JPH06100989A - Cr-ni stainless steel sheet free from working surface roughing and its production - Google Patents

Cr-ni stainless steel sheet free from working surface roughing and its production

Info

Publication number
JPH06100989A
JPH06100989A JP4248060A JP24806092A JPH06100989A JP H06100989 A JPH06100989 A JP H06100989A JP 4248060 A JP4248060 A JP 4248060A JP 24806092 A JP24806092 A JP 24806092A JP H06100989 A JPH06100989 A JP H06100989A
Authority
JP
Japan
Prior art keywords
rolling
steel sheet
drd
stainless steel
colonies
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP4248060A
Other languages
Japanese (ja)
Other versions
JP2677493B2 (en
Inventor
Takatsugu Shindou
卓嗣 進藤
Toshiyuki Suehiro
利行 末広
Masanori Ueda
全紀 上田
Shinichi Teraoka
慎一 寺岡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP4248060A priority Critical patent/JP2677493B2/en
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to ES93908107T priority patent/ES2118950T3/en
Priority to DE69320140T priority patent/DE69320140T2/en
Priority to PCT/JP1993/000497 priority patent/WO1993021355A1/en
Priority to EP93908107A priority patent/EP0594866B1/en
Priority to KR1019930703911A priority patent/KR960014516B1/en
Priority to US08/167,832 priority patent/US5376195A/en
Publication of JPH06100989A publication Critical patent/JPH06100989A/en
Application granted granted Critical
Publication of JP2677493B2 publication Critical patent/JP2677493B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Abstract

PURPOSE:To provide a Cr-Ni stainless steel sheet excellent in surface quality by providing a specific composition and allowing specific colonies to be present uniformly in a mixed state. CONSTITUTION:This stainless steel sheet has a structure wherein (C+N) is <=0.09mass% and Md30 defined by equation is 30-60 deg.C. Colonies A, in which the average sizes in a rolling direction and a sheet-width direction are dRD(A) and drD(A), respectively, and principal crystal orientation is {112}<111> and {113}<332>, and colonies B, in which the average sizes in rolling direction and sheet-width direction are dRD(B) and drD(B), respectively, and principal crystal orientation is {110}<111>, {110}<112>, and {110}<001>, are present uniformly in mixed state in the sheet thickness layer part plane parallel to sheet surface of this steel sheet. At this time, dRD(A) or dRD(B) is <=300mum, and drD(A) or drD(B) is <=200mum. By this method, the occurrence of working surface roughing by the manufacturing process by strip continuous casting method can be prevented.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、鋳型が鋳片と同期して
移動する、いわゆる同期式連続鋳造法によって製品厚さ
に近い厚さの鋳片を鋳造し、熱間圧延を経ずに直接冷間
圧延して製造する加工肌荒れのないCr−Ni系ステン
レス鋼薄板とその製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention casts a slab having a thickness close to the product thickness by a so-called synchronous continuous casting method in which a mold moves in synchronization with the slab, without hot rolling. The present invention relates to a Cr-Ni-based stainless steel thin plate which is directly cold-rolled and has no roughened surface and a manufacturing method thereof.

【0002】[0002]

【従来の技術】従来、連続鋳造法を用いてステンレス鋼
薄板を製造するには、鋳型を鋳造方向に振動させながら
厚さ100mm以上の鋳片に鋳造し、得られた鋳片の表面
手入れを行い、加熱炉において1000℃以上に加熱し
た後、粗圧延機および仕上げ圧延機からなるホットスト
リップミルによって熱間圧延を施し、厚さ数mmのホット
ストリップとしていた。
2. Description of the Related Art Conventionally, in order to produce a stainless steel thin plate by a continuous casting method, a casting having a thickness of 100 mm or more is cast while vibrating the casting mold in the casting direction, and the surface of the obtained casting is cleaned. After being heated to 1000 ° C. or higher in a heating furnace, hot rolling was performed by a hot strip mill consisting of a rough rolling mill and a finishing rolling mill to obtain a hot strip having a thickness of several mm.

【0003】こうして得られたホットストリップを冷間
圧延するに際しては、最終製品に要求される形状(平坦
さ)、材質、表面性状を確保するために、強い熱間加工
を受けたホットストリップを軟化させるための熱延板焼
鈍を行うとともに、表面のスケール等を酸洗工程の後に
研削によって除去していた。従来のプロセスにおいて
は、長大な熱間圧延設備で、材料の加熱および加工のた
めに多大なエネルギーを必要とし、生産性の点でも優れ
た製造プロセスとは言い難かった。また、最終製品は、
集合組織が達成し、ユーザーにおいてプレス加工等を加
えるときは、その異方性を考慮する必要となる等、使用
上の制約も多かった。
When the hot strip thus obtained is cold-rolled, the hot strip subjected to strong hot working is softened in order to secure the shape (flatness), material and surface texture required for the final product. The hot-rolled sheet was annealed for this purpose, and the scale on the surface was removed by grinding after the pickling step. In the conventional process, a huge hot rolling facility requires a large amount of energy for heating and processing the material, and it is difficult to say that the manufacturing process is excellent in terms of productivity. Also, the final product is
There were many restrictions in use, such as the need to consider the anisotropy when a texture was achieved and the user added press work or the like.

【0004】そこで、100mm以上の厚さの鋳片をホッ
トストリップに圧延するために、長大な熱間圧延設備と
多大なエネルギーや圧延動力を必要とするという問題を
解決すべく、最近、連続鋳造の過程でホットストリップ
と同等か、あるいはそれに近い厚さの鋳片(薄帯)を得
るプロセスの研究が進められている。例えば、「鉄と
鋼」′85,A197〜A256や「CAMP ISI
J」vol.1,1988,1670〜1705におい
て特集された論文に、ホットストリップを連続鋳造によ
って直接的に得るプロセスが開示されている。
Therefore, in order to solve the problem that a long hot rolling facility and a large amount of energy and rolling power are required to roll a slab having a thickness of 100 mm or more into a hot strip, recently, continuous casting has been performed. In the process of (1), research on a process for obtaining a slab (thin band) having a thickness equal to or close to that of hot strip is underway. For example, "Iron and Steel"'85, A197 to A256 and "CAMP ISI".
J "vol. 1, 1988, 1670-1705, the process of obtaining hot strip directly by continuous casting is disclosed.

【0005】このような連続鋳造プロセスにあっては、
得ようとする鋳片(ストリップ)のゲージが1〜10mm
の水準であるときはツインドラム方式が、また鋳片のゲ
ージが20〜50mmの水準であるときは、ツインベルト
方式が検討されている。
In such a continuous casting process,
The gauge of the slab (strip) to be obtained is 1 to 10 mm
The twin-drum system is under consideration when the gauge is 20 to 50 mm, and the twin-belt system is examined when the gauge of the slab is 20 to 50 mm.

【0006】[0006]

【発明が解決しようとする課題】この種の方式の連続鋳
造プロセスにおいては、最終形状に近い鋳片を製造し、
熱延工程、熱処理工程等の中間段階を省略または軽減し
ている。そのため、鋳片の組織が製品の材質や表面性状
に大きな影響を与えることが知られている。本発明者ら
が、ストリップ連鋳によるCr−Ni系ステンレス鋼板
製造プロセスによって製造した薄板のプレス成形性を詳
細に研究した結果、以下に具体的に示すように加工肌荒
れと称される表面欠陥が発生することが判明した。
In the continuous casting process of this type, a slab close to the final shape is produced,
Intermediate steps such as hot rolling process and heat treatment process are omitted or reduced. Therefore, it is known that the structure of the slab has a great influence on the material and surface properties of the product. As a result of detailed study of the press formability of a thin plate manufactured by the Cr-Ni-based stainless steel plate manufacturing process by continuous strip casting, the present inventors have found that surface defects called roughening of the processed surface are concretely shown below. It turned out to occur.

【0007】加工肌荒れはCr−Ni系薄板に、2軸応
力負荷状態の張出し成形加工を行うと顕著に発生し、鋼
板表面に圧延方向に平行な起伏や圧延方向と一定の角度
をなす畝筋状の表面欠陥である。この欠陥の最大うねり
高さは、プレス加工度が高い場合は2〜6μmに達し、
従来の連続鋳造/熱間圧延/冷間圧延プロセス(以下
「従来法」と略称する)によって製造される薄板にはみ
られない重大な欠陥である。
The roughened surface is remarkably generated when the Cr-Ni type thin plate is subjected to the bulging process under the biaxial stress load, and the undulations parallel to the rolling direction on the surface of the steel plate and the ribs forming a certain angle with the rolling direction. Surface defects. The maximum waviness height of this defect reaches 2 to 6 μm when the pressing degree is high,
This is a serious defect that cannot be found in the thin plate produced by the conventional continuous casting / hot rolling / cold rolling process (hereinafter abbreviated as “conventional method”).

【0008】加工肌荒れは加工用途のストリップ連鋳薄
板製品の商品価値を、著しく損なうものであり、これを
防止する技術が必要とされていた。本発明は加工肌荒れ
が発生しない表面品質の優れたCr−Ni系ストリップ
連鋳ステンレス鋼薄板、およびその製造方法を提供する
ことを目的とする。
[0008] The roughened surface is a material that significantly impairs the commercial value of strip continuously cast thin plate products for processing applications, and a technique for preventing this has been required. It is an object of the present invention to provide a Cr—Ni-based strip continuously cast stainless steel thin plate having excellent surface quality that does not cause roughened work surface, and a method for manufacturing the same.

【0009】[0009]

【課題を解決するための手段】本発明は、まず下記のC
r−Ni系ステンレス鋼板をその要旨とする。すなわち
C+Nが0.090mass%以下でかつ、Md30=4
13−462(C+N)−9.2Si−8.1Mn−1
3.7Cr−18.5Mo−9.5(Ni+Cu)(各
成分はmass%)で定義されるMd30が30〜60℃
となる組成を有し、しかも鋼板の板面に平行な任意の板
厚層部位面において、圧延方向の平均寸法がdRD(A)
であり板幅方向の平均寸法がdTD(A)である主たる結
晶方位が{112}<111>,{113}<332>
から成るコロニーAと、圧延方向の平均寸法がd
RD(B)であり板幅方向の平均寸法がdTD(B)である
主たる結晶方位が{110}<111>,{110}<
112>,{110}<001>からなるコロニーBの
両者が、鋼板中に互いに均一に混じりあって存在し、か
つdRD(A)又はdRD(B)がそれぞれ300μm以下
であり、dTD(A)又はdTD(B)がそれぞれ200μ
m以下であるCr−Ni系ステンレス鋼板を特徴とす
る。
The present invention firstly comprises the following C
The gist is an r-Ni-based stainless steel plate. That is, C + N is 0.090 mass% or less and Md 30 = 4
13-462 (C + N) -9.2Si-8.1Mn-1
3.7Cr-18.5Mo-9.5 (Ni + Cu) (each component is mass%) has an Md 30 of 30 to 60 ° C.
And the average dimension in the rolling direction is d RD (A) on the surface of any plate thickness layer parallel to the plate surface of the steel plate.
And the main crystal orientations whose average dimension in the plate width direction is d TD (A) are {112} <111>, {113} <332>.
Colony A consisting of and the average size in the rolling direction is d
RD (B) and the average dimension in the plate width direction is d TD (B), the main crystal orientations are {110} <111>, {110} <
Both colonies B consisting of 112>, {110} <001> are present in the steel sheet with each other uniformly mixed, and d RD (A) or d RD (B) are each 300 μm or less, and d TD (A) or d TD (B) is 200μ
A Cr-Ni-based stainless steel plate having a thickness of m or less is featured.

【0010】上記本発明のCr−Ni系ステンレス鋼板
は、溶鋼を鋳型側面が鋳片と同期して移動する連続鋳造
機によって、100℃/sec以上の凝固冷却速度で厚
さ10mm以下の薄帯状鋳片に鋳造し、凝固後は可及的高
温から1200℃までを50℃/sec以上の冷却速度
で冷却し、次いで冷間圧延、最終焼鈍を行う製造方法に
よって提供される。この場合の冷間圧延は、加工率30
%以上の冷間圧延を施し、次いで1000〜1200℃
の温度で中間焼鈍を加えた後に最終板厚まで冷間圧延す
る、いわゆる2回圧延法によってなされてもよい。
The Cr-Ni type stainless steel sheet of the present invention is a thin strip having a thickness of 10 mm or less at a solidification cooling rate of 100 ° C./sec or more by a continuous casting machine in which the side surface of the mold moves in synchronization with the slab of molten steel. It is provided by a manufacturing method of casting into a slab, cooling from the highest possible temperature to 1200 ° C. at a cooling rate of 50 ° C./sec or more after solidification, and then performing cold rolling and final annealing. The cold rolling in this case has a working rate of 30.
% Or more cold rolling, then 1000-1200 ° C
It may be carried out by a so-called double rolling method, in which an intermediate annealing is applied at the temperature of and then cold rolling is performed to a final plate thickness.

【0011】Md30は、一般的に用いられているとお
り、30%の冷間加工を施したときに、組織の50%以
上がマルテンサイトになる温度である。以下、本発明を
詳細に説明する。本発明者らは、SUS304鋼に相当
するCr−Ni系ステンレス鋼ストリップ連鋳片の平均
γ粒径と製品材の加工肌荒れ高さとの関係を調べた。す
なわち表1に示すMd30点が異なる数種類の組成の鋼を
用いて、それぞれについて平均γ粒径を変動させた2.
3mm厚連鋳片を製造した。これらを0.6mm厚まで冷間
圧延し、その後光輝焼鈍(1190℃,20秒保定)と
調質圧延を加えた後、円筒平底張出し加工(ポンチ径5
0mm,張出し高さ10mm)を行ない平底部の加工肌荒れ
高さを測定した。
As is generally used, Md 30 is the temperature at which 50% or more of the structure becomes martensite when cold working is performed at 30%. Hereinafter, the present invention will be described in detail. The present inventors investigated the relationship between the average γ grain size of a Cr—Ni-based stainless steel strip continuous cast piece corresponding to SUS304 steel and the height of roughened surface of worked product material. That is, using steels having several compositions having different Md 30 points shown in Table 1, the average γ grain size was varied for each of them.
A 3 mm thick continuous cast piece was manufactured. These were cold-rolled to a thickness of 0.6 mm, then bright-annealed (1190 ° C, held for 20 seconds) and temper-rolled, and then subjected to cylindrical flat bottom overhanging (punching diameter 5
(0 mm, overhang height 10 mm) was performed to measure the height of roughened surface of the flat bottom.

【0012】[0012]

【表1】 [Table 1]

【0013】図1はその結果をまとめたものである。す
なわち、(1)Md30点が一定値を示す同一組成材の場
合は、鋳片の平均γ粒径が粗大なほど製品の加工肌荒れ
高さが増大する、(2)Md30点が高いと加工肌荒れ高
さが低下する、ことを第一に知見した。
FIG. 1 summarizes the results. That is, (1) in the case of the same composition material in which the Md 30 point shows a constant value, the coarser the average γ grain size of the cast piece, the higher the processed surface roughness of the product, and (2) the higher the Md 30 point, The first finding was that the height of roughened skin was reduced.

【0014】また図2に、Md30点が30.2℃の材料
における加工肌荒れ高さと平均うねり幅および平均うね
り長さとの関係を調べた結果を示す。うねり幅が約20
0μm(凝固平均γ粒径:100μm)以上になるとう
ねり幅に比例して肌荒れ高さが直線的に増大すること、
またうねり長さと肌荒れ高さについても同様の関係があ
ることを解明した。
Further, FIG. 2 shows the results of examining the relationship between the height of roughened work surface and the average waviness width and average waviness length in a material having an Md 30 point of 30.2 ° C. The swell width is about 20
When it becomes 0 μm (solidification average γ particle size: 100 μm) or more, the rough skin height increases linearly in proportion to the waviness width,
It was also clarified that there is a similar relationship between the length of undulation and the height of rough skin.

【0015】加工によって発生するこの種の畝筋状の表
面欠陥は、α系ステンレス鋼におけるリジング現象の例
で知られるように、鋼板中に集合組織が顕著に発達し
て、数種類の「特定の結晶方位からなる結晶粒の集団
(以下コロニーと称する)」を形成し、それらの塑性異
方性によって生ずる場合が多い。本発明者らはCr−N
i系ステンレス鋼ストリップ連鋳工程材、すなわちスト
リップ鋳片、冷延材、焼鈍材、製品材(調質圧延ま
ま)、2軸張り出しプレス加工材の集合組織、金属組
織、成分偏析等を詳細に調べ、加工肌荒れの生成原因を
以下に記すごとく解明した。
The ridge-like surface defects of this kind generated by working, as is known in the example of the ridging phenomenon in α-stainless steel, have a texture developed remarkably in the steel sheet, and several kinds of "specific In many cases, it is caused by the plastic anisotropy, which forms a group of crystal grains composed of crystal orientations (hereinafter referred to as a colony). We have Cr-N
i-type stainless steel strip continuous casting process material, that is, strip slab, cold rolled material, annealed material, product material (as-tempered rolled), detailed texture, metallographic structure, component segregation, etc. The cause of generation of the roughened surface was investigated and clarified as described below.

【0016】すなわち、製品加工肌荒れ高さが2.8μ
mとなったMd30点が27.3℃の組成からなる、平均
γ粒径が粗大な(約130μm)Cr−Ni系ストリッ
プ連鋳片をその例として以下に説明する。図3にこの材
料の製品の1/4板厚層部の結晶方位分布(ODF)解
析結果を示す。ψ2 =0°(図(A))およびψ2 =4
5°(図(B))断面からわかるように、方位密度3.
8の(A){112}<111>と、方位密度3.5の
(B){110}<111>が主要な方位であり、これ
らがほぼ等量づつ存在する(厳密には(A)方位は{1
12}<111>とほぼ同量の{113}<332>も
含んでいる)。また加工肌荒れが許容限度内(1.5μ
m以下)となる従来法プロセス製品板のODF解析を行
ったところ、(A){112}<111>の方位密度は
5.5,(B){110}<111>の方位密度は2.
2であった。すなわち加工肌荒れが発生する場合は、
(B){110}<111>方位の方位密度が相対的に
強まることを知見した。
That is, the roughness of the processed surface of the product is 2.8μ.
As an example, a Cr-Ni-based strip continuous cast piece having a coarse mean γ grain size (about 130 μm) and having a composition in which the Md 30 point of m is 27.3 ° C. will be described below. FIG. 3 shows the crystal orientation distribution (ODF) analysis results of the 1/4 plate thickness layer portion of the product of this material. ψ 2 = 0 ° (Fig. (A)) and ψ 2 = 4
As can be seen from the 5 ° (FIG. (B)) cross section, the orientation density is 3.
(A) {112} <111> of 8 and (B) {110} <111> of azimuth density of 3.5 are major azimuths, and these are present in approximately equal amounts (strictly speaking, (A)). Azimuth is {1
12} <111> and {113} <332> in almost the same amount). Also, the roughened surface is within the allowable limit (1.5μ
When the ODF analysis of the conventional process product plate of (m or less) is performed, the orientation density of (A) {112} <111> is 5.5, and the orientation density of (B) {110} <111> is 2.
It was 2. That is, if roughened skin occurs,
(B) It has been found that the orientation density of {110} <111> orientation is relatively increased.

【0017】次に本発明者らは高輝度単色光(放射光)
細束X線法によって、上記の加工肌荒れの著しい製品の
肌荒れ畝状起伏ピッチに相当する隣接する十数カ所の
0.5mmX1.0mmの局所領域について、透過法による
(110)極点図を測定した。その結果、主として
(A){112}<111>方位粒からなるコロニーと
主として(B){110}<111>,{110}<1
12>,{110}<001>方位粒からなるコロニー
が、それぞれ隣接する別の場所に明かに偏在しているこ
とを解明した。
Next, the present inventors have developed a high-intensity monochromatic light (radiant light).
The (110) pole figure by the transmission method was measured by the fine-bundle X-ray method for 0.5 mm × 1.0 mm local regions at a dozen or more adjacent places corresponding to the rough ridge-like undulation pitch of the above-mentioned product with remarkable rough texture. As a result, colonies mainly composed of (A) {112} <111> oriented grains and mainly (B) {110} <111>, {110} <1
It was clarified that colonies composed of 12>, {110} <001> oriented grains are clearly unevenly distributed in different locations adjacent to each other.

【0018】またこのとき(A)及び(B)方位コロニ
ーの金属組織観察を行ったが、両者に組織的な差異はな
かった。また従来法による製品板について同様の測定を
行ったが、特定方位コロニーの偏在は見られず、(A)
及び(B)方位コロニーは均一に分散していることを確
認した。さらにこのとき(A)及び(B)方位コロニー
の観察された試料面の金属組織観察を行ったが、(A)
及び(B)方位コロニーに組織的な差異はなかった。次
いで二次元元素マッピングの可能なEPMA装置によ
り、これらの領域のNi,Crなどの成分偏析を調べた
が有意の差は認められなかった。以上の結果から、加工
肌荒れは結晶方位に起因する現象であることがわかる。
At this time, the metal structures of the (A) and (B) oriented colonies were observed, but there was no structural difference between them. In addition, the same measurement was performed on the product plate by the conventional method, but uneven distribution of colonies with a specific orientation was not observed, and (A)
It was confirmed that the (B) -oriented colonies were uniformly dispersed. Further, at this time, the metallographic observation of the sample surface where the (A) and (B) orientation colonies were observed was performed.
And (B) orientation colonies showed no systematic differences. Next, the segregation of components such as Ni and Cr in these regions was examined with an EPMA device capable of two-dimensional element mapping, but no significant difference was observed. From the above results, it is understood that the roughened surface is a phenomenon caused by the crystal orientation.

【0019】面心立方晶系に属するγ系ステンレス鋼の
{112}方位と{110}方位をそれぞれ結晶面の法
線方向と平行に1軸圧縮変形(等2軸張り出し変形と等
価であると仮定することができる)すると、結晶塑性学
的には{112}方位粒は{110}方位粒の約84%
の降伏強度を示すと予想される。材料中に(A){11
2}<111>,{113}<332>方位粒と(B)
{110}<111>,{110}<112>,{11
0}<001>方位粒がコロニーを形成し、粗大な領域
寸法ピッチで不均一に存在する場合はそれらの塑性異方
性によって加工時に肌荒れ畝条起伏が起こると考えられ
る。
The {112} and {110} orientations of γ-stainless steel belonging to the face-centered cubic system are uniaxially compressed in parallel to the normal direction of the crystal planes (equivalent to equal biaxial overhanging deformation). It can be assumed) that crystallographically, {112} oriented grains are about 84% of {110} oriented grains.
It is expected to show a yield strength of. In the material (A) {11
2} <111>, {113} <332> oriented grains and (B)
{110} <111>, {110} <112>, {11
When 0} <001> oriented grains form colonies and are nonuniformly present at a coarse region size pitch, it is considered that rough plastic ridges and ridges occur during processing due to their plastic anisotropy.

【0020】この観点から本発明者らは、コロニーの製
品板面における詳細な分布状態を解明するために、結晶
方位トポグラフX線解析装置(ビーム径が50μmのX
線を2次元的移動機能付き回転試料台上の試料に照射し
て、エネルギー分散型検出器により113回折線と22
0回折線の反射積分強度を同時測定し位置別方位分布を
マッピングする装置)によって10mmx10mmの寸法領
域の{113}〜{112}方位コロニーと{110}
方位コロニーの分布状態とそれぞれの平均寸法を解析し
た。このときランダム方位を示す標準試料の反射強度を
1.0として、方位別のX線強度レベルの板面位置との
対応を模式図的に示すと図4のようになる。
From this point of view, the present inventors have investigated a crystal orientation topographic X-ray analyzer (X-ray having a beam diameter of 50 μm) in order to clarify the detailed distribution state of the colonies on the product plate surface.
The sample is placed on a rotating sample table with a two-dimensional moving function, and 113 diffracted lines and 22
A device that simultaneously measures the integrated reflection intensity of 0 diffraction line and maps the orientation distribution according to position) with {113} to {112} orientation colonies and {110} in a size area of 10 mm x 10 mm.
The distribution of orientation colonies and the average size of each were analyzed. At this time, assuming that the reflection intensity of the standard sample showing a random azimuth is 1.0, the correspondence with the plate surface position of the X-ray intensity level for each azimuth is schematically shown in FIG.

【0021】このとき220反射強度と113反射強度
は交互に変動するが、例えば220反射強度が優勢なら
ば(B)方位コロニーとし113反射強度が優勢ならば
A方位コロニーとした。また220反射強度と113反
射強度の交差する位置を(A)及び(B)方位コロニー
の境界位置と定義した。この定義により測定したコロニ
ーA及びBの圧延方向の平均寸法をそれぞれdRD(A)
及びdRD(B)とし、板幅方向の平均寸法をそれぞれd
TD(A)及びdTD(B)とすると、これらの値と加工肌
荒れ高さの関係を求めると図5のようになった。すなわ
ちdRD(A)及びdRD(B)はいずれも300μm以下
であり、またdTD(A)及びdTD(B)がいずれも20
0μm以下である場合に加工肌荒れ高さが許容限度
(1.5μm)以下になる。
At this time, the 220 reflection intensity and the 113 reflection intensity change alternately. For example, if the 220 reflection intensity is dominant, the (B) direction colony is set, and if the 113 reflection intensity is dominant, the A direction colony is set. Further, the position where the 220 reflection intensity and the 113 reflection intensity intersect each other was defined as the boundary position of the (A) and (B) oriented colonies. The average dimensions in the rolling direction of colonies A and B measured by this definition are respectively d RD (A)
And d RD (B), the average size in the width direction is d
Assuming TD (A) and d TD (B), the relationship between these values and the roughened surface height of the processed surface is obtained as shown in FIG. That is, both d RD (A) and d RD (B) are 300 μm or less, and both d TD (A) and d TD (B) are 20
When it is 0 μm or less, the roughened surface height becomes less than the allowable limit (1.5 μm).

【0022】このようにコロニーAとBがある臨界値以
下の寸法で互いに均一に存在すると、加工肌荒れは発生
しないことを知見した。以上の結果は鋼板の板面に平行
な任意の板厚層部位においてもほぼ同様の傾向であっ
た。以下、本発明鋼の成分の効果について説明する。本
発明鋼は、C+Nが0.09mass%以下でかつ、M
30=413−462(C+N)−9.2Si−8.1
Mn−13.7Cr−18.5Mo−9.5(Ni+C
u)(各成分はmass%)で定義されるMd30が30
〜60℃となる組成を有するCr−Ni系ステンレス鋼
である。
As described above, it was found that when the colonies A and B uniformly exist with a size less than a certain critical value, the roughened surface does not occur. The above results showed almost the same tendency at any plate thickness layer portion parallel to the plate surface of the steel plate. The effects of the components of the steel of the present invention will be described below. The steel of the present invention has C + N of 0.09 mass% or less and M
d 30 = 413-462 (C + N ) -9.2Si-8.1
Mn-13.7Cr-18.5Mo-9.5 (Ni + C
u) (each component is mass%) has an Md 30 of 30
It is a Cr-Ni-based stainless steel having a composition of about 60 ° C.

【0023】C+Nは、本発明鋼の製品薄板のプレス加
工に伴う時効割れを助長するため、0.09mass%
以下とする。またMd30と鋳片の平均γ粒径および加工
肌荒れ高さの関係は図1において示したごとくである
が、このような関係が見られる理由を集合組織的に検討
した結果を以下に述べる。
C + N promotes aging cracking accompanying the press working of the product thin plate of the present invention steel, so 0.09 mass%
Below. The relationship between Md 30 and the average γ grain size of the slab and the height of roughened work surface is as shown in FIG. 1, and the reason why such a relationship is observed is summarized below.

【0024】本発明における急冷鋳片の集合組織は{1
10}<uv0>となる。すなわち板面法線と<001
>軸が平行で、γ相の結晶粒はこの軸回りに種々の方向
を向いて回転している。Md30点が30℃以下となる低
Md30材の急冷鋳片を冷延すると、特に鋳片の平均γ粒
径が約100μmを上回るような粗大粒組織である場
合、冷延中の不均一変形が助長される。また加工誘起マ
ルテンサイトの発生量も比較的少ないので、それらが組
織的にも不均一な場所に生成する。このときに生成する
マルテンサイト相はBCC結晶構造を示すので、圧延に
よってこの相はいわゆるα鉄の圧延集合組織を示し、
{113}<011>αや{332}<113>αが主
方位となる。一方、γ母相の圧延集合組織の主方位は
{110}<112>になる。冷延後、焼鈍を行うと前
述のマルテンサイトはγ母相に逆変態する。その際に、
α鉄の圧延方位はK−S方位関係によって、γ相方位
{110}<001>,{110}<112>,{11
0}<111>に変態する。またγ相の圧延方位である
{110}<112>バンド組織の近傍からは、高温域
焼鈍の粒成長方位である{112}<111>や{11
3}<332>が生成する。鋳片の平均γ粒径が粗大な
場合は、冷延時の変形の不均一性が冷延方位の局在化に
反映され、それらがそのまま焼鈍集合組織に影響を及ぼ
す。その結果、{112}方位コロニーと{110}方
位コロニーを形成すると考えられる。
The texture of the quenched slab in the present invention is {1
10} <uv0>. That is, the plate surface normal and <001
The> axis is parallel, and the γ-phase crystal grains are rotating around this axis in various directions. When a rapidly cooled slab of a low Md 30 material having an Md 30 point of 30 ° C. or less is cold-rolled, especially when the slab has a coarse grain structure such that the average γ grain size exceeds about 100 μm, unevenness during cold rolling is observed. Deformation is promoted. Further, since the amount of processing-induced martensite generated is relatively small, they are generated in a structurally non-uniform place. Since the martensite phase generated at this time has a BCC crystal structure, this phase shows a so-called α-iron rolling texture by rolling,
The main orientation is {113} <011> α or {332} <113> α. On the other hand, the main orientation of the rolling texture of the γ matrix is {110} <112>. When annealed after cold rolling, the above-mentioned martensite undergoes reverse transformation into a γ matrix. At that time,
The rolling orientation of α iron depends on the K-S orientation relationship, and the γ phase orientations {110} <001>, {110} <112>, {11
0} <111>. Further, from the vicinity of the {110} <112> band structure, which is the rolling direction of the γ phase, {112} <111> or {11} which is the grain growth direction of high temperature annealing.
3} <332> is generated. When the average γ grain size of the slab is coarse, the non-uniformity of deformation during cold rolling is reflected in the localization of cold rolling orientation, which directly affects the annealing texture. As a result, it is considered that {112} oriented colonies and {110} oriented colonies are formed.

【0025】これに対して、同じ低Md30材であっても
鋳片の平均γ粒径が約100μmを下回るような細粒組
織を示す場合には、冷延時の変形が均一になる。このよ
うな均一変形が支配的になる場合には、冷延及び焼鈍初
期のマルテンサイトやγ相の集合組織形成挙動は粗大γ
粒の場合とほぼ同様であるとすると、{112}粒の近
傍にマルテンサイトがγに逆変態して生成する{11
0}粒が存在する頻度が高まり、{112}粒が{11
0}粒を喰って成長し易くなる。その結果、{110}
方位コロニーの発達が抑制されて、比較的{112}方
位の発達した均一組織が形成される。従って、この場合
の加工肌荒れは小さいものになる。
On the other hand, even if the same low Md 30 material has a fine grain structure such that the average γ grain size of the slab is less than about 100 μm, the deformation during cold rolling becomes uniform. When such uniform deformation becomes dominant, the texture formation behavior of martensite and γ phase in the early stages of cold rolling and annealing is coarse γ.
If it is almost the same as in the case of grains, martensite is transformed into γ in the vicinity of {112} grains and is generated {11
The frequency of existence of 0} grains increases, and {112} grains become {11
0} grains are eaten and growth is facilitated. As a result, {110}
The development of oriented colonies is suppressed, and a uniform tissue with a relatively developed {112} orientation is formed. Therefore, the roughness of the processed surface in this case is small.

【0026】Md30が約30℃以上となる組成の急冷鋳
片を冷延すると、低Md30点材にくらべて、冷延時のマ
ルテンサイト生成量が増大し冷延組織の全面に均一にマ
ルテンサイト相が生成し易くなる。その結果、焼鈍後の
集合組織は比較的多くの{110}方位が発達するが、
{112}と{110}方位が偏在するようなコロニー
の発達は抑制される。特に鋳片の平均γ粒径が確実に1
00μmを下回る場合には、上記の効果が有効に働いて
加工肌荒れも非常に小さくなる。
When a rapidly-quenched slab having a composition of Md 30 of about 30 ° C. or more is cold-rolled, the amount of martensite produced during cold-rolling is increased as compared with a low-Md 30- point material, and the martensite is uniformly spread over the entire surface of the cold-rolled structure. Site phase is easily generated. As a result, the texture after annealing develops a relatively large number of {110} orientations,
The development of colonies in which the {112} and {110} orientations are unevenly distributed is suppressed. Especially, the average γ grain size of the cast piece is surely 1
When it is less than 00 μm, the above-mentioned effect works effectively, and the roughened surface becomes very small.

【0027】Md30をさらに約60℃にまで上げると、
この効果はさらに有効になって、鋳片の平均γ粒径が1
50μm程度に粗大である場合でも、加工肌荒れを極め
て小さくすることができる。しかしMd30を60℃以上
にまで過剰に増大させると、製品薄板の冷間加工性を低
下させるので、これを60℃以下に制限する必要があ
る。
When Md 30 is further raised to about 60 ° C.,
This effect becomes more effective, and the average γ grain size of the slab is 1
Even if the surface roughness is as large as about 50 μm, the roughened surface can be extremely reduced. However, if Md 30 is excessively increased to 60 ° C. or more, the cold workability of the product sheet is deteriorated, so it is necessary to limit this to 60 ° C. or less.

【0028】以上詳述したように、本発明においては製
品加工肌荒れを防止するために、組成に基づくMd30
を30〜60℃の範囲に調整し、急冷ストリップ鋳片の
平均γ粒径を150μm以下に、望ましくは100μm
以下に制御することが必要である。本発明者らは、スト
リップ鋳片の凝固冷却速度、凝固後から1200℃まで
の冷却速度とストリップ鋳片の平均γ粒径の関係を種々
検討した。その結果、前記の組成からなる厚さ10mm以
下のCr−Ni系ステンレス鋼のストリップ鋳片の凝固
冷却速度を100℃/sec以上とし、凝固後は可及的
高温から1200℃までを50℃/sec以上の冷却速
度で冷却すると、得られる鋳片の平均γ粒径が100μ
m以下になることを知見した。
As described in detail above, in the present invention, in order to prevent roughening of the product processed surface, the Md 30 point based on the composition is adjusted within the range of 30 to 60 ° C., and the average γ grain size of the quenched strip slab is adjusted. 150 μm or less, preferably 100 μm
It is necessary to control the following. The present inventors have made various studies on the relationship between the solidification cooling rate of strip slabs, the cooling rate from solidification to 1200 ° C., and the average γ grain size of strip slabs. As a result, the solidification cooling rate of the strip slab of Cr-Ni-based stainless steel having the above composition and having a thickness of 10 mm or less was set to 100 ° C / sec or more, and after solidification, 50 ° C / sec from the highest possible temperature to 1200 ° C. When cooled at a cooling rate of sec or more, the average γ grain size of the obtained cast piece is 100μ.
It was found that it would be less than m.

【0029】このようにして製造したストリップ鋳片
は、冷却後常法どおり冷間圧延および最終焼鈍を行う。
最終焼鈍後、必要に応じて常法どおりの調質圧延を行
う。また冷間圧延は鋳片板厚から最終製品板厚に近い板
厚になるまで、1回の冷間圧延工程(いわゆる1回冷延
法)によってなされても良いし、以下に述べるいわゆる
2回圧延法によってなされても良い。すなわち後者は、
冷間圧延をまず加工率30%以上施し、次いで1000
〜1200℃の温度で中間焼鈍を加えた後に最終板厚ま
で冷間圧延を行う。30%以上の冷間加工を施す理由
は、加工率が30%未満の場合は中間焼鈍後の再結晶組
織が粗大になって、最終製品に加工肌荒れの原因となる
コロニーが残存するために望ましくないためである。中
間焼鈍温度は、粒成長によって方位分布の均一化が進行
し始める温度1000℃から粒粗大化が顕著になって製
品にコロニーが残存する下限の温度1200℃の範囲で
行う必要がある。
After being cooled, the strip slab thus produced is subjected to cold rolling and final annealing in the usual manner.
After the final annealing, temper rolling according to a conventional method is performed as necessary. The cold rolling may be performed by one cold rolling step (so-called one-time cold rolling method) from the thickness of the cast slab to the thickness of the final product, or the so-called two times. It may be made by a rolling method. That is, the latter is
Cold rolling is first applied at a working rate of 30% or more, then 1000
After the intermediate annealing is applied at a temperature of up to 1200 ° C, cold rolling is performed to the final plate thickness. The reason for performing cold working of 30% or more is desirable because when the working ratio is less than 30%, the recrystallized structure after the intermediate annealing becomes coarse and colonies that cause roughened work remain in the final product. Because there is no. The intermediate annealing temperature needs to be set within a range from a temperature of 1000 ° C. at which the orientation distribution becomes uniform due to grain growth to a lower limit temperature of 1200 ° C. at which grain coarsening becomes remarkable and colonies remain in the product.

【0030】[0030]

【実施例】【Example】

実施例1 表2に示す組成に基づくMd30を5水準に変えたCr−
Ni系ステンレス鋼(SUS304鋼)を、双ロール式
連続鋳造機によっておよそ300℃/secの凝固冷却
速度で厚さ2.5mmの薄帯状鋳片に鋳造し、凝固後は1
400℃から1200℃までを20〜500℃/sec
の冷却速度で冷却して種々のγ粒径を有する鋳片を得
た。その後、酸洗、冷間圧延(合計圧延率76%)およ
び最終焼鈍を行い調質圧延を加えて薄板製品を製造し
た。その後結晶方位トポグラフ解析装置によって製品の
1/4板厚層部における板面のコロニー寸法を計測し
た。また製品の円筒平底張出し加工(ポンチ径50mm、
張出し高さ10mm)を行い、平底部の加工肌荒れ高さを
測定した。また張出し加工材の加工性、時効割れ性も観
察した。
Example 1 Cr-in which Md 30 based on the composition shown in Table 2 was changed to 5 levels
Ni-based stainless steel (SUS304 steel) was cast by a twin roll type continuous casting machine at a solidification cooling rate of about 300 ° C./sec into a thin strip-shaped slab having a thickness of 2.5 mm.
20 ~ 500 ℃ / sec from 400 ℃ to 1200 ℃
The slabs having various γ grain sizes were obtained by cooling at a cooling rate of. Then, pickling, cold rolling (total rolling rate 76%) and final annealing were performed, and temper rolling was applied to produce a thin plate product. After that, the colony size of the plate surface in the 1/4 plate thickness layer portion of the product was measured by the crystal orientation topography analyzer. Moreover, the cylindrical flat bottom overhanging process of the product (Punch diameter 50 mm,
The overhanging height was 10 mm), and the height of roughened processed surface of the flat bottom was measured. In addition, the workability and aging crackability of the overhanging material were also observed.

【0031】[0031]

【表2】 [Table 2]

【0032】それらの結果を表3に示す。Md30を30
℃以上にした本発明鋼(サンプル6,7)についてはい
ずれも加工肌荒れ高さが許容限度以下となり良好であっ
たが、Md30を30℃未満とした比較例(サンプル8)
は加工肌荒れが不良となり、Md30を60℃以上とした
比較例(サンプル9)は加工肌荒れは良好であったが、
加工性が不良であった。また時効割れ性はすべてのサン
プルについて良好であった。
The results are shown in Table 3. Md 30 to 30
Regarding the steels of the present invention (Samples 6 and 7) that were heated to ℃ or higher, the processed surface roughness height was all below the allowable limit, which was good, but a comparative example (Sample 8) in which Md 30 was less than 30
The processed surface was poor, and the comparative example (Sample 9) in which Md 30 was 60 ° C. or higher was excellent in processed surface,
The workability was poor. Also, the age cracking property was good for all the samples.

【0033】[0033]

【表3】 [Table 3]

【0034】実施例2 実施例1に記した鋳造条件によって製造した表2に示す
本発明鋼(サンプル7、鋳片の平均γ粒径106μm)
を用いて、2回圧延法による製品材の加工肌荒れ特性を
調べた。すなわち鋳片を酸洗後にまず圧下率40%の冷
間圧延を施し、その後中間焼鈍(1150℃,20秒保
定)を加え、ついで0.6mm厚さになるまで冷間圧延を
行った。その後最終焼鈍焼鈍及び調質圧延を行い、実施
例1と同様に加工肌荒れ、その他の特性を調べた。その
結果を表4に示す。肌荒れは極めて良好であった。
Example 2 The steel of the present invention shown in Table 2 produced under the casting conditions described in Example 1 (Sample 7, average γ grain size of cast slab 106 μm)
Was used to examine the roughness characteristics of the processed surface of the product material by the double rolling method. That is, the slab was pickled, first cold-rolled at a reduction rate of 40%, then subjected to intermediate annealing (1150 ° C., held for 20 seconds), and then cold-rolled to a thickness of 0.6 mm. After that, final annealing annealing and temper rolling were performed, and the roughened surface and other characteristics were examined in the same manner as in Example 1. The results are shown in Table 4. The rough skin was extremely good.

【0035】[0035]

【表4】 [Table 4]

【0036】[0036]

【発明の効果】以上説明したように、本発明によればス
トリップ連鋳法製造プロセスによって加工肌荒れの発生
しない表面品質の優れたCr−Ni系ステンレス鋼薄板
が提供可能になる。
As described above, according to the present invention, it is possible to provide a Cr-Ni-based stainless steel thin plate having an excellent surface quality that does not cause roughening of the processed surface by the strip continuous casting manufacturing process.

【図面の簡単な説明】[Brief description of drawings]

【図1】鋳片平均γ粒径と製品の加工肌荒れ高さの関係
を、いくつかのMd30の材料について比較して示す図で
ある。
FIG. 1 is a view showing a relationship between a cast slab average γ grain size and a processed surface roughness of a product in comparison with some materials having Md 30 .

【図2】加工肌荒れの平均うねり幅、平均うねり長さと
加工肌荒れ高さとの関係を示す図である。
FIG. 2 is a diagram showing the relationship between the average waviness width and average waviness length of processed skin roughness and the processed skin roughness height.

【図3】加工肌荒れの顕著にみられた製品の1/4板厚
層部の結晶方位分布(ODF)の解析結果を示す図であ
る。
FIG. 3 is a diagram showing an analysis result of a crystal orientation distribution (ODF) of a ¼ plate thickness layer portion of a product in which a roughened surface is noticeably observed.

【図4】コロニーの分布状態を模式図的に示した図であ
る。
FIG. 4 is a diagram schematically showing a distribution state of colonies.

【図5】A及びB方位コロニーの平均寸法と加工肌荒れ
高さの関係を示した図である。
FIG. 5 is a diagram showing the relationship between the average size of A and B orientation colonies and the height of roughened skin.

─────────────────────────────────────────────────────
─────────────────────────────────────────────────── ───

【手続補正書】[Procedure amendment]

【提出日】平成4年11月20日[Submission date] November 20, 1992

【手続補正1】[Procedure Amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0024[Name of item to be corrected] 0024

【補正方法】変更[Correction method] Change

【補正内容】[Correction content]

【0024】本発明における急冷鋳片の集合組織は{1
0}<uv0>となる。すなわち板面法線と<001
>軸が平行で、γ相の結晶粒はこの軸回りに種々の方向
を向いて回転している。Md30点が30℃以下となる低
Md30材の急冷鋳片を冷延すると、特に鋳片の平均γ粒
径が約100μmを上回るような粗大粒組織である場
合、冷延中の不均一変形が助長される。また加工誘起マ
ルテンサイトの発生量も比較的少ないので、それらが組
織的にも不均一な場所に生成する。このときに生成する
マルテンサイト相はBCC結晶構造を示すので、圧延に
よってこの相はいわゆるα鉄の圧延集合組織を示し、
{113}<011>αや{332}<113>αが主
方位となる。一方、γ母相の圧延集合組織の主方位は
{110}<112>になる。冷延後、焼鈍を行うと前
述のマルテンサイトはγ母相に逆変態する。その際に、
α鉄の圧延方位はK−S方位関係によって、γ相方位
{110}<001>,{110}<112>,{11
0}<111>に変態する。またγ相の圧延方位である
{110}<112>バンド組織の近傍からは、高温域
焼鈍の粒成長方位である{112}<111>や{11
3}<332>が生成する。鋳片の平均γ粒径が粗大な
場合は、冷延時の変形の不均一性が冷延方位の局在化に
反映され、それらがそのまま焼鈍集合組織に影響を及ぼ
す。その結果、{112}方位コロニーと{110}方
位コロニーを形成すると考えられる。
The texture of the quenched slab in the present invention is {1
0 0} <uv0>. That is, the plate surface normal and <001
The> axis is parallel, and the γ-phase crystal grains are rotating around this axis in various directions. When a rapidly cooled slab of a low Md 30 material having an Md 30 point of 30 ° C. or less is cold-rolled, especially when the slab has a coarse grain structure such that the average γ grain size exceeds about 100 μm, unevenness during cold rolling is observed. Deformation is promoted. Further, since the amount of processing-induced martensite generated is relatively small, they are generated in a structurally non-uniform place. Since the martensite phase generated at this time has a BCC crystal structure, this phase shows a so-called α-iron rolling texture by rolling,
The main orientation is {113} <011> α or {332} <113> α. On the other hand, the main orientation of the rolling texture of the γ matrix is {110} <112>. When annealed after cold rolling, the above-mentioned martensite undergoes reverse transformation into a γ matrix. At that time,
The rolling orientation of α iron depends on the K-S orientation relationship, and the γ phase orientations {110} <001>, {110} <112>, {11
0} <111>. Further, from the vicinity of the {110} <112> band structure, which is the rolling direction of the γ phase, {112} <111> or {11} which is the grain growth direction of high temperature annealing.
3} <332> is generated. When the average γ grain size of the slab is coarse, the non-uniformity of deformation during cold rolling is reflected in the localization of cold rolling orientation, which directly affects the annealing texture. As a result, it is considered that {112} oriented colonies and {110} oriented colonies are formed.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 C21D 8/02 D 7412−4K 9/46 Q C22C 38/44 (72)発明者 寺岡 慎一 千葉県富津市新富20−1 新日本製鐵株式 会社技術開発本部内─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Office reference number FI Technical display location C21D 8/02 D 7412-4K 9/46 Q C22C 38/44 (72) Inventor Shinichi Teraoka Chiba Prefecture 20-1 Shintomi, Futtsu-shi Nippon Steel Corp. Technology Development Division

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 C+Nが0.090mass%以下でか
つ、Md30=413−462(C+N)−9.2Si−
8.1Mn−13.7Cr−18.5Mo−9.5(N
i+Cu)(各成分はmass%)で定義されるMd30
が30〜60℃となる組成を有し、しかも鋼板の板面に
平行な任意の板厚層部位面において、圧延方向の平均寸
法がdRD(A)であり板幅方向の平均寸法がdTD(A)
である主たる結晶方位が{112}<111>,{11
3}<332>から成るコロニーAと、圧延方向の平均
寸法がdRD(B)であり板幅方向の平均寸法がd
TD(B)である主たる結晶方位が{110}<111
>,{110}<112>,{110}<001>から
なるコロニーBの両者が、鋼板中に互いに均一に混じり
あって存在し、かつdRD(A)又はdRD(B)がそれぞ
れ300μm以下であり、dTD(A)又はdTD(B)が
それぞれ200μm以下であることを特徴とする加工肌
荒れのないCr−Ni系ステンレス鋼板。
1. C + N is 0.090 mass% or less and Md 30 = 413-462 (C + N) -9.2Si-
8.1Mn-13.7Cr-18.5Mo-9.5 (N
i + Cu) (Md 30 defined by mass%)
Has a composition of 30 to 60 ° C., and the average dimension in the rolling direction is d RD (A) and the average dimension in the sheet width direction is d on an arbitrary plate thickness layer site surface parallel to the plate surface of the steel sheet. TD (A)
The main crystal orientations are {112} <111>, {11}
3} <332>, the average dimension in the rolling direction is d RD (B), and the average dimension in the strip width direction is d.
The main crystal orientation of TD (B) is {110} <111
>, {110} <112>, and {110} <001> are both present in the steel sheet evenly mixed with each other, and d RD (A) or d RD (B) are each 300 μm. It is below, and d TD (A) or d TD (B) is 200 μm or less, respectively.
【請求項2】 C+Nが0.090mass%以下でか
つMd30=413−462(C+N)−9.2Si−
8.1Mn−13.7Cr−18.5Mo−9.5(N
i+Cu)(各成分はmass%)で定義されるMd30
が30〜60℃となる組成を有する溶鋼を鋳型側面が鋳
片と同期して移動する連続鋳造機によって、100℃/
sec以上の凝固冷却速度で厚さ10mm以下の薄帯状鋳
片に鋳造し、凝固後は可及的高温から1200℃までを
50℃/sec以上の冷却速度で冷却し、次いで冷間圧
延、最終焼鈍を行うことを特徴とする加工肌荒れのない
Cr−Ni系ステンレス鋼板の製造方法。
2. C + N is 0.090 mass% or less and Md 30 = 413-462 (C + N) -9.2Si-
8.1Mn-13.7Cr-18.5Mo-9.5 (N
i + Cu) (Md 30 defined by mass%)
Of molten steel having a composition of 30 to 60 ° C. by a continuous casting machine in which the side surface of the mold moves in synchronization with the slab
It is cast into a strip-shaped slab with a thickness of 10 mm or less at a solidification cooling rate of sec or more, and after solidification, it is cooled from the highest possible temperature to 1200 ° C. at a cooling rate of 50 ° C./sec or more, then cold-rolled, and finally. A method for producing a Cr-Ni-based stainless steel sheet having no roughened surface, characterized by performing annealing.
【請求項3】 冷間圧延において、加工率30%以上の
冷間圧延を施し、次いで1000〜1200℃の温度で
中間焼鈍を加えた後に最終板厚まで冷間圧延する請求項
2記載のCr−Ni系ステンレス鋼板の製造方法。
3. The Cr according to claim 2, wherein in the cold rolling, cold rolling with a working rate of 30% or more is performed, and then intermediate annealing is performed at a temperature of 1000 to 1200 ° C., and then cold rolling is performed to a final plate thickness. -A method for manufacturing a Ni-based stainless steel sheet.
JP4248060A 1992-04-16 1992-09-17 Cr-Ni-based stainless steel thin plate having no roughened surface and method for producing the same Expired - Lifetime JP2677493B2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP4248060A JP2677493B2 (en) 1992-09-17 1992-09-17 Cr-Ni-based stainless steel thin plate having no roughened surface and method for producing the same
DE69320140T DE69320140T2 (en) 1992-04-16 1993-04-16 AUSTENITIC STAINLESS STEEL PLATE WITH EXCELLENT SURFACE AND THEIR PRODUCTION
PCT/JP1993/000497 WO1993021355A1 (en) 1992-04-16 1993-04-16 Austenitic stainless steel sheet with excellent surface quality and production thereof
EP93908107A EP0594866B1 (en) 1992-04-16 1993-04-16 Austenitic stainless steel sheet with excellent surface quality and production thereof
ES93908107T ES2118950T3 (en) 1992-04-16 1993-04-16 AUSTENITIC STAINLESS STEEL SHEET WITH EXCELLENT SURFACE QUALITY AND PRODUCTION OF THE SAME.
KR1019930703911A KR960014516B1 (en) 1992-04-16 1993-04-16 Austenitic stainless steel sheet with excellent surface quality and production thereof
US08/167,832 US5376195A (en) 1992-04-16 1993-04-16 Austenitic stainless steel sheet having excellent surface quality and method of producing the same

Applications Claiming Priority (1)

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JP4248060A JP2677493B2 (en) 1992-09-17 1992-09-17 Cr-Ni-based stainless steel thin plate having no roughened surface and method for producing the same

Publications (2)

Publication Number Publication Date
JPH06100989A true JPH06100989A (en) 1994-04-12
JP2677493B2 JP2677493B2 (en) 1997-11-17

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005501741A (en) * 2001-09-14 2005-01-20 ニューコア・コーポレーション Steel strip casting

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02267225A (en) * 1989-04-05 1990-11-01 Nippon Steel Corp Production of cr-ni stainless steel sheet excellent in surface quality
JPH04214844A (en) * 1990-05-28 1992-08-05 Hitachi Metals Ltd High strength and high toughness stainless steel and its manufacture

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02267225A (en) * 1989-04-05 1990-11-01 Nippon Steel Corp Production of cr-ni stainless steel sheet excellent in surface quality
JPH04214844A (en) * 1990-05-28 1992-08-05 Hitachi Metals Ltd High strength and high toughness stainless steel and its manufacture

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005501741A (en) * 2001-09-14 2005-01-20 ニューコア・コーポレーション Steel strip casting

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