JPH06284924A - Sponge puff for makeup - Google Patents

Abstract

PURPOSE:To provide a cosmetic sponge puff into inner part of which the penetration of cosmetics is prevented and which manifests a soft and good feel to the skin and results in a good makeup effect. CONSTITUTION:This cosmetic sponge puff is made of a microporous polyurethane resin obtained from the knead raw material comprising a water- and oil repelling agent of a fluorine-base, wax-source a metallic salt having no reactive group in the molecule. Or, the cosmetic sponge is made of a microhorous pohyurethane resin penetrated with a water- and oil repelling agent of a water-soluble, liposoluble or water-dispersible fluorine-base wax- source, metallic salt and hept them in the resin.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cosmetic sponge puff.

[0002]

BACKGROUND OF THE INVENTION When a liquid cosmetic, particularly a low-viscosity cosmetic, is applied to a cosmetic sponge puff having an open cell structure, which is made of a microporous urethane resin, NBR, etc. A certain amount of cosmetic material passes through the open cells and is absorbed inside the puff. as a result,
It has been a problem from the past that most of the cosmetics are wasted, the cosmetics do not adhere sufficiently to the skin, and satisfactory makeup cannot be achieved. Moreover, the cosmetics absorbed in the sponge puff may penetrate into the back surface and stain hands, clothes, and the like, and the cosmetics inside the sponge puff may be decomposed.

As a means for solving the above problems,
The following methods have been tried so far.

(1) To reduce the bubble diameter of open cells,
Reduce the expansion ratio.

(2) A rubber-based or thermoplastic resin porous film material is attached to the surface of the cosmetic sponge puff.

(3) The bubbles are not continuous bubbles but single bubbles.

However, according to the method (1), although absorption of the cosmetic into the sponge puff is prevented to some extent, the softness, which is an important characteristic of the cosmetic sponge puff, is impaired, on the other hand. The product value is greatly reduced. Therefore, at present, this method is hardly adopted.

The method (2) is effective in suppressing the absorption of the cosmetic into the sponge puff. But,
There are problems that the manufacturing method is complicated, the quality is not uniform, and the cost is significantly increased.

The method (3) can be carried out by mixing a rubber-based, urethane-based or other resin-based raw material with a chemical foaming agent, kneading the mixture, and heating to promote foaming. According to this method, due to the structure of the bubbles, there is no absorption of the cosmetic into the sponge puff, but the uniformity of the bubbles is poor, the flexibility of the sponge puff is lost, and the feel on the skin is not good. Moreover, there is a problem that a so-called slip phenomenon occurs during makeup, the cosmetic material becomes uneven, and the finish of the makeup is deteriorated.

As described above, all the conventionally used methods have an unsolved problem. The present invention has been made in view of the above, cosmetics do not penetrate into the interior,
It is intended to provide a sponge puff for cosmetics which is excellent in flexibility and feel to the skin, has a good cosmetic effect, is easy to manufacture, and has high quality uniformity.

[0011]

In order to solve the above-mentioned problems, the cosmetic sponge puff of claim 1 is a fluorine-based, wax-based or metal salt-based water-repellent agent having no reactive group in the molecule. It is characterized by comprising a microporous urethane resin material obtained from a kneaded raw material with an oil repellent. Here, the microporous urethane resin material means a foamed polyurethane having an open cell structure and is obtained by a conventionally used method, for example, by extruding a kneaded material and then vaporizing a solvent. However,
The manufacturing method is not limited to this.

A cosmetic sponge puff according to a second aspect of the present invention is a micro sponge containing a water-soluble, oil-soluble or water-dispersible fluorine-based, silicone-based, wax-based, or metal salt-based water / oil repellent. It is characterized by being made of a porous urethane resin material. Here, in order to permeate the water / oil repellent agent, the microporous urethane resin material may be dipped in the water / oil repellent agent, or the water / oil repellent agent may be sprayed on the microporous urethane resin material. In addition, the operation of permeating and holding the water and oil repellent is performed before forming the microporous urethane resin material on the cosmetic sponge puff.
Alternatively, it may be performed after the formation. Further, in order to retain the water and oil repellent agent, a treatment such as heating may be performed.

In the above, fluorine type, silicone type,
As a wax-based or metal salt-based water and oil repellent,
Of the conventionally used water and oil repellents, any one can be used as long as it satisfies the conditions described in each claim. Examples of the water and oil repellents of each system are shown below, but the present invention is not limited to the following examples.

Examples of the fluorine-based water and oil repellent agents include fluorine resin such as tetrafluoroethylene and vinylidene fluoride, and water and oil repellent agents using a fluorine compound having a perfluoroalkyl group. The oil agent has a siloxane bond in the main chain and a methyl group, an ethyl group in the side chain,
Examples include those using an organopolysiloxane having an alkyl group such as a propyl group or a fluoroalkyl group.
Examples of the wax-based water / oil repellent include beeswax and paraffin, and examples of the metal salt include zirconium and fatty acid salts and aluminum and fatty acid salts. Of these, those having no reactive group in the molecule are used in the first aspect, and water-soluble, oil-soluble, or water-dispersible ones are used in the second aspect.

[0015]

In the cosmetic sponge puff according to the first aspect, the entire sponge puff has excellent water and oil repellency due to the action of the water and oil repellent compounded and kneaded in the raw material. Due to this water and oil repellency, the cosmetic cannot penetrate deep into the open cells. That is, the cosmetic material is prevented from penetrating into the sponge puff.

In the makeup sponge puff of claim 2, the water and oil repellent agent is, of course, retained on the surface of the sponge puff.
It also penetrates into the open cells and is retained by the wall surface forming the bubbles to exert a water and oil repellency. Therefore, also in this case, the cosmetic cannot penetrate into the inside of the sponge puff.

[0017]

EXAMPLES Next, the cosmetic sponge puff of the present invention will be described in more detail based on examples.

Example 1 Microporous urethane resin composition (Hilux 45
1-B1, Toyo Polymer Co., Ltd. 5 kg, tetrafluoroethylene resin (Lubron L) as a fluorine-based water and oil repellent
D-100, manufactured by Daikin Industries, Ltd., was added in an amount of 20 g,
Kneaded with a double-arm kneader to homogenize. This is diameter 32
mm single-screw extruder, spindle speed 50 rpm, temperature 5
Under extrusion conditions of 0 ° C., it was extruded through a T-die having a lip length of 300 mm and extruded into a block shape having a thickness of 15 mm.

The solvent is vaporized at a temperature of 70 ° C. under a reduced pressure of 60 mmHg to generate bubbles,
A sponge body was formed.

The sponge body was put on a slicer, and the upper and lower skin layers were removed to prepare a sheet having a thickness of 8 mm.
This sponge sheet was cut with a hydraulic press machine and then polished to form a cosmetic sponge puff having a thickness of 8 mm and a diameter of 60 mm.

Example 2 Microporous urethane resin composition (Hilux 45
1-B1 (manufactured by Toyo Polymer Co., Ltd.) 5 kg in metal salt-based water and oil repellent (Neolax R500, Takamatsu Yushi Co., Ltd.)
50 g) was mixed and kneaded with a double-arm kneader to homogenize.

Using this, a sponge puff for makeup was formed in the same manner as in Example 1.

Example 3 Microporous urethane resin composition (Hilux 45
1-B1, manufactured by Toyo Polymer Co., Ltd. 5 kg, wax-based water and oil repellent (Rivasol K30, Tokai Oil Co., Ltd.)
50 g) was mixed and kneaded with a double-arm kneader to homogenize.

Using this, a sponge puff for cosmetics was formed in the same manner as in Example 1.

Comparative Example 1 Microporous urethane resin composition (Hilux 45
1-B1, Toyo Polymer Co., Ltd.) 5 kg diameter 3
It was extruded from a 2 mm uniaxial extruder through a T-die having a lip length of 300 mm under the extrusion conditions of a spindle speed of 50 rpm and a temperature of 50 ° C.

Using this, a sponge puff for makeup was formed in the same manner as in Example 1.

Example 4 The sponge sheet obtained in Comparative Example 1 was cut with a hydraulic press and then polished to form a cosmetic sponge puff having a diameter of 60 mm.

