WO2002017865A1 - Pre-shampoo conditioning composition - Google Patents
Pre-shampoo conditioning composition Download PDFInfo
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- WO2002017865A1 WO2002017865A1 PCT/US2001/005739 US0105739W WO0217865A1 WO 2002017865 A1 WO2002017865 A1 WO 2002017865A1 US 0105739 W US0105739 W US 0105739W WO 0217865 A1 WO0217865 A1 WO 0217865A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Definitions
- the present invention relates to pre-shampoo conditioning compositions which deliver conditioning benefit to the hair by applying on dry hair and subsequently washing the hair with a shampoo. Specifically, the present invention relates to pre-shampoo conditioning compositions having a phase inversion property.
- shampooing can leave the hair in a wet, tangled, and generally unmanageable state. Once the hair dries, it is often left in a dry, rough, lusterless, or frizzy condition due to removal of the hair's natural oils and other natural conditioning and moisturizing components. The hair can further be left with increased levels of static upon drying, which can interfere with combing and result in a condition commonly referred to as "fly-away hair", or contribute to an undesirable phenomena of "split ends", particularly for long hair.
- conditioners Although some consumers prefer the ease and convenience of a shampoo which includes conditioners, a substantial proportion of consumers prefer the more conventional conditioner formulations which are applied to the hair as a separate step from shampooing.
- conditioners there are two types of product forms that consumers prefer using.
- One form is the rinse off type conditioners, which would be applied during a bathing regimen subsequent to shampooing the hair, and typically be rinsed off from the hair.
- Another form is the leave on type conditioners, which would be applied to the hair in a dry or partially wet condition, typically as part of a styling regimen, and the hair would be left to dry.
- oils which are liquid at room temperature, such as coconut oil
- Such oils are difficult to effectively deliver to the hair.
- the oils When such oils are contained in rinse off conditioning formulations and applied to the hair in a wet condition subsequent to shampooing, the oils would not deposit on and/or penetrate in the hair in an effective manner, and thus easily washed off in the rinsing process.
- leave on conditioning formulations and applied in a relatively dry condition and left to dry the hair would be left with a sticky feel and a negative appearance.
- the conditioning benefit of oils were not achieved with the conventional method of use for such oils.
- hair volume-up is not equal to fly-away hair. Fly-away hair is due to the increased level of static, and represents volume increase of only very minor amount of the hair as a whole, and is not desirable.
- hair volume-up as used herein relates to increase of the bulk of the hair volume. Consumers having fine hair have the desire to achieve hair volume-up while controlling undesirable fly-away of the hair.
- hair conditioner products targeted for such consumers provided the volume-up or less volume- down benefit by decreasing the level of conditioning actives, including oils, included in the composition. This is thought to be emerging from the concept that conditioning actives weigh down the hair.
- hair conditioner products targeted for consumers which desire volume-up generally had only compromised conditioning benefits.
- hair conditioning compositions which provide manageability and volume up to the hair while also providing a smooth, soft, and moisturized feel to the hair.
- hair conditioning compositions which provide such benefits without giving a sticky feel or heavy feel during and after use, or negative appearance after use.
- hair conditioning compositions which provide such benefits which have a clear transparent appearance.
- the present invention is directed to a hair conditioning composition for applying to the dry hair prior to shampooing, comprising: (a) a conditioning oil which is in liquid form at 25°C; and (b) a nonionic surfactant in an amount which provides phase inversion when the composition is in contact with an abundant amount of water.
- the composition of the present invention comprises a conditioning oil which is in liquid form at 25°C, preferably up to about 99.9%, more preferably from about 30% to about 99% by weight of the composition.
- the conditioning oils useful herein are those which deposit on the surface of the hair when it is dry.
- the conditioning oils useful herein are those which can, to some extent, penetrate into the hair and thus not washed off after subsequent shampooing.
- the conditioning oils useful herein are those which can, after phase inversion, provide controlled coverage to the surface of the hair.
- Conditioning oils useful herein include those extracted or derived from a natural resource which contain a variety of compounds, and synthetic oils consisting of more or less a single compound. While volatile conditioning oils are not precluded herein, such oils are either kept to a relatively high boiling point or to a low level so as not to dry the hair, scalp, and hands.
- Useful conditioning oils herein include vegetable oils, animal oils, and oils from other natural resources, synthetic oils, and mixtures thereof.
- the oils are selected according to the characteristics desired for the conditioner formulations. It is preferred that a certain amount of oils having a molecular weight of less than about 1500 is contained. Without being bound by theory, it is believed that oils having such molecular weight have the ability to penetrate into the hair.
- paraffin oil is used at a level of at least about 50% of the composition.
- Such high-paraffin oil composition is believed to provide a light fresh feel to the hair with controlled coverage to the hair.
- Vegetable oils useful herein are canola oil, camellia oil, olive oil, sunflower seed oil, cottonseed oil, soybean oil, peanut oil, olive oil, palm oil, corn oil, rapeseed oil, sesame oil, safflower oil, coconut oil, palm kernel oil, avocado oil, macadamia nut oil, corn oil, persic oil, wheat germ oil, pasanqua oil, linseed oil, perillic oil, teaseed oil, kaya oil, rice bran oil, china paulownia oil, Japanese paulownia oil, jojoba oil, rice germ oil, and mixtures thereof.
