JPH0630951B2 - Recording material - Google Patents
Recording materialInfo
- Publication number
- JPH0630951B2 JPH0630951B2 JP59182171A JP18217184A JPH0630951B2 JP H0630951 B2 JPH0630951 B2 JP H0630951B2 JP 59182171 A JP59182171 A JP 59182171A JP 18217184 A JP18217184 A JP 18217184A JP H0630951 B2 JPH0630951 B2 JP H0630951B2
- Authority
- JP
- Japan
- Prior art keywords
- recording
- recording material
- ink
- polyallylamine
- ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
Landscapes
- Printing Methods (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Duplication Or Marking (AREA)
- Paper (AREA)
Description
【発明の詳細な説明】 ［産業上の利用分野］ 本発明は、インクによる記録に用いられる被記録材（記
録用紙）に関し、特にインクの発色性が優れ、高解像度
で耐水性のある記録画像を形成する被記録材に関する。Description: TECHNICAL FIELD The present invention relates to a recording material (recording paper) used for recording with ink, and particularly to a recorded image having excellent ink color development, high resolution and water resistance. And a recording material for forming the recording medium.
［従来の技術］ 記録液を使用して記録を行う方式は、例えば万年筆によ
る筆記などが古くから一般的なものであるが、最近で
は、いわゆるインクジェット記録方式も出現しここにも
記録液が使用されている。[Prior Art] A method of recording using a recording liquid has been popular since, for example, writing with a fountain pen has been popular for a long time, but recently, a so-called inkjet recording system has also appeared and the recording liquid is used here. Has been done.
インクジェット記録法は、種々の作動原理により記録液
の小滴を発生させ、これを飛翔させて紙などの被記録材
に付着させて記録を行なうものであるが、騒音の発生が
少なく、高速印字、多色印字の行える記録法として注目
されている。インクジェット記録用の記録液としては、
安全性、印刷適正の面から主に水系のものが使用されて
いる。The ink jet recording method is a method in which small droplets of a recording liquid are generated by various operating principles, and the droplets are ejected to adhere to a recording material such as paper for recording, but there is little noise and high-speed printing. , Has attracted attention as a recording method capable of multicolor printing. As a recording liquid for inkjet recording,
Water-based materials are mainly used in terms of safety and printability.
このインクジェット記録法に使用される被記録材として
は、従来通常の紙が一般的に使用されてきた。しかし、
記録の高速化あるいは多色化など、インクジェット機の
性能の向上に伴い、インクジェット用の被記録材に対し
ても、より高度な特性が要求されつつある。すなわち、
カラー写真に匹敵する程度の高解像度、高品質の記録画
質を得るための被記録材としては、 （１）インクの吸収が可及的速やかであること、 （２）インクドットが重なった際に、後で付着したイン
クが前のドットに流れ出さないこと、 （３）インクドットの径が必要以上に大きくならないこ
と、 （４）インクドットの形状が真円に近く、またその周辺
が滑らかであること、 （５）インクドットの濃度が高く、ドット周辺がぼけな
いこと、 （６）インクの発色性が優れたものであること、 等の諸要求を満たすものであることが必要とされる。As a recording material used in this ink jet recording method, conventional ordinary paper has been generally used. But,
Along with the improvement in the performance of the inkjet machine, such as the speeding up of recording or the multicoloring, more advanced characteristics are required for the recording material for inkjet. That is,
As a recording material for obtaining high resolution and high quality recording image quality comparable to that of a color photograph, (1) ink is absorbed as quickly as possible, (2) when ink dots overlap. , The ink attached later does not flow out to the previous dot, (3) the diameter of the ink dot does not become larger than necessary, (4) the shape of the ink dot is close to a perfect circle, and its periphery is smooth. It is necessary to meet various requirements such as: (5) high density of ink dots and no blur around the dots, (6) excellent color development of ink, etc. .
しかしながら、これ等要求性能を全て満たした被記録材
は未だ見当らないのが実状である。例えば、特開昭52-7
4340号記載のインクジェット記録用紙は、インクの吸収
は速やかであるが、ドット径が大きくなりやすく、ドッ
トの周辺がぼけやすい。また記録後の紙の寸法変化が大
きいという欠点を有している。However, the fact is that no recording material satisfying all of these performance requirements has been found yet. For example, JP-A-52-7
The ink jet recording paper described in No. 4340 absorbs ink quickly, but the dot diameter is likely to be large, and the periphery of the dot is easily blurred. It also has a drawback that the dimensional change of the paper after recording is large.
また一方では、インクジェット記録法が水系のインクを
使用するため、記録画像に耐水性が欠け、水がかかった
場合などインクが滲んで判読できなくなるという問題も
あり、これを解決することも要求されていた。On the other hand, since the inkjet recording method uses a water-based ink, there is a problem that the recorded image lacks water resistance and the ink becomes bleeding and becomes unreadable when exposed to water, and it is also required to solve this problem. Was there.
例えば、特開昭56-99693号記載のインクジェット記録用
紙は、ハロゲン化第四アンモニウム等を含有させて耐水
性を付与している。しかし、このような耐水性のあるイ
ンクジェット記録用紙は記録剤（染料等）の耐光性が著
しく低下するという欠点がある。これは、おそらくハロ
ゲンの光触媒作用により染料の光分解が促進されるため
に起こると思われる。For example, the ink jet recording paper described in JP-A-56-99693 contains a quaternary ammonium halide or the like to impart water resistance. However, such a water-resistant inkjet recording paper has a drawback that the light resistance of a recording material (dye or the like) is significantly reduced. This is probably due to the photocatalytic action of the halogen, which promotes the photodegradation of the dye.
［本発明が解決しようとする問題点］ 本発明の目的は、前記のような諸要求の満足させ、特に
耐水性に優れ、かつ耐光性の良好なインクジェット記録
に好適な被記録材を提供することにある。[Problems to be Solved by the Present Invention] An object of the present invention is to provide a recording material suitable for ink jet recording, which satisfies the above-mentioned requirements and is particularly excellent in water resistance and good in light resistance. Especially.
本発明の他の目的は、インクの発色性を改善し、色彩性
に優れた被記録材を提供することにある。Another object of the present invention is to provide a recording material that improves the color developability of ink and is excellent in color.
上記及び他の目的は、以下の本発明によって達成され
る。The above and other objects are achieved by the present invention described below.
［発明の構成及び作用］ すなわち本発明は、基材又は基材上に設けた塗工層に、
式(I) （ｎ＝ 5〜10000） （式中、Ｘ−は硝酸イオン、リン酸イオン、酢酸イオ
ン、安息香酸イオン、Ｐ−トルエンスルホン酸イオン等
を表わし、それらのうち少なくとも１種よりなる）で表
わされるポリアリルアミン塩を含有することを特徴とす
る被記録材である。ただし、式(I) において、ｎは 5〜
10000 で、より好ましくは10〜1000である。ｎが 5より
小さいと耐水性が不充分であり、10000 より大きいと水
溶液にした際、粘度が高く、作業性に乏しい。[Structure and Action of Invention] That is, the present invention provides a substrate or a coating layer provided on the substrate,
Formula (I) (N = 5-10000) (In the formula, X − represents a nitrate ion, a phosphate ion, an acetate ion, a benzoate ion, a P-toluenesulfonate ion and the like, and is composed of at least one of them) A recording material containing a polyallylamine salt. However, in the formula (I), n is 5 to
It is 10,000, more preferably 10 to 1,000. When n is less than 5, the water resistance is insufficient, and when it is more than 10,000, the viscosity of the aqueous solution is high and the workability is poor.
本発明の被記録材の基材としては、代表的には紙を挙げ
ることができるが、布、樹脂フィルムあるいは合成紙等
も基材として使用することができる。Paper can be typically used as the base material of the recording material of the present invention, but cloth, resin film, synthetic paper, or the like can also be used as the base material.
基材に、式(I) で表わされるポリアリルアミン塩を含有
させ、本発明の被記録材を製造する方法としては、例え
ば抄紙工程において該ポリアリルアミン塩の水溶液を使
用して製紙する方法、あるいは含浸液に該ポリアリルア
ミン塩を添加し、これに基材を浸漬する後処理による方
法があるが、いずれの方法を用いてもよい。これらの場
合の該ポリアリルアミン塩水溶液の濃度は、水溶液の呈
する粘度及び該ポリアリルアミン塩の溶解度によっても
最適な範囲は異なるが、一般に0.05〜2 重量％の範囲内
のものを使用するのが適当である。また、基材中に含有
させる該ポリアリルアミン塩の量が多過ぎるとインクの
吸収能が低下するため好ましくない。The substrate, containing a polyallylamine salt represented by the formula (I), as a method for producing the recording material of the present invention, for example, a method of papermaking using an aqueous solution of the polyallylamine salt in a papermaking step, or There is a method in which the polyallylamine salt is added to the impregnating solution and the substrate is dipped in the solution, but any method may be used. The concentration of the aqueous solution of polyallylamine salt in these cases varies depending on the viscosity exhibited by the aqueous solution and the solubility of the polyallylamine salt, but it is generally preferable to use a concentration of 0.05 to 2% by weight. Is. Further, if the amount of the polyallylamine salt contained in the base material is too large, the ink absorbing ability is lowered, which is not preferable.
一方、基材上の塗工層中に式(I) のポリアリルアミン塩
を含有するタイプの本発明被記録材は、塗工液にポリア
リルアミン塩を添加し、この塗工液を基材上に塗布し、
乾燥させることによって製造される。この場合の塗工液
の他の成分としては、従来公知の微粉ケイ酸、クレー、
タルク、ケイソウ土、炭酸カルシウム、硫酸カルシウ
ム、硫酸バリウム、酸化チタン、酸化亜鉛、サチンホワ
イト、ケイ酸アルミニウム、リトボン等の無機質顔料
類；デンプン、ゼラチン、カゼイン、アラビアゴム、ア
ルギン酸ソーダ、カルボキシメチルセルロース、ポリビ
ニルアルコール、ポリビニルピロリドン、ポリアクリル
酸ソーダ等の水溶性高分子；合成ゴムラテックス等の合
成樹脂ラテックス；ポリビニルブチラール、ポリビニル
クロライド等の有機溶剤可溶性樹脂；更には分散剤、蛍
光染料、PH調整剤、消泡剤、潤滑剤、防腐剤、界面活性
剤の各種添加剤を挙げることができる。 塗工液に加え
られるポリアリルアミン塩の量としては、0.03〜 5重量
％の範囲が適当である。該塗工液は、公知の手法、例え
ばロールコーター法、ブレードコーター法、エアナイフ
コーター法等により、通常 1〜50g/m2程度（乾燥塗工
量）の量を基材上に塗工する。好ましくは 2〜30g/m2程
度（乾燥塗工量）塗工する。On the other hand, the recording material of the present invention of the type containing the polyallylamine salt of the formula (I) in the coating layer on the substrate is a polyallylamine salt added to the coating liquid, and the coating liquid is applied to the substrate. Apply to
It is manufactured by drying. Other components of the coating liquid in this case, conventionally known fine powder silicic acid, clay,
Inorganic pigments such as talc, diatomaceous earth, calcium carbonate, calcium sulfate, barium sulfate, titanium oxide, zinc oxide, satin white, aluminum silicate, lithobon; starch, gelatin, casein, gum arabic, sodium alginate, carboxymethyl cellulose, polyvinyl Water-soluble polymers such as alcohol, polyvinylpyrrolidone, and sodium polyacrylate; synthetic resin latexes such as synthetic rubber latex; organic solvent-soluble resins such as polyvinyl butyral and polyvinyl chloride; further dispersants, fluorescent dyes, PH adjusters, and erasers. Various additives such as foaming agents, lubricants, preservatives and surfactants can be mentioned. The amount of polyallylamine salt added to the coating solution is suitably in the range of 0.03 to 5% by weight. The coating solution is generally applied on the substrate in an amount of about 1 to 50 g / m 2 (dry coating amount) by a known method such as a roll coater method, a blade coater method or an air knife coater method. Preferably about 2 to 30 g / m 2 (dry coating amount) is applied.