This sponge puff was dipped in a 1.5% solution of a fluorine-based water and oil repellent agent (Dickguard F-14, manufactured by Dainippon Ink and Chemicals, Inc.) so that the water and oil repellent agent could penetrate into the interior well. Knead by hand and let stand for 10 minutes.

The sponge puff was put on a centrifuge,
After deliquoring so that the squeezing ratio was 35%, it was dried in a constant temperature bath at 90 ° C. for 20 minutes, and further heat-treated at 140 ° C. for 5 minutes.

Example 5 A cosmetic sponge puff having a diameter of 60 mm obtained in the same manner as in Example 4 was added to a 1.5% solution of a silicone water / oil repellent agent (Asahi Silicon Repellant 702, manufactured by Asahi Glass Co., Ltd.). Soaked. This was treated as in Example 4.

Example 6 A cosmetic sponge puff having a diameter of 60 mm obtained in the same manner as in Example 4 was treated with a metal salt-based water and oil repellent agent (Zircoset G5,
It was immersed in a 2.0% solution of Shichifuku Chemical Co., Ltd. This was treated as in Example 4.

Example 7 A cosmetic sponge puff having a diameter of 60 mm obtained in the same manner as in Example 4 was treated with a wax-based water and oil repellent agent (Petrox P-
200, manufactured by Meisei Chemical Co., Ltd.). This was treated as in Example 4.

The absorbent sponge puffs obtained in Examples 1 to 7 and Comparative Example 1 were subjected to an absorbency test and a spreadability test.

In the absorption test, 0.5 ml of the liquid cosmetic composition was dropped on the cosmetic sponge puffs obtained in Examples 1 to 7 and Comparative Example 1, and this cosmetic composition was applied to the surface of the sponge puffs with a finger. Spread with the same force, spread area of cosmetics (cm
² ) was measured.

In the spreadability test, 0.5 ml of the liquid cosmetic composition was dropped on the cosmetic sponge puffs obtained in Examples 1 to 7 and Comparative Example 1, and this was applied to paper (dry PPC paper, Japan Business Supply Co., Ltd.). (Manufactured by K.K.) and the spreading area (cm ² ) of the cosmetic was measured.

The results of the above tests are shown in Table 1.

[0037]

[Table 1]

As is clear from Table 1, the cosmetics adhered to the sponge puffs of Examples 1 to 7 were absorbed into the sponge puffs more than the cosmetics adhered to the cosmetic sponge puff of Comparative Example 1. Was suppressed, and much remained on the surface of the cosmetic sponge puff. This means that the cosmetics are not wasted and an excellent cosmetic effect is obtained.

Next, the makeup sponge puffs obtained in Examples 1 to 7 were tested for water and oil repellency and wash resistance.

The cosmetic sponge puffs obtained in Examples 1 to 7 were dipped in an aqueous solution containing 0.1% of a neutral detergent, washed by rubbing 10 times, washed thoroughly with running water, and then centrifuged. Dehydrated. This was placed in a thermostat at 90 ° C. and dried for 20 minutes. After repeating this operation 5 times, the above absorbency test and spreadability test were performed.

The test results are shown in Table 2.

[0042]

[Table 2]

As can be seen from Table 2, the water and oil repellency imparted to the cosmetic sponge puffs of Examples 1 to 7 has sufficient washing resistance.

The numerical values in Tables 1 and 2 above are all averages of the results of three tests.

[0045]

As described above, according to the cosmetic sponge puff of the present invention, the water and oil repellent agent exerts a lasting effect,
Since the liquid cosmetic is not absorbed inside the sponge puff, the cosmetic is not wasted and is hygienic. Moreover, since it has an open cell structure, it is excellent in flexibility and touch to the skin, and a good cosmetic effect can be obtained. Furthermore, it is easy to manufacture,
A uniform quality product can be obtained at low cost.

Claims (2)

[Claims] 1. A fluorine-based compound having no reactive group in the molecule,
A cosmetic sponge puff made of a microporous urethane resin material obtained by kneading a wax-based or metal salt-based water and oil repellent. 2. A cosmetic comprising a microporous urethane resin material in which a water-soluble, oil-soluble, or water-dispersible fluorine-based, silicone-based, wax-based, or metal salt-based water / oil repellent is permeated and retained. Sponge puff.