JPH06143350A - Forming mold - Google Patents

Forming mold

Info

Publication number
JPH06143350A
JPH06143350A JP29851692A JP29851692A JPH06143350A JP H06143350 A JPH06143350 A JP H06143350A JP 29851692 A JP29851692 A JP 29851692A JP 29851692 A JP29851692 A JP 29851692A JP H06143350 A JPH06143350 A JP H06143350A
Authority
JP
Japan
Prior art keywords
molding die
gate
opening edge
thin film
film layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP29851692A
Other languages
Japanese (ja)
Inventor
Shinichi Hashizume
伸一 橋詰
Takao Kitamura
隆雄 北村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Omron Corp
Original Assignee
Omron Corp
Omron Tateisi Electronics Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Omron Corp, Omron Tateisi Electronics Co filed Critical Omron Corp
Priority to JP29851692A priority Critical patent/JPH06143350A/en
Publication of JPH06143350A publication Critical patent/JPH06143350A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/27Sprue channels ; Runner channels or runner nozzles
    • B29C45/2701Details not specific to hot or cold runner channels
    • B29C45/2708Gates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/37Mould cavity walls, i.e. the inner surface forming the mould cavity, e.g. linings

Abstract

PURPOSE:To improve the impact resistance and wear resistance at the opening edge of a gate hole, prolong the lifetime of a mold and reduce the maintenance and the production cost by a method wherein ion implantation layer is produced on the surface of the periphery of the gate hole, the opening edge of which is chamfered. CONSTITUTION:A chamfering part 14 is formed by chamfering the opening edge 13 of a gate hole 12 constituting the gate 11 of a forming mold 10. In addition, by applying ion implantation treatment to the surface 15 of the periphery of the gate hole 12, ion implantation layer 16 is produced. The dimensions, angle and the like of the chamfering part 14 are properly changed in response to the material of the forming mold 10, the material, shape and the like of a formed product. Further, after the chamfering part 14 is formed by chamfering the opening edge 13 of the gate hole 12 constituting the gate 11 of the forming mold 10, thin film layer 17 is produced at the periphery of the gate hole 12 by PVD method and CVD method.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は成形加工用金型、特に、
そのゲート口における開口縁部の強化に関する。
BACKGROUND OF THE INVENTION The present invention relates to a molding die, and more particularly,
Regarding the reinforcement of the opening edge at the gate opening.

【0002】[0002]

【従来の技術】従来、成形加工用金型は、図7ないし図
9に示すように、キャビティ1を形成する成形加工用金
型であるコア2,3,4,5のうち、ゲート6を有する
コア3、特に、そのゲート口6aの開口縁部6bにおけ
る摩耗,破損を防止するため、ゲート口6a周囲の表面
3aに薄膜層7をCVD(Chemical Vapor Depositi
on)法またはPVD(Physical Vapor Deposition)
法で形成することにより、成形加工用金型であるコア3
の耐衝撃性,耐摩耗性の向上が図られている。
2. Description of the Related Art Conventionally, as shown in FIGS. 7 to 9, a molding die has a gate 6 of a core 2, 3, 4, 5 which is a molding die for forming a cavity 1. In order to prevent abrasion and damage of the core 3 which is included, in particular, the opening edge portion 6b of the gate opening 6a, a thin film layer 7 is formed on the surface 3a around the gate opening 6a by CVD (Chemical Vapor Deposition).
on) method or PVD (Physical Vapor Deposition)
Core 3 which is a mold for molding by being formed by the method
The impact resistance and wear resistance are improved.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、従来例
にかかる金型は、そのゲート口6aの開口縁部6bが鋭
角であるので、高温,高圧の条件下で射出成形が何度も
反復して行なわれると、成形材中に含まれるガラス繊維
等によって開口縁部6bが摩耗,破損しやすく、所望の
寿命が得られないという問題点があった。
However, in the mold according to the conventional example, since the opening edge portion 6b of the gate opening 6a has an acute angle, injection molding is repeated many times under high temperature and high pressure conditions. If this is done, there is a problem in that the opening edge portion 6b is easily worn or damaged by the glass fiber or the like contained in the molding material, and the desired life cannot be obtained.

【0004】本発明は、前記問題点に鑑み、寿命が長い
成形加工用金型を提供することを目的とする。
In view of the above problems, it is an object of the present invention to provide a molding die having a long life.

【0005】[0005]

【課題を解決するための手段】本発明にかかる成形加工
用金型は、前記目的を達成するため、開口縁部に面取り
加工を施したゲート口周囲の表面に、イオン注入層ある
いは薄膜層を形成したものでもよく、また、開口縁部に
面取り加工を施したゲート口周囲の表面にイオン注入層
および薄膜層を順次形成したものでもよい。さらに、本
発明にかかる成形加工用金型は、前述の面取り加工の代
わりにアール付け加工を施したゲート口周囲の表面に、
イオン注入層あるいは薄膜層を形成してもよく、また、
イオン注入層および薄膜層を順次形成したものでもよ
い。特に、前記アール付け加工は射出成形の際に生じる
初期摩耗によるものであってもよい。
In order to achieve the above-mentioned object, a molding die according to the present invention has an ion implantation layer or a thin film layer on the surface around a gate opening whose edge is chamfered. It may be formed, or may be one in which an ion implantation layer and a thin film layer are sequentially formed on the surface around the gate opening whose edge is chamfered. Furthermore, the molding die according to the present invention, on the surface around the gate opening, which is subjected to the rounding process instead of the above-mentioned chamfering process,
An ion implantation layer or a thin film layer may be formed, and
The ion implantation layer and the thin film layer may be sequentially formed. In particular, the rounding process may be due to initial wear that occurs during injection molding.

【0006】[0006]

【作用】したがって、本発明によれば、開口縁部に設け
た面取り部またはアール付け部がイオン注入層または薄
膜層で被覆されることになる。
Therefore, according to the present invention, the chamfered portion or the rounded portion provided at the opening edge portion is covered with the ion implantation layer or the thin film layer.

【0007】[0007]

【実施例】次に、本発明にかかる実施例を図1ないし図
6の添付図面に従って説明する。第1実施例は、図1に
示すように、成形加工用金型10のゲート11を構成す
るゲート口12の開口縁部13に面取り加工を施して面
取り部14を形成した後、ゲート口12周囲の表面15
にイオン注入処理を施してイオン注入層16を形成した
ものである。
Embodiments of the present invention will now be described with reference to the accompanying drawings of FIGS. In the first embodiment, as shown in FIG. 1, the opening edge 13 of the gate opening 12 of the gate 11 of the molding die 10 is chamfered to form a chamfered portion 14, and then the gate opening 12 is formed. Surrounding surface 15
The ion-implanted layer 16 is formed by performing ion-implantation treatment on the.

【0008】面取り部14の大きさ,角度等は、成形加
工用金型10の材質や成形加工製品の材質,形状等によ
って適宜変更すればよく、特に限定するものではない。
The size, angle and the like of the chamfered portion 14 may be appropriately changed depending on the material of the molding die 10 and the material and shape of the molded product, and are not particularly limited.

【0009】イオン注入処理は、イオン化した元素に加
速器で高エネルギーを与え、面取りしたゲート口12周
囲の表面15に元素イオンを突入させて打ち込む方法で
ある。打ち込む元素イオンの種類や元素イオンの打ち込
み量,打ち込み深さ等は成形加工用金型10の材質,形
状,使用条件に応じて任意に選択できる。例えば、成形
加工用金型が超硬合金からなる場合には、打ち込む元素
イオンとしては窒素イオン,炭素イオン,ホウ素イオン
の他、アルゴンなどの不活性ガスイオンが好適である。
The ion implantation process is a method in which high energy is given to an ionized element by an accelerator so that the element ion is rushed into the chamfered surface 15 around the gate port 12 to implant it. The type of elemental ions to be implanted, the amount of elemental ions to be implanted, the depth of implantation, and the like can be arbitrarily selected according to the material, shape, and use conditions of the molding die 10. For example, when the molding die is made of cemented carbide, nitrogen ions, carbon ions, boron ions and inert gas ions such as argon are suitable as the element ions to be implanted.

【0010】第2実施例は、図2に示すように、成形加
工用金型10のゲート11を構成するゲート口12の開
口縁部13に面取り加工を施して面取り部14を形成し
た後、前記ゲート口12周囲の表面15に薄膜層17を
形成したものである。
In the second embodiment, as shown in FIG. 2, after the chamfering portion 14 is formed by chamfering the opening edge portion 13 of the gate opening 12 which constitutes the gate 11 of the molding die 10, the chamfered portion 14 is formed. A thin film layer 17 is formed on the surface 15 around the gate opening 12.

【0011】面取り加工は前述の第1実施例と同様であ
るので、説明を省略する。
The chamfering process is the same as that of the first embodiment described above, and the description thereof will be omitted.

【0012】薄膜層17の形成は既存の方法から任意に
選択でき、大別してPVD法およびCVD法があり、P
VD法としては、例えば、真空蒸着法,スパッタリング
法,イオンプレーティング法,イオン注入蒸着法が挙げ
られ、CVD法としては、例えば、熱CVD法,プラズ
マCVD法,光CVD法が挙げられる。そして、薄膜層
17の形成はこれらの方法を単独で使用してもよく、ま
た、適宜組み合わせて使用してもよい。
The formation of the thin film layer 17 can be arbitrarily selected from the existing methods, and is roughly classified into a PVD method and a CVD method.
Examples of the VD method include a vacuum evaporation method, a sputtering method, an ion plating method, and an ion implantation evaporation method. Examples of the CVD method include a thermal CVD method, a plasma CVD method, and an optical CVD method. Then, for the formation of the thin film layer 17, these methods may be used alone or in appropriate combination.

【0013】薄膜層17を形成する元素,化合物は特に
限定するものではないが、特に、TiN,TiC,BN
等が好適である。
The elements and compounds forming the thin film layer 17 are not particularly limited, but particularly TiN, TiC, BN.
Etc. are suitable.

【0014】薄膜層17の形成方法としては、例えば、
成形加工用金型10が超硬合金からなる場合、ゲート口
12の開口縁部13に面取り加工を施して面取り部14
を形成した後、ゲート口12周囲の表面15にチタンを
真空蒸着させると同時に、窒素イオンをイオン注入して
打ち込むイオン注入蒸着法が代表的である。なお、薄膜
層17は異なる元素,化合物からなる2層構造,3層構
造以上のものであってもよい。
As a method of forming the thin film layer 17, for example,
When the molding die 10 is made of cemented carbide, the chamfered portion 14 is formed by chamfering the opening edge 13 of the gate opening 12.
A typical example is an ion implantation vapor deposition method in which titanium is vacuum deposited on the surface 15 around the gate opening 12 after the formation, and at the same time, nitrogen ions are ion-implanted and implanted. Note that the thin film layer 17 may have a two-layer structure, a three-layer structure, or more composed of different elements and compounds.

【0015】第3実施例は、図3に示すように、前述の
実施例と同様、ゲート口12の開口縁部13に面取り部
14を形成した後、前記ゲート口12周囲の表面15に
イオン注入層16および薄膜層17を順次形成したもの
である。
In the third embodiment, as shown in FIG. 3, the chamfered portion 14 is formed on the opening edge portion 13 of the gate opening 12, and then the ions are formed on the surface 15 around the gate opening 12 as in the above-described embodiments. The injection layer 16 and the thin film layer 17 are sequentially formed.

【0016】面取り部14の形成、イオン注入層16お
よび薄膜層17の形成は前述の第1,第2実施例とほぼ
同様であるので、説明を省略する。
Since the formation of the chamfered portion 14 and the formation of the ion implantation layer 16 and the thin film layer 17 are almost the same as those of the first and second embodiments described above, the description thereof will be omitted.

【0017】本実施例によれば、イオン注入層16を形
成した後に薄膜層17を形成するので、金型10の表面
15に対する薄膜層17の密着強度が向上し、寿命がよ
り一層伸びるという利点がある。
According to this embodiment, since the thin film layer 17 is formed after the ion implantation layer 16 is formed, the adhesion strength of the thin film layer 17 to the surface 15 of the mold 10 is improved and the life is further extended. There is.

【0018】第4実施例は、図4に示すように、前述の
実施例がゲート口12の開口縁部13に形成した面取り
部14にイオン注入層16等を形成したものであるのに
対し、ゲート口12の開口縁部13にアール付け加工を
施してアール付け部18を形成した後、ゲート口12周
囲の表面15にイオン注入処理を施してイオン注入層1
6を形成したものである。
In the fourth embodiment, as shown in FIG. 4, the ion implantation layer 16 and the like are formed in the chamfered portion 14 formed in the opening edge portion 13 of the gate opening 12 in the above-described embodiment. After forming the rounded portion 18 by performing the rounding processing on the opening edge portion 13 of the gate opening 12, the surface 15 around the gate opening 12 is subjected to the ion implantation processing to form the ion implantation layer 1
6 is formed.

【0019】アール付け部18の大きさ,形成方法は、
既存のものから必要に応じて適宜選択すればよく、特に
限定するものではないが、アール付け加工は射出成形し
た際に生じる初期摩耗を利用したものであってもよい。
また、イオン注入処理は前述の第1実施例と同様である
ので、説明を省略する。
The size and forming method of the rounded portion 18 are as follows.
It may be appropriately selected from existing ones and is not particularly limited, but the rounding process may be one utilizing the initial wear that occurs during injection molding.
The ion implantation process is the same as that of the first embodiment described above, and therefore its explanation is omitted.

【0020】第5実施例は、図5に示すように、ゲート
口12の開口縁部13にアール付け加工を施してアール
付け部18を形成した後、前記ゲート口12周囲の表面
15に薄膜層17を形成した場合である。
In the fifth embodiment, as shown in FIG. 5, after the rounded portion 18 of the gate opening 12 is rounded to form the rounded portion 18, a thin film is formed on the surface 15 around the gate opening 12. This is the case where the layer 17 is formed.

【0021】アール付け加工は前述の第4実施例と同様
であり、薄膜層17の形成方法は前述の第2実施例と同
様であるので、説明を省略する。
The rounding process is the same as that of the above-mentioned fourth embodiment, and the method of forming the thin film layer 17 is the same as that of the above-mentioned second embodiment, so the explanation is omitted.

【0022】第6実施例は、図6に示すように、開口縁
部13にアール付け部18を形成した後、前記ゲート口
12周囲の表面15にイオン注入層16および薄膜層1
7を順次形成した場合である。
In the sixth embodiment, as shown in FIG. 6, after the radiused portion 18 is formed on the opening edge portion 13, the ion implantation layer 16 and the thin film layer 1 are formed on the surface 15 around the gate opening 12.
This is a case where 7 are sequentially formed.

【0023】アール付け加工は前述の第4実施例と同様
であり、また、イオン注入層16および薄膜層17の形
成方法は前述の第3実施例と同様であるので、説明を省
略する。
The rounding process is the same as that of the above-mentioned fourth embodiment, and the method of forming the ion implantation layer 16 and the thin film layer 17 is the same as that of the above-mentioned third embodiment, so a description thereof will be omitted.

【0024】[0024]

【発明の効果】以上の説明から明らかなように、本発明
にかかる成形加工用金型によれば、面取り加工で形成さ
れる面取り部またはアール付け加工で形成されるアール
付け部によって開口縁部の角度が鈍角になるとともに、
開口縁部とイオン注入層あるいは薄膜層との接触面積が
増大することによる相乗作用により、ゲート口の開口縁
部における耐衝撃性,耐摩耗性が向上するので、金型の
寿命が伸び、メンテナンスが軽減されて生産コストが低
減するという効果がある。
As is apparent from the above description, according to the molding die of the present invention, the opening edge portion is formed by the chamfered portion formed by chamfering or the rounded portion formed by rounding. Becomes obtuse,
By increasing the contact area between the opening edge and the ion-implanted layer or thin film layer, the impact resistance and wear resistance at the opening edge of the gate opening are improved, so the life of the mold is extended and maintenance is improved. Is reduced and the production cost is reduced.

【図面の簡単な説明】[Brief description of drawings]

【図1】 本発明にかかる成形加工用金型の第1実施例
を示す部分拡大断面図である。
FIG. 1 is a partially enlarged cross-sectional view showing a first embodiment of a molding die according to the present invention.

【図2】 本発明にかかる成形加工用金型の第2実施例
を示す部分拡大断面図である。
FIG. 2 is a partially enlarged sectional view showing a second embodiment of the molding die according to the present invention.

【図3】 本発明にかかる成形加工用金型の第3実施例
を示す部分拡大断面図である。
FIG. 3 is a partially enlarged sectional view showing a third embodiment of a molding die according to the present invention.

【図4】 本発明にかかる成形加工用金型の第4実施例
を示す部分拡大断面図である。
FIG. 4 is a partially enlarged sectional view showing a fourth embodiment of a molding die according to the present invention.

【図5】 本発明にかかる成形加工用金型の第5実施例
を示す部分拡大断面図である。
FIG. 5 is a partially enlarged sectional view showing a fifth embodiment of a molding die according to the present invention.

【図6】 本発明にかかる成形加工用金型の第6実施例
を示す部分拡大断面図である。
FIG. 6 is a partially enlarged sectional view showing a sixth embodiment of a molding die according to the present invention.

【図7】 従来例にかかる成形加工用金型の組み付け状
態を示す断面図である。
FIG. 7 is a cross-sectional view showing an assembled state of a molding die according to a conventional example.

【図8】 従来例にかかるゲート口を有する成形加工用
金型を示す部分斜視図である。
FIG. 8 is a partial perspective view showing a molding die having a gate opening according to a conventional example.

【図9】 従来例にかかるゲート口を有する成形加工用
金型を示す部分拡大断面図である。
FIG. 9 is a partially enlarged sectional view showing a molding die having a gate opening according to a conventional example.

【符号の説明】[Explanation of symbols]

10…成形加工用金型、11…ゲート、12…ゲート
口、13…開口縁部、14…面取り部、15…表面、1
6…イオン注入層、17…薄膜層、18…アール付け
部。
DESCRIPTION OF SYMBOLS 10 ... Mold for processing, 11 ... Gate, 12 ... Gate opening, 13 ... Opening edge, 14 ... Chamfer, 15 ... Surface, 1
6 ... Ion implantation layer, 17 ... Thin film layer, 18 ...

Claims (7)

【特許請求の範囲】[Claims] 【請求項1】 開口縁部に面取り加工を施したゲート口
周囲の表面に、イオン注入層を形成したことを特徴とす
る成形加工用金型。
1. A molding die, wherein an ion-implanted layer is formed on a surface around a gate opening whose opening edge is chamfered.
【請求項2】 開口縁部に面取り加工を施したゲート口
周囲の表面に、薄膜層を形成したことを特徴とする成形
加工用金型。
2. A molding die, wherein a thin film layer is formed on the surface around the gate opening whose opening edge is chamfered.
【請求項3】 開口縁部に面取り加工を施したゲート口
周囲の表面に、イオン注入層および薄膜層を順次形成し
たことを特徴とする成形加工用金型。
3. A molding die, wherein an ion-implanted layer and a thin film layer are sequentially formed on a surface around the gate opening whose opening edge is chamfered.
【請求項4】 開口縁部にアール付け加工を施したゲー
ト口周囲の表面に、イオン注入層を形成したことを特徴
とする成形加工用金型。
4. A molding die, wherein an ion-implanted layer is formed on a surface around a gate opening whose opening edge is rounded.
【請求項5】 開口縁部にアール付け加工を施したゲー
ト口周囲の表面に、薄膜層を形成したことを特徴とする
成形加工用金型。
5. A molding die, wherein a thin film layer is formed on the surface around the gate opening whose opening edge is rounded.
【請求項6】 開口縁部にアール付け加工を施したゲー
ト口周囲の表面に、イオン注入層および薄膜層を順次形
成したことを特徴とする成形加工用金型。
6. A molding die, wherein an ion-implanted layer and a thin film layer are sequentially formed on a surface around a gate opening having a rounded edge portion.
【請求項7】 前記アール付け加工が、樹脂等を成形加
工する際に生じる初期摩耗であることを特徴とする請求
項4,5又は6記載の成形加工用金型。
7. The molding die according to claim 4, wherein the rounding process is initial wear that occurs when molding resin or the like.
JP29851692A 1992-11-09 1992-11-09 Forming mold Pending JPH06143350A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29851692A JPH06143350A (en) 1992-11-09 1992-11-09 Forming mold

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29851692A JPH06143350A (en) 1992-11-09 1992-11-09 Forming mold

Publications (1)

Publication Number Publication Date
JPH06143350A true JPH06143350A (en) 1994-05-24

Family

ID=17860736

Family Applications (1)

Application Number Title Priority Date Filing Date
JP29851692A Pending JPH06143350A (en) 1992-11-09 1992-11-09 Forming mold

Country Status (1)

Country Link
JP (1) JPH06143350A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1048432A1 (en) * 1999-04-28 2000-11-02 Shin-Etsu Chemical Co., Ltd. Mold and method for producing molded fluoroelastomer parts
JP2016087818A (en) * 2014-10-30 2016-05-23 双葉電子工業株式会社 Valve gate apparatus and injection molding die

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1048432A1 (en) * 1999-04-28 2000-11-02 Shin-Etsu Chemical Co., Ltd. Mold and method for producing molded fluoroelastomer parts
US6468463B1 (en) 1999-04-28 2002-10-22 Shin-Etsu Chemical Co., Ltd. Method for producing molded fluoroelastomer parts
JP2016087818A (en) * 2014-10-30 2016-05-23 双葉電子工業株式会社 Valve gate apparatus and injection molding die

Similar Documents

Publication Publication Date Title
EP0543444B1 (en) Die Coating
SE9502258D0 (en) Method for the manufacture of a membrane-containing microstructure
AU2003273873A1 (en) Protective layer, method and arrangement for the production of protective layers
MY130996A (en) Method of fabricating a coated process chamber component
US20030178301A1 (en) Planar magnetron targets having target material affixed to non-planar backing plates
EP1132189A1 (en) Improvements in and relating to injection moulding
JPH06143350A (en) Forming mold
TW367528B (en) Titanium aluminide wetting layer for aluminum contacts
EP1087033A8 (en) Extended life sputter targets
WO2004056698A3 (en) Method for making a planar suspended microstructure, using a sacrificial layer of polymer material and resulting component
JP3837928B2 (en) Member for resin molding apparatus and method for manufacturing the same
JP4096373B2 (en) Hard coating and manufacturing method thereof
JPH06330350A (en) Surface hardening treatment method of injection molding metallic mold
JPH0623444A (en) Metallic die for press work
AU718549B2 (en) Mold for pressing and molded glass substrate for computer me mory by using it
JP3049132B2 (en) Manufacturing method of optical element molding die and optical element molding die
AU2002364794A8 (en) Improved method for coating a support
KR100190294B1 (en) Coating method for glass lens
JP3705634B2 (en) Optical disc substrate injection mold and molding method
ES1043511U (en) Surface-coated object
JP2904672B2 (en) Glass lens mold and method of manufacturing the same
KR970003001Y1 (en) Continuous casting mold
TW359007B (en) Production-method for an isolation-layer acted as intermetal-dielectric
JPH06114844A (en) Mold
JPH03130358A (en) Structure of white ornament coating film