- Particularly preferred are canola oil, camellia oil, olive oil, sunflower seed oil, and mixtures thereof.
- oils and oils from other natural resources useful herein are sardine oil, lard, tallow, turtle oil, eggyolk oil, mink oil, squalane, lanolin, liquid lanolin, liquid paraffin, vaseline, and mixtures thereof.
- Commercially available oils of natural resource useful herein include: canola oil with tradename Canola Salad Oil available from Ajinomoto, and tradenames Cropure Almond, Cropure Apricot Kernel, Cropure avocado, and Cropure Peanut available from Croda.
- Fatty alcohols useful herein as a conditioning oil include those having from about 10 to about 30 carbon atoms, preferably from about 12 to about 22 carbon atoms, and more preferably from about 16 to about 22 carbon atoms. These fatty alcohols can be straight or branched chain alcohols, preferably unsaturated alcohols. Nonlimiting examples of these compounds include oleyl alcohol, palmitoleic alcohol, linoleyl alcohol, and recinoleyl alcohol.
- Fatty acids useful herein as a conditioning oil include those having from about 10 to about 30 carbon atoms, preferably from about 12 to about 22 carbon atoms, and more preferably from about 16 to about 22 carbon atoms. These fatty acids can be straight or branched chain acids and are unsaturated. Suitable fatty acids include, for example, oleic acid, linoleic acid, linolenic acid, ethyl linolenic acid, ethyl linolenic acid, arachidonic acid, and ricinolic acid.
- Fatty acid derivatives and fatty alcohol derivatives useful herein as a conditioning oil are defined herein to include, for example, esters of fatty alcohols, alkoxylated fatty alcohols, alkyl ethers of fatty alcohols, alkyl ethers of alkoxylated fatty alcohols, and bulky ester oils such as pentaerythritol ester oils, trimethylol ester oils, citrate ester oils, glyceryl ester oils, and mixtures thereof.
- Nonlimiting examples of fatty acid derivatives and fatty alcohol derivatives include, for example, methyl linoleate, ethyl linoleate, isopropyl linoleate, isodecyl oleate, isopropyl oleate, ethyl oleate, octyldodecyl oleate, oleyl oleate, decyl oleate, butyl oleate, methyl oleate, octyldodecyl stearate, octyldodecyl isostearate, octyldodecyl isopalmitate, octyl isopelargonate, octyl pelargonate, hexyl isostearate, isopropyl isostearate, isodecyl isononanoate, isopropyl isostearate,
- Bulky ester oils such as pentaerythritol ester oils, trimethylol ester oils, citrate ester oils and glyceryl ester oils useful herein are those which have a molecular weight of less than about 800, preferably less than about 500.
- Hydrocarbons useful herein as a conditioning oil include straight chain, cyclic, and branched chain hydrocarbons which can be either saturated or unsaturated, so long as they have a melting point of not more than about 25°C. These hydrocarbons have from about 12 to about 40 carbon atoms, preferably from about 12 to about 30 carbon atoms, and more preferably from about 12 to about 22 carbon atoms. Also encompassed herein are polymeric hydrocarbons of alkenyl monomers, such as polymers of C 2 - 6 alkenyl monomers. These polymers can be straight or branched chain polymers. The straight chain polymers will typically be relatively short in length, having a total number of carbon atoms as described above. The branched chain polymers can have substantially higher chain lengths.
- the number average molecular weight of such materials can vary widely, but will typically be up to about 500, preferably from about 200 to about 400, and more preferably from about 300 to about 350.
- mineral oils are liquid mixtures of hydrocarbons that are obtained from petroleum. Specific examples of suitable hydrocarbon materials include paraffin oil, mineral oil, dodecane, isododecane, hexadecane, isohexadecane, eicosene, isoeicosene, tridecane, tetradecane, polybutene, polyisobutene, and mixtures thereof.
- fatty alcohols and their derivatives useful herein include: oleyl alcohol with tradename UNJECOL 90BHR available from Shin Nihon Rika, various liquid esters with tradenames SCHERCEMOL series available from Scher, and hexyl isostearate with a tradename HIS and isopropryl isostearate having a tradename ZPIS available from Kokyu Alcohol.
- hydrocarbons useful herein include mixtures of isoparaffins and cycloparaffins with molecular weight of about 330 with tradename CARNATION available from Witco, isododecane, isohexadeance, and isoeicosene with tradenames PERMETHYL 99A, PERMETHYL 101 A, and PERMETHYL 1082 available from Presperse (South Plainfield New Jersey, USA), a copolymer of isobutene and normal butene with tradenames INDOPOL H-100 available from Amoco Chemicals (Chicago Illinois, USA), mineral oil with tradename BENOL available from Witco, BRITOL series and KAYDOL available from Witco, DRAKEOL series available from Penreco, MARCOL series available from Esso, and SUPERLA MINERAL OIL series available from Amoco Lubricants, and isoparaffin with tradename ISOPAR from Exxon Chemical Co. (Houston Texas, USA).
- CARNATION available from Wi
- Poly -olefin oils useful herein are those derived from 1-alkene monomers having from about 6 to about 16 carbons, preferably from about 6 to about 12 carbons atoms.
- 1-alkene monomers useful for preparing the poly ⁇ -olefin oils include 1-hexene, 1-octene, 1-decene, 1- dodecene, 1 -tetradecene, 1 -hexadecene, branched isomers such as 4-methyl-1- pentene, and mixtures thereof.
- Preferred 1-alkene monomers useful for preparing the poly ⁇ -olefin oils are 1 -octene, 1-decene, 1 -dodecene, 1- tetradecene, 1 -hexadecene, and mixtures thereof.
- Poly ⁇ -olefin oils useful herein further have a viscosity of from about 1 to about 35,000 cst, a molecular weight of from about 200 to about 60,000, preferably less than about 6,000, and more preferably less than about 800; and a polydispersity of no more than about 3.
- poly ⁇ -olefin oils herein include polydecenes with tradenames PURESYN 6 having a number average molecular weight of about 500 available from Mobil Chemical Co.
- High molecular weight ester oils useful herein as a conditioning oil include pentaerythritol ester oils, trimethylol ester oils, citrate ester oils, glyceryl ester oils, and mixtures thereof.
- the high molecular weight ester oils herein are "water- insoluble".
- water-insoluble means the compound is substantially not soluble in water at 25°C; when the compound is mixed with water at a concentration by weight of above 1 .0%, preferably at above 0.5%, the compound is temporarily dispersed to form an unstable colloid in water, then is quickly separated from water into two phases.
- Pentaerythritol ester oils useful herein are those having the following formula:
- R 1 , R 2 , R 3 , and R 4 independently, are branched, straight, saturated, or unsaturated alkyl, aryl, and alkylaryl groups having from 1 to about 30 carbons.
- R 1 , R 2 , R 3 , and R 4 independently, are branched, straight, saturated, or unsaturated alkyl groups having from about 8 to about 22 carbons. More preferably, R 1 , R 2 , R 3 and R 4 are defined so that the molecular weight of the compound is from about 500 to about 1200.
- Trimethylol ester oils useful herein are those having the following formula: wherein R 11 is an alkyl group having from 1 to about 30 carbons, and R 12 , R 13 and R 14 , independently, are branched, straight, saturated, or unsaturated alkyl, aryl, and alkylaryl groups having from 1 to about 30 carbons.
- R 11 is ethyl and R 12 , R 13 , and R 14 , independently, are branched, straight, saturated, or unsaturated alkyl groups having from 8 to about 22 carbons. More preferably, R 11 , R 12 , R 13 and R 14 are defined so that the molecular weight of the compound is from about 500 to about 1200.
- pentaerythritol ester oils and trimethylol ester oils herein include pentaerythritol tetraisostearate, pentaerythritol tetraoleate, trimethylolpropane triisostearate, trimethylolpropane trioleate, and mixtures thereof.
- Such compounds are available from Kokyo Alcohol with tradenames KAKPTI, KAKTT1, and Shin-nihon Rika with tradenames PTO, ENUJERUBU TP3SO.
- Citrate ester oils useful herein are those having a molecular weight of at least about 500 having the following formula:
- R 21 is OH or CH 3 COO
- R 22 , R 23 , and R 24 independently, are branched, straight, saturated, or unsaturated alkyl, aryl, and alkylaryl groups having from 1 to about 30 carbons.
- R 21 is OH
- R 22 , R 23 , and R 24 independently, are branched, straight, saturated, or unsaturated alkyl, aryl, and alkylaryl groups having from 8 to about 22 carbons.
- citrate ester oils herein include triisocetyl citrate with tradename CITMOL 316 available from Bernel, triisostearyl citrate with tradename PELEMOL TISC available from Phoenix, and trioctyldodecyl citrate with tradename CITMOL 320 available from Bernel.
- Glyceryl ester oils useful herein are those having a molecular weight of at least about 500 and having the following formula:
- R 41 , R 42 , and R 43 are branched, straight, saturated, or unsaturated alkyl, aryl, and alkylaryl groups having from 1 to about 30 carbons.
- R 41 , R 42 , and R 43 independently, are branched, straight, saturated, or unsaturated alkyl, aryl, and alkylaryl groups having from 8 to about 22 carbons.
- Particularly useful glyceryl ester oils herein include triisostearin with tradename SUN ESPOL G-318 available from Taiyo Kagaku, triolein with tradename CITHROL GTO available from Croda Surfactants Ltd., trilinolein with tradename EFADERMA-F available from Vevy, or tradename EFA- GLYCERIDES from Brooks. NONIONIC SURFACTANTS
- the composition of the present invention comprise nonionic surfactant in an amount which provides phase inversion when the composition is in contact with an abundant amount of water.
- Water may or may not be present in the composition, however, prior to contacting with an abundant amount of water, the composition of the present invention has an oil-continuous phase.
- water may be present as a co- solvent for the nonionic surfactant and aid phase inversion.
- a combination of surfactants can be used.
- Nonionic surfactants include those compounds produced by condensation of alkylene oxide groups, hydrophilic in nature, with an organic hydrophobic compound, which may be aliphatic or alkyl aromatic in nature.
