JPH0644996B2 - マイクロカプセル及びマイクロカプセル化法 - Google Patents
マイクロカプセル及びマイクロカプセル化法Info
- Publication number
- JPH0644996B2 JPH0644996B2 JP60066367A JP6636785A JPH0644996B2 JP H0644996 B2 JPH0644996 B2 JP H0644996B2 JP 60066367 A JP60066367 A JP 60066367A JP 6636785 A JP6636785 A JP 6636785A JP H0644996 B2 JPH0644996 B2 JP H0644996B2
- Authority
- JP
- Japan
- Prior art keywords
- prepolymer
- emulsion
- organic solution
- aqueous solution
- etherified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 47
- 239000003094 microcapsule Substances 0.000 title claims abstract description 23
- 239000000243 solution Substances 0.000 claims abstract description 55
- 239000007788 liquid Substances 0.000 claims abstract description 47
- 239000000839 emulsion Substances 0.000 claims abstract description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000007864 aqueous solution Substances 0.000 claims abstract description 31
- -1 methylol groups Chemical group 0.000 claims abstract description 26
- 239000002775 capsule Substances 0.000 claims abstract description 25
- 238000009833 condensation Methods 0.000 claims abstract description 15
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- 239000007787 solid Substances 0.000 claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 12
- 230000008569 process Effects 0.000 claims abstract description 11
- 230000005494 condensation Effects 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 239000002535 acidifier Substances 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 5
- 239000011347 resin Substances 0.000 claims abstract description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 54
- 239000004009 herbicide Substances 0.000 claims description 27
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- 239000006185 dispersion Substances 0.000 claims description 21
- 239000000126 substance Substances 0.000 claims description 20
- 239000000084 colloidal system Substances 0.000 claims description 17
- 239000004202 carbamide Substances 0.000 claims description 16
- 230000002363 herbicidal effect Effects 0.000 claims description 15
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical group CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 14
- 238000006266 etherification reaction Methods 0.000 claims description 14
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 14
- 230000001681 protective effect Effects 0.000 claims description 14
- 125000000217 alkyl group Chemical class 0.000 claims description 11
- 239000008346 aqueous phase Substances 0.000 claims description 11
- 150000001298 alcohols Chemical class 0.000 claims description 9
- 239000000729 antidote Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 6
- 150000007513 acids Chemical class 0.000 claims description 5
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims description 4
- 150000001447 alkali salts Chemical class 0.000 claims description 4
- 125000002877 alkyl aryl group Chemical class 0.000 claims description 4
- GNVMUORYQLCPJZ-UHFFFAOYSA-M Thiocarbamate Chemical compound NC([S-])=O GNVMUORYQLCPJZ-UHFFFAOYSA-M 0.000 claims description 3
- 239000012190 activator Substances 0.000 claims 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 abstract description 6
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- 229920001807 Urea-formaldehyde Polymers 0.000 abstract 3
- 238000011065 in-situ storage Methods 0.000 abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- 229910052760 oxygen Inorganic materials 0.000 description 17
- 239000012074 organic phase Substances 0.000 description 15
- 239000002904 solvent Substances 0.000 description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- 239000002270 dispersing agent Substances 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 10
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 9
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- 239000003607 modifier Substances 0.000 description 9
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 235000011121 sodium hydroxide Nutrition 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- BMTAFVWTTFSTOG-UHFFFAOYSA-N Butylate Chemical compound CCSC(=O)N(CC(C)C)CC(C)C BMTAFVWTTFSTOG-UHFFFAOYSA-N 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 230000002209 hydrophobic effect Effects 0.000 description 6
- 229920005610 lignin Polymers 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 159000000000 sodium salts Chemical class 0.000 description 6
- 238000000576 coating method Methods 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- DEDOPGXGGQYYMW-UHFFFAOYSA-N molinate Chemical compound CCSC(=O)N1CCCCCC1 DEDOPGXGGQYYMW-UHFFFAOYSA-N 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 229920003265 Resimene® Polymers 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000002917 insecticide Substances 0.000 description 4
- 239000003350 kerosene Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- XLNZEKHULJKQBA-UHFFFAOYSA-N terbufos Chemical compound CCOP(=S)(OCC)SCSC(C)(C)C XLNZEKHULJKQBA-UHFFFAOYSA-N 0.000 description 4
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 4
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 4
- MDBGGTQNNUOQRC-UHFFFAOYSA-N Allidochlor Chemical compound ClCC(=O)N(CC=C)CC=C MDBGGTQNNUOQRC-UHFFFAOYSA-N 0.000 description 3
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
- 230000006208 butylation Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- NAGJZTKCGNOGPW-UHFFFAOYSA-K dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [O-]P([O-])([S-])=S NAGJZTKCGNOGPW-UHFFFAOYSA-K 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 230000036515 potency Effects 0.000 description 3
- 238000013268 sustained release Methods 0.000 description 3
- 239000012730 sustained-release form Substances 0.000 description 3
- XLOPRKKSAJMMEW-SFYZADRCSA-M (R,R)-chrysanthemate Chemical compound CC(C)=C[C@@H]1[C@@H](C([O-])=O)C1(C)C XLOPRKKSAJMMEW-SFYZADRCSA-M 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- OKIJSNGRQAOIGZ-UHFFFAOYSA-N Butopyronoxyl Chemical compound CCCCOC(=O)C1=CC(=O)CC(C)(C)O1 OKIJSNGRQAOIGZ-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VEDTXTNSFWUXGQ-UHFFFAOYSA-N Carbophenothion Chemical compound CCOP(=S)(OCC)SCSC1=CC=C(Cl)C=C1 VEDTXTNSFWUXGQ-UHFFFAOYSA-N 0.000 description 2
- 241000254173 Coleoptera Species 0.000 description 2
- DFCAFRGABIXSDS-UHFFFAOYSA-N Cycloate Chemical compound CCSC(=O)N(CC)C1CCCCC1 DFCAFRGABIXSDS-UHFFFAOYSA-N 0.000 description 2
- WGOWCPGHOCIHBW-UHFFFAOYSA-N Dichlofenthion Chemical compound CCOP(=S)(OCC)OC1=CC=C(Cl)C=C1Cl WGOWCPGHOCIHBW-UHFFFAOYSA-N 0.000 description 2
- GUVLYNGULCJVDO-UHFFFAOYSA-N EPTC Chemical compound CCCN(CCC)C(=O)SCC GUVLYNGULCJVDO-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- PNVJTZOFSHSLTO-UHFFFAOYSA-N Fenthion Chemical compound COP(=S)(OC)OC1=CC=C(SC)C(C)=C1 PNVJTZOFSHSLTO-UHFFFAOYSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 238000012695 Interfacial polymerization Methods 0.000 description 2
- NEKOXWSIMFDGMA-UHFFFAOYSA-N Isopropalin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(C)C)C=C1[N+]([O-])=O NEKOXWSIMFDGMA-UHFFFAOYSA-N 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- ITVQAKZNYJEWKS-UHFFFAOYSA-N Profluralin Chemical compound [O-][N+](=O)C=1C=C(C(F)(F)F)C=C([N+]([O-])=O)C=1N(CCC)CC1CC1 ITVQAKZNYJEWKS-UHFFFAOYSA-N 0.000 description 2
- OKUGPJPKMAEJOE-UHFFFAOYSA-N S-propyl dipropylcarbamothioate Chemical compound CCCSC(=O)N(CCC)CCC OKUGPJPKMAEJOE-UHFFFAOYSA-N 0.000 description 2
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- MWBPRDONLNQCFV-UHFFFAOYSA-N Tri-allate Chemical compound CC(C)N(C(C)C)C(=O)SCC(Cl)=C(Cl)Cl MWBPRDONLNQCFV-UHFFFAOYSA-N 0.000 description 2
- ANIAQSUBRGXWLS-UHFFFAOYSA-N Trichloronat Chemical compound CCOP(=S)(CC)OC1=CC(Cl)=C(Cl)C=C1Cl ANIAQSUBRGXWLS-UHFFFAOYSA-N 0.000 description 2
- 150000003869 acetamides Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
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- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 229940075522 antidotes Drugs 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- HKPHPIREJKHECO-UHFFFAOYSA-N butachlor Chemical compound CCCCOCN(C(=O)CCl)C1=C(CC)C=CC=C1CC HKPHPIREJKHECO-UHFFFAOYSA-N 0.000 description 2
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- 235000014113 dietary fatty acids Nutrition 0.000 description 2
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- SPCNPOWOBZQWJK-UHFFFAOYSA-N dimethoxy-(2-propan-2-ylsulfanylethylsulfanyl)-sulfanylidene-$l^{5}-phosphane Chemical compound COP(=S)(OC)SCCSC(C)C SPCNPOWOBZQWJK-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/18—In situ polymerisation with all reactants being present in the same phase
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Dentistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Plant Pathology (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Lubricants (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US59513684A | 1984-03-30 | 1984-03-30 | |
| US595136 | 1984-03-30 | ||
| EP85301744A EP0158449B1 (en) | 1984-03-30 | 1985-03-13 | Microcapsules and microencapsulation process |
| CN85101429A CN85101429B (zh) | 1984-03-30 | 1985-04-01 | 微型胶囊及包微型胶囊的过程 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60225633A JPS60225633A (ja) | 1985-11-09 |
| JPH0644996B2 true JPH0644996B2 (ja) | 1994-06-15 |
Family
ID=27178822
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60066367A Expired - Fee Related JPH0644996B2 (ja) | 1984-03-30 | 1985-03-29 | マイクロカプセル及びマイクロカプセル化法 |
Country Status (16)
| Country | Link |
|---|---|
| EP (1) | EP0158449B1 (OSRAM) |
| JP (1) | JPH0644996B2 (OSRAM) |
| CN (1) | CN85101429B (OSRAM) |
| AT (1) | ATE30522T1 (OSRAM) |
| AU (1) | AU580289B2 (OSRAM) |
| BR (1) | BR8501403A (OSRAM) |
| DE (1) | DE3560861D1 (OSRAM) |
| DZ (1) | DZ764A1 (OSRAM) |
| EG (1) | EG17053A (OSRAM) |
| ES (1) | ES8605392A1 (OSRAM) |
| GR (1) | GR850802B (OSRAM) |
| HU (1) | HU194749B (OSRAM) |
| MX (1) | MX161395A (OSRAM) |
| RO (1) | RO91881A (OSRAM) |
| TR (1) | TR22336A (OSRAM) |
| YU (1) | YU45710B (OSRAM) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5160529A (en) * | 1980-10-30 | 1992-11-03 | Imperial Chemical Industries Plc | Microcapsules and microencapsulation process |
| AU641694B2 (en) * | 1989-09-28 | 1993-09-30 | Sandoz Ltd. | Microencapsulated agricultural chemicals |
| US5462915A (en) * | 1989-09-28 | 1995-10-31 | Sandoz Ltd. | Process for producing microcapsules |
| JPH04364101A (ja) * | 1991-06-12 | 1992-12-16 | Mitsui Toatsu Chem Inc | 殺虫組成物及びその製造方法 |
| IL104425A (en) * | 1992-01-22 | 1996-10-31 | Zeneca Ltd | Reducing the content of formaldehyde in tiny capsule preparations |
| CN1103540C (zh) * | 1993-11-15 | 2003-03-26 | 泽尼卡有限公司 | 含生物活性化合物悬浮液的微囊 |
| DE4434638A1 (de) * | 1994-09-28 | 1996-04-04 | Hoechst Schering Agrevo Gmbh | Mikroverkapselte Pflanzenschutzmittel, ein Verfahren zu ihrer Herstellung sowie ihre Verwendung |
| US6022501A (en) * | 1996-08-15 | 2000-02-08 | American Cyanamid Company | pH-sensitive microcapsules |
| JPH11322587A (ja) * | 1998-05-18 | 1999-11-24 | Sumitomo Chem Co Ltd | 常温で固体の生理活性物質のマイクロカプセル化方法およびこの方法により得られるマイクロカプセル組成物 |
| DE69907206T2 (de) * | 1998-07-29 | 2003-10-23 | Syngenta Ltd., Haselmere | Mikrokapseln mit von basen ausgelöste freisetzung |
| JP2000342956A (ja) * | 1999-04-01 | 2000-12-12 | Dai Ichi Kogyo Seiyaku Co Ltd | マイクロカプセルの製法およびそれによって得られたマイクロカプセル |
| ATE261764T1 (de) * | 1999-09-10 | 2004-04-15 | Syngenta Ltd | Mikrokapseln mit veränderlicher freisetzung |
| US7045562B2 (en) * | 2003-10-16 | 2006-05-16 | International Business Machines Corporation | Method and structure for self healing cracks in underfill material between an I/C chip and a substrate bonded together with solder balls |
| CN1307878C (zh) * | 2005-07-07 | 2007-04-04 | 云南大学 | 一种印楝素微胶囊的悬浮液配方 |
| CN101731210B (zh) * | 2008-11-05 | 2013-03-27 | 河北农业大学 | 界面聚合法制备农药微胶囊的工艺 |
| CN103351256A (zh) * | 2013-07-23 | 2013-10-16 | 苏州仁成生物科技有限公司 | 一种复合微胶囊保水肥料及其制备方法 |
| CN103396211A (zh) * | 2013-07-23 | 2013-11-20 | 苏州仁成生物科技有限公司 | 一种罗勒专用微胶囊有机肥及其制备方法 |
| CN103351257A (zh) * | 2013-07-23 | 2013-10-16 | 苏州仁成生物科技有限公司 | 一种人参微胶囊肥及其制备方法 |
| US9610228B2 (en) | 2013-10-11 | 2017-04-04 | International Flavors & Fragrances Inc. | Terpolymer-coated polymer encapsulated active material |
| CN103539545A (zh) * | 2013-10-16 | 2014-01-29 | 苏州市石桥生态农业科技园（普通合伙） | 一种含香椿有机微胶囊肥料 |
| CN104560398A (zh) | 2013-10-18 | 2015-04-29 | 国际香料和香精公司 | 杂合芳香包封制剂及其使用方法 |
| CN115089512B (zh) | 2016-02-18 | 2024-08-27 | 国际香料和香精公司 | 聚脲胶囊组合物 |
| EP4438132A3 (en) | 2016-07-01 | 2025-01-15 | International Flavors & Fragrances Inc. | Stable microcapsule compositions |
| EP4209264A1 (en) | 2016-09-16 | 2023-07-12 | International Flavors & Fragrances Inc. | Microcapsule compositions stabilized with viscosity control agents |
| US20180085291A1 (en) | 2016-09-28 | 2018-03-29 | International Flavors & Fragrances Inc. | Microcapsule compositions containing amino silicone |
| BR112021011903A2 (pt) | 2018-12-18 | 2021-08-31 | International Flavors & Fragrances Inc. | Composição de microcápsula, produto de consumo, e, processo para preparar uma composição de microcápsula |
| CN110511815A (zh) * | 2019-08-29 | 2019-11-29 | 华南理工大学 | 一种沉香提取物及其制备方法与应用 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH540715A (de) * | 1970-05-26 | 1973-10-15 | Ciba Geigy Ag | Verfahren zur Einkapselung von in einer Flüssigkeit fein verteilter Substanz |
| US3779941A (en) * | 1970-07-17 | 1973-12-18 | Champion Int Corp | Water-resistant microcapsular opacifier system and products |
-
1985
- 1985-03-13 AT AT85301744T patent/ATE30522T1/de not_active IP Right Cessation
- 1985-03-13 EP EP85301744A patent/EP0158449B1/en not_active Expired
- 1985-03-13 DE DE8585301744T patent/DE3560861D1/de not_active Expired
- 1985-03-20 AU AU40139/85A patent/AU580289B2/en not_active Ceased
- 1985-03-26 EG EG19585A patent/EG17053A/xx active
- 1985-03-27 BR BR8501403A patent/BR8501403A/pt not_active IP Right Cessation
- 1985-03-27 TR TR14840/85A patent/TR22336A/xx unknown
- 1985-03-28 DZ DZ850070A patent/DZ764A1/fr active
- 1985-03-28 RO RO85118176A patent/RO91881A/ro unknown
- 1985-03-28 MX MX204772A patent/MX161395A/es unknown
- 1985-03-29 YU YU51785A patent/YU45710B/sh unknown
- 1985-03-29 GR GR850802A patent/GR850802B/el unknown
- 1985-03-29 ES ES541755A patent/ES8605392A1/es not_active Expired
- 1985-03-29 HU HU851216A patent/HU194749B/hu not_active IP Right Cessation
- 1985-03-29 JP JP60066367A patent/JPH0644996B2/ja not_active Expired - Fee Related
- 1985-04-01 CN CN85101429A patent/CN85101429B/zh not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BR8501403A (pt) | 1985-11-26 |
| JPS60225633A (ja) | 1985-11-09 |
| RO91881A (ro) | 1987-06-30 |
| AU580289B2 (en) | 1989-01-12 |
| HUT41274A (en) | 1987-04-28 |
| EP0158449B1 (en) | 1987-11-04 |
| EP0158449A1 (en) | 1985-10-16 |
| TR22336A (tr) | 1987-02-16 |
| MX161395A (es) | 1990-09-20 |
| DZ764A1 (fr) | 2004-09-13 |
| AU4013985A (en) | 1985-10-03 |
| EG17053A (en) | 1993-12-30 |
| DE3560861D1 (en) | 1987-12-10 |
| YU45710B (sh) | 1992-07-20 |
| GR850802B (OSRAM) | 1985-07-23 |
| ATE30522T1 (de) | 1987-11-15 |
| CN85101429B (zh) | 1988-08-17 |
| HU194749B (en) | 1988-03-28 |
| CN85101429A (zh) | 1987-01-17 |
| YU51785A (en) | 1987-12-31 |
| ES8605392A1 (es) | 1986-03-16 |
| ES541755A0 (es) | 1986-03-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |