブラックマトリックスを
形成したガラス基板を回収できるものである。
In the method for recovering a glass substrate of the present invention, a defective substrate for a color filter such as for a liquid crystal display generated in the manufacturing process is treated with an alkaline aqueous solution containing the above-mentioned alkyl diol and glycol ether for 10 to 10 times.
By soaking for about 15 minutes, the adhesion between the glass substrate and the fixed and solidified color filter layer and the adhesion between the color filter layer and the overcoat layer are reduced, and they are peeled off. The glass substrate on which the black matrix is formed can be recovered in a state in which the glass substrate made of glass is not deteriorated or damaged and can be reused in the manufacturing process without any trouble.

【0009】また、本発明のガラス基板の回収方法にお
いては、製造工程で発生した液晶ディスプレイ用などの
カラーフィルターの不良基板を、必要に応じて濃度98
%程度の濃硫酸に、5〜30分間浸漬することによっ
て、定着固化させたカラーフィルター層とオーバーコー
ト層との表面が粗化して、アルキルジオールとグリコー
ルエーテルとを含有したアルカリ水溶液の、それぞれの
密着力を低下させて剥離させる作用を容易にするもので
ある。
Further, in the glass substrate recovery method of the present invention, a defective substrate of a color filter for a liquid crystal display or the like generated in the manufacturing process may have a concentration of 98 if necessary.
% Of concentrated sulfuric acid, the surfaces of the color filter layer and the overcoat layer, which have been fixed and solidified, are roughened by immersing them in an alkaline aqueous solution containing an alkyl diol and a glycol ether. The adhesive force is reduced to facilitate the peeling action.

【0010】[0010]

【実施例】【Example】

<実施例1>アクリル樹脂系の顔料分散レジストを用い
て、顔料分散法によって製造した液晶ディスプレイ用の
カラーフィルター基板の、製造工程で発生した不良基板
を、濃度98%の濃硫酸(常温)に10分間浸漬した後
に、水洗して、55℃に加温した後述する構成の、アル
キルジオールとグリコールエーテルとを含有したアルカ
リ水溶液に10分間浸漬して、必要に応じて純水中で軽
くスポンジラビング(手こすり)して、アクリル樹脂系の
カラーフィルター層とアクリル樹脂系のオーバーコート
層とを剥離して、洗浄して乾燥させたところ、硼珪酸ガ
ラス製のガラス基板に変質や損傷などを全く与えない
で、支障なく製造工程で再利用できる状態で、ブラック
マトリックスを形成したガラス基板が回収できたもので
ある。
<Example 1> A defective substrate generated in the manufacturing process of a color filter substrate for a liquid crystal display manufactured by a pigment dispersion method using an acrylic resin-based pigment-dispersed resist was changed to 98% concentrated sulfuric acid (normal temperature). After soaking for 10 minutes, rinse with water, heat to 55 ° C., and soak for 10 minutes in an alkaline aqueous solution containing an alkyl diol and glycol ether, which will be described later, and lightly sponge rub in pure water as necessary. (Rubbing) to peel off the acrylic resin color filter layer and the acrylic resin overcoat layer, and after washing and drying, the glass substrate made of borosilicate glass did not show any deterioration or damage. The glass substrate on which the black matrix was formed could be recovered in a state where it could be reused in the manufacturing process without any problem without giving any problem.

【0011】本実施例の、アルキルジオールとグリコー
ルエーテルとを含有したアルカリ水溶液の構成は、プロ
ピレングリコール(HO-CH2-C(-CH3)H-OH))の
24重量部と、エチレングリコールモノメチルエーテル
(CH3-O-CH2-CH2-OH))の8重量部と、水酸化ナ
トリウム(NaOH)の12重量部とを、56重量部の水
(H2O)に溶解したものであった。
The composition of the alkaline aqueous solution containing the alkyl diol and the glycol ether in this example is 24 parts by weight of propylene glycol (HO-CH 2 -C (-CH 3 ) H-OH)) and ethylene glycol. Monomethyl ether
(CH 3 —O—CH 2 —CH 2 —OH)) 8 parts by weight, sodium hydroxide (NaOH) 12 parts by weight, and water 56 parts by weight.
It was dissolved in (H 2 O).

【0012】<実施例2>メラミン-エポキシ樹脂系の
印刷インキを用いて、印刷法によって製造したプロジェ
クション用のカラーフィルター基板の、製造工程で発生
した不良基板を、濃度98%の濃硫酸(常温)に20分間
浸漬した後に、水洗して、55℃に加温した実施例1と
同一構成の、アルキルジオールとグリコールエーテルと
を含有したアルカリ水溶液に15分間浸漬して、純水中
で軽くスポンジラビング(手こすり)して、メラミン-エ
ポキシ樹脂系のカラーフィルター層とアクリル樹脂系の
オーバーコート層とを剥離して、洗浄して乾燥させたと
ころ、実施例1と同様に、硼珪酸ガラス製のガラス基板
に変質や損傷などを全く与えないで、支障なく製造工程
で再利用できる状態で、ブラックマトリックスを形成し
たガラス基板が回収できたものである。
<Embodiment 2> A defective substrate generated in the manufacturing process of a projection color filter substrate manufactured by a printing method using a melamine-epoxy resin-based printing ink is replaced with concentrated sulfuric acid (concentration: 98%) at room temperature. ) For 20 minutes, then washed with water and heated to 55 ° C. for 15 minutes in an alkaline aqueous solution containing alkyl diol and glycol ether having the same structure as in Example 1, and lightly sponge in pure water. The melamine-epoxy resin-based color filter layer and the acrylic resin-based overcoat layer were peeled off by rubbing (rubbing), washed and dried. The glass substrate on which the black matrix is formed can be collected in a state where it can be reused in the manufacturing process without any problems without causing any deterioration or damage to the glass substrate. Those were.

【0013】[0013]

【発明の効果】以上、作用及び実施例に示すとおり、本
発明のガラス基板の回収方法においては、製造工程で発
生した液晶ディスプレイ用などのカラーフィルターの不
良基板を、必要に応じて濃硫酸に浸漬した後に、構造式
HO-R1-OH(式中のR1はCn2n(nは2〜6)を示
す)のアルキルジオールと、構造式R2-(O-CH2-C(-
3)H)n-OR4(式中のR2はアルキル基又はアリル基、
3はH又はメチル基、R4はH又はアルキル基又はアリ
ル基、nは正の整数を示す)のグリコールエーテルと、を
含有したアルカリ水溶液に、10〜15分間程度浸漬す
ることによって、カラーフィルター層とオーバーコート
層とを、それぞれの密着力を低下させて剥離して、硼珪
酸ガラス製のガラス基板に変質や損傷などを全く与えな
いで、支障なく製造工程で再利用できる状態で、ブラッ
クマトリックスを形成したガラス基板を回収できるもの
であって、原材料費(製品価格)の低減と資源の有効活用
とに寄与できるものである。
As described above, according to the operation and the embodiment, in the method for recovering the glass substrate of the present invention, the defective substrate of the color filter such as for the liquid crystal display generated in the manufacturing process is changed to concentrated sulfuric acid if necessary. After the immersion, an alkyl diol of the structural formula HO-R 1 -OH (wherein R 1 represents C n H 2n (n is 2 to 6)) and a structural formula R 2- (O-CH 2 -C (-
R 3 ) H) n —OR 4 (wherein R 2 is an alkyl group or an allyl group,
R 3 is H or a methyl group, R 4 is a H or an alkyl group or an allyl group, and n is a positive integer) glycol ether, and is immersed in an alkaline aqueous solution for about 10 to 15 minutes to obtain a color. The filter layer and the overcoat layer are peeled off by lowering their respective adhesive strengths, and the glass substrate made of borosilicate glass is not deteriorated or damaged at all, and can be reused in the manufacturing process without any trouble. The glass substrate on which the black matrix is formed can be recovered, and it can contribute to the reduction of raw material cost (product price) and effective use of resources.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 G02F 1/1335 500 G09F 9/30 376 7610−5G ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI Technical display location G02F 1/1335 500 G09F 9/30 376 7610-5G

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】製造工程で発生した液晶ディスプレイ用な
どのカラーフィルターの不良基板を、必要に応じて濃硫
酸に浸漬した後に、構造式HO-R1-OH(式中のR1
n 2n(nは2〜6)を示す)のアルキルジオールと、構
造式R2-(O-CH2-C(-R3)H)n-OR4(式中のR2はア
ルキル基又はアリル基、R3はH又はメチル基、R4はH又
はアルキル基又はアリル基、nは正の整数を示す)のグリ
コールエーテルと、を含有したアルカリ水溶液に浸漬し
て、カラーフィルター層とオーバーコート層とを剥離す
ることを特徴とする、ブラックマトリックスを形成した
ガラス基板の回収方法。
1. A liquid crystal display produced in a manufacturing process.
Defective substrate of which color filter, if necessary, concentrated sulfur
Structural formula HO-R after soaking in acid1-OH (R in the formula1Is
CnH 2n(n represents 2 to 6))
Model R2-(O-CH2-C (-R3) H)n-ORFour(R in the formula2A
Rukyl group or allyl group, R3Is H or a methyl group, RFourIs H
Is an alkyl group or an allyl group, and n is a positive integer)
Dipping in an alkaline aqueous solution containing
Peel off the color filter layer and the overcoat layer.
Formed a black matrix, characterized in that
Method of collecting glass substrates.
JP2022494A 1994-02-17 1994-02-17 Method for recovering glass substrate Pending JPH07230081A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2022494A JPH07230081A (en) 1994-02-17 1994-02-17 Method for recovering glass substrate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2022494A JPH07230081A (en) 1994-02-17 1994-02-17 Method for recovering glass substrate

Publications (1)

Publication Number Publication Date
JPH07230081A true JPH07230081A (en) 1995-08-29

Family

ID=12021204

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2022494A Pending JPH07230081A (en) 1994-02-17 1994-02-17 Method for recovering glass substrate

Country Status (1)

Country Link
JP (1) JPH07230081A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009041126A1 (en) * 2007-09-26 2009-04-02 Sharp Kabushiki Kaisha Method for manufacturing liquid crystal panel
JP2010015080A (en) * 2008-07-07 2010-01-21 Toppan Printing Co Ltd Method of regenerating glass substrate for color filter
WO2010016214A1 (en) * 2008-08-04 2010-02-11 凸版印刷株式会社 Apparatus for reclaiming glass substrate
KR20170125119A (en) * 2012-09-26 2017-11-13 다이니폰 인사츠 가부시키가이샤 Glass reprocessing method, remade glass substrate, and photo mask blank and photo mask employing same

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009041126A1 (en) * 2007-09-26 2009-04-02 Sharp Kabushiki Kaisha Method for manufacturing liquid crystal panel
US8134680B2 (en) 2007-09-26 2012-03-13 Sharp Kabushiki Kaisha Manufacturing method of liquid crystal panel
JP2010015080A (en) * 2008-07-07 2010-01-21 Toppan Printing Co Ltd Method of regenerating glass substrate for color filter
WO2010016214A1 (en) * 2008-08-04 2010-02-11 凸版印刷株式会社 Apparatus for reclaiming glass substrate
KR101243545B1 (en) * 2008-08-04 2013-03-20 도판 인사츠 가부시키가이샤 Apparatus for reclaiming glass substrate
JP5299428B2 (en) * 2008-08-04 2013-09-25 凸版印刷株式会社 Glass substrate recycling equipment
KR20170125119A (en) * 2012-09-26 2017-11-13 다이니폰 인사츠 가부시키가이샤 Glass reprocessing method, remade glass substrate, and photo mask blank and photo mask employing same
KR20180129996A (en) * 2012-09-26 2018-12-05 다이니폰 인사츠 가부시키가이샤 Glass reprocessing method, remade glass substrate, and photo mask blank and photo mask employing same

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