JPH07132045A - Preservation of raw green vegetable food with chitosan solution - Google Patents

Preservation of raw green vegetable food with chitosan solution

Info

Publication number
JPH07132045A
JPH07132045A JP14426291A JP14426291A JPH07132045A JP H07132045 A JPH07132045 A JP H07132045A JP 14426291 A JP14426291 A JP 14426291A JP 14426291 A JP14426291 A JP 14426291A JP H07132045 A JPH07132045 A JP H07132045A
Authority
JP
Japan
Prior art keywords
preservation
chitosan solution
vegetable food
green vegetable
raw green
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP14426291A
Other languages
Japanese (ja)
Inventor
Kotofumi Tachibana
事文 立花
Shinichi Sakagami
真一 阪上
Hiroaki Nagatani
宏明 永谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP14426291A priority Critical patent/JPH07132045A/en
Publication of JPH07132045A publication Critical patent/JPH07132045A/en
Pending legal-status Critical Current

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  • Storage Of Fruits Or Vegetables (AREA)

Abstract

PURPOSE:To preserve a raw vegetable or fruit in a state close to natural growing environment. CONSTITUTION:A raw vegetable or fruit is coated with a dilute acidic solution containing chitosan (glucosamine, N-acetyl glucosamine or polyglucosamine) and preserved. This process enables the control of shipment and the stable supply of vegetable, etc.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】 青果生鮮食品は、収穫期などを
迎えると多量の荷が出まわり選別などで手間取り市場に
行く前に商品としての価値がなくなる場合が多々あった
が、保蔵により大幅に改革できる。従って、出荷の調整
ができるので一時的に膨張する人手の問題を緩和し、製
品の値段が安定して、長期間消費者の食卓を賑わすこと
ができる。
[Industrial application] Fresh fruits and vegetables often lose their value as a product before they enter the time-consuming market due to a large amount of cargo coming out at the time of harvest, etc. Can be reformed. Therefore, since shipping can be adjusted, the problem of manpower that temporarily expands can be alleviated, the price of the product can be stabilized, and the table of consumers can be kept busy for a long time.

【0002】[0002]

【従来の技術】 現状では常温放置、低温保蔵、ガス密
封、油脂類の塗布など。
2. Description of the Related Art At present, it is left at room temperature, stored at low temperature, sealed with gas, coated with oils and fats, etc.

【0003】[0003]

【発明が解決しようとする課題】 従来の方法を簡単に
示す (イ)常温放置 そのまま自然のなりゆき。 (ロ)低温保蔵 設備費やコストがかかるばかりでな
く、常温に触れると非常に早く商品価値が下がるので小
売店の損失を招くことが多い。長期間保蔵を見込むので
未熟成の物を収穫することが多く味が落ちる。 (ハ)ガス密封 特殊な装置が必要であったり、設備費
やガスを封入するため容積が大きくなりやすい。長期間
保蔵するので未熟成の物などを収穫するため味が落ち
る。 (ニ)油脂類の塗布 被膜が酸素の供給を断つので腐敗
しても外からでは確認できない事もあり、可食部にワッ
クスなどが付着すると消費者は不安である。特に果物は
規制がほとんどなく、法定の防腐、防カビ剤を除けば何
(有毒物質以外)を塗布してもかまわないのでなおさら
である。 以上のような問題点があった。
[Problems to be Solved by the Invention] The conventional method will be briefly described. (B) Low-temperature storage Not only is it costly to install equipment and costs, but it also leads to loss of retail stores because the product value drops very quickly when exposed to room temperature. Since it is expected to be stored for a long period of time, the unripe ones are often harvested and the taste deteriorates. (C) Gas sealing Since special equipment is required and equipment cost and gas are enclosed, the volume tends to increase. Since it is stored for a long period of time, the taste is lost due to harvesting unripe items. (D) Application of oils and fats Since the coating cuts off the supply of oxygen, it may not be able to be confirmed from the outside even if it rots, and consumers are worried if wax etc. adheres to the edible portion. This is especially true for fruits, where there is almost no regulation and anything (other than toxic substances) can be applied except for legal antiseptics and fungicides. There were the above problems.

【発明の構成】[Constitution of the invention]

【0004】[0004]

【課題を解決するための手段】 従来の問題点をキトサ
ン(グルコサミン、ポリグルコサミン、N-アセチルグル
コサミン)を含んだ希酸性溶液のコート処理で、常温保
蔵を可能にする。
[Means for Solving the Problems] A conventional problem is that a room temperature storage is possible by coating a dilute acidic solution containing chitosan (glucosamine, polyglucosamine, N-acetylglucosamine).

【0005】[0005]

【作用】 青果物などに保蔵液(キトサンを含んだ希酸
性溶液)をコーティングすると、保蔵液に触れた部分は
希酸性溶液の効果により滅菌され、乾燥すると被膜を形
成する。この被膜はワックスなどとは違うキトサンの被
膜である。この被膜は酸素を通し、水分を通さない(蒸
発しにくくする)。また、熟成にしたがって吐出するエ
チレンガスは被膜によって外部に出にくくなる。さら
に、外部からの細菌を直接触れさせない、いわゆるバリ
ヤとしての働きがこの被膜にあるばかりでなく、青果物
の表面にあるキトサナーゼなどの酵素を活性化して細菌
やカビ類から防護する働きがある。従って、細胞が生き
た状態で長期間保蔵することができる。
[Function] When a storage solution (dilute acidic solution containing chitosan) is coated on fruits and vegetables, the portion in contact with the storage solution is sterilized by the effect of the diluted acidic solution, and forms a film when dried. This film is a film of chitosan, which is different from wax. This coating is permeable to oxygen and impermeable to water (making it difficult to evaporate). Further, the ethylene gas discharged as it ages is less likely to come out due to the film. Further, not only this film has a function as a so-called barrier that does not allow external bacteria to be directly contacted, but it also has a function of activating enzymes such as chitosanase on the surface of fruits and vegetables to protect them from bacteria and fungi. Therefore, the cells can be stored in a living state for a long time.

【0006】[0006]

【実施例】 柑橘類、柿、りんご、なし、もも、いち
ご、トマト、なす、きゅーり、人参、大根、その他多種
を行なったが主な加工例を以下に示す。 「加工例1 ミカン」 ミカンの保存は、一般的に風通
しがよく温度が一定な土蔵とか納屋が良いとされてい
る。生産者では保蔵箱やコンテナを利用しており、密封
した箱やポリ袋等ではムレによるカビや腐敗が短時間で
引き起こされ、一つでも汚染すると次々と伝染したり、
直接人の手で触れても良くないことが分っている。そこ
で、無処理のミカンと保蔵液(キトサンを含んだ希酸性
溶液)でコ−ト処理したものと比較してみた。ユーザー
が一般に行なっている方法で実際に対処することが肝要
であると考え原始的な方法であるが、段ボール箱に10
キログラム、ポリ袋には10個づつそれぞれ室温で保管
してみた。ポリ袋は透明で観察は容易であるが、段ボー
ル箱は中の状態が見えない。また、エチレンガスの影響
で腐敗するのは底の方からであるが、観察すると条件が
変わってしまうので毎日観察するわけにはいかない。従
って、段ボール箱の観察は2週間置きとし、ポリ袋は1
週間置きに観察した。結果は表1、表2にまとめる。 「加工例2 柿」 柿もミカンと同様の方法で10キロ
グラム段ボール箱とポリ袋に5個づつで行なってみた。 「加工例3 りんご」 りんごもミカン同様の方法で1
0キログラム段ボール箱とポリ袋に5個づつで行なって
みた。 上記青果物は、八百屋さんの店頭で仕入れた物である
[Examples] Citrus, persimmon, apple, pear, peach, strawberry, tomato, eggplant, cucumber, carrot, radish and various other types were carried out, but the main processing examples are shown below. “Processing example 1 mandarin oranges” It is generally said that mandarin oranges are well-ventilated and kept in a stable temperature at a storehouse or barn. The producers use storage boxes and containers, and in sealed boxes and plastic bags, mold and decay due to stuffiness are caused in a short time, and even if one is contaminated, it will be transmitted one after another,
It turns out that it is not good to touch it directly with human hands. Therefore, it was compared with untreated oranges and those treated with a storage solution (dilute acidic solution containing chitosan). This is a primitive method because it is thought that it is important for the user to actually deal with it by the method that is generally used.
Each of the kilogram and the polybag was stored at room temperature, 10 each. The plastic bag is transparent and easy to observe, but the inside of the cardboard box cannot be seen. Also, although it is from the bottom that it rots under the influence of ethylene gas, it cannot be observed daily because the conditions change when observed. Therefore, the cardboard box should be observed every two weeks, and the plastic bag should be 1
It was observed every other week. The results are summarized in Tables 1 and 2. "Processing Example 2 Persimmon" Persimmons were also processed in the same manner as mandarin oranges, using 5 pieces each in a 10-kg corrugated cardboard box and a plastic bag. "Processing example 3 Apples" Apples 1
I tried 5 pieces each in a 0 kilogram cardboard box and a plastic bag. The fruits and vegetables mentioned above are those purchased at the greengrocer's store.

【0007】[0007]

【発明の効果】 バイオマス資源のカニ、エビなどの甲
殻を形成しているキチン質から抽出されたキトサンが保
護被膜として重要な役目を果している。キトサンは食品
添加物の増粘安定剤として認められており安全であり、
被膜は酸素を通すことができ、自然に近い状態で保蔵で
きる。常温で未処理の物と比べた結果保蔵期間の差が明
らかにでている。保蔵液(キトサンを含んだ希酸性溶
液)のコート処理で、常温保蔵ができ、特別な保蔵庫は
必要なくコストが抑えられる。末端の小売店のロスを激
減できる。熟成された物が保蔵できる。設備は簡単な機
械化だけですむので実用的である。
EFFECTS OF THE INVENTION Chitosan extracted from chitin forming the shell of crabs, shrimps and the like, which are biomass resources, plays an important role as a protective film. Chitosan is recognized as a thickening stabilizer for food additives and is safe,
The coating is permeable to oxygen and can be stored in near-natural conditions. As a result, the difference in storage period is clear as compared with the untreated one at room temperature. By coating the storage solution (dilute acidic solution containing chitosan), it can be stored at room temperature, and no special storage is required, thus reducing costs. It can drastically reduce the loss at retail stores. Aged things can be stored. The equipment is practical because it requires only simple mechanization.

【表の簡単な説明】[Short description of table]

【表1】 段ボール箱に入れた果実の状態 [Table 1] State of fruits placed in a cardboard box

【符号の説明】[Explanation of symbols]

A=処理、B=未処理 A = processed, B = unprocessed

【表2】 ポリ袋に入れた果実の状態 [Table 2] State of fruits in plastic bags

【符号の説明】 A=処理、B=未処理[Explanation of Codes] A = processed, B = unprocessed

───────────────────────────────────────────────────── フロントページの続き (72)発明者 永谷 宏明 愛知県豊橋市野依台1丁目7番地の1 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Hiroaki Nagatani 1-7-7 Noyoridai, Toyohashi City, Aichi Prefecture

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 キトサン(グルコサミン、ポリグルコサ
ミン、N-アセチルグルコサミン)を含んだ希酸性溶液と
そのコーティングに関するものである。
1. A dilute acidic solution containing chitosan (glucosamine, polyglucosamine, N-acetylglucosamine) and its coating.
JP14426291A 1991-04-19 1991-04-19 Preservation of raw green vegetable food with chitosan solution Pending JPH07132045A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14426291A JPH07132045A (en) 1991-04-19 1991-04-19 Preservation of raw green vegetable food with chitosan solution

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14426291A JPH07132045A (en) 1991-04-19 1991-04-19 Preservation of raw green vegetable food with chitosan solution

Publications (1)

Publication Number Publication Date
JPH07132045A true JPH07132045A (en) 1995-05-23

Family

ID=15358006

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14426291A Pending JPH07132045A (en) 1991-04-19 1991-04-19 Preservation of raw green vegetable food with chitosan solution

Country Status (1)

Country Link
JP (1) JPH07132045A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001036519A1 (en) * 1999-11-12 2001-05-25 Kureha Chemical Industry Co., Ltd. Film selectively permeable to carbon dioxide and food packaging film comprising the same
WO2016199934A1 (en) * 2015-06-12 2016-12-15 大日精化工業株式会社 Preservative composition and preservation liquid for fruits and vegetables, and fruits and vegetables

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6413946A (en) * 1987-07-09 1989-01-18 Nanyo Kasei Kk Polishing and coating agent having air permeability

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6413946A (en) * 1987-07-09 1989-01-18 Nanyo Kasei Kk Polishing and coating agent having air permeability

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001036519A1 (en) * 1999-11-12 2001-05-25 Kureha Chemical Industry Co., Ltd. Film selectively permeable to carbon dioxide and food packaging film comprising the same
US6746762B1 (en) 1999-11-12 2004-06-08 Kureha Chemical Industry Co., Ltd. Film selectively permeable to carbon dioxide gas and food packaging film comprising the same
WO2016199934A1 (en) * 2015-06-12 2016-12-15 大日精化工業株式会社 Preservative composition and preservation liquid for fruits and vegetables, and fruits and vegetables
JPWO2016199934A1 (en) * 2015-06-12 2018-03-29 大日精化工業株式会社 Preservative composition and preservation solution for fruits and vegetables, and fruits and vegetables

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