- nonionic surfactants for use in the compositions include the following:
- polyethylene oxide condensates of alkyl phenols e.g., the condensation products of alkyl phenols having an alkyl group containing from about 6 to about 20 carbon atoms in either a straight chain or branched chain configuration, with ethylene oxide, the said ethylene oxide being present in amounts equal to from about 10 to about 60 moles of ethylene oxide per mole of alkyl phenol;
- those derived from the condensation of ethylene oxide with the product resulting from the reaction of propylene oxide and ethylene diamine products
- ethylene oxide e.g., a coconut alcohol ethylene oxide condensate having from about 10 to about 30 moles of ethylene oxide per mole of coconut alcohol, the coconut alcohol fraction having from about 10 to about 14 carbon atoms;
- _ o long chain tertiary amine oxides of the formula [ R1 R2R3
- R contains an alkyl, alkenyl or monohydroxyalkyl radical ranging from about 8 to about 18 carbon atoms in chain length, from 0 to about 10 ethylene oxide moieties and from 0 to 1 glyceryl moieties and R' and R" are each alkyl or monohydroxyalkyl groups containing from about 1 to about 3 carbon atoms;
- long chain dialkyl sulfoxides containing one short chain alkyl or hydroxy alkyl radical of from 1 to about 3 carbon atoms (usually methyl) and one long hydrophobic chain which include alkyl, alkenyl, hydroxy alkyl, or keto alkyl radicals containing from about 8 to about 20 carbon atoms, from 0 to about 10 ethylene oxide moieties and from 0 to 1 glyceryl moieties;
- alkyl polysaccharide (APS) surfactants e.g. alkyl polyglycosides
- alkyl polysaccharide (APS) surfactants e.g. alkyl polyglycosides
- APS surfactants having a hydrophobic group with about 6 to about 30 carbon atoms and a polysaccharide (e.g., polyglycoside) as the hydrophilic group; optionally, there can be a polyalkylene-oxide group joining the hydrophobic and hydrophilic moieties; and the alkyl group (i.e., the hydrophobic moiety) can be saturated or unsaturated, branched or unbranched, and unsubstituted or substituted (e.g., with hydroxy or cyclic rings); a preferred material is alkyl polyglucoside which is commercially available from Henkel, ICI Americas, and Seppic; and
- polyoxyethylene alkyl ethers such as those of the formula RO(CH2CH2) n H and polyethylene glycol (PEG) glyceryl fatty esters, such as those of the formula R(O)OCH2CH(OH)CH2(OCH2CH2) n OH, wherein n is from
- R is an alkyl having from about 8 to about 22 carbon atoms.
- hydrophilic surfactants such as alkyl glucosides, polyglycerin fatty acid esters, polyglycerin alkyl ethers, polyoxyethylene sorbitan fatty acid esters, polyoxypropylene alkyl ethers, polyoxyethylene alkyl phenyl ethers, polyethylene glycol fatty acid esters, ethylene oxide derivatives of polypropylene glycol fatty acid esters, trimethylpropane fatty acid esters, polyoxyethylene hardened castor oil fatty acid esters, polyoxyethylene glyceryl pyroglutamate esters, and mixtures thereof.
- nonionic surfactants useful herein include C12-13 fatty alcohols with an average of 7 moles of ethylene oxide with tradenames Neodol 23-6.5 available from Shell and Dobanol 23-6.5 available from Mitsubishi, and Elfapur LT 65 SLN available from Akzo, sorbeth-40 tetraoleate with tradename Nikkol GO-440 available from Nikko Chemicals, sorbitan isostearate with tradename Crill 6 by Croda, Ariacel 987 available from ICI Americas, Montane-70 available from Seppic, and Nikkol SI-10T available from Nikko Chemicals, oleth-5 with tradename Volpo 5 available from Croda, Brox OL-5 available from Brooks, Ethoxol-5 available from Lanaetex, and Eumulgin 05 available from Henkel.
- a small amount of water can be included in the composition.
- the small amount of water is believed to help stabilize the surfactants in the composition, and further help the phase inversion upon contact of the composition with an abundant amount of water.
- Clarity and/or transparency is an aesthetic benefit which may attract certain consumers who believe such appearance connote purity and mildness.
- the amount of water should be kept to a level such that the composition is not completely emulsified.
- water is kept to a level of no more than about 0.5%, more preferably from about 0.1 % to about 0.5%.
- composition of the present invention may further contain a thickener in an amount which provides the composition to have a viscosity of from about 100 mPa «s to about 200,000 mPa «s, preferably from about 500 mPa «s to about 100,000 mPa «s, more preferably from about 1 ,000 mPa»s to about 100,000 mPa «s.
- a thickener which provides a viscosity of from about
- the viscosity herein is measured by a Brookfield DV-II + viscometer.
- a #52 spindle is used and measured at a condition of using 0.5 ml of the sample at 1 rpm after 1 minute at 27°C.
- a #41 spindle is used and measured at a condition of using 2 ml of the sample at 1 rpm after 3 minutes at 27°C.
- the thickeners useful herein are selected from the group consisting of fatty compounds, waxy compounds, gelling agents, inorganic thickeners, oil soluble polymers, and mixtures thereof.
- the amount and type of thickeners are selected according to the desired viscosity and characteristics of the product.
- a combination of thickeners can be used.
- One preferred combination is the use of a sucrose polyester and a 12-hydroxystearic acid or its esters.
- the total amount of thickeners used is from about 0.1 % to about 60%.
- a thickener comprising a combination of from about 0.1 % to about 10% fatty alcohol and from about 0.1 % to about 50%, preferably up to about 30% of waxy compounds is used.
- from about 0.1 % to about 10% of gelling agents is used.
- a thickener comprising from about 0.1 % to about 10% inorganic thickeners is used.
- the fatty compound useful herein have a melting point of 25°C or higher, and is selected from the group consisting of fatty alcohols, fatty acids, fatty alcohol derivatives, fatty acid derivatives, and mixtures thereof. It is understood by the artisan that, depending on the number and position of double bonds, and length and position of the branches, certain compounds having certain required carbon atoms may have a melting point of less than 25°C.
- the fatty compounds useful as thickeners herein are only those having a melting point of 25°C or higher. It is understood that the fatty compound thickeners herein may also provide conditioning benefits.
- the fatty alcohols useful herein are those having from about 14 to about 30 carbon atoms, preferably from about 16 to about 22 carbon atoms. These fatty alcohols are saturated and can be straight or branched chain alcohols. Nonlimiting examples of fatty alcohols include, cetyl alcohol, stearyl alcohol, behenyl alcohol, and mixtures thereof.
- the fatty acids useful herein are those having from about 10 to about 30 carbon atoms, preferably from about 12 to about 22 carbon atoms, and more preferably from about 16 to about 22 carbon atoms. These fatty acids are saturated and can be straight or branched chain acids. Also included are diacids, triacids, and other multiple acids which meet the requirements herein. Also included herein are salts of these fatty acids. Nonlimiting examples of fatty, acids include lauric acid, palmitic acid, stearic acid, behenic acid, sebacic acid, and mixtures thereof. Fatty acid soaps are also useful herein. Nonlimiting examples of fatty acid soaps include natural soaps with Li, Na, Ca. Ba, and Al metals, including aluminium oleate and aluminium laurate.
- the fatty alcohol derivatives and fatty acid derivatives useful herein include alkyl ethers of fatty alcohols, alkoxylated fatty alcohols, alkyl ethers of alkoxylated fatty alcohols, esters of fatty alcohols, fatty acid esters of compounds having esterifiable hydroxy groups, hydroxy-substituted fatty acids, and mixtures thereof.
- Nonlimiting examples of fatty alcohol derivatives and fatty acid derivatives include materials such as methyl stearyl ether; the ceteth series of compounds such as ceteth-1 through ceteth-45, which are ethylene glycol ethers of cetyl alcohol, wherein the numeric designation indicates the number of ethylene glycol moieties present; the steareth series of compounds such as steareth-1 through 10, which are ethylene glycol ethers of steareth alcohol, wherein the numeric designation indicates the number of ethylene glycol moieties present; ceteareth 1 through ceteareth-10, which are the ethylene glycol ethers of ceteareth alcohol, i.e.
- myristyl myristate available from Croda with tradename Crodamol MM; cetyl alcohol, stearyl alcohol, and behenyl alcohol having tradenames KONOL series available from Shin Nihon Rika (Osaka, Japan), and NAA series available from NOF (Tokyo, Japan); pure behenyl alcohol having tradename 1-DOCOSANOL available from WAKO (Osaka, Japan), various fatty acids having tradenames NEO-FAT available from Akzo (Chicago Illinois, USA), HYSTRENE available from Witco
- Fatty compounds useful herein include fatty acid sugar esters having C-j.
- Fatty compounds useful herein include aluminium salt of phophatididic acid, steroid derivatives, cholesterol esters, and Na, Li, K, and NH4 salts of 12- hydroxyoctadecanoic acid.
- Waxy compounds are useful as thickeners of the present invention.
- Useful herein are petrolatum, which is a mixture of hydrocarbons obtained from petroleum and which is semisolid at room temperature, paraffin wax, microcrystalline wax, ozokerite wax, ceresin wax, carnauba wax, candellila wax, eicosanyl behenate, and mixtures thereof.
- Petrolatum is particularly preferred.
- Commercially available waxy compounds useful herein include petrolatum having a tradename Super White Protopet available from Witco, Candelilla wax NC- 1630 available from Noda wax, Ozokerite wax SP-1021 available from Strahl & Pitsh, and Eicosanyl behenate available from Cas Chemical.
- Gelling Agents are particularly preferred.
- the gelling agents useful as thickeners of the present invention include esters and amides of fatty acid gellants, hydroxy acids, hydroxy fatty acids, cholesterolic materials, lanolinolic materials, other amide gellants, and crystalline gellants.
- N-acyl amino acid amides useful herein are prepared from glutamic acid, lysine, glutamine, aspartic acid and mixtures thereof. Particularly preferred are n-acyl glutamic acid amides corresponding to the following formula: R 2 -NH-CO-(CH 2 ) 2 -CH-(NH-CO-R 1 )-CO-NH-R 2 wherein R 1 is an aliphatic hydrocarbon radical having from about 12 to about 22 carbon atoms, and R 2 is an aliphatic hydrocarbon radical having from about 4 to about 12 carbon atoms.
- Non-limiting examples of these include n-lauroyl-L- glutamic acid dibutyl amide, n-stearoyl-L-glutamic acid diheptyl amide, and mixtures thereof. Most preferred is n-lauroyl-L-glutamic acid dibutyl amide, also referred to as dibutyl lauroyl glutamide.
- This material is commercial available with tradename Gelling agent GP-1 available from Ajinomoto.
- Amidoamines of the following general formula are useful herein: R1 CONH (CH2)m N (R 2 )2 wherein Rl is a residue of C-
- Preferred amidoamine useful in the present invention includes stearamidopropyldimethylamine, stearamidopropyldiethylamine, stearamidoethyldiethylamine, stearamidoethyldimethylamine, palmitamidopropyldimethylamine, palmitamidopropyldiethylamine, palmitamidoethyldiethylamine, palmitamidoethyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldiethylamine, behenamidoethyldiethylamine, behenamidoethyldimethylamine, arachidamidopropyldimethylamine, arachidamidopropyldiethylamine, arachidamidoethyldiethylamine, arachidamidoethyldimethylamine, and mixtures thereof; more preferably stearamidopropy
- gelling agents suitable for use in the compositions include 12- hydroxystearic acid, esters of 12-hydroxystearic acid, amides of 12- hydroxystearic acid and combinations thereof.
- These preferred gellants include those which correspond to the following formula:
- R 1 is R 2 or NR 2 R 3
- R 2 and R 3 are hydrogen, or an alkyl, aryl, or arylalkyl radical which is branched linear or cyclic and has from about 1 to about 22 carbon atoms; preferably, from about 1 to about 18 carbon atoms.
- R 2 and R 3 may be either the same or different; however, at least one is preferably a hydrogen atom.
- Preferred among these gellants are those selected from the group consisting of 12-hydroxystearic acid, 12-hydroxystearic acid methyl ester, 12-hydroxystearic acid ethyl ester, 12-hydroxystearic acid stearyl ester, 12- hydroxystearic acid benzyl ester, 12-hydroxystearic acid amide, isopropyl amide of 12-hydroxystearic acid, butyl amide of 12-hydroxystearic acid, benzyl amide of 12-hydroxystearic acid, phenyl amide of 12-hydroxystearic acid, t-butyl amide of 12-hydroxystearic acid, cyclohexyl amide of 12-hydroxystearic acid, 1-adamantyl amide of 12-hydroxystearic acid, 2-adamantyl amide of 12-hydroxystearic acid, diisopropyl amide of 12-hydroxystearic acid, triester of glycerin and hydroxystearic acid known as trihydroxystearin, and mixtures thereof; even more preferably
- hydroxystearin compounds useful herein include 12-hydroxystearic acid (cosmetic grade) available from Kawaken and CasChem, and trihydroxystearin with tradenames Thixcin R available from Rheox, Flowtone R available from ECC America, and Rheocin available from United Catalysts.
- Suitable amide gellants include disubstituted or branched monoamide gellants, monosubstituted or branched diamide gellants, triamide gellants, and combinations thereof, excluding the n-acyl amino acid derivatives selected from the group consisting of n-acyl amino acid amides, n-acyl amino acid esters prepared from glutamic acid, lysine, glutamine, aspartic acid, and combinations thereof, and which are specifically disclosed in U.S. Patent 5,429,816.
- Alkyl amides or di- and tri-basic carboxylic acids or anhydrides suitable for use in the composition include alkyl amides of citric acid, tricarballylic acid, aconitic acid, nitrilotriacetic acid, succinic acid and itaconic acid such as 1 ,2,3- propane tributylamide, 2-hydroxy-1 ,2,3-propane tributylamide, 1-propene-1 ,2,3- triotylamide, N,N',N"-tri(acetodecylamide)amine, 2-dodecyl-N,N'- dihexylsuccinamide, and 2 dodecyl-N,N'-dibutylsuccinamide.
- alkyl amides of citric acid, tricarballylic acid, aconitic acid, nitrilotriacetic acid, succinic acid and itaconic acid such as 1 ,2,3- propane tributylamide
- alkyl amides of di-carboxylic acids such as di-amides of alkyl succinic acids, alkenyl succinic acids, alkyl succinic anhydrides and alkenyl succinic anhydrides, more preferably 2-dodecyl-N,N'-dibutylsuccinamide.
- gellants useful herein include anthryl derivaties such as 2,3-bis n- decyloxyanthracene, hybrids of steroids and anthryl dervatives such as cholesterol anthraquinone-2-carboxylate, alpha amino acid oligomers such as N- benzyl oxycarbonyl-l-valyl-L-valine-n-octadecyl amide, organometallics such as mononuclear copper beta-diketonates and binulclear Cu and Rh tetracarboxylates, dextrin derivaties such as dextrin palmitate and dextrin myristate, and decaglycerin pentastearic acid.
- anthryl derivaties such as 2,3-bis n- decyloxyanthracene, hybrids of steroids and anthryl dervatives such as cholesterol anthraquinone-2-carboxylate, alpha amino acid oligomers such as N-
- Inorganic thickeners useful herein include silica, oil soluble clays, and mixtures thereof. Highly dispersed, amorphous silicon dioxide of submicron particle size, also known as fumed silica, are particularly useful. Such material is commercially available as the Aerosil series (200, 300, 200CF, and 300CF) available from Degussa. Oil soluble polymers
- Oil soluble polymers are useful as thickeners of the present invention.
- Oil soluble polymers useful herein include guar gum which is a resinous material derived from the ground endosperm of cyanopsis tetragonoloba and close relatives. SENSATES
- the hair conditioning composition of the present invention may further contain a sensate.
- a sensate means a substance that, when applied to the skin, causes a perceived sensation of a change in conditions, for example, but not limited to, heating, cooling, refreshing and the like. Further, sensates may provide reduction of perceived oily and/or sticky feel during use.
- Sensates are preferably utilized at levels of from about 0.001 % to about 10%, more preferably from about 0.005% to about 5%, even more preferably from about 0.01 % to about 1 %, by weight, of the total compositions. Any sensate suitable for use in hair care compositions may be used herein. Preferred sensates for use in the compositions herein are camphor, menthol, l-isopulegol, ethyl menthane carboxamide and trimethyl isopropyl butanamide. ADDITIONAL COMPONENTS
- compositions can be formulated into the present compositions.
- additional components such as Salcare SC96 which is a mixture of Polyquaternium 37, propylene glycol dicaprylate dicaprate, and PPG-1 trideceth-6 commercially available from Ciba Specialty Chemicals, hydrolysed collagen with tradename Peptein 2000 available from Hormel, vitamin E with tradename Emix-d available from Eisai, panthenol available from Roche, panthenyl ethyl ether available from Roche, a mixture of Polysorbate 60 and Cetearyl Alcohol with tradename Polawax NF available from Croda Chemicals, glycerylmonostearate available from Stepan Chemicals, hydrolysed keratin, proteins, plant extracts, and nutrients; preservatives such as benzyl alcohol, methyl paraben, propyl paraben and imidazolidinyl urea; pH adjusting agents, such as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium citrate,
- the conditioning compositions of the present invention are for use to apply on dry hair prior to washing the hair with a shampoo. It has been surprisingly found that the conditioning compositions deliver conditioning benefit to the hair such as manageability and volume up to the hair when used in such way.
- the term "hair volume up” as used herein is not equal to fly-away hair. Fly-away hair is due to the increased level of static, and represents volume increase of only very minor amount of the hair as a whole, and is not desirable.
- hair volume up as used herein relates to increase of the bulk of the hair volume. Consumers having fine hair have the desire to achieve hair volume up while controlling undesirable fly-away of the hair. It has now been found that when applied to hair, a hair care composition as described herein may increase bulk hair volume, while reducing flyaway hair volume.
- a suitable method of using the present composition comprises the steps of;
- conditioning oils of the present invention are left on the hair.
- the conditioning oil left in or on the hair is believed to provide significantly better manageability and appearance benefits to the hair compared to when the hair is washed without pretreatment of the hair with the present composition.
- the shampoo composition to be used in step (b) can be any composition comprising detersive surfactants and is suitable for washing off soils from the hair.
- detersive surfactant as used herein, is intended to distinguish these surfactants from surfactants which are primarily emulsifying surfactants, i.e. surfactants which provide an emulsifying benefit and which have low cleansing performance. It is recognized that most surfactants have both detersive and emulsifying properties. It is not intended to exclude emulsifying surfactants from the present invention, provided the surfactant also possesses sufficient detersive properties to be useful herein.
- Detersive surfactants are typically selected from the group consisting of anionic surfactants, amphoteric surfactants, nonionic surfactants, and mixtures thereof.
- the detersive surfactants comprised in the shampoo composition may or may not be the same as those comprised in the present conditioning composition.
- at least an anionic surfactant is included in the shampoo composition to be used in step (b).
- the amount of the present composition used for treating the hair prior to shampooing depends on the volume of hair and desired conditioning benefits. Typically, from about 2ml to about 40ml, preferably from about 5ml to about 20ml of the present composition is used.
- the present invention does not necessarily preclude overall hair treatment regimens wherein additional rinse off and/or leave on conditioning formulations are applied to the hair subsequent to washing the hair, or subsequent to washing and drying the hair.
- Examples 1 through 8 are hair conditioning compositions of the present invention which are used by applying to the dry hair prior to shampooing the hair.
- Paraffin Oil A blend of iso- and cyclo-paraffins with a molecular weight of approximately 330 with tradename Carnation available from Witco
- compositions of Examples 1-8 as shown above can be prepared by any conventional method. A suitable method is described:
- paraffin oil is heated to above about 50°C, nonionic surfactants is added and stirred, and remaining conditioning oils are added. Preservatives and antioxidants, when present, can be premixed with one of the conditioning oils prior to mixing with other components. The remaining components except water and other heat sensitive components such as perfume and menthol are added. Finally, after the product has cooled down to about 35°C, if present, water, perfume, and menthol are added.
- Example 2 is prepared by heating the paraffin oil to about 75°C, adding the SEFA behenate, and following the same method as described above. Ethanol is added after the product has cooled down to 35°C.
- Example 3 is prepared by heating the paraffin oil to about 75°C, adding the 12-hydroxystearic acid and SEFA behenate, and following the same method as described above. The cooling of the composition from about 75°C to about 30 °C is conducted in about 10 minutes.
- Example 4 is prepared by heating the paraffin oil to about 160°C, adding Dibutyl Lauroyl Glutamide, and following the same method as described above.
- Example 5 is prepared by heating the paraffin oil to about 80°C, adding the trihydroxystearin, and following the same method as described above.
- Examples 1 through 8 can provide conditioning benefit such as increase of bulk hair volume; body fullness; ease of combing, managing and styling the hair; smooth, soft, and moisturized feel to the hair, and shine to the hair.
- Examples 2 through 5 further have a viscosity of from about 1 ,000 mPa»s to about 100,000 mPa»s, and have good spreadability on the hair.
- Examples 1 and 6 through 8 further have a viscosity of at least 100 mPa»s, and have a clear appearance.
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Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01912950A EP1313430A1 (en) | 2000-08-31 | 2001-02-23 | Pre-shampoo conditioning composition |
JP2002522839A JP2004518619A (en) | 2000-08-31 | 2001-02-23 | Conditioning composition before shampoo |
AU2001241677A AU2001241677A1 (en) | 2000-08-31 | 2001-02-23 | Pre-shampoo conditioning composition |
MXPA03001802A MXPA03001802A (en) | 2000-08-31 | 2001-02-23 | PRE-CHAMPU CONDITIONING COMPOSITION. |
US10/375,595 US20030157048A1 (en) | 2001-02-23 | 2003-02-27 | Pre-shampoo conditioning composition |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2000/024018 WO2002017864A1 (en) | 2000-08-31 | 2000-08-31 | Pre-shampoo conditioning composition |
USPCT/US00/24018 | 2000-08-31 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/375,595 Continuation US20030157048A1 (en) | 2001-02-23 | 2003-02-27 | Pre-shampoo conditioning composition |
Publications (1)
Publication Number | Publication Date |
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WO2002017865A1 true WO2002017865A1 (en) | 2002-03-07 |
Family
ID=21741732
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2000/024018 WO2002017864A1 (en) | 2000-08-31 | 2000-08-31 | Pre-shampoo conditioning composition |
PCT/US2001/005739 WO2002017865A1 (en) | 2000-08-31 | 2001-02-23 | Pre-shampoo conditioning composition |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2000/024018 WO2002017864A1 (en) | 2000-08-31 | 2000-08-31 | Pre-shampoo conditioning composition |
Country Status (6)
Country | Link |
---|---|
EP (2) | EP1313429A1 (en) |
JP (2) | JP2004517812A (en) |
CN (2) | CN1454073A (en) |
AU (2) | AU2000270997A1 (en) |
MX (2) | MXPA03001801A (en) |
WO (2) | WO2002017864A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008052956A1 (en) * | 2006-11-04 | 2008-05-08 | Unilever Plc | Make-up remover cosmetic compositions |
WO2009107062A2 (en) * | 2008-02-25 | 2009-09-03 | The Procter & Gamble Company | Hair care compositions comprising sucrose polyesters |
CN107106456A (en) * | 2014-10-03 | 2017-08-29 | 宝洁公司 | Using comprising pre-emulsification preparation personal care composition improve volume and can cardability method |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8318187B2 (en) | 2004-04-30 | 2012-11-27 | The Procter & Gamble Company | Long-wearing cosmetic compositions with improved shine |
US9308397B2 (en) * | 2004-04-30 | 2016-04-12 | The Procter & Gamble Company | Long-wearing cosmetic compositions |
WO2015136568A1 (en) | 2014-03-11 | 2015-09-17 | Doc Japan Co., Ltd. | Cosmetic conditioning oil composition and cosmetic product |
WO2015155046A1 (en) * | 2014-04-10 | 2015-10-15 | Unilever Plc | Method of treating damaged hair |
WO2015155047A1 (en) * | 2014-04-10 | 2015-10-15 | Unilever Plc | Method of shaping hair |
FR3022775B1 (en) * | 2014-06-30 | 2018-03-02 | L'oreal | ANHYDROUS COMPOSITION COMPRISING A LIPOPHILIC GELIFIER, AT LEAST TWO SEPARATE LOADS OF ANOTHER AND A FATTY PHASE |
CN108699491B (en) * | 2016-02-26 | 2020-12-29 | 赢创运营有限公司 | Amide of aliphatic polyamine and 12-hydroxyoctadecanoic acid and lipase-stabilized thickener composition |
US20180344597A1 (en) * | 2017-06-05 | 2018-12-06 | The Procter & Gamble Company | Pre-wash composition for clean benefit |
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WO2008052956A1 (en) * | 2006-11-04 | 2008-05-08 | Unilever Plc | Make-up remover cosmetic compositions |
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CN107106456A (en) * | 2014-10-03 | 2017-08-29 | 宝洁公司 | Using comprising pre-emulsification preparation personal care composition improve volume and can cardability method |
Also Published As
Publication number | Publication date |
---|---|
AU2000270997A1 (en) | 2002-03-13 |
CN1454073A (en) | 2003-11-05 |
MXPA03001802A (en) | 2003-06-04 |
MXPA03001801A (en) | 2003-06-04 |
CN1449275A (en) | 2003-10-15 |
AU2001241677A1 (en) | 2002-03-13 |
WO2002017864A1 (en) | 2002-03-07 |
JP2004518619A (en) | 2004-06-24 |
EP1313429A1 (en) | 2003-05-28 |
EP1313430A1 (en) | 2003-05-28 |
JP2004517812A (en) | 2004-06-17 |
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