JPH0687752B2 - Method of producing feed - Google Patents
Method of producing feedInfo
- Publication number
- JPH0687752B2 JPH0687752B2 JP1293422A JP29342289A JPH0687752B2 JP H0687752 B2 JPH0687752 B2 JP H0687752B2 JP 1293422 A JP1293422 A JP 1293422A JP 29342289 A JP29342289 A JP 29342289A JP H0687752 B2 JPH0687752 B2 JP H0687752B2
- Authority
- JP
- Japan
- Prior art keywords
- sulfuric acid
- concentrated sulfuric
- feed
- fermentation
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/80—Food processing, e.g. use of renewable energies or variable speed drives in handling, conveying or stacking
- Y02P60/87—Re-use of by-products of food processing for fodder production
Landscapes
- Fodder In General (AREA)
Description
本発明は、水分の含有量が高い発酵廃液の乾燥性を向上
させ、好気性微生物により短時間に飼料を変化させる飼
料の製造方法に関する。The present invention relates to a method for producing a feed, which improves the drying property of a fermentation effluent having a high water content and changes the feed in a short time by aerobic microorganisms.
例えば、醪から必要成分を除去した蒸留廃液の原料は農
産物であり、肥料、土地改良剤などに変えて土壌に還元
し、クローズドシステムを形成することは容易に着想さ
れる。 しかし、この廃液を直接土壌に施すと、その初期の段階
で酪酸などの低分子の有機酸や作物の根に障害を与える
物質を生成し、土壌中で腐敗発酵を起こす。それ故、発
酵させることによって分解を進め、腐植酸のように安定
した形で供給する必要がある。 蒸留廃液の発酵に際しては濃縮乾燥が行なわれている。
蒸留廃液が少量の場合には自然乾燥によるが、冬期や晴
天の少ないときには多くの日数を必要とする。またビニ
ールハウスで処理するにしても敷地面積を多量に要し、
更には、乾燥の際には害虫や悪臭に苦慮している。 蒸留廃液の処理量が多い場合は、加熱乾燥及び焼却が行
なわれるが、燃料消費量が廃液1tを処理するのに100〜1
50の重油を要する。 しかも高温加熱のために有機物は炭化して肥料、飼料と
しては無価値なものとなる。For example, the raw material of the distillation waste liquid obtained by removing the necessary components from the mash is an agricultural product, and it is easily conceived that it is converted to fertilizer, land improver, etc. and reduced to soil to form a closed system. However, when this waste liquid is applied directly to the soil, low-molecular organic acids such as butyric acid and substances that damage the roots of crops are produced in the initial stage, and putrefaction fermentation occurs in the soil. Therefore, it is necessary to promote the decomposition by fermentation and supply it in a stable form like humic acid. Concentration and drying are performed during fermentation of the distillation waste liquid.
When the amount of distilling waste liquid is small, it depends on natural drying, but many days are required in winter and when there is little clear weather. Moreover, even if it is processed in a vinyl house, it requires a lot of site area,
In addition, they suffer from pests and odors when dried. If a large amount of distillate waste liquid is processed, it is heated and dried and incinerated, but the fuel consumption is 100 to 1 to treat 1 ton of waste liquid.
Requires 50 heavy oil. Moreover, the organic matter is carbonized due to high temperature heating and becomes worthless as a fertilizer or feed.
本発明は、上記問題点を解決するもので、水分含有率の
高い発酵廃液を短時間に発酵させて飼料を製造する新規
な方法を提供することを目的とする。The present invention solves the above problems, and an object of the present invention is to provide a novel method for producing a feed by fermenting a fermentation waste liquid having a high water content in a short time.
本発明は、発酵廃液に天然ウオラストナイト及び濃硫酸
を添加混合し粒状化したものを培地として、別の培養し
た有効微生物を加え発酵させる飼料の製造方法である。 本発明の被処理物である発酵廃液としては、アルコール
の蒸留廃液、アミノ酸、核酸関連物質等の各種の発酵廃
液が使用可能である。 天然ウオラストナイト、濃硫酸の添加順序は、何れを先
にしても、同時にしても、粒状化は良好である。悪臭除
去には濃硫酸を先に添加するほうが有利である。 発酵廃液を濃硫酸処理すると、溶液中の有機物は腐食、
酸化、蛋白のアミノ酸化が行われる。その赤外線吸収ス
ペクトルをみると、テンポロンやフミゾールなど市販の
腐植酸に近似している。天然ウオラストナイトに濃硫酸
を加えるとCaイオンとSiイオンは活性化し、Siイオンは
シロキサン結合（Si−Ｏ−Si）ならびにシラノール結合
（Si−OH）で細かい粒子の集団となり多孔質に結晶す
る。 この二つの反応を利用して発酵廃液に天然ウオラストナ
イトと濃硫酸を添加混合すると濃硫酸は廃液中にアルカ
リ分と反応し、一部は天然ウオラストナイトのCaイオン
と反応してゾルを生成し、更にゲル生成によってゲル中
のシラノール基（OH）の反応性、イオン交換性により固
粒化、粒状化されると共に水分の吸着により菌類の繁殖
源となる。 また、濃硫酸の稀釈熱及び天然ウオラストナイトの反応
熱によって廃液の温度は85℃位にまで達し、雑菌はすべ
て殺菌され、飼料化する場合の有効な前処理となる。 本発明では天然ウオラストナイトと濃硫酸を添加混合し
て粒状化を生成し、これを菌の繁殖に適した温度まで放
冷し、目的に適した有効菌を添加することによって発酵
させて飼料を製造する。 本発明で使用する天然ウオラストナイトとしては、例え
ばインドWolkem社が供給するものを挙げることができ
る。 天然ウオラストナイトを合成ウオラストナイト（小野田
セメント株式会社）の組成分析表を第１表に示す。 発酵に要する微生物は、主に糸状菌、酵母である。これ
ら微生物を含んだ培養物は、各種のものが市販されてお
り、例えば、糸状菌、細菌、放線菌の好気性微生物を共
存共生させたアンチカロリー（都産業株式会社：商標）
を挙げることが出来る。 アンチカロリーの成分分析を第２表に示す。 本発明では、発酵廃液と天然ウオラストナイト及び濃硫
酸を混合撹拌して粒状化し、更に微生物を添加すること
によって短期間に発酵廃液を飼料化する。発酵廃液と、
天然ウオラストナイト及び濃硫酸の配合割合は、廃液の
濃度によって適宜選択される。例えば通常の蒸留廃液の
場合は、被処理物100重量部に天然ウオラストナイト10
〜20重量部、濃硫酸５〜14重量部の範囲内で配合され
る。この範囲内の場合、天然ウオラストナイト10重量部
の添加量に対し、濃硫酸５〜７重量部の添加時点で粒状
化する。その際の反応熱は処理量によって異なるが75〜
85℃に達する。撹拌時間は３分間程度で十分である。な
お、撹拌を続けるとゾル生成、続くゲル化によって粒状
化し粒径３〜15mmに細分化される。 次に、実施例１で使用したアルコールの蒸留廃液を使用
して、天然ウオラストナイト及び濃硫酸の添加条件を変
化させた場合の実験結果を第３表および第４表に示す。 第３表から明らかなように、濃硫酸の使用量が少ない程
pHは高く、濃硫酸の使用量が多い程団粒化の速度は速
い。またNo.3の10重量部添加まではややゲル化不充分で
ある。 また、第４表から明らかなように、天然ウオラストナイ
ト10重量部では団粒化は不充分である。また、天然ウオ
ラストナイトの使用量が多い程粒状化の速度が速い。 蒸留廃液に天然ウオラストナイトを加え、濃硫酸処理し
た直後の温度は85℃にも達するので殆どの菌は殺菌され
て絶好の培養基となる。これを速やかに放冷し品温が40
℃に下降したときに有効菌を多量に添加する。添加後は
堆積して品温を維持し、純粋培養を行い、好気性発酵を
させるが、酸素供給と品温の均一化をするため一日に二
回の天地返しを行って発酵を促し、迅速に乾燥性を向上
させると共にアルカリ性となして五日目に理想の飼料と
なる。 有効菌の添加量変化による経過試験を第５表に示す。資
料として下記の表に示すものを使用した。 この資料を３等分し40〜50℃まで放冷する。 第５表から明らかように、有効菌の添加量の多い程発酵
は旺盛で、品温も上昇し、良質の飼料が得られる。な
お、品温の調整は堆積の高さによって加減できる。ま
た、ゲル化し粒状化した蒸留廃液のpHは生産当初は3.5
〜4.0であるが経時変化及び乾燥することによって6.5〜
8.0となる。このpHの変化は濃硫酸及び天然ウオラスト
ナイトの使用量により調整できる。 なお、天然ウオラストナイトと共に米ヌカ、コーンブラ
ン等を混入し発酵させると栄養分の高い飼料が得られ
る。The present invention is a method for producing a feed, in which natural wollastonite and concentrated sulfuric acid are added to and mixed with a fermentation waste liquor, which is then used as a medium to which another cultivated effective microorganism is added and fermented. As the fermentation waste liquid which is the object of the present invention, various fermentation waste liquids such as alcohol distillation waste liquid, amino acids and nucleic acid-related substances can be used. Even if the natural wollastonite and the concentrated sulfuric acid are added in any order or at the same time, the granulation is good. It is more advantageous to add concentrated sulfuric acid first to remove the malodor. When the fermentation waste liquid is treated with concentrated sulfuric acid, the organic matter in the solution is corroded,
Oxidation and amino acid conversion of proteins are performed. Looking at its infrared absorption spectrum, it is similar to commercially available humic acids such as Temporon and Fumisol. When concentrated sulfuric acid is added to natural wollastonite, Ca ion and Si ion are activated, and Si ion becomes a group of fine particles by siloxane bond (Si-O-Si) and silanol bond (Si-OH) and crystallizes porous. . When natural wollastonite and concentrated sulfuric acid are added and mixed to the fermentation effluent using these two reactions, concentrated sulfuric acid reacts with the alkali content in the effluent, and part of it reacts with Ca ions of natural wollastonite to form a sol. It is produced, and further, it is solidified and granulated by the reactivity and ion exchange property of the silanol group (OH) in the gel due to the gel formation, and becomes a breeding source of fungi by the adsorption of water. Moreover, the temperature of the waste liquid reaches about 85 ° C due to the heat of dilution of concentrated sulfuric acid and the heat of reaction of natural wollastonite, and all bacteria are sterilized, which is an effective pretreatment for feed production. In the present invention, natural wollastonite and concentrated sulfuric acid are added and mixed to produce granulation, which is allowed to cool to a temperature suitable for the growth of bacteria, and fermented by adding effective bacteria suitable for the purpose to feed. To manufacture. Examples of the natural wollastonite used in the present invention include those supplied by Wolkem of India. Table 1 shows a composition analysis table of natural wollastonite and synthetic wollastonite (Onoda Cement Co., Ltd.). The microorganisms required for fermentation are mainly filamentous fungi and yeasts. Various cultures containing these microorganisms are commercially available. For example, anti-calorie (Tosangyo Co., Ltd .: trademark) coexisting with aerobic microorganisms such as filamentous fungi, bacteria, and actinomycetes.
Can be mentioned. Table 2 shows the component analysis of anti-calorie. In the present invention, the fermentation effluent, natural wollastonite, and concentrated sulfuric acid are mixed and stirred to be granulated, and the fermentation effluent is made into a feed in a short period by adding a microorganism. Fermentation effluent,
The mixing ratio of natural wollastonite and concentrated sulfuric acid is appropriately selected depending on the concentration of the waste liquid. For example, in the case of ordinary distillation waste liquid, natural wollastonite 10
-20 parts by weight and concentrated sulfuric acid 5-14 parts by weight. Within this range, granulation is carried out when 5 to 7 parts by weight of concentrated sulfuric acid is added to 10 parts by weight of natural wollastonite. The reaction heat at that time is 75-
Reachs 85 ° C. A stirring time of about 3 minutes is sufficient. If the stirring is continued, the sol is formed, and the resulting gel is granulated to be subdivided into particles having a diameter of 3 to 15 mm. Next, Tables 3 and 4 show the experimental results when the addition conditions of natural wollastonite and concentrated sulfuric acid were changed using the alcohol distillation waste liquid used in Example 1. As is clear from Table 3, the lower the amount of concentrated sulfuric acid used,
The higher the pH and the higher the amount of concentrated sulfuric acid used, the faster the rate of agglomeration. In addition, gelation is slightly insufficient until 10 parts by weight of No. 3 is added. Also, as is clear from Table 4, agglomeration is insufficient with 10 parts by weight of natural wollastonite. Also, the greater the amount of natural wollastonite used, the faster the granulation rate. Natural wollastonite is added to the distillation effluent, and the temperature immediately after treatment with concentrated sulfuric acid reaches 85 ° C, so most bacteria are sterilized and become a perfect culture medium. This is quickly cooled and the product temperature is 40
When the temperature drops to ℃, add a large amount of effective bacteria. After addition, the product temperature is accumulated to maintain the product temperature, pure culture is performed, and aerobic fermentation is performed, but in order to make oxygen supply and product temperature uniform, upside down twice a day is promoted to promote fermentation, It becomes an ideal feed on the 5th day by improving the dryness quickly and making it alkaline. Table 5 shows the progress test by changing the addition amount of the effective bacteria. The materials shown in the table below were used. Divide this material into 3 equal parts and let them cool to 40-50 ° C. As is clear from Table 5, the higher the amount of effective bacteria added, the more vigorous the fermentation, the higher the product temperature, and the better the quality of feed. The temperature of the product can be adjusted depending on the height of the deposit. The pH of the gelled and granulated distillation effluent is 3.5 at the beginning of production.
~ 4.0 but 6.5 ~
It will be 8.0. This change in pH can be adjusted by adjusting the amounts of concentrated sulfuric acid and natural wollastonite used. In addition, when rice bran, corn blanc, etc. are mixed with natural wollastonite and fermented, a highly nutritious feed can be obtained.
以上説明したように本発明によれば、水分含有率の多い
発酵廃液を処理する場合に、前処理として固液分離しな
くても、そのままの状態で飼料化することができる。 また、有効菌による発酵によって飼料化が短期間にでき
る。As described above, according to the present invention, when treating a fermentation waste liquid having a high water content, it is possible to form a feed as it is without performing solid-liquid separation as a pretreatment. In addition, it can be made into feed in a short time by fermentation with effective bacteria.
以下、実施例により本発明を更に詳細に説明する。 （実施例１） 第６表に示す組成を有する乙類焼酎の蒸留廃液（飼料用
として自然沈降による固液分離をしたもの。なお固液分
離分析値は遠心分離機で固液分離を行った値である。）
100重量部を、排気処理及び撹拌装置を設けた容器に入
れ、撹拌しながら天然ウオラストナイト20重量部を加え
る。天然ウオラストナイトが十分に混合された後、濃硫
酸14重量部を徐々滴下しながら撹拌する。 蒸留廃液に天然ウオラストナイトを加え、濃硫酸処理
し、速やかに放冷して品温が40℃位に下降したときに有
効菌を多量に含んでいる培養物添加する。 本実施例では、微生物を含んだ培養物として、土地改良
材として使用されている都産業（株）の糸状菌、細菌、
放線菌の好気性微生物を共存共生させたもの（アンチカ
ロリー：商標）を使用した。 添加後は堆積して品温を略40℃に維持し、雑菌が入らな
いように純粋培養を行い、好気性発酵をさせる。このた
め酸素供給と品温の均一化をするように一日に２回の天
地返しを行って発酵を促し、迅速に乾燥性を向上させる
と共に酸性からアルカリ性となして５日目に発酵を完了
した。 発酵後の処理物の分析成分を第７表に示す。 本実施例で得られた飼料を通常の配合飼料に対して30％
配合したものを採卵用鶏に与えた。通常の配合飼料であ
れば排卵を開始して６箇月でピークを迎え、14箇月で廃
鶏となるのであるが、本実施例に係る飼料を配合したも
のは、ピークが排卵を開始して８箇月となり、２箇月ほ
ど延びた。また、廃鶏迄の期間も18箇月迄延びた。しか
もその肉質は通常の配合飼料を与えたものは硬いが、本
実施例に係る飼料を配合したものは柔らかく、商品価値
も向上することが、わかった。Hereinafter, the present invention will be described in more detail with reference to Examples. (Example 1) Distillation waste liquor of shochu shochu having the composition shown in Table 6 (solid-liquid separation by natural sedimentation for feed. Solid-liquid separation analysis values were subjected to solid-liquid separation with a centrifuge. It is a value.)
100 parts by weight is placed in a container equipped with an exhaust treatment and a stirring device, and 20 parts by weight of natural wollastonite is added with stirring. After the natural wollastonite is thoroughly mixed, 14 parts by weight of concentrated sulfuric acid is gradually added dropwise and stirred. Natural wollastonite is added to the distilled waste liquid, concentrated sulfuric acid treatment is performed, and the culture liquid containing a large amount of effective bacteria is added when the product temperature drops to about 40 ° C by allowing it to cool quickly. In this example, as a culture containing microorganisms, filamentous fungi, bacteria of Toh Sangyo Co., Ltd., which is used as a land improvement material,
What coexisted and coexisted with the aerobic microorganisms of actinomycetes (anti-calorie: trademark) was used. After the addition, the product is accumulated and the product temperature is maintained at about 40 ° C, pure culture is performed to prevent entry of bacteria, and aerobic fermentation is performed. For this reason, the fermentation is promoted by performing upside down twice a day so that the oxygen supply and the product temperature are made uniform, the drying property is quickly improved, and the acidity changes from alkaline to completion of the fermentation on the 5th day. did. The analytical components of the processed product after fermentation are shown in Table 7. The feed obtained in this example is 30% of the normal mixed feed.
The blended material was fed to chickens for egg collection. In the case of a normal mixed feed, the peak is reached in 6 months after the start of ovulation, and the chickens are abandoned in 14 months. It's been a month and it's been extended by two months. Also, the period until the abandoned chicken was extended to 18 months. Moreover, it was found that the meat quality is hard when fed with the usual mixed feed, but soft when the feed according to the present example is mixed, and the commercial value is improved.
Claims (2)
酸を添加混合し粒状化したものを培地として、別に培養
した有効微生物を加え発酵させることを特徴とする飼料
の製造方法。1. A method for producing a feed, which comprises fermenting waste liquor to which natural wollastonite and concentrated sulfuric acid are added and mixed and granulated as a culture medium to which fermented separately cultivated effective microorganisms are added and fermented.
トナイト10〜20重量部、濃硫酸５〜14重量部を添加混合
することを特徴とする請求項１記載の飼料の製造方法。2. The method for producing a feed according to claim 1, wherein 10 to 20 parts by weight of natural wollastonite and 5 to 14 parts by weight of concentrated sulfuric acid are added and mixed with 100 parts by weight of the waste liquor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1293422A JPH0687752B2 (en) | 1989-11-11 | 1989-11-11 | Method of producing feed |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1293422A JPH0687752B2 (en) | 1989-11-11 | 1989-11-11 | Method of producing feed |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62326035A Division JPH0751468B2 (en) | 1987-12-22 | 1987-12-22 | Fermentation effluent or method for treating excess sludge produced by biological treatment of effluent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02257832A JPH02257832A (en) | 1990-10-18 |
| JPH0687752B2 true JPH0687752B2 (en) | 1994-11-09 |
Family
ID=17794558
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1293422A Expired - Fee Related JPH0687752B2 (en) | 1989-11-11 | 1989-11-11 | Method of producing feed |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0687752B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0623482U (en) * | 1991-09-18 | 1994-03-29 | 詔雄 南方 | Waste liquid treatment device |
| KR100387114B1 (en) * | 1995-12-13 | 2003-08-14 | 주식회사 두산콘프로덕츠코리아 | Pulverization of corn steep liquor |
| DE19621930C1 (en) * | 1996-05-31 | 1997-12-11 | Degussa | Process for the preparation of an animal feed additive based on fermentation broth |
| FR2777571B1 (en) * | 1998-04-21 | 2002-06-28 | Revico | PROCESS FOR RECOVERING DISTILLATION RESIDUES FROM FERMENTATION PRODUCTS |
| AU3335999A (en) | 1998-04-21 | 1999-11-08 | Revico | Method for producing and extracting aromatic compounds |
-
1989
- 1989-11-11 JP JP1293422A patent/JPH0687752B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02257832A (en) | 1990-10-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |