JPH0714862B2 - Effervescent bath agent - Google Patents
Effervescent bath agentInfo
- Publication number
- JPH0714862B2 JPH0714862B2 JP60235911A JP23591185A JPH0714862B2 JP H0714862 B2 JPH0714862 B2 JP H0714862B2 JP 60235911 A JP60235911 A JP 60235911A JP 23591185 A JP23591185 A JP 23591185A JP H0714862 B2 JPH0714862 B2 JP H0714862B2
- Authority
- JP
- Japan
- Prior art keywords
- component
- bath agent
- carbonate
- acid
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/22—Gas releasing
- A61K2800/222—Effervescent
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
Description
【発明の詳細な説明】 発明の分野 本発明は発泡浴剤、さらに詳しくは、発泡成分を保存安
定性を向上させた顆粒状の発泡浴剤に関する。Description: FIELD OF THE INVENTION The present invention relates to a foaming bath agent, and more particularly to a granular foaming bath agent having an improved foaming component with improved storage stability.
発明の背景 従来から、浴槽の湯に添加する浴剤の１つに、発泡性を
付与した発泡浴剤が知られている。このような浴剤に
は、発泡成分として、主に、有機酸成分と炭酸塩成分が
配合されており、浴槽の湯に添加したときに、水の存在
下で両成分が反応して炭酸ガスが生じ、それにより発泡
が起こるものである。ところが、この反応は、保存中の
浴剤の吸湿等によるわずかな水の存在下でも容易に進行
するため、発泡浴剤においては、発泡成分の保存安定性
を向上させることが非常に重要な問題となっている。BACKGROUND OF THE INVENTION Conventionally, a foaming bath agent having foamability is known as one of the bath agents added to hot water in a bathtub. Such a bath agent mainly contains an organic acid component and a carbonate component as foaming components. When added to hot water in a bath, both components react with each other in the presence of water to generate carbon dioxide gas. Occurs, which causes foaming. However, since this reaction easily proceeds even in the presence of a small amount of water due to moisture absorption of the bath agent during storage, in the foaming bath agent, it is a very important problem to improve the storage stability of the foaming component. Has become.
かくして、従来、発泡浴剤には粉末（特開昭−59−7061
0号）や顆粒（特開昭−48−52919号）のものも提案され
ているが、これらは表面積が大きく、そのため、吸湿性
が高くなり、発泡成分の保存安定性が悪くなる傾向にあ
り、主として、比較的吸湿性の低い、発泡成分の保存安
定性のより良好な錠剤形のものが発泡浴剤として実用に
供されている。Thus, conventionally, a foaming bath agent has been powdered (JP-A-59-7061).
No. 0) and granules (JP-A-48-52919) have also been proposed, but these have a large surface area, so that they tend to have high hygroscopicity and poor storage stability of the foaming component. Mainly, tablets having relatively low hygroscopicity and having better storage stability of the foaming component are practically used as a foaming bath agent.
このような事情にかんがみ、本発明者らは、使用上便利
な顆粒状であって、かつ、発泡成分の保存安定性にすぐ
れた発泡浴剤を得るべく鋭意検討を重ねた。その結果、
浴剤成分で有機酸成分と炭酸塩成分を隔離した多層構成
の顆粒とすることにより、その目的が達成できることを
知り、本発明を完成するにいたった。In view of such circumstances, the inventors of the present invention have earnestly studied to obtain a foaming bath agent which is convenient for use and has a granular form and which is excellent in storage stability of the foaming component. as a result,
The inventors have found that the objective can be achieved by using granules having a multi-layered structure in which an organic acid component and a carbonate component are separated by a bath agent component, and have completed the present invention.
