JPH0656554A - Production of porous electrode - Google Patents
Production of porous electrodeInfo
- Publication number
- JPH0656554A JPH0656554A JP4209122A JP20912292A JPH0656554A JP H0656554 A JPH0656554 A JP H0656554A JP 4209122 A JP4209122 A JP 4209122A JP 20912292 A JP20912292 A JP 20912292A JP H0656554 A JPH0656554 A JP H0656554A
- Authority
- JP
- Japan
- Prior art keywords
- electrode
- raw material
- green sheet
- porous
- thickness direction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Measuring Oxygen Concentration In Cells (AREA)
- Powder Metallurgy (AREA)
- Conductive Materials (AREA)
- Inert Electrodes (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、ガスセンサ、湿度セン
サ及び燃料電池等に用いられている多孔質電極の製造方
法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a porous electrode used in gas sensors, humidity sensors, fuel cells and the like.
【０００２】[0002]
【従来の技術と課題】内部に気孔を有する多孔質電極
は、集電性能の他に、ガスを透過させる性能が要求され
る。この多孔質電極のガス透過性を向上させるために
は、電極内の気孔の配向方向を電極の厚み方向に揃えて
ガスの透過経路長を短くし、かつ、電極内の気孔のうち
閉気孔であるものの割合を少なくすればよい。2. Description of the Related Art A porous electrode having pores inside is required to have gas collection performance as well as gas permeation performance. In order to improve the gas permeability of this porous electrode, the gas permeation path length is shortened by aligning the orientation direction of the pores in the electrode with the thickness direction of the electrode, and the closed pores among the pores in the electrode are used. It is better to reduce the ratio of some.
【０００３】しかし、従来の方法は、導電体粉末と、結
合剤と、有機溶剤と、多孔質にするための有機高分子と
からなる電極原料をセラミック基板に塗布し、焼き付け
るだけなので、作製された電極の気孔の配向方向及び閉
気孔の割合を少なくすることができなかった。そこで、
本発明の課題は、電極内の気孔の配向方向が電極の厚み
方向に揃い、かつ、閉気孔が殆どない多孔質電極を提供
することにある。However, according to the conventional method, an electrode raw material composed of a conductor powder, a binder, an organic solvent and an organic polymer for making it porous is applied to a ceramic substrate and baked, so that it is produced. It was not possible to reduce the orientation direction of pores of the electrode and the ratio of closed pores. Therefore,
An object of the present invention is to provide a porous electrode in which the orientation direction of the pores in the electrode is aligned with the thickness direction of the electrode and there are almost no closed pores.
【０００４】[0004]
【課題を解決するための手段】以上の課題を解決するた
め、本発明に係る多孔質電極の製造方法は、（ａ）磁性
体粉末と複合化して長さ方向に磁気極性を有した有機高
分子繊維と、導電体粉末と、結合剤と、溶剤とを混合し
て電極原料を作製する工程と、（ｂ）前記電極原料に静
磁場を印加して前記有機高分子繊維の配向方向を電極の
厚み方向に揃えた状態で、前記電極原料にて電極を成形
する工程と、（ｃ）前記成形された電極を焼成して前記
有機高分子繊維を飛散させ、多孔質電極を作製する工程
と、を備えたことを特徴とする。In order to solve the above-mentioned problems, the method for producing a porous electrode according to the present invention comprises (a) an organic compound having a magnetic polarity in the longitudinal direction which is compounded with a magnetic powder. A step of preparing an electrode raw material by mixing a molecular fiber, a conductor powder, a binder, and a solvent, and (b) applying a static magnetic field to the electrode raw material so that the orientation direction of the organic polymer fiber is an electrode. A step of forming an electrode with the electrode raw material in a state of being aligned in the thickness direction of the electrode, and (c) a step of firing the formed electrode to scatter the organic polymer fibers to produce a porous electrode. , Is provided.
【０００５】[0005]
【作用】以上の方法において、磁性体粉末と複合化した
有機高分子繊維は長さ方向に磁気極性を有するものとな
る。この有機高分子繊維は電極原料に混ぜられた状態で
は、その配向方向は無秩序にあらゆる方向に向いてい
る。この電極原料に静磁場を印加すると、有機高分子繊
維は静磁場の方向に配向する。従って、静磁場を印加し
て、有機高分子繊維の配向方向を電極の厚み方向に揃
え、かつ、有機高分子繊維の長さを電極の厚みと略同じ
か若干長めの寸法にした場合、図２に示すように、高分
子繊維の両端部は成形された電極の表裏面に達する。そ
して、この成形された電極を焼成することにより、この
高分子繊維は飛散して高分子繊維跡に電極の厚み方向に
略配向している開気孔が形成されることになる。In the above method, the organic polymer fiber composited with the magnetic powder has magnetic polarity in the length direction. When the organic polymer fibers are mixed with the electrode raw material, the orientation directions thereof are randomly oriented in all directions. When a static magnetic field is applied to this electrode raw material, the organic polymer fibers are oriented in the direction of the static magnetic field. Therefore, when a static magnetic field is applied, the orientation direction of the organic polymer fibers is aligned with the thickness direction of the electrode, and the length of the organic polymer fibers is set to be approximately the same as or slightly longer than the thickness of the electrode. As shown in FIG. 2, both ends of the polymer fiber reach the front and back surfaces of the molded electrode. Then, by firing the formed electrode, the polymer fibers are scattered to form open pores in the traces of the polymer fibers which are substantially oriented in the thickness direction of the electrode.
【０００６】[0006]
【実施例】以下、本発明に係る多孔質電極の製造方法の
一実施例を説明する。実施例として、固体電解質型燃料
電池の空気側電極及び燃料側電極の製造に適用した場合
について説明する。まず、燃料側電極のグリーンシート
製造方法について説明する。EXAMPLES An example of the method for producing a porous electrode according to the present invention will be described below. As an example, a case where the invention is applied to manufacture of an air side electrode and a fuel side electrode of a solid oxide fuel cell will be described. First, a method for manufacturing the green sheet for the fuel side electrode will be described.
【０００７】図１は燃料側電極の原料２Ａを示す組成図
である。ナイロン材料と磁性体粉末であるバリウムフェ
ライトとを混ぜ、磁場を射出方向に印加しながら射出成
形し、５０μｍの長さに裁断して、長さ方向に磁気極性
を有するナイロン短繊維２ｃを作製する。次に、粉末状
のセラミックス材料である酸化ニッケルとイットリウム
安定化酸化ジルコニウムとを同重量ずつ混合して導電体
粉末２ａとした後、前記ナイロン短繊維２ｃを所定量加
えて混合する。そして、得られた混合物１００重量％に
対して、１５重量％の結合剤（例えば、ポリビニルブチ
ラール系バインダ）、溶剤（エタノール、トルエン）及
び可塑剤等（これらをまとめて図中２ｂで表示する）を
適当量加えてスラリー（泥しょう）とする。この状態で
は、各ナイロン短繊維２ｃの配向方向は無秩序にあらゆ
る方向に向いている。FIG. 1 is a composition diagram showing a raw material 2A for the fuel side electrode. A nylon material and barium ferrite, which is a magnetic powder, are mixed, injection-molded while applying a magnetic field in the injection direction, and cut into a length of 50 μm to produce a nylon short fiber 2c having magnetic polarity in the length direction. . Next, nickel oxide, which is a powdery ceramic material, and yttrium-stabilized zirconium oxide are mixed in equal weights to form a conductor powder 2a, and then a predetermined amount of the nylon short fibers 2c is added and mixed. Then, with respect to 100% by weight of the obtained mixture, 15% by weight of a binder (for example, polyvinyl butyral binder), a solvent (ethanol, toluene), a plasticizer, etc. (these are collectively indicated by 2b in the figure) Add an appropriate amount to make a slurry. In this state, the nylon short fibers 2c are randomly oriented in all directions.
【０００８】次に、図２に示すように、このスラリー状
の原料２ＡにＸ方向の静磁場を印加しながら、ドクター
ブレード法によって厚み４０μｍの燃料側電極のグリー
ンシート２Ｂを作製した。このとき、グリーンシート２
Ｂは静磁場に対して、その厚み方向が平行な状態で作製
される。従って、グリーンシート２Ｂに含まれている各
ナイロン短繊維２ｃは、グリーンシート２Ｂの厚み方向
に略配向している。しかも、ナイロン短繊維２ｃの長さ
寸法はグリーンシート２Ｂの厚み寸法より若干長いの
で、ナイロン短繊維２ｃの両端部はグリーンシート２Ｂ
の表裏面に達している。Next, as shown in FIG. 2, while applying a static magnetic field in the X direction to the slurry-like raw material 2A, a green sheet 2B for a fuel side electrode having a thickness of 40 μm was prepared by the doctor blade method. At this time, green sheet 2
B is produced in a state where its thickness direction is parallel to the static magnetic field. Therefore, each nylon short fiber 2c included in the green sheet 2B is substantially oriented in the thickness direction of the green sheet 2B. Moreover, since the length of the nylon short fiber 2c is slightly longer than the thickness of the green sheet 2B, both ends of the nylon short fiber 2c are green sheet 2B.
Has reached the front and back.
【０００９】次に、空気側電極のグリーンシート製造方
法について説明する。燃料側電極のグリーンシート製造
方法と同様に、粉末状のランタンマンガナイトに前記ナ
イロン短繊維を所定量加えて混合する。そして、得られ
た混合物１００重量％に対して１５重量％の結合剤（例
えば、ポリビニルブチラール系バインダ）及び溶剤（エ
タノール、トルエン）、可塑剤等を適当量加えてスラリ
ー状の空気側電極の原料とする。この状態では、各ナイ
ロン短繊維の配向方向は無秩序にあらゆる方向に向いて
いる。このスラリー状の原料に静磁場を印加しながら、
ドクターブレード法によって厚み４０μｍの空気側電極
のグリーンシートを作製した。このとき、グリーンシー
トは静磁場に対して、その厚み方向が平行な状態で作製
される。従って、グリーンシートに含まれている各ナイ
ロン短繊維はグリーンシートの厚み方向に略配向してい
る。Next, a method of manufacturing the green sheet for the air side electrode will be described. Similar to the method for producing the green sheet for the fuel side electrode, a predetermined amount of the above nylon short fibers is added to and mixed with powdered lanthanum manganite. Then, an appropriate amount of a binder (for example, polyvinyl butyral binder), a solvent (ethanol, toluene), a plasticizer, etc., of 15% by weight with respect to 100% by weight of the obtained mixture is added, and a raw material for an air-side electrode in a slurry state. And In this state, the orientation directions of the respective nylon short fibers are randomly oriented in all directions. While applying a static magnetic field to this slurry-like raw material,
A 40 μm thick air side electrode green sheet was prepared by the doctor blade method. At this time, the green sheet is produced in a state where its thickness direction is parallel to the static magnetic field. Therefore, each nylon short fiber contained in the green sheet is substantially oriented in the thickness direction of the green sheet.
【００１０】さらに、固体電解質となるイットリウム安
定化酸化ジルコニウムのグリーンシートを作製した。す
なわち、粉末状のイットリウム安定化酸化ジルコニウム
１００重量％に対して１５重量％の結合剤（例えばポリ
ビニルブチラール系バインダ）及び溶剤（エタノール、
トルエン）、可塑剤等を適当量加えてスラリー化し、ド
クターブレード法によって、このスラリーから固体電解
質グリーンシートを作製した。Further, a green sheet of yttrium-stabilized zirconium oxide as a solid electrolyte was prepared. That is, 15 wt% of a binder (for example, polyvinyl butyral binder) and a solvent (ethanol, 15 wt% to 100 wt% of powdery yttrium-stabilized zirconium oxide).
Toluene), a plasticizer, etc. were added in appropriate amounts to form a slurry, and a solid electrolyte green sheet was produced from this slurry by the doctor blade method.
【００１１】作製された固体電解質グリーンシートを適
当枚数重ねたものに、燃料側電極のグリーンシートと空
気側電極のグリーンシートをそれぞれ上下から重ねて圧
着し、所定の大きさに裁断して成形体を得た。この成形
体を４００℃の温度下で３時間にわたって加熱して結合
剤を飛散させた後、毎分１℃の速度で１３００℃まで昇
温し、この温度下で２時間焼成した。この焼成によっ
て、ナイロン短繊維は飛散して、ナイロン短繊維跡に成
形体の厚み方向に略配向している開気孔が形成されるこ
ととなる。この後、室温まで冷却することによって、多
孔質電極である燃料側電極２と空気側電極３を表裏面に
設けた固体電解質１を得た（図３参照）。A green sheet for the fuel side electrode and a green sheet for the air side electrode are respectively stacked from above and below on a stack of an appropriate number of the produced solid electrolyte green sheets, and the sheets are cut into a predetermined size to form a molded body. Got The molded body was heated at a temperature of 400 ° C. for 3 hours to scatter the binder, then heated to 1300 ° C. at a rate of 1 ° C./min, and baked at this temperature for 2 hours. By this firing, the short nylon fibers are scattered, and open pores that are substantially oriented in the thickness direction of the molded body are formed in the traces of the short nylon fibers. Then, by cooling to room temperature, a solid electrolyte 1 having a fuel side electrode 2 and an air side electrode 3 which are porous electrodes provided on the front and back surfaces was obtained (see FIG. 3).
【００１２】こうして得られた２種類の実施例品１，２
を気孔率及び発電能力について評価した。評価結果を表
１に示す。比較のために、グリーンシート作製時に静磁
場を印加しないということ以外は、前記製造方法と同様
の方法で作製した従来品１，２の評価結果も合わせて示
す。Two types of example products 1 and 2 thus obtained
Was evaluated for porosity and power generation capacity. The evaluation results are shown in Table 1. For comparison, the evaluation results of the conventional products 1 and 2 manufactured by the same method as the above manufacturing method are also shown, except that the static magnetic field is not applied when manufacturing the green sheet.
【００１３】[0013]
【表１】 [Table 1]
【００１４】電極２，３の気孔率は、電極断面のＳＥＭ
写真を撮り、その写真を画像解析することにより算出し
た。また、図４に示すように、電極２，３にそれぞれ燃
料ガス供給管７ａ，空気供給管７ｂを取り付けて燃料電
池を作製した。この燃料電池を測定回路１９に接続し、
発電能力を測定した。すなわち、燃料電池を１０００℃
の温度に保持しながら、燃料ガスと空気をそれぞれ電極
２，３に供給し、固体電解質１を介して電極反応を起こ
させ、かつ、電流計１１にて観察しながら単位電極面積
当たり０．３Ａ／ｃｍ2の電流が流れる状態下の燃料電
池に発生する電圧値を電圧計１０で測定した。なお、８
ａ，８ｂは白金線、９は可変抵抗器である。この発電能
力の値が大きいほど電極のガス透過性が優れ、かつ、電
池としての性能も優れていることになる。表１は、実施
例品１，２が従来例品１，２より大きな発電能力を有し
ていることが示されている。The porosities of the electrodes 2 and 3 are determined by the SEM of the electrode cross section.
It was calculated by taking a picture and analyzing the picture. Further, as shown in FIG. 4, a fuel gas supply pipe 7a and an air supply pipe 7b were attached to the electrodes 2 and 3, respectively, to fabricate a fuel cell. Connect this fuel cell to the measuring circuit 19,
The power generation capacity was measured. That is, the fuel cell at 1000 ° C
Fuel gas and air are supplied to the electrodes 2 and 3, respectively, while maintaining the temperature of 3 A to cause an electrode reaction through the solid electrolyte 1, and 0.3 A per unit electrode area while observing with an ammeter 11. The voltage value generated in the fuel cell under the condition that a current of / cm 2 flows was measured by the voltmeter 10. 8
Reference numerals a and 8b are platinum wires, and 9 is a variable resistor. The larger the value of this power generation capacity, the better the gas permeability of the electrode and the better the performance as a battery. Table 1 shows that the example products 1 and 2 have a larger power generation capacity than the conventional example products 1 and 2.
【００１５】以上のことから、実施例品１，２の方が電
極２，３のガス透過性に優れていることがわかる。な
お、本発明に係る多孔質電極の製造方法は前記実施例に
限定するものではなく、その要旨の範囲内で種々に変形
することができる。特に、前記実施例では固体電解質型
燃料電池の燃料側電極及び空気側電極に適用した場合を
説明したが、これ以外、例えばガスセンサや湿度センサ
の多孔質電極に適用してもよい。From the above, it can be seen that the products of Examples 1 and 2 are superior in gas permeability of the electrodes 2 and 3. The method for manufacturing the porous electrode according to the present invention is not limited to the above-mentioned embodiment, but can be variously modified within the scope of the gist. In particular, in the above-mentioned embodiment, the case where it is applied to the fuel side electrode and the air side electrode of the solid oxide fuel cell has been described, but other than this, it may be applied to, for example, a porous electrode of a gas sensor or a humidity sensor.
【００１６】[0016]
【発明の効果】以上の説明で明らかなように、本発明に
よれば、静磁場の印加によって、電極の厚み方向に揃え
られ有機高分子繊維を、焼成の際に飛散させて高分子繊
維跡に電極の厚み方向に略配向している開気孔を形成す
ることができる。従って、電極のガス透過性を従来より
アップさせることができ、かつ、集電性にも優れた多孔
質電極を得ることができる。As is apparent from the above description, according to the present invention, by applying a static magnetic field, organic polymer fibers aligned in the thickness direction of the electrode are scattered during firing to leave traces of polymer fibers. It is possible to form open pores that are substantially oriented in the thickness direction of the electrode. Therefore, the gas permeability of the electrode can be improved as compared with the conventional one, and a porous electrode excellent in current collecting property can be obtained.
【００１７】この結果、ガスセンサ、湿度センサ及び燃
料電池等の性能を向上させることが可能になる。As a result, it becomes possible to improve the performance of the gas sensor, the humidity sensor, the fuel cell and the like.
【図１】本発明に係る多孔質電極の製造方法の一実施例
を示す製造手順を説明するための組成図。FIG. 1 is a composition diagram for explaining a manufacturing procedure showing an embodiment of a method for manufacturing a porous electrode according to the present invention.
【図２】図１に続く製造手順を説明するための組成図。FIG. 2 is a composition diagram for explaining a manufacturing procedure subsequent to FIG.
【図３】図１に示した多孔質電極を表裏面に設けた固体
電解質の構造図。FIG. 3 is a structural diagram of a solid electrolyte in which the porous electrodes shown in FIG. 1 are provided on the front and back surfaces.
【図４】図１に示した多孔質電極を備えた燃料電池の発
電能力を測定するための測定回路を示す電気回路図。FIG. 4 is an electric circuit diagram showing a measuring circuit for measuring the power generation capacity of the fuel cell provided with the porous electrode shown in FIG.
２…燃料側電極 ２Ａ…燃料側電極原料 ２Ｂ…燃料側電極グリーンシート ２ａ…導電体粉末 ２ｂ…結合剤、溶剤及び可塑剤等 ２ｃ…ナイロン短繊維（有機高分子繊維） 2 ... Fuel side electrode 2A ... Fuel side electrode raw material 2B ... Fuel side electrode green sheet 2a ... Conductor powder 2b ... Binder, solvent, plasticizer, etc. 2c ... Nylon short fiber (organic polymer fiber)
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｈ０１Ｂ 1/20 Ｚ 7244−5Ｇ ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Office reference number FI technical display location H01B 1/20 Z 7244-5G
Claims (1)
極性を有した有機高分子繊維と、導電体粉末と、結合剤
と、溶剤とを混合して電極原料を作製する工程と、 前記電極原料に静磁場を印加して前記有機高分子繊維の
配向方向を電極の厚み方向に揃えた状態で、前記電極原
料にて電極を成形する工程と、 前記成形された電極を焼成して前記有機高分子繊維を飛
散させ、多孔質電極を作製する工程と、 を備えたことを特徴とする多孔質電極の製造方法。1. A step of preparing an electrode raw material by mixing an organic polymer fiber having a magnetic polarity in the lengthwise direction in a composite with a magnetic powder, a conductive powder, a binder, and a solvent. Applying a static magnetic field to the electrode raw material and aligning the orientation direction of the organic polymer fibers in the thickness direction of the electrode, a step of forming an electrode with the electrode raw material, and firing the formed electrode. And a step of producing a porous electrode by scattering the organic polymer fiber, the method for producing a porous electrode.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4209122A JPH0656554A (en) | 1992-08-05 | 1992-08-05 | Production of porous electrode |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4209122A JPH0656554A (en) | 1992-08-05 | 1992-08-05 | Production of porous electrode |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0656554A true JPH0656554A (en) | 1994-03-01 |
Family
ID=16567656
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4209122A Pending JPH0656554A (en) | 1992-08-05 | 1992-08-05 | Production of porous electrode |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0656554A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10189012A (en) * | 1996-12-20 | 1998-07-21 | Toyota Motor Corp | Electrode for fuel cell and power generation layer, and its manufacture |
| WO2005068397A1 (en) * | 2004-01-13 | 2005-07-28 | Ibiden Co., Ltd. | Pore-forming material for porous body, method for producing pore-forming material for porous body, method for producing porous body, porous body and honeycomb structure |
| JP2007250337A (en) * | 2006-03-15 | 2007-09-27 | Toppan Printing Co Ltd | Electrode catalyst layer for solid polyelectrolyte fuel cell, its manufacturing method and solid polyelectrolyte fuel cell |
| JP2008078075A (en) * | 2006-09-25 | 2008-04-03 | Toppan Printing Co Ltd | Electrode catalyst layer for polymer electrolyte fuel cell, its manufacturing method, and polymer electrolyte fuel cell |
| JP2008078074A (en) * | 2006-09-25 | 2008-04-03 | Toppan Printing Co Ltd | Electrode catalyst layer for polymer electrolyte fuel cell, its manufacturing method, and polymer electrolyte fuel cell |
| JP2008078020A (en) * | 2006-09-22 | 2008-04-03 | Toppan Printing Co Ltd | Electrode catalyst layer for polymer electrolyte fuel cell, its manufacturing method, and polymer electrolyte fuel cell |
| US7754370B2 (en) | 2002-08-21 | 2010-07-13 | Kabushiki Kaisha Toshiba | Fuel cell catalyst material, fuel cell electrode, membrane-electrode assembly, fuel cell, fuel cell catalyst material manufacturing method, and fuel cell electrode manufacturing method |
| JP2011008975A (en) * | 2009-06-23 | 2011-01-13 | Kyodo Printing Co Ltd | Electrode for dye-sensitized solar battery, method of manufacturing the same, and dye-sensitized solar cell |
| JP2015504588A (en) * | 2011-12-07 | 2015-02-12 | サン−ゴバン セラミックス アンド プラスティクス，インコーポレイティド | Solid oxide fuel cell product and formation method |
-
1992
- 1992-08-05 JP JP4209122A patent/JPH0656554A/en active Pending
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10189012A (en) * | 1996-12-20 | 1998-07-21 | Toyota Motor Corp | Electrode for fuel cell and power generation layer, and its manufacture |
| US7754370B2 (en) | 2002-08-21 | 2010-07-13 | Kabushiki Kaisha Toshiba | Fuel cell catalyst material, fuel cell electrode, membrane-electrode assembly, fuel cell, fuel cell catalyst material manufacturing method, and fuel cell electrode manufacturing method |
| JPWO2005068397A1 (en) * | 2004-01-13 | 2007-12-27 | イビデン株式会社 | Porous material for porous material, method for producing porous material for porous material, method for producing porous material, porous material and honeycomb structure |
| WO2005068397A1 (en) * | 2004-01-13 | 2005-07-28 | Ibiden Co., Ltd. | Pore-forming material for porous body, method for producing pore-forming material for porous body, method for producing porous body, porous body and honeycomb structure |
| EP1588995A1 (en) * | 2004-01-13 | 2005-10-26 | Ibiden Co., Ltd. | Pore-forming material for porous body, method for producing pore-forming material for porous body, method for producing porous body, porous body and honeycomb structure |
| EP1588995A4 (en) * | 2004-01-13 | 2008-02-20 | Ibiden Co Ltd | Pore-forming material for porous body, method for producing pore-forming material for porous body, method for producing porous body, porous body and honeycomb structure |
| US7473465B2 (en) | 2004-01-13 | 2009-01-06 | Ibiden Co., Ltd. | Honeycomb structure, porous body, pore forming material for the porous body, and methods for manufacturing the pore forming material, the porous body and the honeycomb structure |
| US7396586B2 (en) | 2004-01-13 | 2008-07-08 | Ibiden Co., Ltd. | Pore forming material for porous body, manufacturing method of pore forming material for porous body, manufacturing method of porous body, porous body, and honeycomb structural body |
| US7387829B2 (en) | 2004-01-13 | 2008-06-17 | Ibiden Co., Ltd. | Honeycomb structure, porous body, pore forming material for the porous body, and methods for manufacturing the pore forming material, the porous body and the honeycomb structure |
| JP2007250337A (en) * | 2006-03-15 | 2007-09-27 | Toppan Printing Co Ltd | Electrode catalyst layer for solid polyelectrolyte fuel cell, its manufacturing method and solid polyelectrolyte fuel cell |
| JP2008078020A (en) * | 2006-09-22 | 2008-04-03 | Toppan Printing Co Ltd | Electrode catalyst layer for polymer electrolyte fuel cell, its manufacturing method, and polymer electrolyte fuel cell |
| JP2008078074A (en) * | 2006-09-25 | 2008-04-03 | Toppan Printing Co Ltd | Electrode catalyst layer for polymer electrolyte fuel cell, its manufacturing method, and polymer electrolyte fuel cell |
| JP2008078075A (en) * | 2006-09-25 | 2008-04-03 | Toppan Printing Co Ltd | Electrode catalyst layer for polymer electrolyte fuel cell, its manufacturing method, and polymer electrolyte fuel cell |
| JP2011008975A (en) * | 2009-06-23 | 2011-01-13 | Kyodo Printing Co Ltd | Electrode for dye-sensitized solar battery, method of manufacturing the same, and dye-sensitized solar cell |
| JP2015504588A (en) * | 2011-12-07 | 2015-02-12 | サン−ゴバン セラミックス アンド プラスティクス，インコーポレイティド | Solid oxide fuel cell product and formation method |
| US9368823B2 (en) | 2011-12-07 | 2016-06-14 | Saint-Gobain Ceramics & Plastics, Inc. | Solid oxide fuel cell articles and methods of forming |
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