JPH0633284A - Water electrolytic cell - Google Patents
Water electrolytic cellInfo
- Publication number
- JPH0633284A JPH0633284A JP4186706A JP18670692A JPH0633284A JP H0633284 A JPH0633284 A JP H0633284A JP 4186706 A JP4186706 A JP 4186706A JP 18670692 A JP18670692 A JP 18670692A JP H0633284 A JPH0633284 A JP H0633284A
- Authority
- JP
- Japan
- Prior art keywords
- gas
- sides
- water electrolysis
- water electrolytic
- feeders
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は水電解セルに関し、さら
に詳しくは気液流路機能をもった給電体を用いた固体高
分子電解質水電解セルの構造に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a water electrolysis cell, and more particularly to a structure of a solid polymer electrolyte water electrolysis cell using a power feeder having a gas-liquid flow path function.
【0002】[0002]
【従来の技術】近年、高効率で水の電気分解が可能な固
体高分子電解質を利用した方法が注目されている。図2
は固体高分子電解質を用いた水電解セルの原理を示す概
略断面図である。図2において、11は固体高分子電解
質水電解セルであり、固体高分子電解質1の両面に触媒
電極2,3を接合し、その両側に多孔性の給電体4,
5、さらにその両側に通電用端子板7,8を設けてお
り、固体高分子電解質1で仕切られた陽極室10と陰極
室9より構成されている。陽極室10へ水を供給し電極
間に直流電流を印加すると、水の電気分解が起こり陽極
室10にて、O2 ガスが発生し、同時に分離された水素
イオンH+ が固体高分子電解質1を通って陰極室9へ向
い、水素イオンH+ が陰極室9で電子e- を得てH2 ガ
スとなる。2. Description of the Related Art Recently, a method using a solid polymer electrolyte capable of electrolyzing water with high efficiency has attracted attention. Figure 2
FIG. 3 is a schematic cross-sectional view showing the principle of a water electrolysis cell using a solid polymer electrolyte. In FIG. 2, reference numeral 11 denotes a solid polymer electrolyte water electrolysis cell, in which catalyst electrodes 2 and 3 are joined to both surfaces of a solid polymer electrolyte 1 and porous power supply members 4 and 4 are provided on both sides thereof.
5 and further provided with energizing terminal plates 7 and 8 on both sides thereof, which are composed of an anode chamber 10 and a cathode chamber 9 partitioned by the solid polymer electrolyte 1. When water is supplied to the anode chamber 10 and a direct current is applied between the electrodes, electrolysis of water occurs, O 2 gas is generated in the anode chamber 10, and at the same time, the separated hydrogen ions H + are solid polymer electrolyte 1 The hydrogen ion H + obtains an electron e − in the cathode chamber 9 and becomes H 2 gas.
【0003】図3は水電解セルを積層した場合の概略断
面図である。固体高分子電解質1の両面に触媒電極2,
3を接合した膜電極接合体の両側に給電体4,5が配置
されている。給電体の材質としては陽極側に白金めっき
したチタンメッシュ(気孔率53.5%)、陰極側には
多孔質のカーボン板(気孔率70%)を用いている。6
は複極板と呼ばれるもので積層化するために用いられ、
ガスの流路を確保するため、両面に溝加工を施したチタ
ン板を使用している。FIG. 3 is a schematic sectional view of a case where water electrolysis cells are laminated. Catalytic electrodes 2 on both sides of the solid polymer electrolyte 1
Feeders 4 and 5 are arranged on both sides of the membrane electrode assembly in which 3 is joined. As the material of the power supply body, a platinum mesh titanium mesh (porosity 53.5%) is used on the anode side, and a porous carbon plate (porosity 70%) is used on the cathode side. 6
Is called a bipolar plate and is used for stacking,
A titanium plate with grooves on both sides is used to secure the gas flow path.
【0004】[0004]
【発明が解決しようとする課題】しかしながら、上記の
従来型水電解セルにおいては陰極、陽極両通電板及び複
極板の構造が、溝加工が施してある複雑な構造をしてお
り、その加工費のために水電解セルのコストアップの大
きな要因となっている。However, in the above-mentioned conventional water electrolysis cell, the structure of the cathode and anode current-carrying plates and the bipolar plate has a complicated structure in which grooves are formed. This is a major factor in increasing the cost of the water electrolysis cell due to the cost.
【0005】本発明は上記技術水準に鑑み、通電板、複
極板の構造が簡素化できる水電解セルを提供しようとす
るものである。In view of the above-mentioned state of the art, the present invention aims to provide a water electrolysis cell in which the structures of the current-carrying plate and the bipolar plate can be simplified.
【0006】[0006]
【課題を解決するための手段】本発明は固体高分子電解
質の両面に触媒電極を接合し、更にその両側に給電体と
通電用端子板を配置した水電解装置において、給電体と
して気液流路機能をもった夫々気孔率95%以上の発泡
金属及び多孔質カーボンを用いてなる水電解セルであ
る。DISCLOSURE OF THE INVENTION The present invention relates to a water electrolysis apparatus in which a catalyst electrode is joined to both sides of a solid polymer electrolyte, and a power feeding body and an energizing terminal plate are arranged on both sides of the catalyst electrode. It is a water electrolysis cell using a foam metal and porous carbon each having a channel function and having a porosity of 95% or more.
【0007】すなわち、本発明は給電体として、非常に
気液透過性のよい発泡金属及び多孔質カーボンを用い、
給電体自身に気液流路機能をもたせたものである。That is, the present invention uses a foam metal and porous carbon, which have very good gas-liquid permeability, as a power supply,
The power supply body itself has a gas-liquid flow path function.
【0008】[0008]
【作用】上記のように給電体自身に気液流路をもたせる
ことにより、通電板及び複極板に溝加工をする必要がな
くなり、セルの構造を簡素化することができる。また、
従来の溝加工に比べ、本発明で用いる給電体は発泡金属
又は多孔質カーボンであるので、表面がなめらかで、膜
電極接合体との接触性もよくなる。By providing the gas feeder with the gas-liquid flow path itself as described above, it is not necessary to form grooves on the current-carrying plate and the bipolar plate, and the structure of the cell can be simplified. Also,
Compared to the conventional groove processing, since the power supply body used in the present invention is a foam metal or porous carbon, the surface is smooth and the contact property with the membrane electrode assembly is improved.
【0009】[0009]
【実施例】以下本発明の一実施例を図1に基づいて説明
する。図1は、本発明に係る積層した場合の水電解セル
の概略断面図である。この水電解セルの各部分は、接し
て配置されているが、図1においては各部分の間隔を開
けた状態で示している。図1において4,5が本発明で
用いた発泡金属製の給電体である。発泡金属はそれ自体
気液流路機能を備えているので、図1のように、両極通
電板7,8及び複極板6に複数の溝加工をすることな
く、給電体4,5を装着できる広い凹みを付けたもので
す。又、図示省略するが、両極通電板7,8及び複極板
6はまったく凹み等は加工せず平板としてもよい。これ
らの給電体4,5は気孔率95%以上で、チタン及びニ
ッケル等の発泡金属製としている。又、この給電体の陰
極側にはカーボンの多孔質体を使用することも可能であ
るが、この時の気孔率は95%以上を確保しなければな
らない。言い変えれば、気孔率95%以上であれば使用
できる。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below with reference to FIG. FIG. 1 is a schematic sectional view of a water electrolysis cell when laminated according to the present invention. The respective parts of this water electrolysis cell are arranged in contact with each other, but in FIG. In FIG. 1, reference numerals 4 and 5 are foamed metal power feeders used in the present invention. Since the metal foam itself has a gas-liquid flow path function, as shown in FIG. 1, the power feeding bodies 4 and 5 are mounted on the bipolar current carrying plates 7 and 8 and the bipolar plate 6 without making a plurality of grooves. It has a wide dent. Further, although not shown in the drawings, the bipolar current-carrying plates 7 and 8 and the bipolar plate 6 may be flat plates without processing any recesses or the like. These power feeders 4 and 5 have a porosity of 95% or more and are made of foam metal such as titanium and nickel. It is also possible to use a carbon porous body on the cathode side of this power supply, but the porosity at this time must be 95% or more. In other words, if the porosity is 95% or more, it can be used.
【0010】[0010]
【発明の効果】本発明のように、気液流路機能を備えた
発泡金属及び多孔質カーボンを給電体として用いると、
通電板、複極板の構造が簡素化でき、水電解セル全体と
して、大幅な製作コストの低減が図れる。また従来の溝
加工に比べ、膜電極接合体との接触性も向上し、性能向
上の要因ともなる。As in the present invention, when the foam metal and the porous carbon having the gas-liquid flow path function are used as the power supply,
The structure of the current-carrying plate and the bipolar plate can be simplified, and the manufacturing cost of the water electrolysis cell as a whole can be significantly reduced. Further, as compared with the conventional groove processing, the contact property with the membrane electrode assembly is improved, which is also a factor for improving the performance.
【図1】本発明の一実施例の水電解セルの説明図。FIG. 1 is an explanatory diagram of a water electrolysis cell according to an embodiment of the present invention.
【図2】従来の固体高分子電解質水電解セルの説明図。FIG. 2 is an explanatory view of a conventional solid polymer electrolyte water electrolysis cell.
【図3】図2の水電解セルを積層した場合の説明図。FIG. 3 is an explanatory view when the water electrolysis cells of FIG. 2 are stacked.
Claims (1)
合し、更にその両側に給電体と通電用端子板を配置した
水電解装置において、給電体として気液流路機能をもっ
た夫々気孔率95%以上の発泡金属及び多孔質カーボン
を用いてなる水電解セル。1. A water electrolysis device in which a catalyst electrode is joined to both sides of a solid polymer electrolyte, and a power supply and an energizing terminal plate are arranged on both sides of the solid polymer electrolyte, and each pore has a gas-liquid flow path function as a power supply. A water electrolysis cell using a metal foam and a porous carbon having a rate of 95% or more.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4186706A JPH0633284A (en) | 1992-07-14 | 1992-07-14 | Water electrolytic cell |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4186706A JPH0633284A (en) | 1992-07-14 | 1992-07-14 | Water electrolytic cell |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0633284A true JPH0633284A (en) | 1994-02-08 |
Family
ID=16193214
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP4186706A Pending JPH0633284A (en) | 1992-07-14 | 1992-07-14 | Water electrolytic cell |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0633284A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006348330A (en) * | 2005-06-14 | 2006-12-28 | Mitsubishi Materials Corp | Porous titanium with skeleton surface having titanium carbonitride layer thereon |
JP2006348329A (en) * | 2005-06-14 | 2006-12-28 | Mitsubishi Materials Corp | Porous titanium having titanium carbide layer on surface of skeleton, and method for producing the same |
JP2010059506A (en) * | 2008-09-04 | 2010-03-18 | Dainippon Printing Co Ltd | Electrolysis cell for generating hydrogen, and electrolysis cell stack for generating hydrogen |
MD4207C1 (en) * | 2011-10-10 | 2013-09-30 | Государственный Университет Молд0 | Process for manufacturing a combined volume-porous flow-through electrode and process for electrolytic production of hydrogen |
JP2018090899A (en) * | 2016-12-06 | 2018-06-14 | パナソニックIpマネジメント株式会社 | Electrochemical hydrogen pump |
-
1992
- 1992-07-14 JP JP4186706A patent/JPH0633284A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006348330A (en) * | 2005-06-14 | 2006-12-28 | Mitsubishi Materials Corp | Porous titanium with skeleton surface having titanium carbonitride layer thereon |
JP2006348329A (en) * | 2005-06-14 | 2006-12-28 | Mitsubishi Materials Corp | Porous titanium having titanium carbide layer on surface of skeleton, and method for producing the same |
JP2010059506A (en) * | 2008-09-04 | 2010-03-18 | Dainippon Printing Co Ltd | Electrolysis cell for generating hydrogen, and electrolysis cell stack for generating hydrogen |
MD4207C1 (en) * | 2011-10-10 | 2013-09-30 | Государственный Университет Молд0 | Process for manufacturing a combined volume-porous flow-through electrode and process for electrolytic production of hydrogen |
JP2018090899A (en) * | 2016-12-06 | 2018-06-14 | パナソニックIpマネジメント株式会社 | Electrochemical hydrogen pump |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20001107 |