発明の概要 本発明は、顆粒核と、その表面を被覆している２層以上
の表面層からなる多層構造を有する顆粒状であって、有
機酸成分と炭酸塩成分が１層以上の浴剤成分層を介して
個別に配置されてなる発泡浴剤を提供するものである。
本発明の発泡浴剤においては、有機酸成分と炭酸塩成分
とが他の浴剤成分で隔離されているため、吸湿による両
成分の反応が充分に抑制され、顆粒状であっても発泡成
分の保存安定性を著しく向上させることができる。SUMMARY OF THE INVENTION The present invention is a bath agent having a multi-layered structure consisting of a granule core and two or more surface layers coating the surface thereof, wherein the organic acid component and the carbonate component are one or more layers. It is intended to provide a foaming bath agent which is individually arranged via component layers.
In the foaming bath agent of the present invention, the organic acid component and the carbonate component are separated from each other by the other bath agent components, so that the reaction of both components due to moisture absorption is sufficiently suppressed, and the foaming component is even in the granular form. The storage stability of can be significantly improved.
発明の詳説 本発明の発明浴剤は、顆粒核と、その表面を被覆してい
る２層以上の表面層からなる多層構造の顆粒である。表
面層の数は２層以上であれば特に限定するものではない
が、安定性上、製造工程上、コスト上、保存性等の観点
から３〜４層が好ましい。有機酸成分および炭酸塩成分
は、顆粒核、表面層のいずれに配置してもよく、各々を
複数の層に分けてもよいが、両成分は、少なくとも１層
の浴剤成分層で隔離されていることが必要である。かか
る配置の例としては、有機酸成分を顆粒核とし、これ
に、順次、浴剤成分層、炭酸塩成分層および浴剤成分層
を被覆したもの、炭酸塩成分を顆粒核とし、これに、順
次、浴剤成分層、有機酸成分層および浴剤成分層を被覆
したもの、浴剤成分を中心核とし、これに、順次、有機
酸成分層、浴剤成分層、炭酸塩成分層および浴剤成分層
を被覆したものが挙げられる。顆粒の大きさとしては、
例えば、平均粒径0.05mm〜20.00mmが挙げられ、視覚
上、安定性上、溶解性上から、0.5〜10.0mmが好まし
い。Detailed Description of the Invention The bath agent of the present invention is a granule having a multi-layer structure comprising a granule core and two or more surface layers coating the surface thereof. The number of surface layers is not particularly limited as long as it is two or more, but from the viewpoint of stability, manufacturing process, cost, storability, etc., 3 to 4 layers are preferable. The organic acid component and the carbonate component may be arranged in either the granule nucleus or the surface layer, and each may be divided into a plurality of layers, but both components are separated by at least one bath agent component layer. It is necessary to have As an example of such an arrangement, an organic acid component is used as a granule nucleus, which is sequentially coated with a bath agent component layer, a carbonate component layer and a bath agent component layer, and a carbonate component is used as a granule nucleus. One in which a bath agent component layer, an organic acid component layer and a bath agent component layer are sequentially coated, and a bath agent component is the central core, and an organic acid component layer, a bath agent component layer, a carbonate component layer and a bath The thing which coat | covered the agent component layer is mentioned. As for the size of granules,
For example, the average particle size is 0.05 mm to 20.00 mm, and 0.5 to 10.0 mm is preferable from the viewpoint of visual sense, stability and solubility.
用いる有機酸成分としては、乾燥クエン酸、酒石酸、リ
ンゴ酸、マロン酸、ピリドンカルボン酸、コハク酸、フ
マル酸、クエン酸一ナトリウム、コハク酸一ナトリウ
ム、フマル酸ナトリウムが挙げられ、これらは単独で
も、２種以上併用してもよい。通常、有機酸成分は浴剤
全量に基づいて、５〜75重量％の範囲で配合される。Examples of the organic acid component used include dry citric acid, tartaric acid, malic acid, malonic acid, pyridonecarboxylic acid, succinic acid, fumaric acid, monosodium citrate, monosodium succinate, and sodium fumarate. You may use 2 or more types together. Usually, the organic acid component is blended in the range of 5 to 75% by weight based on the total amount of the bath agent.
炭酸塩成分としては、乾燥炭酸水素ナトリウム、炭酸ナ
トリウム、セスキ炭酸ナトリウム、炭酸カリウム、炭酸
水素カリウム、炭酸アンモニウムが挙げられ、これらも
単独でも、２種以上併用してもよい。通常、炭酸塩成分
は用いる有機酸成分の重量に基づいて、10〜250重量％
の範囲で配合される。Examples of the carbonate component include dry sodium hydrogen carbonate, sodium carbonate, sodium sesquicarbonate, potassium carbonate, potassium hydrogen carbonate, and ammonium carbonate, and these may be used alone or in combination of two or more. Usually, the carbonate component is 10 to 250% by weight based on the weight of the organic acid component used.
It is mixed in the range of.
本明細書における「浴剤成分」なる語は前記の発泡成分
以外の、浴剤に用いられる各種の成分を意味する。かか
る浴剤成分を例としてはつぎのような成分が挙げられ
る。The term "bath agent component" as used herein means various components used in a bath agent other than the above-mentioned foaming component. Examples of such bath agent components include the following components.
温泉成分、その他無機成分：塩化ナトリウム、湯の華、
ホウ砂、ホウ酸、硫酸ナトリウム、硫化カリウム、硫化
ナトリウム、硫黄、酸化カルシウム、硝酸カリウム、硝
酸ナトリウム、硝酸カルシウム、亜硫化鉄、硫酸アルミ
ニウム、メタケイ酸、中性白土、チオ硫酸ナトリウム、
ポリリン酸ナトリウム、カリ石鹸、リン酸水素カルシウ
ム、臭化カリウム、塩化カリウム、塩化アンモニウム、
硫酸鉄、消石灰、過マンガン酸カリウム、リン酸ナトリ
ウム、次亜硫酸ナトリウム、チオ硫酸カルシウム、水酸
化ナトリウム、雲母末など。Hot spring ingredients, other inorganic ingredients: sodium chloride, hot water,
Borax, boric acid, sodium sulfate, potassium sulfide, sodium sulfide, sulfur, calcium oxide, potassium nitrate, sodium nitrate, calcium nitrate, iron sulfite, aluminum sulfate, metasilicic acid, neutral clay, sodium thiosulfate,
Sodium polyphosphate, potassium soap, calcium hydrogen phosphate, potassium bromide, potassium chloride, ammonium chloride,
Iron sulfate, slaked lime, potassium permanganate, sodium phosphate, sodium hyposulfite, calcium thiosulfate, sodium hydroxide, mica powder, etc.
有機賦形剤、香料成分等：ステアリルアルコール、流動
パラフィン、白色ワセリン、カゼイン、脱脂粉乳、dl−
メントール、−メントール、ハッカ油、グリセリン、
エタノール、ｄ−カンフル、dl−カンフル、テレピン
油、ヒノキ油、橙皮油、サルチル酸メチル、ケイヒ油、
ベルガモット油、菖蒲油、パイン油、ラベンダー油、ヌ
カ油、オリーブ油、大豆油、竜脳、プロピレングリコー
ル、水溶性高分子（例えば、カルボキシメチルセルロー
スナトリウム、ヒドロキシプロピルセルロース、プルラ
ン等）、糖類（例えば、デキストリン、乳糖等）、各種
着色料など。Organic excipients, flavor components, etc .: stearyl alcohol, liquid paraffin, white petrolatum, casein, skim milk powder, dl-
Menthol, -menthol, peppermint oil, glycerin,
Ethanol, d-camphor, dl-camphor, turpentine oil, cypress oil, orange peel oil, methyl salicylate, cinnamon oil,
Bergamot oil, iris oil, pine oil, lavender oil, nuka oil, olive oil, soybean oil, Borneolum, propylene glycol, water-soluble polymers (for example, sodium carboxymethyl cellulose, hydroxypropyl cellulose, pullulan, etc.), sugars (for example, dextrin, Lactose, etc.), various colorants, etc.
生薬抽出物：アオキ、アオギリ、アオツヅラフジ、アカ
ネ、アカメガシワ、アケビ、アセビ、イタドリ、イチジ
ク、イノコヅチ、ウド、ウラジロガシ、エビスグサ、オ
ウバク、オトギリソウ、オナモミ、カラスウリ、カラタ
イ、キランソウ、クララ、クリ、ゲッケイジュ、ゴシュ
ユ、サクラ、サラシナショウマ、シキミ、シソ、ショウ
ガ、ショウキョウ、ショウブ、スイカズラ、スギ、セキ
ショウ、ソクズ、チョウセンニンジン、トウキ、トウ
ヒ、ナギナタコウジュ、ナンテン、ニワトコ、ネナシカ
ズラ、バショウ、ハマゴウ、ハマボウフウ、ビワ、マタ
タビ、ミヤマシキミ、メハジキ、ヤツデ、ヤマモモ、ヨ
クイニン、ヨモギ、ワレモコウ、ミカン、ハトムギ、ホ
オノキ、エゾウコギ、センキュウ、カミツレ、ケイガ
イ、フジバカマ、ユズ、ヨロイグサ、カキドウシ、ハッ
カコウ、モモノハ、ブクリョウ、ローズマリー、ホップ
などの抽出エキス。Crude drug extract: Aoki, Aogiri, Atsutsuruji, Akane, Akamegashiwa, Akeboshi, Acer shrimp, Itadori, Fig, Fig. Sakura, salamander, shikimi, perilla, ginger, ginger, ginger, honeysuckle, cedar, sekisho, sokuzu, ginseng, tokyo, spruce, naginata kouju, nanten, elderberry, nashikazu, bakusho, hagomago, hibiscus, habamabou Miyamakikimi, swordfish, yamde, bayberry, yokinin, mugwort, waremoko, mandarin orange, pearl barley, honoki, eleuthero, senkyu, chamomile, kayigai, wisteria fish, yuzu Yoroigusa, Kakidoushi, Hakkakou, Momonoha, Bukuryou, rosemary, extract of such as the hop.
本発明においては、浴剤成分は特に限定するものではな
く、前記のごとき、各種の浴剤成分を単独で、あるいは
２種以上組合わせて用いることができ、各成分の配合量
も、所望の成分に応じ、発泡成分の保存安定性を損なわ
ない範囲で適宜選択することができる。もちろん、有機
酸成分、炭酸塩成分の各々に適宜他の浴剤成分を混合し
てもよい。In the present invention, the bath agent component is not particularly limited, and as described above, various bath agent components can be used alone or in combination of two or more kinds, and the blending amount of each component is also desired. Depending on the component, it can be appropriately selected within a range that does not impair the storage stability of the foaming component. Of course, other bathing agent components may be appropriately mixed with the organic acid component and the carbonate component, respectively.
本発明の発泡浴剤は、顆粒核の周囲に常法に従って所望
の成分の層を順次形成させていくことにより製造でき
る。顆粒核は、適当な粒径を有する固形の有機酸成分ま
たは炭酸塩成分の顆粒であってもよく、また、適宜の成
分を用いて常法、例えば、湿式造粒により調整した顆粒
でもよい。各層は、例えば、所望の成分の適当な分散液
を顆粒上に噴霧し、乾燥して被覆させることができ、要
すれば、水溶性高分子や糖類などの結合剤を用いること
もできる。特に、遠心流動コーティング造粒装置（例え
ば、フロイント産業（株）製）を用いると、層構造の明
瞭な、球状の顆粒が得られるので好ましい。The effervescent bath agent of the present invention can be produced by sequentially forming layers of desired components around the granule core according to a conventional method. The granule nucleus may be a granule of a solid organic acid component or carbonate component having an appropriate particle size, or may be a granule prepared by an ordinary method using an appropriate component, for example, wet granulation. Each layer can be coated, for example, by spraying an appropriate dispersion of desired components onto the granules, drying and coating, and if necessary, a binder such as a water-soluble polymer or saccharide can also be used. In particular, it is preferable to use a centrifugal fluidized coating granulator (for example, manufactured by Freund Sangyo Co., Ltd.) because spherical granules having a clear layer structure can be obtained.
本発明な発泡浴剤は、缶、ビン、合成樹脂、紙容器等、
各種の容器に入れて保存、流通させることができ、顆粒
状であるにもかかわらず、発泡成分の保存安定性が著し
く向上しており、保存、流通過程における発泡成分の反
応による炭酸ガスの発生で包装容器が膨張したり、破裂
したり、あるいは、使用時における炭酸ガス発生量の低
下などを防止することができる。The foaming bath agent of the present invention includes cans, bottles, synthetic resins, paper containers, etc.
Although it can be stored and distributed in various containers and is in the form of granules, the storage stability of the foaming component is remarkably improved, and carbon dioxide gas is generated by the reaction of the foaming component during the storage and distribution process. Thus, it is possible to prevent the packaging container from expanding, bursting, or lowering the amount of carbon dioxide gas generated during use.
つぎに実施例を挙げて本発明をさらに詳しく説明する
が、これらに限定されるものではない。Next, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.
実施例１ 成 分 重量％ クエン酸 15.0 無水硫酸ナトリウム 59.4 炭酸水素ナトリウム 7.5 炭酸ナトリウム 7.5 トウヒエキス 0.5 着色料 0.1 カルボキシメチルセルロースナトリウム0.05％水溶液 1
0.0 香料 適量 クエン酸を顆粒核とし、カルボキシメチルセルロースナ
トリウム水溶液を結合剤とし、第１の表面層として、無
水硫酸ナトリウム、第２の表面層としてトウヒエキス、
炭酸水素ナトリウムおよび炭酸ナトリウムを混合した炭
酸塩成分層および第３の表面層として、着色料および香
料の混合物層を順次噴霧し、乾燥し、顆硫核も含めて、
４層の多層構造を有する、平均粒径1.5mmの顆粒状の所
望の発泡浴剤を得た。Example 1 Component% by weight Citric acid 15.0 Anhydrous sodium sulfate 59.4 Sodium hydrogen carbonate 7.5 Sodium carbonate 7.5 Spruce extract 0.5 Coloring agent 0.1 Sodium carboxymethylcellulose 0.05% Aqueous solution 1
0.0 Fragrance Suitable amount Citric acid as granule core, sodium carboxymethylcellulose aqueous solution as binder, anhydrous sodium sulfate as first surface layer, spruce extract as second surface layer,
As a carbonate component layer and a third surface layer in which sodium hydrogen carbonate and sodium carbonate are mixed, a mixture layer of a colorant and a fragrance is sequentially sprayed, dried, and the condyle sulfur core is also included.
A desired foaming bath agent in the form of granules having an average particle diameter of 1.5 mm having a multilayer structure of 4 layers was obtained.
実施例２ 成 分 重量％ 顆粒状セスキ炭酸ナトリウム 20.0 無水硫酸ナトリウム 40.0 コハク酸 28.9 ローズマリーエキス 0.5 液状ラノリン 0.5 着色料 0.1 プルラン30％水溶液 10.0 セスキ炭酸ナトリウムを顆粒核とし、プルラン水溶液を
結合剤とし、第１の表面層として、液状ラノリンと無水
硫酸ナトリウムの1/10量の混合物を噴霧し、被覆した。
ついで、コハク酸の有機酸成分層を第２の表面層として
被覆し、さらに、第３の表面層として、残りの無水硫酸
ナトリウム、ローズマリーエキスおよび着色料の混合物
を被覆し、乾燥して、所望の多層構造を有する、平均粒
径1.0mmの顆粒状発泡浴剤を得た。Example 2 Ingredient% by Weight Granular Sodium Sesquicarbonate 20.0 Anhydrous Sodium Sulfate 40.0 Succinic Acid 28.9 Rosemary Extract 0.5 Liquid Lanolin 0.5 Coloring Agent 0.1 Pullulan 30% Aqueous Solution 10.0 Sodium sesquicarbonate as a granule core, aqueous pullulan solution as a binder, As a first surface layer, a 1/10 amount mixture of liquid lanolin and anhydrous sodium sulfate was sprayed and coated.
Then, an organic acid component layer of succinic acid is coated as a second surface layer, and further, a mixture of the remaining anhydrous sodium sulfate, rosemary extract and colorant is coated as a third surface layer, dried, A granular foaming bath agent having a desired multilayer structure and an average particle size of 1.0 mm was obtained.
実施例１および実施例２で得られた発泡浴剤と、同一成
分を用いた粉末ならびに従来の顆粒化技術による顆粒
（標準品１および２）の安定性を試験した。結果を第１
表に示す。試料はいずれもアルミニウムをラミネートし
たフィルムで密封包装し、温度40℃、湿度75％の条件下
で保存し、容器の膨張の有無により安定性を試験した。The stability of the effervescent bath agents obtained in Examples 1 and 2, the powders using the same components and the granules according to the conventional granulation technique (Standards 1 and 2) were tested. First result
Shown in the table. Each sample was hermetically packaged with a film laminated with aluminum, stored under the conditions of a temperature of 40 ° C. and a humidity of 75%, and the stability was tested by the presence or absence of expansion of the container.
なお、50日間放置後も変化が見られなかった。実施例１
および実施例２の試料を浴湯中に投じたところ、良好な
発泡性が得られ、皮膚にマッサージ効果をもたらした。 No change was observed even after being left for 50 days. Example 1
When the sample of Example 2 was put into a bath water, good foaming property was obtained, and a massage effect was provided on the skin.
Claims (3)
上の表面層からなる多層構造を有する顆粒状であって、
乾燥クエン酸、酒石酸、リンゴ酸、マロン酸、ピロリド
ンカルボン酸、コハク酸、フマル酸、クエン酸一ナトリ
ウム、コハク酸一ナトリウムおよびフマル酸一ナトリウ
ムから選ばれる少なくとも１種の有機成分と、乾燥炭酸
水素ナトリウム、炭酸ナトリウム、セスキ炭酸ナトリウ
ム、炭酸カリウム、炭酸水素カリウムおよび炭酸アンモ
ニウムから選ばれるすくなくとも１種の炭酸塩成分とが
１層以上の浴剤成分層を介して個別に配置されているこ
とを特徴とする発泡浴剤。1. A granule having a multi-layer structure comprising a granule core and two or more surface layers coating the surface thereof,
At least one organic component selected from dry citric acid, tartaric acid, malic acid, malonic acid, pyrrolidonecarboxylic acid, succinic acid, fumaric acid, monosodium citrate, monosodium succinate and monosodium fumarate, and dry hydrogen carbonate It is characterized in that at least one carbonate component selected from sodium, sodium carbonate, sodium sesquicarbonate, potassium carbonate, potassium hydrogen carbonate and ammonium carbonate is separately arranged through one or more bath agent component layers. Effervescent bath agent.
に、浴剤成分層を介して炭酸塩成分層を設けた請求項
（１）の発泡浴剤。2. The foaming bath agent according to claim 1, wherein an organic acid component is placed in the granule core, and a carbonate component layer is provided on the surface of the granule nucleus via a bath agent component layer.
に、浴剤成分層を介して有機酸成分層を設けた請求項
（１）の発泡浴剤。3. The effervescent bath agent according to claim 1, wherein a carbonate component is placed in the granule core, and an organic acid component layer is provided on the surface of the nucleus component via a bath agent component layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60235911A JPH0714862B2 (en) | 1985-10-21 | 1985-10-21 | Effervescent bath agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60235911A JPH0714862B2 (en) | 1985-10-21 | 1985-10-21 | Effervescent bath agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6293222A JPS6293222A (en) | 1987-04-28 |
| JPH0714862B2 true JPH0714862B2 (en) | 1995-02-22 |
Family
ID=16993061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60235911A Expired - Fee Related JPH0714862B2 (en) | 1985-10-21 | 1985-10-21 | Effervescent bath agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0714862B2 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0714863B2 (en) * | 1986-06-02 | 1995-02-22 | 忠生 白石 | Staggered bath salts |
| JPH10182421A (en) * | 1996-12-27 | 1998-07-07 | Kose Corp | Bath preparation |
| JP4057170B2 (en) * | 1998-11-16 | 2008-03-05 | 一丸ファルコス株式会社 | Cosmetic composition containing moisturizing plant extract |
| JP5650434B2 (en) * | 2010-04-30 | 2015-01-07 | 株式会社クロイスターズ | Granular bath |
| JP5935172B2 (en) * | 2013-01-22 | 2016-06-15 | 株式会社東洋新薬 | Effervescent skin external preparation |
| JP2014210734A (en) * | 2013-04-19 | 2014-11-13 | クラシエホームプロダクツ株式会社 | Acidic bath composition |
| GB201404178D0 (en) * | 2014-03-10 | 2014-04-23 | Cosmetic Warriors Ltd | Composition |
| CN112137917A (en) * | 2020-11-02 | 2020-12-29 | 浙江有北化妆品有限公司 | Double-layer bath essence composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5673021A (en) * | 1979-11-20 | 1981-06-17 | Lion Corp | Tablet of acetylsalicylic acid |
| JPS5970610A (en) * | 1982-10-15 | 1984-04-21 | Kao Corp | Foaming bathing agent |
-
1985
- 1985-10-21 JP JP60235911A patent/JPH0714862B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5673021A (en) * | 1979-11-20 | 1981-06-17 | Lion Corp | Tablet of acetylsalicylic acid |
| JPS5970610A (en) * | 1982-10-15 | 1984-04-21 | Kao Corp | Foaming bathing agent |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6293222A (en) | 1987-04-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2941926A (en) | Chlorophyll dental powder | |
| BR0003158A (en) | Instant melting oral dosage formulation | |
| JPS63190815A (en) | Powdery hair dye composition | |
| MXPA97001839A (en) | Process to establish gelat products | |
| JPH0714862B2 (en) | Effervescent bath agent | |
| PL181215B1 (en) | Improved pharmaceutic composition containing ibuprofen and codeine | |
| JPS61207322A (en) | Foamable solid composition containing ascorbic acid | |
| US6180092B1 (en) | Dissolvable air freshener | |
| ATE17650T1 (en) | DRY POWDERED N-ACETYL-P-AMINOPHENOL COMPOSITIONS AND PROCESS FOR THEIR PREPARATION. | |
| US4093745A (en) | Method for producing a prilled urea bath bead composition | |
| CN106398923B (en) | Generate the manufacturing method of the solid cosmetic perfumed soap of carbon dioxide | |
| NZ504566A (en) | The amorphous form of zafirulkast (Form A), a leukotriene antagonist, as a pharmaceutical composition in a multi-layered sustained release formulation for treatment of asthma and related conditions | |
| JPH08325137A (en) | Bathing agent | |
| JPS638309A (en) | Bathing agent or cosmetic, dissolved in use and containing clathrate of aromatic essential oil component | |
| JP6207324B2 (en) | Skin cosmetics | |
| JPS62132816A (en) | Foamable bathing agent | |
| JPS60181014A (en) | Bath agent and production thereof | |
| JPH02205A (en) | Perfume-containing coating agent for soft capsule | |
| JP2589257B2 (en) | Bath composition | |
| JP2010280617A (en) | Dentifrice packaged in container | |
| DE3166825D1 (en) | Process for manufacture of a coated acetylsalicylic-acid formulation | |
| JPS6226214A (en) | Solid bath composition slowly soluble in hot water | |
| JPS60181013A (en) | Bath agent and production thereof | |
| JP2572691B2 (en) | Composite powder and bath agent composition containing the same | |
| JPH0242811B2 (en) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |