JPH06346180A - Valve guide member made of fe-base sintered alloy, excellent in wear resistance - Google Patents

Abstract

PURPOSE:To produce a valve guide member made of Fe-base sintered alloy, excellent in wear resistance. CONSTITUTION:The valve guide member for internal combustion engine is composed of an Fe-base sintered alloy having a composition consisting of, by weight, 1-4% C, 1.5-6% Cu, 0.1-0.8% P, 0.2-4% Mn, 0.05-1% S, and the balance Fe with inevitable impurities and also having a structure in which hard Fe-C-P compound, MnS, and free graphite are dispersed and distributed in a matrix composed essentially of pearlite. Moreover, the theoretical density rat.io at the end on one side or at the ends on both sides is regulated to 87-97%, and further, the theoretical density ratio in the part on the other side or the central part is regulated to 79-85%.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an Fe-based sintered alloy valve guide member for an internal combustion engine that exhibits excellent wear resistance.

[0002]

2. Description of the Related Art It is well known that many Fe-based sintered alloys have been conventionally applied to the manufacture of valve guide members for internal combustion engines.

[0003]

On the other hand, in recent years, the high output and high speed of internal combustion engines have been remarkable, and along with this,
The conditions of use of these structural members become even more severe, and especially for valve guide members that undergo severe sliding wear with the valve that is inserted into the center hole and reciprocates, the wear resistance is further improved. Although many conventional Fe-based sintered alloy valve guide members do not exhibit sufficient wear resistance to meet these requirements, the development of valve guide members that exhibit excellent wear resistance in a stable manner is required. Is desired.

[0004]

Therefore, the present inventors have
From the above viewpoints, as a result of research to develop a valve guide member made of an Fe-based sintered alloy having excellent wear resistance, the valve guide member of an internal combustion engine is expressed in weight% (hereinafter,
% Represents% by weight), C: 1 to 4%, Cu:
1.5-6%, P: 0.1-0.8%, Mn: 0.2
% To 4%, S: 0.05 to 1%, and the balance consisting of Fe and unavoidable impurities, and a matrix mainly composed of pearlite, a hard Fe-CP compound, manganese sulfide (hereinafter , MnS), and Fe-based sintered alloy having a structure in which free graphite is dispersed, and one side end or both side ends, preferably one side end (that is, only the valve seat side) In case of 1) of the total length
/ 5 to 1/2, 1 / of the total length for both ends
The theoretical density ratio of the length of 5 to 1/3 is relatively 87 to 9
If the structure is such that the density is 7% and the theoretical density ratio of the other side portion or the central portion is low density of 79 to 85%, the resulting Fe-based sintered alloy valve guide member is Of the hard Fe-C-P compound dispersed in the core and the high density portion formed at one end or both ends, and improvement of self-lubricity due to MnS and free graphite also dispersed in the base. In addition, the research results show that the low-density portion formed on the other side or the central portion, combined with the improvement of the oil retaining effect, exhibits excellent wear resistance even in practical use under severe conditions.

The present invention has been made based on the above-mentioned research results. C: 1 to 4%, C
u: 1.5-6%, P: 0.1-0.8%, Mn:
0.2 to 4%, S: 0.05 to 1%, with the balance consisting of Fe and inevitable impurities, and a base mainly composed of pearlite, a hard Fe-CP compound, Mn.
It is composed of a Fe-based sintered alloy having a structure in which S and free graphite are dispersed and distributed, and the theoretical density ratio of one end or both ends is set to 87 to 97%, and the theoretical density ratio of the other end or the central part. It is characterized by a valve guide member having excellent wear resistance, which is 79 to 85%.

Next, the reason why the composition and the theoretical density ratio of the Fe-based sintered alloy constituting the valve guide member of the present invention are limited as described above will be explained. A. Composition (a) In the CC component, pearlite of the base material is formed and strengthened, and a hard Fe-C-P-based compound is formed to improve the hardness. It has a function of improving the self-lubricating property by being distributed, and thus improving the wear resistance of the member. However, if the content is less than 1%, the desired improving effect on the function cannot be obtained, while the content is 4%. If it exceeds 0.1%, it becomes brittle and the desired strength cannot be obtained. Therefore, the content is defined as 1 to 4%.

(B) Cu The Cu component has a function of forming a solid solution in the matrix to strengthen it and stabilize the pearlite matrix, but if the content thereof is less than 1.5%, it is desirable for the above-mentioned effect. However, even if the content exceeds 6%, no further improvement effect is obtained due to the above-mentioned action, and rather the material becomes brittle, so the content is 1.5-6. Defined as%.

(C) The P P component not only improves the sinterability and contributes to the strength improvement, but also has the action of forming a Fe--C--P compound as described above to improve the wear resistance. , Its content is 0.1
If the content is less than 0.1%, the desired effect cannot be obtained, while if the content exceeds 0.8%, the base material is excessively hardened and coarse Fe-C-P compounds tend to precipitate. Since the machinability is significantly deteriorated, its content is set to 0.1
It was set at 0.8%.

(D) Mn and S Both of these components mainly exist as MnS dispersedly distributed in the base material to enhance self-lubricating property, thereby contributing to the improvement of wear resistance of the member and the action of improving machinability. With
Their contents are Mn: less than 0.2% and S :, respectively.
If it is less than 0.05%, a slight solid solution in the matrix is unavoidable, so the ratio as MnS becomes less than 0.2%, and the desired improving effect on the above-mentioned action cannot be obtained. When the content of Mn is 4% and the content of S is 1%, the distribution ratio of MnS becomes too large, and as a result, the strength of the member is reduced. 2-4%, S: 0.05-1%
I decided.

B. Theoretical Density Ratio By increasing the density of one end or both ends of the valve guide member, the hardness of this part is further increased, while at the same time, the oil-retaining effect is sufficiently exhibited in the low-density part, and therefore the wear resistance is improved. Although it is possible to contribute to the improvement, if the theoretical density ratio of the high density portion is less than 87%, sufficient hardness cannot be improved. On the other hand, in order to increase it to more than 97%, the compacting pressure of the green compact is increased. It is necessary to increase the sintering temperature as well as the sintering temperature, which shortens the service life of the molding die and reduces the dimensional accuracy after sintering. When the ratio is less than 79%, the strength of the valve guide member decreases, and cracks are likely to occur during press-fitting and mounting to the cylinder head, while when the theoretical density ratio exceeds 85%, the desired oil retaining effect is obtained. Is not possible and wear progress is promoted. Therefore, the theoretical density ratio of the high density portion is 87 to 97% and that of the low density portion is 79%.
~ 85%.

[0011]

EXAMPLES Next, the valve guide member of the present invention will be specifically described by way of examples. As raw material powder, particle size:-
80mesh Fe powder, same-150mesh carbon powder, same-
Cu powder of 100 mesh, Fe-27% of -150 mesh
P alloy powder, Cu-8% P alloy powder of the same -200 mesh,
And -200 mesh of MnS powder, these raw material powders were mixed in a predetermined mixing ratio, 1% of zinc stearate was added and mixed in a V-type mixer for 30 minutes, and then these mixed powders were mixed with each other as shown in FIG. As shown in the schematic vertical cross-sectional view in (a), the inside of the die 1 passes through the center hole of the die 1, the upper surface of the lower punch 2 fitted into the center hole from below, and the center hole of the lower punch 2. When the core rod 3 is inserted into the cavity formed by the outer peripheral surface of the core rod 3 and then a high-density portion is formed at one end, the pressure is 5 to 7 ton / s as shown in (b). Adjust within the range of cm ² ,
When the upper punch 4 is press-fitted into the center hole of the die 1 while the stroke is also adjusted and high-density portions are formed at both ends, the pressure and stroke are adjusted as shown in (c). Meanwhile, the lower punch 2 is fixed, the upper punch 4, the die 1, and the core rod 3 are lowered at predetermined strokes to press-mold the green compacts S and S ', respectively. In the decomposed gas atmosphere of, the temperature is kept at 650 ° C. for 20 minutes for degreasing, and then the temperature is raised to a predetermined temperature within a range of 1050 to 1150 ° C.
By holding at this temperature for 60 minutes to sinter, and after finishing the sintering, the composition has the composition shown in Tables 1 and 2, both of which have a hard F base on a pearlite-based substrate.
It is composed of a Fe-based sintered alloy having a structure in which the e-C-P compound, MnS, and free graphite are dispersed and distributed, and one end or both ends are defined as theoretical density ratios shown in Tables 1 and 2. , Further length: 50mm × outer diameter: 12mm × inner diameter:
The present invention Fe-based sintered alloy valve guide member having a dimension of 6.6 mm (hereinafter referred to as the present invention sintered bubble guide) 1
To 11 and the content of any one of the alloy constituents, or the theoretical density ratio at one end or both ends is outside the scope of the present invention, a comparative Fe-based sintered alloy valve guide member (hereinafter, (Comparative sintering valve guide) 1-
6 were produced respectively.

[0012]

[Table 1]

[0013]

[Table 2]

Then, various sintered valve guides obtained as a result are press-fitted with the high density portion positioned on the valve seat side on the exhaust side of the Al cast cylinder head of a DOHC engine with a displacement of 2000cc. Then, using the unleaded gasoline as the fuel with the finished inner diameter, a real machine test was performed at 6000 rpm for 380 hours, and the inner diameter at the inner surface position 5 mm from the edge on the valve seat side was measured. Was measured, and the change in inner diameter after the test with respect to the inner diameter before the test was measured as the wear amount. The measurement results are shown in Tables 1 and 2.

[0015]

From the results shown in Tables 1 and 2, the sintered valve guides 1 to 11 of the present invention all show excellent wear resistance in spite of extremely high speed continuous operation for a long time. As can be seen from Comparative Sintered Valve Guides 1 to 6, if any of the component composition and the theoretical density ratio of the Fe-based sintered alloy constituting it deviates from the scope of the present invention, the desired excellent resistance is obtained. It is clear that the wear resistance cannot be ensured. As described above, Fe of the present invention
A valve guide member made of a base sintered alloy exhibits excellent wear resistance even when used under severe conditions, and has characteristics capable of sufficiently responding to high performance and high speed of an internal combustion engine.

[Brief description of drawings]

FIG. 1 is a schematic vertical cross-sectional view showing a press forming process of a green compact.

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Claims (2)

[Claims] 1. By weight%, C: 1 to 4%, Cu: 1.5 to 6%, P: 0.1 to 0.8%, Mn: 0.2 to 4%, S: 0.05 % To 1%, the balance consisting of Fe and unavoidable impurities, and a structure mainly composed of pearlite, in which a hard Fe-CP compound, manganese sulfide, and free graphite are dispersed and distributed. It is made of a Fe-based sintered alloy and has a theoretical density ratio of 87 to 97% at one end.
And a theoretical density ratio of the other side portion is set to 79 to 85%, which is an Fe-based sintered alloy valve guide member having excellent wear resistance. 2. By weight%, C: 1 to 4%, Cu: 1.5 to 6%, P: 0.1 to 0.8%, Mn: 0.2 to 4%, S: 0.05 % To 1%, the balance consisting of Fe and unavoidable impurities, and a structure mainly composed of pearlite, in which a hard Fe-CP compound, manganese sulfide, and free graphite are dispersed and distributed. Fe-based sintered alloy having excellent wear resistance, which is made of a Fe-based sintered alloy and has a theoretical density ratio of 87 to 97% at both end portions and a theoretical density ratio of 79 to 85% at a central portion. Bonded valve guide member.