JPH06107527A - Cleansing agent composition for hair - Google Patents

Abstract

PURPOSE:To obtain a cleansing agent for hair having excellent refreshing feeling and excellent conditioning properties. CONSTITUTION:This cleansing composition for hair is obtained by blending a cleansing agent composition for hair containing the blend of an amphoteric surfactant and a nitrogen-containing water-soluble high polymer with cool feeling substance such as menthol or camphor and a warm feeling substance such as capsicum tincture or zingiberis rhizoma tincture.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair cleansing composition having both excellent conditioning properties and an excellent refreshing feeling.

[0002]

2. Description of the Related Art In recent years, along with changes in lifestyle or changes in consumer consciousness for shampoo,
The functions required for shampoo have changed significantly. That is, there is a demand for a shampoo that not only removes stains on the hair and scalp but also imparts a moist and supple feel to the hair after washing and drying, and a good comb-like finish. Conventionally, this problem has been solved by using a water-soluble quaternary nitrogen-containing polymer and an amphoteric surfactant in combination. On the other hand, especially for men, the function of imparting a refreshing refreshing feeling during and after washing hair is widely accepted, and many products having this function are on the market. Conventionally, this function has been added by blending a cooling sensation substance, and many cooling sensation substances have been proposed so far. (Japanese Patent Publication Sho 63-456
50, JP-A-47-16647, JP-A-47-16
649, JP-A-47-16650, JP-A-58-8.
8334, JP-A-61-194049, JP-A-62.
However, it is difficult to give a sufficient cooling sensation with a combination of conventionally used techniques when the above two functions are combined, and a technique capable of imparting both functions has not been found yet.

[0003]

Means for Solving the Problems As a result of intensive studies to solve the above problems, in a composition containing an amphoteric surfactant and a quaternary nitrogen-containing water-soluble polymer, menthol, camphor, borneol, cineol menthone, Methyl salicylate, spearmint, peppermint, menthyl malonate, glycosyl-mono-menthyl-O-acetate, 3-l-menthoxypropane-1,2-diol,
At least one cooling sensation substance selected from l-menthyl-3-hydroxybutyrate, capsicum tincture, ginger tincture, nicotinic acid and its derivatives, vanillylamide nonanoate, capsaicin, dihydrocapsaicin, nordihydrocapsaicin, 8-methyl- The present invention found a hair cleansing composition capable of imparting both excellent conditioning properties and an excellent cooling sensation by blending at least one or more warming substances selected from N-vanillyl 6-nonamide, ginger rolls, and gingerrons. The invention was completed.

That is, the present invention provides a composition containing an amphoteric surfactant and a quaternary nitrogen-containing water-soluble polymer, including menthol, camphor, borneol, cineol menthone, methyl salicylate, spearmint, peppermint, menthyl malonate and glycosyl. Monomenthyl O-acetate, 3-L-menthoxypropane-1,2
-Diol, at least one or more cooling sensation substances selected from l-menthyl-3-hydroxybutyrate, capsicum tincture, ginger tincture, nicotinic acid and its derivatives, vanillylamide nonanoate, capsaicin, dihydrocapsaicin, nordihydrocapsaicin, A hair-cleansing composition containing at least one or more warming substances selected from 8-methyl-N-vanillyl 6-nonamide, gingerol, and gingerron.

Examples of the amphoteric surfactant used in the present invention include imidazolinium betaine-type amphoteric surfactant, amidobetaine-type amphoteric surfactant, alkylbetaine-type amphoteric surfactant, sulfobetaine-type amphoteric surfactant, Examples include foshobetaine-type amphoteric surfactants.

The imidazolinium betaine-type amphoteric surfactant has the formula (1)

[Chemical 1] And equation (2)

[Chemical 2] [Wherein R 1 and R 3 are alkyl or alkenyl groups having 7 to 19 carbon atoms, R 2 and R 4 are —CH 2 COOM or —CH 2 CH 2 COOM, R 5 is —CH 2 COOM or —CH 2 CH 2 COOM or hydrogen, and M is independently hydrogen, an alkali metal, Cation derived from alkanolamine]

As examples of this, N-lauroyluru N'-carboxyethyl-N '-(2-hydroxyethyl) ethylenediamine and its sodium salt or triethanolamine salt, N-undecyl-N'-carboxymethyl-N'-(2-hydroxyethyl) ) Ethylenediamine and its sodium salt or triethanolamine salt,
N-Lauroyl Lou N'-Carboxymethyl-N '-(2
-Hydroxyethyl) ethylenediamine sodium salt or triethanolamine salt, N-undecyl-N
-(2-hydroxyethyl) -N'-carboxymethylethylenediamine sodium salt or triethanolamine salt, N-undecyl-N- (2-hydroxyethyl) -N'-carboxymethylethylenediamine sodium salt or triethanolamine salt, N -Lauroyl Lou N- (2-hydroxyethyl) -N'-carboxymethylethylenediamine sodium salt or triethanolamine salt, N-Lauroyl Lou N- (2-hydroxyethyl) -N, N'-bis (carboxymethyl) ethylenediamine sodium salt or Examples thereof include a triethanolamine salt, a sodium salt of N-lauroyl roux N- (2-hydroxyethyl) -N ′, N′-bis (carboxyethyl) ethylenediamine, a triethanolamine salt and the like.

Amidobetaine type amphoteric surfactants are represented by the formula (3)

[Chemical 3] [In the formula, R6 is an aliphatic primary alcohol residue having 7 to 17 carbon atoms]

Examples of this include betayl laurylamidopropyldimethylaminoacetic acid, betaine myristylamidopropyldimethylaminoacetic acid, betaine stearylamidopropyldimethylaminoacetic acid, betaine oleylamidopropyldimethylaminoacetic acid and betaine cocoylamidopropyldimethylaminoacetic acid.

The alkyl betaine-type amphoteric surfactant has the formula (4)

[Chemical 4] [In the formula, R7 is an aliphatic primary alcohol residue having 7 to 17 carbon atoms]

As examples of this, betayl lauryldimethylaminoacetate, betaine myristyldimethylaminoacetate,
Stearyl dimethylamino acetic acid betaine, oleyl dimethyl amino acetic acid betaine, cocoyl dimethyl amino acetic acid betaine, etc. are mentioned.

These amphoteric surfactants may be used alone or in combination.
Any one or more of these may be used in combination, and the amount thereof is preferably 0.1 to 20% by weight, more preferably 1 to 15% by weight. If it is less than 0.1% by weight, the desired effect cannot be obtained, and if it exceeds 20% by weight, it is not preferable from the economical viewpoint.

Examples of the quaternary nitrogen-containing water-soluble polymer used in the present invention include poly (dimethylmethylene piperidium chloride), hydroxyethyl cellulose dimethyl diallyl ammonium chloride polymer, dimethyl diallyl ammonium chloride / acrylic acid copolymer, Dimethyldiallylammonium chloride / acrylamide copolymer, guar gum hydroxypropyltrimethylammonium chloride ether, hydroxyethylcellulose hydroxypropyltrimethylammonium chloride ether, quaternary nitrogen-containing poly (trialkylaminoethylmethacrylate) derivative, water solubility of tetraethylpentamine and epichlorohydrin Cationic polymer, quaternary nitrogen-containing collagen protein hydrolyzate, quaternary nitrogen-containing dextran, quaternary nitrogen-containing Such as keratin protein hydrolyzate thereof.

These quaternary nitrogen-containing water-soluble polymers are 1
One kind or two or more kinds may be used in an arbitrary combination, and the blending amount thereof is preferably 0.01 to 2% by weight, more preferably 0.1 to 1% by weight. 0.01
If it is less than wt%, the desired effect cannot be obtained,
If it exceeds 2% by weight, the hair feels stiff after drying, which is not preferable.

Cooling substances include menthol, camphor, borneol, cineol menthone, methyl salicylate, spearmint, peppermint, menthyl malonate, glycosyl-mono-menthyl-O-acetate, 3-l-menthoxypropane-1,2-diol, l.ー Menchiru 3
-Hydroxybutyrate, 0.001 to 10 based on the total amount of the composition from the desired function and economical viewpoint.
%, Preferably 0.01 to 3% by weight.

Warming substances include capsicum tincture, ginger tincture, nicotinic acid and its derivatives, nonanoic acid vanillylamide, capsaicin, dihydrocapsaicin,
Examples thereof include nordihydrocapsaicin, 8-methyl-N-vanillyl 6-nonamide, ginger roll and gingerron. Further, as the nicotinic acid derivative, benzyl nicotinate, methyl nicotinate, nicotinic acid amide, tocopherol nicotinate, butoxyethyl nicotinate,
Beta-Butoxyethyl nicotinate, nicotinic acid 1- (4
-Methylphenyl) ethyl, etc., and 0.000 based on the total amount of the composition from the desired function and economical viewpoint.
The amount is 1 to 5% by weight, preferably 0.001 to 1% by weight.

Further, in the present invention, well-known components can be blended within a range that does not impair the effect. Well-known ingredients include anionic surfactants, cationic surfactants, nonionic surfactants, pearling agents, wetting agents, conditioning agents, preservatives, coloring agents, antidandruff agents and other medicinal agents, and fragrances. is there. The hair cleansing composition of the present invention can be prepared by mixing and dissolving each component according to a conventional method.

[0018]

EXAMPLES Next, the present invention will be described in more detail with reference to Examples and Comparative Examples. Needless to say, the present invention is not limited to the embodiments. Unless otherwise specified, [%] means [% by weight]. (Evaluation method) 1. Feeling at the time of rinsing The evaluation was performed according to the following 5 grades by the use evaluation of 10 professional panelists. Rating 1: Very good, Rating 2: Slightly good, Rating 3: Normal, Rating 4: Slightly bad, Rating 5: Very bad Evaluation Criteria ○: When 10 people have a rating of 3 or less, the feeling during rinsing is good. X: When 10 persons have a score of 4 or more, the feel during rinsing is poor. Cool sensation The use was evaluated by 10 professional panelists, and was evaluated according to the following 5 grades. Rating 1: Very good, Rating 2: Somewhat good, Rating 3: Normal, Rating 4: Somewhat bad, Rating 5: Very bad ◎: Very cool feeling when the average rating of 10 people is less than 1.5 Strong ◯: When the average score of 10 people is 1.5 to less than 2.5, the refreshing feeling is strong. Δ: When the average score of 10 people is from 2.5 to 3.5, the cooling feeling is slightly weak. When the average score of 10 people is 3.5 or more, the refreshing feeling is weak

[0019]

[Table 1] As shown in Table 3, the hair cleansing composition having the excellent feeling during rinsing and the excellent refreshing feeling in the formulation of the example was obtained.

[0020]

EFFECTS OF THE INVENTION According to the present invention, a hair cleansing composition having both excellent conditioning properties and an excellent refreshing feeling can be obtained.

Claims (1)

[Claims] 1. A composition comprising an amphoteric surfactant and a quaternary nitrogen-containing water-soluble polymer, which comprises menthol, camphor, borneol, cineole menthone, methyl salicylate, spearmint, peppermint, menthyl malonate, glycosyl-mono-menthiru. O-acetate, 3
-Menthoxypropane-1,2-diol, at least one or more cooling sensation substances selected from l-menthyl-3-hydroxybutyrate, and capsicum tincture, ginger tincture, nicotinic acid and its derivatives, vanillylamide nonanoate, Capsaicin, dihydrocapsaicin, nordihydrocapsaicin, 8-methyl-N
-Vanililou 6-Cleansing composition for hair comprising at least one warming substance selected from non-amide, ginger roll and gingerron