［効果］ このようにして基材又は基材上に設けた塗工層の中に式
(I) で表わされるポリアリルアミン塩を含有してなる本
発明の被記録材は、インクが速やかにその内部に吸収さ
れ、異色の記録液が短時間内に同一箇所に重複して付着
した場合にも記録液の流れ出しや滲み出し現象がなく、
高解像度の鮮明な画像を与えるものである。しかも得ら
れた画像は耐水性、耐光性双方とも優れており、インク
ジェット記録用の被記録材として好適なものである。[Effect] In the substrate or the coating layer provided on the substrate in this way, the formula
In the recording material of the present invention containing the polyallylamine salt represented by (I), when the ink is quickly absorbed in the recording material and the recording liquids of different colors are adhered to the same place in a short time in duplicate. However, there is no flow or bleeding phenomenon of the recording liquid,
It gives a clear image with high resolution. Moreover, the obtained image is excellent in both water resistance and light resistance, and is suitable as a recording material for inkjet recording.
以下、参考例、実施例及び比較例に従って本発明を更に
詳細に説明する。Hereinafter, the present invention will be described in more detail with reference to Reference Examples, Examples and Comparative Examples.
参考例１ ポリアリルアミン塩として、w（超遠心法で求めた重
量平均分子量）60000 のポリアリルアミン塩酸塩 PAA-H
Cl-H（日東紡（株）製）を使用して、下記組成に基づき
塗工用組成物を作成した。Reference Example 1 As polyallylamine salt, polyallylamine hydrochloride PAA-H having w (weight average molecular weight determined by ultracentrifugation method) of 60,000
Cl-H (manufactured by Nitto Boseki Co., Ltd.) was used to prepare a coating composition based on the following composition.
微粉ケイ酸 100 重量部 ポリビニルアルコール 50 〃 PAA-HCl-H 1 〃 水 500 〃 一方、基材としては、JIS P8122 に基づくサイズ度が35
秒の一般上質紙（秤量65g/m2）を使用し、この基材上に
上記塗工用組成物を乾燥塗工量15g/m2の割合でブレード
コーター法により塗工し、常法により乾燥させて被記録
材を得た。この被記録材に対して、下記４色のインクを
用いてカラーインクジェット記録を行い、記録特性の評
価を行った。Finely divided silicic acid 100 parts by weight Polyvinyl alcohol 50 〃 PAA-HCl-H 1 〃 Water 500 〃 On the other hand, as the base material, the size degree based on JIS P8122 is 35
Second general high-quality paper (weighing 65 g / m 2 ) is used, and the above coating composition is coated on this substrate at a dry coating amount of 15 g / m 2 by the blade coater method, and then the ordinary method is used. A recording material was obtained by drying. On this recording material, color inkjet recording was performed using the following four colors of ink, and the recording characteristics were evaluated.
イエローインク（組成） C.I.アシッドイエロー23 2 重量部 ジエチレングリコール 30 〃 水 70 〃 マゼンタインク（組成） C.I.アシッドレッド35 2 重量部 ジエチレングリコール 30 〃 水 70 〃 シアンインク（組成） C.I.ダイレクトブルー86 2 重量部 ジエチレングリコール 30 〃 水 70 〃 ブラックインク（組成） C.I.ダイレクトブラック19 2 重量部 ジエチレングリコール 30 〃 水 70 〃 被記録材の記録特性の評価結果を表１に示す。滲み度
は、印字ドットの直径を実体顕微鏡で測定し、インクド
ロプレットの何倍になったかで示した。発色性は、マク
ベス濃度計を用いて光学濃度（O.D.）測定した。Yellow ink (composition) CI Acid Yellow 23 2 parts by weight Diethylene glycol 30 〃 Water 70 〃 Magenta ink (composition) CI Acid Red 35 2 parts by weight Diethylene glycol 30 〃 Water 70 〃 Cyan ink (composition) CI Direct Blue 86 2 parts by weight Diethylene glycol 30 〃 Water 70 〃 Black ink (composition) CI Direct Black 19 2 parts by weight Diethylene glycol 30 〃 Water 70 〃 Table 1 shows the evaluation results of the recording characteristics of the recording material. The degree of bleeding was measured by measuring the diameter of the printed dot with a stereoscopic microscope and indicated by the multiple of the ink droplet. The color developability was measured by optical density (OD) using a Macbeth densitometer.
耐水性は、被記録材を流水に１時間浸漬し、浸漬後マク
ベス濃度計を用いて測定した光学濃度（O.D.）を、浸漬
前のOD値と比較して評価した。また、耐光性は、キセノ
ンフェードメーター 100時間照射し測色色差計 ND-1001
-DP （日本電色工業（株）製）を用いて未照射のものと
の色差（ハンターΔＥ）を求めた。The water resistance was evaluated by immersing the recording material in running water for 1 hour and comparing the optical density (OD) measured with a Macbeth densitometer after immersion with the OD value before immersion. In addition, the light resistance is measured by the xenon fade meter for 100 hours and the color difference colorimeter ND-1001
-DP (manufactured by Nippon Denshoku Industries Co., Ltd.) was used to determine the color difference (Hunter ΔE) from the unirradiated one.
参考例２ ポリアリルアミン塩として、w（超遠心法で求めた重
量平均分子量）10000 のポリアリルアミン塩酸塩 PAA-H
Cl-L（日東紡（株）製）を使用し、その１％水溶液を作
成し、これにサイズ度０秒の一般紙（坪量70g/m2）を浸
漬し、乾燥して、基材に対して約0.5 重量％のポリアリ
ルアミン塩酸塩を含浸させた被記録材を得た。この被記
録材を参考例１と同様にして評価した結果を表１に示
す。Reference Example 2 As a polyallylamine salt, polyallylamine hydrochloride PAA-H having w (weight average molecular weight determined by ultracentrifugation method) of 10,000
Cl-L (manufactured by Nitto Boseki Co., Ltd.) was used to prepare a 1% aqueous solution thereof, and ordinary paper (size: 70 g / m 2 ) having a size of 0 seconds was dipped in this, dried and A recording material impregnated with about 0.5% by weight of polyallylamine hydrochloride was obtained. The results of evaluation of this recording material in the same manner as in Reference Example 1 are shown in Table 1.
実施例１ ポリアリルアミン塩として、w 5000 のポリアリルア
ミン酸塩を使用したほかは、参考例１と同様にして被記
録材を作成した。記録特性は参考例１と同様にして評価
し、その結果を表１に示す。Example 1 A recording material was prepared in the same manner as in Reference Example 1 except that w 5000 of polyallylamine salt was used as the polyallylamine salt. The recording characteristics were evaluated in the same manner as in Reference Example 1, and the results are shown in Table 1.
比較例１ ポリアリルアミン塩酸塩を塗工用組成物に添加しなかっ
たことを除いては、参考例１と同様にして被記録材を作
成した。記録特性は参考例１と同様にして評価し、その
結果を表１に示す。Comparative Example 1 A recording material was prepared in the same manner as in Reference Example 1 except that polyallylamine hydrochloride was not added to the coating composition. The recording characteristics were evaluated in the same manner as in Reference Example 1, and the results are shown in Table 1.
比較例２ 参考例２で使用した基材を無処理のまま被記録材とし
た。記録特性は参考例１と同様にして評価し、その結果
を表１に示す。Comparative Example 2 The base material used in Reference Example 2 was used as a recording material without any treatment. The recording characteristics were evaluated in the same manner as in Reference Example 1, and the results are shown in Table 1.
比較例３ 参考例１で使用したポリアリルアミン塩酸塩の代わり
に、ラウリルトリメチルアンモニウムクロライドを用い
たことを除いては、参考例１と同様にして被記録材を作
成した。記録特性は参考例１と同様にして評価し、その
結果を表１に示す。Comparative Example 3 A recording material was prepared in the same manner as in Reference Example 1, except that lauryltrimethylammonium chloride was used instead of the polyallylamine hydrochloride used in Reference Example 1. The recording characteristics were evaluated in the same manner as in Reference Example 1, and the results are shown in Table 1.
実施例２〜４ ポリアリルアミン塩酸塩に代え、w2000のポリアリル
アミン酢酸塩、w7000 のポリアリルアミンｐ−トルエ
ンスルホン酸塩、w100000のポリアリルアミン安息香
酸塩を使用して参考例１と同様にそれぞれ被記録材を作
成し、記録特性評価を行なった結果、何れにおいても参
考例１とほぼ同じ結果が得られた。 Examples 2 to 4 In place of the polyallylamine hydrochloride, w2000 polyallylamine acetate, w7000 polyallylamine p-toluenesulfonate, and w100000 polyallylamine benzoate were used, respectively. As a result of making the materials and evaluating the recording characteristics, almost the same results as in Reference Example 1 were obtained in all cases.
Claims (1)
ン、安息香酸イオン、ｐ−トルエンスルホン酸イオン等
を表わし、それらのうち少なくとも１種よりなる）で表
わされるポリアリルアミン塩を含有することを特徴とす
る被記録材。1. A base material or a coating layer provided on a base material is of the formula (I) (N = 5 to 10000) (in the formula, X − represents a nitrate ion, a phosphate ion, an acetate ion, a benzoate ion, a p-toluenesulfonate ion and the like, and is composed of at least one of them). A recording material containing a polyallylamine salt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59182171A JPH0630951B2 (en) | 1984-08-31 | 1984-08-31 | Recording material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59182171A JPH0630951B2 (en) | 1984-08-31 | 1984-08-31 | Recording material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6158788A JPS6158788A (en) | 1986-03-26 |
| JPH0630951B2 true JPH0630951B2 (en) | 1994-04-27 |
Family
ID=16113583
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59182171A Expired - Lifetime JPH0630951B2 (en) | 1984-08-31 | 1984-08-31 | Recording material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0630951B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6811839B2 (en) | 2000-11-09 | 2004-11-02 | Canon Kabushiki Kaisha | Recording medium and image forming process using the same |
| US7008671B2 (en) | 2000-12-28 | 2006-03-07 | Canon Kabushiki Kaisha | Recorded matter, method of producing recorded matter, method for improving image fastness, image fastness-improving agent, image fastness improving kit, dispenser, and applicator |
| US8158223B2 (en) | 2008-03-14 | 2012-04-17 | Canon Kabushiki Kaisha | Ink jet recording medium and production process thereof, and fine particle dispersion |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2670454B2 (en) * | 1989-04-03 | 1997-10-29 | キヤノン株式会社 | Recording material and recording method using the same |
| CA2138734C (en) | 1993-12-28 | 2000-11-14 | Mamoru Sakaki | Recording medium and image-forming method employing the same |
| JP3486492B2 (en) * | 1994-10-27 | 2004-01-13 | キヤノン株式会社 | Recording paper and image forming method using the same |
| JP3591938B2 (en) | 1994-10-27 | 2004-11-24 | キヤノン株式会社 | Ink jet recording medium and image forming method using the same |
| US6084619A (en) * | 1995-04-21 | 2000-07-04 | Seiko Epson Corporation | Ink jet recording method |
| US6326323B1 (en) | 1998-02-13 | 2001-12-04 | Komatsu Seiren Co., Ltd. | Fabric for ink-jet recording |
| JP3928365B2 (en) | 2001-03-26 | 2007-06-13 | セイコーエプソン株式会社 | INKJET RECORDING MEDIUM, RECORDING METHOD THEREOF, AND INKJET RECORDED PRODUCT |
| JP3920643B2 (en) * | 2002-01-08 | 2007-05-30 | 富士フイルム株式会社 | Inkjet recording sheet and method for producing the same |
| US8053159B2 (en) * | 2003-11-18 | 2011-11-08 | Honeywell International Inc. | Antireflective coatings for via fill and photolithography applications and methods of preparation thereof |
| US7955669B2 (en) | 2007-10-31 | 2011-06-07 | Canon Kabushiki Kaisha | Ink jet recording medium and ink jet recording method |
| JP2010031095A (en) * | 2008-07-25 | 2010-02-12 | Idemitsu Technofine Co Ltd | Ultraviolet-curable coating agent and molded article |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59183435A (en) * | 1983-03-31 | 1984-10-18 | Fujitsu Ltd | Unit processing system |
-
1984
- 1984-08-31 JP JP59182171A patent/JPH0630951B2/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6811839B2 (en) | 2000-11-09 | 2004-11-02 | Canon Kabushiki Kaisha | Recording medium and image forming process using the same |
| US7008671B2 (en) | 2000-12-28 | 2006-03-07 | Canon Kabushiki Kaisha | Recorded matter, method of producing recorded matter, method for improving image fastness, image fastness-improving agent, image fastness improving kit, dispenser, and applicator |
| US8158223B2 (en) | 2008-03-14 | 2012-04-17 | Canon Kabushiki Kaisha | Ink jet recording medium and production process thereof, and fine particle dispersion |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6158788A (en) | 1986-03-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |